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Material Safety Data Sheet

Alcohol denatured 190 proof MSDS
Section 1: Chemical Product and Company Identification
Product Name: Alcohol denatured 190 proof

Contact Information:
[Link], Inc.
14025 Smith Rd.
Houston, Texas 77396

Catalog Codes: SLA4291

CAS#: Mixture.

US Sales: 1-800-901-7247
International Sales: 1-281-441-4400

RTECS: Not applicable.

TSCA: TSCA 8(b) inventory: Ethyl alcohol 200 Proof;
Isopropyl alcohol; Methyl alcohol

Order Online: [Link]

CHEMTREC (24HR Emergency Telephone), call:
1-800-424-9300

CI#: Not applicable.

Synonym:

International CHEMTREC, call: 1-703-527-3887

Chemical Name: Alcohol, Denatured with IPA and

Methanol

For non-emergency assistance, call: 1-281-441-4400

Chemical Formula: C2-H5-OH

Section 2: Composition and Information on Ingredients

Composition:
Name

CAS #

% by Weight

Ethyl alcohol 200 Proof

64-17-5

90

Isopropyl alcohol

67-63-0

Methyl alcohol

67-56-1

Toxicological Data on Ingredients: Ethyl alcohol 200 Proof: ORAL (LD50): Acute: 7060 mg/kg [Rat.]. 3450 mg/kg [Mouse].
VAPOR (LC50): Acute: 20000 ppm 8 hours [Rat]. 39000 mg/m 4 hours [Mouse]. Isopropyl alcohol: ORAL (LD50): Acute: 5045
mg/kg [Rat]. 3600 mg/kg [Mouse]. 6410 mg/kg [Rabbit]. DERMAL (LD50): Acute: 12800 mg/kg [Rabbit]. Methyl alcohol: ORAL
(LD50): Acute: 5628 mg/kg [Rat.]. DERMAL (LD50): Acute: 15800 mg/kg [Rabbit.].

Section 3: Hazards Identification

Potential Acute Health Effects:
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of
skin contact (permeator).
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof]. Classified
A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 200 Proof]. Classified A4 (Not classifiable for human
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or animal.) by ACGIH, 3 (Not classifiable for human.) by IARC [Isopropyl alcohol]. MUTAGENIC EFFECTS: Mutagenic for
mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for bacteria and/or yeast. [Ethyl alcohol 200 Proof]. Mutagenic
for mammalian somatic cells. [Methyl alcohol]. Mutagenic for bacteria and/or yeast. [Methyl alcohol]. TERATOGENIC
EFFECTS: Classified PROVEN for human [Ethyl alcohol 200 Proof]. Classified POSSIBLE for human [Methyl alcohol].
DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol 200 Proof]. Classified Reproductive
system/toxin/female, Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof]. Classified Reproductive system/
toxin/female, Development toxin [POSSIBLE] [Isopropyl alcohol]. Classified Reproductive system/toxin/female, Reproductive
system/toxin/male [POSSIBLE] [Methyl alcohol]. The substance is toxic to blood, the reproductive system, liver, upper
respiratory tract, skin, eyes, central nervous system (CNS). The substance may be toxic to kidneys, lungs, brain, peripheral
nervous system, gastrointestinal tract. Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be [Link] clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention if symptoms appear.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.
Auto-Ignition Temperature: The lowest known value is 363C (685.4F) (Ethyl alcohol 200 Proof).
Flash Points: CLOSED CUP: Between -18C (0F) and 23C (73F).
Flammable Limits: The greatest known range is LOWER: 6% UPPER: 36.5% (Methyl alcohol)
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Highly flammable in presence of open flames and sparks, of heat. Flammable in presence of combustible materials. Slightly
flammable to flammable in presence of oxidizing materials.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
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Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,
water spray or fog.
Special Remarks on Fire Hazards:
Containers should be grounded. CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME Vapor may travel considerable
distance to source of ignition and flash back. (Ethyl alcohol 200 Proof)
Special Remarks on Explosion Hazards:
Ethanol has an explosive reaction with the oxidized coating around potassium metal. Ethanol ignites and then explodes on
contact with acetic anhydride + sodium hydrosulfate (ignites and may explode), disulfuric acid + nitric acid, phosphorous(III)
oxide platinum, potassium-tert-butoxide+ acids. Ethanol forms explosive products in reaction with the following compound :
ammonia + silver nitrate (forms silver nitride and silver fulminate), iodine + phosphorus (forms ethane iodide), magnesium
perchlorate (forms ethyl perchlorate), mercuric nitrate, nitric acid + silver (forms silver fulminate) silver nitrate (forms ethyl
nitrate) silver(I) oxide + ammonia or hydrazine (forms silver nitride and silver fulminate), sodium (evolves hydrogen gas). (Ethyl
alcohol 200 Proof)

Section 6: Accidental Release Measures

Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:
Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined
areas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS
and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do
not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear
suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids, alkalis, moisture.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and
sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Do not store above 23C (73.4F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
Ethyl alcohol 200 Proof TWA: 1000 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 1000 (ppm) from OSHA (PEL)
[United States] TWA: 1900 (mg/m3) from OSHA (PEL) [United States] TWA: 1000 (ppm) from NIOSH TWA: 1000 (ppm)
[United Kingdom (UK)] TWA: 1920 (mg/m3) [United Kingdom (UK)] TWA: 1000 STEL: 1250 (ppm) [Canada] Isopropyl alcohol
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TWA: 983 STEL: 1230 (mg/m3) [Australia] TWA: 200 STEL: 400 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 980
STEL: 1225 (mg/m3) from NIOSH TWA: 400 STEL: 500 (ppm) from NIOSH TWA: 400 STEL: 500 (ppm) [United Kingdom
(UK)]

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.
Odor: Alcohol like.
Taste: Not available.
Molecular Weight: Not applicable.
Color: Clear Colorless.
pH (1% soln/water): Not available.
Boiling Point: The lowest known value is 64.5C (148.1F) (Methyl alcohol). Weighted average: 78C (172.4F)
Melting Point:
May start to solidify at -88.5C (-127.3F) based on data for: Isopropyl alcohol. Weighted average: -112C (-169.6F)
Critical Temperature: The lowest known value is 235C (455F) (Isopropyl alcohol).
Specific Gravity: Weighted average: 0.79 (Water = 1)
Vapor Pressure: The highest known value is 13.3 kPa (@ 20C) (Methyl alcohol). Weighted average: 6.01 kPa (@ 20C)
Vapor Density: The highest known value is 2.07 (Air = 1) (Isopropyl alcohol). Weighted average: 1.59 (Air = 1)
Volatility: Not available.
Odor Threshold: The highest known value is 100 ppm (Ethyl alcohol 200 Proof) Weighted average: 97.15 ppm
Water/Oil Dist. Coeff.: The product is equally soluble in oil and water.
Ionicity (in Water): Non-ionic.
Dispersion Properties: See solubility in water, methanol, diethyl ether, n-octanol, acetone.
Solubility:
Easily soluble in cold water, hot water, n-octanol. Soluble in methanol, diethyl ether, acetone.

Section 10: Stability and Reactivity Data

Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Excess Heat, ingnition sources, incompatible materials
Incompatibility with various substances:
Reactive with oxidizing agents, acids, alkalis, moisture. Slightly reactive to reactive with metals.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Ethanol rapidly absorbs moisture from the air. Can react vigorously with oxiders. The following oxidants have been
demonstrated to undergo vigorous/explosive reaction with ethanol: barium perchlorate, bromine pentafluoride, calcium
hypochlorite, chloryl perchlorate, chromium trioxide, chromyl chloride, dioxygen difluoride, disulfuryl difluoride, fluorine nitrate,
hydrogen peroxide, iodine heptafluoride, nitric acid nitrosyl perchlorate, perchloric acid permanganic acid, peroxodisulfuric
acid, potassium dioxide, potassium perchlorate, potassium permanganate, ruthenium(VIII) oxide, silver perchlorate, silver
peroxide, uranium hexafluoride, uranyl perchlorate. Ethanol reacts violently/expodes with the following compounds: acetyl
bromide (evolves hydrogen bromide) acetyl chloride, aluminum, sesquibromide ethylate, ammonium hydroxide & silver oxide,
chlorate, chromic anhydride, cyanuric acid + water, dichloromethane + sulfuric acid + nitrate (or) nitrite, hydrogen peroxide +
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Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact. Inhalation.
Toxicity to Animals:
Acute oral toxicity (LD50): 3450 mg/kg [Mouse]. (Ethyl alcohol 200 Proof). Acute dermal toxicity (LD50): 12800 mg/kg [Rabbit].
(Isopropyl alcohol).
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof]. Classified
A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 200 Proof]. Classified A4 (Not classifiable for human
or animal.) by ACGIH, 3 (Not classifiable for human.) by IARC [Isopropyl alcohol]. MUTAGENIC EFFECTS: Mutagenic for
mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for bacteria and/or yeast. [Ethyl alcohol 200 Proof]. Mutagenic
for mammalian somatic cells. [Methyl alcohol]. Mutagenic for bacteria and/or yeast. [Methyl alcohol]. TERATOGENIC
EFFECTS: Classified PROVEN for human [Ethyl alcohol 200 Proof]. Classified POSSIBLE for human [Methyl alcohol].
DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol 200 Proof]. Classified Reproductive
system/toxin/female, Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof]. Classified Reproductive system/
toxin/female, Development toxin [POSSIBLE] [Isopropyl alcohol]. Classified Reproductive system/toxin/female, Reproductive
system/toxin/male [POSSIBLE] [Methyl alcohol]. Contains material which may cause damage to the following organs: kidneys,
lungs, brain, peripheral nervous system, gastrointestinal tract.
Other Toxic Effects on Humans:
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May affect genetic material (mutagenic) Causes adverse reproductive effects and birth defects (teratogenic) , based on
moderate to heavy consumption. May cause cancer based on animal data. Human: passes through the placenta, excreted in
maternal milk. (Ethyl alcohol 200 Proof)
Special Remarks on other Toxic Effects on Humans:
Acute potential health effects: Skin: causes skin irritation Eyes: causes eye irritation Ingestion: May cause gastrointestinal tract
irritation with nausea, vomiting, diarrhea, and alterations in gastric secretions. May affect the brain, behavior/central nervous
system (central nervous system depression - amnesia, headache, muscular incoordination, excitation, mild euphoria, slurred
speech, drowsiness, staggaring gait, fatigue, changes in mood/personality, excessive talking, dizziness, ataxia, somnolence,
coma/narcosis, hallucinations, distorted perceptions, general anesthetic), peripherial nervous system (spastic paralysis),
vision (diplopia). Moderately toxic and narcotic in high concentrations. May also affect metabolism, blood, liver, respiration
(dyspnea), and endocrine system. Contains Methanol, which may cause blindness if swallowed May affect respiratory tract,
cardiovascular(cardiac arrhythmias, hypotension), and urinary systems. Inhalation: May cause irritation of the respiratory tract
and affect brain, behavior/central nervous system with symptoms similar to ingestion. Chronic Potential Health Effects: Skin:
Prolonged or repeated skin contact may casue dermatitis, an allergic reaction. Ingestion: Prolonged or repeated ingestion will
have similiar effects as acute ingestion. It may also affect the brain.

Section 12: Ecological Information

Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

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Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 3: Flammable liquid.
Identification: : Denatured Alcohol (Ethyl alcohol 200 Proof) UNNA: 1987 PG: II
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:
Rhode Island RTK hazardous substances: Ethyl alcohol 200 Proof; Isopropyl alcohol; Methyl alcohol Pennsylvania RTK: Ethyl
alcohol 200 Proof; Isopropyl alcohol; Methyl alcohol Florida: Ethyl alcohol 200 Proof; Isopropyl alcohol Minnesota: Isopropyl
alcohol; Methyl alcohol Massachusetts RTK: Ethyl alcohol 200 Proof; Isopropyl alcohol; Methyl alcohol New Jersey: Ethyl
alcohol 200 Proof; Isopropyl alcohol; Methyl alcohol TSCA 8(b) inventory: Ethyl alcohol 200 Proof; Isopropyl alcohol; Methyl
alcohol TSCA 4(a) final testing order: Isopropyl alcohol TSCA 8(d) H and S data reporting: Isopropyl alcohol: Effective date:
12/15/86 Sunset Date: 12/15/96 TSCA 12(b) one time export: Isopropyl alcohol SARA 313 toxic chemical notification and
release reporting: Isopropyl alcohol 5%; Methyl alcohol 5% CERCLA: Hazardous substances.: Methyl alcohol: 5000 lbs. (2268
kg);
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS B-2: Flammable liquid with a flash point lower than 37.8C (100F). CLASS D-2B: Material causing other toxic effects
(TOXIC).
DSCL (EEC):
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 3
Reactivity: 0
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 0
Flammability: 3
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.
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Other Special Considerations: Not available.

Created: 10/09/2005 03:38 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall [Link] be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if [Link]
has been advised of the possibility of such damages.

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