MATERIAL SAFETY DATA SHEET

Product Trade Name: PARAGON 100 E+

Revision Date: 06-Feb-2014

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING

Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according
to the criteria of ADG.

Manufacturer/Supplier Halliburton Australia Pty. Ltd.

15 Marriott Road
Jandakot
WA 6164
Australia

ACN Number: 009 000 775

Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300

Product Emergency Telephone

Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274

Fire, Police & Ambulance - Emergency Telephone

Australia: 000
Papua New Guinea: 000
New Zealand: 111

Identification of Substances or Preparation

Product Trade Name: PARAGON 100 E+

Synonyms: None
Chemical Family: Aromatic hydrocarbon
UN Number: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: 3[Y]
Poisons Schedule: S6
Application: Solvent

Prepared By Chemical Compliance

Telephone: 1-580-251-4335
e-mail: [email protected]

2. HAZARDS IDENTIFICATION

Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according
to the criteria of ADG.

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Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness,
and other central nervous system effects. May be harmful if swallowed. Potential
carcinogen. May cause lung damage if swallowed. Combustible

Classification Xn - Harmful.

Risk Phrases R65 Harmful: may cause lung damage if swallowed.

R40 Limited evidence of a carcinogenic effect.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.

Safety Phrases S2 Keep out of reach of children.

S23 Do not breathe gas, fumes, vapour or spray.

S24 Avoid contact with skin.

S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this
container or label.

HSNO Classification 3.1D Flammable Liquids - Low hazard

6.1D (Oral) Acutely Toxic Substances
6.3B Mildly irritating to the skin
6.4A Irritating to the eye
6.7B Suspected human carcinogens
6.9B Harmful to human target organs or systems
9.1A Very ecotoxic in the aquatic environment

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances CAS Number PERCENT (w/w) Australia NOHSCNew Zealand ACGIH TLV-TWA
WES
Heavy aromatic petroleum 64742-94-5 60 - 100% Not applicable Not applicable Not applicable
naphtha
Naphthalene 91-20-3 5 - 10% TWA: 10 ppm TWA: STEL: 15 ppm TWA: 10 ppm
52 mg/m3 STEL: 79 mg/m3 STEL: 15 ppm
STEL: 15 ppm TWA: 10 ppm TWA:
STEL: 79 mg/m3 52 mg/m3
1,2,4 Trimethylbenzene 95-63-6 1 - 5% TWA: 25 ppm TWA: TWA: 25 ppm TWA: 25 ppm
123 mg/m3 123 mg/m3
Non-Hazardous Substance to Total of 100%

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably
mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove
contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of
water for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent
aspiration.

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Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Suitable Extinguishing Media

Carbon dioxide, dry chemical, foam.

Extinguishing media which must not be used for safety reasons

Avoid spraying water directly into storage containers due to danger of boilover.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in
fire. Avoid spraying water directly into storage containers due to danger of
boilover. Decomposition in fire may produce toxic gases. Vapors are heavier than
air and may accumulate in low areas. Vapors may travel along the ground to be
ignited at distant locations.

Special Protective Equipment Full protective clothing and approved self-contained breathing apparatus required
for Fire-Fighters for fire fighting personnel.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary Use appropriate protective equipment. Wear self-contained breathing apparatus in
Measures enclosed areas.

Environmental Precautionary Prevent from entering sewers, waterways, or low areas.

Measures

Procedure for Cleaning / Remove ignition sources and work with non-sparking tools. Isolate spill and stop
Absorption leak where safe. Contain spill with sand or other inert materials. Scoop up and
remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands
after use. Launder contaminated clothing before reuse. Ground and bond
containers when transferring from one container to another. Avoid breathing mist.
Material is slippery underfoot. Open container slowly to release pressure.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Store in a
cool well ventilated area. Keep container closed when not in use. Store locked up.
Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas
without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below
occupational exposure limits or if exposure is unknown, wear a NIOSH certified,
European Standard EN 149, or equivalent respirator when using this product.
Selection of and instruction on using all personal protective equipment, including
respirators, should be performed by an Industrial Hygienist or other qualified
professional.

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

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Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear
Odor: Sweet aromatic
pH: 7
Specific Gravity @ 20 C (Water=1): 0.897
Density @ 20 C (kg/l): 0.897
Bulk Density @ 20 C (kg/M3): 898
Boiling Point/Range (C): 167
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): 66
Flash Point Method: TCC
Autoignition Temperature (C): 545
Flammability Limits in Air - Lower (g/m 3): Not Determined
Flammability Limits in Air - Lower (%): 0.8
Flammability Limits in Air - Upper (g/m3): Not Determined
Flammability Limits in Air - Upper (%): 5.9
Vapor Pressure @ 20 C (mmHg): 0.56
Vapor Density (Air=1): 4.7
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate=1): < 0.1
Solubility in Water (g/100ml): Insoluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistokes): .99
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): Not Determined
Decomposition Temperature (C): > 210

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to Strong oxidizers.

Avoid)

Hazardous Decomposition Carbon monoxide and carbon dioxide.

Products

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

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Sympotoms related to exposure
Acute Toxicity
Inhalation May cause respiratory irritation. May cause central nervous system depression including
headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech,
giddiness and unconsciousness.

Eye Contact May cause eye irritation

Skin Contact May cause skin irritation.
Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty
breathing, wheezing, coughing up blood and pneumonia, which can be fatal. May cause
central nervous system depression including headache, dizziness, drowsiness, muscular
weakness, incoordination, slowed reaction time, fatigue blurred vision, slurred speech,
giddiness, tremors and convulsions.

Chronic Effects/Carcinogenicity
The International Agency for Research on Cancer (IARC) has evaluated naphthalene and
determined it to be a possible carcinogen to humans (Group 2B, based on sufficient
evidence in experimental animals and inadequate evidence in humans).

Toxicology data for the components

Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Heavy aromatic 64742-94-5 > 5000 mg/kg (Rat) > 2000 mg/kg (Rabbit) 590 mg/m3 ( Rat ) 4 h
petroleum naphtha
Naphthalene 91-20-3 490 mg/kg ( Rat ) 2500 mg/kg (Rat) 340 mg/m3 ( Rat ) 1 h
20 g/kg (Rabbit)
1120 mg/kg (Rabbit)
1,2,4 Trimethylbenzene 95-63-6 3400 mg/kg ( Rat ) 3160 mg/kg (Rabbit) 18 g/m3 ( Rat ) 4 h
8970 mg/kg ( Rat ) > 3440 mg/kg (Rat)

12. ECOLOGICAL INFORMATION

Ecotoxicological Information

Ecotoxicity Product
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity: TLM48: 12 mg/l (Acartia tonsa)

Acute Algae Toxicity: EC50: < 1 mg/l (Skeletonema costatum)

Ecotoxicity Substance
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates
Microorganisms
Heavy aromatic 64742-94-5 EC50: < 1 mg/l LC50: 2.34 mg/L No information available EC50(48h): 0.95 mg/L
petroleum naphtha (Skeletonema costatum) (Oncorhynchus mykiss) (Daphnia magna)
LC50: 41 mg/L EC50(48H): 0.55 mg/L
(Pimephales promelas) (Daphnia magna)
LC50: 0.84 mg/L
(Oncorhynchus mykiss)
Naphthalene 91-20-3 EC50(72h): 0.4 mg/L LC50(96h) 6.08 mg/L No information available EC50(48h): 2.16 mg/L
(Skeletonema costatum) (Pimephales promelas) (Daphnia magna)
LC50(96h): 1.2 mg/L
(Oncorhynchus
gorbuscha)
LC50(96h): 1.6 mg/L
(Oncorhynchus mykiss)
NOEC(40d): 0.37 mg/L
(Oncorhynchus kisutch)
NOEC(30d): < 0.85 mg/L
Pimephales promelas)

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1,2,4 95-63-6 No information available LC50: 7.19-8.28 mg/L No information available EC50: 6.14 mg/L
Trimethylbenzene (Pimephales promelas) (Daphnia magna)
LC50(48h): 3.6 mg/L
(Daphnia magna)
LC50(96h): 2.16 mg/L
(Mysidopsis bahia)

12.2 Persistence and degradability

Substances Persistence and Degradability

Naphthalene Readily biodegradable (100% @ 7d)
1,2,4 Trimethylbenzene Readily biodegradable

12.3 Bioaccumulative potential

Substances Log Pow

Heavy aromatic petroleum naphtha 2.9 - 6.1
Naphthalene 3.28
1,2,4 Trimethylbenzene 3.42

12.4 Mobility in soil

No information available

12.5 Results of PBT and vPvB assessment

No information available.

12.6 Other adverse effects

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation
ADR
Not restricted

Air Transportation
ICAO/IATA
Not restricted

Sea Transportation
IMDG
Not restricted

Other Transportation Information

Labels: None

15. REGULATORY INFORMATION

Chemical Inventories

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Australian AICS Inventory All components listed on inventory or are exempt.
New Zealand Inventory of All components listed on inventory or are exempt.
Chemicals
US TSCA Inventory All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS

Classification Xn - Harmful.

Risk Phrases R65 Harmful: may cause lung damage if swallowed.

R40 Limited evidence of a carcinogenic effect.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.

Safety Phrases S2 Keep out of reach of children.

S23 Do not breathe gas, fumes, vapour or spray.
S24 Avoid contact with skin.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and
show this container or label.

16. OTHER INFORMATION

The following sections have been revised since the last issue of this SDS
Not applicable

Contact

Australian Poisons Information Centre

24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100

New Zealand National Poisons Centre

0800 764 766

Additional information For additional information on the use of this product, contact your local Halliburton
representative.

For questions about the Safety Data Sheet for this or other Halliburton products,
contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to

accuracy or completeness. The information is obtained from various sources
including the manufacturer and other third party sources. The information may not
be valid under all conditions nor if this material is used in combination with other
materials or in any process. Final determination of suitability of any material is the
sole responsibility of the user.

***END OF MSDS***

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