TUGAS Termodinamika Bubble Point & Dew Point (Sayid Jakfar, Levina Mandalagiri, Indah Damayanti, Devi Lestariningsih,

Reika Ditassya Puspita, Mafaz Setyawan, Lia Pemulasari, Hesti Prihastuti)

Psaturated
Material Name A B C
A - B/(T+C) Psat=exp(A-B/(T+C))
Benzene 13.7819 2726.81 217.572 4.9163 136.4968

Ethylbenzene 13.9726 3259.93 212.3 3.1888 24.2603

Mencari P Bubble Mencari P DEW PBubble untuk kedua campuran di atas PDew untuk kedua campuran di atas

Xi (Liquid fraction) Yi (Vapor fraction) P1Sat P2Sat Yi (Vapor fraction) Xi (Liquid fraction) Diagram P-x-y Campuran Benzene/Ethylbenzene
PBubble PDew
X1 X2 T Y1 Y2 T X1 X2 Y1 Y2 Y1 Y2 X1 X2 160.00

0.90 0.10 90 o
C 0.05 0.95 90 o
C 0.00 1.00 24.26 0.00 1.00 136.50 24.26 0.00 1.00 24.26 0.00 1.00

0.05 0.95 29.87 0.23 0.77 136.50 24.26 0.05 0.95 25.30 0.01 0.99 140.00
136.50
ln P1Sat = ln P2 Sat = A2 - 0.10 0.90 35.48 0.38 0.62 136.50 24.26 0.10 0.90 26.43 0.02 0.98
130.88
0.15 0.85 41.10 0.50 0.50 136.50 24.26 0.15 0.85 27.67 0.03 0.97 125.27
120.00 119.66
P1Sat = exp(A1 - ) P1Sat = 136.50 KPa
P2Sat = exp( A2 - ) P2Sat = 24.26 KPa 0.20 0.80 46.71 0.58 0.42 136.50 24.26 0.20 0.80 29.04 0.04 0.96 Liquid Region 114.05
108.44 110.85
0.25 0.75 52.32 0.65 0.35 136.50 24.26 0.25 0.75 30.54 0.06 0.94
100.00
102.83
PBubble

Pressure [kPa]
0.30 0.70 57.93 0.71 0.29 136.50 24.26 0.30 0.70 32.20 0.07 0.93
97.21
93.32
PBubble = X1 . P1Sat + X2 . P2Sat PDew = 0.35 0.65 63.54 0.75 0.25 136.50 24.26 0.35 0.65 34.06 0.09 0.91 91.60
85.99
0.40 0.60 69.15 0.79 0.21 136.50 24.26 0.40 0.60 36.15 0.11 0.89 80.00 80.38 80.58
Pbubble = 125.27 KPa Pdew = 25.30 KPa 0.45 0.55 74.77 0.82 0.18 136.50 24.26 0.45 0.55 38.51 0.13 0.87 74.77
69.15 70.90
0.50 0.50 80.38 0.85 0.15 136.50 24.26 0.50 0.50 41.20 0.15 0.85 63.54 63.29
60.00
0.55 0.45 85.99 0.87 0.13 136.50 24.26 0.55 0.45 44.29 0.18 0.82 57.93 57.16
P . Yi = X1 . P1Sat + X2 . P2Sat 0.79
52.32
47.88
52.11
0.60 0.40 91.60 0.89 0.11 136.50 24.26 0.60 0.40 47.88 0.21 46.71 44.29
40.00 41.10 41.20
. 0.65 0.35 97.21 0.91 0.09 136.50 24.26 0.65 0.35 52.11 0.25 0.75 38.51
. X1 = 35.48 34.06 36.15
Y1 = Y1 = 0.98 Y1 = 0.01 0.71 29.87 30.54 32.20
0.70 0.30 102.83 0.93 0.07 136.50 24.26 0.70 0.30 57.16 0.29
24.26 25.30 26.43
27.67 29.04 PDew
0.75 0.25 108.44 0.94 0.06 136.50 24.26 0.75 0.25 63.29 0.35 0.65 20.00 Vapor Region
0.80 0.20 114.05 0.96 0.04 136.50 24.26 0.80 0.20 70.90 0.42 0.58
. .
Y2 =
Y2 = 0.02
X2 = Y2 = 0.99 0.85 0.15 119.66 0.97 0.03 136.50 24.26 0.85 0.15 80.58 0.50 0.50
0.00
0.90 0.10 125.27 0.98 0.02 136.50 24.26 0.90 0.10 93.32 0.62 0.38 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

0.95 0.05 130.88 0.99 0.01 136.50 24.26 0.95 0.05 110.85 0.77 0.23 X1, Y1 Pbubble, X1 Pdew, Y1
1.00 0.00 136.50 1.00 0.00 136.50 24.26 1.00 0.00 136.50 1.00 0.00

Tekanan 90 kPa

Material Name A B C

Benzene 13.7819 2726.81 217.572

Ethylbenzene 13.9726 3259.93 212.3

TBubble untuk kedua campuran di atas TDew untuk kedua campuran di atas
Mencari T Bubble Mencari T DEW P1Sat P2Sat
Xi (Liquid fraction)
TBubble
Yi (Vapor fraction)
(for TDew) (for Tbubble)
Yi (Vapor fraction)
TDew
Xi (Liquid fraction)
Diagram T-x-y Campuran Benzene/Ethylbenzene
X1 X2 P Y1 Y2 P X1 X2 Y1 Y2 Y1 Y2 X1 X2 150.00

1.00 0.00 90 1.00 0.00 90 0.00 1.00 131.80 0.00 1.00 394.60 90.00 0.00 1.00 131.80 0.00 1.00
140.00
1. Tentukan nilai α tebakan awal αa = 6.2141 1. Tentukan nilai α tebakan awal αa = 6.21 0.05 0.95 126.00 0.19 0.81 382.10 76.50 0.05 0.95 130.40 0.01 0.99

2. Cari Nilai P2Sat dari persamaan: 2. Cari Nilai P1Sat dari persamaan: 0.10 0.90 120.90 0.34 0.66 369.60 65.94 0.10 0.90 128.90 0.02 0.98
131.80
Vapor Region
130.00 130.40
0.15 0.85 116.30 0.46 0.54 356.80 57.48 0.15 0.85 127.40 0.04 0.96 128.90
127.40
126.00
P2 Sat = P2Sat = 14.483 KPa P1Sat = 𝑃 . (𝑌1 + 𝑌2. α) P1Sat = 90 KPa 0.20 0.80 112.10 0.55 0.45 343.90 50.63 0.20 0.80 125.80 0.05 0.95
125.80
124.10
122.40
TDew
. 120.00 120.90 120.50
0.25 0.75 108.40 0.62 0.38 330.80 45.00 0.25 0.75 124.10 0.07 0.93 118.60
116.30 116.60
114.40

Temperature [oC]
3. Cari nilai T dari persamaan 3. Cari nilai T dari persamaan 0.30 0.70 105.00 0.69 0.31 317.50 40.33 0.30 0.70 122.40 0.09 0.91 112.10 112.10
110.00 109.70
108.40
0.35 0.65 101.80 0.74 0.26 304.00 36.41 0.35 0.65 120.50 0.10 0.90 107.00
105.00 104.10
T= - C2 T = 76.20 oC T= - C1 T = 76.2 oC 0.40 0.60 98.95 0.78 0.22 290.30 33.08 0.40 0.60 118.60 0.12 0.88
100.00
101.80 101.00
98.95
0.45 0.55 96.29 0.82 0.18 276.30 30.23 0.45 0.55 116.60 0.15 0.85 96.29 97.46
93.83 93.47
4. Klarifikasi nilai α dari persamaan 4. Klarifikasi nilai α dari persamaan 0.50 0.50 93.83 0.85 0.15 262.10 27.77 0.50 0.50 114.40 0.17 0.83 90.00
91.54
89.40 88.85
0.55 0.45 91.54 0.87 0.13 247.50 25.63 0.55 0.45 112.10 0.20 0.80 TBubble 87.40
85.52
ln α = [A1-A2] - + ln α = [A1-A2] - + 83.75
82.07 83.30
0.60 0.40 89.40 0.89 0.11 232.60 23.75 0.60 0.40 109.70 0.23 0.77 80.00 80.49
78.99
77.56 76.20
α = exp[A1-A2] - + α = exp[A1-A2] - + 0.65 0.35 87.40 0.91 0.09 217.30 22.09 0.65 0.35 107.00 0.27 0.73

0.69 70.00
Liquid Region
0.70 0.30 85.52 0.93 0.07 201.50 20.63 0.70 0.30 104.10 0.31

αf = 6.21 αf = 6.21 0.75 0.25 83.75 0.95 0.05 185.30 19.32 0.75 0.25 101.00 0.36 0.64
60.00
∆α = 0.00 ∆α = 0.00 0.80 0.20 82.07 0.96 0.04 168.40 18.15 0.80 0.20 97.46 0.43 0.57

5. Mencari fraksi Y1 & Y2 5. Mencari fraksi X1 & X2 0.85 0.15 80.49 0.97 0.03 150.70 17.09 0.85 0.15 93.47 0.51 0.49
50.00
0.90 0.10 78.99 0.98 0.02 132.00 16.14 0.90 0.10 88.85 0.61 0.39
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
P1Sat = exp(A1 - ) P1Sat
P2Sat = exp(A2 - ) P2Sat
= 90.00 KPa = 14.48 KPa 0.95 0.05 77.56 0.99 0.01 112.00 15.27 0.95 0.05 83.30 0.76 0.24 X1, Y1 Tbubble, X1 Tdew, Y1
. 1.00 0.00 76.20 1.00 0.00 90.00 14.50 1.00 0.00 76.20 1.00 0.00

Y1 =
.
Y1 = 1.00
X1 = X1 = 1.00

. .
Y2 = Y2 = 0.00
X2 = X2 = 0.00