material safety data sheet

According to Regulation (EU) No 453/2010

Saniswiss biosanitizer R

SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name : Saniswiss biosanitizer R

1.2. Relevant identified uses of the substance or mixture and uses advised against
Application : SU22 Professional use. For industrial or institutional use. PC8 Biocide. PT1 Human hygiene
biocidal products.

1.3. Details of the supplier of the safety data sheet

Supplier : Saniswiss SA
ch. des tulipiers 19
1208 Geneva
Switzerland

t : +41 22 718 75 75
f : +41 22 718 75 76
: info@[Link]
: [Link]

1.4. Emergency telephone number

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EMERGENCY TELEPHONE NUMBER, for DOCTORS/FIRE BRIGADE/POLICE only:
CH - Telephone : +41 22 718 75 75 (During oflce hours only)

SECTION 2 HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (99/45/EC) : Flammable.
CLP classification : Flammable liquid, hazard category 3.
(1272/2008/EC)
Human health hazards : Low hazard for usual industrial or commercial handling.
Physical/chemical hazards : Flammable.
Environmental hazards : Not classified as dangerous according to statutory EC-Directives.
Other information : Keep out of the reach of children.

2.2. Label elements

Label elements (1272/2008/EC):
Hazard pictograms :

Signal word : Warning

H- and P-phrases : H226 Flammable liquid and vapour.

saniswiss sa • chemin des tulipiers 19 • 1208 Geneva • Switzerland • t +41 22 718 75 75 • info@[Link] • [Link]
saniswiss sa is an ISO 13485 certified company. All saniswiss™ products have the CE 1253 mark.
material safety data sheet
According to Regulation (EU) No 453/2010

Saniswiss biosanitizer R

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.

H319 Causes severe eye irritation. Precautionary statements – Prevention:

P264 Wash hands thoroughly after handling

P280 Wear protective gloves/protective clothing/eye protection/face

protection.
P305 + P351 + P338 IF IN CONTACT WITH EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rising.
P370+P378 In case of fire: Use carbondioxide (CO2), alcohol resistant foam, dry chemical or
alc water fog to extinguish.
P233 Keep container tightly closed.
P501 Dispose of contents/container to an oflcial chemical waste depot.
Additional labelling: none.

2.3. Other hazards

Other information : Does not contain PBT or vPvB substances in concentrations higher than 0,1%.CTION 3
COMPOSITION / INFORMATION ON INGREDIENTS

3.2. Mixtures

Product description : Mixture.

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Information on hazardous substances:
Substance name Concentration CAS nr. EC number Symbols R-phrases
(w/w) (%)
Hydrogen peroxide 0,1 - < 3 7722-84-1 231-765-0 O; C 5-8-20/22-35
Ethanol 25-65 64-17-5 200-578-6 F 11

Reference is made to chapter 16 for full text of each relevant R phrase. Occupational exposure limit(s), if relevant, are listed in
section 8.

Substance name REACH nr. Hazard Class Pictograms H-phrases

Hydrogen peroxide 01-2119485845-22 Ox. Liq. 1; Acute Tox. GHS03; GHS05; H271; H332; H302;
4; Skin Corr. 1A GHS07 H314
Ethanol 01-2119457610-43 Flam. Liq. 2; Eye Irrit. 2 GHS02; GHS07 H225; H319

Reference is made to chapter 16 for full text of each relevant H phrase.

SECTION 4 FIRST-AID MEASURES

4.1. Description of first aid measures

First aid measures

Inhalation : Move victim into fresh air. Consult a doctor if victim feels unwell.
Skin contact : Take ou contaminated clothing. Wash ou skin with plenty of water before product dries up.
Eye contact : Wash out with (lukewarm) water for at least 15 minutes. Remove contact lenses. Consult a doctor if
irritation persists.
Ingestion : Do not induce vomiting. Do rinse the mouth. Give one glass of water. Never give anything by mouth
to an unconscious person. Consult a doctor if victim feels unwell.

4.2. Most important symptoms and euects, both acute and delayed

Euects and symptoms

Inhalation : May cause headache, dizziness and a feeling of sickness.
Skin contact : Under normal conditions of use, according to the instructions, no specific euects and/or symptoms
are known. Prolonged contact may dry out and defat the skin.
Eye contact : May cause stinging of eyes and redness.

saniswiss sa • chemin des tulipiers 19 • 1208 Geneva • Switzerland • t +41 22 718 75 75 • info@[Link] • [Link]
saniswiss sa is an ISO 13485 certified company. All saniswiss™ products have the CE 1253 mark.
material safety data sheet
According to Regulation (EU) No 453/2010

Saniswiss biosanitizer R

Ingestion : May cause a feeling of sickness, vomiting and diarrhoea.

4.3. Indication of any immediate medical attention and special treatment needed

Note to physicians : None known.

SECTION 5 FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media
Suitable : Carbondioxide (CO2). Alcohol resistant foam. Dry chemical. Water fog.
Not suitable : Water jet.

5.2. Special hazards arising from the substance or mixture

Special exposure hazards : Heating causes oxygen release, intensifying the fire.
Hazardous thermal : Carbon monoxide may be evolved if incomplete combustion occurs.
decomposition products

5.3. Advice for firefighters

Special protective : Use adequate respiratory equipment in case of insuflcient ventilation.

equipment for fire-fighters

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SECTION 6 ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions : Danger of slipping. Clean up spills immediately. Wear shoes with non-slip soles. Avoid contact
with spilled or released material. Keep away from sources of ignition — No smoking. Vapours are
heavier than air. Build up (of gasses) in low areas involves risk of suuocation.

6.2. Environmental precautions

Environmental precautions : Avoid release of product into sewers, surface water and/or ground water. Large spills: contain with
dike. Due to the products biocidal activity, large scale discharge may impair the biological system in
sewage plants. Inform the oflcial bodies if necessary.
Other information : Notify authorities if any exposure to the general public or the environment occurs or is likely to
occur.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Collect spilled material in containers. Absorb residues in sand or other inert material. Do not use
saw-dust. Dispose at an authorised waste collection point. Wash away remainder with plenty of
water and soap.

6.4. Reference to other sections

Reference to other sections : See also section 8.

SECTION 7 HANDLING AND STORAGE

7.1. Precautions for safe handling

saniswiss sa • chemin des tulipiers 19 • 1208 Geneva • Switzerland • t +41 22 718 75 75 • info@[Link] • [Link]
saniswiss sa is an ISO 13485 certified company. All saniswiss™ products have the CE 1253 mark.
material safety data sheet
According to Regulation (EU) No 453/2010

Saniswiss biosanitizer R

Handling : Handle in accordance with good occupational hygiene and safety practices in well-ventilated areas.
Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment. Use only non-sparking tools. Take precautionary measures against static discharge.
Electrostatic discharge may cause fire. Ensure electrical continuity by bonding and grounding
(earthing) all equipment. Do not breathe vapour. Avoid contact with eyes.

7.2. Conditions for safe storage, including any incompatibilities

Storage : Keep in a cool, dry and well-ventilated place (< 35 °C). Keep away from oxidizing agents. Protect
from sunlight. Keep away from food, drink and animal feedingstuus.
Recommended packaging : Keep only in the original container.
Non recommended : Steel (except stainless steel).
packaging

7.3. Specific end use(s)

Use : Use biocides safely. Always read the label and product information before use.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Occupational exposure : Occupational exposure limits have not been established for this product. Derived no-euect levels

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limits (DNEL) have not been established for this product. Predicted no-euect concentrations (PNEC) have
not been established for this product.
Workplace exposure limits (mg/m³):
Chemical name Country TWA 8 hour STEL 15 min Comments
(mg/m3) (mg/m3)
Hydrogen peroxide GB 1,4 2,8 -
Ethanol GB 1920 - -

Derived no-euect level (DNEL) for workers:

Chemical name Route of DNEL, short-term DNEL, long-term
exposure
Local euect Systemic euect Local euect Systemic euect
Hydrogen peroxide Inhalation 3 mg/m3 1,4 mg/m3
Ethanol Inhalation 343 mg/kg bw/day
Dermal 1900 mg/m3 950 mg/m3
Inhalation

Derived no-euect level (DNEL) for consumers:

Chemical name Route of DNEL, short-term DNEL, long-term
exposure
Local euect Systemic euect Local euect Systemic euect
Hydrogen peroxide Inhalation 1,93 mg/m3 24 mg/kg bw/day
Ethanol Dermal
Inhalation 950 mg/m3 0,21 mg/m3
206 mg/kg bw/day
Oral 114 mg/m3
87 mg/kg bw/day

saniswiss sa • chemin des tulipiers 19 • 1208 Geneva • Switzerland • t +41 22 718 75 75 • info@[Link] • [Link]
saniswiss sa is an ISO 13485 certified company. All saniswiss™ products have the CE 1253 mark.
material safety data sheet
According to Regulation (EU) No 453/2010

Saniswiss biosanitizer R

Predicted no-euect concentration (PNEC):

Chemical name Route of exposure Fresh water Marine water
Water
Hydrogen peroxide Sediment 0,0126 mg/l 0,0126 mg/l 0,0138 mg/l
Intermittent water 0,047 mg/kg 0,047 mg/kg 4,66 mg/l
STP 0,0023 mg/kg
Soil
Water
Ethanol Sediment 0,96 mg/l 0,79 mg/l 2,75 mg/l
Intermittent water 3,6 mg/kg 2,9 mg/kg
580 mg/l
STP 0,63 mg/kg
Soil 0,72 mg/kg food
Oral

8.2. Exposure controls

Engineering measures : Use only in well-ventilated areas. Comply with standard precautionary measures for working
with chemicals. See Directive 2004/37/EG on the protection of workers from the risks related to

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exposure to carcinogens or mutagens at work.
Hygienic measures : When using do not eat, drink or smoke.
Personal protective equipment:
The eflciency of personal protective equipment depends among other things on temperature and degree of ventilation. Always get
professional advice for the particular local situation.
Body protection : Use of specific protective industrial clothing is not required under normal conditions of use.
Respiratory protection : Take care of suflcient ventilation. Wear suitable respiratory protection in case of large scale
exposure. Suitable: gas filter type A (brown), class I or higher on e.g. a facemask in accordance
with EN 140.
Hand protection : Wear suitable gloves in case of large scale exposure. Suitable material: nitril. ± 0,5 mm Indication
of permeation breakthrough time: 6 hours.
Eye protection : Wear appropriate safety glasses when there is danger of possible eye contact.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance : Liquid.
Colour : Colourless.
Odour : Perfumed.
Odour threshold : Not known.
pH : 4,9
Solubility in water : Soluble.
Partition coeflcient : Not applicable.
(n-octanol/water)
Flash point : 26 °C
Flammability (solid, gas) : Not applicable. Liquid. See flashpoint.
Auto ignition temperature : > 178 °C
Boiling point/boiling range : 77 °C

saniswiss sa • chemin des tulipiers 19 • 1208 Geneva • Switzerland • t +41 22 718 75 75 • info@[Link] • [Link]
saniswiss sa is an ISO 13485 certified company. All saniswiss™ products have the CE 1253 mark.
material safety data sheet
According to Regulation (EU) No 453/2010

Saniswiss biosanitizer R

Melting point/melting range : -27 °C

Explosive properties : None known. Does not contain explosives.
Explosion limits (in air) : Not known. Lower explosion limit in air (%): 3,4 ( Ethanol )
: Upper explosion limit in air (%): 19
Decomposition temperature : Not applicable.
Viscosity (20°C) : Not known.
Viscosity (40°C) : Not relevant. The product contains < 10% substances having an aspiration hazard.
Vapour pressure (20°C) : 5800 Pa
Vapour density (20°C) : >1 (air = 1)
Relative density (20°C) : 0,93 g/ml
Evaporation rate : <1 (n-butyl acetate = 1)

SECTION 10 STABILITY AND REACTIVITY

10.1. Reactivity

Reactivity : See sub-sections below.

10.2. Chemical stability

Stability : Stable under normal conditions.

10.3. Possibility of hazardous reactions

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Reactivity : No other hazardous reactions known.

10.4. Conditions to avoid

Conditions to avoid : See section 7.

10.5. Incompatible materials

Materials to avoid : Keep away from oxidizing agents. Keep away from reducing agents. Keep away from halogenated
substances. Keep away from heavy metals.

10.6. Hazardous decomposition products

Hazardous decomposition : Not known.

products

SECTION 11 TOXICOLOGICAL INFORMATION

11.1. Information on toxicological euects

No toxicological research has been carried out on this product.

Inhalation
Acute toxicity : Calculated LC50: > 10 mg/l. Ingredients of unknown toxicity: < 1 %. ATE: > 5 mg/l. Low toxicity. Not
classified - based on available data, the classification criteria are not met. May cause headache,
dizziness and a feeling of sickness.
Corrosion/irritation : Not classified - based on available data, the classification criteria are not met.
Sensitisation : Not classified - based on available data, the classification criteria are not met.
Carcinogenicity : Not classified - based on available data, the classification criteria are not met.
Mutagenicity : Not expected to be mutagenic. Not classified - based on available data, the classification criteria
are not met.
Skin contact

saniswiss sa • chemin des tulipiers 19 • 1208 Geneva • Switzerland • t +41 22 718 75 75 • info@[Link] • [Link]
saniswiss sa is an ISO 13485 certified company. All saniswiss™ products have the CE 1253 mark.
material safety data sheet
According to Regulation (EU) No 453/2010

Saniswiss biosanitizer R

Acute toxicity : Calculated LD50: > 5000 mg/[Link]. Ingredients of unknown toxicity: < 1 %. ATE: > 2000 mg/[Link].
Low toxicity. Not classified - based on available data, the classification criteria are not met.
Corrosion/irritation : Prolonged contact may dry out and defat the skin. Not classified - based on available data, the
classification criteria are not met.
Sensitisation : Not classified - based on available data, the classification criteria are not met.
Mutagenicity : Not expected to be mutagenic. Not classified - based on available data, the classification criteria
are not met.
Eye contact
Corrosion/irritation : Slight irritation possible. Not classified - based on available data, the classification criteria are not
met.
Ingestion
Acute toxicity : Calculated LD50: > 5000 mg/[Link]. Ingredients of unknown toxicity: < 1 %. ATE: > 2000 mg/[Link].
Low toxicity. Not classified - based on available data, the classification criteria are not met. May
cause hampered eyesight.
Corrosion/irritation : May cause a feeling of sickness, vomiting and diarrhoea. Not classified - based on available data,
the classification criteria are not met.
Carcinogenicity : Not classified - based on available data, the classification criteria are not met.
Mutagenicity : Not expected to be mutagenic. Not classified - based on available data, the classification criteria
are not met.

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SECTION 12 ECOLOGICAL INFORMATION

12.1. Toxicity

No ecotoxicological research has been carried out on this product.

Ecotoxicity : Calculated LC50 (fish): 273 mg/l. Calculated EC50 (waterflea): 233 mg/l. Contains < 1 % of
components with unknown hazards to the aquatic environment. Not classified - based on available
data, the classification criteria are not met.

12.2. Persistence and degradability

Persistence – degradability : No specific information known. The surfactants contained in this preparation comply with the
biodegradability criteria as laid down in Regulation (EC) 648/2004 on detergents.

12.3. Bioaccumulative potential

Bioaccumulative potential : No specific information known.

12.4. Mobility in soil

Mobility : If product enters soil, it will be highly mobile and may contaminate groundwater.

12.5. Results of PBT and vPvB ass

PBT/vPvB assessment : Does not contain PBT or vPvB substances in concentrations higher than 0,1%.

12.6. Other adverse euects

Other information : Not applicable.

SECTION 13 DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

saniswiss sa • chemin des tulipiers 19 • 1208 Geneva • Switzerland • t +41 22 718 75 75 • info@[Link] • [Link]
saniswiss sa is an ISO 13485 certified company. All saniswiss™ products have the CE 1253 mark.
material safety data sheet
According to Regulation (EU) No 453/2010

Saniswiss biosanitizer R

Product residues : The generation of waste should be avoided or minimised wherever possible. Containers may be
recycled. This material and its container must be disposed of in a safe way.
Additional warning : Residues may cause an explosion hazard. Do not puncture, cut or weld uncleaned drums.
European waste catalogue : Dispose hazardous waste in accordance with Directive 91/689/EEC under acknowledgement of a
waste code according to Commission Decision 2000/532/EC to an oflcial chemical waste depot.
Local legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations.
Local regulations may be more stringent than regional or national requirements and must be
complied with.

SECTION 14 TRANSPORT INFORMATION

14.1. UN number

UN nr. : UN 1170

14.2. UN proper shipping name

Transport name : ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)

14.3/14.4/14.5. Transport hazard class(es)/Packing group/Environmental hazards

ADR/RID (road / railway)

Class :3

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Classification code : F1
Packaging group : III
Danger label : 3
:

IMDG (sea)
Class : 3
Packaging group : III
EmS (fire / spill) :F-E/S- D
Marine pollutant : No
IATA (air)
Class :3

14.6. Special precautions for user

Other information : Country specific variations may apply. It is possible that a "Limited Quantity" exemption applies to
the transport of this product.

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Marpol : Not intended to be carried in bulk according to International Maritime Organisation (IMO)
instruments.

SECTION 15 REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

saniswiss sa • chemin des tulipiers 19 • 1208 Geneva • Switzerland • t +41 22 718 75 75 • info@[Link] • [Link]
saniswiss sa is an ISO 13485 certified company. All saniswiss™ products have the CE 1253 mark.
material safety data sheet
According to Regulation (EU) No 453/2010

Saniswiss biosanitizer R

Community regulations : Regulation (EC) No 453/2010 (REACH), Regulation (EC) No 1272/2008 (CLP), Regulations (EU)
No 528/2012 (biocides) and other regulations.
Labelling in accordance with Regulations (EU) No 528/2012.
Application : PT1 . Human hygiene biocidal products.
Liquid. Contains: 380,1 g/kg Ethanol and 8 g/kg Hydrogen peroxide .
Directions for use and : 3 ml per application. For professional use only.
dosage

15.2. Chemical safety assessment

Chemical safety : Not applicable.
assessment

SECTION 16 OTHER INFORMATION

16.1. Other information

The information in this safety data sheet is compiled in compliance with Regulation (EC) No 453/2010 dated 20 May 2010
and accurate to the best of our knowledge and experience at the date of issue specified. It is the user’s obligation to use this
product safely and to comply with all applicable laws and regulations concerning the use of the product. This safety data sheet
complements the technical information sheets but does not replace them and ouers no warranty with regard to product properties.

fdsF 06032012 - rev.21032014

Users are also forewarned for any hazards involved when the product is used for other purposes than those for which it is
designed.
Changed or new information with regard to the previous release is indicated with an asterisk (*).
Full text of R-phrases mentioned in section 3:
R5 Heating may cause an explosion.
R8 Contact with combustible material may cause fire.
R11 Highly flammable.
R20/22 Harmful by inhalation and if swallowed.
R35 Causes severe burns.
Full text of H-phrases mentioned in section 3:
H225 Highly flammable liquid and vapour.
H271 May cause fire or explosion; strong oxidiser.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
List of abbreviations and acronyms that could be (but not necessarily are) used in this safety data sheet:
ADR : European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE : Acute Toxicity Estimate
CLP : Classification, Labeling & Packaging
CMR : Carcinogenic, Mutagenic or toxic for Reproduction
EEC : European Economic Community
EU : European Union
IATA : International Air Transport Association
IBC : Intermediate Bulk Container
IBC Code : International Bulk Chemical Code
IMDG : International Maritime Dangerous Goods Code
MAC : Maximum Allowable Concentration
MARPOL : International Convention for the Prevention of Pollution From Ships
OECD : Organisation for Economic Co-operation and Development

saniswiss sa • chemin des tulipiers 19 • 1208 Geneva • Switzerland • t +41 22 718 75 75 • info@[Link] • [Link]
saniswiss sa is an ISO 13485 certified company. All saniswiss™ products have the CE 1253 mark.
material safety data sheet
According to Regulation (EU) No 453/2010

Saniswiss biosanitizer R

PBT : Persistent, Bioaccumulative and Toxic

PC : Chemical product category
PT : Product type
REACH : Registration, Evaluation, Authorisation and Restriction of Chemicals
RID : Regulations concerning the International Carriage of Dangerous Goods by Rail
STP : Sewage Treatment Plant
SU : Sector of Use
TWA/STEL : Time-Weighted Average/Short Term Exposure Limit
UN : United Nations
VOC : Volatile Organic Compounds
vPvB : Very Persistent and Very Bioaccumulative
Number format : "," used as decimal separator.

fdsF 06032012 - rev.21032014

saniswiss sa • chemin des tulipiers 19 • 1208 Geneva • Switzerland • t +41 22 718 75 75 • info@[Link] • [Link]
saniswiss sa is an ISO 13485 certified company. All saniswiss™ products have the CE 1253 mark.