Astm D396-05
Astm D396-05
Designation: D 396 – 05
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6. Keywords
Available from U.S. Government Printing Office, Superintendent of Docu-
ments, 732 N. Capitol St., NW, Mail Stop: SDE, Washington, DC 20401. 6.1 burner fuels; fuel oils; furnace oils; petroleum and
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For information on the precision of the ASTM test methods for fuel oils refer petroleum products
to “An Evaluation of Methods for Determination of Sulfur in Fuel Oils” by A. R.
Crawford, Esso Mathematics and Systems Inc. and G. V. Dyroff, Esso Research and
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Engineering Co., 1969. This document is available from the Publications Section, Supporting data have been filed at ASTM International Headquarters and may
API Library, American Petroleum Institute, 1220 L St., NW, Washington, DC 20005. be obtained by requesting Research Report RR:D02-1553.
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min 1.3 1.3 1.9 1.9 1.9 >5.5 ... ... ...
max 2.1 2.1 3.4 3.4 5.5 24.0E
Kinematic viscosity at 100°C, mm2/s D 445
min ... ... ... ... ... ... 5.0 9.0 15.0
max ... ... ... ... ... ... 8.9E 14.9E 50.0E
Ramsbottom carbon residue on 10 % D 524 0.15 0.15 0.35 0.35 ... ... ... ... ...
distillation residue % mass, max
Ash, % mass, max D 482 ... ... ... ... 0.05 0.10 0.15 0.15 ...
Sulfur, % mass maxF D 129 ... 0.50 ... 0.50 ... ... ... ... ...
D 2622 0.05 0.05
Copper strip corrosion rating, max, D 130 No. 3 No. 3 No. 3 No. 3 ... ... ... ... ...
3 h at 50°C
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Density at 15°C, kg/m D 1298
min ... ... ... ... >876G ... ... ... ...
max 850 850 876 876 ... ... ... ... ...
Pour Point °C, maxH D 97 −18 −18 −6 −6 −6 −6 ... ... I
A
It is the intent of these classifications that failure to meet any requirement of a given grade does not automatically place an oil in the next lower grade unless in fact
it meets all requirements of the lower grade. However, to meet special operating conditions, modifications of individual limiting requirements may be agreed upon among
the purchaser, seller, and manufacturer.
B
Under United States regulations, Grades No. 1 S5000, No. 1 S500, No. 2 S5000, No. 2 S500, and No. 4 (Light) are required by 40 CFR Part 80 to contain a sufficient
amount of the dye Solvent Red 164 so its presence is visually apparent. At or beyond terminal storage tanks, they are required by 26 CFR Part 48 to contain the dye Solvent
Red 164 at a concentration spectrally equivalent to 3.9 lb per thousand barrels of the solid dye standard Solvent Red 26.
C
The amount of water by distillation by Test Method D 95 plus the sediment by extraction by Test Method D 473 shall not exceed the value shown in the table. For Grade
No. 6 fuel oil, the amount of sediment by extraction shall not exceed 0.50 mass %, and a deduction in quantity shall be made for all water and sediment in excess of 1.0
mass %.
D
Test Method D 2887, Simulated Distillation, was determined to be an acceptable alternative test method to Test Method D 86, Physical Distillation, based on Research
Report RR:D02-1553. This report has been filed at ASTM International Headquarters and may be obtained by request.
E
Where low sulfur fuel oil is required, fuel oil falling in the viscosity range of a lower numbered grade down to and including No. 4 can be supplied by agreement between
the purchaser and supplier. The viscosity range of the initial shipment shall be identified and advance notice shall be required when changing from one viscosity range
to another. This notice shall be in sufficient time to permit the user to make the necessary adjustments.
F
Other sulfur limits may apply in selected areas in the United States and in other countries.
G
This limit ensures a minimum heating value and also prevents misrepresentation and misapplication of this product as Grade No. 2.
H
Lower or higher pour points can be specified whenever required by conditions of storage or use. When a pour point less than −18°C is specified, the minimum viscosity
at 40°C for grade No. 2 shall be 1.7 mm2/s and the minimum 90 % recovered temperature shall be waived.
I
Where low sulfur fuel oil is required, Grade No. 6 fuel oil will be classified as Low Pour ( +15°C max) or High Pour (no max). Low Pour fuel oil should be used unless
tanks and lines are heated.
APPENDIX
(Nonmandatory Information)
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X1.3.2 Grades No. 2 S5000 and No. 2 S500 are middle municipal laws and is based on accepted practice in handling
distillates somewhat heavier than grades No. 1 S5000 and and use.
No. 1 S500. They are intended for use in atomizing type X1.4.1.2 Reduced Temperature Properties—The fuel’s
burners which spray the oil into a combustion chamber where cloud and pour points are good measures for determining low
the tiny droplets burn while in suspension. These grades of oil temperature operability with a batch of fuel oil. It is especially
are used in most domestic burners and in many medium important to consider these fuel properties if the heating oil
capacity commercial-industrial burners where ease of handling will be subjected to low ambient temperatures at time of use.
and ready availability sometimes justify higher cost over the Fuel temperatures can fluctuate markedly in small, residential,
residual fuels. The low sulfur grade S500 may be specified by outdoor, above ground tanks compared with indoor, basement
federal, state, or local regulations and can result in reduced tanks, or underground tanks. A decrease or stoppage of fuel
deposits on ferrous heat exchanger surfaces compared to Grade flow can occur in small transfer lines used for residential
No. 2 S5000 when burned under similar conditions. heating applications because the fuel line temperature will
X1.3.3 Grade No. 4 (Light) is a heavy distillate fuel or fluctuate with ambient temperature faster than will bulk tank
distillate/residual fuel blend meeting the specification viscosity contents. Fuel oils purchased during the summer, but not used
range. It is intended for use both in pressure-atomizing until the cold heating season arrives, can be a serious source of
commercial-industrial burners not requiring higher cost distil- problems. This is because when these fuels are produced they
lates and in burners equipped to atomize oils of higher are intended for use during the warm season and thus typically
viscosity. Its permissible viscosity range allows it to be have higher cloud and pour points than fuels produced for use
pumped and atomized at relatively low-storage temperatures. during the cold season. Fuels can be produced for use at low
X1.3.4 Grade No. 4 is usually a heavy distillate/residual temperatures with lower cloud and pour points by blending
fuel blend but can be a heavy distillate fuel meeting the with low paraffin fuels, such as kerosine or No. 1 fuel, and
specification viscosity range. It is intended for use in burners additives, or a combination thereof, to improve low tempera-
equipped with devices that atomize oils of higher viscosity than ture operability. The key to effective treatment is routine
domestic burners can handle. Its permissible viscosity range monitoring of incoming and stored fuels, and testing of the
allows it to be pumped and atomized at relatively low storage treated fuels. Although this specification only sets maximum
temperatures. Thus, in all but extremely cold weather it limits for the pour point, the recommendations for cloud point
requires no preheating for handling. of distillate fuels in Specification D 975 may be applied to
X1.3.5 Grade No. 5 (Light) is residual fuel of intermediate heating fuels under extreme cold conditions. Some pipeline
viscosity for burners capable of handling fuel more viscous companies or local specifications have included requirements
than grade No. 4 without preheating. Preheating may be for both cloud and pour points for certain grades of fuel oil.
necessary in some types of equipment for burning and in colder (1) Pour Point—The pour point is an indication of the
climates for handling. lowest temperature at which a fuel oil is capable of flowing
X1.3.6 Grade No. 5 (Heavy) is a residual fuel more viscous under very low forces. The pour point is prescribed in
than Grade No. 5 (Light) and is intended for use in similar accordance with the conditions of storage and use. Higher pour
service. Preheating may be necessary in some types of equip- point fuels are permissible where heated storage and adequate
ment for burning and in colder climates for handling. piping facilities are provided. An increase in pour point can
X1.3.7 Grade No. 6, sometimes referred to as Bunker C, is occur when residual fuel oils are subjected to cyclic tempera-
a high-viscosity oil used mostly in commercial and industrial ture variations that can occur in the course of storage or when
heating. It requires preheating in the storage tank to permit the fuel is preheated and returned to storage tanks. To predict
pumping, and additional preheating at the burner to permit these properties, Test Method D 3245 may be required.
atomizing. The extra equipment and maintenance required to (2) Cloud Point (Test Method D 2500)—The cloud point
handle this fuel usually preclude its use in small installations. defines the temperature at which a cloud or haze of wax
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Subcommittee D02.E0 has identified the location of selected changes to this standard since the last issue
(D 396–04) that may impact the use of this standard.
(1) Updated the nomenclature for grades of fuel oil to match (3) Removed footnote B from Table 1 and renumbered the
Specification D 975. footnotes accordingly.
(2) Added footnote to Table 1 to include a reference to
RR:D02–1553.
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