MATERIAL SAFETY DATASHEET
Conforms to regulation (EC) No. 1907/2006 (REACH), Annex II – Europe
Version: 27 June 2013 Tel: +31 (0)36 2000 300
1. Substance/preparation and company identification
Identification of the materials:
Cawiton® PR 8246
This materials code is given on each minimal packaging size (bag or octabin).
Typical use of the materials:
The materials are suitable for producing plastic parts by injection moulding or extrusion
Identification of the manufacturer:
The materials have been produced by:
Wittenburg b.v.
Productieweg 12,
3899 AK Zeewolde,
The Netherlands
Phone: + 31 (0)36 2000 300
Emergency assistance:
24 hour emergency Assistance is available on the phone number: +31 (0)36 2000 300
2. Hazards identification
HMIS Hazard Class:
Health: 0
Flammability: 1
Physical Hazards: 0
Human Health Hazards:
Danger of burns while handling the hot product
Environmental Hazards:
None
Safety Hazards:
Electrostatic charges may be generated during handling. Risk of self-ignition of bulk products above certain
temperatures.
3. Composition/Information on ingredients
SUBSTANCES ARE NON HAZARDOUS AND NOT CLASSIFIED
Chemical nature: Butyl acrylate-styrene-acrylonitrile copolymer (ASA). Contains a mineral filler.
4. First-aid measures
If inhaled:
MSDS Cawiton PR 8246
Rubberfabriek Wittenburg BV [Link]@[Link] ̸ [Link]
Productieweg 12, 3899 AK Zeewolde Tel: +31(0) 362000300/ Fax: +31(0) 362000301
The Netherlands Chamber of Commerce nr. 3200126
Page: 1 of 5
MATERIAL SAFETY DATASHEET
After inhalation of decomposition products, remove the affected person to a source of fresh air and keep calm. Provide
medical aid.
On skin contact:
Areas affected by molten material should be quickly placed under running cold water. Burns caused by molten
material require hospital treatment.
On contact with eyes:
In case of contact with eyes, rinse immediately for at least 15 minutes with plenty of water. If irritation develops, seek
immediate medical attention.
On ingestion:
Rinse mouth and then drink plenty of water. If difficulties occur: Seek medical attention
Note to the physician:
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
5. Fire fighting measures
Suitable extinguishing media:
Dry extinguishing media, foam, carbon dioxide, water spray or fog, sand or earth may be used for small fires only.
Specific hazards:
The following substances/groups of substances may be released in case of fire: carbon dioxide, carbon monoxide,
styrene and traces of hydrogencyanide.
Special protective equipment:
Full protective clothing and self-contained breathing apparatus.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations
6. Accidental release measures
Personal precautions:
Avoid inhalation. Sources of ignition should be kept well clear.
Methods for cleaning up or taking up:
Sweep/shovel up. Avoid raising dust. Ensure adequate ventilation.
Additional information:
High risk of slipping in case of leakage/spillage of granulate.
7. Handling and storage
Handling:
Processing machines must be fitted with local ventilation.
Storage:
Protect against moisture. Avoid extreme heat (>60°C). Avoid all source of ignition: heat, sparks or open flame.
Specific use:
Avoid dust formation. Dust can form an explosive mixture with air. Provide adequate ventilation. When the product is
ground (chopped), dust explosion regulations should be followed.
The process parameters must be set within the range as recommended in the technical datasheet.
MSDS Cawiton PR 8246
Rubberfabriek Wittenburg BV [Link]@[Link] ̸ [Link]
Productieweg 12, 3899 AK Zeewolde Tel: +31(0) 362000300/ Fax: +31(0) 362000301
The Netherlands Chamber of Commerce nr. 3200126
Page: 2 of 5
MATERIAL SAFETY DATASHEET
8. Exposure controls and personal protection
Residual monomers
Residual monomers are not routinely measured. If adequate ventilation is used, it is expected that monomer
concentrations remain well below the limits given below.
Ingredient agency value
Nuisance Dust OSHA-PEL 15 mg/m3
Respirable Dust OSHA-PEL 5 mg/m3
100-42-5: Styrene MAC (NL) 8 hours 107 mg/m3 25 ppm
107-13-1: Acrylonitrile MAC (NL) 8 hours - 1 ppm
141-32-2: n-butylacrylate MAC (NL) 8 hours 11 mg/m3 2 ppm
MAC (NL) 15 minutes 53 mg/m3 10 ppm
Personal protective equipment
Respiratory protection (only when dust has formed):
Breathing protection in case of dust. Particle filter Type P1 or FFP1 (low efficiency for solid particles e.g. EN143, 149).
Hand protection:
Use additional heat protection gloves when handling hot molten masses (e.g. of textile or leather).
Eye protection:
Safety glasses with side-shields (frame goggles) (EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical
protection suit (according to DIN-EN 465)
General safety and hygiene measures:
Avoid contact of molten material with skin. Avoid inhalation of dust/mists/vapours. Eye wash fountains and safety
showers must be easily accessible. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and chemical Properties
Form : granules
Colour : white
Odour : faint odour of plastics
Softening temperature : > 70°C
3
Density : approx. 1240 kg/m (20°C, 1 bar)
3
Bulk density : 500 - 900 kg/m (20°C)
Solubility in water : insoluble
10. Stability and reactivity
Stability:
The material is stable under ambient conditions. It oxidises exothermically above ambient temperature.
Conditions to avoid:
Avoid extreme heat. Avoid all sources of ignition: heat, sparks or open flame.
MSDS Cawiton PR 8246
Rubberfabriek Wittenburg BV [Link]@[Link] ̸ [Link]
Productieweg 12, 3899 AK Zeewolde Tel: +31(0) 362000300/ Fax: +31(0) 362000301
The Netherlands Chamber of Commerce nr. 3200126
Page: 3 of 5
MATERIAL SAFETY DATASHEET
Thermal decomposition:
To avoid thermal decomposition, do not expose to temperatures above 300°C. See technical datasheet for appropriate
processing temperatures.
Substances to avoid:
Strong oxidizing agents and strong acids and strong base
Hazardous reactions:
The material is chemically stable.
Hazardous decomposition products:
The following substances/groups of substances may be released: carbon dioxide, carbon monoxide, styrene and
traces of aliphatic and aromatic hydrocarbons including aldehydes and organic acids. Monomers, oxides,
hydrocarbons, low molecular weight oligomers and/or gaseous/vapours products.
11. Toxicological information
If handled properly and in accordance with general occupational hygiene rules, the product
is unlikely to be harmful to health. There are no experimental data available for this product.
12. Ecological information
Basis for assessment
No ecotoxicological data has been generated for this product. The information below is based on raw material data
and/or on data of similar products.
Ecotoxicity
Persistence and degradability:
Assessment: No data available concerning biodegradation and elimination.
Bioaccumulation potential:
The product will not be readily bioavailable due to its consistency and insolubility in water.
Other ecotoxicological advice:
No data can be given due to the products insolubility in water
Acute toxicity –Fish
Expected to be practically non toxic, LC/EC/IC 50 > 1000 mg/l.
Acute Toxicity - Invertebrates
Expected to be practically non toxic, LC/EC/IC 50 > 1000 mg/L
Acute Toxicity - Algae
Expected to be practically non toxic, LC/EC/IC 50 > 1000 mg/L
Acute Toxicity - Bacteria
Expected to be practically non toxic, LC/EC/IC 50 > 1000 mg/L
Sewage Treatment
Expected to be practically non toxic, LC/EC/IC 50 > 1000 mg/L
13. Disposal considerations
MSDS Cawiton PR 8246
Rubberfabriek Wittenburg BV [Link]@[Link] ̸ [Link]
Productieweg 12, 3899 AK Zeewolde Tel: +31(0) 362000300/ Fax: +31(0) 362000301
The Netherlands Chamber of Commerce nr. 3200126
Page: 4 of 5
MATERIAL SAFETY DATASHEET
Product Disposal:
Recover or recycle if possible, otherwise; incinerate or use a licensed landfill.
Container Disposal:
Remove all packaging for recovery or disposal.
Local Legislation:
Consult local, state, federal, international or country specific regulations as appropriate.
14. Transport information
Statutory transport regulations
The product is not classified as hazardous under international transport law
15. Regulatory information
EU labelling regulations 1272/2008/EC (CLP)
This document is compliant with the Globally Harmonized System (GHS) for the classification, labelling, and
packaging (CLP) of substances and mixtures.
EU Regulation (EC) 1907/2006 REACH
Polymers are exempted from registration and evaluation. Therefore, Wittenburg products are exempted by regulation.
Annex V exempts from registration additives used in our polymers as antioxidants, defoaming agents, stabilisers, etc.,
and exempts substances that are naturally occurring that have not been chemically modified, Article 2(7)(b).
EU Directive 2011/65/EC, amending 2002/95/EC Restrictions of Hazardous Substances (RoHS) in electrical and
electronic equipment Restricted substances: Lead, Mercury, Cadmium, Hexavalent Chromium, PBB and PBDE
Not regulated.
EU Directive 94/62/EC as amended by 2004/12/EC (Packaging and packaging waste)
Not regulated. The product meets the requirement for the total amount of cadmium, chromium, lead and mercury to be
less than 100 parts per million.
16. Other information
In addition to the information given in the safety data sheet we refer to the products specific ‘Technical
Datasheet’.
Disclaimer
The information contained herein is based on the present state of our knowledge and does not therefore guarantee
certain properties. Recipients of our product must take responsibility for observing existing laws and regulations.
The information given in the Material Safety Data Sheet only applies to the described product in connection
with its appropriate use. All information is based on the latest state of our knowledge. In particular, it
describes our product under the aspect of possible hazards and pertaining safety measures. The information
does not constitute any guarantee of specific product and/or quality properties. The information given in this
Material Safety Data Sheet is not required according to article 31 and Annex II of Regulation (EC) No.
1907/2006. It merely serves the purpose of providing sufficient information on a voluntary basis to ensure
safe use of the compound/product. There is no obligation on the part of Wittenburg B.V. to revise this document.
MSDS Cawiton PR 8246
Rubberfabriek Wittenburg BV [Link]@[Link] ̸ [Link]
Productieweg 12, 3899 AK Zeewolde Tel: +31(0) 362000300/ Fax: +31(0) 362000301
The Netherlands Chamber of Commerce nr. 3200126
Page: 5 of 5
