Ionic Compounds
Giant Ionic Lattices
Giant Ionic Lattice: Giant three-dimensional lattice structure held together by the strong attraction
between oppositely charged ions.
Example:
The lattice structure of Sodium Chloride
Positions of the ions in a crystal of Sodium Chloride
Melting and boiling point of compounds with giant ionic lattices:
Melting and boiling point depends on the force that holds the particles.
Giant Ionic Lattices are held together by the strong attraction between oppositely
charged ions with many ions and bonds in structure.
Large amounts of heat energy is needed to overcome forces and break down the
bonds.
Therefore compounds with giant ionic lattices have high melting and boiling points.
Ionic charge is directly proportional to the melting and boiling point in an ionic
compound.
e.g. Magnesium oxide has higher melting point that NaCl. This is because in MgO, 2+ ions
are attracting 2- ions and in sodium chloride, the attraction is weaker because there are only
1+ and 1- ions attracted.
Ionic Compounds & Electrical Conductivity
Ionic Compounds: Formed when atoms of metals transfer electrons to atoms of non-metals to form
compounds made up of ions.
Particles of ionic compounds in solids and when molten or in solution form
Electrical Conductivity of Ionic Compounds:
Ionic compounds cannot conduct electricity when solid as ions are fixed in structure and are
not free to move.
However, ionic compounds can conduct electricity when molten or in aqueous solution as
their ions are free to move to conduct an electric charge.