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Inert Gas Confined Space Safety Guide

This document discusses inert gas confined space entry and monitoring worker safety in these environments. It describes how inert gases like nitrogen are used to displace oxygen and prevent explosions during industrial processes. One example given is catalyst maintenance in oil refineries. The document outlines the risks of working in inert atmospheres, including the need to continuously monitor for oxygen levels, explosive gases, and toxic gases. It describes shortcomings of traditional monitoring solutions and advantages of a wireless monitoring system that can detect a broader range of gases and provide remote monitoring of worker environments.

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0% found this document useful (0 votes)
219 views2 pages

Inert Gas Confined Space Safety Guide

This document discusses inert gas confined space entry and monitoring worker safety in these environments. It describes how inert gases like nitrogen are used to displace oxygen and prevent explosions during industrial processes. One example given is catalyst maintenance in oil refineries. The document outlines the risks of working in inert atmospheres, including the need to continuously monitor for oxygen levels, explosive gases, and toxic gases. It describes shortcomings of traditional monitoring solutions and advantages of a wireless monitoring system that can detect a broader range of gases and provide remote monitoring of worker environments.

Uploaded by

Afshad
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Application Note AP-231  10/09/BD

AREARAE INERT FOR INERT GAS CONFINED


SPACE ENTRY
One of the most dangerous confined space entries is when an inert
atmosphere is present. Inert or “non-reactive” atmospheres are
used to displace oxygen or other reactive gases when the presence
of that gas presents an explosion risk to either the process being
performed or the compounds being stored. Some examples of
inert process applications include the transportation of flammable
cargo, catalytic processes in the petrochemical refining industry
and welding operations. These industrial processes must maintain
oxygen levels well below the combustion point for the catalyst
or the chemicals being processed and therefore well below the
viability point for any workers involved. The most commonly used
inert gas is nitrogen though other including “post-combustion”
gases are sometimes used with the objective of reducing the
atmospheric presence of oxygen from its normal twenty percent to a
range of less than four percent to eight percent.

This white paper will address the issues with inert atmosphere
confined space entry and the application of wireless gas detection
in monitoring the work environment.

Catalysts are substance that initiate or accelerate a chemical


reaction without itself being affected. Catalysts are often used atmosphere and the worker breathing air works from a trailer on
within oil refinery reactor pressure vessels to accelerate the crude the ground. The purged atmosphere must be continually monitored
oil reduction process into the desired output compounds. Refinery for real-time oxygen level, explosive gases such as volatile organic
hydro-treating reactors typically contain catalysts composed of compounds as well as carbon monoxide.
the following elements: Molybdenum (Mo), Nickel (Ni), Cobalt THE RISKS OF WORKING IN AN INERT ATMOSPHERE
(Co). When the catalyst beds must be serviced a technique called
• The inert atmosphere needs to be monitored for explosive gases.
“gas blanketing” is used to prevent the external atmosphere from
And if people are involved they must have an adequate breathing
reacting with the catalyst and bringing it into the explosive range.
supply
Nitrogen is pumped into the vessel until it is purged, then a service
technician with special life-support breathing helmet and protective • Regular calibration and testing of the equipment used to generate
suit enter the pressure vessel. Catalysts are removed from reactors inert gas is required to ensure that it works correctly. A sensor
in a highly reactive, sulfided state. The entire catalyst change out to measure the level of the inert gas and/or oxygen is needed to
process can take as long as a week to complete. ensure atmosphere is not in flammable range.
• The inert atmosphere needs to be monitored for toxic gases.
Worker safety is the primary concern during this type of work.
For example in refinery catalyst maintenance the presence
Technicians generally work with a safety-locked helmet with
of benzene, VCM, toluene, xylene, EDC, and many other
redundant air supplies, real-time radio contact with the safety team
hydrocarbons can exist. (VOC = PID)
and personal back-up controls. The person operating both the purge

RAE Systems by Honeywell  877-723-2878  [Link] 1


Application Note AP-231  10/09/BD

WHAT ARE THE SHORTCOMINGS OF SOLUTIONS USED Measured Results


TODAY? The AreaRAE Inert is capable of accurate VOC measurements in
Traditional Wheatstone bridge/catalytic bead based lower explosive zero and low oxygen environments.
limit (LEL) sensors require oxygen to detect flammable gases.
Typically a dilution fitting is used to introduce enough oxygen in PID measurements of Hexane in an inert environment were within
the air to allow the LEL sensor to read properly. Dilution fittings are +/- 10% of the known value.
cumbersome to use and are often used incorrectly. Using the PID to measure Octane and then converting to % LEL, the
LEL sensors only display in one percent increments. Most are not AreaRAE has a resolution of 0.02% LEL by volume when compared
very accurate below 5% LEL. They cannot detect hydrocarbons at with existing systems that have a resolution of 3% LEL by volume.
toxic levels (only flammable levels).

In order to increase the safety of the workers in the inert


atmosphere, remote monitoring by a second person is needed.
Without a wireless system, users must hard wire traditional fixed
LEL sensors to get remote readings. This is heavy, time consuming,
expensive, and very difficult to transport.

ADVANTAGES OF THE AREARAE INERT WIRELESS SYSTEM


A wireless monitoring system allows real-time remote monitoring
of the inert atmosphere to ensure worker safety and the data can be
shared by both the service provider and the site safety officer.

A wireless system is quick to deploy and does not encumber the


service technician with additional hoses or cables.

Sensitive photoionization detectors are used to detect hydrocarbons.

A high range carbon monoxide sensor is used to measure the


presence of CO as well as hydrogen. This is in addition to the
Oxygen sensor which is used as a second sensor to ensure oxygen
levels are low enough to prevent spontaneous explosion.

Flexible firmware allows switching between the NORMAL operation


mode and INERT mode.

RAE Systems by Honeywell  877-723-2878  [Link] 2

Common questions

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When working in an inert atmosphere during industrial processes, risks include the presence of explosive gases, which requires ongoing monitoring. Workers must have adequate breathing supplies, as the enclosed space has low oxygen. Toxic gases, such as benzene, toluene, and xylene, also need monitoring as they can exist in refinery maintenance scenarios, posing health risks to workers. Regular equipment calibration ensures these potential hazards are accurately measured and managed .

Nitrogen is commonly used as an inert gas in industrial applications because it effectively displaces oxygen and other reactive gases, preventing combustion and maintaining a stable atmosphere for processes sensitive to explosion risks. Alternative gases can include 'post-combustion' gases, which are sometimes utilized to achieve the same displacement effect, lowering the atmospheric oxygen to less than 4-8% .

Traditional Wheatstone bridge/catalytic bead LEL sensors require oxygen to detect flammable gases, making them unsuitable for inert atmospheres that lack sufficient oxygen. These sensors, which only display in one percent increments, are not accurate below 5% LEL and fail to detect hydrocarbons at toxic levels. Wireless systems like the AreaRAE Inert overcome these shortcomings by providing accurate measurements through photoionization detectors and enabling remote real-time monitoring without the need for oxygen, enhancing safety and efficiency .

The AreaRAE Inert system's firmware offers flexibility by allowing switching between NORMAL and INERT operational modes, enabling it to adapt to different environmental conditions and requirements in industrial settings. This capability ensures precise gas detection across various scenarios without equipment replacement, thus enhancing operational efficiency. It contributes to quicker deployment and transition times, optimizing the monitoring processes and ensuring continuous safety assurance .

Inert gases such as nitrogen are used in industrial applications like the transportation of flammable cargo, catalytic processes in petrochemical refining, and welding operations to displace oxygen and other reactive gases. This displacement is necessary to prevent explosions that could occur due to the reactive nature of the gases involved in these industrial processes .

Gas blanketing involves the use of inert gases like nitrogen to purge environments of reactive gases during refining processes, crucially maintaining safety by preventing potential explosions. This technique is essential in catalytic reactor vessels where catalysts must be serviced. It prevents the external atmosphere from reacting with the highly reactive sulfided catalyst, maintaining the inert conditions and thus ensuring safe operations for technicians .

The critical sensors used in the inert monitoring system for refinery maintenance include photoionization detectors for VOCs, a high range carbon monoxide sensor for CO and hydrogen, and an oxygen sensor. The photoionization detectors provide sensitive hydrocarbon measurements. The carbon monoxide sensor detects CO levels, ensuring they remain safe for workers. The oxygen sensor monitors oxygen levels to prevent conditions conducive to spontaneous explosions .

Wireless monitoring systems improve the process of catalyst maintenance in refinery settings by allowing real-time remote monitoring of oxygen and toxic gas levels without requiring service technicians to manage cumbersome hoses or cables. These systems use sensitive photoionization detectors to measure hydrocarbons and high range sensors for carbon monoxide detection. This ensures both safety and efficiency in a process that involves the removal of highly reactive, sulfided catalysts from pressure vessels .

Wireless gas detection technology, like the AreaRAE Inert system, plays a crucial role in ensuring safety during inert atmosphere confined space entry by providing real-time remote monitoring of oxygen and toxic gas levels. This system allows both service providers and site safety officers to access data, facilitating quick deployment and eliminating the need for cumbersome hoses or cables. Additionally, it uses sensitive detectors to accurately measure hydrocarbons and carbon monoxide levels even in zero or low oxygen environments .

The AreaRAE Inert monitors VOCs in low or zero oxygen environments using sensitive photoionization detectors. It achieves VOC measurements with accuracy within +/- 10% of known values. When measuring Octane in an inert environment, it provides a resolution of 0.02% LEL by volume, which is significantly more precise than existing systems that offer a resolution of 3% LEL by volume .

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