Lonza Water Treatment Technologies

LSIME, Basel, 2011

Lonza Water Treatment Technologies
Industrial Cooling water
 Bactericides
 Algaecides

Paper
 Slimicides
 Chlorine Stabilizers
 Defoamers

Pools and Spas

 Sanitizers
 Algaecides

Petroleum Process Additives - Oil Field

 Bactericides & Corrosion Inhibitors

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Lonza Water Treatment

Lonza Water Treatment provides customer value by:

 Providing knowledgeable application expertise to solve difficult

water treatment problems
 Offering a broad biocide product portfolio to optimize solutions

 Supplying products globally to support global customers

 Building strong customer partnerships and relationships for

successful outcomes

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Lonza Water Treatment – Product range
 Biocides
 Halohydantoins (Dantobrom®; BCDMH)
 Quaternaries
 Bardac® (DDAC); Barquat® (ADBAC);
 Barquat® PQ & PQ-2
 Isothiazolinone (Isocil® RW; Isocil® Ultra)
 Preservative system
 DMDMH / Isothiazolinone (Dantoserve®)
 Dantogard® 2000
 Stabilizer
 Equinox® Stabilizer 15
 Oil Field Corrosion Inhibitors
 Carbonate Quat (Carboshield®)
 Pyridine Quats (Uniquat®)
 Imidazolidines; Imidazolidines quat (Unamine®)
 Defoamers
 Amides (Acrawax® C; Glycowax®)
 PEG and PGE Esters (Pegosperse®; Polyaldo®)
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Lonza Water Treatment – main products
Equinox® Stabilizer 15 in combination with a Chlorine source
 improves paper machine & cooling tower performance and extends run
time by controlling biological deposits on surfaces
Lonza Halohydantoins
 Cost effective, fast-acting, broad spectrum bactericide, fungicide and
algicide applicable for many types of water systems
Lonza Quaternary Compounds
 Broadly applicable, cost effective, as algaecides, bactericides,
slimicides and molluscicides
Isocil® RW
Broad spectrum biocide, compatible with organics and widely
applicable to many water based systems
Bardac® LF 18 – Non BPD region
 cost effective, broad spectrum, easy to use algaecide for cooling water
systems
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Lonza Biocides
Lonza Halohydantoins
Lonza Halohydantoins – Water Treatment Uses

Existing Potential
Product Cooling Paper Pools/Spas Wastewater Potable
Dantobrom® x x x
BCDMH x x x x x

BCDMH and Dantobrom®

 Are oxidizing biocides
 Provide a controlled release of chlorine and bromine
 Have replaced liquid, solid and gas chlorine products in many applications
 Can be considered wherever chlorine or bromine biocides are used

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Lonza Halohydantoins - Typical Uses
Industrial Water Treatment
1. Recirculating Cooling Water Systems
2. Once-Through Cooling Water Systems
3. Evaporative Condensers
4. Brewery Pasteurizers
5. Industrial Air Washers
6. Photoprocessing Wash Water
7. Paper And Paperboard Process Water
8. Influent Water Systems
(Lagoons, Flow-Through Filters, Etc.)
9. Sewage Systems (Septic Tanks, Leach Fields, Tank Lines,
Sewers, Lagoons, Sewage Effluent Water)

Recreational Water Treatment

1. Swimming pools
2. Hot tubs and spas

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Lonza Halohydantoin Biocides

Combination of four components: CH3 O

1. Dimethylhydantoin (DMH) R
2. Methylethylhydantoin (MEH)
3. Bromine (Br) N N
X X
4. Chlorine (Cl)
O
R = CH3 or CH2CH3 X = Cl or Br

Major Products:
1. Dantobrom® RW (DMH; MEH; Br; Cl)
2. BCDMH (DMH; Br; Cl)

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Lonza Halohydantoins – Composition

Dantobrom
60.0% Bromochlorodimethylhydantoin (BCDMH)
27.4% Dichlorodimethylhydantoin (DCDMH)
10.6% Dichloromethylethylhydantoin (DCMEH)
2.0% Inert (Max.)

BCDMH
97.7% Bromochlorodimethylhydantoin (BCDMH)
2.3% Inert (Max.)

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Lonza Halohydantoins – on-demand hydrolysis

CH3 CH3
O O
H2O R
R
+ HOBr
N N N N
Br Cl H Cl
O O

CH3 CH3
O H2O O
R R
+ HOCl
N N N N
H Cl H H
O O

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Lonza Halohydantoins – Application Rates
Industrial Water
 Continuous Feed
Halogen: 0.5 to 1.5 ppm Cl2 Total Halogen
(0.1 to 0.2 ppm Cl2 Max Free)
Usage: 0.15 to 0.25 lbs/day/1,000 gallons system volume
0.18 to 0.30 kg/day/10M3 system volume
 Slug or Shock Feed
Halogen: Max 1 to 2 ppm Cl2 Total Halogen
(Max 0.5 ppm Cl2 Free)
Usage: 3X/Wk 0.10 to 0.20 lbs/slug/1,000 gallons system volume
0.12 to 0.24 kg/slug/10M3 system volume
5-7X/Wk 0.03 to 0.06 lbs/slug/1,000 gallons system volume
0.04 to 0.07 kg/slug/10M3 system volume

Swimming Pools
Halogen: 0.5 to 1.5 ppm Cl2 Total Halogen (1-3 ppm Br2 )
Usage: 0.18 to 0.30 kg//10M3

Spas
Halogen: 1.5 - 3 ppm Cl2 Total Halogen (3 - 6 ppm Br2 )
Usage: 8 - 12 g /1.1 m3/day
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Dantobrom® and Dantoin® BCDMH Tablets

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Lonza Quaternaries & Amines
Lonza Quaternaries & Amines
R CH3

+ - R N CH2 Cl
R N CH3 Cl
+ CH3 -

CH3

BARDAC® BARQUAT®
where R = C8-C18

C H2 C H2 CH 2 NH2
N [C 5H11 N O]+ Cl-
H25 C12 C H2 CH 2 C H 2 N H2 n = 4-6

Lonzabac® 12 Barquat® PQ

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Lonza Quaternaries – Application areas

Applied as algicides, bactericides, slimicides and molluscicides:

1. Cooling (Algicide, Bactericide, Molluscicide)

 Recirculating
 Once - through (molluscicide claims)
2. Papermaking (Slimicide)
3. Pool (Algicide & Algal Flocculent)
 In Season
 Winterization
4. Oil field flood & Salt water disposal
(Bactericide/Slimicide/Corrosion Inhibition)

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Barquat® (ADBAC) - Bardac® (DDAC) comparison

 ADBACs - Barquat®
 Similar efficacies and performance properties

 Foaming tendencies

 DDAC - Bardac®, Dialkyls

 Diverse efficacies and performance properties

 Improved efficacy in salt water than ADBACs

 Foam decreases with chain length

Bardac LF 18 = low foam)

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 Lonzabac 12
Bis (3-aminopropyl) dodecyl amine (CH2)3NH2
N
(CH2)3NH2

■ Free of halogen
■ Low corrosion (against iron / steel)
■ Compatible with surfactants
■ Complimentary biocidal effect in combination with complexing agents
(e.g. EDTA, NTA)
■ Effective also under neutral conditions (pH 7-9, neutralization with e.g.
lactic acid, glycolic acid, H4 EDTA, H NTA)
■ Little residues on surfaces
■ Tuberculocidal efficacy
■ Easy to defoam
LPC Lonzabac 12 presentation (LMI 1) slide 19
 Lonzabac 12 – Compatibility with surfactants

Compatibility
■ Lonzabac® 12 is compatible with cationic surfactants
■ Lonzabac® 12 is compatible with nonionic surfactants
■ Lonzabac® 12 is compatible with many anionic surfactants
(e.g. Fatty alcohol sulfate, Fatty alcohol ether sulfate etc.)
Remarks
■ All combinations must be checked for its chemical / physical stability and
biocidal performance
 The efficacy is very much dependent on e.g. pH value and the amine /
surfactant ratio (typically 3 / 1).
■ Amines like Lonzabac® 12 are not compatible with aldehydes (e.g. in perfume)

LPC Lonzabac 12 presentation (LMI 1) slide 20

 Lonzabac 12 – Synergistic biocidal effect

Complimentary biocidal effect in combination with complexing

agents
■ EDTA
■ NTA
■ MGDA (Methylglycin diacetic acid trisodium salt, Trilon M, readily
biodegradable)

Preferred active ratio Lonzabac® 12 / complexing agent: 3 / 1

Increasing Performance
pH 7 pH 14

LPC Lonzabac 12 presentation (LMI 1) slide 21

 Lonzabac 12 – Synergistic fungicidal effect

Complimentary fungicidal effect in combination with:

■ Piperazine
■ Guanidine salt e.g. Guanidin carbonate
■ Mono ethanol amine
■ Octyl amine

Preferred active ratio Lonzabac 12 / synergist: 1-2 / 1

Increasing Performance
pH 9 pH 14

LPC Lonzabac 12 presentation (LMI 1) slide 22

 Lonzabac 12 – biocidal efficacy
Minimum Inhibition Concentration (MIC) of LONZABAC 12.30
- Staphylococcus aureus 50 ppm
- Escherichia coli 500 ppm
- Proteus mirabilis 250 ppm
- Pseudomonas aeruginosa 50 ppm
- Candida albicans 100 ppm
LONZABAC 12.100 according EN 1276
Quantitative Suspension Test (log reduction ≥ 5.0); Contact time: 5 min. ;
Interfering substance: Albumine, 300mg/kg CaCO3
0.3% Albumine 0.03% Albumine
- Escherichia coli 0.025% 0.025%
- Staphylococcus aureus 0.10% 0.05%
- Pseudomonas aeruginosa 0.50% 0.025%
- Enterococcus hirae 0.05% 0.05%

LPC Lonzabac 12 presentation (LMI 1) slide 23

Non foaming algaecides

Polymeric Quats
Barquat® PQ; Barquat® PQ-2
Polymeric Quats
 Barquat® PQ and Barquat® PQ-2 are non foaming long chain
polymeric quaternary ammonium compounds which have
excellent performance against sessile and planktonic algae and
are also effective clarifiers

Principle applications are swimming pools and industrial

water treatment

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Polymeric Quats - Efficacy
University of Barcelona algaecide test
Chlorella vulgaris
 Algaecidal at 1.0 ppm

 Algaestatic at 0.5 ppm

DGHM inhibitory concentration

 E Coli > 50 ppm
 Ps aeruginosa > 500ppm

Excellent Algaecide / Poor Bactericide

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Polymeric Quats – Application rates
Swimming Pools – Barquat PQ-2
 Initial shock dose of 20-30 ppm
 Maintenance dose of 5-10 ppm
 10 ppm = 100g Barquat PQ-2/10,000 litres

Cooling Towers – Barquat PQ

 Initial slug dose of 20-40 ppm
 Maintenance of 5-20 ppm

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Polymeric Quats – Benefits
 Non Foaming
 can be used in heavily aerated water systems without the need for anti
foams

 Clarification through rapid algaecide performance

 this also reduces the load on the oxidising biocide

 Simple and economical to apply

 in use stability allows twice weekly shock dosing
 simple on site test methods can accurately measure the level of Barquat
PQ/PQ-2

 Stable in hard water and over a broad pH and temperature range

 Safe at use concentrations

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Isothiazolinones: Isocil® RW; Isocil® Ultra
 Isocil® RW & Ultra

Isocil RW is a mixture of two actives:

O O

N CH N CH
3 3
S S
Cl
5-chloro-2-methyl-4-isothiazolin-3-one 2-methyl-4-isothiazolin-3-one

Product concentrations: 14%; 1.5%

Isocil RW Ultra does not contain copper stabilizer

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Isocil® RW
 Strengths:
- Broad Spectrum Biocide
- pH insensitive up to 9.5
- Compatible with most organics
- Non-foaming liquid
- Easily deactivated with bisulfite

 Weaknesses:
- Strong skin sensitizer & corrosive
- Incompatible with 10 and 20 amines and sulfides
- Only fair algaecide
- Slow kill rate
- Commercial Limitation

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Isocil® RW – Typical Uses

ppm Active
Recirculating Cooling Water 2.25 - 13
Air Washers 2.25 - 13
Pulp and Paper 3.3 - 11.25
Oil Field Applications 2.25 - 13

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Halogen Stabilizer

Equinox® Stabilizer 15
Equinox Stabilizer 15

Equinox Stabilizer 15
 is a patented,
 liquid,
 Hydantoin programme,
 which enhances hypochlorite efficacy
 and reduces OBA’s, PAE, PAM, Starch and AKD requirements
in the paper industry

 Application
 paper industry
 Industrial water applications (e.g. cooling towers)

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Equinox® Stabilizer 15 – Benefits
The Equinox programme (Equinox Stabilizer 15 + active chlorine source)
improves performance via:
 Broad microbiological control of planktonic bacteria, fungi and yeasts and
exceptional control and inhibition of biofilms.
 Ease of application and control via a simple two pump dosing system and
static T mixer.
 Simple monitoring via DPD or Redox.
 Cost effectiveness compared to both non- oxidising and oxidising
programmes.
 Excellent environmental profile and safety in use.
 Unlike Ammonium Bromide it is not pH dependant.
 Any molar ratio combination greater than 1:1.5 can be used without risk of
problems.

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Equinox® Stabilizer 15 – Properties
 Physical Characteristics
 15% active aqueous solution
 pH = 9.8
CH3
O
 Stability
 Crystallization point < 40oC
CH3
 Stable for >1 year at 20oC
 Stable for > 1 month at 50oC
 DOT hazard Classification N N
 Non-hazardous
 DMH ingredient
H H
 DMH Oral LD 50 (rat) >10,000mg/kg
 Eye irritation: mild irritant O
 Skin irritation: mild irritant
 Registration status
 EPA reviewed non-registered stabilizer
 TSCA registered

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 Equinox® Stabilizer 15 – Mechanism of Action

Stabilization CH3 CH3

O O
Equinox reacts with
H2O CH3
NaOCl forming a CH3
stabilized + NaOCl N N
+ NaOH
N N
intermediate. Very Rapid
H H
Release Cl H
O
O
Stabilized intermediate

Controlled Release CH3 C H3

Stabilized intermediate O H2O O
CH3 CH3
serves as a
organochlorine Moderate + HOCl
N N “On-demand” N N
“reservoir” releasing
H Release
active chlorine “on- Cl H H

demand”. O O
Stabilized intermediate

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Equinox® Stabilizer 15

Microorganism
Up to six-fold increase in HOCL Efficacy.
Control
Worker Safety Non-Toxic and inert as supplied

Low Material and No specialized feeders, low viscosity liquid

Equipment Costs supplied in totes or bulk.
Environmentally
Biodegradable with reduced AOX effluent
Responsible
Compatible with Up to five-fold increase in additive compatibility
Additives compared to free halogen programs.
Easy to Use Constant concentration liquid feed.

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Halogen Stabilizer

Oilfield Corrosion Inhibitors

Oilfield corrosion inhibitors – Carboshield™
Didecyl Dimethyl Ammonium Carbonate / Bicarbonate (DDABC)
CH3

C10H21 N C10H21 HCO3- / CO3-2

CH3

Carboshield™ benefits:
 Chloride free (Didecyl Dimethyl Carbonate Bicarbonate)
 Excellent Corrosion Inhibitor through film forming effect in sweet conditions
 Good environmental profile (including CEFAS Registration)

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Oilfield corrosion inhibitors – Carboshield™

Carboshield™ reduces failure risk, increase the installation operability

and extend the equipment life

Carboshield™ applications:
 Completion fluids: wellbore cleaning

 Production Chemicals: corrosion inhibors in sweet environments

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 Oilfield corrosion inhibitors – Uniquat™ 10-80 HQ
Uniquat™ 10-80 HQ is a Benzyl Alkyl Pyridine Quat with high
quaternization degree that offers an excellent cost performance
solution for challenging technical environments
Outstanding corrosion inhibition performance in acid conditions:
 Sour gas fields
 Sour oil fields
 Acid stimulation jobs
High temperature stability (> 250 °C), ideal for:
 Down-the-hole injection
 Deep drilling applications

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Oilfield corrosion inhibitors – Uniquat™ 10-80 HQ
19% to 42% more quat than other alkyl pyridine  Better cost performance
quats available on the market
 Protect your assets under severe operating
conditions like sour fields or acid stimulation
jobs
Outstanding corrosion inhibition performance
 Reduce Failure Risks
under acid protection
 Reduce Operator risk by limiting H2S
leakage
 Increase Operability
High water solubility (high quat content)  Ideal for applications with high TDS and
Brines
High temperature stability > 250°C  Ideal for deep drilling and down-the-hole
injection
Excellent stability over time - Long shelf life  Efficacy remains consistent - No storage
issue with our product's shelf-life
Good chemical compatibility  Easy to formulate with other quats, non ionic
surfactants and commonly used biocides
High Quality Product and High production batch  No quality issue or change in performance
consistency that could impact the final product
performance.
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Back-up
Dantobrom® RW Typical Properties
Total Available Halogen as %Cl2 62
Available Chlorine, % Cl2 44
Available Bromine, % Br2 41
Total Insolubles, % <1
Water Solubility (g/100g @ 25C) 0.54
Color White
Odor Halogen
Briquette Wt. (grams) 12
Briquette Density (g/cm3) 1.6
Briquette Bulk Density (lb/ft3) 65
Briquette Dimensions, cm (L x W x T) 4 x 2 x 1.5
Stability In Water Stable
Moisture Retention (% @ 25C for 6 hrs.) 7
Melting Range (C) 120-148
Decomposition Temperature (C) 175
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