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FICHA DE DATOS DE SEGURIDAD

ACIDO FOSFOROSO
ACC# 21882

Section 1 - Chemical Product Identification

MSDS Name: Phosphorous acid

Catalog Numbers: AC201150000, AC201150010, AC201150020, AC201150050,
AC201155000, A246-500
Synonyms: Phosphonic acid; Orthophosphorous acid. Both CAS numbers in
Section 2 are legitimate. Some references use 13598-36-2 while others use
10294-56-1.

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS

10294-56-1 Phosphorous acid >98.5 233-663-1

13598-36-2 Phosphorous acid >98 .5 237-066-7

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white chunks.

Danger! Causes burns by all exposure routes. Air sensitive. Hygroscopic (absorbs
moisture from the air).
Target Organs: Respiratory system, gastrointestinal system, eyes, skin.
Potential Health Effects
Eye: Causes eye burns.
Skin: Causes skin burns.
Ingestion: Causes gastrointestinal tract burns.
Inhalation: Causes chemical burns to the respiratory tract.
Chronic: Repeated contact may cause corneal damage. Chronic exposure may
cause effects similar to those of acute exposure.

Section 4 - First Aid Measures

Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15
minutes. Get medical aid immediately.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get medical aid
immediately. Wash clothing before reuse.
Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If
victim is fully conscious, give a cupful of water. Never give anything by mouth to an
unconscious person.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in

pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed containers cool.
Substance is noncombustible. Contact with metals may evolve flammable hydrogen
gas.
Extinguishing Media: Use extinguishing media most appropriate for the
surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 1

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the Protective
Equipment section. Avoid generating dusty conditions. Cover with sand, dry lime or
soda ash and place in a closed container for disposal. Provide ventilation. Evacuate
unnecessary personnel.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and

wash before reuse. Use with adequate ventilation. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin,
or on clothing. Keep container tightly closed. Discard contaminated shoes. Do not
use with metal spatula or other metal items.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated
area away from incompatible substances. Keep away from metals. Corrosives area.
Do not store in metal containers. Storage under a nitrogen blanket has been
recommended. Store protected from moisture.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be

equipped with an eyewash facility and a safety shower. Use adequate ventilation to
keep airborne concentrations low.
Exposure Limits

Chemical Name ACGIH NIOSH OSHA - Final PELs

Phosphorous acid none listed none listed none listed

Phosphorous acid none listed none listed none listed

OSHA Vacated PELs: Phosphorous acid: No OSHA Vacated PELs are listed for this
chemical. Phosphorous acid: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR
1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be
followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties

Physical State: Chunks

Appearance: white
Odor: practically odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 200 deg C
Freezing/Melting Point:73 deg C
Decomposition Temperature:200 deg C
Solubility: Soluble.
Specific Gravity/Density:1.6510 g/cm3
Molecular Formula:H3O3P
Molecular Weight:82.00

Section 10 - Stability and Reactivity

Chemical Stability: Stable at room temperature in closed containers under normal

storage and handling conditions. Hygroscopic: absorbs moisture or water from the
air. Phosphorous acid absorbs oxygen very readily from the air to form phosphoric
acid.
Conditions to Avoid: Moisture, exposure to air.
Incompatibilities with Other Materials: Metals, strong bases.
Hazardous Decomposition Products: Oxides of phosphorus, phosphine.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:
CAS# 10294-56-1 unlisted.
CAS# 13598-36-2: SZ6400000
LD50/LC50:
Not available.
CAS# 13598-36-2:
Oral, mouse: LD50 = 1700 mg/kg;
Oral, rat: LD50 = 1895 mg/kg;
.

Carcinogenicity:
CAS# 10294-56-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 13598-36-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found

Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is

classified as a hazardous waste. US EPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must
consult state and local hazardous waste regulations to ensure complete and
accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG

Shipping
PHOSPHOROUS ACID PHOSPHOROUS ACID
Name:

Hazard Class: 8 8

UN Number: UN2834 UN2834

Packing Group: III III

 Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 10294-56-1 is listed on the TSCA inventory.
CAS# 13598-36-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 10294-56-1: delayed, reactive.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under
the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the
CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the
CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 10294-56-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 13598-36-2 can be found on the following state right to know lists: New
Jersey.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 22 Harmful if swallowed.
R 35 Causes severe burns.

Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).

WGK (Water Danger/Protection)

CAS# 10294-56-1: No information available.
CAS# 13598-36-2: 1
Canada - DSL/NDSL
CAS# 10294-56-1 is listed on Canada's DSL List.
CAS# 13598-36-2 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all of the information
required by those regulations.
Canadian Ingredient Disclosure List
CAS# 13598-36-2 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 2/15/1999

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Norbright be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Norbright has been advised of
the possibility of such damages.