MATERIAL SAFETY DATA SHEET
Last changed: 03/Dec/1998 Internal no.: :rev LdV-2 Replaces date: 08/Mar/1995
OXYGEN CONTROL
1. PRODUCT AND COMPANY
TRADE NAME OXYGEN CONTROL
APPLICATION OXYGEN SCAVENGER
ART-NO 655 571315 (25 liter)
Producer/Importer UNITOR CHEMICALS, Kjemi-Service AS
Address [Link] 49
Zipcode & City 3163 Borgheim
Country Norway
Telephone + 47 33 35 15 00
Fax + 47 33 35 15 05
Issued by Leen de Visser (+31 6 538 63736)
Emergency number Int. +44 1865 407333
Int. +1 703 5273887
USA (800) 424-9300
Greece Int. +30 1 7793777
2. COMPOSITION OF PRODUCT
No Ingredients name CAS-NO Cons.(weight%) Classification
1 hydrazine 302-01-2 10-30 T,45-10-23/24/25-34-43
2 Water 7732-18-5 60-90
Legend T+=Very toxic, T=Toxic, C=Corrosive, Xn=Harmful, Xi=Irritant, IK=No classification required, E=Explosive, O=Oxidising,
F+=Extremely flammable, F=Very flammable, Fo=Flammable, N=Dang. to the environment, Mut=Genetoxic,
Sens=Sensitizing, Carc=Carcinogen, Repr=Causes birth defects
INGREDIENT COMMENTS
When hydrazine is dissolved in water, it chemically changes to hydrazine hydrate (N2H4.H2O)
3. HAZARD IDENTIFICATION
Toxic
[Link].
Soluble in water.
May cause cancer.
Harmful by inhalation, in contact with skin and if swallowed.
Causes burns.
May cause sensitization by skin contact.
4. FIRST AID
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MATERIAL SAFETY DATA SHEET
Last changed: 03/Dec/1998 Internal no.: :rev LdV-2 Replaces date: 08/Mar/1995
OXYGEN CONTROL
GENERAL
Seek medical attention if any signs of unconsciousness or discomfort [Link] this safety data sheet to the
physician present.
INHALATION
Immediately move the exposed person to fresh air. Keep warm and in a quiet [Link] artificial respiration if
breathing has stopped. Get medical advice if discomfort develops.
SKIN CONTACT
Wash skin thoroughly with soap and water for several [Link] medical attention if irritation persists after
[Link] contaminated clothing [Link] contaminated clothing before reuse.
EYE CONTACT
Flush with large amounts of water (open eyelids) for at least 15 [Link] medical attention immediately. Continue to
rinse.
INGESTION
Never give anything to drink and never try to induce vomiting if the patient is not fully conscious.
Give plenty of water or milk to [Link] medical advice immediately.
5. FIRE FIGHTING MEASURES
PROPER FIREFIGHTING EQUIPMENT
Use extinguishing media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARDS
[Link] may explode if heated.
6. ACCIDENTAL RELEASE MEASURES
SAFETY MEASUREMENTS TO PROTECT PERSONS
Use personal protective equipment as specified in section 8.
SAFETY MEASUREMENTS TO PROTECT ENVIRONMENT
Avoid release of significant quantities of the product to water sources, sewers or the environment in general.
PROPER METHODS FOR DAMAGE LIMITATION AND CLEANUP
Remove spill with absorbent materials and/or mechanical equipment, and dispose of in accordance with section
[Link] with large amounts of water to clean the [Link] well.
OTHER INFORMATION
Small amounts can be flushed to sea or drain with large amounts of water.
7. HANDLING AND STORAGE
HANDLING ADVICE
Use personal protective equipment as specified in section [Link] contact with skin and [Link] facilities should
be available at the workplace.
STORAGE
S-3/9/49 Keep only in the original container in a cool, well ventilated place.S-3/9/49 Containers must be kept tightly
closed.
8. EXPOSURE CONTROL AND PERSONAL PROTECTION
Ingredients name CAS-no TLV value TLV Year
hydrazine 302-01-2 0.1 ppm 1995
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OXYGEN CONTROL
EXPOSURE CONTROL
Arrange working conditions and methods to avoid direct contact with the product.
RESP. PROTECTION
If ventilation is inadequate, use:Gas mask with cartridge K (ammonia, green) may be necessary.
EYE PROTECTION
Wear eye protection if there is a possibility of direct contact or splashes.
HAND PROTECTION
Use protective gloves of impervious material, e.g. rubber/plastic.
SKIN PROTECTION
Protective clothing should be worn if there is a possibility of direct contact or splashes.
OTHER INFORMATION
Eating, smoking and water fountains prohibited in immediate work area.S-13 Keep away from food, drink and animal
feedingstuffs.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form Liquid.
Colour Colourless.
Odour Ammonia-like.
Solubility Completely soluble in water.
Melting point/range -14 ºC (760 mm Hg) Density 1.01 @ 20 ºC
Expl. limit LEL-UEL., %-%: N/A Solubility in water 100%
Vapor pressure 20 mbar @ 20 ºC Saturation conc. N/A
Decomposition temp. N/A Rel. density sat. air (air=1) N/A
pH Solution 9 - 10 (1%) Boiling point/range 102 ºC (760 mm Hg)
Flash point N/A pH konsentrat: 12
Molecular weight N/A Viscosity 1.04 mPa.s @ 20 ºC
Ignition temp N/A Smelling limits lo-hi N/A
Rel. vapor density (air=1) N/A Rel. evap. velocity
Air reactive Water reactive
OTHER INFORMATION
N/A = Not applicable.
N/E = Not established.
10. STABILITY AND REACTIVITY
STABILITY
Stable under normal conditions.
MATERIALS TO AVOID
Avoid contact with acids.
Avoid contact with:Oxidizing materials. & heavy metallic salts.
HAZARDOUS DECOMPOSITION PRODUCTS
No decomposition if stored and used as [Link] toxic gas in contact with [Link] decompasation
generates:Hydrogen. & Ammonia.
OTHER INFORMATION
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OXYGEN CONTROL
Do not allow to [Link] intense heating.
11. TOXICOLOGICAL INFORMATION
OTHER TOX. INFORMATION
LD50/oral/rat =670 mg/kg* LD50 value for anhydrous substance.
LC50/inhalation/4h/rat =0.75 mg/l (N2H4)
GENERAL
Irritating to eyes, respiratory system and skin.
INHALATION
Vapour or aerosol (liquid particles) will irritate upper respiratory tract.
SKIN CONTACT
Prolonged or repeated exposure causes severe irritation.
EYE CONTACT
May cause intense discomfort, lacrimation and temporary vision impairment.
INGESTION
Toxic if swallowed.
SESITATION
May cause sensitization.
CANCER
EU Carcinogen Category 2.
Animal tests conducted under conditions comparable with the workplace situation have shown the substance to be
carcinogenic.
12. ECOLOGICAL INFORMATION
MOBILITY
Dissolves in water .
BREAKDOWN
Dumping of large amounts may cause pollution and deplete oxygen due to the degradation process which consumes
oxygen.
ACCUMULATION
Does not bioaccumulate.
ECOTOXITY
Exhibits low toxicity to water organisms.
OTHER INFORMATION
No environmental problems are expected if the product is handled/used correctly.
13. DISPOSAL
S-35 This material and its container must be disposed of in a safe way.S-35 In accordance with local and national
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OXYGEN CONTROL
regulations.
14. TRANSPORT INFORMATION
GENERAL
Goods classified for transport : YES
UN-no: : 3293
PROPER SHIPPING NAME : Hydrazine, aqueous solution
Flash point : N/A
Packing group : III
Label information:
ADR
Class : 6.1
Item. : 65c
Haz. id. no. : 60
ERI-Card : 6-03
TREM-Card : 61G65c
Labeltype : 6.1
Labelcolour : White./Black.
IMDG-CODE
Class : 6.1
Subsidiary risk : -
Marine pollutant : NO
EMS : 6.1-02
MFAG : 720
Page Number : 6161-1
Labeltype : 6.1
Labelcolour : White./Black.
IATA-DGR
Class : 6.1
Subsidiary risk : -
Labeltype : 6.1
Labelcolour : White./Black.
Aircraft Cat. : Passenger & Cargo aircraft
US DOT
Class : 6.1
Marine pollutant : NO
RQ : l lb
Labeltype : 6.1
Labelcolour : White./Black.
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MATERIAL SAFETY DATA SHEET
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OXYGEN CONTROL
15. REGULATORY INFORMATION
Classification
Toxic
COMPOSITION
hydrazine (10-30)
R-PHRASES
R-45 May cause cancer.
R-20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R-34 Causes burns.
R-43 May cause sensitization by skin contact.
S-PHRASES
S-53 Avoid exposure - obtain special instructions before use.
S-45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
REFERENCES
Classified according to European directive on classification of dangerous preparations 90/492/EEC.
OTHER INFORMATION
EU Carcinogen Category 2.
The product is labelled in accordance with EU directive 88/379.
16. OTHER INFORMATION
ISSUED: 03/Dec/1998
VENDOR NOTES
The safety data sheet fulfills requirements specified in Directive 93/112/[Link] safety data sheet has been prepared
on the basis of information given by our suppliers and our present [Link] given is intented to present
guidelines for safe handling, use, processing, storage, transport, disposal and discharge; it is not intended to be a
guarantee or quality [Link] intent of this safety data sheet is to give a description of the product with regard to
safe storage, handling and [Link] given applies only to the product itself, and not in combination with other
products or in any processed form, unless this is specified in the [Link] believe that all information in this safety data
sheet (which replaces all previous versions) was correct at the date of [Link] is the responsibility of the recipient of
this safety data sheet to ensure that information given here is read and understood by all who use, handle, dispose of or
in any way come in contact with the product.
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