Unit 1 Principles of Chemistry
Atomic Structure
Tr. Kyaw Zin Thant
Learning Objectives
What is an element, atom, molecule?
ELEMENTS are substances that can’t be split into anything simpler by chemical means.
Elements contain only one type of atom and cannot be split into anything simpler.
(E.g., Hydrogen, Oxygen, Carbon)
ATOMS can be described as the smallest part of an element that has the properties of
that element.
(E.g., hydrogen atom, oxygen atom)
MOLECULES are two or more atoms joined together chemically by covalent bonds.
(E.g., ozone O3, carbon dioxide CO2, water H2O)
SPECIAL NOTE
A hydrogen molecule (H2) consists of 2 hydrogen atoms joined together chemically.
A water molecule consists of 2 hydrogen atoms and 1 oxygen atom joined together chemically.
Atoms
Protons
ATOM Neutrons P, N, E are called SUB-ATOMIC particles because they are smaller than an atom
Electrons
Memorise this
Particle Relative mass Charge
Proton 1 +1
Neutron 1 0
Electron 1/1840 = 0.0005 -1
Atomic number or Proton number (Z)
Atomic number: The number of protons in an atom’s nucleus is called the atomic number or the proton number.
Mass number or Nucleon number (A)
Mass number: The number of protons and neutrons in an atom’s nucleus is called the mass number or the nucleon number.
mass number = number of protons + number of neutrons
Isotopes
Isotopes are atoms of the same element which have the same atomic number but different mass numbers.
They have the same number of protons but different number of neutrons.
Number of
Isotopes Carbon-12 Carbon-13 Carbon-14
Protons
Electrons
Neutrons
SPECIAL NOTE
The fact that they have different mass numbers makes no difference for their chemical reactions.
The chemical properties are controlled by the number and arrangement of electrons and which is the same for all 3 isotopes.
Relative atomic mass
Relative atomic mass is the ratio of the average mass of one atom of an element to one twelfth of the mass of a carbon-12 atom.
35Cl 37Cl
A natural sample of chlorine contains more 35Cl isotope than 37Cl isotope because the relative atomic mass is closer to 35 than 37.
Relative atomic mass
A naturally occurring sample of the element boron contains 20% 10B and 80% 11B.
Calculate the relative atomic mass.
Electrons
Atoms are electrically neutral (no overall charge) because the number of protons is equal to the number of electrons.
Number of electrons = Number of protons
Number of protons =
Number of electrons =
Number of protons = Number of neutrons =
Number of electrons =
Number of neutrons =