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Stereochemistry Handwritten Notes - ChemContent

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3K views35 pages

Stereochemistry Handwritten Notes - ChemContent

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noothan gude
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© © All Rights Reserved
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Homanons Bomors | (identéeat) SAMO COnSKEey yes Na ‘ ' ary Stercavsomarrs Constitetia Brats athe) fsamors | (Oon- Supreimpesabse 8 Fnantfomors | Décsfev eons Opreccet ACE era, ‘the rotation OF Proune poroized £éy ht Is encoun as wee aervely cn SupHanees possessing hs properties Axe CoULed] Op Cal Gotéve » The op}cax activity ahsenved and measured by a fnstrument canted. pararémoke Prane posarizod Light (ppL) i In: cdlnasy Sght Vibration aceurs * Qu -the pranes Percpencliewvar tone cliecHier én. Which “Lhe liavel when eydireny AGKe 400} htowh aiteor presm- “then Vibraricn takes peace EES AE Mn ONY ane ANEetcare ; TL 15 Ceetted} Mane. potortcad Ligh (pL Onde , Plane - orcnizad. Kolinat y Light Mahe ty if ra R Vv Matyion Onelinaay Sampee tobe | PPh ChONTOM hight t norco) (ctrexau cOnposrdl J FEIUC = poraydmaiere Seriq xine > befere reojatien’ Bmroyen “Rings OFKA you) ' GAZ anfee CF yolaKan “Tengee OF ROlatcer cand] pect e_polatran OPHeCoumly AcHve compounds Tolaie INE Psane of Ne Porarst zoo Baht AN KO ON ON OF e&- The arse &, Measured] iA deynoo( s) fs eater ano one OF vojadeen Co J A cornpourel Thaw) reorarcthe prcuneof- Polorruer] asynt & Sato] - be spi’camy acttve + Be pee ee 7 q }K——______| oprenuy active comp cue] QM exI5 ta Fou Fons: (0 Deentaier] (al) a) Force 9 IP the ttoaiien CF ANG plane i$ 46 “hy rene terocrwse) hen “ne Subsione i caveo} dextrocolasercy ( LakO® tr, Lat @) Lerclovoaratony (4) Orl(-) fern _ LEAHa itorasion FARO pecine és Ne JOEL Canticocnwise) than the Jobsiano 5 eee haevoroaraery (kaso! 2aen @- ean te ap-fécou Sommers hich have atleast ~Rp chircou Centrea but Posses prone of OyMniTey 5 caued mescform . Its Opa: (nactye dre Mra compe! anne Fe tha “so}etien Cased » afer hate 6% tho morecuse ts" nos lise by tho Lowen past @ tho mosecueo + er col HH} OH pioneoe HH }-—on Syameny Oo} re Ol+ ow ou 4) racemic mixtuice OL) ante} + Equimolare Mexluo. OF POIs oF eNaNéamr | | 3S ceca} reacemic ‘mexqurce Tt iS epitcauy *Madtive clue 0 exsercnou Lemgensote r@ the soicetion CoLUSeo} by the ol Foor fs nevicay tea] rby fro 4 ftom. rape oF notation ofeperdts pon @ “he nadoree of Subsinade. Q concoptratian aFne sarnpee ©) Lonyth OF tube Ot) >» von angth OF ho Light Temperate tt ) “the conmey) parasimelercuse the Sadiem - DVN om moreuRy seen AN + ow New medley Spoeira- porarémoter Use phowcens ber They give morce accurate Value. le Spocrfee Rajation — Specific icoradéen. 15 Ihe obseue Qnyre oF tegiarion, PF A-clm Cloem) tude és seq and Contant satay af Sampee is | a Me | [sp], AXC Sporific rcolatien- ahgescved anje oF ie oes cent °) ce renin Om )x q/me TP PUA. SAMPLE GF OPieCatty Active - Gobsyanaa [3 used hoy ' “bere d| reqpteesenis clensity OF & fore Saumpoo ie maons “specrfee reoleucer) 4s Melopencloh ae nt ts I) OF tobe (2) » ater) OF a Hae) Echt Excess SM 44M0S We decss kil A MIXIUICo OU iS NeHAGe Optecay pure, eannitomer Nor A (acenviecl mixtone. ono Lnaniemey 7S present) excoss: oF sho athores . “tho ereenifomerie ‘excoeds (ee) A130 Corttco| he op yor puacly 1 H20L3, How muah! move + {SOF “one Caantetmer. Fnanieemanie excos $(ee) =% OF ano Sania (= KONE other coumanen ford : TPG mixture, conan 15% GF ore ehantemey GN 957. OR WA Others then Whe ey Oxc03s 'f59 DIM 00 = 15% ~aGy, - 50%, f thene 15 G. sox exceny FONG!) Oanfimer OY hE Sacomie Mixtere 1 anficna io craniancte © iS %y- thoy haw ruch af kath CmMinemnce fs prorat} soot Jax eo MEARS Aho re garMoyara an errors OF 45 % BEAN Enanane Ad gh OF We racemic Matto OF bot? onankemans- POL ra ane Misti conhins An are amount oF bath Saanarvrs. fthas 12°57. 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Plane of ¥symmoiry = i ae paano os cord hicoyyh “the micldgo of a mosecuse In Suth Ya L tuny What One hare of -the molewwLe iS Q Merstox WMaAZe OF tho ohare he. EX I~ oH cn) % ~D Plane of Syramoty Nem Ton Mrag} te © centeay Canby, of ) On 2OV 4 coon | Vy run “titers oe] Conta cay oan, Se ee eg en eee. Wo plano of Symoceey \ —) bex bon onon- \ \ iden) atm) GH chi3 a) conse OF Gy romenrcy (1) ; i ot point can mosecuio en) fe ati ts dicate 19 One ire «TPO cotta yo egoal clfslance in oppas pee 7 mnodts anolhor sins att qor bl Cts A BIC = foc Wigs x (3) Avis of Syarnaitty \ HCn) !- An ima: inany axis “nica which ee is rearited by an ane ane fee crientatiod af LIN® abjeek sy i fren 1S me avientatiane 130° ~ rl 7 x Sh | Ch Adentecal | SS Sinveloe - Sa al Ey + which of-tho foncuhy Molecules aro china ? N ' ) 3) | wl! on fH () ct GH @) :. " H yy | on Ck t £ ! + ye : @ Di IN ol co Anse @) - = oe OCs nese ff ont ae & = mbsene o present Calton: "Absent syrumetnte SH . Ch= present achiral eae Zisummeinicmarecte op kealt oa Hive ich Chisar Gkanly active ne Ky Reb & 4’ paeyent opuesent a a See dynvetnic S ymnicl Co eerent yircad nekraa Gee inacive 0 Synnotnee ope conty nV _ chiral 1 kc nacre mace one nals tith Asgav Nn carbon @torn lie feucat HOU 4a fl b- a GOH ie Pe, "Hl cH Kaci acid N07 cio! | c=0 | one FH —c20H ! HOCH J cot CHp0H pthieal Centre 4) f gurl nal . Ayts t- ds husene: Reick eal Cc CHS oo ( on) AYN 4-chisal Cenie fray ACL fi oftfcally Act symone cash") ) rts © if asymmetric Oy Nn toa 3 ore “dans V0 hed a I? chiral ¢-atoo °C asyamecnc calm) cus CHg ¥ a cn) 4 fA g- butanat a t ¢ ro gg Paalno <2 chraso butane HOW ff ™ Le je & Pee de oll CHa achiral | an can. achiral Conte ay an) * ‘y Due 100 chat ian A b - C= «© (gb) a a I ra JF ms at doubie Ww ro 0¢ lech, bonels axe even hands a's © Goly Ub ; NY Eo, 'O:Q6 ' : oA ND Db ' oD ep fo . a. NAN J Ado 0 dbidd \/ + ! Pee perdcusays ane en Hine Lo plane b Vho groups cu the ond! ANG grocpsat Me ng OF Quencs are peyenat’ OF Cuenesare cn CUtaY 48 cach anon | Game PLand x lg Heno Axisersymmetny * pero fiance oF. Scyromoty | Her Paes projont ow: feosens } i Absent ] Cy -Pbsent Hend Cy > present Symmonue, pchixat i Fbsenb optcat inactive ws Pent wb Pee a, J h eee aa eee ce See a= 0 =e Disco~pmoetree v —— : ‘erat mreCO Chives geamentoag i ‘ Opiecany active ' A) Vs a. ' pet Died Bw. his

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