Alkene
www.etoosindia.com
01. The relative stability of the compounds
is in the order -
(A) I > II > III > IV > V > VI
(B) VI > V > IV > III > II > I
(C) I > III > V > II > IV > VI
(D) II > I > IV > III > V > VI
02. The carbon -carbon bond length in the following
compounds
(A) III < II < I < IV
(B) IV < I < II < III
(C) I < II < III < IV
(D) I < IV < III < II
03. The most common reaction of alkenes are those of
(1) Nucleophilic substitution
(2) Electrophilic substitution
(3) Electrophilic addition
(4) Nucleophilic addition
04. The reaction is a example of
CH2 = CHCH3 + HBr CH3CHBrCH3
(1) Nucleophilic addition
(2) Electrophilic addition
(3) Electrophilic substitution
(4) Free radical addition
05. The markownikoff's rule is used in connection with
(1) Stereochemistry of elimination reactions
(2) Stability of free radicals.
(3) Activity of enzymes
(4) Addition of acids to double bonds
06.
07. The catalyst used in kharash reaction , is –
(1) Only halogenated compound
(2) Any peroxide
(3) Al2 (SO4)3
(4) TiCl4
08. Reactivity of alkenes towards HX increases in the
order
(1) Isobutene > Propene > Ethene
(2) Isobutene > Ethene > Propene
(3) Ethene > Propene > Isobutene
(4) Propene > Ethene > Isobutene
09. Ethylene forms ethylene chlorohydrin by the action of
(1) Dry HCI gas
(2) Dry chlorine gas
(3) Solution of chlorine gas in water
(4) None
10. 3- Methyl-2 pentene on reaction with HOCI gives -
11.
(1) Glycol
(2) Dial
(3) Dioic acid
(4) None of these
12. Olefines can be converted to paraffins by –
(1) Halogenation
(2) Hydrolysis
(3) Hydration
(4) Hydrogenation
13. R – CH = CH2 adds on water in the presence of
dilute sulphuric acid or phosphoric acid to from -
(1) R – CH (OH) – CH3
(2) R – CH2 – CH2OH
(3) R – CHOH – CH2 – CH2 – CHOH – R
(4)
14. 2° alcohol.
The alkene would be:-
(1) CH3 – CH = CH2
(2) CH3CH2 – CH = CH2
(3)
(4) CH3 – CH = CH – CH3
15. Isobutylene on hydroboration followed by reaction
with H2O2 / OH–
(1) Primary alcohol
(2) Secondary alcohol
(3) Tertiary alcohol
(4) Dihydric alcohol
16. Prilieschaive's reaction involve –
(1) Epoxidation of alkene
(2) Hydroformylation of alkene
(3) Partial hydrogenation of alkene
(4) Combustion of unsaturated hydrocarbon
17. Two jars A and B are filled with hydrocarbons. Br2
in CCl4 is added to these jars. A does not decolourise
the Br2 solution, but B decolourises. What are A and
B
(1) Alkane and alkene
(2) Alkene and alkane
(3) Alkene and alkyne
(4) Alkyne and alkane
18. Which of the following characteristics apply both to
ethene and ethyne –
(1) Form white precipitate with AgNO3 solution
(2) Explode when mixed with chlorine
(3) Decolourise Baeyer's reagent
(4) Rapidly absorbed by cold conc. H2SO4
19. Baeyer's reagent is –
(1) Alkaline permanganate solution
(2) Acidified permanganate solution
(3) Neutral permanganate solution
(4) Aqueous bromine solution
20. Ozonolysis of 2- methyl butene-2 yields –
(1) only aldehyde
(2) Only ketone
(3) Both aldehyde and ketone
(4) Aldehyde or ketone
21. Which set of products is expected on reductive
ozonolysis of the following diolefin ?
22. Propene when heated with chlorine at about 500°C
forms -
23. Addition of halogen acid is least in –
(1) CH2 = CHCH3
(2) CH2 = CH2
(3) (CH3)2C = CH – CH3
(4) (CH3)2C = CH2
24.
Products,
the products are
25. For hydroformylation , the suitable reagent is –
(1) CO + H2O
(2) H – CHO
(3) CO + H2
(4) HCOOH
26.
27.
28. HCl does not form Anti - Markownikoff's product
with propene, because –
(1) HCl is a polar covalent molecule
(2) Dipole -Dipole attraction exists between HCI
molecules
(3) Formation of CI is energetically unfavourable
(4) Chlorine has the highest electron affinity
29. Choose the correct statement –
(1) Addition of HCl to vinyl chloride yield vicinal
dichloride
(2) There is difference between peroxide effect and
Kharash effect
(3) Peroxide is a ready source of free radical in the
Markownikoff's reaction
(4) Propene with HCl in presence of peroxide gives
isopropyl chloride
30. Initial attack in the reaction between 1 -butene and
bromine will be –
(1) Bromonium ion
(2) Bromide ion
(3) Bromine atom
(4) Bromine molecule
31. 2- methyl propene is isomeric with butene-1.
They can be distinguished by-
(1) Baeyer's reagent
(2) Ammonical AgNO3
(3) Br2 solution
(4) O3, H2O/Zn
32. Which of the following is the structure of propylene
chlorohydrin
33. An alkene on oxidation with acidic KMnO4 gives
only acetic acid , what is alkene –
(1) CH3 = CH – CH3
(2) CH3 – CH = CH – CH3
(3) Ethylene
(4) 2- Pentene
34. Ethylene reacts with osmium tetroxide to form an
osmic ester which on hydrolysis gives
(1) Ethyl alcohol + osmic acid
(2) Glyoxal + Osmic acid
(3) Ethylene glycol + H2OsO4
(4) Glycollic acid + H2OsO4
35. In the addition of HBr to propene in the absence of
peroxides the first step involves the addition of
(1) H+ (2) Br–
(3) H (4) Br
36. In which of the following kharasch effect operate -
(1) CH3CH2CH = CH2 + HCl
(2) CH3CH2 – CH = CH2 + HBr
(3) CH3CH = CH – CH3 + HBr
(4) CH3CH2CH = CH2 + HI
37. 1-Butene on heating with aluminium sulphate at
high temperature (200°- 300°) isomerises to give
(1) 2-Butene
(2) Isobutylene
(3) Both the above
(4) Cyclobutane
38.
39.
40. Ethylene reacts with Br2 to give 1, 2-dibromoethane.
The anti -addition takes place due to the formation
of the intermediate -
41. trans -2 - Butene reacts with cold dilute KMnO4
solution to produce –
(1) Meso -2, 3-butanediol
(2) () –2-butanol
(3) () 2, 3 - butanediol
(4) 2, 3- butanedione
42. A hydrocarbon (X), C6H12, on catalytic
hydrogenation gives n- hexane. (X) on addition with
HBr forms only a single bromocompound. (X) is -
(1) CH3CH2CH2CH2CH = CH2
(2) CH3CH2CH2CH = CHCH3
(3) (CH3)2C = C(CH3)2
(4) CH3CH2CH = CHCH2CH3
43. In the reaction possible products are -
44.
The product of the above reaction is -
45. In presence of CHCl3 and alc. KOH , cyclo hexene
gives
46. Which of the following is maximum reactive
towards NBS
(1) PhCH3
(2) Ph CH2 – CH3
(3) PhCH2 – CH = CH2
(4) Ph – CH – CH = CH2
47. The major product of the following reaction is
48.
49. On ozonolysis of an alkene by H2O/Zn, the product
obtained is cyclobutane carbaldehyde. The
structure of alkene is -
50. In the elimination of reactions, that is , in the
formation of alkenes , the reactivity of halogens in
alkyl halides is in the order –
(1) I > Br > CI
(2) CI > Br > I
(3) Br > CI > I
(4) None
51. Ethyl chloride on heating with alcoholic potash
gives –
(1) C2H4
(2) C2H2
(3) C2H6
(4) CH4
52.
01.
53. Alcohols undergo dehydration in the following
sequence –
(1) 1° > 2° > 3°
(2) 3° > 2° > 1°
(3) 1° > 3° > 2°
(4) 3° > 1° > 2°
54.
55. n-Butyl alcohol on dehydration forms -butylene
as the chief product. This happens because of the
rearrangement -
56. Which ester on pyrolysis gives isobutylene
57.
(A) and (B) are geometrical isomers than -
(1) A is trans, B is cis
(2) A and B both are cis
(3)A and B both are trans
(4) A is cis , B is trans
58.
59. Arrange the following alkanols a, b and c in order
of their reactivity towards acid catalysed
dehydration -
(1) a > b > c (2) b > a > c
(3) b > c > a (4) c > b > a
60.
which is most easily dehydrohalogenated –
(1) I (2) II
(3) III (4) all with same case
61.
The product can be
62.
(A) and (B) in the above reaction sequence are-
(1) s-Butyl bromide, - Butylene
(2) t-Butyl bromide, Isobutylene
(3) s-Butyl bromide, - Butylene
(4) n-Butyl bromide, - butylene
63. Electrochemical oxidation of the succinate ion
(1, 4-butanedioate ion) into ethylene proceeds
through the formation of the intermediate -
64. The products A and B in the reaction
are given by the set -
(1) CH3–CH2–CH(OH)–CH3 and CH3–CH2–CH = CH2
(2) CH3–CH=CH–CH3 and CH3–CH2 – CH2 – CH2OH
(3) CH3–CH = CH – CH3 and CH3 – CH2 – CH = CH2
(4) CH3–CH2–CH2–CH2OH and CH3 – CH2–CH=CH2
65. Arrange the following alkanols A, B and C in order
of their reactivity towards acid catalysed
dehydration
(1) A > B > C (2) B > A > C
(3) B > C > A (4) C > B > A
66. Which of the following compound undergoes
dehydrochlorination most easily when treated with
alcoholic KOH -
67. Which alkene on heating with hot and conc.
KMnO4 solution gives acetone and a gas, which
turns lime water milky –
(1) 2–Methyl–2–butane
(2) Isobutylene
(3) 1-Butene
(4) 2-Butene
68. Find the product of following reaction
69.
Major product (Z) is –
(1) Optically active 1° - alcohol
(2) Optically active 2° - alcohol
(3) Optically inactive 1° - alcohol
(4) Optically inactive 3° - alcohol
