CHEMISTRY

EASY GAME
Q1. 10 ml of K2Cr2O7 solution liberated iodine from KI solution. The liberated iodine was titrated by 16 ml
of M/25 sodium thiosulphate solution. Calculate the concentration of K2Cr2O7 solution in gram per litre.
Q2. A polyvalent metal weighing 0.1 gm and have atomic weight 51.0 reacted with dil. H2SO4 to give 43.9
ml of H2 at NTP. The solution containing the metal in the lower oxidation state was found to require 58.8
ml of 0.1 N KMnO4 for complete oxidation. What are valencies of metal?
Q3. 1.2 gm of a commercial sample of oxalic acid was dissolved in 200 ml of H2O. 10 ml of this sample
required 8.5 ml of N/10 KMnO4. Calculate % purity of the sample.
Q4. 0.5 gm of an oxalate sample is dissolved in H2O and diluted up to 100ml. 10 ml of this solution was
treated with 15 ml N/20 KMnO4 solution. Calculate the % purity of the sample.
Q5. In an ore, the only oxidisable material is Sn++. This ore is titrated with a dichromate solution containing
2.5 gm of K2Cr2O7 in 0.5 litre. A 0.40 gm sample of the ore required 10cm3 of titrant to reach equivalence
point. Calculate % of tin in the ore.
Q6. 0.804 gm sample of iron ore was dissolved in acid. Iron was iodized to +2 state and it required 47.2 ml
of 0.112 N KMnO4 solution for titration. Calculate % of Fe and Fe3O4 in ore.
Q7. A mixture of KMnO4 and K2Cr2O7 weighing 0.24 gm on being treated with KI in acid solution liberates
just sufficient I2 to react with 60ml of 0.1 N hypo (Na2S2O3). Find out % of Cr and Mn in mixture.
Q8. One litre of pure water was added to 500 ml (density = 1.2 gm/ml) of 32% HNO3(by mass). What is the
% by mass of HNO3 in the solution obtained?
Q9. A solution of ethanol in water is 10% by volume. If the solution and pure ethanol have densities of
0.9866 gm/ml and 0.785 gm/ml respectively. Find % by weight.
Q10. The mole fraction of CH3OH in an aqueous solution is 0.02 and its density is 0.994 gm/ml. Determine its
molarity and molality.
Q11. The density of a 3M sodium thiosulphate aqueous solution is 1.25 gm/ml. Calculate the % by wt. of
sodium thiosulphate. (b) The mole fraction of sodium thiosulphate. (c) The molalitites of Na+ and S2O32–
ions.
Q12. How much BaCl2 would be needed to make 250 ml of a solution having the same conc. of Cl– ions as
are contained in 3.78 gm of NaCl per 100ml.
Q13. What are the final concebtration of all the ions when following are mixed: 50 ml of 0.12 M Fe(NO3)2,
100 ml of 0.10 M FeCl3 and 100 ml of 0.26 M Mg(NO3)2.
Q14. Upon mixing 45 ml of 0.25 M lead nitrate solution with 25 ml of 0.10 M chromic sulpahte, precipitation
of lead sulphate takes place. How many moles of lead sulphate are formed. Also calculate the molar
conc. of the species left behind in final solution. Assume that lead sulphate is completely insoluble.
Q15. Na2CO3 solution is made up by dissolving 22.5 gm of Na2CO3·10H2O in water and adding water until
the total volume is 200 ml. The density of the resulting solution is 1.04 gm/ml. Calculate (a) molarity (b)
mole fraction of Na2CO3 in the solution (c) molalities of Na+ and CO32– ions.
Q16. What would be the molality of a solution made by mixing equal volumes of 30% by mass of H2SO4
(density = 1.218 gm/ml) and 70% by mass of H2SO4 (density = 1.61 gm/ml). Also, calculate the molarity
of the solution.
Q17. Determine the volume of dilute nitric acid (d = 1.11 gm L–1, 19% HNO3) that can be prepared by
diluting with water 50 mL of conc. HNO3 (d = 1.42 g mL–1, 69.8%)
Q18. The powerful antitumor medicine Cisplatin PtCl2(NH3)2 has spherical particles of diameter 6.6 x 10-4
cm. Compute how many atoms of platinum are in the average particle of Cisplatin.
[density of Cisplatin is 3.86 g/cm3]
Q19. To a sample of an element X (at. wt. 70) element Y (at. wt. 120) is added as impurity. The ratio of atoms
of X to Y in the mixture is 1 : 10-7. How many gms of Y will be required for 100 gm of X for this ratio.
Q20. Chemical bottles labelled to contain the blue coloured NiSO4.6H2O instead has the green coloured
NiSO4.7H2O. How many fewer gms of Ni are in 1 lb (453.6 gm) NiSO4.7H2O than would be in 1 lb of
NiSO4.6H2O?
Q21. 0.15 g of urea was treated with excess of sodium nitrite and dil H2SO4 acid. Due to reaction CO2 and N2
gases are evolved. The mixture is passed through a concentrated solution of KOH which absorbs CO2.
The volume of the remaining gas at STP will be ______.
Q22. 1.879 g metal bromide, heated in steam of HCl gave one gm metal chloride. If the sp. heat of metal is
0.14 cal/gm calculate mol. wt. of metal bromide.
Q23. Potassium superoxide reacts with H2O to give KOH and O2. How many moles of oxygen can be
produced by reacting 0.15 mol potassium superoxide and 0.1 mol H2O?
Q24. X gm of NaCl were gently heated with conc. H2SO4. The gas formed was absorbed in water and
neutralised by adding NH4OH. The resulting solution was reacted with NaNO3, and the product are
heated to give 2.464 L gas at STP. find the value of X.
Q25 A fluorine disposal plant was constructed to carry out the reactions:
F2 + 2NaOH  2NaF + H2O + ½ O2, 2NaF + CaO + H2O  CaF2 + 2NaOH
As the plant operated, excess lime was added to bring about complete precipitation of the fluorides as
CaF2. Over a period of operation, 1900 kg of fluorine was fed into the plant and 1 tonne of lime was
required. What was the percentage utilization of lime?
Q26. What molar concentration of K4Fe(CN)6 should be used so that 40 mL of the solution titrates 130.8mg
Zn (dissolved) by forming K2Zn3[Fe(CN)6]2.(Zn = 65.4).
Q27. 4g of a sample of blue vitriol (CuSO4.5H2O) were dissolved in water. BaCl2 solution was mixed in
excess to this solution. The precipitate obtained was washed and dried. It weighed 2.33g. Determine the
percentage by weight of sulphate radical in the sample. (Cu = 63.5, S = 32, Ba = 137).
Q28. 1 gram of CaC2O4 is heated at such a temperature that it is entirely changed to CaCO3. If all the CaCO3
thus obtained is suspended in 100 ml of water and CO2 gas is passed through to dissolve the suspension,
what is the molarity of the calcium bicarbonate solution?
Q29. A particular 100-octane aviation gasoline used 1.00 cm3 of tetraethyllead, (C2H5)4Pb, of density 1.66g/
cm3, per litre of product. This compound is made as follows:
4C2H5Cl + 4NaPb  (C2H5)4Pb + 4NaCl + 3Pb. How many g of ethyl chloride, C2H5Cl, is needed to
make enough tetraethyllead for 1.00 L of gasoline?
Q30. Chlorine gas is produced in the laboratory by the reaction K2Cr2O7 + 14HCl  2KCl + 2CrCl3 +
7H2O + 3Cl2. If a 60g sample of K2Cr2O7 (95% pure) is allowed to react with 0.3 litre HCl solution
(density = 1.15g/cc) and containing 30% by mass of HCl, how much Cl2 is produced?
Q31. Exactly 50ml of Na2CO3 solution is equivalent to 56.3 ml of 0.102N HCl in an acid-base neutralization.
How many gm CaCO3 would be precipitated if an excess of CaCl2 solution were added to 100 ml of
this Na2CO3 solution.
Q32. A 0.5 g sample containing MnO2 is treated with HCl, liberating Cl2. The Cl2 is passed into a solution
of KI and 30.0 cm3, 0.1M Na2S2O3 are required to titrate the liberated iodine. Calculate the % of
MnO2 in the sample. (at. wt. Mn =55)
Q33. Mn2+ (aq.) can be determined by titration with MnO4-(aq.)
Mn2+ + MnO4- + -OH  MnO2 + H2O(unbalanced)
A 25.0 ml sample of Mn2+ (aq.) required 34.77 ml of 0.05876 KMnO4(aq.) for its titration. What
is the molarity of Mn2+(aq.)
Q34. A 100 mL solution consists of H2C2O4 and H2SO4 in 1 : 1 molar ratio. 25 mL of this solution requires 30
mL of KOH which was prepared by adding 5.6 gm KOH in 500 mL of solution. Find out the volume of
CO2 liberated at STP if 50 mL of this solution is boiled.
Q35. 25 mL solution containing a mixture of Na2CO3 and NaOH required 19.5 mL of 1 N HCl for HPh end
point and in a separate titration 25 mL of the same mixture required 25.9 mL of same HCl for MeOH
end point. Calculate strength of each base in mixture. [St(Na2CO3)=27.0 g/L, St(NaOH)=20.85 g/L]

Middle Game
Q1. A mixture of CuSO4·5H2O and MgSO4·7H2O was heated until all the water was driven off. If 5.0 g of
mixture gave 3 g of anhydrous salts, what was the percentage by mass of CuSO4·5H2O in the original
mixture?
Q2. Chlorine dioxide (ClO2), has been used as a disinfectant in air conditioning systems. It reacts with water
according to the reaction: ClO2 + H2O  HClO3 + HCl
In an experiment, a 10.0 L sealed flask containing ClO2 and some inert gas at 300 K and 1.0 atmosphere
pressure is opened in a bath containing excess of water and all ClO2 is reacted quantitatively. The
resulting solution requried 200 mL 0.9 M NaOH solution for naturalization. Determine mole fraction of
ClO2 in the flask.
Q3. Consider the following reactions:
XeF2 + F2  XeF6
and XeF6 + (–CH2–CH2)n  (–CH2–CH2–)n  (–CH2–CH2–) + HF + XeF4
Determine mass of F2 (g) required for preparation of 1.0 kg fluorinated polymer.
Q4. 2.0 g of a sample containing NaCl, NaBr and some inert impurity is dissolved in enough water and
treated with excess of AgNO3 solution. A 2.0 g of precipitate was formed. Precipitate on shaking with
aqueous NaBr gain 0.76 g of weight. Determine mass percentage of NaCl in the original sample.
Q5. A solution contain both Na2CO3 and NaHCO3. 10mL portion of this solution is mixed with few drops of
phenolphthalein indicator and titrated against 0.08 M H2SO4 solution. 7.0 mL of acid was requried to
reach the end point A 5.0 mL portion of this solution was then taken for further analysis and a few drops
of methyl orange was added to it and finally titrated against same acid solution. 3.53 mL of acid was
required to reach the end point. Determine mass of Na2CO3 and NaHCO3 per litre of solution. Ignore
volume change due to addition of indicator.
Q6. A mixture was known to contain both KNO3 and K2SO3. To 0.486 g of the mixture, dissolved in enough
water to give 50 mL solution, was added 50 mL of 0.15 M HCl solution. The reaction mixture was
heated to expel all SO2 and then 25 mL of the reaction mixture was titrated with 0.1 M KOH. The
titration required 12.11 mL of the base. Calculate mass percentage of K2SO3 in the mixture.
Q7. A complex of cobalt with ammonia is analyzed for determining its formula, by titrating it against a
standardized acid as follows:
Co(NH3)xCl2(aq) + HCl  NH4+ (aq) + Co(3+(aq) + Cl–(aq)
A 1.58 g complex required 23.63 mL 1.5 M HCl to reach the equivalence point. Determine formula. If
the reaction mixture at equivalence point is treated with excess of AgNO3 solution, what mass of AgCl
will precipitate out?
Q8. 2.725 g of a mixture of K2C2O4, KHC2O4 and H2C2O4·2H2O is dissolved in 100 mL H2O and its 10mL
portion is titrated with 0.1 N HCl solution.
20 mL acid was required to reach the equivalence point. In another experiment, 10mL portion of the
same stock solution is titrated with 0.1 N KOH solution. 20 mL of base was required to reach the
equivalence point. Determine mass percentage of each component in the mixture.
Q9. An unknown cupric salt with formula Cux(CO3)y(OH)z is analyzed to determine the exact formula. A
1.7225 g sample of salt was dissolved in 100 mL of pure water. A 50 mL portion of this solution required
10 mL 1.0 N H2SO4 solution to reach the equivalence point if phenolphthalein was used as indicator.
Another 50 mL portion was titrated using methyl orange as indicator and 15 mL acid of same strength
was required. Deduce the formula of the salt.
Q10. In acidic solution, 45 mL KMnO4 solution is requried to react with 50 mL 0.25 N Na2C2O4 solution.
How many mL of this same KMnO4 solution would be required to oxidise 25 mL 0.1 N K2C2O4
solution in alkaline medium where KMnO4 is reduced to MnO2.
Q11. A 6.1 g sample containing oxalic acid dihydrate, sodium oxalate and NaHC2O4 and is dissolved in 100
mL of water and its 10.0 mL portion required 16 mL 0.25 M HCl to reach the equivalence point. In
another experiment 10.0 mL portion of the same stock solution required 24 mL 0.25 M NaOH to reach
the equivalence point. Determine the mass percentage of all components in the original mixture.
Q12. A 0.127 g of an unsaturated oil was treated with 25 mL of 0.1 M ICl solution. The unreacted ICl was
then treated with excess of KI. Liberated iodine required 40 mL 0.1 M hypo solution. Determine mass
of I2 that would have been required with 100.0 g oil if I2 were used in place of ICl.
Q13. One gram of an impure sample of NaCl was dissolved in water and treated with excess of AgNO3
solution. The precipitate AgCl thus, formed undergo decomposition into Ag and Cl2(g) and latter
disproportionate into chlorate (V) and chloride ions and chloride is re-precipitated due to presence of
excess of AgNO3. If the original precipitate was 60% decomposed and final precipitate weigh 1.5 gram,
determine mass percentage of NaCl in original sample.
Q14. The CO in a 20.3 L sample of gas was converted to CO2 by passing the gas over iodine pentoxide
heated to 1500C. I2O5(s) + 5CO (g)  5CO2(g) + I2(g). The iodine distilled at this temperature and
collected in a vessel containing 8.25 ml of 0.011 M Na2S2O3. The excess Na2S2O3 was back titrated
with 2.16 ml of 0.00947 M I2 solution. Calculate the number of milligrams of CO per litre of the sample.
Q15. A gas mixture was passed at the rate of 2.5 L/min. through a solution of NaOH for a total of 64
minutes. The SO2 in the mixture was retained as sulphite ion: SO2(g) + 2OH–  SO32– + H2O. After
acidification with HCl, the sulphite was titrated with 4.98 mL of 0.003125 M KIO3.
IO3– + SO3– + HCl  ICl2– + SO42– + H2O. If density of the mixture is 1.2 gm/lt, calculate
concentration of SO2 in ppm.
Q16. The chromate ion may be present in waste from a chrome plating plant. It is reduced to insoluble chromium
hydroxide by dithionate ion in basic medium S2O42– + Cr2O42–  SO32– + Cr(OH)3. 100 ml of water
require 387 gm of Na2S2O4. Calculate molarity and normality of CrO42– in waste water. Also express
concentration in ppm of Na2CrO4.
Q17. CuSO4 reacts with KI in an acidic medium to liberate I2 2CuSO4 + 4KI  Cu2I2 + 2K2SO4 + I2.
Mercuric periodate Hg5(IO6)2 reacts with a mixture of KI & HCl according to the following equation:
Hg5(IO6)2 + 34KI + 24 HCl  4K2HgI4 + 8I2 + 24 KCl + 12 H2O
The liberated iodine is titrated against Na2S2O3 solution; 1 ml of which is equivalent to 0.0499 gm of
CuSO4·5H2O. What volume in ml of Na2S2O3 solution will be required to react with the I2 liberated from
0.7245 gm of Hg5(IO6)2?
Given Mol. wt. of Hg5(IO6)2 = 1448.5 gm/mol; Mol. wt. of CuSo4·5H2O = 249.5 gm/mol
Q18. A 4.476 gm sample of a petroleum product was burned in a tube furnace and the SO2 produced was
collected in a 3% H2O2 solution
SO2 + H2O2  H2SO4
A 25 ml portion of 0.00923 M NaOH was introduced into the solution of H2SO4, following which the
excess base was back-titrated with 13.3 ml of 0.01 M HCl. Calculate parts per million of sulphur in the
sample.
Q19. The arsenic in a 1.223 gm sample of a pesticide was converted to H3AsO4 by suitable treatment. The
acid was then neutralized and exactly 40 ml of 0.08 M AgNO3 was added to precipitate the arsenic
quantitavely as Ag3AsO4. The excess Ag+ in the filterate required 11.27 ml of 0.1 M KSCN as
Ag+ + SCN–  AgSCN (s) Calculate the percent As2O3 in the sample. (As2O3 = 198)
Q20. A mixture of HCl and H2PO4 is titrated with 0.1 M NaOH. The first end-point (methyl red) occurs at 35
ml and the second end - point (bromothymol blue) occurs at a total of 50 ml. 15 ml after the first end-
point, calculate the millimoles of HCl & H3PO4 present in the solution.
Q21. The purity of hydrazine, N2H4, sample is determined by titration with iodine. A sample of the only liquid
weighing 1.4286 gm is dissolved in water and diluted to 1 litre. A 50 ml of this solution required 42.41 ml
I2 solution. I2 solution was standardized against 0.4123 gm primary standard As2O3 by dissolving As2O3
in a small amount of NaOH solution, adjusting the pH to 8, and titrating requiring 40.28 ml iodine
solution. What is the percent purity by weigh of the hydrazine. (As = 75; I = 127)
H2AsO3– + I2 + H2O  HAsO42– + 2I– + 3H+
N2H4 + 2I2  N2 + 4H+ + 4I–
Q22. A sample of water has its hardness due to only CaSO4. When the water is passed through an anion
exchange resin, SO42– ions are replaced by OH–. A 25 ml sample of this water sample so treated
requires 21.58 ml of 10–3 M H2SO4 for titration. What is the hardness of water expressed in ppm of
CaSO4? Assuming that density of water is 1 gm/ml.
Q23. 5 gm of bleaching powder was suspended in water and volume made up to half a litre. 20 ml of this
suspension when acidified with acetic acid and treated with excess of potassium iodide solution liberated
iodine which required 20 ml of a decinormal hypo solution for titration. Calculate percentage of available
chlorine in bleaching powder.
Q24. The elemental Se, dispersed in a 5 ml sample in “Head & Shoulders” shampoo for dandruff control, was
determined by suspending the sample in a warm, ammoniacal solution that contained 45 ml of 0.02 M
AgNO3.
6Ag+ + 3Se(s) + 6NH3 + 3H2O  2Ag2Se(s) + Ag2SeO3(s) + 6NH4+
The mixture was next treated with excess nitric acid which dissolved the Ag2SeO3 but not the Ag2Se.
The Ag+ ions from the Ag2SeO3 and the excess AgNO3 consumed 16.74 ml of 0.0137 M KSCN in a
volhard titration. How many milligrams of Se were contained per milliliter of sample?
Q25. A 0.646 gm sample containing BaCl2·2H2O was dissolved and an excess of a K2CrO4 solution added.
After a suitable period, the BaCrO4 was filtered, washed and redissolved in HCl to convert CrO42– to
Cr2O72–. An excess of KI was added, and the liberated iodine was titrated with 84.7 ml of 0.137 M
sodium thiosulphate. Calculate the present of BaCl2· 2H2O.
Q26. It was desired to neutralize a certain solution prepared by mixing KCl and hydrobromic acid. Titration of
10ml of this solution with 0.1M AgNO3 solution required 50ml of the latter for the complete precipitation
of the halides. The resulting precipitate when filtered, washed and dried weighed 0.771 gm. How much
0.1M NaOH must have been used for the neutralization of 10ml of the solution.
Q27. 1 gm sample of KClO3 was heated under such conditions that a part of it decomposed according to the
equation
(1) 2KClO3  2 KCl + 3O2
and remaining underwent change according to the equation.
(2) 4KClO3  3 KClO4 + KCl
If the amount of O2 evolved was 146.8 ml at S.T.P., calculate the % of weight of KClO4 in the residue.
Q28. When the Bayer process is used for recovering Aluminium from siliceous ores, some aluminium is always
lost because of the formation of an unworbable ‘mud’ having the following average formula: 3Na2O ·
3Al2O3 ·· 5SiO2 · 5H2O. Since Aluminium & Sodium ions are always in excess in the solution from which
precipitate is formed, the precipitation of Silicon in the ‘mud’ is complete. A certain ore contained 13%
Kaolin (Al2O3 · 2 SiO2 · 2 H2O) and 87% Gibbsite (Al2O3 · 3H2O). What % of total aluminium in this
ore is recoverable in the Bayer process.
Q29. A definite amount of BaCl2 was dissolved in HCl solution of unknown normality 20 ml of this solution
was treated with 21.4 ml of N/10 NaOH for complete neutralization. Further 20 ml of solution was
added to 50 ml of N/10 Na2CO3 & the precipitate was filtered off. The filterate reacted with 10.5 ml
of 0.8 N/10 H2SO4 using phenolphthalein indicator. Calculate the strength of BaCl2 & HCl in mixture.
Q30. 25 mL of a 0.107M H3PO4 was titrated with a 0.115M solution of a NaOH solution to the end point
identified by the colour change of the indicator, bromocresol green. This required 23.1 mL. The titration
was repeated using phenolphthalein indicator. This time, 25 mL of same H3PO4 solution required 46.8
mL of same NaOH solution.
What is the coefficient 'n' in the equation H3PO4 + nOH  nH2O + [H(3n) PO4]n for each reaction?
Q31. A sample of fuming sulphuric acid containing H2SO4, SO3 and SO2 weighing 1.00g is found to require
23.47 mL of 1.00 N alkali for neutralisation. A separate sample shows the presence of 1.50% SO2. Find
the percentage of "free" SO3, H2SO4 and "combined" SO3 in the sample.
Q32. An acid solution of a KReO4 sample containing 26.83 mg of combined rhenium was reduced by
passage through a column of granulated zinc. The effluent solution, including the washings from the
column, was then titrated with 0.10 N KMnO4. 11.45 mL of the standard permanganate was required
for the re-oxidation of all the rhenium to the perrhenate ion, ReO4– . Assuming that rhenium was only
element reduced. What is the oxidation state to which rhenium was reduced by the Zn column.
(Atomic mass of Re = 186.2)
Q33. Chrome alum K2SO4 . Cr2(SO4)3 . 24 H2O is prepared by passing SO2 gas through an aqueous
solution of K2Cr2O7 acidified with dilute sulphuric acid till the reduction is complete. The alum is
crystallized followed by filtration/centrifugation. If only 90% of the alum can be recovered from the
above process, how much alum can be prepared from 10kg of K2Cr2O7? Give the number of
moles of electrons supplied by SO2 for reducing one mole of K2Cr2O7.
Q34. A 1.87gm. sample of chromite ore(FeO.Cr2O3) was completely oxidized by the fusion of peroxide.
The fused mass was treated with water and boiled to destroy the excess of peroxide. After acidification
the sample was treated with 50ml. of 0.16M Fe2+. In back titration 2.97 ml of 0.005 M barium
dichromate was required to oxidize the excess iron (II). What is the percentage of chromite in the
sample?
Q35. 25 mL of a solution containing HCl was treated with excess of M/5 KIO3 and KI solution of
unknown concentration where I2 liberated is titrated against a standard solution of 0.021M Na2S2O3
solution whose 24 mL were used up. Find the strength of HCl and volume of KIO3 solution
consumed. ANSWER

EASY GAME
Q1. 3.136 g/l Q2. 2 & 5 Q3. 63.75% Q4. 66% Q5. 15.051%

Q6. %Fe = 36.82% Q7. %Cr = 20.93; %Mn = 14.224% Q8. 12% Q9. 7.957%

Q10. 1.088M; 1.134m Q11. (w/w)% = 37.92; xB = 0.065; m Na  = 7.732; mS 2O 23 = 3.866

Q12. 16.8 g Q13. [Fe2+]=0.024M; [Fe3+]=0.04M; [Mg2+]=0.104M; [Cl-]=0.12M; [NO3-]=0.321M

Q14. PbSO4 = 7.5 x 10-3 moles, [Cr3+] = 0.071M; [NO3-] = 0.321M

Q15. 0.393M; x Na 2 CO 3 = 7.576 x 103; m Na  = 0.848; m CO 32 = 0.4761 Q16. 11.402m; 7.614m

Q17. 234.983ml Q18. 1.167 x 1012 Q19. 1.714 x 10-5g Q20. 6.518 g

Q21. 56 ml Q22. 45.377 g mol-1 Q23. 0.113 mole Q24. 6.435 g

Q25. 28% Q26. 3.338 x 10-2M Q27. 24.5% Q28. 0.078M

Q29. 1.326g Q30. 41.322g Q31. 0.574g Q32. 26.1%

Q33. 0.123M Q34. 268.8ml Q35. Strength = 27.136 g/l (Na2CO3)

MIDDLE GAME
Q1. 76.069g Q2. 0.090 Q3. 3.04 kg Q4. 49.955%

Q5. 11.872 g/l –Na2CO3; 6.720 g/l –NaHCO3 Q6. 43.174% K2SO3 Q7. x  5 ; 7.195g AgCl

Q8. K2C2O4 = 28%; KHC2O4 = 50.752%; H2C2O4.2H2O = 21.248% Q9. CuCO3.2Cu(OH)2

Q10. 15 ml Q11. 41.295% H2C2O4.2H2O; 21.951% –Na2C2O4; 36.754% –NaHC2O4

Q12. 100g Q13. 40.767% Q14. 0.172 mg/l Q15. 10.375ppm

Q16. 1.483 x 10-2 mol/l; 4.449 x 10-2 equivalant/L; 2.402 x 103 ppm Q17. 40 ml Na2S2O3 solution.

Q18. 349.419 ppm Q19. 5.594% As2O3 Q20. m moles of HCl = 0, m moles of H3PO4 = 0

Q21. 98.219% Q22. 117.395 ppm CaSO4 Q23. 35.5% available Cl2

Q24. 7.947 mg/ml Q25. %BaCl2.2H2O = 99.766% Q26. 12.02 ml Q27. 49.8%

Q28. 9.75% Q29. 3.906g/l –HCl; 4.368 g/l BaCl2

Q30. For Bromocresol, n = 1; For Phenolphthalein n = 2

Q31. Free SO3= 63.1%; H2SO4 = 35.4%; Combined SO3 = 28.89% Q32. 0.5 of Re = -3

Q33. n-factor of K2Cr2O7 = 6; 30.551 Kg Alum Q34. 15.794% Q35. vol of KIO3 = 0.420ml