Methanol Thermodynamic Properties From

176 to 673 K at Pressures to 700 Bar

Cite as: Journal of Physical and Chemical Reference Data 16, 799 (1987); https://doi.org/10.1063/1.555786
Submitted: 30 January 1987 . Published Online: 15 October 2009

Robert D. Goodwin

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Journal of Physical and Chemical Reference Data 16, 799 (1987); https://doi.org/10.1063/1.555786 16, 799

© 1987 American Institute of Physics for the National Institute of Standards and Technology.
 Methanol Thermodynamic Properties From 176 to 673 K at Pressures
to 700 Bar
Robert D. Goodwin

Thermophysics Division, National Engineering Laboratory, National Bureau ofStandards, Boulder, Colorado 80303

Received January 30,1987; revised manuscript received June 11, 1987

Available data for vapor pressures and for the orthobaric densities of methanol are
examined and formulated. Then, PpT data are correlated by an equation of state (EOS)
which is constrained to the given coexistence boundary. Via ideal gas state specific heats,
the thermodynamic properties of methanol then are obtained by numerical integrations of
the EOS, and are tabulated along isobars. A comparison is made with some recent calori-
metric enthalpy differences data over a wide range of the EOS surface.

Key words: compressibility factors; densities; enthalpies; entropies; equation of state; fugacities;
heats of vaporization; ideal gas; Joule-Thomson coefficients; methanol; orthobaric densities; specif-
ic heats; speeds of sound; thermodynamic properties; vapor pressures; vir1al coetficients.

Contents

1. Introduction......................................................... 800 6. Acknowledgments.. ........... ....... ........... ................. 891

2. Developing the Equation of State ........................ 801 7. References ............................................................ 891
·2.1. Methanol Vapor Pressures .......................... 801
2.2. Methanol Orthobaric Densities .................. 801
2.2.a. Saturated Liquid Densities .............. 801 List of Tables
2.2. b. Saturated Vapor Densities ... ........... 805 1. Selected fixed-point values for methanoL.......... 801
2.2.c. Alternative Vapor Densities Equa- 2. Summary of vapor-pressure data for methanol. 801
tion. .................................................. 810 3. Methanol vapor-pressure data .......... ................. 802
2.3. The Virial Equation .................................... 810 4. Summary of orthobaric-densities data for
2.4. Pressure-Density-Temperature Data ......... 811 methanol........... ......... ......... ......... ..... ....... .......... 805
2.5. The Equation of State ................................. 811 5. Methanol saturated liquid densities data ........... 805
3. Thermal Properties and Computations................ 844 6. Methanol saturated vapor densities data........... 807
3.1. Functions for Ideal Gas States ....... .... ......... 844 7. Summary of Pp T data for methanoL...... .......... 811
3.2. The Homogeneous Domain .... _...... _............ 844 8. Zubarev methanol isotherm fitting .................... 812
3.3. Properties at Coexistence ............... ....... ...... 846 9. Comparison of PpT data for methanoL............ 815
3.3.a. Specific Heats on the Vapor Bound- 10. Methanol critical isotherm................................. 845
ary ................................................... 846 11. Methanol ideal ~as state data ............................. 846
3.3.b. Saturated Liquid Enthalpies and En- 12. Methanol interpolated ideal gas state functions. 847
tropies ................................... ~.... ...... 848 13. Comparison with methanol CO' (T) data of Carl-
3.3.c. Saturated Liquid Specific Heats ...... 848 sonIWestrum, 1971..... .................. .............. ....... 848
3.4_ Compressed Liquid States .. __ ._ ... __ ._._._ ... __ ..... 848 14. Comparison of methanol enthalpy data ...... ....... 8'0
3.5. Comparisons.. ....... ....... ....... ....... ........... ...... 848 15. Joule-Thomson inversion locus for methanol... 851
4. Tables of Thermophysical Properties. ................. 849 16. Properties of saturated liquid methanol............. 852
4.1. The Joule-Thomson Inversion Locus ......... 849 17. Properties of methanol along isobars ........ ......... 856
4.2. Properties at Coexistence ............................ 849
4.3. Properties Along Selected Isobars .... .... ...... 849
5. Comments. ....... .......... ....... ....... ....... ........... .......... 849
List of Figures
1. Methanol coexistence boundary .. ..... ......... .......... 800
© 1987 by the U.S. Secretary of Commerce on behalf of the United States.
This copyright is assigned to the American Institute of Physics and the
2. Methanol vapor densities deviations .... ................ 810
American Chemical Society. 3. Derived C v (T) u at the liquid boundary ..... ......... 849
Reprints available from ACS; see Reprints List at back of issue. 4. Comparison of enthalpy differences at 515.2 K ... 851

0047-2689/87/040799-94/$10.00 799 J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987
800 ROBERT D. GOODWIN

Symbols and Units S(p,T) entropy, J mol- l K- 1

T temperature, K
Subscripts c and t refer to critical and liquid triple points
Tu(p) liquid-vapor coexistence temperature
Subscripts g and 1 refer to saturated vapor and liquid
u(T) defined where used
Subcript (]" refers to liquid-vapor coexistence
x(T) defined where used
a, P, r,li,E, p exponents in various functions V 1/p, molal VOlume, L/mol
B(T),C(T) virial coefficients, Eq. (4) W(p,T) speed of sound, mls
Cu(T) saturated liquid specific heat, J mol- 1 K- 1 Z(P,p,T) P I (p' R . T), the "compressibility factor"
C" (p.T) isochoric specific heat. J mol- 1 K- 1
CII isochoric specific heat at the critical point
(C.P.), 161.14J mol- l K- 1
isochoric specific heat at the liquid boundary,
Jmol- 1 K- 1 1. Introduction
Cp(p,T) isobaric specific heat, J mol- 1 K- 1 Methanol is a major commodity chemical whose heavy
E(p,T) internal energy, J/mo} industrial use has been described by Machado and Streett. 42
E~ =H~ 35 374.762 J/mol (arbitrary) Thermodynamic charts for methanol have been prepared by
f fugacity, bar Smith,60 and a Pp T surface was correlated by Bhattacharyya
liP fugacityIpressure coefficient and Thodos. 6 In an ongoing series of reports, fundamental
F(p,T) defined function in the EOS properties were collected by Wilhoit, et al.68 A valuable sur-
G(p,T) Gibbs energy, J/mo} vey was presented by bubank, 17 and a book on the thermo-
H(p,T) enthalpy, J/mol physical properties was published in Russian by Zubarev,
H~ enthalpy for ideal gas state at T = 0 Prusakov, and Sergeyeva. 74
L liter, 10- 3 m 3 Polymerization of methanol in the vapor state is a trou-
mol 32.0424 g of methanol (molecular weight) blesome phenomenon for the experimentalist and correlator.
P pressure, bar (1 bar:::: lOS N/m2) This has been examined by Weltner and Pitzer,67 Inskeep,29
P' 1.013 25 bar (latm) Kell,33 Tucker,66 Kudchadker,38 Bartczak,5 Francis,21 and
Pu(T) vapor pressure of saturated liquid, bar Nath.47
Pu(p) p u [ T u (p) ], vapor pressure as function of In the present correlation of the thermodynamic prop-
density, bar erties of methanol we rely heavily on the PpT data of Ma-
/)JJvap, heat of vaporization, J/mol chado and Streett42 and on the recent data of Straty. 63 Iso-
l
gas constant, 8.3145 J mol- K-t, 0.083 145 . chore curvatures in Straty's PpT data change sign at a
(bar L/mol) IK reduced density near 0.83, not at the critical density. We
p density, mol/L thus obtain a specific heat CII (p,T) , which is finite at the
u piPc, reduced density critical pOint, via Eq. {10), below.
Uo 0.825, reversal of isochore curvatures, Eq. Symbols and units are given in the list above, and the
(6) coexistence phase diagram is outlined in Fig. 1. Selected
Pllp" , rec1ncec11iqnic1 c1emdty at triple point fixed-point values are listed in Table t ~ The triple-point tem-

30--------------------------------------~--------~

...J
:::: 20
o
e
>='
I-
Cii Coexistence Boundary
Z
W 10
Q
C.P.

O~--2~OO-----------3LOO----------4-0-0==~------5~OO----------8-00

T. K
FIG. 1. Methanol coexistence boundary.

J. Phys. Chern. Ref. Data. Vol. 16. No. 4.1987

 THERMODYNAMIC PROPERTIES OF METHANE 801

TABLE 1. Selected fixed-point values for methanol In(Pu ) =a/x+b+cx+dx2 +ex3 +f(l-x)P, (1)
Triple point Boiling point Critical point where

Temperature, K 175.59 337.668 512.60 a= - 10.752848790, d 4.373231 941,

Pressure, bar 1.835'10- 6 1.013 25 80.9464
Density, mol/L, b= 16.758206642, e= - 2.381 377 449,
vapor 1.271.10- 7 3.8131'10- 2
23.352
8.40
8.40
c= - 3.603 424623, f= 4.572 198 698.
liquid 28.226

The root-mean-square (rms) relative pressure deviation of

perature is from Carlson and Westrum. to Young70 reported 0.34% for 83 selected data is not as precise as obtained for
Tc = 513.15 K, Pc = 79.59 ± 0.08 bar, Pc = 8.455 mol/L. many other substances. Data of Straty63 at ID = 99 [( ID)
The only recent determination of critical parameters appar- identification of data sources] were used before discovering
ently is that of Kay and Donham 32 : Tc = 512.58 K, that he doubted their accuracy, based on apparatus limita-
Pc = 80.972 bar, Pc = 8.49 mol/L. tions. The data ofYoung,70 ID = 10, based on those of Ram-
Our critical density, Pc 8.40 mol/L, was adjusted in say and· Young, 53 are included to provide information on
the course of fitting orthobaric densities. The boiling-point possible temperature-scale adjustments (column IlT),
temperature in Table 1 is from Eq. ( 1 ) at Y 1.013 25 bar, which would be useful to salvage their extensive and precise
and the triple-point pressure is from Eq. (1) at T = T t • Oth- orthobaric densities and Pp T data.
er fixed-point orthobaric densities are from Eqs. (2) and (3) Column Resid. in Table 3 gives values of the residual,
at appropriate temperatures.
In(PuiPt )/In(PcIPt ) - (1 - TtIT)/( 1 - TtITc ),

the examination of which is most helpful for developing any

2. Developing the Equation of State vapor-pressure equation.
The present isochoric equation of state (EOS) is con-
strained to the formulated coexistence boundary (vapor
2.2. Methanol Orthobaric Densities
pressures and orthobaric densities). The winno.wing of
masses of data, to cull inaccurate but often precise sets, is a Table 4 presents some sources of orthobaric density
difficult but necessary process. Hence, some excluded data data for methanol.
are presented in this report, but are used with zero weight for
the least-squares determination of the coefficients in fitting 2.2.a. Saturated liquid Densities
functions. The selected virial nos for low-density regions Deviations from Eq. (2) arc givcn ill Table 5 using
also is presented below [Eq. (4)] . Apparently no high-pres- x(T) == T /Tc, u(T) == (1 - x), and exponent {3 = 0.35.
sure melting line Pm (T) has been established for methanol, Then
which forms glasses under these conditions. See, however,
e.g., Carlson and Westrum 10 for calorimetric transitions at (PI/Pc -1) = aufJ + b(x - 1) + c(x2 - 1) + d(x 3 - 1),
low pressures and temperatures. (2)
where
2.1. Methanol Vapor Pressures
a= 2.51730906, c= 3.06681768,
Some of the available vapor-pressure data for methanol
are listed in Table 2. Deviations from Eq. (1) are given in b - 2.466 694 19, d - 1.32507680.
Ta.ble 3 using x (T) ;;; T /Tc' P u (T) in ba.r, and exponent The rms relative density deviation is 0.17% for 43 selected
p = 1.70. Then data. Data at ID = 72 have been obtained from formulated

TABLE 2. Summary of vapor-pressure data for methanol

ID Author/year Range ofT, K Range of P, bar

87 Ramsay, 1887 (Ref. 53) 263-512 0.02-78.3

lU Young, 19lU (Ref. 7U) 263-512 0.02-78.3
13 Mundel, 1913 (Ref. 46) 205-229 1.4-10- 4-1.3-10- 3
51 Waltner, 1951 313-338 0.35-1.00
55 Kay, 1955 (Ref. 32) 403-503 8.4-69.0
64 SkllAtes, 1964 (Ref. 59) 403 503 8.4 69.0
67 Hirata, 1967 (Ref. 28) 363-473 2.5-39.4
70 Ambrose/Sprake, 1970 (Ref. 3) 222-357 0.1-2.1
73 Zubarev, 1972 175-510 1.9'10- 6-77.4
74 Counsell, 1973 (Ref. 13) 306-338 0.25-1.0
71 Gibbard, 1974 (Ref. 23) 288-338 0.10-1.0
75 Ambrose/Sprake/Townsend, 1975 (Ref. 4) 353-463 1.8-33.1
83 Machado,1983 298-473 0.2-40.1
65 Miller, 1984 (Ref. 45) 175-180 1. 7 '10- 6-4.1-10- 6
99 Straty, 198' 488-'08 '3-74

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

802 ROBERT D. GOODWIN

Table 3. Comparison of reported vapor pressures with values calculated from Eq. (1)

ID Wt. T TITe p Calc. P % Resid. .:1T

K bar bar Dev.
55 1.00 403.162 0.78650 0.83771E+Ol 0.84168E+Ol -0.47 0.01257 -0.178
55 1.00 413.166 0.80602 0.10880E+02 O. 10899E+02 -0.17 0.01138 -0.068
55 1.00 423.170 0.82554 O. 13921E+02 O. 13926E+02 -0.04 0.01010 -0.015
55 1.00 433.175 0.84505 0.17582E+02 0.17578E+02 0.02 0.00879 0.010
55 1.00 443.179 0.86457 0.21946E+02 0.21940E+02 0.03 0.00746 0.013
55 1.00 453.184 0.88409 0.27110E+02 0.27104E+02 0.02 0.00616 0.010
55 1.00 463.188 0.90361 0.33191E+02 0.33171E+02 0.06 0.00493 0.030
55 1.00 473.193 0.92312 0.40252E+02 0.40253E+02 -0.00 0.00370 -0.001
55 1.00 483.197 0.94264 0.48449E+02 0.48475E+02 -0.05 0.00254 -0.029
55 1.00 493.201 0.96216 0.57971E+02 0.57987E+02 -0.03 0.00153 -0.016
55 1.00 503.204 0.98167 0.68975E+02 0.68984[+02 -0.01 0.00064 -0.007
64 1.00 403.160 0.78650 0.83770E+01 0.84164E+Ol -0.47 0.01257 -0.176
64 1.00 413.170 0.80603 O. 108 80E+02 O. 10900E+02 -0.18 0.01137 -0.072
64 1.00 423.170 0.82554 O. 13920E+02 0.13926E+02 -0.04 0.01009 -0.018
64 1.00 433.180 0.84506 0.17581E+02 0.17580E+02 0.01 0.00878 0.003
64 1.00 443.180 0.86457 0.21946E+02 0.21940E+02 0.03 0.00746 0.012
64 1.00 453.180 0.88408 0.27110E+02 0.27102E+02 0.03 0.00617 0.014
64 1.00 463.190 0.90361 0.33191E+02 0.33173E+02 0.06 0.00493 0.028
64 1.00 473.190 0.92312 0.40251E+02 0.40251E+02 0.00 0.00370 0.000
64 1.00 483.200 0.94265 0.48449E+02 0.48478E+02 -0.06 0.00254 -0.032
64 1.00 493.200 0'.96215 0.57971E+02 0.57986E+02 -0.03 0.00153 -0.015
64 1.00 503.200 0.98166 0.68974C..,..02 0.68979D.,.02 -0.01 0.00064 -0.004
65 0.20 175.063 0.34152 0.16930E-05 o. 16824E-05 0.63 -0.00001 0.038
65 0.20 175.603 0.34257 0.18270E-05 0.18394E-05 -0.67 -0.00037 -0.041
65 0.20 176.484 0.34429 0.20150E-05 0.21248£-05 -5.17 -0.00240 -0.317
65 0.20 177 .145 0.34558 0.24000E-05 0.23653E-05 1.47 0.00188 0.091
65 0.20 178.136 0.34751 0.27330E-05 0.27734E-05 -1.46 0.00088 -0.091
65 0.20 179.077 0.34935 0.32400E-05 0.32204E-05 0.61 0.00267 0.039
65 0.20 180.278 0.35169 0.41060E-05 0.38875E-05 5.62 0.00619 0.361
70 1.00 288.049 0.56194 0.98150E-01 0.98303E-Ol -0.16 0.02468 -0.028
70 1.00 292.386 0.57040 0.12468E+00 0.12487E+00 -0.15 0.02451 -0.028
70 1.00 296.473 0.57837 0.15519E+00 0.15534E+00 -0.09 0.02436 -0.018
70 1.00 300.233 0.58571 0.188581.3+00 0.18879E+00 -0.11 0.02415 -0.022
70 1.00 303.061 0.59122 0.21769E+00 0.21784E+00 -0.07 0.02400 -0.014
70 1.00 306.035 0.59702 O.25206E+00 0.25243E+00 -0.15 0.02377 -0.030
70 1.00 309.008 0.60282 a.l9128E+00 0.29158E+Oa -0.10 0.02359 -0.021
70 1.00 313.787 0.61215 0.36493E+00 0.36529E+00 -0.10 0.02323 -0.021
70 1.00 318.557 0.62145 0.45347E+00 0.45401E+00 -0.12 0.02282 -0.027
70 1.00 322.026 0.62822 0.52884E+00 0.52941E+00 -0.11 0.02253 -0.024
70 1.00 326.465 0.63688 0.64036E+OO 0.64101E+00 -0.10 0.02212 -0.024
70 1.00 329.578 0.64295 0.72975E+00 0.73053E+00 -0.11 0.02182 -0.026
70 1.00 333.964 0.65151 0.87345E+00 0.87422E+00 -0.09 0.02139 -0.022
70 1.00 336.934 0.65730 0.98330E+00 0.98434E+00 -0.11 0.02101 -0.027
70 1.00 337.867 0.65912 o . 10200E+0 1 O. 10212E+Ol -0.12 0.02096 -0.031
70 1.00 341.553 0.66631 o. 11711E+01 0.11784E+01 -0.11 0.02057 -0.028
70 1.00 344.920 0.67288 o . 13374E+Ol O. 13 390E+Ol -0.12 0.02019 -0.032
70 1.00 348.833 0.68052 o . 15464E+0 1 0.15480E+01 -0.10 0.01975 -0.028
70 1.00 352.776 0.68821 0.17831E+Ol 0.17851E+Ol -0.12 0.01929 -0.032
70 1.00 356.828 0.69611 0.20565E+01 0.20592E+01 -0.13 0.01879 -0.037
71 5.00 288.000 0.56184 0.98030E-01 0.98033E-01 -0.00 0.02476 -0.001
71 5.00 293.000 0.57160 o . 12909E+00 0.12909E+00 0.00 0.02457 0.000
71 5.00 298.000 0.58135 0.16826E+00 0.16825E+00 0.00 0.02434 0.001
71 5.00 303.000 0.59110 0.21719E+00 0.21718E+00 0.01 0.02405 0.001
71 5.00 308.000 0.60086 0.27779E+00 0.27717E+00 0.01 0.02372 0.002
71 5.00 313.000 0.61061 0.35221E+00 0.352]6E+00 0.01 0.02335 0.003
71 5.00 318.000 0.62037 0.44286E+00 0.44280E+00 .0.01 0.02295 0.003
71 5.00 323.000 0.63012 0.55246E+00 0.55238E+00 0.01 0.02251 0.003
71 5.00 328.000 0.63988 0.68403E+00 0.68393E+OO 0.02 0.02204 0.004
71 5.00 333.000 0.64963 0.84090E+00 0.84077E+00 0.02 0.02155 0.004
71 :>.UU JJIL UUU U.6=>938 U.1U267E+UI U.lU266h+U1 U.Ol U.U2102 0.003
74 1.00 306.130 0.59721 0.25333E+00 0.25361E+00 -0.11 0.02378 -0.023
74 1.00 321.050 0.62632 0.50667E+00 0.50720E+00 -0.10 0.02262 -0.024
74 1.00 330.560 0.64487 0.76002E+00 0.76085E+00 -0.11 0.02172 -0.026
74 1.00 337.610 0.65862 0.10098E+Ol o . 1011 OE+O 1 -0.11 0.02099 -0.029
75 1.00 353.460 0.68954 0.18300E+Ol 0.18292E+01 0.05 0.01930 0.013
75 1.00 362.960 0.70808 0.25443E+Ol 0.25387E+Ol 0.22 0.01824 0.066
75 1.00 373.660 0.72895 0.35957E+01 0.35919E+Ol 0.11 0.01682 0.033
75 1.00 383.280 0.74772 0.48181E+Ol o .48179E+Ol 0.00 0.01551 0.001
75 1.00 392.860 0.76641 0.63S11E+Ol 0.63531E+Ol -0.03 0.01421 -0.011
75 1.00 403.380 0.78693 0.84676E+Ol 0.84656E+Ol 0.02 0.01282 0.009
75 1.00 413.110 0.80591 0.10879E+02 o.10883E+02 -0.04 0.01146 -0.016

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 803

Table 3. Comparison of reported vapor pressures with values calculated from Eq. (1) -
Continued

ID Wt. T T1Tc P Calc. P % Resid. <1T

K bar bar Dev.
75 1.00 423.190 0.82558 0.13934E+02 0.13933E+02 0.01 0.01012 0.004
75 1.00 432.920 0.84456 0.17478E+02 0.17476E+02 0.01 0.00881 0.004
75 1.00 443.040 0.86430 0.21897E+02 0.21874E+02 0.11 0.00753 0.049
75 1.00 453.270 0.88426 0.27187E+02 0.27152E+02 0.13 0.00621 0.062
75 1.00 462.900 0.90304 0.33108E+02 0.32983E+02 0.38 0.00515 0.192
99 1.00 488.137 0.95228 0.52857E+02 0.53000E+02 -0.27 0.00190 -0.151
99 1.00 493.175 0.96210 0.57916E+02 0.57961E+02 -0.08 0.00150 -0.044
99 1.00 498.178 0.97187 0.63180E+02 0.63258E+02 -0.12 0.00101 -0.071
99 1.00 503.133 0.98153 0.68912E+02 0.68900E+02 0.02 0.00066 0.010
99 1.00 503.202 0.98167 0.68962E+02 0.68981E+02 -0.03 0.00063 -0.016
99 1.00 508.130 0.99128 0.75135E+02 0.75029E+02 0.14 0.00035 0.083
99 1.00 508.148 0.99131 0.75128E+02 0.75052E+02 0.10 0.00033 0.059

10 0.00 263.150 0.51336 0.20665E-01 0.20999E-01 -1.59 0.02389 -0.232

10 0.00 273.150 0.53287 0.39463E-01 0.40521E-01 -2.61 0.02349 -0.414
10 0.00 283.150 0.55238 0.72927E-01 0.74295E-01 -1.84 0.02384 -0.316
10 0.00 293.150 0.57189 0.12799E+00 0.13014E+00 -1.65 0.02362 -0.306
10 0.00 303.150 0.59140 0.21332E+00 0.21882E+00 -2.51 0.02259 -0.502
10 0.00 313.150 0.61091 0.34730E+00 0.35463E+00 -2.07 0.02215 -0.444
10 0.00 323.150 0.63041 0.54129E+00 0.55599E+00 -2.64 0.02097 -0.609
10 0.00 333.1~0 0.64992 0.53326E+00 0.lS4~91E+00 -1.49 0.02067 -0.365
10 0.00 353.150 0.68894 0.17879E+Ol 0.18091E+Ol -1.17 0.01864 -0.330
10 0.00 363.150 0.70845 0.25291E+Ol 0.25549E+Ol -1.01 0.01752 -0.302
10 0.00 373.150 0.72796 0.34944E+Ol 0.35348E+Ol -1.14 0.01617 -0.363
10 0.00 383.150 0.74746 0.47476E+01 0.47993E+Ol -1.0S 0.01491 -0.363
10 0.00 393.150 0.76697 0.63341E+Ol 0.64051E+Ol -1.11 0.01355 -0.395
10 0.00 403.150 0.78648 0.83220E+01 0.84141E+Ol -1.10 0.01221 -0.413
10 0.00 413.150 0.80599 0.10760E+02 0.10894E+02 -1.23 0.01078 -0.489
10 0.00 423.150 0.82550 0.13780E+02 0.13919E+02 -1.00 0.00955 -0.418
10 0.00 433.150 0.84501 0.17368E+02 0.17568E+02 -1.14 0.00813 -0.502
10 0.00 443.150 0.86451 0.21721E+02 0.21926E+02 -0.94 0.00692 -0.432
10 0.00 453.150 0.88402 0.26783E+02 0.27085E+02 -1.12 0.00552 -0.540
10 0.00 463.150 0.90353 0.32817E+02 0.33146E+02 -0.99 0.00434 -0.502
10 0.00 473.150 0.92304 0.39713E+02 0.40220E+02 -1.26 0.00299 -0.666
10 0.00 483.150· 0.94255 0.47689E+02 0.48433E+02 -1.54 0.00170 -0.843
10 0.00 493.150 0.96206 0.56759E+02 0.57935E+02 -2.03 0.00038 -1.152
10 0.00 498.150 0.97181 0.61724E+02 0.63227E+02 -2.38 -0.00029 -1.370
10 0.00 503.150 0.98156 0.67213E+02 0.68920E+02 -2.48 -0.00078 -1.445
10 0.00 505.150 0.98547 0.69597E+02 0.71318E+02 -2.41 -0.00090 -1.414
10 0.00 507.150 0.98937 0.71913E+02 0.73790E+02 -2.54 -0.00112 -1.495
10 0.00 509.150 0.99327 0.74159E+02 0.76340E+02 -2.86 -0.00144 -1.683
10 0.00 510.150 0.99522 0.75987E+02 0.77647E+02 -2.14 -0.00109 -1.260
10 0.00 511.150 0.99717 0.76762E+02 0.78975E+02 -2.80 -0.00154 -1.651
10 0.00 511.650 0.99815 0.77766E+02 0.79649E+02 -2.36 -0.00131 -1. 392
10 0.00 512.150 0.99912 0.78315E+02 0.80328E+02 -2.51 -0.00142 -1.474
13 0.00 205.750 0.40139 0.13600E-03 0.12147E-03 11.96 0.02164 1.021
13 0.00 206.850 0.40353 0.14670E-03 0.13808E-03 6.25 0.01904 0.539
13 0.00 210.650 0.41094 0.221-30E-03 0.21261E-03 4.09 0.01910 0.367
13 0.00 212.750 0.41504 0.28260E-03 0.26796E-03 5.46 0.02048 0.501
13 0.00 216.150 0.42167 0.39330E-03 0.38574E-03 1.96 0.01951 0.186
13 0.00 218.650 0.42655 0.50530E-03 0.50031E-03 1.00 0.01962 0.097
13 0.00 221.250 0.43162 0.65460E-03 0.65127E-03 0.51 0.01997 0.051
13 0.00 225.050 0.43904 0.93590E-03 0.94617E-03 -1.09 0.01990 -0.113
13 0.00 226.650 0.44216 0.10930E-02 0.1102SE-02 -0.89 0.02033 -0.094
13 0.00 228.750 0.44625 0.13150E-02 0.13437E-02 -2.13 0.02002 -0.229
51 0.00 313.100 0.61081 0.34664E+00 0.35381E+00 -2.03 0.02218 -0.435
51 0.00 327.900 0.63968 0.66661E+00 0.68106E+00 -2.12 0.02082 -0.505
51 0.00 337.800 0.65899 0.10066E+Ol 0_ 101 R:<iF.+01 -1 _17 0.01037 -0.299
67 0.00 362.850 0.70786 0.25230E+Ol 0.25294E+Ol -0.25 0.01799 -0.075
67 0.00 368.750 0.71937 0.30499E+Ol 0.30717E+Ol -0.71 0.01698 -0.220
67 0.00 373.650 0.72893 0.35565E+Ol 0.35908E+Ol -0.95 0.01622 -0.304
67 0.00 388.350 0.75761 0.55222E+Ol 0.55880E+Ol -1.18 0.01416 -0.408
67 0.00 391.350 0.76346 0.60086E+Ol 0.60882E+01 -1.31 0.01368 -0.461
67 0.00 412.250 0.80423 O. 10426E+02 O. 10650E+02 -2.10 0.01039 -0.831
67 0.00 414.050 0.80774 0.10913E+02 0.11143E+02 -2.07 0.01017 -0.826
67 0.00 426.850 0.83272 0.14824E+02 0.15192E+02 -2.42 0.00823 -1.035
67 0.00 444.350 0.86686 0.22180E+02 0.22501E+02 -1.43 0.00648 -0.663
67 0.00 449.350 0.87661 0.24632E+02 0.25024E+02 -1.57 0.00575 -0.746
67 0.00 453.850 0.88539 0.27064E+02 0.27479E+02 -1.51 0.00520 -0.734
67 0.00 458.050 0.89358 0.29516E+02 0.29936E+02 -1.40 0.00473 -0.694

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

804 ROBERT D. GOODWIN

Table 3. Comparison of reported vapor pressures with values calculated from Eq. (1) -
Continued

ID Wt. T T1Tc P Calc. P % Resid. LlT

K bar bar Dev.
67 0.00 462.050 0.90139 0.31968E+02 0.32432E+02 -1.43 0.00422 -0.721
67 0.00 465.850 0.90880 0.34430E+02 0.34952E+02 -1.49 0.00372 -0.764
67 0.00 469.250 0.91543 0.36882E+02 0.37333E+02 -1. 21 0.00348 -0.628
67 0.00 472.650 0.92206 0.39355E+02 0.39841E+02 -1.22 0.00307 -0.643
73 0.00 175.400 0.34218 0.18870E-05 0.17788E-05 6.08 0.00322 0.368
73 0.00 180.000 0.35115 0.39090E-05 0.37226E-05 5.01 0.00568 0.321
73 0.00 190.000 0.37066 o . 16930E-04 o . 16255E-04 4.15 0.01087 0.299
73 0.00 200.000 0.39017 0.62740E-04 0.60635E-04 3.47 0.01500 0.279
73 0.00 210.000 0.40968 0.20350E-03 O. 19771E-03 2.93 0.01826 0.261
73 0.00 220.000 0.42918 0.58810E-03 0.57421E-03 2.42 0.02074 0.239
73 0.00 230.000 0.44869 0.15390E-02 0.15085E-02 2.02 0.02261 0.220
73 0.00 240.000 0.46820 0.36870E-02 0.36312E-02 1.54 0.02386 0.183
73 0.00 250.000 0.48771 0.81890E-02 0.80965E-02 1.14 0.02469 0.149
73 0.00 260.000 0.50722 o. 17000E-01 0.16875E-01 0.74 0.02509 0.105
73 0.00 270.000 0.52673 0.33270E-01 0.33134E-01 0.41 0.02519 0.063
73 0.00 280.000 0.54623 0.62080E-01 0.61698E-01 0.62 0.02530 0.104
73 0.00 290.000 0.56574 O. 10940E+00 O. 10958E+00 -0.16 0.02460 -0.030
73 0.00 300.000 0.58525 0.18600E+00 0.18655E+00 -0.30 0.02406 -0.058
73 0.00 310.000 0.60476 0.30430E+00 0.30574E+00 -0.47 0.02330 -0.099
73 0.00 320.000 0.62427 0.48170E+00 0.48419E+00 -0.51 0.02248 -0.116
73 0.00 330.000 0.64378 0.73950E+00 0.74343E+00 -0.53 0.02154 -0.128
73 0.00 340.000 0.66329 0.11044E+01 0.11099E+01 -0.49 0.02052 -0.128
73 0.00 350.000 0.68279 o . 16082E+01 o. 16153E+01 ,..0.44 0.01943 -0.121
73 0.00 360.000 0.70230 0.22880E+Ol 0.22970E+01 -0.39 0.01826 -0.114
7J 0.00 :~70.000 O.7?lRl 0.31880E+01 o 31979E+01 -0~31 0.01705 -0.097
73 0.00 380.000 0.74132 0.43570E+Ol 0.43670E+Ol -0.23 0.01581 -0.076
73 0.00 390.000 0.76083 0.58450E+01 0.58588E+01 -0.24 0.01448 -0.083
73 0.00 400.000 0.78034 0.77030E+01 0.77338E+01 -0.40 0.01304 -0.147
73 0.00 410.000 0.79984 o. 10000E+02 0.10058E+02 -0.58 0.01158 -0.225
73 0.00 420.000 0.81935 o. 12830E+02 0.12903E+02 -0.57 0.01023 -0.233
73 0.00 430.000 0.83886 0.16260E+02 0.16346E+02 -0.53 0.00890 -0.229
73 0.00 440.000 0.85837 0.20400E+02 0.20471E+02 -0.35 0.00767 -0.158
73 0.00 450.000 0.87788 0.25300E+02 0.25368E+02 -0.27 0.00641 -0.127
73 0.00 460.000 0.89739 0.31080E+02 0.31133E+02 -0.17 0.00520 -0.085
73 0.00 470.000 0.91689 0.37800E+02 0.37875E+02 -0.20 0.00396 -0.104
73 0.00 480.000 0.93640 0.45610E+02 0.45715E+02 -0.23 0.00280 -0.124
73 0.00 490.000 0.95591 0.54660E+02 0.54793E+02 -0.24 0.00172 -0.136
73 0.00 500.000 0.97542 0.65170E+02 0.65285E+02 -0.18 0.00081 -0.102
73 0.00 510.000 0.99493 0.77430E+02 0.77449E+02 -0.02 0.00013 -0.015
83 0.00 298.150 0.58164 0.16900E+00 0.16957E+00 -0.34 0.02413 -0.065
83 0.00 313.150 0.61091 0.35300E+00 0.35463E+00 -0.46 0.02307 -0.099
83 0.00 323.150 0.63041 0.55300E+00 0.55599E+00 -0.54 0.02218 -0.124
83 0.00 333.150 0.64992 0.84100E+00 0.84591E+00 -0.58 0.02119 -0.143
83 0.00 343.150 0.66943 0.12460E+01 0.12525E+Ol -0.52 0.02016 -0.136
83 0.00 353.150 0.68894 0.18010E+Ol 0.18091E+01 -0.45 0.01905 -0.126
83 0.00 363.150 0.70845 0.25460E+01 0.25549E+Ol -0.35 0.01789 -0.104
83 0.00 373.150 0.72796 0.35240E+01 0.35348E+Ol -0.30 0.01665 -0.097
83 0.00 383.150 0.74746 0.47900E+Ol 0.47993E+01 -0.19 0.01541 -0.066
83 0.00 393.150 0.76697 0.63870E+01 0.64051E+Ol -0.28 0.01403 -0.101
83 0.00 403.150 0.78648 0.83760E+01 0.84141E+01 -0.45 0.01258 -0.171
83 0.00 413.150 0.80599 0.10834E+02 O. 10894E+02 -0.55 0.01116 -0.220
83 0.00 423.150 0.82550 0.13843E+02 0.13919E+02 -0.55 0.00981 -0.229
83 0.00 433 150 0.84501 0.17490E+0:2 0.17568E+0:2 -0.44 0.00852 -0.196
83 0.00 443.150 0.86451 0.21855E+02 0.21926E+02 -0.32 0.00727 -0.150
83 0.00 453.150 0.88402 0.27024E+02 0.27085E+02 -0.23 0.00603 -0.109
83 0.00 463.150 0.90353 0.33083E+02 0.33146E+02 -0.19 0.00480 -0.097
83 0.00 473.150 0.92304 0.40137E+02 0.40220E+02 -0.21 0.00359 -0.109

83 data points, rms deviation 0.339%.

ID code: (10) Young, (13) Mundell, (51) Weltner, (55) Kay, (64) Skaates, (65) Miller,
(67) Hirata, (70) Ambrose I Sprake, (71) Gibbard, (73) Zubarev, (74) Counsell.
(75) Ambrose I Sprake I Townsend. (83) Machado. (99) Straty.

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 805

TABLE 4. Summary of orthobaric density data for methanol (1). AtID = 69, data are from virial Eqs. (4) and (1). At
ID = 72, data are from formulations of our derived iso-
ID Author/year Range ofT, K
chores of Zubarev (Table 9, ID = 90), and Eq. (1). At
87 Ramsay, 1887 (Ref. 53) 263-512 ID = 99 we used individual representations of the Straty63
10 Young, 1910 (Ref. 70) 263-512 pseudoisochores, with Eq. (1). Many deviations in Table 6
55 Kay, 1955 (Ref. 32) 403-503 are unacceptably large (see Fig. 2). Derived heats of vapori-
72 Via Zubarev, 1985 423-512
73 Zubarev, 1973 (Ref. 74) 175-510 zation depend directly on these vapor densities via Eq. (17).
83 Machado, 1983 (Ref. 42) 298-473 In the last column of Table 6 under F(z) are given experi-
85 Via MachadolTait, 1985 298-489 mental values of (Zg - I )/(Zc - 1). In the limit of low
90 Via Cu (n data, 1985 176-325 densities, one obtains from Eqs. ( 1 ) and (3),
99 Via Straty, 1985 376-511
Zu .-exp( - O.13Tc/Tu), i.e., Zu -0 in this limit,
Tu(p)-O.

isochores, obtained in turn from formulations of the Zu-

barev74 isotherms. Data at ID = 85 are obtained from Tait Table 5. Comparison of reported saturated liquid densities with values
equation formulations of the isotherms of Machado and calculated from Eq. (2)
Streett. 42 ID Wt. T Calc. p % dp/dT
K molll mol/l Dev. (molll)/K
2.2.b. Saturated Vapor Densities
73 1.00 180.000 0.35115 28.091 28.083 0.03 -0.0323
The computation of M along isotherms via Eq. (9), 73 1.00 190.000 0.37066 27.766 27.763 0.01 -0.0316
731.00200.0000.3901727.44827.450 -0.01 -0.0310
using EOS Eq. (6), involves a leading term for the saturated 73 1.00 210.000 0.40968 27.138 27.143 -0.02 -0.0305
vapor at Tu (p) for each density along the isotherm, Good- 73 1.00 220.000 0.42918 26.835 26.840 -0.02 -0.0301
73 1.00 230.000 0.44869 26.538 26.541 -0.01 -0.0297
win,24 73 1.00 240.000 0.46820 26.248 26.245 0.01 -0.0294
73 1.00 250.000 0.48771 25.942 25.952 -'0.04 -0.0292
0.01 -0.0291
1lE= (P {RTu(p) [Zu(p) - 1] + ... } dp
, (2a) 73 1.00 260.000 0.50722 25.665 25.661
73 1.00 270.000 0.52673 25.373 25.371 0.01 -0.0290
Jo p 73 1.00 280.000 0.54623 25.087 25.080 0.03 -0.0291
73 1.00 290.000 0.56574 24.788 24.789 -0.00 -0.0292
where it is important that the integrand approach zero in the 73 1.00 300.·000 0.58525 24.497 24.495 0.01 -0.0295
limit of low densities. Our earlier formulation of the satu- 731.00310.0000.6047624.19324.199 -0.02 -0.0299
73 1.00 320.000 0.62427 23.896 23.898 -0.01 -0.0303
rated vapor densities Pg' has been used for various simple 83 1.00 298.150 0.58164 24.552 24.550 0.01 -0.0294
fluids, e.g., Goodwin,26 but is not suitable for methanol. 83 1.00 313.150 0.61091 24.105 24.104 0.00 -0.0300
831.00323.1500.6304123.80223.802 0.00 -0.0305
Hence we have used Eq. (3), where x(T)=T/Tc , 83 1.00 333.150 0.64992 23.492 23.493 -0.01 -0.0312
u(T) (l-x),/3=O.35, 83 1.00 343.150 0.66943 23.178 23.178 0.00 -0.0320
831.00 353.150 0.6889422.85322.853 -0.00 -0.0329
tl3 1.00363.1'0 0.70tl4' 22.'22 22.:H8 0.02 -0.0341
83 1.00 373.150 0.72796 22.179 22.171 0.04 -0.0354
83 1.00 383.150 0.74746 21.821 21.809 0.05 -0.0370
and 83 1.00 393.150 0.76697 21.448 21.430 0.08 -0.0389
83 1.00 403.150 0.78648 21.053 21.031 0.11 -0.0411
a 10.61966850, c 3.81845421, 8. 3 1 . 00 A 1 ~ . 1 50 °.R0599 10.635 ,0.£.0& O.D -0.04'l1>
83 1.00 423.150 0.82550 20.188 20.156 0.16 -0.0467
b= - 2.556 682 02, d= 4.79556752. 83 1.00 433.150 0.84501 19.70619.670 0.18 -0.0505
83 1.00 443.150 0.86451 19.179 19.143 0.19 -0.0552
For 53 selected data in Table 6 the rms of relative deviations 83 1. 00 453.150 0.88402 18 .599 18.563 0.19 -0.0610
is 0.21%. 83 1. 00 463.150 0.90353 17.94517.916 0.16 -0.0688
83 1.00 473.150 0.92304 17.199 17.177 0.13 -0.0796
Above the first blank line in Table 6, we derived the 99 5.00 375.748 0.73302 22.062 22.079 -0.08 -0.0358
vapor density data from experimental heats of vaporization 99 5.00 424.224 0.82759 20.120 20.106 0.07 -0.0471
99 5.00 442.521 0.86329 19.206 19 . 178 0.15 -0.0548
ofthe named authors (ID) via the Clapeyron Eq. (17) using 99 5.00 448.744 0.87543 18.827 18.826 0.01 -0.0583
99 5.00 414.525 0.92572 17.025 17.061 0.24 0.0814
Eq. (1). Thus our derived heats of vaporization in Table 16 99 5.00 484.996 0.94615 16.11616.125 -0.05 -0.1001
will have the same accuracy (with respect to experimental 99 5.00 496.354 0.96831 14.76514.792 -0.19 -0.1403
99 5.00 504.367 0.98394 13.420 13.420 0.00 -0.2163
data) as the fit of the vapor density data in Table 6. However, 99 5.00 508.505 0.99201 12.386 12.320 0.53 -0.3382
at Tn = gO, nata are from fitting onr Hqnid entropies and
10 0.00 273.150 0.53287 25.279 25.279 -0.00 -0.0290
experimental CO' (T) data simultaneously [Sec. 3.3(c)]. 10 0.00 283.150 0.55238 24.992 24.989 0.01 -0.0291
Given the formulated liquid entropies, SO' ( T) / 10 0.00 293.150 0.57189 24.702 24.697 0.02 -0.0293
10 0.00 303.150 0.59140 24.421 24.402 0.08 -0.0296
J mol-' 1 K -1, then the vapor densities in mollL are 10 0.00 313.150 0.61091 24.155 24.104 0.21 -0.0300
10 0.00 323.150 0.03041 23.875 23.&02 0.31 -0.0305
100.00333.1500.6499223.57823.493 0.36 -0.0312
pg(T) = 100 ('::';)/[Sg(T) -SO'(T)], (3a) 100.00343.1500.6694323.28223.178 0.45 -0.0320
10 0.00 353.150 0.68894 22.954 22.853 0.44 -0.0329
10 0.00 363.150 0.70845 22.626 22.518 0.48 -0.0341
where for the vapor at these low densities we have approxi- 10 000 373 150 0.72796 12.'283 22 171 0.50 -0.0354
mated 10 0.00 383.150 0.74746 21.908 21.809 0.46 -0.0370
10 0.00 393.150 0.76697 21.534 21.430 0.48 -0.0389
Sg (T) = S' (T) + R In[P" /Pcr (T)]. (3b) 10 0.00 403.150 0.78648 21.128 21.031
10 0.00 413.150 0.80599 20.723 20.608
0.46
0.56
-0.0411
-0.0436
At Tn = ,:\g in TAhle h the vapor den~1t1es are ohtainen 100.00423.1500.8255020.27020.156 0.56 -0.0467
10 0.00 433.150 0.84501 19.786 19.670 0.59 -0.0505
from the Beattie-Bridgman EOS of Lashakov39 with Eq. 100.00 443.1500.86451 19.22519.143 0.43 -0.0552

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

806 ROBERT D. GOODWIN

Table 5. Comparison of reported saturated liquid densities with values

calculated from Eq. (2) - Continued

ID Wt. T TITc Calc. P % dplldT

K mol/l mol/l Dev. (mol/l)/K

10 0.00 453.150 0.88402 18.663 18.563 0.54 -0.0610

10 0.00 463.150 0.90353 18.007 17.916 0.51 -0.0688
10 0.00 473 .150 0.92304 17.258 17.177 0.47 -0.0796
10 0.00 483.150 0.94255 16.400 16.306 0.58 -0.0960
10 0.00 493.150 0.96206 15.292 15.216 0.50 -0.1251
10 0.00 498.150 0.97181 14.590 14.531 0.41 -0.1511
10 0.00 503.150 0.98156 13.763 13.672 0.67 -0.1981
10 0.00 505.150 0.98547 13.404 13.245 1.20 -0.2306
10 0.00 507.150 0.98937 12.936 12.737 1.56 -0.2816
10 0.00 509.150 0.99327 12.343 12.090 2.09 -0.3775
10 0.00 510.150 0.99522 12.015 11.671 2.95 -0.4704
10 0.00 511. 150 0.99717 11.563 11.119 3.99 -0.6596
10 0.00 511.650 0.99815 11.344 10.744 5.59 -0.8667
55 0.00 403.162 0.78650 20.966 21.030 -0.31 -·0.0411
55 0.00 413.166 0.80602 20.517 20.607 -0.44 -0.0437
55 0.00 423.170 0.82554 20.036 20.155 -0.59 -0.0468
55 0.00 433.175 0.84505 19.530 19.669 -0.71 -0.0505
55 0.00 443.179 0.86457 18.978 19.141 -0.85 -0.0552
55 0.00 453.184 0.88409 18.38:5 18.:561 -0.9~ -0.0611
55 0.00 463.188 0.90361 17.730 17.913 -1.02 -0.0688
55 0.00 473.193 0.92312 17.002 17.174 -1.00 -0.0797
55 0.00 483.197 0.94264 16.135 16.301 -1.02 -0.0961
55 0.00 493.201 0.96216 15.014 15.210 -1.29 -0.1253
55 0.00 50.'1. ?04 0.98167 13.485 13.661 -1.29 -0.1988
72 0.00 494.178 0.96406 15.000 15.086 -0.57 -0.1295
72 0.00 501.279 0.97791 14.000 14.021 -0.15 -0.1765
72 0.00 506.223 0.98756 13.000 12.985 0.11 -0.2546
72 0.00 509.029 0.99303 12.000 12.135 -1.12 -0.3692
72 0.00 510.633 0.99616 11.000 11.427 -3.74 -0.5418
72 0.00 512.001 0.99883 10.000 10.393 -3.78 -1.1679
73 0.00 330.000 0.64378 23.589 23.591 -0.01 -0.0310
73 0.00 340.000 0.66329 23.255 23.278 -0.10 -0.0317
73 0.00 350.000 0.68279 22.931 22.957 -0.11 -0.0326
73 0.00 360.000 0.70230 22.599 22.625 -0.12 -0.0337
73 0.00 370.000 0.72181 22.244 22.262 -0.17 -O.UJ:>U
73 0.00 380.000 0.74132 21. 885 21.925 -0.18 -0.0365
73 0.00 390.000 0.76083 21.494 21.552 -0.27 -0.0382
73 0.00 400.000 0.18034 21.081 21.159 -0.34 -0.0403
73 0.00 410.000 0.79984 20.668 20.744 -0.37 -0.0428
73 0.00 420.000 O. R193S 20.226 20.302 -0.37 -0.0-157
73 0.00 430.000 0.83886 19.740 19.828 -0.44 -0.0492
73 0.00 440.000 0.85837 19.217 19.314 -0.50 -0.0536
73 0.00 450.000 0.87788 18.643 18.752 -0.58 -0.0590
73 0.00 460.000 0.89739 18.008 18.128 -0.66 -0.0661
73 0.00 470.000 0.91689 17.281 17.422 -0.81 -0.0758
73 0.00 480.000 0.93640 16.460 16.598 -0.83 -0.0900
73 0.00 490.000 0.95591 15.442 15.592 -0.96 -0.1137
73 0.00 500.000 0.97542 14.096 14.239 -1.00 -0.1649
73 0.00 510.000 0.99493 11.602 11.740 -1.18 -0.4527
85 0.00 298.120 0.58158 24.547 24.551 -0.01 -0.0294
85 0.00 322.540 0.62922 23.82;5 23.820 0.02 -0.030.'5
85 0.00 342.830 0.66881 23.188 23.188 -0.00 -0.0319
85 0.00 362.900 0.70796 22.527 22.527 0.00 -0.0340
85 0.00 382.600 0.74639 21.847 21.830 0.08 -0.0369
85 0.00 402.340 0.78490 21.088 21.064 0.11 -0.0409
85 0.00 421.610 0.82249 20.26R 20.22R 0.20 -0.046'
85 0.00 441.900 0.86208 19.262 19.212 0.26 -0.0545
85 0.00 463.060 0.90336 17.980 17.922 0.32 -0.0687
85 0.00 478.620 0.93371 16.808 16.721 0.52 -0.0876
85 0.00 488.860 0.95369 15.807 15.719 0.56 -0.1102
99 0.00 510.898 0.99668 11.078 11.277 -1. 76 -0.5948

43 data points, rms deviation 0.1700/0

ID rode: (10) Young, (55) Kay, (72) ROO I Zubarev, (73) Zubarev,
(83) Machado, (85) Machado I v.p. I Tait. (99) Straty.

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 807

Table 6. Comparison of reported saturated vapor densities with values calculated from Eq. (3)

lD Wt. T TITc p Calc. p % dp/dT Z f(Z)

K molll molll Dev. (molll)/K (exp.)
31 2.00 313.100 0.61081 0.14034E-01 0.14074E-01 -0.29 0.6196E-03 0.96843 0.04080
31 2.00 327.900 0.63968 0.26105E-Ol 0.26153E-01 -0.19 0.1042E-02 0.95694 0.05564
31 2.00 337.800 0.65899 0.38281E-01 0.38320E-Ol -0.10 0.1433E-02 0.94732 0.06807
49 0.00 273.150 0.53287 0.18105E-02 0.18183E-02 -0.43 0.1084E-03 0.98548 0.01877
51 2.00 313.100 0.61081 0.14043E-01 0.14074E-01 -0.22 0.6196E-03 0.96780 0.04160
51 2.00 327.900 0.63968 0.26095E-01 0.26153E-01 -0.22 0.1042E-02 0.95730 0.05517
51 2.00 337.800 0.65899 0.38223E-Ol 0.38320E-01 -0.25 o. 1433E-02 0.94876 0.06621
74 2.00 306.130 0.59721 0.10256E-Ol 0.10276E-Ol -0.20 0.4753E-03 0.97151 0.03681
74 2.00 321.050 0.62632 o. 19786E-01 0.19784E-Ol 0.01 0.8247E-03 0.96031 0.05128
74 2.00 330.560 0.64487 0.29053E-01 0.29050E-01 0.01 0.1137E-02 0.95284 0.06094
74 2.00 337.610 0.65862 0.38052E-01 0.38049E-01 0.01 0.1424E-02 0.94646 0.06918
75 2.00 306.130 0.59721 0.10253E-01 0.10276E-01 -0.23 0.4753E-03 0.97179 0.03645
75 2.00 321.050 0.62632 0.19789E-Ol 0.19784E-01 0.02 0.8247E-03 0.96017 0.05147
75 2.00 330.560 0.64487 0.29068E-01 0.29050E-01 0.06 0.1137E-02 0.95235 0.06157
75 2.00 337.610 0.65862 0.38075E-Ol 0.38049E-01 0.07 0.1424E-02 0.94589 0.06992
76 2.00 298.150 0.58164 0.69920E-02 0.70273E-02 -0.50 0.3446E-03 0.97830 0.02803
76 2.00 313.150 0.61091 0.14041E-01 0.14105E-Ol -0.46 0.6207E-03 0.97004 0.03871
76 2.00 323.150 0.63041 0.21;506E-01 0.21581E-01 -0.3:5 O.8869E-03 0.96220 0.04884
76 2.00 333.150 0.64992 0.32039E-Ol 0.32123E-01 -0.26 0.1237E-02 0.95316 0.06052
76 2.00 337.850 0.65909 0.38287E-Ol 0.38392E-01 -0.27 0.1435E-02 0.94890 0.06603
76 2.00 343.150 0.66943 0.46661E-01 0.46653E-Ol 0.02 0.1688E-02 0.94078 0.07652
90 30.00 175.590 0.34255 0.12712E-06 0.12708E-06 0.03 0.2022E-07 0.98898 0.01424
90 30.00 200.000 0.39017 0.36926E-05 0.36949E-OS -0.06 0.4421E-06 0.98747 0.01619
90 30.00 225.000 0.43894 0.51049E-04 0.51057E-04 -0.02 0.4704E-05 0.98598 0.01811
90 30.00 250.000 0.48771 0.39591E-03 0.39564E-03 0.07 0.2879E-04 0.98383 0.02090
90 1.00 275.000 0.53648 0.20304E-02 0.20287E-02 0.08 0.1192E-03 0.98001 0.02582
90 LOO 300_000 0_585:25 0_768:29E-0:2 0_76899E-0:2 -0_09 0_3719E-03 0_9731\6 0_031\30
90 1.00 325.000 0.63402 0.23146E-01 0.23275E-Ol -0.55 0.9449E-03 0.96279 0.04808

69 1.00 300.000 0.58525 0.76300E-02 0.76899E-02 -0.78 0.3719E-03 0.98020 0.02558

69 1.00 305.000 0.59501 0.96800E-02 0.97510E-02 -0.73 0.4547E-03 0.97728 0.02936
69 1.00 310.000 0.60476 0.12180E-Ol 0.12261E-Ol -0.66 0.5516E-03 0.97387 0.03376
69 1.00 315.000 0.61451 0.15200E-Ol 0.15294E-Ol -0.61 0.6644E-03 0.97042 0.03822
69 1.00 320.000 0.62427 0.18830E-Ol 0.18934E-Ol -0.55 0.7948E-03 0.96645 0.04335
69 1.00 325.000 0.63402 0.23160E-Ol 0.23275E-Ol -0.49 0.9449E-03 0.96221 0.04883
69 1.00 330.000 0.64378 0.28300E-Ol 0.28419E-Ol -0.42 0.1117E-02 0.95742 0.05502
69 1.00 335.000 0.65353 0.34360E-Ol 0.34480E-Ol -0.35 0.1312E-02 0.95230 0.06163
69 1.00 340.000 0.66329 0.41460E-01 0.41582E-01 -0.29 0.1534E-02 0.94697 0.06853
69 1.00 345.000 0.67304 0.49750E-01 0.49864E-01 -0.23 0.1784E-02 0.94110 0.07610
69 1.00 350.000 0.68279 0.59360E-Ol 0.59476E-Ol -0.19 0.2066E-02 0.93509 0.08387
69 1.00 355.000 0.69255 0.70470E-Ol 0.70581E-Ol -0.16 0.2382E-02 0.92862 0.09224
69 1.00 360.000 0.70230 0.83240E-Ol 0.83360E-Ol -0.14 0.2736E-02 0.92190 0.10092
69 1.00 365.000 0.71206 0.97870E-Ol 0.98009E-Ol -0.14 0.3131E-02 0.91481 0.11008
69 1.00 370.000 0.72181 0.11456E+00 0.11474E+00 -0.16 0.3571E:.02 0.90739 0.11966
69 1.00 375.000 0.73156 o . 13353E+00 0.13380E+00 -0.20 0.4060E-02 0.89967 0.12965
69 1.00 380.000 0.74132 0.lSS03E+00 0.lSS43E+00 -0.26 0.460313-02 0.89155 0.14013
69 1.00 385.000 0.75107 O. 17932E+00 O. 17993E+00 -0.34 0.5205E-02 0.88306 0.15111
69 1.00 390.000 0.76083 0.20669E+'00 0.20759E+00 -0.43 0.5873E-02 0.87416 0.16261
69 1.00 395.000 0.77058 0.23746E+00 0.23877E+00 -0.55 0.6612E-02 0.86481 0.17469
99 2.00 481.345 0.93903 0.20614E+01 0.20727E+Ol -0.55 0.5319E-01 0.56800 0.55821
99 2.00 482.074 0.94045 0.21125E+01 0.21120E+Ol 0.03 0.544SE-Ol 0.56087 0.56743
99 2.00 490.940 0.95774 0.26911E+01 0.26774E+Ol 0.51 0.7496E-01 0.50720 0.63677
99 2.00 497.198 0.96995 0.32335E+Ol 0.32175E+Ol 0.50 0.9989E-01 0.46525 0.69099
99 2.00 502.738 0.98076 0.38896E+Ol 0.38718E+Ol 0.46 0.1413E+00 0.42091 0.74827
99 2.00 506.925 0.98893 0.45858E+Ol 0.45887E+Ol -0.06 0.2117E+00 0.38031 0.80074

10 0.00 273.150 0.53287 0.17539E-02 0.18183E-02 -3.54 0.1084E-03 1.01726 -0.02231

10 0.00 283.150 0.55238 0.31084E-02 0.32243E-02 -3.59 0.1774E-03 1.01525 -0.01970
10 0.00 293.150 0.57189 0.52899E-02 0.54738E-02 -3.36 0.2787E-03 1.00933 -0.01206
10 0.00 303.150 0.59140 0.8651013-02 0.8939813-02 -3.23 0.422513-03 1.00350 -0.00453
10 0.00 313.150 0.61091 0.13713E-Ol 0.1410SE-Ol -2.78 0.6207E-03 0.99324 0.00873
10 0.00 323.150 0.63041 0.21032E-01 0.21581E-Ol -2.55 0.8869E-03 0.98391 0.02079
10 0.00 333.150 0.64992 0.31396E-Ol 0.32123E-Ol -2.26 0.1237E-02 0.97269 0.03529
10 0.00 343.150 0.66943 0.45721E-Ol 0.46653E-Ol -2.00 0.1688E-02 0.96013 0.05152
10 0.00 353.150 0.68894 0.65039E-Ol 0.66287E-Ol -1. 88 0.2261E-02 0.94731 0.06808
10 0.00 363.150 0.70845 0.90124E-Ol 0.92358E-Ol -1.77 0.2980E-02 0.93268 0.08699
10 0.00 373.150 0.72796 0.12434E+OO 0.12646E+00 -1.68 0.3873E-02 0.91632 0.10813
10 0.00 383.150 0.74746 o. 16778E+00 O. 17051E+00 -1.60 0.497SE-02 0.89793 0.13189

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

808 ROBERT D. GOODWIN

Table 6. Comparison of reported saturated vapor densities with values calculated from Eq. (3) - Continued

ID Wt. T Calc. p % z Hz)

" T1Tc p dp/dT
(molll)/K (exp.)
K molll moll! Dev.
10 0.00 393.150 0.76697 0.22289E+00 0.22680E+00 -1.72 0.6330E-02 0.87909 0.15623
10 0.00 403.150 0.78648 0.29271E+00 0.29813E+00 -1.82 0.7993E-02 0.85758 0.18403
10 0.00 413.150 0.80599 0.37950E+00 0.38794E+00 -2.18 0.1004E-Ol 0.83570 0.21230
10 0.00 423.150 0.82550 0.48748E+00 0.50055E+00 -2.61 0.1257E-Ol 0.81158 0.24347
10 0.00 433.150 0.84501 0.62230E+00 0.64149E+00 -2.99 o. 1574E-Ol 0.78388 0.27927
10 0.00 443.150 0.86451 0.78833E+00 0.81808E+00 -3.64 0.1975E-01 0.75485 0.31677
10 0.00 453.150 0.88402 0.99431E+00 0.10403E+01 -4.42 0.2494E-01 0.72299 0.35794
10 0.00 463.150 0.90353 o . 12 515E+0 1 0.13226E+Ol -5.38 0.3188E-01 0.68779 0.40342
10 0.00 473.150 0.92304 0.15838E+Ol o . 16872E+01 -6.13 0.4163E-Ol 0.64550 0.45806
10 0.00 483.150 0.94255 0.20351E+01 0.21716E+01 -6.28 0.5641E-01 0.59243 0.52665
10 0.00 493.150 0.96206 0.26949E+01 0.28509E+Ol -5.47 0.8229E-Ol 0.52431 0.61466
10 0.00 498.150 0.97181 0.31302E+01 0.33150E+Ol -5.57 0.1051E+00 0.48768 0.66200
10 0.00 503.150 0.98156 0.37045E+01 0.39310E+01 -5.76 0.1459E+00 0.44472 0.71751
10 0.00 505.150 0.98547 0.39853E+Ol 0.42490E+Ol -6.20 0.1739E+00 0.42606 0.74162
10 0.00 507.150 0.98937 0.43099E+01 0.46370E+01 -7.05 0.2179E+00 0.40603 0.76751
10 0.00 509.150 0.99327 0.46969E+01 0.51453E+01 -8.71 0.3009E+00 0.38394 0.79605
10 0.00 511 .150 0.99717 0.52462E+Ol 0.59361E+Ol -11. 62 0.5490E+00 0.35421 0.83446
10 0.00 511.650 0.99815 0.55832E+Ol 0.62515E+Ol -10.69 0.7345E+00 0.33534 0.85885
10 0.00 512.150 0.99912 0.58610E+Ol 0.67164E+Ol -12.74 0.1227E+01 0.32186 0.87627
20 0.00 273.150 0.53287 0.17808E-02 0.18183E-02 -2.06 0.1084E-03 1.00191 -0.00246
20 0.00 283.150 0.55238 0.31839E-02 0.32243E-02 -1.25 0.1774E-03 0.99116 0.01142
20 0.00 293.150 0.57189 0.54248E-02 0.54738E-02 -0.90 0.2787E-03 0.98423 0.02037
20 0.00 298.150 0.58164 0.69818E-02 0.70273E-02 -0.65 0.3446E-03 0.97973 0.02619
20 0.00 303.150 0.59140 0.88838E-02 0.89398E-02 -0.63 0.4225E-03 0.97722 0.02944
20 0.00 313.150 0.61091 0.14026E":01 0.14105E-01 -0.56 0.6207E-03 0.97106 0.03740
20 0.00 323.150 0.63041 0.21449E-Ol 0.21581E-Ol -0.61 0.8869E-03 0.96475 0.04555
20 0.00 333.1:50 0.6499.2 O ..H90IE-OI O.3:lllJc-Ul -U.69 U. Ll37h-U:Z U.9:>729 U.U':>19
20 0.00 337.850 0.65909 0.38148E-01 0.38392E-01 -0.64 0.1435E-02 0.95236 0.06155
20 0.00 343.150 0.66943 0.46476E-01 0.46653E-01 -0.38 0.1688E-02 0.94452 0.07169
20 0.00 353.150 0.68894 0.66022E-01 0.66287E-01 -0.40 0.2261E-02 0.93320 0.08631
20 0.00 363.150 0.70845 0.91952E-01 0.92358E-Ol -0.44 0.2980E-02 0.92022 0.10309
20 0.00 373.150 0.72796 0.12574E+00 O. 12646E+00 -0.57 0.3873E-02 0.90608 0.12135
20 0.00 383.150 0.74746 0.16943E+00 0.17051E+00 -0.63 0.4975E-02 0.88918 0.14319
20 0.00 393.150 0.76697 0.22452E+00 0.22680E+00 -1.01 0.6330E-02 0.87271 0.16448
20 0.00 403.150 0.78648 0.29442E+00 0.29813E+00 -1.24 0.7993E-02 0.85259 0.19048
20 0.00 413.150 0.80599 0.37939E+00 0.38794E~00 2.20 0.1004EOl 0.83594 0.21200
20 0.00 423.150 0.82550 0.48764E+00 0.50055E+00 -2.58 0.1257E-Ol 0.81132 0.24381
20 0.00 433.150 0.84501 0.62206E+00 0.64149E+00 -3.03 o. 1574E-01 0.78418 0.27887
20 0.00 443.150 0.86451 0.78810E+00 0.81808E+00 -3.66 0.1975E-Ol 0.75508 0.31648
20 0.00 453.150 0.88402 0.99327E+00 0.10403E+Ol -4.52 0.2494E-Ol 0.72374 0.35697
20 0.00 463.150 0.90353 0.12498E+Ol 0.13226E+Ol -5.50 0.3188E-01 0.68869 0.40227
20 0.00 473.150 0.92304 0.15802E+Ol 0.16872E+01 -6.34 0.4163E-01 0.64700 0.45614
20 0.00 483.150 0.94255 0.20252E+01 0.21716E+Ol -6.74 0.5641E-01 0.59532 0.52290
20 0.00 493.150 0.96206 0.26651E+01 0.28509E+Ol -6.52 0.8229E-Ol 0.53016 0.60710
20 0.00 503.150 0.98156 0.36121E+Ol 0.39310E+01 -8.11 0.1459E+00 0.45609 0.70282
39 0.00 400.000 0.78034 0.26030E+00 0.27385E+00 -4.95 0.7432E-02 0.89335 0.13781
39 0.00 405.000 0.79009 0.29740E+00 0.31324E+00 -5.06 0.8341E-02 0.88225 0.15215
39 0.00 410.000 0.79984 0.33910E+00 0.35742E+00 -5.13 0.9349E-02 0.87008 0.16787
39 0.00 415.000 0.80960 0.38570E+00 0.40691E+00 -5.21 0.1047E-01 0.85739 0.18428
39 0.00 420.000 0.81935 0.43790E+00 0.46231E+00 -5.28 0.I171E-01 0.84378 0.20186
39 0.00 425.000 0.82911 0.49640E+00 0.52430E+00 -5.32 0.1311E-01 0.82918 0.22072
39 0.00 430.000 0.83886 0.56190E+00 0.59364E+00 -5.35 0.1466E-01 0.81368 0.24075
39 0.00 435.000 0.84861 0.63530E+00 0.67122E+00 -5.35 0.1641E-Ol 0.79722 0.26203
39 0.00 440.000 0.85837 0.71770E+00 0.75807E+00 -5.32 0.1837E-Ol 0.77967 0.28470
39 0.00 445.000 0.86812 0.81030E+00 0.85539E+00 -5.27 0.2060E-Ol 0.76106 0.30875
39 0.00 450.000 0.87788 0.91470E+00 0.96463E+00 -5.18 0.231SE-Ol 0.74123 0.33437
39 0.00 455.000 0.88763 o .10329E+01 0.1087SE+Ol -5.02 0.2607E-Ol 0.72002 0.36177
39 0.00 460.000 0.89739 0.11674E+01 0.12261E+01 -4.79 0.2946E-Ol 0.69729 0.39115
39 0.00 465.000 0.90714 o . 13214E+Ol 0.13830E+Ol . -4.46 0.3343E-Ol 0.67285 0.42272
39 0.00 470.000 0.91689 o. 14997E+Ol 0.15616E+01 -3.97 0.3816E-Ol 0.64628 0.45707
39 0.00 475.000 0.92665 o. 17088E+01 0.17662E+01 -3.25 0.4388E-Ol 0.61715 0.49470
39 0.00 480.000 0.93640 0.19597E+01 0.20027E+Ol -2.15 0.5097E-Ol 0.58451 0.53688
39 0.00 485.000 0.94616 0.22723E+Ol 0.22793E+Ol -0.31 0.6.00SE-Ol 0.54664 0.58582
39 0.00 490.000 0.95591 0.26942E+Ol 0.26083E+Ol 3.29 0.7219E-01 0.49918 0.64713
39 0.00 495.000 0.96567 0.35755E+Ol 0.30097E+01 18.80 0.8953E-Ol 0.40670 0.76663
55 0.00 453.184 0.88409 0.10360E+Ol 0.10412E+01 -0.50 0.2496E-Ol 0.69433 0.39497
55 0.00 463.188 0.90361 0.12860E+01 o. 13238E+Ol -2.86 0.3191E-Ol 0.66977 0.42671
55 0.00 473.193 0.92312 0.16320E+Ol 0.16890E+Ol -3.37 0.4168E-Ol 0.62691 0.48209

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 809

Table 6. Comparison of reported saturated vapor densities with values calculated from Eq. (3) - Continued

ID Wt. T TITe p Calc. p % dp/dT Z feZ)

K mol/l molll Dev. (mol/I)/K (expJ

55 0.00 483.197 0.94264 0.20910E+Ol 0.21743E+Ol -3.83 0.5650E-01 0.57703 0.54654

55 0.00 493.201 0.96216 0.27960E+Ol 0.28551E+Ol -2.07 0.8247E-01 0.50575 0.63865
55 0.00 503.204 0.98167 0.38390E+Ol 0.39389E+Ol -2.54 0.1465E+00 0.42948 0.73720
69 0.00 400.000 0.78034 0.27199E+00 0.27385E+00 -0.68 0.7432E-02 0.85495 0.18742
69 0.00 405.000 0.79009 0.31069E+00 0.31324E+00 -0.81 0.8341E-02 0.84451 0.20092
69 0.00 410.000 0.79984 0.35403E+00 0.35742E+00 -0.95 0.9349E-02 0.83339 0.21529
69 0.00 415.000 0.80960 0.40255E+00 0.40691E+00 -1.07 0.1047E-01 0.82150 0.23065
69 0.00 420.000 0.81935 0.45690E+00 0.46231E+00 -1.17 0.1171E-01 0.80869 0.24720
69 0.00 425.000 0.82911 0.51787E+00 0.52430E+00 -1.23 o. 1311E-01 0.79481 0.26514
69 0.00 430.000 0.83886 0.58644E+00 0.59364E+00 -1.21 0.1466E-Ol 0.77963 0.28475
69 0.00 435.000 0.84861 0.66390E+00 o. 67122E+00 -1.09 0.1641E-01 0.76287 0.30641
69 0.00 440.000 0.85837 0.75200E+00 0.75807E+00 -0.80 o .1837E-01 0.74411 0.33065
69 0.00 445.000 0.86812 0.85326E+00 0.85539E+00 -0.25 0.2060E-01 0.72274 0.35826
69 0.00 450.000 0.87788 0.97171E+00 0.96463E+00 0.73 0.2315E-Ol 0.69774 0.39056
69 0.00 455.000 0.88763 o .11149E+01 0.10875E+01 2.52 0.2607E-01 0.66707 0.43019
69 0.00 460.000 0.89739 0.13020E+01 0.12261E+01 6.19 0.2946E-01 0.62519 0.48431
70 0.00 298 .150 0.58164 0.95000E 02 0.70273E 02 35.19 0.3-1-16E-03 0.72003 0.36176
70 0.00 298.150 0.58164 0.87000E-02 0.70273E-02 23.80 0.3446E-03 0.78624 0.27621
70 0.00 323.150 0.63041 0.45700E-01 0.21581E-01 111. 76 0.8869E-03 0.45280 0.70707
70 0.00 323.1.50 0.63041 0.44600E-Ol 0.21581E-Ol 106.66 0.8869E-03 0.46397 0.69263
70 0.00 348.150 0.67918 O.88700E-01 0.55754E-Ol 59.09 0.1958E-02 0.58798 0.53239
70 0.00 348.150 0.67918 0.11510E+OO O.55754E-Ol 106.44 0.lY5SE·02 0.4~;;12 O. 'JUbbb
70 0.00 348.150 0.67918 0.80500E-Ol 0.55754E-Ol 44.38 0.1958E-02 0.64788 0.45500
70 0.00 373.150 0.72796 0.15720E+00 0.12646E+00 24.31 0.3873E-02 0.72475 0.35566
10 0.00 373.150 0.72796 0.16070E+00 0.12646E+00 27.07 0.3873E-02 0.70897 0.37606
70 0.00 373.150 0.72796 0.15400E+00 o. 12646E+00 21.78 0.3873E·02 0.73981 0.33620
70 0.00 398.150 0.77673 0.32630E+00 0.26039E+00 25.31 0.7119E-02 0.68091 0.41232
70 0.00 398.150 0.77673 0.31200E+00 0.26039E+00 19.82 0.7119E-02 0.71212 0.37199
70 0.00 423.150 0.82550 0.59570E+00 0.50055E+00 19.01 0.1257E-Ol 0.66414 0.43399
70 0.00 423.150 0.82550 0.58480E+00 0.50055E+00 16.83 o .1257E-Ol 0.67652 0.41799
70 0.00 448.150 0.87427 0.88870E+00 0.92272E+00 -3.69 0.2217E-Ol 0.73682 0.34007
70 0.00 448.150 0.87427 0.86930E+00 0.92272E+00 -5.79 0.2217E-Ol 0.75327 0.31882
70 0.00 473.150 0.92304 0.15951E+01 0.16872E+01 -5.46 o .4163E-Ol 0.64095 0.46395
70 0.00 473.150 0.92304 0.15515E+Ol 0.16872E+01 -8.04 0.4163E-Ol 0.65896 0.44068
72 0.00 422.851 0.82491 0.50000E+00 0.49680E+00 0.64 0.1249E-Ol 0.78618 0.27629
72 0.00 452.282 0.88233 0.10000E+01 0.10189E+01 -1.85 0.2443E-01 0.70744 0.37804
72 0.00 480.407 0.93720 0.20000E+01 0.20236E+01 -1.17 0.5163E-01 0.57655 0.54716
72 0.00 495.127 0.96591 0.30000E+Ol 0.30211E+Ol -0.70 0.9007E-Ol 0.48568 0.66459
72 0.00 504.615 0.98442 0.40000E+Ol 0.41583E+Ol -3.81 0.1653E+00 0.42109 0.74804
72 0.00 509.423 0.99380 0.50000E+Ol 0.52298E+01 -4.39 0.3187E+00 0.36214 0.82421
72 0.00 512.237 0.99929 0.60000E+Ol 0.68310E+01 -12.17 0.1421E+Ol 0.31481 0.88537
72 0.00 512.240 0.99930 0.70000E+Ol 0.68353E+01 2.41 0.1429E+Ol 0.26985 0.94347
73 0.00 175.400 0.34218 0.12939E-06 0.12329E-06 4.95 0.1966E-07 0.94270 0.07405
73 0.00 180.000 0.35115 0.26094E-06 0.25158E-06 3.72 0.3792E-07 0.95322 0.06044
73 0.00 190.000 0.37066 0.10728E-05 0.10419E-05 2.97 0.1395E-06 0.95909 0.05286
73 0.00 200.000 0.39017 0.37701E-05 0.36949E-05 2.03 0.4421E-06 0.96718 0.04241
73 0.00 210.000 0.40968 0.11645E-04 o. 11480E-04 1.44 0.1233E-05 0.97239 0.03568
73 0.00 220.000 0.42918 0.32151E-04 0.31837E-04 0.98 0.3084E-05 0.97638 0.03052
73 0.00 230.000 0.44869 0.80998E-04 0.80030E-04 1. 21 0.7020E-05 0.97387 0.03377
7;; U.OU 240.0UO U.4O~2U U.l~499.E-U;; U.l~471E-U3 U.lo U.1473E-U4 U.9ts306 U.U21 Ll
73 0.00 250.000 0.48771 0.39495E-03 O.39564E-03 -0.18 0.2879E-04 0.98624 0.01778
73 0.00 260.000 0.50722 0.79029E-03 O.79375E-03 -0.44 0.5288E-04 0.98775 0.01583
73 0.00 270.000 0.52673 0.14911E-02 o. 15032E-02 -0.81 0.9201E-04 0.98984 0.01312
73 0.00 280.000 0.54623 0.26858E-02 0.27053E-02 -0.72 0.1526E-03 0.98675 0.01712
73 0.00 290.000 0.56574 0.46044E-02 0.46536E-02 -1.06 0.2427E-03 0.98701 0.01679
73 0.00 300.000 0.58525 0.76212E-02 0.76899E-02 -0.89 0.3719E-03 0.98134 0.02412
73 0.00 310.000 0.60476 0.12162E-Ol 0.12261E-01 -0.80 0.5516E-03 0.97529 0.03193
73 0.00 320.000 0.62427 0.18789E-Ol 0.18934E-Ol -0.77 0.7948E-03 0.96856 0.04063
73 0.00 330.000 0.64378 0.28294E-Ol 0.28419E-Ol -0.44 0.1117E-02 0.95762 0.05477
73 0.00 340.000 0.66329 o .41429E-Ol 0.41582E-01 -0.37 0.1534E-02 0.94767 0.06762
73 0.00 350.000 0.68279 0.59377E-01 0.59476E-Ol -0.17 0.2066E-02 0.93482 0.08422
73 0.00 360.000 0.70230 0.83179E-Ol 0.83360E-Ol -0.22 0.2736E-02 0.92258 0.10004
73 0.00 370.000 0.72181 0.11461E+OO 0.11474E+00 -0.12 0.3571E-02 0.90699 0.12019
73 0.00 380.000 0.74132 o. 15488E+00 o . 15543E+00 -0.35 O.4603E-02 0.89240 0.13903
73 0.00 390.000 0.76083 0.20641E+00 0.20759E+00 -0.57 0.5873E-02 0.87536 0.16106
73 0.00 400.000 0.78034 0.27020E+00 0.27385E+00 -1.33 0.7432E-02 0.86060 0.18012
73 0.00 410.000 0.79984 0.34948E+00 0.35742E+00 -2.22 0.9349E-02 0.84424 0.20127
73 0.00 420.000 0.81935 0.44712E+00 0.46231E+00 -3.29 0.1171E-Ol 0.82639 0.22433

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

810 ROBERT D. GOODWIN

Table 6. Comparison of reported saturated vapor densities with values calculated from Eq. (3) - Continued

ID Wt. T TITc I' Calc. r % dr/ dT Z feZ)

K molll molll Dev. (molll)!K (exp.)
73 0.00 430.000 0.83886 0.57581E+00 0.59364E+OO -3.00 0.1466E-01 0.79403 0.26614
73 0.00 440.000 0.85837 0.73432E+00 0.75807E+00 -3.13 0.1837E-01 0.76202 0.30750
73 0.00 450.000 0.87788 0.93720E+00 0.96463E+00 -2.84 0.2315E-Ol 0.72344 0.35736
73 0.00 460.000 0.89739 0.11866E+01 0.12261E+Ol -3.22 0.2946E-Ol 0.68598 0.40576
73 0.00 470.000 0.91689 0.15450E+Ol 0.15616E+Ol -1.07 0.3816E-01 0.62734 0.48154
73 0.00 480.000 0.93640 0.20006E+Ol 0.20027E+Ol -0.11 0.5097E-Ol 0.57257 0.55231
73 0.00 490.000 0.95591 0.27138E+Ol 0.26083E+Ol 4.05 0.7219E-01 0.49558 0.65179
73 0.00 500.000 0.97542 0.37153E+Ol 0.35202E+Ol 5.54 0.1171E+00 0.42268 0.74599
73 0.00 510.000 0.99493 0.52896E+Ol 0.54267E+Ol -2.53 0.3665E+00 0.34529 0.84599
99 0.00 510.025 0.99498 0.53494E+Ol 0.54359E+Ol -1.59 0.3690E+00 0.34156 0.85081

53 data points, rms deviation 0.211 %.

m code: (10) Young, (20) Eubank, (31) Fiock, (39) Lashakov, (~9) Staveley, (5t) Weltner, (55) Kay,
(69) virial I v.p., (70) Kudchadker, (72) RDG I Zubarev, (73) Zubarev, (74) Counsell,
(75) Counsell I Qval" (76) Svoboda, (90) via r (T' (99) Straty.

2.2.c. Alternative Vapor Density Equation 2.3. The Vi rial Equation

After completing the present report, we reinvestigated For the vinal equation of state,
the formulation of saturated vapor densities to obtain ZO' -+ 1 Z(P,p,T) = 1 +B(T)p + C(T)p2 +''', (4)
asp-+O. The argument is temperature, T. On integrating Eq.
(9) along isotherms using EOS (6), however, T= Tu (P), we used 18 mixed Pp T data from Ke1l 33 and from Kud-
P = PO' [TO' (p)] for Eq. (2a), and then the argument is den- chadker/ 7 at 298 to 573 K, to formulate B( T) in Llmol,
sity, p. In either case, symbols refer to the state of saturated using x( T) == T 11000,
vapor at coexistence, where x == T lTc, u == (1 - x), Z ==P I
(4a)
(pRT), f3 = 0.35,
Bl = 3.6922, B3 = 1.3098,
Z = 1 + (Ze - l)exp[!(x)], (3c)
B2 = - 4.3214, B4 = - 0.015 008.
7 with an average absolute deviation of 0.021 Limo!.
lex) =Al(1- l/x) +A 2u# + 2: Ai Ui -2, (3d) Corresponding data for C(T) in (L/mo1)2 have been
;=3
formulated graphically,
Al= 77.0276242, As= 270.449 459,
C(T) = - exp[Cl - C2 (T /100)], (4b)
A2 = - 0.797 401 6, A6= - 600.239 197,
C 1 = 17.1634, C2 = 4.4545.
A3= 73.261 311 3, A7= 887.047221.
A4= 51.823505 7, For methanol, C( T) always is negative in the present range
of reduced temperatures of 0.58 to 0.97, quite in contrast to
This equation yields Z = 1 in the limit of low temperatures. simple substances.

10 I I I I

Methanol

5~
Deviations of Saturated Vapor Densities
from Calculated Values 0
0
-
0
'it

~
-..;;; 0
0 0 0 o .... U ..., 0 0 d ....... • • • -
~
0
0
0
0 d d
•0
<I 0 0 0 0 ~ d d
-5 r-
o Zubavev
o Laahakov
c c 0 D D c c
0
-
d Kay
• Straty
I I I I
-10
300 350 400 450 500

T, K
FIG. 2. Methanol vapor densities deviations

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 811

2.4. Pressure-Density-Temperature Data chore ( density) the coexistence temperature Tu (p ), as

The location of available Pp T data for methanol was found by iteration from Eqs. (2) and (3), and thus the vapor
plotted in P-T coordinates by Machado and Streett. 42 Recent pressure, Pu [ T a (p) ] becomes a function of density. In out-
data of Straty63 along isochores (at densities from 0.25 to line
2.62Xthe critical) extend from 378 to 573 K at pressures P - PO' (p) = pR [T - TO' (p)] + O'(pRTc )F(p,T).
from 26 to 342 bar. Sources of data are given in Table 7. To (6)
obtain least-squares coefficients of the EOS, we used 164 The function F(p,T) consists of two temperature-dependent
data of Machado and Streett42; 220 data of Straty63; and 16 functions, each with an isochoric (density dependent) coef-
low-density data generated by virial Eq. (4), above, which ficient. Let x(T) -=T lTc, u(p,T) -= T ITa (p), then,
constitute 400 points from more than 1606 available data
points. The vapor pressures, Eq. (1), and the orthobaric F(p,T) -=B(p)<P(p,T) + C(p)\f!(p,T), (6a)
densities, Eqs. (2) and (3), also contribute to the EOS as <P(p,T) -=In[ (1 + u2 )/21, (6b)
constraints. \f!(p,T) -= (1Ix)ln[ 1 + e(U - 1) ] Ie, (6c)
The Pp T data of Zubarev and Bagdonas71, 72 were given B(p) -=Btu exp( - yu), (6d)
first as raw data (with some typographic errors) , and then as and
smoothed tables. We corrected the raw data errors where
possible and arranged these data onto isotherms. Each iso- C(p) = [C1 + C 2u + C 3u?] (u - 0o)cxp( - 6u). (6e)
therm then is represented by a polynomial, in which the Function <l> (p. T) has an inflection versus U (T) at coexis-
number of terms n were selected: tence (zero curvature). Function \f!(p,T) has large curva-
ture versus u (T) approaching coexistence, but its coeffi-
In(Z) = I A;O'i, (5) cient, C(p), changes sign at a reduced density, 0'0 = 0.825.
1=1
The coefficients B (p ), C (p) were tediously formulated by
where O'-=plpc is the reduced density. In Table 8 we give T, trial fitting ofthePpT data. To obtain a well-behaved critical
p, P, Z, ZcaJc' and the differences uf Z ill percc;;nt. The cudTI- isotherm, we constrain the slope of the critical isochore to
cientsA; are given at the top of each isotherm in Table 8. By equal the slope of vapor-pressure Eq. (1), both at the critical
reading these isotherms at rounded densities, we obtain the point, via the least-squares program of McCarty.43
isochoric Zubarev data given in Table 9 at ID = 90. Parameters and coefficients for Eq. (6) are
2.5. The Equation of State y = 0.82, £5 = 3.3, E= 7.0, 0'0 = 0.825
Bt = 3.271 66657, C2 = 24.38401246,
An outline of this EOS was given by Goodwin. 25 At
present (see the Introduction) the specific heat Cv (p,T) is C t = - 20.376 962 79, C3 = - 75.609 064 80.
finite at the critical point. The following isochoric EOS gives Deviations of experimental densities and pressures from the
pressure as a function of temperature along paths of constant EOS, Eq. (6), are presented in Table 9. At the bottom of
density (isochores) which originate on the liquid-vapor co- each author's individual table in Table 9, aplp avo is the
existence boundary, specified by vapor pressure Eq. (1), and trend of density deviations, obtained as the average of signed
by the orthobaric densities Eqs. (2) and (3). For any iso- relative deviations in percent. lAP IP I avo is the average of

TABLE 7. Summary of PpT data for methanol

RQ.ngc of the data Relative deviations in percent

ap/p
Rel.wt. a dP/P
ID Author/year % T,K p, mollL P. bar Npb rms trendC av. d

87 Ramsay, 1887 (Ref. S3) 0.1 373-513 0.07-7.8 2.1-80 192 7.0 + 1.8 1.2
93 Amagat, 1893, (Ref. 2) 0.0 273-303 2S.5-27.6 1~2000 46 0.7 -0.6 12.5
·13 Bridgman, 1913 (Ref. 9) 0.0 293-353 24.5-28.8 490-2942 42 1.1 -1.0 13.1
16 Seitz, 1916 (Ref. ~7) 0.0 In-273 2~.~-29.~ 101-1013 70 0.5 -0.5 20.8
39 Lashakov, 1939 (Ref. 39) 0.0 443-563 0.3-3.7 10-97 97 3.5 +2.1 1.3
54 Kretschmer, 1954 (Ref. 35) 0.0 310-390 0.006-0.037 0.2-1.0 36 1.5 -1.4 1.4
55 Petty, 1955 (Ref. 50) 0.0 366-411 0.02-0.29 0.7-8.6 23 0.7 -0.4 0.6
67 Zubarev, 1967 (Ref. 71) 0.1 413-573 0.1-20.4 4.0-218 189 1.4 -0.1 0.5
68 Kudchadker, 1970 (Ref. 38) 0.0 298-473 0.002-1.6 0.05-40 103 11.2 +4.3 3.9
70 Finkelstein, 1970 (Ref. 19) 0.1 473-573 6.1-20.9 86-727 162 1.3 -0.1 6.9
83 Machado, 1983 (Ref. 42) 12.3 298-489 15.8-25.4 5-1038 164 0.2 +0.1 3.3
99 Straty, 1985 (Ref. 63) 81.1 378-573 2.1-22.1 25-342 220 0.7 -0.0 0.6
69 Virial Eq., 1985 6.1 430-570 0.2-0.4 6.7-18 16 0.7 -0.2 0.6

a ReI. wt., %, see Sec. 2.4.

bNP = number of PpT data.
C Trend = average of signed relative density deviations.

d Av. = average of absolute relative pressure deviations.

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

812 ROBERT D. GOODWIN

Table 8. Comparison of ID code (73) Zubarev PpT data Table 8. Comparison of ID code (73) Zubarev PI'T data
with values calculated from Eq. (5) with values calculated from Eq. (5) -
Continued
Isotherm 1: T = 413.150 K
A, = -0.34736588E+Ol
Isotherm 4: T = 473.150 K
A, = -0.17880657E+Ol
A2 = 0.52462056[+02
A2 = -0.43182251E+01
A';3 = -0.22110983E+04
A3 = 0.31219773E+Ol
% A4 = -0.44020608E+00
Wt. fl f' Z Z
molil bar (data) (catc.) Dev.
Wt. f' P Z Z %
1.00 0.1222 4.018 0.95685 0.95480 0.21 molll bar (data) (calc.) Dev.
1.00 0.1298 4.228 0.94849 0.95190 -0.36
1.00 0.1613 5.196 0.93785 0.93894 -0.12 1.00 0.1456 5.557 0.97041 0.96825 0.22
1.00 0.2285 7.127 0.90811 0.90470 0.38 1.00 0.3190 11.674 0.93021 0.92871 0.16
1.00 0.2450 7.536 0.89555 0.89447 0.12 1.00 0.4915 17.169 0.88799 0.88800 -0.00
1.00 0.3361 9.411 0.81517 0.82151 -0.77 1.00 0.6387 21.395 0.85144 0.85251 -0.12
0.51 1.0'0 0.7974 25.482 0.81235 0.81383 -0.18
1.00 0.3614 9.930 0.79982 0.79576
1.00 0.9617 29.299 0.77439 0.77359 0.10
7 data points, average deviation 0.35%. 1.00 1.2966 35.327 0.69258 0.69236 0.03
1.00 17.3961 51.291 0.07495 0.07495 -0.00
1.00 19.2682 200.590 0.26463 0.26463 0.00
Isotherm 2: T = 433.150 K 9 data points, average deviation 0.09%.
A, = -0.199328001:+01
A2 -0.40014274E+02
A3 =: 0.68906431E+03
A4 =: -0.71360918E+04 Isotherm 5: T = 493.150 K
A1 == -o.14795422E+01
Wt. P 7- 7. % A2 = -0.35842775E+01
Jl
moll I bar (data) (calc.) Dev. A3 = 0.67540983E+Ol
A4 = -o.41617149E+Ol
1.00 0.1111 3.877 0.96860 0.96851 0.01 AS == 0.87259346E+oo
1.00 0.1168 4.069 0.96697 0.96669 0.03
1.00 0.2042 6.892 0.93696 0.93734 -0.04 Wt. p P Z Z %
J .00 O • .l44b IS. lJ4 0.'12271 0.922'17 -0.03 moill bar (data) (calc.) Dev.
1.00 0.3637 11.506 0.87854 . O. 87770 0.10
1.00 0.4289 13.117 0.84914 0.84969 -0.06 1.00 0.1650 6.574 0.97147 0.97006 0.15
1.00 0.5633 15.799 0.77874 0.77868 0.01 1.00 0.1842 7.295 0.96571 0.96647 -0.08
1.00 0.2939 11.394 0.94561 0.94567 -0.01
7 data points, average deviation 0.04%. 1.00 0.4697 17.529 0.91025 0.91139 -0.12
1.00 0.7280 25.685 0.86048 0.85987 0.07
1.00 0.9873 32.716 0.80815 0.80798 0.02
1.00 1.3124 40.117 0.74550 0.74431 0.16
Isotherm 3: T = 453.150 K 1.00 1.3920 41.513 0.72733 0.72913 -0.25
A, == -O.19170507E+01 1.00 1.4303 42.365 0.72239 0.72190 0.07
A2 = -o.10340721E+02 1.00 1.9088 49.774 0.63596 0.63597 -0.00
A3 = 0.76187032E+Ol 1.00 2.2356 53.420 0.58277 0.58273 0.01
A4 = -0.12849398E+Ol 1.00 16.5537 94.010 0.13850 0.13850 -0.00
1.00 18.4252 218.030 0.28859 0.28859 0.00
Wt. p P Z Z %
moll) bar (data) (calc.) Dev. 13 data points. average deviation 0.07%.
1.00 0.1488 5.379 0.95974 0.96353 -0.39
1.00 0.2752 9.623 0.92805 0.92900 -0.10
1.00 0.4932 16.068 0.86472 0.86358 0.13 Isotherm 6: T = 503.150 K
1.00 0.6005 18.830 0.83224 0.82932 0.35 A, = -0.14774971E+01
1.00 0.8075 23.079 0.75860 0.76096 -0.31 A2 = -o.20129723E+01
1.00 0.9492 25.525 0.71375 0.71329 0.06 A3 = 0.35286904E+01
1.00 18.4798 27.177 0.03903 0.03903 0.00 A4 = -O.27690155E+ot
1.00 20.3526 216.140 0.28186 0.28186 -0.00 A5 = 0.1l383922E+01
A6 "" -O.17069560E+OO
8 data points. average deviation 0.17%.
Wt. (' P Z Z %
molll bar (data) (calc.) Dev.
1.00 0.2015 6.134 0.96,504 0.96411 0.10
1.00 0.3828 14.905 0.93077 0.93129 -0.06
1.00 0.7777 28.032 0.86162 0.85947 0.25
1.00 1.0935 36.752 0.80339 0.80298 0.05
1.00 1.5048 46.086 0.73210 0.73225 -0.02
1.00 1.9265 53.365 0.66216 0.66423 -0.31
1.00 2.7915 63.220 0.54136 0.54162 -0.05
1.00 3.0037 64.850 0.51608 0.51512 0.19
1.00 13.9924 71.480 0.12211 0.12211 0.00
1.00 14.8740 83.760 0.13461 0.13489 -0.21
1.00 15.8460 107.360 0.16195 0.16115 0.50
1.00 16.7213 140.570 0.20095 0.20174 -0.39
1.00 17.7121 207.590 0.28016 0.27990 0.09

13 data points. average deviation 0.17%.

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 813

Table 8. Comparison of Jl) code (73) Zubarev PpT data Table 8. Comparison of ID code (73) Zubarev PpT data
with values calculated from Eq. (5) - with values calculated from Eq. (5) -
Continued Continued

Isotherm 7: T = 509.530 K Isotherm 10: T = 517.950 K

A, = -0.20312018E+01 A, = -O.16183303E+01
A2 = 0.99821982E+00 A2 = 0.51149640E+OO
A3 = -O.83396654E+00 A3 = -O.28969726E+01
A4 = 0.334423461:+00 A4 = 0.62763540E+01
As = -O.56832515E+01
Wt. p l' Z Z % As = 0.23750067E+Ol
molll bar (data) (calc.) Dev. A7 = -0.37041775E+OO

1.00 3.2717 70.130 0.50597 0.50597 -0.00 Wt. p f' Z Z %

1.00 12.8983 79.670 0.14580 0.14580 0.00 moll I bar (data) (calc.) Dev.
1.00 14.7552 100.870 0.16137 0.16137 -0.00
1.00 16.6092 165.260 0.23486 0.23486 0.00 1.00 2.6766 69.240 0.60070 0.60106 -0.06
1.00 3.0477 73.470 0.55977 0.55987 -0.02
4 data points, average deviation 0.00%. 1.00 3.2914 75.980 0.53604 0.53455 0.28
1.00 3.9792 80.400 0.46918 0.47027 -0.23
1.00 4.5427 83.040 0.42447 0.42510 -0.15
Isotherm 8: T = 513.150 K 1.00 4.9357 84.310 0.39665 0.39727 -0.16
A, = -0. 13869434E+O1
1.00 5.0970 85.130 0.38784 0.38667 0:30
1.00 5.7955 86 3'0 0.34"8' 0.14"f,9 0.04
A2 = -U.l 'J3J2'J()';l:+U 1
1.00 6.3952 87.090 0.31622 0.31617 0.01
A3 = 0.49930021 E+01
A4 = -0.730275611:+01
1.00 6.8275 87.470 0.29749 0.29764 -0.05
As = 0.78330417E+01
1.00 6.9896 87.820 0.29175 0.29122 0.18
1.00 7.6137 88.130 0.26878 0.26882 -0.01
As = -O.53834432E+Ol
1.00 S.2650 gS.J130 0.24845 0.24886 -0.16
A 7 = 0.20008806E+01
1.00 8.8888 88.920 0.23229 0.23243 -0.06
As = -0.29739445E+OO
1.00 9.4314 89.350 0.21998 0.22000 -.0.01
Wt. 1.00 10.7802 91.070 0.19617 0.19587 0.15
p P Z
molll bar (data) (calc.) Dev. 1.00 11 .2545 91.960 0.18974 0.18973 0.00
1.00 13.0733 101480 o 1&025 o 18040 -0.08
1.00 1.7007 52.231 0.71980 0.71995 -0.02 1.00 14.8989 131. 830 0.20546 0.20540 0.03
1.00 2.4867 64.940 0.61207 0.61140 0.11 1.00 16.7401 209.570 0.29070 0.29071 -0.00
1.00 2.7741 68.130 0.57562 0.57619 -0.10
1.00 3.5380 74.570 0.49400 0.49376 0.05 20 data points, average deviation O.lWo.
1.00 4.2484 77 .970 0.43015 0.43038 -0.05
1.00 4.3765 78.450 0.42013 0.42018 -0.01
1.00 4.6518 79.220 0.39915 0.39940 -0.06 Isotherm 11: T = 523.150 K
1.00 5.3836 80.730 0.35147 0.35121 0.07 A1 = -O.12965102E+01
1.00 6.0682 81.420 0.31448 0.31410 0.12 A2 = -O.12984460E+Ol
1.00 6.4018 81.500 0.29838 0.29839 -0.00 A3 = 0.20446507E+01
1.00 7.2511 81.610 0.26379 0.26419 -0.15 A4 = -O.34527581E+OO
1.00 7.8969 81.820 0.24284 0.24279 0.02 As = -O.10411478E+01
1.00 8.2958 81.830 0.23119 0.23120 -0.00 As = 0.74574276E+OO
1.00 9.1040 81.850 0.21072 0.21081 -0.04 A7 = -O.14515165E+OO
1.00 9.7284 82.060 0.19770 0.19750 0.10
1.00 10.1922 82.140 0.18889 0.18883 0.03 Wt. f' P Z Z %
1.00 10.9735 82.650 0.17653 0.17652 0.01 molll bar (data) (calc.) Dev.
1.00 11.5545 83.410 0.16919 0.16935 -0.09
1.00 13.3943 92.300 0.16151 0.16146 0.03 1.00 0.2972 12.326 0.95340 0.95370 -0.03
1.00 15.2171 124.220 0.19133 0.19134 -0.01 1.00 0.8801 33.032 0.86285 0.86261 0.03
1.00 17.0614 208.600 0.28656 0.28656 0.00 1.00 1.1279 40.472 0.82495 0.82473 0.03
1.00 1.1839 42.040 0.81634 0.81628 0.01
21 data points, average deviation 0.05%. 1.00 1.7946 56.852 0.72830 0.72801 0.04
1.00 2.9387 74.880 0.58580 0.58608 -0.05
1.00 3.4719 80.100 0.53040 0.53124 -0.16
Isotherm T ~ 514.150 K 1.00 3.5810 81.100 0.52066 0.52088 -0.04
A1 = -O.16086341E+01 1.00 4.7999 88.510 0.42394 0.42296 0.23
A2 = -O.85034633E+OO 1.00 5.2744 90.100 0.39273 0.39258 0.04
A3 0.20399674E+01 1.00 5.4116 90.540 0.38464 0.38449 0.04
A4 = -O.140n368ETOl 1.00 6.6736 93.550 0.32227 0.32211 0.05
As = 0.36561771 E+OO 1.00 7.2470 94.230 0.29893 0.29967 -0.25
1.00 8.5470 96.150 0.25863 0.25884 -0.08
Wt. p P Z Z % 1.00 9.0003 96.910 0.24754 0.24733 0.09
molll bar (data) (calc.) Dev. 1.00 10.4345 99.500 0.21922 0.21892 0.14
1.00 10.8153 100.420 0.21346 0.21342 0.02
1.00 6.2693 82.470 0.30772 0.30761 0.03 1.00 12.6376 110.240 0.20054 0.20083 -0.14
1.00 8.1655 83.020 0.23783 0.23815 -0.13 1.00 14.4652 138.300 0.21980 0.21964 0.08
1.00 10.0608 83.490 0.19412 0.19370 0.22 1.00 16.3021 206.880 0.29175 0.29255 -0.27
1.00 11. 9573 86.030 0.16830 0.16861 -0.18 1.00 16.3388 210.020 0.29551 0.29477 0.25
1.00 13.8582 99.670 0.16824 0.16810 0.08
1.00 15.6741 145.290 0.21683 0.21687 -0.02 21 data points, average deviation 0.10%.

6 data points, average deviation 0.11%.

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

814 ROBERT D. GOODWIN

Table 8. Comparison of ID code (73) Zubarev PpT data Table 8. Comparison of ID code (73) Zubarev PpT data
with values calculated rrom Eq. (5) - with values calculated rrom Eq. (5) -
Continued Continued

Isotherm 12: T = 533.150 K Isotherm 14: T = 553.150 K

Al = -0.11905675E+Ol Al = -0.11142259E+Ol
A 2 = -0.13346006E+0 1 A2 = -0.57574298E+00
A3 = 0.27445200E+0] A3 = 0.12409446E+01
A4 = -0.21280175E+03 A4 = -0.7581635813+00
As = 0.79583776E+00 As = 0.194998841:+00
A6 = -0.10255988E+00
Wt. p P Z Z %
Wt. f' P Z Z % moll I bar (data) (calc,) Dev.
molll bar (data) (calc.) Dev.
1.00 2.4230 78.970 0.70864 0.70866 -0.00
1.00 1.3796 49.050 0.80203 0.80185 0.02 1.00 4.1178 106.400 0.56182 0.56178 0.01
1.00 2.3607 70.720 0.67579 0.67637 -0.09 1.00 5.8784 123.240 0.45584 0.45588 -0.01
1.00 3.1131 82.050 0.59457 0.59471 -0.02 1.00 7.6569 135.540 0.38489 0.38486 0.01
1.00 3.1979 83.180 0.58676 0.586.11 0.08 1.00 9.4489 147.830 0.34018 0.34019 -0.00
1.00 4.1407 92.450 0.50367 0.50339 0.06 1.00 11.2512 165.010 0.31888 0.31888 0.00
1.00 4.4205 94.460 0.48205 0.48219 -0.03
}.OO 4.9428 97.760 0.44618 0.44632 -0.03 6 data points. average deviation 0.00%.
1.00 5.0142 98.240 0.44197 0.44176 0.05
1.00 5.9502 102.730 0.38948 0.38894 0.14
}.OO 6.7826 105.300 0.35023 0.35117 -0.27 Isotherm 15: T = 563.150 K
1.00 6.2480 103.660 0.37427 0.37454 -0.07 A, = -0.10343831E+Ol
1.00 7.7662 108.760 0.31592 0.31541 0.16 A2 = -0.51530284£+00
1.00 9.5867 114.360 0.26910 0.26893 0.06 A3 = 0.11244725E+Ol
1.00 11.4092 123.390 0.24397 0.24420 -0.09 A4 = -0.66972068E+OO
1.00 13.2341 143.260 0.24420 0.24410 0.04 As = 0.16935352E+00
1.00 15.0672 189.800 0.28417 0.28419 -0.01
Wt. p P Z Z %
16 data points. average deviation 0.08%. molll bar (data) (calc.) Dev.
1.00 1.6297 61.680 0.80831 0.80834 -0.00
Isotherm 13: T = 543.150 K
1.00 3.2748 99.860 0.65125 0.65123 0.00
Al = -O.11044012E+Ol
1.00 5.0142 124.540 0.53045 0.53042 0.01
A2 = -O.12391635E+01
1.00 6.7913 141.930 0.44634 0.44641 -0.02
A3 = 0.27030339E+Ol
1.00 8.5823 157.520 0.39199 0.39192 0.02
1.00 10.3859 175.860 0.36163 0.36166 -0.01
A4 = -O.22672008E+01
As = 0.94211755E+OO
1.00 12.2023 204.020 0.35708 0.35708 0.00
A6 = -0.14311807E+OO
7 data points, average deviation 0.01%.
Wt. p P Z Z %
molll bar (data) (calc.) Dev.
Isotherm 16: T = 573.150 K
1.00 0.8621 34.469 0.88533 0.88363 0.19 A, = -0.95078540E+OO
1.00 1.1645 44.421 0.84468 0.84324 0.17 A2 = -0.50658628E+00
1.00 t.7702 61.170 0.76517 0.76601 -0.11 A:5 = O.10542908I!+Ol
1.00 2.0044 66.570 0.73542 0.73785 -0.33 A4 = -0.59380764E+00
1.00 2.8843 83.690 0.64250 0.64201 0.08 As 0.14361683E+OO
1.00 3.7990 96.020 0.55968 0.55927 0.07
1.00 4.7315 104.920 0.49103 0.49091 0.03 Wt. f' P Z Z %
1.00 5.4810 110.520 0.44651 0.44584 0.15 molll bar (data) (calc.) Dev.
1.00 5.6630 111.450 0.43579 0.43605 -0.06
].00 6.5976 116.660 0.39154 0.39189 -0.09 1.00 1.4342 57.540 0.84188 0.84169 0.02
1.00 7.3021 120.180 0.36444 0.36449 -0.01 1.00 3.0507 100.230 0.68944 0.69001 -0.08
1.00 7.5225 121.210 0.35680 0.35683 -0.01 1.00 3.9555 117.260 0.62208 0.62137 0.11
1.00 8.4783 125.570 0.32796 0.32810 -0.04 1.00 4.7661 129.290 0.56924 .0.56945 -0.04
1.00 9.1296 128.720 0.31220 0.31240 -0.06 1.00 5.7222 141.400 0.51854 0.51877 -0.04
1.00 9.3954 130.330 0.30717 0.30684 0.11 1.00 6.5294 150.610 0.48403 0.48384 0.04
1.00 10.3601 136.130 0.29096 0.29079 0.06 1.00 7.4904 160.780 0.45043 0.45042 0.00
1.00 10.9600 140.540 0.28394 0.28414 -0.07 1.00 8.3145 169.590 0.42801 0.42803 -0.00
1.00 12.2401 154.580 0.27965 0.27937 0.10 1.00 9.2748 180.540 0.40848 0.40857 -0.02
1.00 12.8014 162.840 0.28167 0.28193 -0.09 1.00 10.1143 191.460 0.39723 0.39713 0.02
1.00 14.6526 210.200 0.31766 0.31763 0.01 1.00 11.0810 206.250 0.39058 0.39060 -0.01

20 data points, average deviation 0.09%. 11 data points, average deviation 0.04%.

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 815

Table 9a. Comparison of II) code (13) Bridgeman PI'T data with values calculated
from Eq. (6)

Wt. T I' Calc. I' :11'/1' P Calc. P :1 piP

K mol/l molll % bar bar %
0.001 293.150 25.7348 25.8805 -0.56 490.333 419.812 16.80
0.001 293.150 26.5260 26.7667 -0.90 980.665 837.029 17.16
0.001 293.150 27.2524 27.5045 -0.92 1470.998 1294.824 ]3.61
0.001 293.150 27.8192 28.1466 -1.16 1961.330 1703.662 15.12
0.001 293.150 28.3083 28.7192 -1.43 2451.663 2094.541 17.05
0.001 293.150 28.7526 29.2376 -1.66 2941.995 2481.900 18.54
0.001 101.1"i0 ?"i."11·' ?"i.n107 -0.47 490 .1.1~ 4~4.0n~ 12.96
0.001 303.150 26.3134 26.5394 -0.85 980.665 848.536 15.57
0.001 303. ISO 27.0454 27.2923 -0.90 1470.998 ]301.588 13.02
0.001 303.150 27.6246 27.9463 -1.15 1961.330 1712.456 14.53
0.001 303.150 28.1256 28.5291 -1 .41 2451.663 2106.686 16.38
0.001 303.150 28.5803 29.0568 -1.64 2941.995 2497.279 17.81
0.001 313.150 25.2793 25.3819 -0.40 490.333 443.261 10.62
0.001 313.150 26.1042 26.3143 -0.80 980.665 860.300 13.99
0.001 313.150 26.8500 27.0828 -0.86 1470.998 1314.068 11.94
0.001 313.150 27.4387 27.7487 -1.12 1961.330 1725.337 13.68
0.001 313.150 27.9515 28.3416 -1.38 2451.663 2123.192 15.47
0.001 313.150 28.4133 28.8784 -1.61 2941.995 2514.560 17.00
0.001 323.150 25.0389 25.1335 -0.38 490.333 448.227 9.39
0.001 323.150 25.8930 26.0912 -0.76 980.665 869.517 12.78
0.001 323.150 26.6631 26.8758 -0.79 1470.998 1330.031 10.60
0.001 323.150 27.2671 27.5536 -1.04 1961.330 1746.333 12.31
0.001 323.150 27.7856 28.1565 -1.32 2451.663 2143.777 14.36
0.001 323.150 28.2545 28.7022 -1.56 2941.995 2536.391 15.99
0.001 333.150 24.7909 24.8851 -0.38 490.333 449.776 9.02
0.001 333.1::50 2::5.6799 2::5.5695 -0.7J 950.66::5 576.~94 11.57
0.001 333. ]50 26.4732 26.6710 -0.74 ]470.998 1342.184 9.60
0.001 333.150 27.0917 27.3610 -0.98 1961.330 1762.337 11.29
0.001 333.150 27.6246 27.9738 -1.25 2451.663 2165.80.9 13.20
0.001 333.150 28.0975 28.5283 -1.51 2941.995 2557.109 15.05
0.001 343.150 24.5335 24.6360 -0.42 490.333 447.724 9.52
0.001 343.150 25.4601 25.6497 -0.74 980.665 879.233 11.54
0.001 343.150 26.2751 26.4683 -0.73 1470.998 1347.525 9.16
0.001 343.150 26.9129 27.1707 -0.95 1961.330 1773.793 10.57
0.001 343.150 27.4626 27.7934 -1.19 2451.663 2184_550 12.23
0.001 343.150 27.9422 28.3564 -1.46 2941.995 2576.831 14.17
0.001 353.150 24.2697 24.3858 -0.48 490.333 443.915 10.46
0.001 353.150 25.2213 25.4306 -0.82 980.665 871.750 12.49
0.001 353.150 26.0692 26.2674 -0.75 1470.998 1346.821 9.22
0.001 353.150 26.7336 26.9825 -0.92 1961.330 1783.111 9.99
0.001 353.150 27.2995 27.6151 -1.14 2451.663 2200.276 11.43
0.001 353.150 27.7947 28.1867 -1.39 2941.995 2600.805 13.12
42 data points, I~pl pi rms = 1.059%, :1plp avo = -0.99%, 1:1 pi PI avo = 13.11%,
weight = 0.02%.

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

816 ROBERT D. GOODWIN

Table 9b. Com.parison of (D code (16) Seitz Pp1' data with values calculated
from Eq. (6)

175.200 28.4318 ~O.2S

175.200 28.6111 -0.37
0.001 175.200 28.6451 28.7797 -0.47 303.975 222.607 36.55
0.001 175.200 28.7804 28.9394 -0.55 405.300 304.434 33.13
0.001 175.200 28.9105 29.0914 -0.62 506.625 386.567 31.06
0.001 175.200 29.0333 29.2367 -0,70 601.950 461.354 30.08
0.001 175.200 29.1522 29.3760 -0.76 709.275 548.472 29.32
0.001 175.200 29.2686 29.5100 -0.82 810.600 630.797 28.50
0.001 175.200 29.3792 29.6390 -0.88 911.925 711.603 28.15
0.001 175.200 29.4871 29.7635 -0.93 1013.250 793.040 27.77
0.001 181.800 28.1538 28.2220 -0.24 101.325 65.309 55.15
0.001 181.800 28.3004 28.4051 -0.37 202.650 143.848 40.88
0.001 181.800 28.4421 28.5711 -0.47 303.975 223.927 35.75
0.001 181.800 28.5819 28.7401 -0.55 405.300 306.894 :n.07
0.001 181. 800 28.7134 28.8952 -0.63 506.625 388.382 30.45
0.001 181. 800 28.8412 29.0435 -0.70 607.950 470.816 29.13
0.001 181.800 28.9684 29.1857 -0.74 709.275 556.123 27.54
0.001 181.800 29.0901 29.3224 -0.79 810.600 640.720 26.51
0.001 181.800 29.2061 29.4541 -0.84 911.925 724.128 25.93
0.001 181.800 29.3161 29.5812 -0.90 1013.250 805.871 25.73
0.001 204.250 27.4730 27.5299 -0.21 101.325 73.191 38.44
0.001 204.250 27.6367 27.7255 -0.32 202.650 155.804 30.07
0.001 204.250 27.7963 27.9091 -0.40 303.975 240.998 26.13
0.001 204.250 27.9468 28.0828 -0.48 405.300 325.537 24.50
0.001 204.250 28.0912 28.2482 -0.56 506.625 410.342 23.46
0.001 204.250 28.2261 28.4062 -0.63 607.950 492.837 23.36
0.001 204.250 28.3515 28.5517 -0.70 709.275 576.276 23.08
0.001 204.250 28.4869 28.7034 -0.75 810.600 661.438 22.55
0.001 204.250 28.6094 28.3438 -0.81 911.925 744.809 22.44
0.001 204.250 28.7314 28.9794 -0.86 1013.250 830.487 22.01
0.001 223.210 26.9244 26.9669 -0.16 101.325 81.354 24.55
0.001 223.210 27.1063 27.1735 -0.25 202.650 168.868 20.00
0.001 223.210 27.2788 27.3670 -0.32 303.975 257.033 18.26
0.001 223.210 27.4402 27.5499 -0.40 405.300 343.886 17.86
0.001 223.210 27.5930 27.7237 -0.47 506.625 429.978 17.83
0.001 223.210 27.7398 27.8897 -0.54 607.950 516.293 17.75
0.001 223.210 27.8790 28.0487 -0.61 709.275 601.327 17.95
0.001 ·223.210 28.0150 28.2017 -0.66 810.600 687.416 17.92
0.001 223.210 28.1475 28.3490 -0.11 911.925 114.294 11.78
0.001 223.210 28.2782 28.4913 -0.75 1013.250 862·.782 17.44
0.001 235.100 26.5106 26.6046 -0.13 101.325 85.935 17.91
0.001 235.700 26.7647 26.8189 -0.20 202.650 176.337 14.92
0.001 235.700 26.9488 27.0192 -0.26 303.975 267.625 13.58
0.001 235.700 27.1194 27.2082 -0.33 405.300 356.970 13.54
O.OOZ 235.7()0 27.2803 27.3877 -0.39 506.625 445.414 13.74
0.001 235.700 27.4313 27.5589 -0.46 607.950 532.002 14.28
0.001 235.700 27.5764 27.7229 -0.53 709.275 618.561 14.67
0.001 235.700 27.7185 27.8805 -0.58 810.600 706.494 14.74
0.001 235.700 27.8575 28.0323 -0.62 911. 925 795.551 14.63
0.001 235.700 27.9932 28.1789 -0.66 1013.250 885.477 14.43
0.001 252.350 26.1055 26.1296 -0.09 101.325 90.989 11.36
0.001 252.350 26.3134 26.3549 -0.16 202.650 183.398 10.50
0.001 252.350 26.5066 26.5649 -0.22 303.975 275.148 10.48
0.001 252.350 26.6885 26.7626 -0.28 405.300 366.634 10.55
0.001 252.350 26.8614 26.9498 -0.33 506.625 458.160 10.58
0.001 252.350 27.0251 27.1283 -0.38 607.950 548.805 10.78
0.001 252.350 27.1820 27.2990 -0.43 109.275 639.400 10.93
0.001 252.350 27.3319 27.4628 -0.48 810.600 729.325 11.14
0.001 252.350 27.4790 27.6206 -0.51 911.925 820.804 11.10
0.001 252.350 27.6186 27.7727 -0.55 1013.250 910.640 11.27

J. Phya. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 817

Table 9h. Corn pa rison of ID code (16) Sei tz !J{lT data with values calculated
from Eq. (6) - Continued

Wt. T {l Calc. f' LJ.{'/l' P Calc. P 6.P/P

K molll molll % bar bar %
0.001 273.150 25.5230 25.5441 -0.08 101 .325 92.876 9.10
0.001 273.150 25.7519 25.7853 -0.13 202.650 188.079 7.75
0.001 273.150 25.9634 26.0089 -0.17 303.975 282.815 7.48
0.001 273.150 26.1582 26.2183 -0.23 405.300 375.601 7.91
0.001 273.150 26.3436 26.4162 -0.27 506.625 468.822 8.06
0.001 273.150 26.5205 26.6041 -0.31 607.950 562.235 8.13
0.001 273.150 26.6913 26.7836 -0.34 709.275 656.581 8.03
0.001 273.150 26.8529 26.9555 -0.38 810.600 749.604 8.14
0.001 273.150 27.0078 27.1208 -0.42 911.925 842.225 8.28
0.001 273.150 27.1558 27.2801 -0.46 1013.250 933.862 8.50

70 data points, l6.p/ {'I rms = 0.529%, 6.p/ p avo = -0.48%, I6.P/ PI avo = 20.82%,
weight = 0.03%.

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

818 ROBERT D. GOODWIN

Table 9c. Comparison of ID code (39) Lashakov PpT data with values calculated
from Eq. (6)

Wt. T p Calc. p .1p/ p P Calc. P LJ.P/P

K molll molll % bar bar %

0.001 443.150 0.3121 0.3144 -0.73 10.436 10.368 0.66

0.001 45_'L 150 0.3121 0.3126 -0.16 10.740 10.725 0.15
0.001 463.150 0.3121 0.3114 0.22 11.044 11.067 -0.21
0.001 473.150 0.3121 0.3106 0.47 11.348 11. 399 -0.44
0.001 483.150 0.3121 0.3102 0.62 11. 652 11. 721 -0.58
0.001 493.150 0.3121 0.3099 0.69 11.956 12.035 -0.65
0.001 503.150 0.3121 0.3099 0.70 12.260 12.342 0.66
0.001 513.150 0.3121 0.3100 0.66 12.564 12.644 -0.63
0.001 523.150 0.3121 0.3103 0.58 12.868 12.940 -0.56
0.001 533.150 0.3121 0.3106 0.47 13.172 13.233 -0.46
0.001 543.150 0.3121 0.3110 0.34 13.476 13.521 -0.33
0.001 553.150 0.3121 0.3115 0.20 13.780 LL~Ub -0.19
0.001 563.150 0.3121 0.3120 0.03 14.084 14.089 -0.03
0.001 443.150 0.6242 0.6470 -3.52 18.796 18.319 2.60
0.001 453.150 0.6242 0.6310 -1.08 19.454 19.294 0.83
0.001 463.150 0.6242 0.6209 0.53 20.113 20.198 -0.42
0.001 473.150 0.6242 0.6143 1.60 20.772 21.046 -1.30
0.001 483.150 0.6242 0.6117 2.03 21.481 21.850 -1.69
0.001 493.150 0.6242 0.6106 2.23 22.190 22.616 -1. 88
0.001 503.150 0.6242 0.6104 2.25 22.899 23.352 -1.94
0.001 513.150 0.6242 0.6110 2.16 23.609 24.061 -1.88
0.001 523.150 0.6242 0.6121 1.97 24.318 24.749 -1.74
0.001 533.150 0.6242 0.6136 1.72 25.027 25.418 -1.54
0.001 543.150 0.6242 0.6155 1.41 25.737 26.070 -1.28
0.001 553.150 0.6242 0.6175 1.07 26.446 26.708 -0.98
0.001 563.150 0.6242 0.6198 0.71 27.155 27.333 -0.65
0.001 463.150 0.9363 0.9449 -0.92 27.355 27.190 0.61
0.001 473.150 0.9363 0.9241 1.32 28.467 28.732 -0.92
0.001 483.150 0.9363 0.9162 2.19 29.683 30.164 -1.59
0.001 493.150 0.9363 0.9088 3.02 30.793 31.508 -2.27
0.001 503.150 0.9363 0.9086 3.04 32.009 32.780 -2.35
0.001 513.150 0.9363 0.9103 2.85 33.224 33.993 -2.26
0.001 523.150 0.9363 0.9095 2.94 34.319 35.155 -2.38
0.001 533.150 0.9363 0.9137 2.47 35.535 36.274 -2.04
0.001 543.150 0_9363 0.9185 193 16_751 17.1~7 -1.62
0.001 553.150 0.9363 0.9238 1.35 37.966 38.409 -1.15
0.001 563.150 0.9363 0.9270 1.00 39.091 39.433 -0.87
0.001 473.150 1.2483 1.2395 0.71 34.451 34.593 -0.41
0.001 483.150 1.2483 1.2167 2.60 36.173 36.772 -1.63
0.001 493.150 1.2483 1.2062 3.49 37.896 38.791 2.31
0.001 503.150 1.2483 1.2071 3.42 39.719 40.683 -2.37
0.001 513.150 1.2483 1.2068 3.44 41.422 42.470 -2.47
0.001 523.150 1.2483 1.2141 2.82 43.246 44.171 -2.10
0.001 533.150 1.2483 1.2201 2.32 44.988 45.799 -1.77
0.001 543.150 1.2483 1.2261 1.82 46.691 47.365 -1.42
0.001 553.150 1. 2483 1.2369 0.93 48.514 48.878 -0.74
0.001 563.150 1.1483 1.2457 0.21 50.257 50.345 -0.17
0.001 483.150 1.5604 1.5090 3.41 41.138 41. 889 -1.79
0.001 493.150 1.5604 1.5145 3.03 43.874 44.656 -1.75
0.001 503.150 1.5604 1.5126 3.16 46.306 47.228 -1.95
0.001 513.150 1.5604 1. 5133 3.12 48.636 49.642 -2.03
0.001 523.150 1.5604 1.5234 2.43 51.068 51.928 -1.66
0.001 533.150 1.5604 1.5361 1.58 53.500 54.107 -1.12
0.001 543.150 1.5604 1.5467 0.89 55.830 56.195 -0.65
0.001 553.150 1.5604 1.5624 -0.13 58.262 58.206 0.10
0.001 563.150 1.5604 1.5753 -0.95 60.592 60.150 0.74
0.001 483.150 1.8725 1.7839 4.97 44.763 45.741 -2.14
0.001 493.150 1.8725 1. 8138 3.24 48.514 49.306 -1.61
0.001 .503.1.50 1.8725 1. 8126 3.31 51.651 52.601 -1.81
0.001 513.150 1.8725 1. 8175 3.03 54.691 55.681 -1.78
0.001 523.150 1.8725 1.8296 2.34 57.731 58.587 -1.46
0.001 533.150 1.8725 1.8413 1. 70 60.667 61.348 -1.11
0.001 543.150 1.8725 1. 8582 0.77 63.652 63.988 -0.52
0.001 483.150 2.1846 2.0563 6.24 47.500 4fL!587 -2.24
0.001 493.150 2.1846 2.1013 3.96 52.054 52.930 -1.66
0.001 503.150 2.1846 2.1093 3.57 56.004 56.977 -1.71
0.001 513.150 2.1846 2.1190 3.10 59.756 60.749 -1.63
0.001 513.150 1.1846 1.1381 2.18 63.501 64.298 -1.24
0.001 533.150 2.1846 2.1625 1.02 67.246 67.666 -0.62
0.001 543.150 2.1846 2.1854 -0.04 70.899 70.882 0.02

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 819

Table 9c. Comparison of lD code (39) Lashakov P{'T data with values calculated
rrom Eq. (6) - Continued

Wt. T {' Calc. {' fJ.('/ {' P Calc. P fJ.P/P

K molll molll % bar bar %

0.001 493.150 2.4967 2.3639 5.62 54.610 55.686 -1.93

0.001 503.150 2.4967 2.3981 4.11 59.474 60.504 -1.70
0.001 513.150 2.4967 2.4137 3.44 63.932 64.984 -1.62
0.001 523.150 2.4967 2.4490 1.95 68.496 69.196 -1.01
0.001 533.150 2.4967 2.4884 0.33 73.051 73.188 -0.19
0.001 543.150 2.4967 2.5134 -0.66 77.307 76.999 0.40
0.001 493.150 2.8088 2.5998 8.04 56.430 57.711 -2.22
0.001 503.150 2.8088 2.6655 5.38 62.102 63.306 -1.90
0.001 513.150 2.8088 2.7019 3.96 67.373 68.504 -1.65
0.001 523.150 2.8088 2.7568 1.89 72.735 73.389 -0.89
0.001 533.150 2.8088 2.8079 0.03 78.006 78.019 -0.02
0.001 543.150 2.8088 2.8415 -1.15 82.976 82.441 0.65
0.001 503.150 3.1209 2.8907 7.96 63.936 65.492 -2.38
0.001 513.150 3.1209 2.9744 4.92 70.117 71.409 -1.81
0.001 523.150 3.1209 3.0583 2.05 76.298 76.971 -0.87
0.001 533.150 3.1209 3.1392 -0.58 82.479 82.248 0.28
0.001 543.150 3.1209 3.1732 -1.65 88.051 87.291 0.87
0.001 503.150 3.4330 3.0641 12.04 65.136 67.152 -3.00
0.001 513.150 3.4330 3.2098 6.95 72 .135 73.781 -2.23
0.001 523.150 3.4330 3.3358 2.91 79.124 80.020 -1.12
0.001 533.150 3.4330 3.4571 -0.70 86.212 85.947 0.31
0.001 543.150 3.4330 3.5088 -2.16 92.599 91.619 1.07
0.001 503.150 3.7450 3.2179 16.38 66.060 68.372 -3.38
0.001 513.150 3.7450 3.4436 8.75 73.854 75.697 -2.43
0.001 523.150 3.7450 3.6369 2.97 81. 757 82.604 -1.03
0.001 533.150 3.7450 3.7852 -1.06 89.563 89.179 0.43
0.001 543.150 3.7450 3.8566 -2.89 96.761 95.483 1.34

97 data points. lfJ.p/ pi rms = 3.526%, fJ.p/ p avo = 2.11%, I.::lP/ PI avo = 1.3()11o,
weight = 0.02%.

J. Phys. Chern. Ref. Data, Vol. 18, No.4, 1987

820 ROBERT D. GOODWIN

Table 9d. Comparison of lD cooe (54) Kretschmer PpT data with values
calculated from Eq. (6)

Wt. T II Calc. I' t11'/'1 P Calc. P t1PI P

K mol/l mol/l % bar bar %
0.001 310.000 0.0079 0.0080 -1.21 0.200 0.198 1.21
0.001 320.000 0,0076 0,0077 -1,40 0,200 0,197 1.41
0.001 320.000 0.0154 0.0156 -0.93 0.400 0.396 0,92
0.001 330.000 0.0073 0.0075 -1.45 0.200 0.197 1.46
0.001 330.000 0,0148 0.0150 -1.39 0.400 0.395 1.38
0.001 330.000 0,0226 0.0228 -0.95 0.600 0.594 0.93
0.001 340.000 0,0071 0.0072 -1.45 0.200 0.197 1.46
0.001 340.000 0.0143 0.0146 -1.52 0.400 0.394 1.52
0.001 340.000 0.0217 0.0220 -1.44 0.600 0.592 1.42
0.001 340.000 0.0292 0.0296 -1.16 0.800 0.791 1. 14
O.oot 340.000 0.0370 0.0373 -0.62 1.000 0.994 0.60
(l.OO1 350.000 0.0069 0.0070 -1.43 0.200 0.197 1.44
(l.OOt 350.000 0.0139 0.0141 -1.54 0.400 0.394 1.55
0.001 350.000 0.0210 0.0213 -1.57 0.600 0.591 1.57
0.001 350.000 0.0281 0.0286 -1.53 0.800 0.788 1.51
0.001 350.000 0.0355 0.0360 -1.39 1.000 0.987 1.36
0_001 360_000 0.0067 0.0068 -1.40 0.200 0.197 1. 41
0.001 360.000 0.0135 0.0137 -1.53 0.400 0.394 1.53
O.OOt 360.000 0.0203 0.0206 -1.59 0.600 0.591 1.59
0.001 360.000 0.0272 0.0277 -1.62 0.800 0.787 1. 61
0.001 360.000 0.0342 0,0348 -1.61 1.000 0.984 1.60
0.001 370.000 0.0065 0.0066 -1,37 0.200 0.197 1. 38
0.001 370.000 0.0131 0.0133 -1,50 0.400 0.394 1.51
0.001 370.000 0.0197 0.0200 -1.58 0.600 0.591 1.58
0.001 370.000 0.0264 0.0268 -1.62 0.800 0.787 1.62
0.001 370.000 0.0331 0.0337 -1.65 1.000 0.984 1.64
0.001 380.000 0.0064 0.0064 -1.34 0.200 0.197 1.35
0.001 380.000 0.0127 0.0129 -1.47 0.400 0.394 1.48
0.001 380.000 0.0192 0.0195 -1.54 0.600 0.591 1.55
0.001 380.000 0.0257 0.0261 -1.59 0.800 0.787 1.60
0.001 380.000 0.0322 0.0327 -1.63 1.000 0.984 1.63
0.001 390.000 0.0062 0.0063 -1.31 0.200 0.197 1.32
0.001 390.000 0.0124 0.0126 -1.44 0.400 0.394 1.45
0.001 390.000 0.0187 0.OJ89 -1.51 0.600 0.59J 1.51
0.001 390.000 0.0250 0.0253 -1.55 0.800 0.788 1.56
0.001 390.000 0.0313 0.0318 -1.~9 1.000 0.984 1.~9

36 data points, I~plpi rms = 1.445%, tJplp avo = -1.43%, ItJP/PI avo = 1.43%,
weight = 0.01%.

J. Phys. Chem. Aef. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 821

Table ge. Comparison of II) code (55) Petty 1'(11' data with values calculated
from Eq. (6)

Wt. T /' Calc. /' Llplp J' Calc. P LlPIP

K molll mo)/) % bar bar %

0.001 366.483 0.0231 0.0233 -0.81 0.689 0.684 0.80

0.001 366.483 0.0343 (L0345 -0.60 1.014 1.008 0.59
o.OO} 366.483 0.0473 0.0474 -0.39 1.379 1.374 0.38
0.001 366.483 0.0726 0.0726 0.04 2.068 2.069 -0.04
0.001 366.483 0.1002 0.0990 1. 22 2.758 2.788 -1.10
0.001 388.706 0.0217 0.0219 -0.86 0.689 0.684 0.85
0.001 3&&.706 o.(n:n () 0313 -0 66 1 014 1.007 O.h.'5
0.001 388.706 0.0441 0.0443 -0.45 1.379 1.373 0.45
0.001 388.706 0.0671 0.0672 -0.15 2.068 2.065 0.14
0.001 388.706 0.0908 0.0908 0.01 2.758 2.758 -0.01
0.001 388.706 0.1153 0.1152 0.14 3.447 3.452 -0.13
0.001 388.706 0.1409 0.1405 0.31 4.137 4.148 -0.28
O.OO} 388.706 0.1966 0.1947 1.00 5.516 5.563 -0.84
0.001 410.928 0.0204 0.0206 -1.03 0.689 0.682 1.03
0.001 410.928 0.0302 0.0304 -0.91 1.014 1.004 0.91
0.001 410.928 0.0413 0.0416 -0.80 1.379 1.368 0.79
0.001 410.928 0.0625 0.0629 -0.67 2.068 2.055 0.65
0.001 410.928 0.0840 0.0846 -0.66 2.758 2.740 0.64
0.001 410.928 0.1060 0.1067 -0.64 3.447 3.426 0.62
(LOO1 410.928 0.1285 0.1293 -0.63 4.137 4.112 0.60
0.001 410.928 0.1750 0.1761 -0.62 5.516 5.485 0.57
O.OOl 410.928 0.2240 0.2256 -0.71 6.895 6.851 0.63
0.001 410.928 0.2901 0.2928 -0.91 8.618 8.554 0.76

23 data points. 1.:11'/,,1 rms = 0.694%, .:1fl/f' avo = -0.38%. I.:1P/PI avo = 0.59%.
weIght = O.UI%.

J. Phys. Chem. Ret Data, Vol. 16, No. 4,1987

822 ROBERT D. GOODWIN

Table 9f. Comparison of ID code (67) Zubarev PpT data with values calculated
from Eq. (6)

Wt. T p Calc. p .6.p/p P Calc. P .6.p/p

K molll moll I % bar bar %

0.001 413.150 0.1222 0.1244 -1.76 4.018 3.951 1. 70

,0.001 413.150 0.1298 0.1313 -1.18 4.228 4.181 1.13
0.001 413.150 0.1613 0.1637 -1.45 5.196 5.126 1.37
0.001 413.150 0.2285 0.2320 -1.51 7.127 7.032 1.35
0.001 413.150 0.2450 0.2472 -0.91 7.536 7.476 0.80
0.001 413.150 0.3361 0.3218 4.45 9.411 9.747 -3.44
0.001 413.150 0.3614 0.3440 5.05 9.930 10.321 -3.79
0.001 433.150 0.1111 0.1129 -1.54 3.877 3.819 1.51
0.001 433.150 0.1168 0.1187 -1.54 4.069 4.009 1.51
0.001 433.150 0.2042 0.2068 -1.25 6.892 6.812 1.18
0.001 433.150 0.2448 0.2477 -1.19 8.134 8.046 1.09
0.001 433.150 0.3637 0.3677 -1.09 11 .506 11.400 0.93
0.001 433.150 0.4289 0.4311 -0.51 13.117 13.063 0.41
0.001 433.150 0.5633 0.5499 2.45 15.799 16.075 -1.72
0.001 453.150 0.1488 0.1499 -0.77 5.379 5.339 0.75
0.001 453.150 0.2752 0.2772 -0.73 9.623 9.559 0.67
0.001 4::53.1::50 0.4932 0.4962 -0.61 16.065 1;5.956 0.::51
0.001 453.150 0.6005 0.6047 -0.70 18.830 18.728 0.55
0.001 453.150 0.8075 0.8001 0.92 23.079 23.221 -0.61
0.001 453.150 0.9492 0.9373 1.26 25.525 25.716 -0.74
0.000 453.150 18.4798 18.5647 -0.46 27.177 19.631 38.44
0.001 453.150 20.3526 20.3042 0.24 216.140 223.700 -3.38
0.001 473.150 0.1456 0.1472 -1.10 5.557 5.497 1.09
0.001 473.150 0.3190 0.3202 -0.38 11.674 11.633 0.35
0.001 473.150 0.4915 0.4910 0.10 17.169 17.183 -0.08
0.001 473.150 0.6387 0.6368 0.30 21.395 21.1\48 -0.25
0.001 473.150 0.7974 0.7946 0.35 25.482 25.549 -0.26
0.001 473.150 0.9617 0.9628 -0.11 29.299 29.276 0.08
0.001 473.150 1.2966 1.2950 0.13 35.327 35.352 -0.07
0.001 473.150 17.3961 17.4294 -0.19 51.291 49.728 3.14
0.001 473.150 19.2682 19.2971 -0.15 200.590 197.194 1.72
0.001 493.150 0.1650 0.1666 -0.96 6.574 6.513 0.94
0.001 493.150 0.1842 0.1854 -0.64 7.295 7.250 0.62
0.001 493.150 0.2939 0.2946 -0.25 11. 394 11.367 0.23
0.001 493.150 0.4697 0.4680 0.35 17.529 17.584 -0.31
0.001 493.150 0.7280 0.7254 0.36 25.685 25.761 -0.30
0.001 493.150 0.9873 0.9837 0.36 32.716 32.805 -0.27
0.001 493.150 1.3124 1.3131 -0.05 40.117 40.104 0.03
0.001 493.150 1.3920 1.3846 0.54 41.513 41.654 -0.34
0.001 493.150 1.4303 1.4301 0.02 42.365 42.369 -0.01
0.001 493.150 1.9088 1.9086 0.01 49.774 49.777 -0.01
0.001 493.150 2.2356 2.2340 0.07 53.420 53.435 -0.03
0.001 493.150 16.5537 16.5411 0.08 94.010 94.513 -0.53
0.001 493.150 18.4252 18.4292 -0.02 218.030 217.652 0.17
0.001 503.150 0.2015 0.2025 -0.51 8.134 8.094 0.50
0.001 503.150 0.3828 0.3810 0.46 14.905 14.969 -0.43
0.001 503.150 0.7777 0.7725 0.67 28.032 28.188 -0.55
0.001 503.150 '1.0935 1.0859 0.70 36.752 36.943 -0.52
0.001 503.150 1.5048 1.5014 0.22 46.086 46.151 -0.14
0.001 503.150 1.9265 1.9225 0.21 53.365 53.425 -0.11
0.001 503.150 2.7915 2.7979 -0.23 63.220 63.168 0.08
0.001 503.150 3.0037 3.0205 -0.55 64.850 64.738 0.17
0.001 503.150 13.9924 14.0016 -0.07 71.480 71. 397 0.12
0.001 503.150 14.8740 14.9189 ~0.30 83.760 82.944 0.98
0.001 503.150 15.8460 15.8570 -0.07 107.360 107.000 0.34
0.001 503.150 16.7213 16.7498 -0.17 144.570 143.111 1.02
0.001 503.150 17.7121 17.7265 -0.08 207.590 206.452 0.55
0.001 509.530 3.2717 3.2330 1.20 70.130 70.397 -0.38
U.UUl ~UY.~3U 12 .~Y~3 Ll. ~1o:l U.17 79.610 19.771 -0.13
0.001 509.530 14.7552 14.7659 -0.07 100.870 100.655 0.21
0.001 509.530 16.6092 16.6265 -0.10 165.260 164.350 0.55
0.001 513.150 1.7007 1.6876 0.78 52.231 52.488 -0.49
0.001 513.150 2.4867 2.4931 -0.26 64.940 64.861 0.12
0.001 513.150 2.7741 2.7726 0.05 68.130 68.145 -0.02
0.001 513.150 3.5380 3.5533 -0.43 74.570 74.473 0.13
0.001 513.150 4.2484 4.2428 0.13 77.970 77.991 -0.03
0.001 513.150 4.3765 4.3787 -0.05 78.450 78.443 0.01
0.001 513.150 4.6518 4.6356 0.35 79.220 79.263 -0.05
0.001 513.150 5.3836 5.4413 -1.06 80.730 80.658 0.09
0.001 513.150 6.0682 6.3603 -4.59 81.420 81.277 0.18

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 823

Table 9[, Comparison of ID code (67) Zubarev PpT data with· values calculated
from Eq. (6) - Continued

Wt. T p Calc. p ~p/p P Calc. P ~P/P

K molll molll % bar bar %

0.001 513.150 6.4018 6.5921 -2.89 81.500 81.436 0.08

0.001 513.150 7.2511 7.1304 1.69 81.610 81.625 -0.02
0.000 513.150 7.8969 9.6737 -18.37 81.820 81.678 0.17
0.000 513.150 8.2958 9.7322 -14.76 81.830 81.701 0.16
0.001 513.150 9.1040 9.8364 -7.45 81.850 81.754 0.12
0.001 513.150 9.7284 10.4656 -7.04 82.060 81. 829 0.28
0.001 513.150 10.1922 10.6107 -3.94 82.140 81.946 0.24
0.001 513.150 10.9735 11.1861 -1.90 82.650 82.419 0.28
0.001 513.150 11.5545 11.6584 -0.89 83.410 83.208 0.24
0.001 513.150 13.3943 13.4266 -0.24 92.300 92.001 0.33
0.001 513.150 15.2171 15.2362 -0.13 124.220 123.679 0.44
0.001 513.150 17.0614 17.0866 -0.15 208.600 206.932 0.81
0.001 514.150 6.2693 6.1712 1.59 82.470 82.530 -0.07
0.001 514.150 8.1655 7.9503 2.71 83.020 83.056 -0.04
0.001 514.150 10.0608 10.0057 0.55 83.490 83.514 -0.03
0.001 514.150 11.9573 11.9099 0.4.0 86.030 86_172 -0.16
0.001 514.150 13.8582 13.8488 0.07 99.670 99.793 -0.12
0.001 514.150 15.6741 15.7663 -0.58 145.290 141. 892 2.40
0.001 517.950 2.6766 2.6689 0.29 69.240 69.334 -0.14
0.001 517.950 3.0477 3.0538 -0.20 73.470 73.411 0.08
0.001 517 .. 1:150 :S.:l914 6.3297 -1.15 75.980 7:;.655 0.43
0.001 517.950 3.9792 3.9661 0.33 80.400 80.474 -0.09
0.001 517;950 4.5427 4.5253 0;38 83.040 83.107 -0.08
0.001 517.950 4.9357 4.8977 0.78 84.310 84.422 -0.13
0.001 517.950 5.0970 5.2054 -2.08 85.130 84.862 0.32
0.001 517.950 5.7955 5.8253 -0.51 86.310 86.265 0.05
0.001 517~950 6.3952 6.4732 -1.21 87.090 87.013 0.09
0.001 517.950 6.8275 6.9206 -1.35 87.470 87;398 0.08
0.001 517.950 6.9896 7.4296 -5.92 87.820 87.521 0.34
0.001 517.950 7.6137 7.9322 -4.02 88.130 87;935 0.22
0.001 517.950 8.2650 8.4198 -1.84 88.430 88.333 0.11
0.001 517.950 8.8888 9.1488 -2.84 88.920 88.736 0.21
o.ooi 517.950 9.4314 9.6773 -2.54 89.350 89.138 0.24
0.001 517.950 10.7802 10.9427 -1.48 91.070 90.760 0.34
0.001 517.950 11.2545 11. 3252 -0.62 91.960 91.776 0.20
0.001 517.950 13.0733 13.0975 -0.18 101.480 101.257 0.22
0.001 517.950 14.8989 14.9139 -0.10 131.830 131.435 0.30
0.001 517.950 16.7401 16.7627 -0.13 209.570 208.195 0.66
0.001 523.150 0.2972 0.2967 0.17 12.326 12.346 -0.16
0.001 523.150 0.8801 0.8690 1.28 33.032 33.388 -1.07
0.001 523.150 1.1279 1.1147 1.19 40.472 40.849 -0.92
0;001 523.150 1.1839 1.1703 1.17 42.040 42.419 -0.89
0.001 523.150 1.7946 1.7865 0.46 56.852 57~019 -0.29
0.001 523.150 2.9387 2.9327 0.20 74.880 74.949 -0.09
0.001 523.150 3.4719 3.4419 0.87 80.100 80.366 .;.0.33
0.001 523.150 3.5810 3.5571 0.67 81.100 81.300 -0.25
0.001 523.150 4.7999 4.7657 0.72 88.510 88.654 -0.16
0.001 523.150 5.2744 5.1876 1.67 90.100 90.381 -0.31
0.001 523.1S0 S.4116 5.3255 1.62 90.540 90.798 -0.28
0.001 523.150 6.6736 6.7180 -0.66 93.550 93;481 0.07
0.001 523.150 7.2470 7.1892 0.81 94.230 94.308 -0.08
0.001 523.150 8.5470 8.6473 -1.16 96.150 96.013 0.14
0.001 523.150 9.0003 9.1702 -1.85 96.910 96.654 0.27
0.001 523.150 10.4345 10.4888 -0.52 99.500 99.362 0.14
0.001 523.150 10.8153 10.8163 -0.01 100.420 100.417 0.00
0.001 523.150 12.6376 12.6406 -0.02 110.240 110.214 0.02
0.001 523.150 14.4652 14.4870 -0.15 138.300 137.787 0.37
0.001 523.150 16.3021 16.32>19 -0.14 206.880 205.652 0_60
0.001 523.150 16.3388 16.3823 -0.27 210.020 207.631 1.15
0.001 533.150 1.3796 1.3654 1.04 49.050 49.434 -0.78
0.001 533.150 2.3607 2.3520 0.37 70.720 70~873 -0.22
0.001 533.150 3.1131 3.1053 0.25 82.050 82.149 -0.12
0.001 533.150 3.1979 3.1957 0.07 83.180 83.208 -0.03
0.001 533.150 4.1407 4.1113 0.72 92.450 92.691 -0.26
0.001 533.150 4.4205 4.3696 1.17 94.460 94.830 -0.39
0.001 533.150 4.9428 4.8702 1.49 97.760 98.181 -0.43
0.001 533.150 5.0142 4.9530 1.24 98.240 98.584 -0.35
0.001 533.150 5.9502 5.9086 0.70 . 102.730 102.890 -0.16
0.001 533.150 6.7826 6.6502 1.99 105.300 105.709 -0.39
0.000 533.150 6.2480 6.7666 -7.66 105.660 103.976 1.62

J.Phys. Chem. Ref. Data, Yol~ 16, No.4, 1987

824 ROBERT D. GOODWIN

Table 9f. Comparison of ID code (67) Zubarev l'/IT data with values calculated
[rom Eq. (6) - Continued

Wt. T (I Calc. f' ~1'/f' J) Calc. P f:lP/P

K molll molll % bar bar %
0.001 533.150 7.7662 7.8442 -0.99 108.760 108.541 0.20
0.001 533.150 9.5867 9.6327 -0.48 114.360 114.191 0.15
0.001 533.150 11.4092 11.4015 0.07 123.390 123.444 -0.04
0.001 533.150 13.2341 13.2105 0.18 143.260 143.644 -0.27
0.001 533.150 15.0672 15.0626 0.03 189.800 189.969 -0.09
o OOt 543 l50 o &671 O.R"')Q i OR \4 .4£1'1 .14.794 -O.'H
0.001 543.150 1.1645 1.1524 1.05 44.421 44.797 -:0.84
0.001 543. ISO 1.7702 1.7552 0.86 61.170 61.539 -0.60
0.001 543.150 2.0044 1.9850 0.98 66.570 67.004 -0.65
0.001 543.150 2.8843 2.8858 -0.05 83.690 83.667 0.03
0.001 543.150 3.7990 3.7913 0.20 96.020 96.108 -0;09
0.001 543.150 4.7315 4.6983 0.71 104.920 105.194 -0.26
0.001 543.150 5.4810 5.4627 0.33 110.520 110.637 -0.11
0.001 543.150 5.6630 5.6101 0.94 111.450 111.774 -0.29
0.001 543.150 6.5976 6.5613 0.55 116.660 116.839 -0.15
0.001 543.150 7.3021 7.3073 -0.07 120.180 120.156 0.02
0.001 543.150 7.5225 7.5328 -0.14 121.210 121.163 0.04
0.001 543.150 8.4783 8.4702 0.10 125.570 125.609 -0.03
0.001 543.150 9.1296 9.0970 0.36 128.720 128.892 -0.13
0.001 543.150 9.3954 9.3939 0.02 130.330 130.338 -0.01
0.001 543.150 10.3601 10.3210 0.38 136.130 136.407 -0.20
0.001 543.150 10.9600 10.8915 0.63 140.540 141.127 -0.42
0.001 543.150 12.2401 12.1952 0.37 154.580 155.196 -0.40
0.001 543.150 12.8014 12.7405 0.48 162.840 163.878 -0.63
0.001 543.150 14.6526 14.6356 0.12 210.200 210. ~U~ -U.29
0.00] 553. ]50 2.4230 2.4148 0.34 78.970 79.143 -0.22
0.001 553.150 4.1178 4.1189 -0.03 106.400 106.387 0.01
0.001 553.150 5.8784 5.8670 0.19 123.240 123.327 -0.07
0.001 553.150 7.6569 7.6719 -0.20 135.540 135.442 0.07
0.001 553.150 9.4489 9.4186 0.32 147.830 148.070 -0.16
0.001 553.150 11.2512 11. ]722 0.71 165.010 165.997 -0.59
0.001 563.150 1.6297 1.6123 1.08 61.680 62.189 -0.82
0.001 563.150 3.2748 3.2886 -0.42 99.860 99.614 0.25
0.001 563.150 5.0142 5.0228 -0.17 124.540 124.442 0.08
0.001 563.150 6.7913 6.8096 -0.27 141.930 141.771 0.11
0.001 563.150 8.5823 8.5929 -0.12 157.520 157.422 0.06
0.001 563.150 10.3859 10.3239 0.60 175.860 176.640 -0.44
0.001 563.150 12.2023 12.1004 0.84 204.020 206.105 -1.01
0.001 573.150 1.4342 1.4199 1.01 57.540 58.007 -0.81
0.001 573.150 3.0507 3.0654 -0.48 100.230 99.926 0.30
0.001 573.150 3.9555 3.9826 -0.68 117.260 116.806 0.39
0.001 573.150 4.7661 4.7662 -0.00 129.290 129.289 0.00
0.001 573.150 5.7222 5.6990 0.41 141.400 141.677 -0.20
0.00] 573.150 6.5294 6.5050 0.38 150.610 150.878 -0.18
0.001 573.150 7.4904 7.4469 0.58 160.780 161.248 -0.29
0.001 573.150 8.3145 8.2491 0.79 169.590 170.330 -0.43
0.001 573.150 9.2748 9.1742 1.10 180.540 181.809 -0.70
0.001 573.150 10.1143 9.9901 1.24 191.460 193.267 -0.94
0.001 573.150 11.0810 10.9221 1.45 206.250 209.097 -1.36

189 data points. ILlp/pl rros = 1.438%, Llp/ p avo = -0.100/0, If:lP/ PI avo = 0.46%,
weight = 0.07% .

.I. Phys. Chem. Ref. Doto, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 825

Table 9g. Comparison of ID code (68) Kudchadker PpT data with values
calculated from Eq. (6)

Wt. T p Calc. p tlp/p P Calc. P tlP/P

K molll molll % bar bar %

0.001 298.150 0.0021 0.0021 -0.84 0.051 0.050 0.84

0.001 298.150 0.0025 0.0025 -0.52 0.061 0.060 0.52
0.001 298.150 0.0029 0.0029 -0.04 0.071 0.071 0.04
0.001 298.150 0.0034 0.0033 0.58 0.081 0.082 -0.57
0.001 298.150 0.0038 0.0038 1.43 0.091 0.092 -1.40
0.001 298.150 0.0043 0.0042 2.54 0.101 0.104 -2.45
0.001 298.150 0.0048 0.0046 3.96 0.111 0.116 -3.77
0.001 298.150 0.0053 0.0050 5.87 0.122 0.129 -5.49
0.001 298.150 0.0059 0.0054 8.26 0.132 0.142 -7.55
0.001 298.150 0.0065 0.0059 11.28 0.142 0.158 -10.02
0.001 323.150 0.0023 0.0023 -1.17 0.061 0.060 1.18
0.001 323.150 0.0030 0.0031 -1.08 0.081 0.080 1.08
0.001 323.150 0.0038 0.0038 -0.87 0.101 0.100 0.87
0.001 323.150 0.0058 0.0058 0.19 0.152 0.152 -0.18
0.001 323.150 0.0079 0.0077 2.30 0.203 0.207 -2.23
0_001 :n:l_150 0_010:l 0.0097 5.98 0.253 0.268 -5.57
0.001 323.150 0.0130 0.0116 11.95 0.304 0.340 -10.51
0.001 323.150 0.0165 0.0136 21.53 0.355 0.429 -17.39
0.001 323.150 0.0214 0.0156 37.02 0.405 0.551 -26.43
0.001 323.150 0.0288 0.0176 63.89 0.456 0.738 -38.21
0.000 323.150 0.0425 0.0196 116.95 0.507 1.075 -52.88
0.001 348.150 0.0021 0.0021 -1. 21 0.061 0.060 1.22
0.001 348.150 0.0035 0.0036 -1.28 0.101 0.100 1.29
0.001 348.150 0.0071 0.0071 -1.15 0.203 0.200 1.16
0.001 348.150 0.0144 0.0144 0.14 0.405 0.406 -0.14
0.001 348.150 0.0183 0.0180 1.51 0.507 0.514 -1.46
0.001 348.150 0.0225 0.0217 3.54 0.608 0.629 -3.36
0.001 348.150 0.0322 0.0291 10.47 0.811 0.893 -9.21
0.001 348.150 0.0455 0.0367 23.91 1.013 1.245 -18.59
0.001 348.150 0.0546 0.0405 34.83 1.115 1.481 -24.74
0.001 348.150 0.0669 0.0444 50.68 1.216 1.796 -32.30
0.001 373.150 0.0020 0.0020 -1.15 0.061 0.060 1.16
0.001 373.150 0.0033 0.0033 -1.22 0.101 0.100 1.23
0.001 373.150 0.0066 0.0066 -1.26 0.203 0.200 1.27
0.001 373.150 0.0132 0.0134 -1.13 0.405 0.401 1.13
0.001 373.150 0.0200 0.0201 -0.79 0.608 0.603 0.79
0.001 373.150 0.0269 0.0269 -0.27 0.811 0.808 0.26
0.001 373.150 0.0340 0.0338 0.45 1.013 1.018 -0.44
0.001 373.150 0.0413 0.0408 1.36 1.216 1.232 -1.31
0.001 373.150 0.0490 0.0478 2.48 1.419 1.453 -2.34
0.001 373.150 0.0570 0.0549 3.80 1.621 1.680 -3.52
0.001 373.150 0.0654 0.0620 5.36 1.824 1.917 -4.87
0.001 373.150 0.0742 0.0693 7.16 2.027 2.164 -6.35
0.001 398.150 0.0031 0.0031 -1.19 0.101 0.100 1.20
0.001 398.150 0.0154 0.0156 -1.38 0.507 0.500 1.38
0.001 398.150 0.0311 0.0315 -1.11 1.013 1.002 1.11
0.001 398.150 0.0473 0.0476 -0.59 1.520 1.511 0.58
0.001 398.150 0.0640 0.0639 0.19 2.027 2.030 -0.18
0.001 398.150 0.0815 0.0805 1.23 2.533 2.563 -1.17
0.001 398.150 0.1005 0;0974 3.12 3.040 3.130 -2.88
0.001 398.150 0.1194 0.1147 4.09 3.546 3.682 -3.69
0.001 398.150 0.1402 0.1323 5.98 4.053 4.277 -5.23
0.001 398.150 0.1627 0.1503 8.22 4.560 4.899 -6.93
0.001 398.150 0.1872 0.1689 10.84 5.066 5.553 -8.77
0.001 398.150 0.2141 0.1879 13.94 5.573 6.244 -10.75
0.001 398.150 0.2440 0.2076 17.55 6.080 6.973 -12.81
0.001 398.150 0.2570 0.2156 19.19 6.282 7.277 -13.67
0.001 423.150 0.0590 0.0596 -1.04 2.027 2.006 1.03
0.001 423.150 0.0899 0.0903 -0.48 3.040 3.026 0.47
0.001 423.150 0.1220 0.1217 0.28 4.053 4.064 -0.27
0.001 423.150 0.1559 0.1539 1.26 5.066 5.127 -1.18
D.OOI 423.150 0.1916 0.1871 2.43 6.080 6.216 -2.19
0.001 423.150 0.2298 0.2213 3.85 7.093 7.339 -3.36
0.001 423.150 0.2711 0.2569 5.55 8.106 8.502 -4.65
0.001 423.150 0.3160 0.2939 7.52 9.119 9.703 -6.01
0.001 423.150 0.3652 0.3327 9.78 10.133 10.943 -7.41
0.001 423.150 0.4200 0.3736 12.44 11.146 12.227 -8.84
0.001 423.150 0.4815 0.4170 15.47 12.159 13.540 -10.20
0.001 448.150 0.0068 0.0069 -1.20 0.253 0.250 1.21
0.001 448.150 0.0136 0.0138 -1.33 0.507 0.500 1.34

J. Phys. Chem. Ref. Data, Val. 16, No. 4, 1987

826 ROBERT D. GOODWIN

Table 9g. Comparison of ID code (68) Kudchadker PpT data with values
calculated from Eq. (6) - Continued

Wt. T (' Calc. " fj,rlp P Calc. P fj,P/P

K molll molll % bar bar %

(LOOI 448.150 0.0274 0.0278 -1 .41 1.013 0.999 1.42

0.001 448.150 0.0552 0.0560 -1.28 2.027 2.001 1.28
0.001 448.150 0.0836 0.0845 -1.08 3.040 3.008 1.07
0.001 448.150 0.1123 0.1134 -0.97 4.053 4.015 0.95
(LOO1 448.150 0.1418 0.1428 -0.70 5.066 5.032 0.68
0.001 448.150 0.1720 0.1727 -0.43 6.080 6.055 0.41
0.001 448.150 0.2029 0.2032 -0.15 7.093 7.083 0.14
0.001 448.150 0.2346 0.2342 0.15 8.106 8.117 -0.14
0.001 448.150 0.2671 0.2660 0.43 9.119 9.155 -0.39
0.001 448.150 0.3005 0.2985 0.66 10.133 10.193 -0.59
0.001 448.150 0.3706 0.3662 1.20 12.159 12.287 -1.04
0.001 448.150 0.4451 0.4380 1.62 14.186 14.378 -1.34
0.001 448.150 0.5246 0.5151 1. 84 16.212 16.451 -1.45
0.001 448.150 0.6095 0.5988 1. 78 18.239 18.484 -1.33
0.001 448.150 0.6540 0.6438 1.59 19.252 19.475 -1.15
0.001 448.150 0.7002 0.6912 1.30 20.265 20.451 -0.91
0.001 473.150 0.0129 0.0131 -1.33 0.507 0.500 1.34
0.001 473.150 0.0259 0.0263 -1.45 1.013 0.999 1.46
0.001 473.150 0.0520 0.0528 -1.51 2.027 1.996 1. 52
0.001 473.150 0.1051 0.1066 -1.44 4.053 3.996 1.44
0.001 473.150 0.1595 0.1614 1. 21 6.080 6.008 1.18
0.001 473.150 0.2154 0.2176 -0.98 8.106 8.030 0.94
0.001 473.150 0.2732 0.2752 -0.72 10.133 10.064 0.68
0.001 473.150 0.3329 0.3346 -0.51 12.159 12.102 0.47
0.001 473.150 0.3949 0.3961 -0.30 14.186 14.146 0.28
0.001 473.150 0.4594 0.4599 -0.11 16.212 16.197 0.10
0.001 473.150 0.5269 0.5265 0.07 18.239 18.250 -0.06
0.001 473.150 0.5979 0.5963 0.27 20.265 20.311 -0.23
0.001 473.150 0.7919 0.7884 0.44 25.331 25.417 -0.34
0.001 473.150 1.0180 1.0162 0.18 30.398 30.435 -0.12
0.001 473.150 1.1201 1.1219 -0.16 32.424 32.391 0.10
0.001 473.150 1.2304 1.2395 -0.73 34.451 34.303 0.43
0.001 473. 1~0 1.5572 1.6280 -4.35 39.618 38.838 2.01

103 data points, Ifj,p/ pi rms = 11.172%, fj,p/p avo = 4.25%, Ifj,P/PI avo = 3.92%,
weight = 0.04%.

Table 9h. Comparison of II) code (69) virial equation P"T data with values
calculated from Eq. (6)

Wt. T (' Calc. " L:J.p/p jl Calc. P fj,P/P

K moIll moIlI % bar bar %
1.000 430.000 0.2000 0.2025 1.23 6.690 6.614 1.16
1.000 450.000 0.2000 0.2017 -0.86 7.083 7.025 0.82
1.000 470.000 0.2000 0.2010 -0.51 7.453 7.417 0.49
1.000 490.000 0.2000 0.2005 -0.27 7.814 7.794 0.26
1.000 510.000 0.20()O 0.2003 -0.16 8.17-1 8.161 0.16
t.OOO 530.000 0.2000 0.2004 -0.19 8.535 8.519 0.19
1.000 550.000 0.2000 0.2007 -0.34 8.902 8.872 0.34
1.000 570.000 0.20()O 0.2012 -0.60 9.275 9.220 0.60
1.000 430.000 0.4000 0.4055 -1. 37 12.303 12.167 1.12
1.000 450.000 0.4000 0.4027 -0.67 13.299 13.222 0.58
1.000 470.000 0.4000 0.3994 0.14 14.153 14.170 -0.12
1.000 490.000 0.4000 0.3971 0.73 14.948 15.048 -0.66
1.000 510.000 0.4000 0.3960 1.01 15.727 15.876 -0.94
1.000 530.000 0.4000 0.3961 0.99 16.513 16.668 -0.93
1.000 550.000 0.4000 0.3972 0.71 17.316 17.433 -0.67
1.000 570.000 0.4000 0.3992 0.19 18.143 18.177 -0.18

16 data poin t..<;, Ifj,p/ pi rms = 0.7 30o/(), fj,l'lp avo = -0.15%, Ifj,P/PI avo = 0.58%,
weight = 6.15%.

J. Phy•. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 827

Table 9i. Comparison of ID code (70) Finkelstein PpT data with values calculated
from Eq. (6)

Wt. T f' Calc. p LJ.plp P Calc. P LJ.PIP

K molll mol/i % bar bar %

0.001 473.150 16.9170 18.0422 -6.24 86.184 25.969 231.87

0.001 473.150 17.5729 18.2842 -3.89 103.421 58.410 77.06
0.001 473.150 18.7144 18.6972 0.09 137.895 139.476 -1.13
0.001 473.150 18.9471 18.8429 0.55 151.685 162.091 -6.42
0.001 473.150 19.1454 18.9800 0.87 165.474 183.224 -9.69
0.001 473.150 19.3165 19.1095 1.08 179.264 202.894 -11. 65
0.001 473.150 19.4657 19.2324 1.21 193.053 221.168 -12.71
0.001 473.150 19.5968 19.3495 1.28 206.843 238.138 -13.14
0.001 473.150 19.7199 19.4614 1.33 220.632 254.865 -13.43
0.001 473.150 19.8166 19.5686 1.27 234.422 268.563 -12.71
0.001 473.150 19.9097 19.6716 1.21 248.211 282.212 -12.05
0.001 473.150 19.9997 19.7707 1.16 262.001 295.864 -11.45
0.001 473.150 20.0757 19.8663 1.05 275.790 307.734 -10.38
0.001 473.150 20.1449 19.9586 0.93 289.580 318.837 -9.18
0.001 473.150 20.2082 20.0480 0.80 303.369 329.238 -7.86
0.001 473.150 20.2664 20.1345 0.66 317.159 338.998 -6.44
0.001 473.150 20.3201 20.2185 0.50 330.948 348.172 -4.95
0.001 473.150 20.3744 20.3001 0.37 344.738 357.640 -3.61
0.001 473.150 20.4831 20.4945 -0.06 379.212 377.115 0.56
0.001 473.150 20.5745 20.6769 -0.50 413.685 394.071 4.98
0.001 473.150 20.6525 20.8489 -0.94 448.159 408.954 9.59
0.001 473.150 20.7199 21.0117 -1.39 482.633 422.116 14.34
0.001 473.150 20.7786 21.1665 -1.83 517.107 433.835 19.19
0.001 473.150 20.8302 21.3141 -2.27 551.581 444.331 24.14
0.001 473.150 20.8760 21.4552 -2.70 586.054 453.786 29.15
0.001 473.150 20.9169 21.5905 -3.12 620.528 462.344 34.21
0.001 473.150 20.9325 21.7205 -3.63 655.002 465.647 40.66
0.001 473.150 20.9893 21. 8457 -3.92 689.476 477.777 44.31
0.001 493.150 15.8038 16.3337 -3.24 86.184 70.122 22.91
0.001 493.150 16.6378 16.7625 -0.74 103.421 97.980 5.55
0.001 493.150 17.4071 17.4084 -0.01 137.895 137.817 0.06
0.001 493.150 17.6496 17.6195 0.17 151.685 153.764 -1.35
0.001 493.150 17.8648 17.8122 0.30 165.474 169.442 -2.34
0.001 493.150 18.0660 17.9901 0.42 179.264 185.474 -3.35
0.001 493.150 18.2491 18.1555 0.52 193.053 201.291 -4.09
0.001 493.150 18.4176 18.3103 0.59 206.843 216.919 -4.65
0.001 493.150 18.5740 18.4560 0.64 220.632 232.392 -5.06
0.001 493.150 18.7203 18.5938 0.68 234.422 247.747 -5.38
0.001 493.150 18.8582 18.7246 0.71 248.211 263.021 -5.63
0.001 493.150 18.9947 18.8493 0.77 262.001 278.924 -6.07
0.001 493.150 19.1191 18.9683 0.80 275.790 294.146 -6.24
0.001 493.150 19.2331 19.0824 0.79 289.580 308.708 -6.20
0.001 493.150 19.3481 19.1919 0.81 303.369 324.001 -6.37
0.001 493.150 19.4543 19.2973 0.81 317.159 338.685 -6.36
0.001 493.150 19.5574 19.3988 0.82 330.948 353.473 -6.37
0.001 493.150 19.6578 19.4969 0.83 344.738 368.389 -6.42
0.001 493.150 19.8805 19.7285 0.77 379.212 403.341 .-5.98
0.001 49:1.1~0 20.0R19 19.94:1:1 0.h9 411.hR5 417.270 -5.19
0.001 493.150 20.2594 20.1439 0.57 448.159 469.059 -4.46
0.001 493.150 20.4140 20.3321 0.40 482.633 498.272 -3.14
0.001 493.150 20.5432 20.5098 0.16 517.107 523.807 -1.28
0.001 493.150 20.6576 20.6780 -0.10 551.581 547.295 0.78
0.001 493.150 20.7596 20.8380 -0.38 586.054 568.949 3.01
0.001 493.150 20.8511 20.9905 -0.66 620.528 588.963 5.36
0.001 493.150 20.9337 21;1363 -0.96 655.002 607.505 7.82
0.001 493.150 21.0086 21. 2761 -1.26 689.476 624.722 10.37
0.001 513.150 12.3320 12.5251 -1.54 86.184 85.363 0.96
0.001 513.150 13.8276 14.2980 -3.29 103.421 96.632 7.03
0.001 513.150 15.2668 15.6666 -2.55 137.895 125.095 to.23
0.001 513.150 15.8219 16.0241 -1.26 151.685 143.595 5.63
0.001 513.150 16.2547 16.3304 -0.46 165.474 161. 886 2.22
0.001 513.150 16.6070 16.5997 0.04 179.264 179.662 -0.22
0.001 513.150 16.9087 16.8409 0.40 193.053 197.188 -2.10
0.001 513.150 17.1609 17.0600 0.59 206.843 213.622 -3.17
0.001 513.150 17.3762 17.2612 0.67 220.632 229.027 -3.67
0.001 513.150 17.5651 17.4475 0.67 234.422 243.653 -3.79
0.001 513.150 17.7311 17.6213 0.62 248.211 257.408 -3.57
0.001 513.150 17.8822 17.7842 0.55 262.001 270.706 -3.22
0.001 513.150 18.0255 17.9379 0.49 275.790 284.015 -2.90
0.001 513.150 18.1572 18.0833 0.41 289.580 296.868 -2.46

J. Phys. Chern. Ref_ Oata, Vol. 18, No. ',1Da7

828 ROBERT D. GOODWIN

Table 9i. Comparison of ID code (70) Finkelstein PpT data with values calculated
from Eq. (6) - Continued

Wt. T p Calc. p ~plp P Calc. P ~pIP

K molll molll % bar bar 0/0

0.001 513.150 18.2832 18.2215 0.34 303.369 309.758 -2.06

0.001 513.150 18.4090 18.3532 0.30 317.159 323.202 -1.87
0.001 513.150 18.5302 18.4790 0.28 330.948 336.735 -1.72
0.001 513.150 18.6518 18.5996 0.28 344.738 350.885 -1.75
0.001 513.150 18.9549 18.8810 0.39 379.212 388.821 -2.47
0.001 513.150 19.2494 19.1381 0.58 413.685 429.534 -3.69
0.001 513.150 19.5204 19.3753 0.75 448.159 470.579 -4.76
0.001 513.150 19.7554 19.5957 0.81 482.633 509.136 -5.21
0.001 513.150 19.9439 19.8019 0.72 517.107 542.182 -4.62
0.001 513.150 20.0900 19.9956 0.47 551.581 569.130 -3.08
0.001 513.150 20.2207 20.1785 0.21 586.054 594.271 -1. 38
0.001 513.150 20.4010 20.3519 0.24 620.528 630.627 -1.60
0.001 513 .150 20.6481 20.5168 0.64 655.002 683.692 -4.20
0.001 513.150 20.8380 20.6740 0.79 689.476 727.147 -5.18
0.001 533.150 6.1656 6.0924 1.20 103.421 103.685 -0.25
0.001 533.150 12.7542 12.8506 -0.75 137.895 136.602 0.95
0.001 533.150 13.4400 13.6778 -1.74 1:51.68:5 147.173 3.07
0.001 533.150 13.9756 14.2788 -2.12 165.474 158.060 4.69
0.001 533.150 14.4634 14.7544 -1.97 179.264 170.495 5.14
0.001 533.150 14.8992 15.1503 -1.66 193.053 184.046 4.89
0.001 533.150 15.2887 15.4908 -1.30 206.843 198.431 4.24
0.001 533.150 15.6466 15.7906 -0.91 220.632 213.806 3.19
0.001 533.150 15.9718 16.0590 -0.54 234.422 229.783 2.02
0.001 533.150 16.2629 16.3026 -0.24 248.211 245.879 0.95
0.001 533.150 16.5326 16.5259 0.04 262.001 262.433 -0.16
0.001 533.150 16.7740 16.7323 0.25 275.790 278.703 1.05
0.001 533.150 16.9986 16.9245 0.44 289.580 295.155 -1.89
0.001 533.150 17.2037 17.1044 0.58 303.369 311. 361 -2.57
0.001 533.150 17.3953 17.2737 0.70 317.159 327.578 -3.18
0.001 533.150 17.5707 17.4336 0.79 330.948 343.373 -3.62
0.001 533.150 17.7311 17.5853 0.83 344.738 358.661 -3.88
0.001 533.150 18.0895 17.9340 0.87 379.212 395.901 -4.22
0.001 533.150 18.3958 18.2470 0.82 413.685 431.338 -4.09
0.001 533.150 18.6598 18.5314 0.69 448.159 464.759 -3.57
0.001 533.150 18.8988 18.7926 0.57 482.633 497.468 -2.98
0.001 533.150 19.1140 19.0342 0.42 517.107 529.050 -2.26
0.001 533.150 19.3184 19.2594 0.31 551.581 560.999 -1.68
0.001 533.150 19.5167 19.4703 0.24 586.054 593.932 -1.33
0.001 533.150 19.7104 19.6689 0.21 620.528 627.992 -1.19
0.001 533.150 19.9084 19.8566 0.26 655.002 664.858 -1.48
0.001 533.150 20.1082 20.0346 0.37 689.476 704.255 -2.10
0.001 553.150 7.8943 8.0304 -1.70 137.895 136.996 0.66
0.001 553.150 9.6014 9.8830 -2.85 151.685 149.303 1.59
0.001 553.150 11.1322 11.2096 -0.69 165.474 164.520 0.58
0.001 :5:53.1:50 12.31:51 12.1:57:5 1.30 179.264 182.003 -1.50
0.001 553.150 13.0117 12.8767 1.05 193.053 196.046 -1.53
0.001 553.150 13.5057 13.4517 0.40 206.843 208.285 -0.69
0.001 553.150 13.9414 13.9299 0.08 220.632 220.991 -0.16
0.001 553.150 14.3256 14.3393 -0.10 234.422 233.928 0.21
0.001 553.150 14.6694 14.6974 -0.19 248.211 247.070 0.46
0.001 553.150 14.9834 15.0160 -0.22 262.001 260.519 0.57
0.001 553.150 15.2700 15.3033 -0.22 275.790 274.121 0.61
0.001 553.150 15.5389 15.5651 -0.17 289.580 288.142 0.50
0.001 553.150 15.7955 15.8058 -0.07 303.369 302.752 0.20
0.001 553.150 16.0335 16.0287 0.03 317.159 317.464 -0.10
0.001 553.150 16.2618 16.2365 0.16 330.948 332.691 -0.52
0.001 553.150 16.4812 16.4311 0.31 344.738 348.431 -1.06
0.001 553.150 16.9725 16.8704 0.60 379.212 387.925 -2.25
0.001 ::5:53.1:50 17.3846 17.2::564 0.74 413.68;5 426.077 -2.91
0.001 553.150 17.7074 17.6013 0.60 448.159 459.507 -2.47
0.001 553.150 17.9322 17.9136 0.10 482.633 484.795 -0.45
0.001 553.150 18.0734 18.1992 -0.69 517.107 501.569 3.10
0.001 553.150 18.1768 18.4627 -1.55 551.581 514.296 7.25
0.001 553.150 18.2978 18.7075 -2.19 586.054 529.701 10.64
0.001 553.150 18.5332 18.9362 -2.13 620.528 561.260 10.56
0.001 553.150 18.6532 19.1510 -2.60 655.002 578.200 13.28
0.001 553.150 18.7861 19.3535 -2.93 689.476 597.649 15.36
0.001 573.150 6.5400 6.6031 -0.96 151.685 150.994 0.46
0.001 573.150 7.8295 7.8791 -0.63 165.474 164.930 0.33
0.001 573.150 9.0907 9.0715 0.21 179.264 179.501 -0.13

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 829

Table 9i. Comparison of lD code (70) Finkelstein PpT data with values calculated
from Eq. (6) - Continued

Wt. T p Calc. f' £lp/" P Calc. P £lP/P

K molll molll % bar bar %
0.001 573.150 9.9830 10.0997 -1.16 193.053 191.358 0.89
0.001 573.150 10.8865 10.9557 -0.63 206.843 205.627 0.59
0.001 573.150 11.7927 11.6679 1.07 220.632 223.318 -1.20
0.001 573.150 12.5266 12.2687 2.10 234.422 241.069 -2.76
0.001 573.150 13.1099 12.7843 2.55 248.211 258.017 -3.80
0.001 573.150 13.5718 13.2339 2.55 262.001 273.611 -4.24
0.001 573.150 13.9385 13.6316 2.25 275.790 287.587 -4.10
0.001 573.150 14.2444 13.9877 1. 83 289.580 300.454 -3.62
0.001 573.150 14.5111 14.3100 1.41 303.369 312.666 -2.97
0.001 573.150 14.7504 14.6041 1.00 317.159 324.475 -2.25
0.001 573.150 14.9800 14.8747 0.71 330.948 336.622 -1.69
0.001 573.150 15.2041 15.1252 0.52 344.738 349.294 -1.30
0.001 573.150 15.7450 15.6809 0.41 379.212 383.560 -1.13
0.001 573.150 16.2473 16.1588 0.55 413.685 420.609 -1.65
0.001 573.150 16.6655 16.5786 0.52 448.159 455.828 -1.68
0.001 573.150 16.9929 16.9533 0.23 "82.633 486.488 -0 79
0.001 573.150 17.3092 17.2921 0.10 517.107 518.938 -0.35
0.001 573.150 17.6066 17.6015 0.03 551.581 552.173 -0.11
0.001 573.150 17.8776 17.8864 -0.05 586.054 584.945 0.19
0.001 573.150 18.2066 18.1506 0.31 620.528 628.169 -1.22
0.001 573.150 18.4247 18.3970 U.l!:> 6:5:5.002 6!59.019 -0.61
0.001 573.150 18.6662 18.6280 0.21 689.476 695.397 -0.85

162 data points, ILl 1'11'1 rms = 1.313%, £lIlli' avo .. -0.05%, laP/PI avo = 6.87%,
"Wf"ight O.Ofl%.

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

830 ROBERT D. GOODWIN

Table 9j. Comparison of ID code (83) Machado PpT data with values calculated
from Eq. (6)

Wt. T P Calc. p LJp/p P Calc. P LJP/p

K molll molll % bar bar %

0.000 298.120 24.5621 24.5659 -0.02 5.140 3.929 30.82

0.000 298.120 24.5815 24.5869 -0.02 12.030 10.256 17.30
0.200 298.120 24.6028 24.6077 -0.02 18.920 17.289 9.43
0.200 298.120 24.6455 24.6496 -0.02 32.970 31.588 4.38
0.200 298.120 24.7060 24.7105 -0.02 53.830 52.263 3.00
0.200 298.120 24.7452 24.7467 -0.01 66.470 65.930 0.82
0.200 298.120 24.8378 24.8433 -0.02 101.080 99.067 2.03
0.200 298.120 25.1358 25.1482 -0.05 218.720 213.724 2.34
0.200 298.120 25.2865 25.2975 -0.04 280.920 276.237 1. 70
0.200 298.120 25.4536 25.4639 -0.04 353.660 349.054 1.32
0.200 298.120 25.6187 25.6186 0.00 424.610 424.629 -0.00
0.200 298.120 25.7561 25.7499 0.02 487.290 490.295 -0.61
0.200 298.120 26.0246 26.0232 0.01 625.060 625.774 -0.11
0.200 298.120 26.2721 26.2787 -0.03 762.840 759.172 0.48
0.200 298.120 26.5042 26.5195 -0.06 900.630 891.640 1.01
0.200 298.120 26.7152 26.7476 -0.12 1038.430 1018.390 1.97
O.OOU j},"2.,4U 2;'L ~416 23.~365 0.02 5.140 6.609 -22.23
0.000 322.540 23.8635 23.8604 0;01 12.030 12.927 -6.94
0.200 322.540 23.8854 23.8840 0.01 18.920 19.319 -2.06
0.200 322.540 23.9367 23.9315 0.02 32.970 34.522 -4.50
0.200 322.540 24.0085 24.0002 0.01 53.830 56.376 -4.5'
0.200 322.540 24.0473 24.0410 0.03 66.470 68.474 -2.93
0.200 322.540 24.1534 24.1491 0.02 101.080 102.485 -1.37
0.200 322.540 24.4985 24.4871 0.05 218.720 222.930 -1.89
0.200 322.540 24.6631 24.6510 0.05 280.920 285.618 -1.64
0.200 322 . .540 24.8.536 24.8324 0.09 3.53.660 362.418 -2.42
0.200 322.540 25.0170 25.0002 0.07 424.610 431.890 -1.69
0.200 322.540 25.1601 25.1419 0.07 487.290 495.540 -1.66
0.200 322.540 25.4536 25.4352 0.07 625.060 634.052 -1.42
0.200 322.540 25.7264 25.7077 0.07 762.840 772.614 -1.27
0.200 322.540 25.9747 25.9632 0.04 900.630 907.080 -0.71
0.200 322.540 26.2059 26.2043 0.01 1038.430 1039.417 -0.09
0.000 342.830 23.1948 23.2035 -0.04 5.140 2.950 74.22
0.200 342.830 23.2294 23.2307 -0.01 12.030 11. 701 2.81
0.200 342.830 23.2553 23.2574 -0.01 18.920 18.373 2.98
0.200 342.830 23.3127 23.3111 0.01 32.970 33.386 -1.25
0.200 342.830 23.3895 23.3885 0.00 53.830 54.123 -0.54
0.200 342.830 23.4422 23.4341 0.03 66.470 68.739 -3.30
0.200 342.830 23.5644 23.5549 0.04 101.080 103.854 -2.67
0.200 342.830 23.7220 23.7157 0.03 149.780 151.741 -1.29
0.200 342.830 23.9385 23.9281 0.04 218.720 222.251 -1.59
0.200 342.830 24.1198 24.1070 0.05 280.920 285.516 -1.61
0.200 342.830 24.3247 24.3038 0.09 353.660 361.684 -2.22
0.200 342.830 24.5120 24.4847 0.11 424.610 435.642 -2.53
0.200 342.830 24.6689 24.6368 0.13 487.290 500.873 -2.71
0.200 342.830 24.9909 24.9498 0.16 625.060 644.048 -2.95
0.200 342.830 25.2804 25.2386 0.17 762.840 783.620 -2.65
0.200 342.830 25.5474 25.5079 0.15 900.630 921.560 -2.27
0.200 342.830 25.7923 25.7610 0.12 1038.430 1055.989 -1.66
0.200 362.900 22.5382 22.5390 -0.00 5.140 4.971 3.39
0.200 362.900 22.5675 22.5704 -0.01 12 .030 11.394 5.59
0.200 362.900 22.6002 22.6014 -0.01 18.920 18.655 1.42
0.200 362.900 22.6642 22.6632 0.00 32.970 33.199 -0.69
0.200 362.900 22.1:5:51 22.1:51,0 0.01 :53.830 :54.:588 -1.39
0.200 362.900 22.8117 22.8041 0.03 66.470 68.333 -2.73
0.200 362.900 22.9577 22.9412 0.07 101.080 105.373 -4.07
0.200 362.900 23.1329 23.1221 0.05 149.780 152.822 -1.99
0.200 362.900 23.3773 23.3585 0.08 218.720 224.445 -2.55
0.200 362.900 23.5822 23.5559 0.11 280.920 289.504 -2.97
0.200 362.900 23.8089 23.7713 0.16 353.660 366.871 -3.60
0.200 362.900 24.0030 23.9680 0.15 424.610 437.693 -2.99
0.200 362.900 24.1834 24.1324 0.21 487.290 507.366 -3.96
0.200 362.900 24.5235 24.4683 0.23 625.060 648.977 -3.69
0.200 362.900 24.8318 24.7759 0.23 762.840 789.124 -"3.33
0.200 362.900 25.1176 25.0609 0.23 900.630 929.256 -3.08
0.200 362.900 25.3749 25.3273 0.19 1038.430 1063.970 -2.40
0.000 382.600 21.8854 21.8692 0.07 12.030 15.061 -20.13
0.000 382.600 21. 9193 21.9059 0.06 18.920 21.450 -11. 79
0.200 382.600 21. 9919 21.9789 0.06 32.970 35.516 -7.17
0.200 382.600 22.0993 22.0829 0.07 53.830 57.225 -5.93

J. Phys. Chem. Ref. Data, Vol. 16, NO.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 831

Table 9j. Comparison of ID code (83) Machado PpT data with values calculated
from Eq. (6) - Continued

Wt. T p Calc. p ,1p/p P Calc. P L1P/P

K molll molll % bar bar %
0.200 382.600 22.1637 22.1435 0.09 66.470 70.735 -6.03
0.200 382.600 22.3302 22.3020 0.13 101.080 107.488 -5.96
0.200 382.600 22.5415 22.5086 0.15 149.780 157.896 -5.14
0.200 382.600 22.8117 22.7753 0.16 218.720 228.650 -4.34
0.200 382.600 23.0373 22.9955 0.18 280.920 293.280 -4.21
0.200 382.600 23.2831 23.2334 0.21 353.660 369.579 -4.31
0.200 382.600 23.4969 23.4489 0.20 424.610 441.109 -3.74
0.200 382.600 23.6824 23.6278 0.23 487.290 507.091 -3.90
0.200 382.600 24.0548 23.9905 0.27 625.060 650.995 -3.98
0.200 382.600 24.3875 24.3196 0.28 762.840 792.815 -3.78
0.200 382.600 24.6884 24.6223 0.27 900.630 932.172 -3.38
0.200 382.600 24.9629 24.9037 0.24 1038.430 1068.646 -2.83
0.000 402.340 21.1083 21.0893 0.09 12.030 14.905 -19.29
0.000 402.340 21.1484 21.1345 0.07 18.920 21.058 -10.15
0.200 402.340 21.2390 21.2237 0.07 32.970 35.447 -6.99
0.200 402.340 21.3685 21.3494 0.09 53.830 57.100 -5.73
0.200 402.340 21.4433 21.4222 0.10 66.470 70.232 -5.36
0.200 402.340 21.6306 21.6100 0.10 101.080 105.050 -3.78
0.200 402.340 21.8778 21. 8513 0.12 149.780 155.429 -3.63
0.200 402.340 22.1873 22 .1575 0.13 218.720 225.871 -3.17
0.200 402.340 22.4377 22.4066 0.14 280.920 289.090 -2.83
0.200 402.340 22.7038 22.6727 0.14 353.660 362.599 -2.47
0.200 402.340 22.9442 22.9113 0.14 424.610 434.832 -2.35
0.200 402.340 23.1364 23.1078 0.12 487.290 496.706 1.90
0.200 402.340 23.5484 2.1.5026 0.19 1125.0110 642.101 -2.11<ii
0.200 402.340 23.9092 23.8569 0.22 762.840 784.311 -2.74
0.200 402.340 24.2341 24.1802 0.22 900.630 924.731 -2.61
0.200 402.340 24.5235 24.4787 0.18 1038.430 1060.000 -2:03
0.200 421.610 20.4112 20.3882 0.11 32.970 35.907 -8.18
0.200 421.610 20.5740 20.5460 0.14 53.830 57.690 -6.69
0.200 421.610 20.6652 20.6361 0.14 66.470 70.666 -5.94
0.200 421.610 20.8963 20.8653 0.15 101.080 106.044 -4.68
0.200 421.610 21.1785 21.1533 0.12 149.780 154.332 -2.95
0.200 421.610 21.5395 21.5108 0.13 218.720 224.696 -2.66
0.200 421.610 21.8181 21.7963 0.10 280.920 285.940 -1.76
0.200 421.610 22.1291 22.0971 0.14 353.660 361.860 -2.27
0.200 421.610 22.6182 22.5811 0.16 487.290 498.436 -2.24
0.200 421.610 23.0526 23.0133 0.17 625.060 638.511 -2.11
0.200 421.610 23.4334 23.3968 0.16 762.840 776.817 -1.80
0.200 421.610 23.7798 23.7434 0.15 900.630 915.875 -1.66
0.200 421.610 24.0845 24.0611 0.10 1038.430 1049.024 -1.01
0.200 441.900 19.3686 19.3436 0.13 32.970 35.273 -6.53
0.200 441. 900 19.5874 19.5591 0.14 53.830 56.748 -5.14
0.200 441.900 19.7161 19.6790 0.19 66.470 70.537 -5.77
0.200 441.900 20.0081 19.9757 0.16 101.080 105.153 -3.87
0.200 441. 900 20.3513 20.3357 0.08 149.780 152.062 -1.50
0.200 441. 900 20.7947 20.7678 0.13 218.720 223.412 -2.10
0.200 441. 900 21.1183 21.1041 0.07 280.920 283.727 -0.99
0.200 441.9UU 21.4669 21.4516 0.07 353.660 357.075 -0.96
0.200 441. 900 21. 7679 21. 7548 0.06 424.610 427.840 -0.76
0.200 441.900 22.0089 21.9996 0.04 487.290 489.774 -0.51
0.200 441. 900 22.4911 22.4795 0.05 625.060 628.641 -0.57
0.200 441.900 22.9138 22.8993 0.06 762.840 767.921 -0.66
0.200 441. 900 23.2866 23.2746 0.05 900.630 905.256 -0.51
0.200 441. 900 23.6143 23.6156 -0.01 1038.430 1037.880 0.05
0.200 463.060 18.2967 18.2677 0.16 53.830 55.764 -3.47
0.200 463.060 18.4623 18.4492 0.07 66.470 67.427 -1.42
0.200 463.060 18.8891 18.8734 0.08 101.080 102.511 -1.40
0.200 463.060 19.3494 19.3548 -0.03 149.780 149.173 0.41
0.200 463.060 19.9060 19.9017 0.02 218.720 219.331 -0.28
0.200 463.060 20.3089 20.3111 -0.01 280.920 280.554 0.13
0.200 463.060 20.7174 20.7233 -0.03 353.660 352.542 0.32
0.200 463.060 21.0599 21.0756 -0.07 424.610 421.263 0.79
0.200 463.060 21.3568 21.3560 0.00 487.290 487.469 -0.04
0.200 463.060 21.8701 21.8969 -0.12 625.060 617.691 1.19
0.200 463.060 22.3382 22.3620 -0.11 762.840 755.325 0.99
0.200 463.060 22.7369 22.7725 -0.16 900.630 888.037 1.42
0.200 463.060 23.0953 23.1418 -0.20 1038.430 1020.322 1. 77
0.200 478.620 17.0241 16.9749 0.29 53.830 55.809 -3.55
0.200 478.620 17.3102 17.2662 0.26 66.470 68.580 -3.08

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

832 ROBERT D. GOODWIN

Table 9j. Comparison of j)) code (83) Machado P{lT data with values calculated
from Eg. (6) - Continued

Wt. T (' Calc. (' fJ.('/ (l P Calc. P fJ.PIP

K molll mol/l % bar bar %
0.200 478.620 17.8897 17.8804 0.05 101.080 101.695 -0.60
0.200 478.620 18.5149 18.5130 0.01 149.780 149.943 -0.11
0.200 478.620 19.1912 19.1854 0.03 218.720 219.398 -0.31
0.200 478.620 19.6664 19.6685 -0.01 280.920 280.623 0.11
0.200 478.620 20.1242 20.1427 -0.09 353.660 350.596 0.87
0.200 478.620 20.5118 20.5405 -0.14 424.610 419.159 1.30
0.200 478.620 20.8335 20.8531 -0.09 487.290 483.180 0.85
0.200 478.620 21.4125 21.4478 -0.16 625.060 616.145 1.45
0.200 478.620 21.9023 21.9520 -0.23 762.840 748.348 1.94
0.200 478.620 22.3318 22.3925 -0.27 900.630 880.609 2.27
0.200 478.620 22.7121 22.7855 -0.32 1038.430 1011.565 2.66
0.200 488.860 15.7923 15.7259 0.42 53.830 55.278 -2.62
0.200 488.860 16.2765 16.2195 0.35 66.470 68.227 -2.57
0.200 488.860 17.0763 17.0894 -0.08 101.080 100.421 0.66
0.200 488.860 17.8795 17.8804 -0.01 149.780 149.713 0.04
0.200 488.860 18.6498 18.Mi68 -0.09 218.720 210.9R9 0.80
0.200 488.860 19.1805 19.2118 -0.16 280.920 276.997 1.42
0.200 488.860 19.6838 19.7357 -0.26 353.660 345.837 2.26
0.200 488.860 20.1126 20.1690 -0.28 424.610 414.773 2.37
0.200 488.860 20.4352 20.5062 -0.35 487.290 473.523 2.91
0.200 488.860 21.0627 21.1413 -0.37 625.060 606.531 3.05
0.200 488.860 21.5827 21.6743 -0.42 762.840 737.627 3.42
0.200 488.860 22.0384 22.1366 -0.44 900.630 869.879 3.54
0.200 488.860 22.4377 22.5467 -0.48 1038.430 1000.326 3.81

weight = 0.02%.

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 833

Table 9k. Comparison of ID code (87) Ramsay PpT data with values calculated
from Eq. (6)

Wt. T p Calc. p C:.p/p P Calc. P LJ.P/P

K molll molll % bar bar %

0.001 373.150 0.0691 0.0712 ~3.03 2.080 2.020 2.96

0.001 373.150 0.0779 0.0799 -2.44 2.318 2.265 2.35
0.001 373.150 0.0939 0.0960 -2.21 2.753 2.697 2.09
0.001 373.150 0.1106 0.1127 -1.87 3.188 3.134 1.72
0.001 373.150 0.1175 0.1182 -0.56 3.328 3.311 0.51
0.001 373.150 0.1254 0.1232 1. 75 3.454 3.508 -1.53
0.001 393.150 0.0690 0.0710 -2.79 2.210 2.151 2.77
0.001 393.150 0.0779 0.0800 -2.66 2.480 2.417 2.62
0.001 393.150 0.0939 0.0960 -2.20 2.949 2.887 2.14
0.001 393.150 0.1105 0.1132 -2.33 3.445 3.370 2.24
0.001 393.150 0.1253 0.1281 -2.19 3.866 3.788 2.07
0.001 393.150 0.1565 0.1594 -1.82 4.718 4.641 1.67
0.001 393.150 0.1873 0.1893 -1.06 5.493 5.442 0.93
0.001 393.150 0.2195 0.2200 -0.21 6.245 6.234 0.18
0.001 413.150 0.3068 0.3123 -1.77 9.186 9.052 1.48
0.001 413.150 0.3649 0.3697 -1.30 10.503 10.397 1.02
0.001 413.150 0.3791 0.3787 0.11 10.698 10.707 -0.08
0.001 413.150 0.4030 0.3801 6.02 10.727 11. 253 -4.68
0.001 433.150 0.0689 0.0708 -2.59 2.461 2.399 2.61
0.001 433.150 0.0938 0.0959 -2.27 3.312 3.239 2.26
0.001 433.150 0.1174 0.1200 -2.20 4.113 4.026 2.17
0.001 433.150 0.1563 0.1594 -1.94 5.398 5.299 1.88
0.001 433.150 0.1871 0.1900 -1.53 6.369 6.278 1.45
0.001 433.150 0.2326 0.2368 -1. 78 7.806 7.678 1.66
0.001 .<:133.150 0.3067 0.A125 -1. R6 10.006 9.843 1.66
0.001 433.150 0.3647 0.3716 -1.86 11.608 11.427 1.59
0.001 433.150 0.4496 0.4557 -1.35 13.708 13.562 1.08
0.001 433.150 0.5092 0.5153 -1.19 15.064 14.929 0.90
0.001 433.150 0.5864 0.5943 -1.33 16.689 16.536 0.93
0.001 433.150 0.6245 0.6259 -0.22 17.285 17.260 0.14
0.001 453.150 0.3065 0.3126 -1.96 10.742 10.550 1.82
0.001 453.150 0.3645 0.3696 -1.39 12.482 12.328 1.25
0.001 453.150 0.4494 0.4550 -1.23 14.941 14.786 1.05
0.001 453.150 0.5862 0.5931 -1.17 18.548 18.378 0.92
0.001 453.150 0.6912 0.6959 -0.67 20.926 20.824 0.49
0.001 453.150 0.8430 0.8507 -0.91 24.031 23.890 0.59
0.001 453.150 0.9701 0.9820 -1.21 26.230 26.047 0.70
0.001 473.150 0.0689 0.0701 -1.80 2.684 2.636 1. 81
0.001 473.150 0.0937 0.0953 -1.67 3.629 3.569 1.67
0.001 473.150 0.1172 0.1192 -1.61 4.521 4.450 1.60
0.001 473.150 0.1562 0.1585 -1.43 5.970 5.887 1.41
0.001 473.150 0.1869 0.1893 -1.25 7.091 7.006 1.22
0.001 473.150 0.2323 0.2353 -1.27 8.735 8.630 1.22
0.001 473.150 0.3063 0.3098 -1.12 11.320 11.203 1.05
0.001 473.150 0.3643 0.3687 -1.19 13.291 13.147 1.10
0.001 473.150 0.4491 0.4540 -1.08 16.028 15.875 0.97
0.001 473.150 0.5859 0.5889 -0.52 20.054 19.968 0.43
0.001 473.150 0.6908 0.6979 -1.02 23.037 22.849 0.82
0.001 473.150 0.8426 0.8557 -1.53 26.931 26.626 1.15
0.001 473.150 1.0420 1.0858 -4.03 31.753 30.911 2.72
0.001 473.150 1.4954 1.5282 -2.15 38.498 38.100 1.04
0.001 493.150 0.7815 0.7891 -0.96 27.524 27.309 0.79
0.001 493.150 1.0628 1.0697 -0.64 34.809 34.646 0.47
0.001 493.150 1.3302 1. 3413 -0.83 40.677 40.458 0.54
0.001 493.150 1.7722 1.7822 -0.56 48.073 47.932 0.30
0.001 493.150 2.1212 2.0980 1.11 52.017 52.268 -0.48
0.001 493.150 2.3516 2.3080 1.89 54.116 54.504 -0.71
0.001 493.150 2.4879 2.4335 2.24 55.191 55.619 -0.77
0.001 493.150 2.5739 2.5074 2.65 55.767 56.251 -0.86
0.001 493.150 2.6359 2.5714 2.51 56.233 56.672 -0.78
0.001 493.150 2.6683 2.5815 3.36 56.303 56.883 -1.02
0.001 498.150 0.7814 0.7878 -0.81 27.996 27.810 0.67
0.001 498.150 1.0627 1.0674 -0.44 35.526 35.410 0.33
0.001 498.150 1.3300 1.3398 -0.73 41. 706 41.502 0.49
0.001 498.150 1. 7718 1.7745 -0.15 49.524 49.482 0.08
0.001 498.150 2.1206 2.1039 0.79 54.044 54.244 -0.37
0.001 498.150 2.3509 2.3101 1.77 56.354 56.769 -0.73
0.001 498.150 2.6350 2.5832 2.00 58.882 59.299 -0.70
0.001 498.150 2.8058 2.7585 1. 71 60.219 60.545 -0.54
0.001 498.150 2.9979 2.9085 3.07 61.204 61.727 -0.85

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

834 ROBERT D. GOODWIN

Table 9k. Comparison of lD code (87) Ramsay PpT data with values calculated
from Eq. (6) - Continued

Wt. T p Calc. f' iJ{,j p P Calc. P iJP/p

K molll moll I % bar bar %

0.001 498.150 3.0391 2.9317 3.66 61.344 61.952 -0.98

0.001 498.150 3.0823 2.9557 4.29 61.486 62.178 -1.11
0.001 503.150 0.0673 0.0690 -2.50 2.820 2.750 2.54
0.001 503.150 0.0915 0.0937 -2.32 3.816 3.728 2.35
0.001 503.150 0.1146 0.1177 -2.62 4.777 4.653 2.65
0.001 503.150 0.1527 0.1566 -2.55 6.329 6.171 2.56
0.001 503.150 0.1827 0.1874 -2.52 7.543 7.358 2.52
0.001 503.150 0.2271 0.2340 -2.97 9.361 9.091 2.97
0.001 503.150 0.2994 0.3070 -2.47 12.151 11.864 2.42
0.001 503.150 0.3561 0.3656 -2.61 14.337 13.985 2.52
0.001 503.150 0.4389 0.4490 -2.24 17.361 17.002 2.11
0.001 503.150 0.5726 0.5822 -1.64 21.961 21.641 1.48
0.001 503.150 0.6752 0.6876 -1 .81 25.398 25.003 1.58
0.001 503.150 0.8234 0.8349 -1.37 29.892 29.555 1.14
0.001 503.150 1.0536 1.0609 -0.68 36.110 35.924 0.52
0.001 503.150 1.461& 1.4559 0.40 45.175 45.294 -0.26
0.001 503.150 0.7814 0.7863 -0.62 28.447 28.300 0.52
0.001 503.150 1.0626 1.0664 -0.36 36.253 36.155 0.27
0.001 503.150 1.3297 1.3354 -0.42 42.636 42.513 0.29
0.001 503.150 1.7712 1.7678 0.19 50.917 50.974 -0.11
0.001 503.150 2.1202 2.1000 0.96 55.881 56.148 -0048
0.001 503.150 2.3500 2.3155 1.49 58.553 58.944 -0.66
0.001 503.150 2.6359 2.5826 2.06 61.343 61.836 -0.80
0.001 503.150 2.8040 2.7134 3.34 62.520 63.268 -1.18
0.001 503.150 2.9979 2.8632 4.70 63.729 64.698 -1.50
0.001 503.150 3.2187 3.0436 5.75 65.003 66.065 -1. 61
0.001 503.150 3.4746 3.2635 6.47 66.311 67.339 -1.53
0.001 503.150 3.5980 3.3006 9.01 66.507 67.847 -1. 98
0.001 505.150 0.7814 0.7890 -0.96 28.724 28.493 0.81
0.001 505.150 1.0626 1.0672 -0.43 36.568 36.448 0.33
0.001 505.150 1.3297 1.3342 -0.33 43.010 42.911 0.23
0.001 505.150 1.7712 1.7774 -0.35 51.666 51.561 0.21
0.001 505.150 2.1202 2.0992 1.00 56.605 56.892 -0.51
0.001 505.150 2.3500 2.3350 0.64 59.619 59.796 -0.30
0.001 505.150 2.6359 2.5865 1. 91 62.343 62.823 -0.76
0.001 505.150 2.9979 2.8979 3.45 65.100 65.856 -1.15
0.001 505.150 3.2187 3.0781 4.57 66.421 67.327 -1.34
0.001 505.150 3.4746 3.2754 6.08 67.662 68.720 -1.S4
0.001 50S.150 3.7760 3.50S5 7.72 68.868 69.989 -1.60
0.001 507.150 0.7814 0.7892 -0.99 28.927 28.685 0.84
0.001 507.150 1.0626 1.0663 -0.35 36.837 36.739 0.27
0.001 507.150 1.3297 1.3333 -0.26 43.384 43.304 0.18
0.001 507.150 1. 7712 1.7695 0.09 52.110 52.140 -0.06
0.001 507.150 2.1202 2.1079 0.58 57.454 57.627 -0.30
0.001 507.150 2.3500 2.3207 1.26 60.276 60.636 -0.59
0.001 507.150 2.6359 2.5814 2.11 63.239 63.795 -0.87
0.001 507.150 2.9979 2.9103 3.01 66.297 66.998 -1.05
0.001 507.150 3.4746 3.3333 4.24 69.286 70.081 -1.13
0.001 507.150 3.7760 3.5354 6.81 70.396 71.486 -1.53
0.001 507.150 4.1325 3.8169 8.27 71.649 72.706 -1.45
0.001 507.150 4.2946 3.8359 11.96 71.722 73.127 -1.92
0.001 509.150 0.7812 0.7899 -1.10 29.139 28.870 0.93
0.001 S09.150 1.0622 1.0680 -0.54 37.172 37.016 0.42
0.001 509.150 1. 3292 1.3371 -0.60 43.864 43.680 0.42
0.001 509.150 1.7702 1.7696 0.04 52.682 52.694 -0.02
0.001 509.150 2.1187 2.1111 0.36 58.221 58.331 -0.19
0.001 509.150 2.6336 2.6113 0.86 64.495 64.731 -0.37
0.001 509.150 2.9951 2.9034 3.16 67.322 68.101 -1.14
0.001 509.150 3.4746 3.2924 5.53 70.300 71.425 -1.58
0.001 509.150 3.7760 3.5693 5.79 71.950 72.964 -1.39
0.001 509.150 4.1325 3.7756 9.45 72.962 74.336 -1.85
0.001 509.150 4.5640 4.0006 14.08 73.879 75.474 -2.11
0.001 511. 150 0.7812 0.7878 -0.84 29.266 29.059 0.71
0.001 511. 150 1.0622 1.0672 -0.46 37.434 37.301 0.36
0.001 511.150 1.3292 1.3340 -0.36 44.179 44.065 0.26
0.001 511 .150 1.7702 1.7646 0.32 53.154 53.258 -0.19
0.001 511.150 2.1187 2.1068 0.57 58.867 59.046 -0.30
0.001 511. 150 2.6336 2.5860 1. 84 65.148 65.677 -0.81
0.001 511 .150 2.9951 2.9009 3.25 68.368 69.211 -1.22
0.001 511.150 3.4746 3.3228 4.57 71.757 72.752 -1.37

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 835

Table 9k. Comparison of lJ) code (87) Ramsay PrT data with values calculated
from Eq. (6) - Continued

Wt. T (J Calc. (J iJl'/(' J) Calc. fJ iJP/P

K molll molll % bar bar %

0.001 511.150 4.1325 3.8174 8.26 74.623 75.947 -1. 74

0.001 511.150 4.5640 4.0926 11.52 75.798 77 . 258 -1.89
0.001 511.150 4.8604 4.1869 16.08 76.142 77.889 -2.24
0.001 512.150 0.7812 0.7877 -0.82 29.358 29.152 0.70
0.001 512.150 1.0622 1.0700 -0.73 37.654 37.442 0.57
0.001 512.150 1.3292 1.3313 -0.16 44.306 44.256 0.11
0.001 512.150 1.7702 1.7740 -0.21 53.608 53.538 0.13
O.O()1 512.150 2.1187 2.1019 0.80 59.143 59.400 -0.43
0.001 512.150 2.6336 2.6122 0.82 65.904 66.145 -0.37
0.001 512.150 2.9951 2.9254 2.38 69.126 69.760 -0.91
0.001 512.150 3.4746 3.3214 4.61 72.370 73.408 -1.41
0.001 512.150 4.1325 3.8966 6.05 75.738 76.745 -1.31
0.001 512.150 4.5640 4.0472 12.77 76.403 78.142 -2.23
0.001 512.150 5.0936 4.4302 14.98 77.764 79.243 -1.87
0.001 512.150 5.4790 4.5424 20.62 78.084 79.735 -2.07
0.001 512.650 2.6336 2.6156 0.69 66.173 66.378 -0.31
0.001 512.650 2.9951 2.9616 1.13 69.729 70.034 -0.44
0.001 512.650 3.4746 3.3312 4.30 72.751 73.735 -1.33
0.001 512.650 4.1325 3.8702 6.78 75.983 77 .143 -1.50
0.001 512.650 4.5640 4.1239 10.67 77 . 108 78.583 1. 88
0.001 512.650 5.0936 1.11538 H.37 78.264 79.732 -1.84
0.001 512.650 5.7687 4.4863 28.58 78.362 80.523 -2.68
0.001 513.150 0.0673 0.0685 -1.80 2.857 2.806 1. 81
0.001 513.150 0.0728 0.0744 -2.15 3.101 3.035 2.18
0.001 513.150 0.0760 0.0775 -2.04 3.229 3.164 2.06
0.001 :513.1:50 0.0831 0.0849 -2..17 3.533 3.457 2.20
0.001 513.150 0.0915 0.0934 -2.03 3.884 3.805 2.05
0.001 513.150 0.1146 0.1173 -2.31 4.862 4.751 2.33
0.001 513.150 0.1526 0.1565 -2.47 6.461 6.304 2.49
0.001 513.150 0.1827 0.1871 -2.38 7.699 7.520 2.39
0.001 513.150 0.2270 0.2335 -2.79 9.557 9.297 2.79
0.001 513.150 0.2993 0.3067 -2.42 12.436 12.148 2.37
0.001 513.150 0.3560 0.3643 -2.30 14.653 14.334 2.23
0.001 513.150 0.4388 0.4482 -2.09 17.799 17.452 1.99
0.001 513.150 0.5714 0.5818 -1.79 22.597 22.232 1.64
0.001 513.150 0.6751 0.6870 -1.74 26.183 25.784 1.55
0.001 513.150 0.8232 0.8295 -0.76 30.765 30.569 0.64
0.001 513.150 1.0533 1.0564 -0.29 37.421 37.335 0.23
0.001 513.150 1.4618 1.4608 0.07 47.484 47.506 -0.05
0.001 513.150 0.7812 0.7881 -0.87 29.464 29.246 0.75
0.001 513.150 1.0622 1.0706 -0.78 37.812 37.583 0.61
0.001 513.150 1.3292 1.3357 -0.49 44.602 44.446 0.35
0.001 513.150 1.7702 1.7906 -1.14 54.197 53.816 0.71
0.001 513.150 2.1187 2.1065 0.58 59.564 59.753 -0.31
0.001 513.150 2.6336 2.6103 0.90 66.343 66.611 -0.40
0.001 513.150 2.9951 2.9478 1.60 69.869 70.306 -0.62
0.001 513.150 3.4746 3.3667 3.20 73.318 74.061 -1.00
0.001 513.150 4.1325 3.8185 8.22 76.088 77.539 -1.87
0.001 513.150 5.0936 4.3427 17.29 78.32& 80.220 -2.36
0.001 513.150 5.7687 4.7237 22.12 79.447 81.064 -2.00
0.001 513.150 6.6444 4.8284 37.61 79.693 81.515 -2.23
0.001 513.150 7.8335 4.9973 56.75 80.044 81.674 -2.00

192 Clata points, iLlr/rl rms = 7.032%, Llr/r avo = 1.75%, iLlP/ Pi avo = 1.24%,
weight 0.07%.

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

836 ROBERT D. GOODWIN

Table 9l. Comparison of ID code (90) ROO / Zubarev PpT data with values
calculated from Eq. (6)

Wt. T p Calc. p 6.p/ p P Calc. P 6.P/P

K molil molil % bar bar %
0.001 413.150 0.1000 0.1015 -1.48 3.308 3.261 1.44
0.001 433.150 0.1000 0.1016 -1.56 3.501 3.448 1.54
0.001 453.150 0.1000 0.1013 -1.33 3.677 3.629 1.32
0.001 473.150 0.1000 0.1011 -1.12 3.849 3.807 1.11
0.001 493.150 0.1000 0.1012 -1.15 4.027 3.982 1.14
0.001 503.150 0.1000 0.1010 -1.01 4.109 4.068 1.01
0.001 509.530 0.1000 0.1003 -0.32 4.136 4.123 0.31
0.001 513.150 0.1000 0.1010 -1.01 4.196 4.154 1.01
0.001 514.150 0.1000 0.1007 -0.73 4.193 4.163 0.73
0.001 517.950 0.1000 0.1007 -0.71 4.225 4.195 0.71
0.001 523.150 0.1000 0.1010 -0.99 4.282 4.240 0.99
0.001 533.150 0.1000 0.1010 -1.03 4.370 4.325 1.03
0.001 543.150 0.1000 0.1010 -1.03 4.456 4.410 1.03
0.001 553.150 0.1000 0.1010 -0.95 4.538 4.495 0.95
0.001 563.150 0.1000 0.1010 -0.98 4.625 4.580 0.99
0.001 573.150 0.1000 0.1010 -1.00 4.711 4.664 1.00
0.001 413.150 0.2000 0.2029 -1.42 6.324 6.243 1.30
0.001 433.150 0.2000 0.2026 -1.30 6.762 6.680 1.23
0.001 453.150 0.2000 0.2021 -1.03 7.158 7.088 0.98
0.001 473.150 0.2000 0.2012 -0.62 7.522 7.477 0.60
0.001 493.150 0.2000 0.2013 0.64 7.901 7.852 0.62
0.001 503.150 0.2000 0.2008 -0.42 8.069 8.036 0.41
0.001 509.530 0.2000 0.1981 0.95 8.077 8.152 -0.92
0.001 513.150 0.2000 0.2007 -0.37 8.247 8.218 0.36
0.001 514.150 0.2000 0.1997 0.13 8.225 8.236 -0.13
0.001 517.950 0.2000 0.1997 0.17 8.290 8.304 -0.17
0.001 523.150 0.2000 0.2008 -0.39 8.429 8.397 0.38
0.001 533.150 0.2000 0.2009 -0.43 8.612 8.575 0.43
0.001 543.150 0.2000 0.2009 -0.46 8.792 8.752 0.46
0.001 553.150 0.2000 0.2006 -0.31 8.955 8.927 0.31
0.001 563.150 0.2000 0.2007 -0.36 9.134 9.101 0.36
0.001 573.150 0.2000 0.2009 -0.44 9.315 9.275 0.43
0.001 433.150 0.5000 0.4977 0.47 14.674 14.726 -0.35
0.001 453.150 0.5000 0.5022 -0.44 16.228 16.169 0.37
0.001 473.150 0.5000 0.4995 0.10 17.427 17.442 -0.09
0.001 493.150 0.5000 0.4987 0.26 18.562 18.605 -0.23
0.001 503.150 0.5000 0.4965 0.71 19.034 19.156 -0.64
0.001 509.530 0.5000 0.4814 3.86 18.833 19.499 -3.42
0.001 513.150 0.5000 0.4955 0.92 19.527 19.691 -0.83
0.001 514.150 0.5000 0.4898 2.09 19.372 19.744 -1. 88
0.001 517.950 0.5000 0.4902 2.01 19.580 19.943 -1.82
0.001 523.150 0.5000 0.4957 0.87 20.050 20.212 -0.80
0.001 533.150 0.5000 0.4959 0.83 20.562 20.721 -0.77
0.001 543.150 0.5000 0.4960 0.80 21.062 21.220 -0.74
0.001 553.150 0.5000 0.4945 1.12 21.482 21.709 -1.05
0.001 563.150 0.5000 0.4949 1.02 21. 978 22.191 -0.96
0.001 573.150 0.5000 0.4957 0.86 22.481 22.666 -0.81
0.001 453.150 1.0000 0.9819 1.84 26.229 26.502 -1.03
0.001 473.150 1.0000 0.9998 0.02 30.065 30.070 0.02
0.001 493.150 1.0000 0.9962 0.38 33.026 33.121 -0.29
0.001 503.150 1.0000 0.9915 0.86 34.285 34.514 -0.66
0.001 509.530 1.0000 0.9409 6.28 33.694 35.366 -4.73
0.001 513.150 1.0000 0.9863 1.39 35.446 35.838 -1.09
0.001 514.150 1.0000 0.9660 3.51 34.986 35.967 -2.73
0.001 517.950 1.0000 0.9725 2.82 35.643 36.453 -2.22
0.001 523.150 1.0000 0.9872 1.29 36.720 37.106 -1.04
0.001 533.150 1.0000 0.9870 1.32 37.910 38.325 -1.08
0_001 54.:L 150 1_0000 0.9&69 1.32 39.068 39.503 -1.10
0.001 553.150 1.0000 0.9823 1. 80 40.029 40.645 -1.52
0.001 563.150 1.0000 0.9838 1.65 41.170 41.757 -1.41
0.001 573.150 1.0000 0.9861 1.41 42.321 42.841 -1.21
0.001 493.150 2.0000 1.9996 0.02 50.896 50.901 -0.01
0.001 503.150 2.0000 2.0089 -0.44 54.627 54.500 0.23
0.001 509.530 2.0000 1.8804 6.36 54.721 56.669 -3.44
0.001 513.150 2.0000 1.9920 0.40 57.728 57.860 -0.23
0.001 514.150 2.0000 1.9222 4.05 56.858 58.185 -2.28
0.001 517.950 2.0000 1.9743 1.30 58.949 59.402 -0.76
0.001 523.150 2.0000 1.9936 0.32 60.908 61.026 -0.19
0.001 533.150 2.0000 1.9908 0.46 63.844 64.033 -0.29
0.001 543.150 2.0000 1.9904 0.48 66.690 66.905 -0.32

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 837

Table 91. Comparison of ID code (90) ROO I Zubarev PpT data with values
calculated from Eq. (6) - Continued

Wt. T p Calc. p Llpl p P Calc. P LlPIP

K moll I mol/l % bar bar %

0.001 553.150 2.0000 1.9840 0.81 69.279 69.665 -0.55

0.001 563.150 2.0000 1.9887 0.57 72.037 72 .329 -0.40
0.001 573.150 2.0000 1.9950 0.25 74.773 74.909 -0.18
0.001 503.150 3.0000 2.9991 0.03 64.706 64.712 -0.01
0.001 509.530 3.0000 2.9168 2.85 67.645 68.353 -1.04
0.001 513.150 3.0000 3.0075 -0.25 70.419 70.351 0.10
0.001 514.150 3.0000 2.8688 4.57 69.623 70.895 1.79
0.001 517.950 3.0000 3.0059 -0.20 72.993 72.933 0.08
0.001 523.150 3.0000 2.9963 0.12 75.609 75.651 -0.06
0.001 533.150 3.0000 2.9950 0.17 80.610 80.677 -0.08
0.001 543.150 3.0000 2.9972 0.09 85.436 85.478 -0.05
0.001 553.150 3.0000 3.0010 -0.03 90.110 90.092 0.02
0.001 563.150 3.0000 3.0101 -0.34 94.741 94.548 0.20
0.001 573.150 3.0000 3.0181 -0.60 99.247 98.868 0.38
0.001 509.530 4.0000 4.2807 -6.56 75.104 74.174 1.25
0_001 513 _150 ,LOOOO 4_007:'i -0_19 77 .003 76.969 0.04
0.001 514.150 4.0000 3.7928 5.46 76.672 77.731 -1.36
0.001 517.950 4.0000 4.0201 -0.50 80.700 80.590 0.14
0.001 523.150 4.0000 3.9607 0.99 84.150 84.412 -0.31
0.001 533.150 4.0000 3.9698 0.76 91.248 91.511 -0.29
0.001 543.150 4.0000 3.9814 0.47 98.133 98.332 -0.20
0.001 553.150 4.0000 4.0016 -0.04 104.942 104.921 0.02
0.001 563.150 4.0000 4.0153 -0.38 111.541 111.318 0.20
0.001 573.150 4.0000 4.0185 -0.46 117.857 117.550 0.26
0.000 509.530 5.0000 12.6675 -60.53 78.766 76.552 2.89
0.001 513.150 5.0000 5.0030 -0.06 80.055 80.049 0.01
0.001 514.150 5.0000 4.1275 5.76 80.363 81.006 -0.79
0.001 517.950 5.0000 5.0060 -0.12 84.620 84.603 0.02
0.001 523.150 5.0000 4.9101 1.83 89.099 89.441 -0.38
0.001 533.150 5.0000 4.9308 1.40 98.113 98.504 -0.40
0.001 543.150 5.0000 4.9590 0.83 106.993 107.302 -0.29
0.001 553.150 5.0000 4.9904 0.19 115.791 115.882 -0.08
0.001 563.150 5.0000 5.0080 -0.16 124.370 124.279 0.07
0.001 573.150 5.0000 4.9979 0.04 132.492 132.520 -0.02
0.001 513.150 6.0000 6.0685 -1.13 81.277 81.235 0.05
0.001 514.150 6.0000 5.7843 3.73 82.160 82.348 -0.23
0.001 517.950 6.0000 6.0205 -0.34 86.583 86.556 0.03
0.001 523.150 6.0000 5.9246 1.27 92.098 92.260 -0.18
0.001 533.150 6.0000 5.9236 1.29 102.788 103.079 -0.28
0.001 543.150 6.0000 5.9641 0.60 113.531 113.731 -0.18
0.001 553.150 6.0000 5.9915 0.14 124.181 124.245 -0.05
0.001 563.150 6.0000 6.0102 -0.17 134.738 134.642 0.07
0.001 573.150 6.0000 5.9772 0.38 144.675 144.938 -0.18
0.001 513.150 7.0000 8.0860 -13.43 81.689 81.591 0.12
0.001 514.150 7.0000 7.3751 -5.09 82.916 82.827 0.11
0.001 517.950 7.0000 7.1980 -2.75 87.668 87.529 0.16
0.001 523.150 7.0000 7.0738 -1.04 94.071 93.967 0.11
0.001 533.150 7.0000 6.9738 0.38 106.282 106.359 -0.07
0.001 543.150 7.0000 6.9998 0.00 118.760 118.761 -0.00
0.001 553.150 7.0000 7.0086 -0.12 131. 224 131.167 0.04
0.001 563.150 7.0000 7.0237 -0.34 143.778 143.574 0.14
0.001 573.150 7.0000 6.9642 0.51 155.593 155.978 -0.25
0.001 513.150 8.0000 9.6231 -16.87 81. 812 81.684 0.16
0.001 514.150 8.0000 8.5725 -6.68 83.125 83.028 0.12
0.001 517.950 8.0000 8.3800 -4.53 88.405 88.171 0.27
0.001 523.150 8.0000 8.1813 -2.22 95.525 95.289 0.25
0.001 533.150 8.0000 8.0230 -0.29 109.266 109.201 0.06
0.001 543.150 8.0000 8.0132 -0.17 123.413 123.352 0.05
0.001 553.150 8.0000 8.0105 -0.13 137.763 137.693 0.05
0.001 563.150 8.0000 8.0217 -0.27 152.379 152.188 0.13
0.001 573.150 8.0000 7.9445 0.70 166.194 166.807 -0.37
0.001 513.150 8.2000 9.7035 -15.49 81.825 81.696 0.16
0.001 514.150 8.2000 8.6125 -4.79 83.132 83.062 0.08
0.001 517.950 8.2000 8.5834 -4.47 88.534 88.293 0.27
0.001 523.150 8.2000 8.3789 -2.13 95.786 95.550 0.25
0.001 533.150 8.2000 8.2270 -0.33 109.850 109.772 0.07
0.001 543.150 8.2000 8.2099 -0.12 124.331 124.284 0.04
0.001 553.150 8.2000 8.2071 -0.09 139.075 139.027 0.03
0.001 563.150 8.2000 8.2178 -0.22 154.115 153.956 0.10
0.001 573.150 8.2000 8.1388 0.75 168.351 169.037 -0.41

J. Phys. Chem. Ref. Data, Vof.16, No.4, 1987

838 ROBERT D. GOODWIN

Table 91. Comparison of ID code (90) ROO / Zubarev PpT data with values
calculated from Eq. (6) - Continued

Wt. T p Calc. p ilp/ p P Calc. P tJ.P/P

K moVI moVI % bar bar %

0.001 513.150 8.4000 9.7705 -14.03 81.837 81.707 0.16

0.001 514.150 8.4000 8.6181 -2.53 83.133 83.095 0.05
0.001 517.950 8.4000 8.7790 -4.32 88.662 88.418 0.28
0.001 523.150 8.4000 8.5694 -1.98 96.043 95.814 0.24
0.001 533.150 8.4000 8.4287 -0.34 110.438 110.354 0.08
0.001 543.150 8.4000 8.4053 -0.06 125.258 125.233 0.02
0.001 553.150 8.4000 8.4015 -0.03 140.401 140.384 0.01
0.001 563.150 8.4000 8.4129 -0.15 155.871 155.754 0.08
0.001 573.150 8.4000 8.3326 0.81 170.535 171.304 -0.45
0.001 513.150 8.6000 9.8316 -12.53 81.849 81.719 0.16
0.001 514.150 8.6000 8.6125 -0.14 83.132 83.130 0.00
0.001 517.950 8.6000 8.9641 -4.06 88.788 88.545 0.27
0.001 523.150 8.6000 8.7542 -1.76 96.299 96.085 0.22
0.001 533.150 8.6000 8.6298 -0.35 111.037 110.947 0.08
0.001 543.150 8.6000 8.5997 0.00 126.199 126.200 -0.00
0.001 553.150 8.6000 8.5974 0.03 141. 748 141.767 -0.01
0.001 563.150 8.6000 8.6072 -0.08 157.653 157.586 0.04
0.001 573.150 8.6000 8.5260 0.87 172.753 173.613 -0.50
0.001 513.150 8.8000 9.8922 -11 .04 81.862 81. 732 0.16
0.001 514.150 8.8000 8.6011 2.31 83.130 83.166 -0.04
0.001 517.950 8.8000 9.1434 -3.76 88.916 88.676 0.27
0.001 523.150 8.8000 8.9358 -1.52 96.559 96.364 0.20
0.001 533.150 8.8000 8.8297 -0.34 111.649 111.557 0.08
0.001 543.150 8.8000 8.7934 0.07 127.159 127.192 -0.03
0.001 553.150 8.8000 8.7914 0.10 ,143.120 143.182 -0.04
U.OUI 563.150 8.8000 8.8009 -0.01 159.467 159.458 0.01
0.001 573.150 8.8000 8.7192 0.93 175.012 175.971 -0.54
0.001 513.150 9.0000 9.9562 -9.60 81.877 81.746 0.16
0.001 514.150 9.0000 8.6011 4.64 83.130 83.204 -0.09
0.001 517.950 9.0000 9.3180 -3.41 89.048 88.813 0.26
0.001 523.150 9.0000 9.1153 -1.27 96.826 96.653 0.18
0.001 533.150 9.0000 9.0291 -0.32 112.280 112.186 0.08
0.001 543.150 9.0000 8.9867 0.15 128.144 128.213 -0.05
0.001 553.150 9.0000 8.9852 0.16 144.526 144.635 -0.08
0.001 563.150 9.0000 8.9940 0.07 161.320 161.378 -0.04
0.001 573.150 9.0000 8.9123 0.98 177.319 178.385 -0.60
0.001 513.150 10.0000 10.4392 -4.21 82.047 81.888 0.19
0.001 514.150 10.0000 9.3666 6.76 83.284 83.488 -0.24
0.001 517.950 10.0000 10.1681 -1.65 89.861 89.670 0.21
0.001 523.150 10.0000 10.0207 -0.21 98.418 98.375 0.04
0.001 533.150 10.0000 10.0229 -0.23 115.894 115.799 0.08
0.001 543.150 10.0000 9.9569 0.43 133.685 133.962 -0.21
0.001 553.150 10.0000 9.9517 0.49 152.289 152.719 -0.28
0.001 563.150 10.0000 9.9547 0.46 171. 437 171. 961 -0.30
0.001 573.150 10.0000 9.8767 1.25 189.847 191.602 -0.92
0.001 513.150 11.0000 11.2046 -1.83 82.673 82.445 0.28
0.001 514.150 11.0000 10.8651 1.24 84.086 84.239 -0.18
0.001 517.950 11.0000 11.0803 -0.72 91.362 91.188 0.19
0.001 523.150 11.0000 10.9957 0.04 100.996 101.011 -0.01
0.001 533.150 11.0000 11.0138 -0.12 120.853 120.770 0.07
0.001 543.150 11.0000 10.9425 0.53 140.975 141.475 -0.35
0.001 553.150 11.0000 10.9248 0.69 162.071 162.942 -0.53
0.001 563.150 11.0000 10.9167 0.76 183.814 185.030 -0.66
0.001 573.150 11.0000 10.8440 1.44 204.890 207.631 -1.32
0.000 509.530 12.0000 4.5590 163.21 75.804 76.934 -1.47
0.001 513.150 12.0000 12.1019 -0.84 84.552 84.245 0.36
0.001 514.150 12.0000 12.0074 -0.06 86.329 86.305 0.03
0.001 517.950 12.0000 12.0514 -0.43 94.516 94.287 0.24
0.001 523.150 12.0000 12 .0123 -0.10 105.641 105.567 0.07
0.001 533.150 12.0000 11. 9979 0.02 128.234 128.253 -0.01
0.001 543.150 12.0000 11.9423 0.48 151.303 152.023 -0.47
0.001 553.150 12.0000 11.9200 0.67 175.400 176.667 -0.72
0.001 563.150 12.0000 -11.8977 0.86 200.056 202.027 -0.98
0.001 573.150 12.0000 11.8258 1.47 224.044 227.978 -1. 73
0.001 509.530 13.0000 13.0002 -0.00 80.300 80.299 0.00
0.001 513.150 13.0000 13.0442 -0.34 89.179 88.873 0.34
0.001 514.150 13.0000 13.0073 -0.06 91. 337 91. 284 0.06
0.001 :517.9:50 13.0000 13.0348 -0.27 100.910 100.604 0.30
0.001 523.150 13.0000 13.0226 -0.17 113.975 113.730 0.22
0.001 533.150 13.0000 12.9770 0.18 139.679 140.015 -0.24

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METH,ANE 839

Table 9l. Comparison of IJ) code (90) RDG / Zubarev PpT data with values
calculated from Eq. (6) - Continued

Wt. T I' Calc. (' fJ.p/p P Calc. P fJ.P/P

K mol/[ molll % bar bar %
0.001 543.150 13.0000 12.9496 0.39 166.508 167.437 -0.55
0.001 553.150 13.0000 12.9549 0.35 194.770 195.781 -0.52
0.001 563.150 13.0000 12.9185 0.63 222.742 224.881 -0.95
0.001 573.150 13.0000 12.8396 1. 25 249.813 254.605 -1.88
0.001 503.150 14.0000 14.0108 -0.08 71.563 71.465 0.14
0.001 509.530 14.0000 14.0485 -0.35 89.331 88.734 0.67
0.001 513.150 14.0000 14.0138 -0.10 99.078 98.886 0.19
0.001 514.150 14.0000 13.9821 0.13 101.478 101.732 -0.25
0.001 517.950 14.0000 14.0191 -0.14 113.007 112.698 0.27
0.001 523.150 14.0000 14.0196 -0.14 128.427 128.062 0.28
0.001 533.150 14.0000 13.9660 0.24 157.840 158.620 -0.49
0.001 543.150 14.0000 13.9643 0.26 189.308 190.287 -0.51
0.001 553.150 14.0000 14.0515 -0.37 224.522 222.854 0.75
0.001 503.150 15.0000 15.0487 -0.32 86.260 85.296 1. 13
0.001 509.530 15.0000 14.9976 0.02 105.851 105.907 -0.05
0.001 513.150 15.0000 15.0148 -0.10 118.290 117.917 0.32
0.001 514.150 15.0000 15.0069 -0.05 121. 448 121.272 0.15
0.001 517.950 15.0000 15.0136 -0.09 134.533 134.156 0.28
0.001 523.150 15.0000 15.0172 -0.11 152.633 152.110 0.34
0.001 533.150 15.0000 14.9918 0.05 187.260 187.551 -0.16
0.001 543.150 15.0000 14.9964 0.02 223.855 223.999 -0.06
0.001 493.150 16.0000 16.2842 -1. 75 84.451 75.452 11.93
0.001 503.150 16.0000 15.9853 0.09 111.711 112.230 -0.46
0.001 509.530 16.0000 15.9771 0.14 135.696 136.591 -0.66
0,001 513 .150 16.0000 lh.04Jf.o -0.27 152.502 150.678 1. 21
0.001 514.150 16.0000 16.1660 -1.03 161.853 154.600 4.69
0.001 517.950 16.0000 16.0228 -0.14 170.635 169.619 0.60
0.001 523.150 16.0000 16.0279 -0.17 191.771 190.444 0.70
0.001 533.150 16.0000 16.0929 -0.58 236.265 231. 267 2.16
0.001 . 493 .150 17.0000 16.8279 1.02 106.423 114.826 -7.32
0.001 503.150 17.0000 16.9630 0.22 156.111 158.234 -1.34
0.001 509.530 17.0000 17.0765 -0.45 191.442 186.626 2.58
0.001 513.150 17.0000 17.0314 -0.18 204.974 202.942 1.00
0.001 473.150 18.0000 17.8950 0.59 76.700 83.390 -8.02
0.001 493.150 18.0000 17.8128 1.05 165.518 180.064 -8.08
0.001 503.150 18.0000 18.0525 -0.29 235.016 230.354 2.02

246 data points, lfJ.pl ('I rms = 2.854%, fJ.p/ p avo == -0.33%, IfJ.PI PI avo = 0.67%,
weight = 0.09%.

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

840 ROBERT D. GOODWIN

Table 9m. Comparison of ID code (93) Amagat PI'T data with values calculated
from Eq. (6)

Wt. T p Calc. f' L1"/" P Calc. P L1PIP

K molll molll % bar bar %

0.001 273.150 25.5166 25.5441 -0.11 101.325 90.307 12.20

0.001 273.150 25.7374 25.7853 -0.19 202.650 181.855 11.43
0.001 273.150 25.9435 26.0089 -0.25 303.975 273.596 11.10
0.001 273.150 26.1393 26.2183 -0.30 405.300 366.349 10.63
0.001 273.150 26.3216 26.4162 -0.36 506.625 457.537 10.73
0.001 273.150 26.4927 26.6041 -0.42 607.950 547.268 11.09
0.001 273.150 26.6575 26.7836 -0.47 709.275 637.602 11.24
0.OU1 17';.I'U 10.1$11$" 10.'1'" -U.'1 1$1O.6UU 71').611 11. HJ
0.001 273.150 26.9675 27.1208 -0.57 911.925 817.783 11.51
0.001 273.150 27.1121 27.2801 -0.62 1013.250 906.482 11.78
0.001 273.150 27.3823 27.5827 -0.73 1215.900 1080.207 12.56
0.001 273.150 27.7642 28.0030 -0.85 1519.875 1343.922 13.09
0.001 273.150 28.3305 28.6328 -1.06 2026.500 1775.450 14.14
0.001 282.350 25.5012 25.5355 -0.13 202.650 188.147 7.71
0.001 282.350 25.7139 25.7657 -0.20 303.975 280.510 8.37
0.001 282.350 25.9142 25.9809 -0.26 405.300 373.205 8.60
0.001 282.350 26.1015 26.1838 -0.31 506.625 464.834 8.99
0.001 282.350 26.2806 26.3763 -0.36 607.950 556.924 9.16
0.001 282.350 26.4539 26.5599 -0.40 709.275 650.182 9.09
0.001 282.350 26.6154 26.7356 -0.45 810.600 740.837 9.42
0.001 282.350 26.7704 26.9043 -0.50 911.925 831.210 9.71
0.001 282.350 26.9187 27.0667 -0.55 1013.250 920.742 10.05
0.001 282.350 27.2025 27.3752 -0.63 1215.900 1100.781 10.46
0.001 282.350 27.5945 27.8033 -0.75 1519.875 1368.229 11.08
0.001 282.350 28.1632 28.4443 -0.99 2026.500 1796.505 12.80
0.001 297.000 25.3554 25.3806 -0.10 303.975 293.055 3.73
0.001 297.000 25.5631 25.6058 -0.17 405.300 385.569 5.12
0.001 297.000 25.7610 25.8174 -0.22 506.625 479.079 5.75
0.001 297.000 '25.9514 26.0175 -0.25 607.950 573.906 5.93
0.001 297.000 26.1339 26.2080 -0.28 709.275 669.273 5.98
0.001 297.000 26.3025 26.3899 -0.33 810.600 761.341 6.47
0.001 297.000 26.4622 26.5644 -0.38 911 .925 852.060 7.03
0.001 297.000 26.6126 26.7321 -0.45 1013.250 940.658 7.72
0.001 297.000 26.9043 27.0502 -0.54 1215.900 1121.235 8.44
0.001 297.000 27.3083 27.4908 -0.66 1519.875 1390.677 9.29
0.001 297.000 27.9021 28.1494 -0.88 2026.500 1828.754 10.81
0.001 303.200 25.2238 25.4477 -0.88 405.300 306.492 32.24
0.001 303.200 25.4242 25.6632 -0.93 506.625 394.640 28.38
0.001 303.200 25.6123 25.8669 -0.98 607.950 482.120 26.10
0.001 303.200 25.7952 26.0604 -1.02 709.275 571.666 24.07
0.001 303.200 25.9728 26.2451 -1.04 810.600 662.776 22.30
0.001 303.200 26.1420 26.4221 -1.06 911. 925 753.459 21.03
0.001 303.200 26.3052 26.5922 -1.08 1013.250 844.518 19.98
0.001 303.200 26.6098 26.9144 -1 .13 1215.900 1023.944 18.75
0.001 303.200 27.0194 27.3603 -1.25 1519.875 1284.954 18.28
0.001 303.200 27.6337 28.0264 -1.40 2026.500 1720.028 17.82

46 data points, l..1p/pl rms = 0.680%, ..11'/1' avo = -0.59%, I..1P/ PI avo = 12.46%,
weight = 0.02%.

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 841

Table 9n. Comparison of ID code (99) Straty PpT data with values calculated
from Eq. (6)

Wt. T p Calc. p LJp/ p P Calc. P LJP/P

K molll moll1 % bar bar %

1.000 483.127 2.0612 2.0719 -0.52 47.624 47.533 0.19

1.000 488.158 2.0605 2.0597 0.04 49.610 49.617 -0.02
1.000 493.154 2.0599 2.0591 0.04 51.587 51.596 -0.02
1.000 498.157 2.0592 2.0784 -0.92 53.734 53.495 0.45
1.000 503.196 2.0586 2.0765 -0.86 55.582 55.337 0.44
1.000 508.204 2.0579 2.0743 -0.79 57.344 57.102 0.42
1.000 513.206 2.0573 2.0721 -0.72 59.045 58.809 0.40
1.000 518.085 2.0567 2.0712 -0.70 60.669 60.423 0.41
1.000 523.178 2.0560 2.0668 -0.52 62.255 62.060 0.31
1.000 528.160 2.0554 2.0673 -0.58 63.844 63.619 0.35
1.000 533.157 2.0548 2.0619 -0.34 65.285 65.144 0.22
1.000 543.130 2.0536 2.0585 -0.24 68.192 68.084 0.16
1.000 553.208 2.0524 2.0555 -0.15 71.006 70.932 0.10
1.000 563.196 2.0512 2.0547 -0.17 73.739 73.650 0.12
1.000 573.175 2.0500 2.0549 -0.24 76.409 76.276 0.18

1.000 488.133 2.1117 2.1090 0.13 50.079 50.105 -0.05

1.000 493.158 2.1111 2.0980 0.62 52.020 52.163 -0.27
1.000 498.169 2.1104 2.1002 0.49 54.006 54.130 -0.23
1.000 503.052 2.1097 2.1158 -0.29 56.053 55.973 0.14
1.000 508.058 2.1091 2.1152 -0.29 57.887 57.799 0.15
1.000 513.082 2.1084 2.1144 -0.28 59.662 59.569 0.15
1.000 518.053 2.1078 2.1132 -0.26 61. 359 61.269 0.15
1.000 523.176 2.1071 2.1106 -0.16 63.030 62.969 0.10
1.000 528.136 2.1065 2.1109 -0.21 64.655 64.572 0.13
1.000 533.126 2.1058 2.1076 -0.08 66.178 66.143 0.05
1.000 543.111 2.1046 2.1051 -0.02 69.193 69.182 0.02
1.000 553.162 2.1033 2.1055 -0.11 72.164 72.112 0.07
1.000 563.210 2.1021 2.1060 -0.19 75.032 74.934 0.13
1.000 573.129 2.1009 2.1064 -0.26 77.774 77.628 0.19

1.000 493.122 2.6907 2.6719 0.70 56.890 57.008 -0.21

1.000 498.179 2.6899 2.6539 1.36 59.462 59.736 -0.46
1.000 503.127 2.6890 2.6534 1.34 61.983 62.297 -0.50
1.000 508.165 2.6882 2.6454 1.62 64.382 64.811 -0.66
1.000 513.179 2.6873 2.6627 0.92 66.953 67.226 -0.41
1.000 518.204 2.6865 2.6702 0.61 69.373 69.572 -0.29
1.000 523.140 2.6857 2.6727 0.49 71.637 71.808 -0.24
1.000 528.196 2.6849 2.6702 0.55 73.827 74.038 -0.28
1.000 533.205 2.6841 2.6687 0.58 75.953 76.189 -0.31
1.000 543.208 2.6825 2.6704 0.45 80.129 80.338 -0.26
1.000 553.207 2.6809 2.6717 0.34 84.138 84.314 -0.21
1.000 563.067 2.6794 2.6733 0.23 87.965 88.092 -0.14
1.000 573.171 2.6778 2.6736 0.16 91. 739 91. 835 -0.11
1.000 503.116 3.2324 3.2054 0.84 65.968 66.119 -0.23
1.000 508.115 3.2314 3.1869 1.40 68.948 69.251 -0.44
1.000 513.191 3.2304 3.2010 0.92 72.089 72.322 -0.32
1.000 518.107 3.2294 3.2126 0.52 75.054 75.205 -0.20
1.000 !i23.13Y 3.22~4 3.2UYU 0.61 77 .H7b 7lLU72 -U.25
1.000 528.137 3.2274 3.2093 0.56 80.642 80.843 -0.25
1.000 533.101 3.2265 3.2115 0.47 83.347 83.529 -0.22
1.000 543.110 3.2245 3.2151 0.29 88.630 88.762 -0.15
1.000 553.153 3.2226 3.2163 0.20 93.703 93.805 -0.11
1.000 563.206 3.2207 3.2177 0.09 98.620 98.674 -0.05
1.000 573.184 3.2189 3.2198 -0.03 103.375 103.357 0.02

1.000 508.144 3.8884 3.8611 0.71 72.573 72.679 -0.15

1.000 513.176 3.g872 3.8673 0.51 76.356 76.455 0.13
1.000 518.155 3.8860 3.8695 0.43 79.984 80.083 -0.12
1.000 523.150 3.8848 3.8674 0.45 83.503 83.626 -O.lS
1.000 528.187 3.8836 3.8681 0.40 86.985 87.111 -0.14
1.000 533.127 3.8825 3.8710 0.30 90.349 90.453 -0.12
1.000 543.143 3.8801 3.8762 0.10 96.977 97.020 -0.04
1.000 553.151 3.8779 3.8795 -0.04 103.368 103.346 0.02
1.000 563.165 3.8756 3.8822 -0.17 109.575 109.475 0.09
1.000 573.132 3.8733 3.8841 -0.28 115.587 115.403 0.16

1.000 508.162 4.5855 4.5735 0.26 74.604 74.627 -0.03

1.000 513.203 4.5841 4.5438 0.89 79.010 79.125 -0.15

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

842 ROBERT D. GOODWIN

Table 9n. Comparison of ID code (99) Straty PpT data with values calculated
from Eq. (6) - Continued

Wt. T p Calc. p Llp/p P Calc. P LlP/P

K moUl moUl % bar bar %

1.000 518.147 4.5827 4.5433 0.87 83.277 83.428 -0.18

1.000 523.186 4.5813 4.5370 0.98 87.499 87.712 -0.24
1.000 528.074 4.5799 4.5450 0.77 91.581 91.781 -0.22
1.000 533.179 4.5785 4.5419 0.81 95.702 95.949 -0.26
1.000 543.117 4.5758 4.5510 0.55 103.638 103.854 -0.21
1.000 553.180 4.5731 4.5550 0.40 111.419 111 .613 -0.17
1.000 563.124 4.5704 4.5599 0.23 118.945 119.078 -0.11
1.000 573.087 4.5678 4.5616 0.14 126.292 126.383 -0.07

1.000 513.177 5.3485 5.3728 -0.45 80.671 80.639 0.04

1.000 518.125 5.3469 5.3565 -0.18 85.645 85.624 0.02
1.000 523.133 5.3452 5.3361 0.17 90.556 90.584 -0.03
1.000 528.149 5.3436 5.3269 0.31 95.408 95.474 -0.07
1.000 533.129 5.3420 5.3276 0.27 100.189 100.259 -0.07
1.000 543.169 5.3388 5.3266 0.23 109.640 109.722 -0.07
1.000 553.191 5.3356 5.3258 0.18 118.871 118.956 -0.07
1.000 563.191 5.3325 5.3241 0.16 127.902 127.992 -0.07
1.000 573.185 5.3294 5.3190 0.20 136.734 136.867 -0.10

0.000 513.111 6.7130 8.1595 -17.73 81.641 81.486 0.19

1.000 518.135 6.7110 6.9236 -3.07 87.699 87.525 0.20
1.000 523.131 6.7089 6.8151 -1.56 93.674 93.513 0.17
1.000 528.136 6.7069 6.7756 -1.01 99.651 99.495 0.16
1.000 533.127 6.7049 6.7529 -0.71 105.591 105.443 0.14
1.000 543.127 6.7009 6.7283 -0.41 117.446 117.314 0.11
1.000 553.181 6.6969 6.7037 -0.10 129.238 129.192 0.04
1.000 563.191 6.6930 6.6848 0.12 140.892 140.963 -0.05
1.000 573.161 6.6891 6.6672 0.33 152.396 152.634 -0.16

0.000 513.189 6.7561 7.8249 -13.66 81. 725 81.590 0.17

1.000 518.197 6.7540 6.9518 -2.85 87.798 87.637 0.18
1.000 523.196 6.7520 6.8473 -1.39 93.802 93.658 0.15
1.000 528.187 6.7499 6.8136 -0.93 99.798 99.654 0.14
1.000 533.181 6.7479 6.7955 -0.70 105.785 105.640 0.14
1.000 543.127 6.7439 6.7725 -0.42 117.659 117.522 0.12
1.000 553.109 6.7399 6.7532 -0.20 129.484 129.395 0.07
1.000 563.124 6.7359 6.7323 0.05 141.227 141.258 -0.02
1.000 573.112 6.7320 6.7147 0.26 152.854 153.042 -0.12

0.000 513.117 8.3698 10.1425 -17.48 81.875 81.659 0.26

1.000 518.161 8.3672 8.7054 -3.88 88.919 88.693 0.25
1.000 523.187 8.3647 8.5398 -2.05 96.057 95.820 0.25
1.000 528.148 8.3622 8.4968 -1.58 103.238 102.954 0.28
1.000 533.134 8.3597 8.4587 -1.17 110.503 110.212 0.26
1.000 . 543.113 8.3547 8.4042 -0.59 125.198 124.961 0.19
1.000 553.123 8.3497 8.3524 -0.03 140.U17 139.999 U.Ul
1.000 563.218 8.3447 8.3011 0.53 154.965 155.358 -0.25
1.000 573.187 8.3399 8.2605 0.96 169.776 170.676 -0.53

0.000 513.129 9.7789 10.2962 -5.02 81.949 81.805 0.18

1.000 518.165 9.7760 9.8881 -1.13 89.903 89.788 0.13
1.000 523.178 9.7730 9.8521 -0.80 98.128 97.977 0.15
1.000 528.134 9.7701 9.8478 -0.79 106.502 106.279 0.21
1.000 533.193 9.7671 9.8112 -0.45 115.115 114.944 0.15
1.000 543.186 9.7612 9.7665 -0.05 132.563 132.530 0.02
1.000 553.211 9.7554 9.7121 0.45 150.334 150.700 -0.24
1.000 563.218 9.7496 9.6603 0.92 168.274 169.253 -0.58
1.000 573.177 9.7439 9.6142 1.35 186.291 188.052 -0.94

I.UUU ~IJ.IJ7 11.U766 11.2T22 -1. 74 !s2.7J7 52.:500 0.29

1.000 523.168 11.0698 11 .1357 -0.59 101. 521 101.285 0.23
1.000 533.129 11 .0631 11.0966 -0.30 121.318 121.111 0.17
1.000 553.179 11.0498 10.9890 0.55 162.876 163.593 -0.44
1.000 573.164 11.0366 10.8923 1.32 205.760 208.322 -1.23

1.000 513.094 12.3824 12.4278 -0.37 85.630 85.442 0.22

1.000 518.104 12.3786 12.4075 -0.23 96.699 96.531 0.17
1.000 523.176 12.3747 12.3776 -0.02 108.169 108.147 0.02
1.000 528.184 12.3709 12.3616 0.08 119.868 119.954 -0.07
1.000 533.172 12.3671 12.3439 0.19 131. 758 132.011 -0.19

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 843

Table 9n. Comparison of ID code (99) Straty PpT data with values calculated
from Eq. (6) - Continued

Wt. T (J Calc. (J .1('lp P Calc. P .1 PIP

K molll molll % bar bar %

1.000 543.099 12.3596 12.3087 0.41 156.027 156.757 -0.47

1.000 553.143 12.3521 12.2617 0.74 181.038 182.648 -0.88
1.000 563.198 12.3447 12.2131 1.08 206.457 209.258 -1.34
1.000 573.200 12.3373 12.1689 1. 38 232.108 236.282 -1.77

1.000 508.166 13.4168 13.4388 -0.16 79.772 79.613 0.20

1.000 :'iD.l77 13.4126 13.4276 -0.11 92.379 92.238 0.15
1.000 518.130 13.4084 13.4225 -0.11 105.305 105.144 0.15
1.000 523.168 13.4042 13.4024 0.01 118.628 118.652 -0.02
1.000 528.108 13.4001 13.3910 0.07 132.089 132.230 -0.11
1.000 533.127 13.3959 13.3733 0.17 145.929 146.324 -0.27
1.000 543.162 13.3876 13.3368 0.38 174.186 175.279 -0.62
1.000 553.111 13.3795 13.3025 0.58 202.876 204.836 -0.96
1.000 563.117 13.3714 13.2660 0.79 232.157 235.253 -1.32
1.000 573.116 13.3633 13.2300 1.01 261.770 266.207 -1.67

1.000 498.122 14.7640 14.7945 -0.21 66.474 66.051 0.64

1.000 503.121 14.7591 14.7907 -0.21 81.409 80.881 0.65
1.000 508.109 14.7544 14.7821 -0.19 96.712 96.176 0.56
1.000 513.119 14.7496 14.7720 -0.15 112.455 111.966 0.44
1.000 518.110 14.7449 14.7617 -0.11 128.490 128.080 0.32
1.000 523.121 14.7403 14.7491 -0.06 144.833 144.596 0.16
1.000 528.175 14.7356 14.7337 0.01 161.501 161.557 -0.03
1.000 533.193 14.7310 14.7203 0.07 178.328 178.666 -0.19
1.000 543.107 14.7219 14.6999 0.15 212.348 213 .147 -0.38
1.000 553.109 14.7129 14.6736 0.27 247.094 248.700 -0.65
1.000 563.205 14.7038 14.6440 0.41 282.4,96 285.206 -0.95
1.000 573.121 14.6949 14.6231 0.49 317.986 321.556 -1.11

1.000 488.117 16.1127 16.1249 -0.08 61.053 60.714 0.56

1.000 493.112 16.1072 16.1233 -0.10 ·79.024 78.523 0.64
1.000 498.169 16.1017 16.1160 -0.09 97.544 97.052 0.51
1.000 503.123 16.0965 16.1143 -0.11 116.298 115.632 0.58
1.000 508.189 16.0912 16.1044 -0.08 135.543 135.008 0.40
1.000 513.178 16.0860 16.0995 -0.08 155.014 154.428 0.38
1.000 518.102 16.0810 16.0973 -0.10 174.632 173.882 0.43
1.000 523.119 16.0759 16.0899 -0.09 194.649 193.964 0.35
1.000 528.086 16.0708 16.0852 -0.09 214.812 214.070 0.35
1.000 533.210 16.0657 16.0749 -0.06 235.535 235.033 0.21
1.000 543.106 16.0557 16.0668 -0.07 276.695 276.036 0.24
1.000 553.203 16.0457 16.0512 -0.03 318.834 318.479 0.11

0.000 478.140 17.0218 17.0738 -0.30 55.934 53.799 3.97

1.000 483.166 17.0158 17.0705 -0.32 76.288 73.833 3.33
1.000 488.146 17.0100 17 .06n -O.J~ 97.U43 94.173 3.U5
1.000 493.156 17.0043 11.0658 -0.36 118.268 115.013 2.78
1.000 498.116 16.9981 11.0652 -0.39 139.805 136.129 2.70
1.000 503.104 16.9932 17.0628 -0.41 161.712 157.639 2.58
1.000 508.170 16.9876 17.0569 -0.41 184.049 179.779 2.38
1.000 513.173 16.9823 17.0293 -0.28 204.943 201. 915 1.50
1.000 518.122 16.9769 17.0232 -0.27 227.137 224.024 1.39
1.000 523.101 16.9115 17.0189 -0.28 249.811 246.493 1.35
1.000 528.115 16.9662 17.0144 -0.28 272.779 269.256 1.31
1.000 533.115 16.9609 11.0086 -0.28 295.757 292.138 1.24
1.000 538.118 16.9555 17.0051 -0.29 319.071 315.111 1.24
1.000 538.177 16.9555 17.0035 -0.28 319.220 315.446 1.20

0.000 448.138 18.8836 18.8750 0.05 25.435 26.095 -2.53

1.000 4~3.164 IlL ~2I4 HLl:I2U4 0.U1 46.030 40.114 -0.17
1.000 458.137 18.8144 18.8172 -0.01 70.792 70.561 0.33
1.000 463.168 18.8077 18.8123 -0.02 96.198 95.794 0.42
1.000 468.170 18.8012 18.8099 -0.05 122.095 121.291 0.66
1.000 473.119 18.7949 18.8096 -0.08 148.291 146.877 0.96
1.000 478.094 18.7886 18.8086 -0.11 174.889 172.895 1.15
1.000 483.179 18.1823 18.8052 -0.12 202.151 199.779 1.19
1.000 488.169 18.1762 18.8050 -0.15 229.486 226.396 1.36
1.000 493.111 18.7702 18.8075 -0.20 257.090 252.962 1.63
1.000 498.130 18.7641 18.808-1 -0.24 285.176 280.121 1.80
1.000 503.112 18.1581 18.8109 -0.28 313.445 307.239 2.02
1.000 508.165 18.1520 18.8118 -0.32 342.100 334.875 2.16

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

844 ROBERT D. GOODWIN

Table 9n. Comparison of lJ) code (99) Straty PI,T data with values calculated
from Eq. (6) - Continued

Wt. T I' Odc. I' C!./'/I' P Calc. P C!.p/P

K molll moll I % bar bar %

0.000 443.181 19.2634 19.2185 0.23 28.485 32.421 -12.14

1.000 448.168 19.1994 19.1693 0.16 49.946 52.662 -5.16
1.000 453.131 19.1923 19.1652 0.14 75.674 78.251 -3.29
1.000 458.175 19.1854 19.1610 0.13 102.300 104.729 -2.32
1.000 463.153 19.1788 19.1576 0.11 129.056 131.255 -1.68
1.000 468.182 19.1723 19.1552 0.09 156.563 158.401 -1.16
1.000 473.184 19.1659 19.1536 0.06 184.319 185.698 -0.74
1.000 478.177 19.1.596 19.152.5 0.04 212.374 213.198 -0.39
1.000 483.176 19.1533 19.1530 0.00 240.915 240.948 -0.01
1.000 488.. 121 19.1471 19.1558 -0.05 269.660 268.592 0.40
1.000 493.104 19.1409 19.1566 -0.08 298.594 296.615 0.67
1.000 498.180 19.1347 19.1566 -0.11 328.161 325.321 0.87

0.000 433.112 20.1080 20.0861 0.11 63.077 65.763 -4.09

1.000 443.132 20.0935 20.0726 0.10 120.849 123.607 -2.23
1.000 453.116 20.0798 20.0638 0.08 180.444 182.706 -1.24
1.000 1\63.157 20.0661\ 20.0579 0.0-1 21\ 1.931\ 21\3.208 -0.52
1.000 473.134 20.0533 20.0580 -0.02 304.838 304.106 0.24

0.000 378.164 22.1156 22.1053 0.05 26.325 28.396 -7.29

1.000 383.118 22.0516 22.0518 -0.00 51.245 51.195 0.10
1.000 388.164 22.0430 22 .0364 0.03 84.802 86.181 -1.60
1.000 393.122 22 .0351 22.0239 0.05 118.666 121.089 -2.00
1.000 398.142 22.0273 22.0101 0.08 153.008 156.820 -2.43
1.000 403.144 22.0198 21.9984 0.10 187.935 192.787 -2.52
1.000 408.159 22.0123 21.9873 0.11 223.326 229.105 -2.52
1.000 413.133 22.0049 21.9783 0.12 259.051 265.330 -2.37
1.000 418.150 21.9976 21.9698 0.13 295.386 302.090 -2.22
1.000 423.134 21.9903 21. 9629 0.12 331. 991 338.730 -1.99

220 data points, lC!.p/1'1 rms = 0.675%, ilp/ p avo = -0.02%, IC!.P/ PI avo = 0.59%,
weight = 81.09%.

absolute relative pressure deviations in percent. The weight AI= 3.63861627, A6 = - 3286.183 71,
gives the relative least-squares weight assigned to this data A2= - 31.383 548 8, A7= 3538.294 44,
source, obtained as the sum of weights for all of his points,
divided by the sum of weights for all of the 400 data used, in
A3= 197.493 130, Ag = - 2181.106 71,
percent. The largest relative density deviations in the data of A4= - 769.861 023, A9= 585.635 19,
Straty63 at ID = 99 in Table 9 apparently occur near As =
1956.07428.
0'0 = 0.825 rather than near 0' = 1.0, the critical density. Specific heats are obtained from C; (n = dIr (T) 1dT.
Behavior of the calculated critical isotherm is given in Entropies are represented using x(n == T 1100,
Table 10. As a consequence of constraints on the EOS, there
are no negative slopes, (ap lap) T' along this isotherm. SeCT) = BIln(1 + T) + /(x)
R i=2
Bi ( ex±
(1 + ex)
)i-2,(8)

lex) == 1/( 1 + d In(1 + llx)],

3. Thermal Properties and Computations where e = 0.30, d = 0.25, and
3.1. Functions for Ideal Gas States BI =4.95694573, B6 = - 1462.31695,
B2 = 3.625593 78, B7 = 2666.79301,
For the hypothetical ideal gas states at F = 1.013 25
bar (1 atm), spectroscopic specific heats, enthalpics, and B", = - 20.482 766 8, Dg = - 2295.923 87.
entropies have been generously contributed by Dr. Jing B4 = 10.181 7794, B9 = 786.75536,
Chao. II His "molecular model treats the methanol vapor as Bs = 340.165 534.
a mixture of monomers, dimers, and tetramers." We have The rms relative deviations in percent are given at the bot-
formulated these data (Table 11), and have given interpolat- tom of Table 11, where for C; (T)IR the first three data are
ed results in Table 12. ignored.
Enthalpies are represented by using x ( T) == Til 00,
E=2.0, 3.2. The Homogeneous Domain
9
[HO(n -E~]IRT=4+ L Ai [exp( -€lx)F, (7) The homogeneous domain of Fig. 1 includes all regions
which can be reached by integration along isotherms, start-
i=I
where ing at zero density, without crossing the vapor-liquid coexis-

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 845

Table 10. The critical isotherm for methanol

pi Pc P Z aPlap aplaT aPlaT a 2 PlaT 2

bar bar/(molll) (moll1)/K bar/K (bar/K)/K

0.50 77.363 0.43219 3.75351 -0.2153E+00 0.80804 -0.004435

0.52 77.952 0.41872 3.25868 -0.2584E+OO 0.84196 -0.004460
0.:54 71).461 0.40565 2.61265 -0.3111E;-00 0.87496 -0.004448
0.56 78.899 0.39354 2.41265 -0. 3759E+OO 0.90695 -0.004399
0.58 79.274 0.38178 2.05585 -0.4562E+OO 0.93787 -0.004310
0.60 79.592 0.37053 1.73941 -0.5563E+00 0.96768 -0.004181
0.62 79.861 0.35979 1.46045 -0.6822E+00 0.99634 -0.004010
0.64 80.085 0.34952 1.21609 -0. 8419E+00 1.02384 -0.003798
0.66 80.271 0.33972 1.00349 -0.1047E+Ol 1.05018 -0.003545
0.68 80.424 0.33036 0.81984 -0.1312E+Ol 1.07539 -0.003250
0.70 80.548 0.32141 0.66239 -0. 1660E+Ol 1.09948 -0.002914
0.72 80.648 0.31287 0.52853 -0. 2124E+01 1.12251 -0.002540
0.74 80.727 0.30471 0.41576 -0.2753E+01 1.14454 -0.002128
0.76 80.789 0.29692 0.32171 -0.3623E+01 1.16564 -0.001680
0.78 80.836 0.28948 0.24418 -0.4857E+01 1.18590 -0.001198
0.80 80.871 0.28237 0.18112 -0.6655E+01 1.20540 -0.000684
0.82 80.897 0.27557 0.13065 -0.9371E+01 1.22425 -0.000141
0.84 80.916 0.26907 0.09103 - 0 . 1365E+02 1.24255 0.000429
0.86 80.929 0.26285 0.06069 -0.2077E+02 1.26040 0.001024
0.88 80.937 0.25690 0.03818 -0. 3347E+02 1.27792 0.001641
0.90 80.942 0.25121 0.02217 -0.5842E+02 1.29521 0.002278
0.92 80.944 0.24576 0.01147 -0. 1144E+03 1.31239 0.002931
0.94 80.946 0.24053 0.00494 -0.2691E+03 1. 32956 0.003599
0.96 80.946 0.23552 0.00152 -0. 8862E+03 1.34682 0.004279
0.98 80.946 0.23072 0.00020 -0. 6656E+04 1.36428 0.004969
1.00 &0.946 0.22610 0.00000 1 38202 0.005667
1.02 80.946 0.22167 0.00021 -0.6585E+04 1.40014 0.006371
1.04 80.947 0.21741 0.00158 -0. 8992E+03 1.41875 0.007078
1.06 80.947 0.21331 0.00518 -0.2774E+03 1.43797 0.007785
1.08 80.949 0.20936 0.01210 - 0 . 1204E+03 1.45793 0.008490
1.10 80.951 0.20556 0.02356 -0. 6276E+02 1.47873 0.009191
1.12 80.957 0.20190 0.04090 -0. 3669E+02 1.50051 0.009884
1.14 80.966 0.19838 0.06561 -0.2322E+02 1.52340 0.010566
1.16 80.979 0.19499 0.09937 -0. 1557E+02 1.54750 0.011235
1.18 81.000 0.19174 0.14407 -0.1092E+02 1.57294 0.011888
1.20 81.028 0.18861 0.20177 -0.7929E+Ol 1.59984 0.012522
1.22 81.068 0.18561 0.27479 -0.5926E+Ol 1.62831 0.013135
1.24 81.122 0.18273 0.36564 -0.4536E+Ol 1.65846 0.013723
1.26 81.192 0.17999 0.47710 -0.3543E+01 1.69039 0.014286
1.28 81.283 0.17738 0.61215 -0.2817E+Ol 1.72421 0.014819
1.30 81.399 0.17490 0.77402 -0.2274E+Ol 1.76000 0.015321
1.32 81.545 0.17256 0.96614 -0.1861E+Ol 1.79786 0.015790
1.34 81. 726 0.17036 1.19221 -0. 1542E+Ol 1. 83787 0.016224
1.36 81.948 0.16831 1.45608 -0. 1291E+Ol 1.88009 0.016621
1. 38 82.218 0.16641 1.76186 0.1092E,01 1.92459 0.016980
1.40 82.542 0.16469 2.11380 -0. 9326E+00 1.97142 0.017300
1.42 82.931 0.16313 2.51635 -0.8030E+00 2.02063 0.017579
1.44 83.391 0.16176 2.97410 -0.6968E+00 2.07225 0.017817
1.46 83.933 0.16058 3.49180 -0.6089E+00 2.12632 0.018013
1.48 84.568 0.15961 4.07431 -0. 5358E+00 2.18286 0.018168
1.50 85.306 0.15885 4.72660 -O.4743E+00 2.24186 0.018280

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

846 ROBERT D. GOODWIN

Tuble 11. Idea I gas st a te j U Ill! inns for methanol

T [lr(7')..E~]/ NT % .',~,('I')/ If % (',,(T)/ R %

K (data) (calc.) Dev. (data) (ca Ie,) Dev. (data) (calc,) Dev.
250.0 4.5132 4.5133 -0.0013 27.9259 27.9259 -0.0000 4.981 4.981 0.003
300.0 4.6171 4.6171 0.0009 28.8616 28.8615 0.0005 5.311 5.310 0.005
350.0 4.7456 4.7456 0.0{)03 29.7107 29.7112 -0.0015 5.734 5.734 -0.006
400.0 4.8984 4.8985 -0.0009 30.5081 30.5076 0.0017 6.208 6.208 -0.004
450.0 5.0711 5.0712 -0.0005 31.2671 31.2671 -0.0000 6.697 6.697 0.001
500.0 5.2579 5.2580 -0.0007 31.9971 31.9977 -0.0018 7.179 7.179 0.006
550.0 5.4538 5.4538 0.0014 32.7043 32.7038 0.0016 7.642 7.641 0.003
600.0 5.6546 5.6545 0.0005 33.3875 33.3877 -0.0008 8.081 8.081 -0.001
650.0 5.8572 5.8573 -0.0004 34.0514 34.0511 0.0009 8.494 8.495 -0.004
700.0 6.0597 6.0597 -0.0006 34.6948 34.6950 -0.0005 8.883 8.884 -0.005
750.0 6.2603 6.2603 -0.0002 35.3202 35.3205 -0.0007 9.249 9.249 -0.004
800.0 6.4579 6.4579 -0.0008 35.9288 35.9284 0.0010 9.592 9.592 -0.000
850.0 6.6519 6.6519 0.0000 36.5193 36.5197 0.0009 9.915 9.914 0.003
900.0 6.8417 6.8416 0.0006 37.0954 37.0950 0.0012 10.218 10.217 0.004
950.0 7.0269 7.0269 0.0004 37.6547 37.6551 -0.0010 10.502 10.502 0.002
1000.0 7.2074 7.2074 0.0007 38.2007 38.2006 0.0003 10.769 10.770 -0.006
rms 0.0007% rms = O,{XH 0% rms OJ)()4%

tence boundaries. In this report, the numerical values of E

(15)
andH are based on E = 0 for saturated liquid at the triple p
point. They were determined by adding the selected value and
H~ =
E~ =
35 374.762 J/moltotheideal gas state values of
(E' - E~) and (lr - E~) from Eq. (7).
AG= (H -E~) -Ho - T(S-SO),
We start computations for thermal properties in the ho- where AG is the isothermal Gibbs free-energy change, and
mogeneous domain with ideal gas state functions at zero the selected value E ~ was added to our tabulated values for
density, and then integrate numerically along isotherms (see H(p,T) relative to (11 - E~) from Eq. (7).
Goodwin26) using the EOS in the following relations,
3.3. Properties at Coexistence
M= f[P- T(:~)l ;, , (9)
To obtain specific heats for compressed liquid states via
Eq. (10) it is necessary to start with values Cu (T)" for the
Tf(aaT2p)dp2P'
2
(10)
isochoric specific heat, Cv (p, T) at the liquid coexistence
boundary. Also, for the computation of properties along iso-
bars, it is economical to have formulas for isochoric specific
and
heats at the saturated vapor boundary, and for enthalpies
+ r [R _(ap)/p] dp . (11)
p
AS=R In (~)
(pRT) Jo aT p
and entropies on the saturated liquid boundary.

3.3.a. Specific Heats on the Vapor Boundary

E4uatioll (11) is for usc with initial entropies ill hypotheti-
cal ideal gas states at F' = 1.013 25 bar H atm). For all Data for Cv ( T) 0-' the isochoric specific heat at the va-
other initial states, por boundary, are produced with Eq. (10), and have a
"hook" approaching Tc due to the behavior of isochore cur-
(Ila) vatures. At the critical point, Cu (T)" has the value
Cv = 161.14 (J/mol)/K. Let x(T)==T/Tc ' u(T)
In each (p, T) state, reached by above integrations, we com- == (1 - x), then
pute
H=E+P/p, (12) In(UCU(T)0-)=A1Ut:+
Cv
±
;=2
Aiu i - 1
, (16)

C. = C, + T [(;~)/( ::) lfo 2

, (13) whereu==p/pc 1 E = 0.37, and

and AI = 2.619 990, A4 = 63.387330,

A2 = 8.540 236, As = - 189.708463,
(14)
A3 = 9.176 559, A6 = 205.567230.
The fugacity/pressure coefficient!/P for any state is com- For 42 data at 180.0,T<512.3 K therms relative devi-
puted by reference to the hypothetical ideal gas state at the ation for Cv (T)" is 0.24%, and the largest deviation of a
same temperature and at F' = 1.013 25 bar, datum from the calculated value is - 0.60% at 180 K.

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 847

Table 12. Interpolated ideal gas state functions for methanol

T C(t)-E~ Er(T)-E~ S"(T) C~(T) C;(T)

K J/mo! J/mo! J/(mol·K) J/(mo!·K) J/(mol·K)
175.59 4936.4 6396.3 218.043 30.81 39.12
180.00 5072.4 6569.0 219.015 30.90 39.21
190.00 5382.6 6962.3 221.142 31.13 39.44
200.00 5695.0 7357.9 223.170 31.37 39.68
210.00 6010.1 7756.1 225.112 31.64 39.96
220.00 6328.0 8157.2 226.977 31.95 40.26
230.00 6649.1 8561.5 228.773 32.29 40.60
240.00 6973.9 8969.4 230.509 32.67 40.99
250.00 7302.8 9381.4 232.190 33.10 41.41
260.00 7636.1 9797.8 233.823 33.57 41.88
270.00 7974.3 10219.2 235.413 34.08 42.39
273.15 8081.9 10353.0 235.906 34.25 42.56
280.00 8317.8 10645.8 236.965 34.63 42.94
290.00 8667.0 11078 .2 238.482 35.22 43.53
298.15 8956.1 11435.0 239.696 35.72 44.04
300.00 9022.2 11516.6 239.969 35.84 44.15
310.00 9383.9 11961.4 241.427 36.49 44.81
320.00 9752.2 12412.8 242.861 37.18 45.49
330.00 10127.5 12871. 3 244.272 37.88 46.20
337.67 10420.2 13227.7 245.340 38.44 46.76
340.00 10510.0 13336.9 245.662 38.61 46.93
350.00 10899.8 13809.9 247.034 39.36 47.68
360.00 11297.3 14290.5 248.388 40.13 48.44
370.00 11702.5 14778.9 249.726 40.91 49.22
380.00 12115.5 15275.0 251.049 41. 70 50.02
390.00 12536.5 15779.2 252.359 42.50 50.81
400.00 12965.6 16291.4 253.656 43.31 51.62
410.00 13402.7 16811.6 254.940 44.12 52.43
420.00 13847.9 17340.0 256.213 44.93 53.24
430.00 14301.2 17876.5 257.476 45.74 54.06
440.00 14762.7 18421.1 258.728 46.56 54.87
450.00 15232.4 18973.9 259.970 47.37 55.68
460.00 15710.1 19534.8 261.203 48.18 56.49
470.00 16195.9 20103.7 262.426 48.98 57.30
480.00 16689.8 20680.7 263.641 49.79 58.10
490.00 17191.6 21265.7 264.847 50.58 58.90
500.00 17701.4 21858.6 266.045 51.37 59.69
510.00 18219.0 22459.4 267.235 52.16 60.47
520.00 18744.5 23068.0 268.416 52.93 61.25
530.00 19277.7 23684.4 269.590 53.70 62.02
540.00 19818.5 24308.4 270.757 54.47 62.78
550.00 20367.0 24939.9 271.916 55.22 63.53
560.00 20922.9 25579.0 273.067 55.97 64.28
570.00 21486.3 26225.6 274.211 56.71 65.02
580.00 22057.0 26879.4 275.349 57.44 n~.7~
590.00 22635.0 27540.5 276.479 58.16 66.47
600.00 23220.1 28208.8 277.602 58.87 67.19
610.00 23812.4 28884.2 278.719 59.58 67.89
620.00 24411. 7 29566.7 279.828 60.27 68.59
630.00 25017.9 30256.0 280.931 60.96 69.28
640.00 25630.9 30952.2 282.028 61.64 69.96
650.00 26250.7 31655.1 283.117 62.31 70.63
660.00 26877.2 32364.7 284.201 62.98 71.29
670.00 27510.2 33080.9 285.278 63.63 71.95
680.00 28149.8 33803.7 286.349 64.28 72.59
690.00 28795.8 34532.8 287.413 64.92 73.23
700.00 29448.2 35268.3 288.471 65.55 73.86

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 ROBERT D. GOODWIN

;1.:Ui. :~;illlII:lted Liquid En1halples and Entropies Table 13. Comparison of ID code
(10) Carlson I Westrum
The hLal of vaporization in J/mol from the Clapeyron ('("F( T) data with values
equation, calculated from Eq. (22)

dPa ) (17)
Qvap =.l:llIvap = lOOT ( dT (v g - VI)' T {',7 ('o %
K J/(mol·K) J/(mo!·K) Dev.
yields the enthalpy and entropy of saturated liquid, (daw) (calc.)

(18) 180.00 70.75 71.04 -0.41

Hu =.HI = (H g - Qvap),
190.00 70.79 70.78 0.02
Sa =,SI = (Sg - QvapIT). (19) 200.00 70.96 70.77 0.26
210.00 71.25 71.01 0.34
The following formula for H 0' (T), the enthalpy of satu- 220.00 71.71 71.48 0.33
rated liquid, uses arguments u (T) =. (Te - T) I (Te - T t ) 230.00 72.34 72.15 0.26
240.00 73.09 73.02 0.10
and the exponent f3 = 0.35, 250.00 74.06 74.07 -0.02
(Ha -He) 6 260.00 75.14 75.29 -0.19
U + (U f3 - U) L i
Ai U - 1, (20) 270.00
273.15
76.44
76.90
76.65
77 .11
-0.28
-0.27
(H t -He) 1= I
280.00 77.95 78.16 -0.27
Ht= 0.0, He = 30030.1 J/mol, 290.00 79.62 79.78 -0.20
298.15 81.13 81.19 -0.08
Al= 0.421 081 10, A4 = 5.541 31457, 300.00 81.50 81.52 -0.02
A2 = 0.689955 69, As = - 5.079075 50, 310.00 83.60 83.36 0.28
320.00 85.94 85.29 0.76
A3 = - 2.575 06538, A6 = 1.46899092.
For41 data at 190.0<T<512.3 K, the rms relative deviation
The following formula for C u (T) u' the isochoric spe-
for Hu (T) is 0.34%. The maximum deviations of data from
cific heat at the liquid boundary, uses arguments x== (T /
the calculated values are - 1.70% at 190 K, and - 2.61 %
T e ), U=. (1 - x), and parameters a = 1, E = 0.70. The criti-
at 180 K.
cal-point value ofCv (T)u is Cu = 161.14 (J/mol)/K,
The following formula for Su (T), the entropy ofsatu-
rated liquid, uses arguments x ( T) == T lTc, u ( T) =. (1 - x), Cu(T)aICu =Ao + (1-Ao)f(x) exp[a(1- llx)],
and exponent f3 = 0.35, 6
f(x) == 1 + A1u + E
L Aju l
- 1, (24)
(Su - Se) f3
=Atu +A 2 In(x) +L 5
Aj(x
1-2
- 1),
where Ao = 58/Cv , and
i=2

CSt -Se) i=3

(21)
Al = - 18.505 575, A4 = 136.856019,
St = 90.083, Se = 196.128 (J/mol)/K,
A2 = 35.208953, As = - 175.234460,
Al = 0.351 885933, A4 - - 3.604841 554,
A3 = - 64.875 865, A6 = 94.705808.
A2 = - 1.315787023, As = 1.274787 183.
For 37 Cu (T)u data derived by Eq. (23) at 17S.59..;;T..;;;500
A3 = 4.062495 073, K, the rms relative deviation is 0.10%. The behavior of these
For 44 Sa (T) data at 175.59<T..;;;512.60 the rms relative data is shown in Fig. 3.
deviation is 0.11 %, and the maximum deviation of a datum
from the calculated value is + 0.26 (J/mol)/K at 200 K. 3.4. Compressed Liquid States
3.3.G. Saturated Liquid Specific Heats For thermal pl-operlies aloll~ isobars, Table 17, we use
Specific heats Ca (T) along the saturated liquid path, Eq. (24) for Cv (T)a' and the formulated Ha (T), So' (T),
are computed using the relation Ca (T) TdSu (T)ldT. Eqs. (20) and (21).
From Eq. (21) with x = T lTc, U = (1 - x), Sn Then, starting with E, S, e" on the saturated liQuid
= (St Se), f3 0.35, boundary, we integrate along isotherms up to any given
(p,T), (P,T) point, using Eqs. (9), (10), and (11a), and
Ca(T) = Sn x!(x) ,
then apply Eqs. (12), (l3), and (14) at that point on the
A
+L
5
I(x) = - Ad3u p- 1 + _2 Ai (t - 2)Xi-' 3. (22) PpT surfac;e.
X 1=3

Experimental data of Carlson and Westrum 10 for CO' ( T) 3.5. Comparisons

were used in simultaneous fitting with our derived S", (T)
data to obtain coefficients Ai for Eq. (21). These data are Saturated liquid specific heat data CO' (T) of Carlson
compared with calculated results in Table 13. The isochoric and Westrum 10 are compared with our results from Eq. (22)
specific heat at this liquid boundary is computed by the rela- in Table 13. Deviations are under 0.5% except at their high w

tion est tempera.ture, 320 K.

Single-phase enthalpy differences data of Wormald, et
Cu(T)a = Ca(T) + T(;~)(d;)frf, (23) al. 69 have as reference state the saturated liquid at 298.15 K,
where our value of the enthalpy from Table 16 is 9146.7 II
where Pi is the density of saturated liquid. mol. In Table 14 we compare enthalpy differences at their

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 849

200~--~----------~~--------~----------~--~

~ COPOI
-
.....
0
E
150 Methanol

Isochoric Specific Heats

"
~
at the •
Liquid Boundary
~

-
I-
.
b
I
)
~

> 100
0
/
~- -------- -----""
--- .------ ."..

50~---20~O------------G~OO------------4~O-O-----------6-00-----

T. K
FIG. 3. Derived Cu (T)O' at the liquid boundary.

pressures along their isotherms. The largest differences oc- (26)

cur along the near-critical isotherm at 515.2 K, as seen in
Fig. 4.
4. Tables of Thermophysical Properties 4.3. Properties Along Selected Isobars
All of the following tabulated properties are interpolat- Table 17 gives properties along isobars, computed by
ed or extrapolated in regions for which no Pp T data exist; see methods of Sec. 3, using EOS Eq. (6). Each isobar starts at
Table 7. No melting line is used here. the triple-point temperature, hence is extrapolated into the
pseudosolid region. Each page for isobars atP <Pc contains
4.1. The Joule-Thomson Inversion Locus a blank line for the transition from saturated liquid to satu-
The P-p~T coordinates of the louIe-Thomson inver- rated vapor at the coexistence temperature. As described in
sion, (aT lap)H = 0, are presented in Table 15. For each Sec. 3.4, the properties for compressed liquid states at T < Tc
temperature the density is iterated to satisfy the condition, are based on formulated enthalpies and entropies for the sat-
T(ap laT) = p(ap lap), by starting with an initial trial den- urated liquid, Eqs. (20) and (21). Small discontinuities at
sity,pu T = Tc along isobars at P> Pc are expected, due to change
Pi/Pc =exp[1.01322-0.16444(T/Tc )], (25) in the paths of computation from T < Tc to T> T c' Sec. 3.
which is a good approximation of the p (T) relation for the
Joule-Thomson locus.
5. Comments
4.2. Properties at Coexistence The consistency among various data for saturated va-
Table 16 gives some properties at the liquid coexistence por densities in Table 6 (see Fig. 2) is very poor, and the BOS
boundary, computed by methods of Sec. 3.3. Here, dP",ldT representation of some of the Straty Pp T data (at reduced
is the slope of the vapor-pressure curve, Eq. (1); dpI I dT is densities near 0.8 and near coexistence) is seen in Table 9 to
the slope of the saturated liquid densities curve, Eq. (2); be rather poor.
whereasBP laTandaP lap are slopes ofthesingle-phasePpT Thus a meticulous experimental examination of all Pp T
surface at the liquid boundary. In the second part of Table characteristics of the coexistence region is needed for an im-
16, C v is the isochoric specific heat at the liquid boundary, proved correlation of the thermodynamic properties of
whereas CO' is the specific heat along the saturated liquid methanol. Specific heat and speed of sound data over wide
path; and Cp is the isobaric specific heat at the saturated ranges of the PpT surface clearly would strengthen confi-
liquid boundary. Properties of the saturated vapor are given dence in derived properties. The formulation of a BWR-type
in Table 17 at the coexistence boundary. of EOS, by simultaneous fitting of PpT and enthalpy data,
In Table 17 are given values of the louIe-Thomson co- may be desirable, aided by the background given in the pres-
efficient, Il == (aT lap) H' computed by the relation, ent report.

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

850 ROBERT D. GOODWIN

Table 14. Comparison of ID code (69) Wormald Table 14. Comparison of ID code (69) Wormald
!Y.fI data with calculated values !Y.11 data with calculated values -
Continued
p (l !Y.H !Y.JI Diff. %
bar 010111 kllmol kllmol Dev. P (l !Y.H !Y.H Diff. %
(data) (calc.) bar molil kllmol klima! Dev.
(data) (calc.)
T = 373.2 K
T = 498.2 K
1.0 0.033 41.162 40.637 0.524 1. 29
2.1 0.072 40.819 40.176 0.643 1.60 1.0 0.025 48.483 47.669 0.814 1. 71
3.4 0.121 39.665 39.483 0.183 0.46 8.3 0.209 47.919 47.013 0.906 1. 93
7.4 22.189 6.796 6.744 0.052 0.77 14.7 0.381 47.343 46.363 0.979 2.11
30.2 22.300 6.873 6.786 0.087 1. 28 21.8 0.587 46.458 45.511 0.948 2.08
50.7 22.395 6.831 6.825 0.006 0.09 29.8 0.850 45.564 44.374 1.190 2.68
117.2 22.678 7.129 6.959 0.171 2.45 33.8 0.999 44.984 43.727 1.257 2.87
36.0 1.086 44.520 43.346 1.173 2.71
T = 398.2 K 43.0 1.403 43.597 41.993 1.604 3.82
52.0 1.944 41.790 39.809 1.980 4.97
1.0 0.031 42.751 41.985 0.766 1. 82 57.5 2.424 40.181 38.034 2.148 5.65
1.8 0.057 42.517 41.766 0.751 1. 80 62.5 3.141 38.162 35.662 2.500 7.01
3.4 0.110 42.027 41.271 0.755 1. 83 68.0 14.883 23.833 22.201 1.632 7.35
4.6 0.152 41.726 40.833 0.893 2.19 73.9 15.223 23.750 22.008 1.741 7.91
5.9 0.200 40.790 40.277 0.513 1.27 83.0 15.627 23.455 21.787 1.668 7.66
9.0 21.242 9.475 9.226 0.249 2.69 96.4 16.079 22.997 21.550 1.447 6.71
43.0 21.448 9.360 9.267 0.093 1.00 117.0 16.605 22.789 21.293 1.496 7.02
118.4 21.846 9.654 9.379 0.276 2.94 129.2 16.860 22.507 21.177 1.330 6.28
T = 423.2 K T= 510.2 K
1.0 0.029 43.828 43.351 0.477 1. 10 35.6 1.005 45.930 44.841 1.089 2.43
2.7 0.080 43.453 43.009 0.444 1.03 48.6 1.544 43.930 42.789 1.141 2.67
4.4 0.133 43.523 42.632 0.891 2.09 58.8 2.125 42.325 40.736 1.589 3.90
6.8 0.211 42.825 42.010 0.815 1.94 64.5 2.567 41.078 39.306 1.772 4.51
12.0 0.410 41.085 40.176 0.909 2.26 69.0 3.033 39.617 37.919 1.698 4.48
13.2 0.465 40.537 39.615 0.922 2.33 74.0 3.834 38.217 35.794 2.423 6.77
18.9 20.197 12.477 11. 843 0.634 5.35 75.5 4.228 37.269 34.862 2.406 6.90
33.6 20.319 12.487 11.843 0.644 5.44 81.2 12.875 27.169 25.006 2.163 8.65
71.6 20.603 12.442 11.855 0.588 4.96 83.7 13.286 26.858 24.734 2.124 8.59
120.0 20.918 12.481 11.890 0.591 4.97 86.0 13.570 26.441 24.548 1.893 7.71
89.5 13.909 26.140 24.330 1 .811 7.44
T = 448.2 K 100.5 14.639 25.429 23.873 1.556 6.52
113.5 15.216 25.035 23.529 1.505 6.40
1.0 0.027 45.260 44.749 0.511 1.14
3.3 0.092 44.866 44.403 0.463 1.04
5.6 0.158 44.831 44.034 0.797 T = 515.2 K
1. 81
8.2 0.237 44.:273 43.562 0.711 1. 63 54.2 1.761 43.687 42.579 1.108 2.60
12.0 0.361 43.731 42.752 0.979 2.29 60.8 2.140 42.815 41.318 1.497 3.62
15.8 0.499 42.866 41.773 1.093 2.62 67.2 2.604 41.469 39.882 1.587 3.98
18.5 0.610 42.216 40.945 1.270 3.10 77.7 3.842 38.509 36.584 1.924 5.26
21.9 0.774 41.283 39.683 1.600 4.03 82.1 5.089 3f..897 3~. 939 1.9.';7 8.71
27.3 18.895 15.358 14.688 0.670 4.56 85.4 10.320 34.183 27.620 6.563 23.76
47.8 19.143 15.704 14.640 1.064 7.27 85.8 10.739 33.872 27.289 6.583 24.12
73.6 19.415 15.646 14.599 1.047 7.17 88.7 12.059 29.127 26.309 2.818 10.71
112.5 19.768 15.534 14.566 0.968 6.64 89.5 12.259 28.582 26.167 2.415 9.23
91.6 12.670 26.765 25.878 0.887 3.43
T 473.2 K 99.2 13.573 26.637 25.263 1.374 5.44
105.5 14.051 26.534 24.950 1.585 6.35
1.0 0.026 46.188 0.735 1.59 1.504 6.15
121.3 14.861 25.945 24.441
6.8 0.181 46.394 45.509 0.885 1. 94
12.7 0.351 45.321 44.694 0.626 1. 40
16.8 0.479 44.923 T = 523.2 K
44.024 0.899 2.04
22.0 0.659 44.142 43.036 1.106 2.57 1.0 0.023 49.820 49.195 0.624 1.27
28.2 0.912 43.004 41.605 1.399 3.36 19.1 0.470 48.221 47.850 0.370 0.77
33.0 1.153 41.953 40.232 1.721 4.28 34.0 0.899 47.208 46.391 0.817 1. 76
37.8 1.470 40.771 38.469 2.302 5.98 49.4 1.453 45.593 44.485 1.108 2.49
42.3 17.223 19.447 18.007 1.440 8.00 63.6 2.143 43.440 42.278 1.162 2.75
49.4 17.385 19.306 17.944 1.362 7.59 75.8 3.011 41.460 39.831 1.628 4.09
49.8 17.393 19.408 17.940 1.468 8.18 85.0 4.085 39.037 37.265 1.772 4.76
66 ..~ 17.715 19 ..~15 17.&22 1.493 8.38 91.1 5.536 36.935 34.477 2.458 7.13
90.4 18.101 19.104 17.695 1.409 7.96 97.4 9.427 33.215 29.666 3.549 11.96
118.3 18.469 18.966 17.592 1.374 7.81 103.3 11.552 29.844 27.888 1.956 7.01
107.4 12.264 28.989 27.350 1.639 5.99
112 .9 12.909 28.313 26.881 1.432 5.33
121.4 13 . .592 27.822 26.402 1.420 5.38

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 851

Table 14. Comparison of ID code (69) Wormald Table 15. The Joule-Thomson inversion locus for
f).H data with calculated values - methanol
Continued
T f' P T f' P
P p f).H f).H Diff. % K molll bar K molll bar
bar moll! kllmol kllmal Dev.
(data) 425 20.255 36.31 620 18.980 1025.45
(calc.)
430 20.211 60.23 630 18.921 1073.34
T = 548.2 K 440 20.127 109.17 640 18.863 1120.69
450 20.049 159.26 650 18.805 1167.49
1.0 0.022 51.386 50.767 0.620 1.22 460 19.974 210.16 660 18.746 1213.70
17.4 0.401 50.399 49.843 0.556 1.12 470 19.903 261.63 670 18.687 1259.34
33.0 0.799 49.179 48.762 0.417 0.85 480 19.834 313.48 680 18.628 1304.37
49.1 1.280 48.028 47.391 0.637 1.35 490 19.767 365.54 690 18.569 1348.78
61.8 1. 733 46.872 46.129 0.742 1.61 500 19.702 417.69 700 18.509 1392.57
76.0 2.353 45.523 44.516 1.007 2.26 510 19.638 469.84 710 18.449 1435.71
90.2 3.149 43.764 42.644 1.119 2.62 520 19.575 521.89 720 18.388 1478.21
98.6 3.747 42.664 41.374 1.290 3.12 530 19.513 573.78 730 18.327 1520.04
106.4 4.433 41.027 40.041 0.986 2.46 540 19.452 625.44 740 18.266 1561.20
114.2 5.314 39.668 38.507 1.161 3.02 550 19.392 676.81 750 18.204 1601.68
130.4 7.969 36.862 34.842 2.020 5.80 560 19.332 727.87 760 18.142 1641.45
570 19.273 778.56 770 18.079 1680.53
T = 573.2 K 580 19.214 828.8-1 780 18.015 171R.RR
590 19.155 878.70 790 17.950 1756.50
1.0 0.021 52.966 52.383 0.583 1. 11
600 19.097 928.11 800 17.885 1793.37
18.0 0.393 51.915 51.626 0.289 0.56
610 19.038 977.03 810 17.819 1829.50
33.3 0.754 51.409 50.827 0.582 1. 15
47.4 1.124 50.422 49.944 0.478 0.96
62.0 1.559 49.685 48.900 0.785 1.60
75.2 2.010 48.455 47.852 0.603 1.26
89.0 2.555 47.455 46.655 0.800 1. 71
102.8 3.191 46.093 45.355 0.738 1.63
111. 8 3.665 45.276 44.447 0.829 1.86
122.3 4.293 44.068 43.320 0.748 1. 73
136.4 5.292 42.504 41.682 0.823 1. 97

50~------~1~------~1--------~1_________

0
11
0 Methanol. T = 515.2 K

0
40 - 11
0
-
E 0
...,...... A

~
.. 11
%
<I
30 J-
Enthalpy Differences
-
o Wormald et at (1984) 00
o
11 This Report 1111
A

Pc
20~______~I________J~J______~I______~
o 4 8 12 16

DENSITY. molll

FIG. 4. Comparison of enthalpy differences at 515.2 K.

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

852 ROBERT D. GOODWIN

Table 16. Properties of saturated liquid methanol

T P PI Pg ZI Zg dPc/dT dplldT aPiaT aPlap

K bar moll! molll baTIK (mollI)/K bar/K bar/(mollI)
175.590 0.00000 28.226 0.00000 0.00000 0.98929 0.000000 -0.03260 16.3765 502.3808
180.000 0.00000 28.083 0.00000 0.00000 0.98868 0.000001 -0.03228 15.9926 495.3595
185.000 0.00001 27.922 0.00000 0.00000 0.98809 0.000001 -0.03195 15.5773 487.6127
190.000 0.00002 27.763 0.00000 0.00000 0.98759 0.000002 -0.03162 15.1817 480.0603
195.000 0.00003 27.606 0.00000 0.00000 0.98718 0.000004 -0.03132 14.8043 472 .6711

200.000 0.00006 27.450 0.00000 0.00000 0.98685 0.000008 -0.03103 14.4438 465.4163
205.000 0.00011 27.296 0.00001 0.00000 0.98657 0.000013 -0.03077 14.0989 458.2697
210.000 0.00020 27.143 0.00001 0.00000 0.98635 0.000022 -0.03051 13.7686 451.2072
215.000 0.00034 26.991 0.00002 0.00000 0.98616 0.000036 -0.03028 13.4519 444.2069
220.000 0.00057 26.840 0.00003 0.00000 0.98599 0.000058 -0.03007 13.1478 437.2484

225.000 0.00094 26.690 0.00005 0.00000 0.98582 0.000091 -0.02987 12.8556 430.3134
230.000 0.00151 26.541 0.00008 0.00000 0.98565 0.000139 -0.02970 12.5744 423.3849
235.000 0.00236 26.393 0.00012 0.00000 0.98545 0.000208 -0.02954 12.3035 416.4478
240.000 0.00363 26.245 0.00018 0.00001 0.98520 0.000304 -0.02941 12.0423 409.4882
245.000 0.00547 26.099 0.00027 0.00001 0.98489 0.000438 -0.02929 11.7902 402.4938

250.000 0.00810 25.952 0.00040 0.00002 0.98451 0.000621 -0.02920 11.5465 395.4535
255.000 0.01178 25.807 0.00056 0.00002 0.98403 0.000865 -0.02912 11. 3109 388.3576
260.000 0.01688 25.661 0.00079 0.00003 0.98345 0.001187 -0.02907 11.0826 381.1976
265.000 0.02381 25.516 0.00110 0.00004 0.98273 0.001606 -0.02904 10.8615 373.9664
270.000 0.03313 25.371 0.00150 0.00006 0.98186 0.002144 -0.02903 10.6468 366.6578
273.150 0.04052 25.279 0.00182 0.00007 0.98123 0.002556 -0.02904 10.5148 362.0115

275.000 0.04550 25.226 0.00203 0.00008 0.98083 0.002827 -0.02905 10.4384 359.2671
2&0.000 0.06170 25.0&0 0.00271 0.00011 0.97962 0.0036&4 -0.02909 10.2357 351.7904
285.000 0.08268 24.935 0.00357 0.00014 0.97820 0.004748 -0.02915 10.0385 344.2251
290.000 0.10958 24.789 0.00465 0.00018 0.97657 0.006054 -0.02924 9.8464 336.5696
295.000 0.14369 24.642 0.00601 0.00024 0.97470 0.007643 -0.02935 9.6590 328.8235
298.150 0.16957 24.550 0.00703 0.00028 0.97339 0.008809 -0.02944 9.5433 323.8970

300.000 0.18655 24.495 0.00769 0.00031 0.97257 0.009558 -0.02949 9.4761 320.9870
305.000 0.23990 24.347 0.00975 0.00039 0.97017 0.011848 -0.02966 9.2974 313.0614
310.000 0.30574 24.199 0.01226 0.00049 0.96747 0.014562 -0.02986 9.1225 305.0491
315.000 0.38632 24.049 0.01529 0.00061 0.96447 0.017756 -0.03008 8.9513 296.9532
320.000 0.48419 23.898 0.01893 0.00076 0.96114 0.021486 -0.03034 8.7834 288.7775

325.000 0.60218 23.745 0.02327 0.00094 0.95746 0.025814 -0.03063 8.6186 280.5268
330.000 0.74343 23.591 0.02842 0.00115 0.95342 0.030801 -0.03095 8.4567 272.2064
335.000 0.91140 23.436 0.03448 0.00140 0.94900 0.036514 -0.03131 8.2974 263.8224
337.668 1.01325 23.352 0.03813 0.00155 0.94648 0.039882 -0.03152 8.2134 259.3256
340.000 1.10989 23.278 0.04158 0.00169 0.94418 0.043019 -0.03171 8.1404 255.3816
345.000 1.34303 23.118 0.04986 0.00203 0.93894 0.050386 -0.03214 7.9857 246.8909
350.000 1.61530 22.957 0.05948 0.00242 0.93328 0.058685 -0.03262 7.8329 238.3583
355.000 1.93155 22.792 0.07058 0.00287 0.92716 0.067987 -0.03313 7.6819 229.7917
360.000 2.29697 22.625 0.08336 0.00339 0.92057 0.078365 -0.03370 7.5323 221.1997
365.000 2.71711 22.455 0.09801 0.00399 0.91351 0.089891 -0.03431 '7.3841 212.5910
370.000 3.19791 22.282 0.11474 0.00467 0.90594 0.102638 -0.03498 7.2369 203.9747

375.000 3.74565 22.105 0.13380 0.00543 0.89786 0.116679 -0.03570 7.0906 195.3601
380.000 4.36698 21.925 0.15543 0.00630 0.88925 0.132086 -0.03648 6.9449 186.7564
385.000 5.06891 21. 740 0.17993 0.00728 0.88009 0.148931 -0.03733 6.7996 178.1732
390.000 5.85881 21.552 0.20759 0.00838 0.87036 0.167286 -0.03825 6.6546 169.6201
395.000 6.74441 21. 358 0.23877 0.00962 0.86006 0.187222 -0.03924 6.5094 161.1064

400.000 7.73378 21.159 0.27385 0.01099 0.84915 0.208809 -0.04032 6.3640 152.6418
405.000 8.83536 20.954 0.31324 0.01252 0.83764 0.232117 -0.04150 6.2179 144.2357
410.000 10.05794 20.744 0.35742 0.01422 0.82549 0.257218 -0.04278 6.0711 135.8975
41:5.000 11.4106:5 20.:526 0.40691 0.01611 0.81269 0.284181 -0.04418 5.9231 127.6365
420.000 12.90297 20.302 0.46231 0.01820 0.79922 0.313079 -0.04571 5.7736 119.4620

425.000 14.54478 20.069 0.52430 0.02051 0.78506 0.343983 -0.04739 5.6224 111.3831
430.000 16.34628 19.828 0.59364 0.02306 0.77018 0.376970 -0.04924 5.4690 103.409~
435.000 18.31808 19.576 0.67122 0.02587 0.75456 0.412119 -0.05129 5.3131 95.5494
440.000 20.47121 19.314 0.75807 0.02897 0.73815 0.449512 -0.05358 5.1542 87.8132
445.000 22.81710 19.040 0.85539 0.03239 0.72094 0.489241 -0.05613 4.9918 80.2102

450.000 25.36768 18.752 0.96463 0.03616 0.70287 0.531406 -0.05902 4.8254 72.7506
455.000 28.13540 18.449 1.08749 0.04031 0.68388 0.576117 -0.06231 4.6542 65.4450

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 853

Table 16. Properties of saturated liquid methanol - Continued

T p Pl Pg Zl Zg dPc/dT dplldT 3PI3T 3PI3p

K bar molll molll barlK Cmol!l)IK barlK bar/Cmol/I)
460.000 31.13331 18.128 1.22609 0.04490 0.66391 0.623504 -0.06610 4.4776 58.3051
465.000 34.37514 17.787 1.38303 0.04999 0.64287 0.673714 -0.07052 4.2946 51.3439
470.000 37.87545 17.422 1.56164 0.05563 0.62064 0.726927 -0.07576 4.1042 44.5764

475.000 41.64978 17.028 1.76625 0.06193 0.59708 0.783360 -0.08210 3.9049 38.0202
480.000 45.71487 16.598 2.00270 0.06901 0.57196 0.843286 -0.08997 3.6951 31.6968
485.000 50.08904 16.124 2.27926 0.07703 0.54497 0.907058 -0.10008 3.4725 25.6337
490.000 54.79264 15.592 2.60826 0.08626 0.51563 0.975149 -0.11369 3.2338 19.8670
495.000 59.84883 14.978 3.00968 0.09709 0.48316 1.048234 -0.13331 2.9742 14.4471

500.000 65.28500 14.239 3.52022 0.11029 0.44611 1.127355 -0.16491 2.6856 9.4486
505.000 71.13544 13.279 4.22307 0.12758 0.40117 1.214378 -0.22764 2.3514 4.9948
510.000 77 .44920 11.740 5.42672 0.15558 0.33657 1.314067 -0.45275 1. 9192 1.3365
511.000 78.77455 11.215 5.85653 0.16532 0.31658 1.336902 -0.61898 1.8015 0.7506
511.500 79.44602 10.867 6.14682 0.17189 0.30391 1.349086 -0.78834 1. 7317 0.4853
512.000 80.12378 10.394 6.55016 0.18107 0.28734 1. 362154 -1.16663 1.6462 0.2435
512.300 80.53370 9.964 6.92642 01897" 0.J.nCJ7 1 ..~707CJ5 -1.&2781 1.5774 0.1131
512.600 80.94644 8.400 8.40000 0.22610 0.22610 1.382020 1. 3820 0.0000

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

854 ROBERT D. GOODWIN

Table 16. Properties of saturated liquid methanol - Continued

T Qvap E H S Cv Cq Cp liP W
K J/mol J/mol Jlmol J/(mol·K) J/(mol·K) J/(mol'K) JI(mol·K) m/s

175.590 41755.4 .0 .0 90.083 59.41 71.25 71.18 1.00006 1370

180.000 41592.3 334.6 334.6 91.902 59.27 71.04 71.05 1.00006 1361
185.000 41410.9 711.0 711.0 93.894 59.13 70.88 70.94 1.00007 1351
190.000 41233.1 1084.4 1084.4 95.816 59.03 70.78 70.87 1.00008 1341
195.000 41058.7 1455.2 1455.2 97.674 58.97 70.74 70.84 1.00008 1331

200.000 40887.1 1823.7 1823.7 99.473 58.95 70.77 70.85 1.00009 1321
205.000 40718.0 2190.6 2190.6 101.220 58.98 70.86 70.92 1.00009 1311
210.000 40550.9 2556.1 2556.1 102.919 59.06 71.01 71.04 1.00009 1301
215.000 40385.4 2920.9 2920.9 104.576 59.19 71.22 71.21 1.00010 1291
220.000 40221.0 3285.3 3285.3 106.194 59.37 71.48 71.44 1.00010 1281
225.000 40057.0 3650.1 3650.1 107.777 .59.6U 71.79 71.73 1.0aOl0 1271
230.000 39893.1 4015.7 4015.7 109.331 59.88 72.15 72.08 1.00010 1261
235.000 39728.6 4376.5 4376.5 110.856 60.21 72.56 72.48 .99715 1250
240.000 39563.0 4732.7 4732.7 112.355 60.59 73.02 72.93 .99134 1240
245.000 39395.7 5091.:2 5091.2 11.'LR33 61.01 73.53 73.43 .98585 1229
250.000 39226.1 5452.6 5452.6 115.293 61.48 74.07 73.99 .98065 1218
255.000 39053.7 5817.2 5817.3 116.737 61.98 74.66 74.59 .97570 1207
260.000 38877.9 6185.5 6185.6 118.167 62.51 75.29 75.24 .97095 1196
265.000 38698.1 6:5:57.8 6:557.9 119.584 63.08 75.95 75.92 .96636 1185
270.000 38513.7 6934.3 6934.4 120.992 63.68 76.65 76.64 .96189 1173
273.150 38394.9 7173.9 7174.1 121.873 64.06 77.11 77.12 .95912 1166

275.000 38324.1 7315.4 7315.6 122.390 64.30 77 .39 77.40 .95749 1161
280.000 38128.8 7701.5 7701.7 123.780 04.94 18.16 78.19 .95316 1149
285.000 37927.0 8092.5 8092.8 125.164 65.59 78.96 79.01 .94880 1137
290.000 37718.2 8488.7 8489.1 126.541 66.26 79.78 79.86 .94445 1125
295.000 37501.9 8890.1 8890.7 127.897 66.95 80.64 80.73 .94187 1112
298.150 37361.4 9145.9 9146.6 128.763 67.38 81.19 81.29 .93864 1104

300.000 37277.3 9297.1 9297.9 129.259 67.64 81.52 81.62 .93802 1099
305.000 37044.0 9709.6 9710.6 130.611 68.33 82.43 82.54 .93465 1086
310.000 36801.2 10127.7 10129.0 131.945 69.03 83.36 83.47 .93281 1072
315.000 36548.3 10551.5 10553.1 133.302 69.73 84.31 84.42 .92786 1059
320.000 36284.8 10981.0 10983.0 134.664 70.43 85.29 85.40 .92174 1045
325.000 36010.0 11415.9 11418.4 136.008 71.12 86.28 86.38 .91703 1031
330.000 35723.3 11856.2 11859.3 137.331 71.81 87.30 87.39 .91401 1016
335.000 35424.1 12302.0 12305.9 138.674 72.50 88.33 88.41 .90823 1002
337.668 35259.1 12541.9 12546.2 139.373 72.86 88.89 88.97 .90684 994
340.000 35111. 8 12752.9 12757.7 139.996 73.18 89.38 89.46 .90415 987
345.000 34785.6 13208.9 13214.7 141. 319 73.85 90.45 90.52 .89912 971

350.000 34445.1 13669.8 13676.9 142.631 74.51 91.53 91.61 .89468 956
355.000 34089.5 14135.5 14143.9 143.946 75.17 92.63 92.72 .88904 940
360.000 33718.2 14605.7 14615.8 145.258 .75.81 93.75 93.85 .88298 924
365.000 33330.6 15080.3 15092.4 146.557 76.45 94.89 95.01 .87754 908
370.000 32926.1 15559.2 15573.5 147.844 77.07 96.05 96.21 .87249 891
375.000 32504.0 16042.2 16059.1 149.138 77.68 97.23 97.43 .86597 874
380.000 32063.6 16529.3 16549.2 150.423 78.28 98.42 98.70 .85947 857
385.000 31604.2 17020.3 17043.6 151. 703 78.87 99.65 100.01 .85282 839
390.000 3112:5.2 11:51:5.4 17542.5 152.960 79.-1-1 100.90 101.36 .84766 821
395.000 30625.8 18014.5 18046.1 154.228 80.00 102.18 102.77 .84069 803

400.000 30105.2 18518.0 18554.5 155.489 80.54 103.50 104.24 .83383 785
405.000 29562.7 19025.9 19068.1 156.749 81.05 104.86 105.78 .82647 766
410.000 28997.5 19538.8 19587.3 158.0(.)5 lH.:55 106.2.8 107.39 .81921 747
415.000 28408.4 20057.2 20112.7 159.264 82.03 107.75 109.10 .81137 727
420.000 27794.7 20581.8 20645.3 160.521 82.48 109.29 110.91 .80362 7~8

425.000 :27155.0 1111.'L4 21185.9 161. 782 82.91 110.91 112.85 .79563 687
430.000 26488.2 21653.3 21735.8 163.048 83.31 112.64 114.9:5 .78163 667
435.000 25792.6 22202.8 22296.3 164.321 83.70 114.50 117.23 .77957 646
440.000 25066.7 22763.3 22869.3 165.607 84.06 116.51 U9.74 .77129 624
445.000 24308.3 23336.9 23456.8 166.908 84.42 118.71 122.55 .76307 602

450.000 23515.0 23925.7 24060.9 168.229 84.77 121.15 125.73 .75471 580

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 855

Table 16. Properties of saturated liquid methanol - Continued

T Qva1! E H S Cu Co Cp f/P W
K J/mol J/mol J/mol J/(mol·K) J/(mol·K) J/(mol·K) J/(mol·K) mls
455.000 22683.6 24532.2 24684.7 169.570 85.15 123.89 129.39 .74670 557
460.000 21810.3 25159.1 25330.9 170.945 85.57 127.03 133.70 .73836 533
465.000 20890.2 25810.0 26003.2 172.357 86.07 130.67 138.87 .73002 508
470.000 19917.0 26487.8 26705.2 173.818 86.72 135.00 145.23 .72104 482

475.000 18881.8 27197.4 27442.0 175.331 87.58 140.26 153.29 .71203 455
4RO.00O 17772.9 27944.1 2R219.5 17n.90R RR.79 Un .R4 163.R4 .70294 427
485.000 16572.8 28734.4 29045.0 178.563 90.52 155.39 178.27 .69357 396
490.000 15255.0 29577 .4 29928.9 180.311 93.06 167.06 199.16 .68420 364
495.000 13775.9 30488.1 30887.7 182.188 96.88 184.13 231.99 .67441 328
500.000 12053.9 31494.2 31952.7 184.242 102.81 212.03 291.05 ,66491 288
505.000 9903.5 32660.3 33196.0 186.641 112.62 268.13 429.63 .65326 243
510.000 6641.0 34240.3 34900.0 189.891 131. 77 471. 38 1151.55 .64232 190
511.000 5573.4 34714.1 35416.5 190.877 138.52 621.79 1895.16 .64014 179
511.500 4876.5 35014.7 35745.7 191.509 142.85 775.07 2819.01 .63890 172
512.000 3937.8 35411.4 36182.2 192.350 148.35 1117.42 5422.70 .63759 166
512.300 3090.8 35763.8 36572.0 193.104 152.79 1715.70 11509.98 .63683 163
5U.600 0.0 37065.9 38029.5 195.939 161.14 .63603 0

J. Phys. Chern. Ref. Data, Vol. 16, No. 4.1987

856 ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars

T f' Z aPlaT aPlap E H S Cv Cp flP JL W

K molll bar/K bar/(mollI) llmol J/mol J/(mol·K) J/(mol·K) J/(mol·K) K/bar m/s
0.10000 bar
175.590 28.22619 0.00024 16.377675 502.4272 -0.1 0.3 89.985 59.41 71.18 0.00002 -0.0397 1370
180.000 28.08313 0.00024 15.993773 495.4055 343.5 343.8 91.750 59.27 71.05 0.00004 -0.0397 1361
190.000 27.76364 0.00023 15.182830 480.1053 1103.1 1103.5 95.583 59.03 70.87 0.00017 -0.0398 1341
200.000 27.45042 0.00022 14.444829 465.4605 1841.6 1842.0 99.212 58.95 70.85 0.00063 -0.0398 1321
210.000 27.14274 0.00021 13.769622 451.2510 2565.9 2566.3 102.670 59.06 71.04 0.00205 -0.0396 1301
220.000 26.83988 0.00020 13.148802 437.2917 3282.5 3282.9 105.983 59.37 71.44 0.00588 -0.0393 1281
230.000 26.54111 0.00020 12.575322 423.4277 3997.2 3997.6 109.175 59.88 72.07 0.01523 -0.0388 1261
240.000 26.24565 0.00019 12.043207 409.5299 4715.4 4715.8 112.263 60.59 72.93 0.03609 -0.0382 1240
250.000 25.95269 0.00019 11.547365 395.4933 5441.7 5442.1 115.265 61.47 73.99 0.07927 -0.0374 1218
260.000 25.66141 0.00018 11.083385 381.2338 6179.9 6180.3 118.193 62.51 75.24 0.16293 -0.0365 1196
270.000 25.37094 0.00018 10.647420 366.6870 6933.3 6933.7 121.060 63.68 76.64 0.31600 -0.0355 1173
280.000 25.08036 0.00017 10.236074 351. 8073 7704.2 7704.6 123.874 64.94 78.19 0.58218 -0.0344 1149
288.355 24.83680 0.00017 9.909081 339.0989 8363.2 8363.6 126.192 66.04 79.58 0.93633 -0.0334 1129

288.355 0.00427 0.97713 0.000364 23.1967 43808.6 46151.3 257.238 36.34 45.40 0.93633 31.6769 300
290000 0.00.1')4 0977.17 000036:> ?3 3450 418£,1.<) MinO.7 ?~7.1<)4 16.41 45.45 0.94641 30.6227 301
300.000 0.00409 0.97923 0.000347 24.2340 44232.9 46675.4 258.936 36.67 45.54 0.94933 25.7539 306
310.000 0.00396 0.98065 0.000333 25.1079 44604.6 47132.2 260.434 37.09 45.86 0.95190 22.3093 311
320.000 0.00383 0.98182 0.000322 25.9719 44980.7 47593.0 261.897 37.62 46.32 0.95420 19.7487 315
330.000 0.00371 0.98281 0.000311 26.8291 45362.2 48058.8 263.331 38.23 46.87 0.95625 17.7756 320
31\0.000 0.00360 0.98367 0.000301 27.6812 45749.8 48530.5 264.739 38.89 47.48 0.95814 16.2128 324
350.000 0.00349 0.98442 0.000292 28.5296 46143.9 49008.6 266.126 39.58 48.15 0.95987 14.9476 329
360.000 0:00339 0.98509 0.000283 29.3751 46544.9 49493.5 267.492 40.31 48.85 0.96145 13.9047 333
370.000 0.00330 0.98569 0.000275 30.2183 46953.3 49985.6 268.840 41.05 49.57 0.96293 13.0319 337
380.000 0.00321 0.98623 0.000268 31.0598 47369.1 50485.1 270.172 41.82 50.32 0.96430 12.2917 341
390.000 0.00313 0.98672 0.000260 31.8999 1\7792.5 50992.1 271.1\&9 1\2.60 51.09 0.965S6 11.6S68 14:'1
400.000 0.00305 0.98717 0.000254 32.7387 48223.7 51506.8 272.793 43.39 51.86 0.96676 11.1066 349
410.000 0.00297 0.98759 0.000247 33.5767 48662.7 52029.3 274.083 44.19 52.65 0.96787 10.6254 353
420.000 0.00290 0.98797 0.000241 34.4138 49109.7 52559.8 275.361 44.99 53.44 0.96893 10.2012 357
430.000 0.00283 0.98833 0.000235 35.2503 49564.7 53098.2 276.628 45.79 54.24 0.96992 9.8243 360
440.000 0.00276 0.98867 0.000230 36.0862 50027.6 53644.5 277.884 46.60 55.04 0.97084 9.4872 364
450.000 0.00270 0.98898 0.000225 36.9217 50498.7 54199.0 279.130 47.41 55.84 0.97174 9.1838 368
460.000 0.00264 0.98928 0.000220 37.7568 50977.7 54761. 3 280.366 48.21 56.64 0.97257 8.9092 372
470.000 0.00259 0.98956 0.000215 38.5915 51464.7 55331.7 281.593 49.01 57.44 0.97337 8.6594 375
480.000 0.00253 0.98982 0.000211 39.4260 51959.7 55910.0 282.810 49.81 58.23 0.97412 8.4309 379
490.000 0.00248 0.99007 0.000206 40.2602 52462.6 56496.2 284.019 50.60 59.02 0.97484 8.2211 382
500.000 0.00243 0.99031 0.000202 41.0941 52973.4 57090.3 285.219 51.39 59.80 0.97553 8.0275 386
510.000 0.00238 0.99053 0.000198 41.9279 53492.0 57692.2 286.411 52.17 60.58 0.97618 7.8484 389
515.000 0.00236 0.99064 0.000196 42.3448 53754.2 57996.1 287.004 52.56 60.97 0.97649 7.7636 391
520.000 0.00233 0.99075 0.000194 42.7616 54018.3 58301.9 287.595 52.95 61.35 0.97680 7.6819 393
530.000 0.00229 0.99095 0.000190 43.5950 54552.4 58919.2 288.771 53.71 62.12 0.97740 7.5267 396
540.000 0.00225 0.99115 0.000187 44.4284 55094.1 59544.2 289.939 54.48 62.88 0.97797 7.3816 400
560.000 0.00217 0.99151 0.000180 46.0948 56200.0 60816.6 292.253 55.97 64.37 0.97904 7.1176 406
580.000 0.00209 0.99185 0.000174 47.7608 57335.6 62118.7 294.537 57.44 65.83 0.98003 6.8830 413
600.000 0.00202 0.99216 0.000168 49.4266 58500.1 63449.7 296.793 58.88 67.26 0.98093 6.6728 419
620.000 0.00195 0.99245 0.000162 51.0922 59693.0 64809.0 299.022 60.28 68.66 0.98178 6.4828 426
640.000 0.00189 0.99272 0.000157 52.7575 60913.4 66195.9 301.224 61.64 70.03 0.98255 6.3100 432
660.000 0.00184 0.99297 0.000153 54.4227 62160.8 67609.8 303.399 62.98 71.36 0.98328 6.1519 438
680.000 0.00178 0.99321 0.000148 56.0878 63434.6 69050.0 305.549 64.28 72.66 0.98396 6.0064 444
700.000 0.00173 0.99343 0.000144 57.7528 64734.0 70515.9 307.673 65.55 73.93 0.98459 5.8720 450
720.000 0.00168 0.99363 0.00011\0 59.1\176 66058.5 72006.8 309.773 66.79 75.16 0 .. 98519 5.7471 456
740.000 0.00164 0.99383 0.000136 61.0824 67407.4 73522 .1 311.849 68.00 76.37 0.98574 5.6308 462
760.000 0.00159 0.99401 0.000132 62.7471 68780.0 75061. 2 313.901 69.17 77.54 0.98626 5.5221 468
780.000 0.00155 0.99418 0.000129 64.4118 70176.0 76623.6 315 .• 930 70.32 78.69 0.98676 5.4201 474
800.000 0.00151 0.99435 0.000126 66.0764 71594.5 78208.5 317.936 71.44 79.81 0.98722 5.3242 479

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 857
Table 17. Properties of methanol along isobars - Continued

T p Z 8PI8T 8PI8p E H S Cv Cp flP Il W

K molll barlK bar/(mol/l) J/mol J/mol Jl(mol·K) J/(mol·K) J/(mol·K) Klbar m/s
0.20000 bar
175.590 28.22638 0.00049 16.378864 502.4735 -0.1 0.6 89.985 59.41 71.18 0.00001 -0.0397 1370
180.000 28.08333 0.00048 15.994936 495.4513 343.4 344.1 91.750 59.27 71.05 0.00002 -0.0397 1361
190.000 27.76385 0.00046 15.183942 480.1503 1103.0 1103.7 95.583 59.03 70.87 0.00008 -0.0398 1341
200.000 27.45063 0.00044 14.445894 465.5049 1841.5 1842.2 99.212 58.95 70.85 0.00032 -0.0398 1321
210.000 27.14296 0.00042 13.770648 451.2948 2565.8 2566.6 102.670 59.06 71.04 0.00102 -0.0396 1301
220.000 26.84011 0.00041 13.14979i 437.3352 3282.4 3283.1 105.983 59.37 71.44 0.00294 -0.0393 1281
230.000 26.54135 0.00039 12.576280 423.4710 3997.1 3997.9 109.174 59.88 72.07 0.00762 -0.0388 1261
240.000 26.24589 0.00038 12.044138 409.5732 4715.3 4716.1 112.263 60.59 72.93 0.01805 -0.0382 1240
250.000 25.95294 0.00037 11.548272 395.5366 5441.6 5442.3 115.264 61.47 73.99 0.03964 -0.0374 1218
260.000 25.66168 0.00036 11.084271 381.2772 6179.8 6180.6 118.193 62.51 75.23 0.08148 -0.0365 1196
270.000 25.37122 0.00035 10.648288 366.7308 6933.2 6933.9 121.059 63.68 76.64 0.15803 -0.0355 1173
280.000 25.08065 0.00034 10.236928 351.8513 7704.1 7704.9 123.874 64.94 78.19 0.29114 -0.0344 1149
290.000 24.78899 0.00033 9.847159 336.6099 8494.5 8495.3 126.645 66.26 79.86 0.51237 -0.0332 1125
300.000 24.49521 0.00033 9.476237 320.9930 9305.3 9306.1 129.379 67.64 81.62 0.86527 -0.0319 1099
301.366 24.45486 0.00033 9.426906 318.8312 9417.7 9418.5 129.750 67.83 81. 87 0.92669 -0.0317 1095
301.366 0.00821 0.97194 0.00071~ 23.97M 44197.6 46633.0 253.236 35.05 47.61 0.92669 24.1412 305
310.000 0.00796 0.97428 0.000686 24.7903 44523.6 47034.8 254.484 38.11 47.38 0.93736 20.3182 310
320.000 0.00770 0.97642 0.000657 25.7028 44910.7 47508.6 255.989 38.34 47.41 0.94067 17.1372 314
330.000 0.00745 0.97814 0.000632 26.5958 45300.1 47983.9 257.452 38.76 47.69 0.94358 14.7826 319
340.000 0.00722 0.97957 0.000610 27.4753 45693.7 48462.9 258.882 39.29 48.12 0.94617 12.9810 324
J~U.UUU U.UU'/Ul U.91SU76 O.OOO~90 28.34:50 46092.:5 48946.6 260.284 39.90 48.6;5 0.94851 11 .5669 328
360.000 0.00681 0.98179 0.000571 29.2075 46497.3 49436.1 261.663 40.56 49.25 0.95063 10.4343 332
370.000 0.00662 0.98268 0.000554 30.0645 46908.7 49931.8 263.022 41.26 49.90 0.95257 9.5119 336
380.000 0.00644 0.98347 0.000539 30.9172 47326.9 50434.2 264.362 41.99 50.59 0.95436 8.7501 340
390.000 0.00627 0.98416 0.000524 31.7664 47752.4 50943.7 265.685 42.74 51. 31 0.95601 8.1132 345
400.000 0.00611 0.98479 O.OOO~HO 32.6130 4816;~5. 3 ;:H460.S 266.994 43.50 52.05 0.95754 7.5750 348
410.000 0.00595 0.98535 0.000497 33.4573 48625.9 51984.9 268.288 44.28 52.81 0.95897 7.1159 352
420.000 0.00581 0.98587 0.000484 34.2999 49074.1 52516.8 269.570 45.07 53.58 0.96031 6.7209 356
430.000 0.00567 0.98634 0.000473 35.1409 49530.2 53056.5 270.840 45.86 54.36 0.96157 6.3783 360
440.000 0.00554 0.98677 0 .. 000461 35.9807 49994.1 53604.1 272.099 46.66 55.14 0.96275 6.0791 364
450.000 0.00541 0.. 98717 0.000451 36.8195 50465.9 54159.4 273.347 47.46 55.93 0.96387 5.8160 368
460.000 0.00530 0.98754 0.000441 37.6574 50945.6 54722.7 274.584 48.25 56.72 0.96492 5.5832 371
470.000 0.00518 0.98789 0.000431 38.4946 51433.3 55293.8 275.813 49.05 57.50 0.96592 5.3760 375
480.000 0.00507 0.98822 0.000422 39.3311 51928.8 55872.7 277.031 49.84 58.29 0.96687 5.1906 378
490.000 0.00497 0.98852 0.000413 40.1671 52432.2 56459.5 278.241 50.63 59.07 0.96776 5.0239 382
500.000 0.00487 0.98881 0.000405 41.0027 52943.4 57054.1 279.443 51.41 59.85 0.96862 4.8731 385
510.000 0.00477 0.98909 0.000397 41.8379 53462.4 57656.5 280.635 52.19 60.62 0.96944 4.7363 389
515.000 0.00472 0.98922 0.000393 42.2553 53724.8 57960.6 281.229 52.58 61.01 0.96983 4.6725 391
520;000 0.00468 0.98934 0.000389 42.6727 53989.1 58266.6 281. 820 52.97 61.39 0.97021 4.6115 392
530.000 0.00459 0.98959 0.000381 43.5072 54523.5 58884.3 282.997 53.73 62.15 0.97095 4.4972 396
540.000 0.00450 0.98982 0.000374 44.3415 55065.4 59509.5 284.165 54.49 62.91 0.97165 4.3921 399
560.000 0.00434 0.99026 0.000361 46.0095 56171. 8 60782.6 286.480 55.99 64.40 0.97298 4.2055 406
580.000 0.00419 0.99066 0.000348 47.6768 57307.8 62085.1 288.766 57.45 65.85 0.97420 4.0445 412
600.000 0.00405 0.99102 0.000336 49.3435 58472.6 63416.5 291.022 58.88 67.28 0.97533 3.9039 419
620.000 0.00391 0.99136 0.000325 51.0099 59665.7 64776.1 293.252 60.28 68.68 0.97638 3.7799 425
640.000 0.00379 0.99167 0.000315 52.6759 60886.4 66163.4 295.454 61.65 70.04 0.97735 3.6693 432
660.000 0.00367 0.99196 0.000305 54.3417 62134.0 67577.5 297.629 62.98 71.37 0.97826 3.5699 438
680.000 0.00357 0.99224 0.000296 56.0073 63407.9 69017.9 299.779 64.28 72.67 0.97909 3.4799 444
700.000 0.00346 0.99249 0.000288 57.6727 64707.5 70484.0 301.904 65.55 73.93 0.97988 3.3977 450
720.000 0.00337 0.99273 0.000280 59.3380 66032.1 71975.0 304.004 66.79 75.17 0.98063 3.3224 456
740.000 0.00327 0.99295 0.000272 61.0031 67381.1 73490.5 306.080 68.00 76.37 0.98131 3.2528 462
760.000 0.00319 0.99317 0.000265 62.6682 68753.9 75029.8 308.133 69.17 77.55 0.98197 3.1883 468
780.000 0.00310 0.99337 0.000258 64.3332 70149.9 76592.2 310.162 70.32 78.69 0.98258 3.1283 474
800.000 0.00303 0.99356 0.000252 65.9981 71568.6 78177.3 312.168 71.44 79.81 0.98316 3.0722 479

J. Phys. Chem. Ref. Data, Vol. 16, No. 4,1987

H!JH ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

T p z aPiaT aPlap E If S Cv Cp flP J.L W

K mol/l bar/K bar/(molll) llmol J/mol J/(mol·K) J!(mol·K) J/(mol·K) K/bar mls

0.50000 bar
175.590 28.22698 0.00121 16.382429 502.6125 -0.4 1.4 89.984 59.41 71.18 0.00000 -0.0397 1370
180.000 28.08393 0.00119 15.998425 495.5889 343.2 345.0 91. 748 59.27 71.05 0.00001 -0.0397 1361
190.000 27.76448 0.00114 15.187275 480.2852 1102.8 1104.6 95.581 59.03 70.87 0.00003 -0.0398 1341
200.000 27.45127 0.00110 14.449090 465.6377 1841.3 1843.1 99.211 58.95 70.85 0.00013 -0.0398 1321
210.000 27.14362 0.00105 13.773723 451.4262 2565.6 2567.4 102.668 59.06 71.04 0.00041 -0.0396 1301
220.000 26.84080 0.00102 13.152761 437.4656 3282.1 3284.0 105.982 59.37 71.44 0.00118 -0.0393 1281
230.000 26.54206 0.00099 12.579156 423.6009 3996.8 3998.7 109.173 59.88 72.07 0.00305 -0.0388 1261
240.000 26.24662 0.00095 12.046930 409.7029 4715.0 4716.9 112.261 60.59 72.93 0.00722 -0.0382 1240
250.000 25.95370 0.00093 11.550992 395.6665 5441.2 5443.2 115.263 61.47 73.99 0.01587 -0.0374 1219
260.000 25.66246 0.00090 11.086929 381.4076 6179.4 6181.4 118.191 62.51 75.23 0.03261 -0.0365 1196
270.000 25.37204 0.00088 10.650892 366.8619 6932.8 6934.8 121.058 63.67 76.64 0.06324 -0.0355 1173
280.000 25.08150 0.00086 10.239487 351.9834 7703.7 7705.7 123.873 64.93 78.19 0.11652 -0.0344 1150
290.000 24.78989 0.00084 9.849682 336.7432 8494.0 8496.1 126.643 66.26 79.86 0.20505 -0.0332 1125
300.000 24.49614 0.00082 9.478732 321.1276 9304.9 9306.9 129.377 67.63 81.62 0.34628 -0.0319 1099
310.000 24.19915 0.00080 9.124124 305.1372 10136.8 10138.8 132.081 69.03 83.47 0.56330 -0.0305 1073
:no.ooo 2~.&97n& 0.00079 &.71\3509 ?RR.7&4& 109&9. & 10991.9 134 75& 70.43 85.40 0.88547 -0.0290 1045
320.726 23.87559 0.00079 8.759272 287.5844 11052.5 11054.6 134.952 70.53 85.54 0.91387 -0.0289 1043
320.726 0.01952 0.96063 0.001783 24.8889 44738.6 47300.3 247.963 41. 77 52.52 0.91387 17.2614 312
330.000 0.01889 0.96493 0.001686 25.8695 45125.4 47773.0 249.403 41.18 51.35 0.92015 14.2995 317
340.000 0.01&')6 0.96&50 0.001603 26_8683 45545.3 48283.1 250.926 41.04 50_78 0.92460 11.9282 322
350.000 0.01769 0.97132 0.001534 27.8270 45963.5 48790.1 252.396 41.21 50.67 0.92845 10.1281 326
360.000 0.01716 0.97359 0.001475 28.7578 46383.2 49297.4 253.825 41.57 50.82 0.93183 8.7294 331
370.000 0.01666 0.97547 0.001423 29.6684 46806.2 49807.1 255.222 42.06 51.15 0.93484 7.6220 335
380.000 0.01620 0.97705 0.001376 30.5638 47233.8 50320.8 256.592 42.63 51.60 0.93755 6.7315 339
390.000 0.01576 0.97838 0.001334 31.4476 47666.8 50839.4 257.939 43.26 52.14 0.94000 6.0059 343
400.000 0.01535 0.97954 0.001295 32.3224 48105.9 51363.6 259.267 43.94 52.74 0.94220 5.4082 347
410.000 0.01496 0.98054 0.001258 33.1899 48551.6 51894.2 260.577 44.64 53.38 0.94426 4.9108 351
420.000 0.01459 0.98142 0.001225 34.0517 49004.3 52431.5 261. 872 45.37 54.06 0.94616 4.4933 355
430.000 0.01424 0.98220 0.001193 34.9088 49464.0 52975.6 263.152 46.12 54.77 0.94793 4.1402 359
440_000 0_01391 0_98290 0.001164 35.7620 49931.1 53526.9 26-1.419 46.88 55.-19 0.94957 3.8394 363
450.000 0.01359 0.98353 0.001136 36.6121 50405.7 54085.6 265.675 47.64 56.23 0.95111 3.5815 367
460.000 0.01328 0.98410 0.001109 37.4595 50887.8 54651.6 266.919 48.41 56.98 0.95255 3.3591 370
470.000 0.01299 0.98462 0.001084 38.3047 51377.4 55225.2 268.152 49.19 57.73 0.95391 3.1662 374
480.000 0.01272 0.98510 0.001060 39.1481 51874.8 55806.2 269.375 49.96 58.49 0.95519 2.9980 378
-190.000 0.01245 0.98554 0.001038 39.9899 52379.7 56394.9 270.589 50.74 59.24 0.95640 2.8506 381
500.000 0.01220 0.98594 0.001016 40.8303 52892.3 56991.1 271.794 51.51 60.00 0.95755 2.7208 385
510.000 0.01195 0.98632 0.000995 41.6697 53412.5 57594.9 272.989 52.27 60.76 0.95864 2.6060 388
515.000 0.01184 0.98650 0.000985 42.0890 53675.4 57899.6 273.584 52.65 61.13 0.95917 2.5536 390
520.000 0.01172 0.98668 0.000975 42.5081 53940.3 58206.2 274.176 53.03 61.51 0.95968 2.5041 392
530.000 0.01150 0.98701 0.000956 43.3456 54475.6 58825.0 275.355 53.79 62.26 0.96066 2.4132 395
540.000 0.01128 0.98732 0.000938 44.1825 55018.4 59451.3 276.526 54.54 63.00 0.96161 2.3317 399
560.000 0.01087 0.98789 0.000904 45.8544 56126.3 60726.0 278.843 56.03 64.47 0.96337 2.1925 405
580.000 0.01049 0.98841 0.000872 47.5245 57263.3 62029.8 281.131 57.48 65.91 0.96496 2.0782 412
600.000 0.01014 0.98888 0.000842 49.1933 58429.1 63362.3 283.390 58.91 67.33 0.96645 1.9832 418
620.000 0.00980 0.98930 0.000815 50.8610 59622.9 61\722.8 285.620 60.30 68.72 0.96783 1.9032 ~25
640.000 0.00949 0.98970 0.000789 52.5280 60844.3 66110.7 287.823 61.66 70.07 0.96911 1.8349 431
660.000 0.00920 0.99006 0.000764 54.1944 62092.4 67525.5 290.000 62.99 71.40 0.97030 1.7759 437
680.000 0.00893 0.99040 0.000742 55.8603 63366.8 68966.4 292 .151 64.29 72.69 0.97141 1.7245 443
700.000 0.00867 0.99071 0.000720 57.5259 64666.8 70432.9 294.276 65.56 73.95 0.97245 1.6791 450
720.000 0.00843 0.99101 0.000700 59.1912 65991:7 71924.3 296.377 66.79 75.19 0.97342 1.6387 456
740.000 0.00820 0.99128 0.000681 60.8563 67341.0 73440.1 298.453 68.00 76.39 0.97434 1.6025 461
760.000 0.00798 0.99155 0.000663 62.5213 68713.9 74979.5 300.506 69.17 77 .56 0.97518 1.5697 467
780.000 0.00777 0.99179 0.000646 64.1862 70110.2 76542.3 302.535 70.32 78.70 0.97600 1.5398 473
800.000 0.00758 0.99203 0.000629 65.8510 71529.0 78127.6 304.542 71.44 79.82 0.97676 1.5123 479

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 859
Table 17. Properties of methanol along isobars - Continued

T p Z 8PI8T 8PI8p E H S Cv Cp liP IJ. W

K molll bar/K bar/(mol/l) llmol llmol J/(mol·K) J/(mol·K) Jl(mol·K) K/bar m/s
1.01325 bar
175.590 28.22800 0.00246 16.388524 502.8501 -0.7 2.9 89.982 59.41 71.18 0.00000 -0.0397 1371
180.000 28.08497 0.00241 16.004386 495.8239 342.8 346.4 91.746 59.27 71.05 0.00000 -0.0397 1362
190.000 27.76554 0.00231 15.192970 480.5158 1102.4 1106.0 95.579 59.03 70.87 0.00002 -0.0398 1341
200.000 27.45238 0.00222 14.454552 465.8649 1840.8 1844.5 99.208 58.95 70.85 0.00006 -0.0398 1321
210.000 27.14476 0.00214 13.778978 451.6508 2565.1 2568.8 102.666 59.05 71.04 0.00020 -0.0396 1302
220.000 26.84197 0.00206 13.157834 437.6885 3281.6 3285.4 105.980 59.36 71.44 0.00058 -0.0393 1282
230.000 26.54327 0.00200 12.584068 423.8229 3996.3 4000.2 109.171 59.88 72.07 0.00151 -0.0388 1261
240.000 26.24787 0.00193 12.051702 409.9246 4714.5 4718.3 112.259 60.58 72.93 0.00357 -0.0382 1240
250.000 25.95500 0.00188 11.555640 395.8885 5440.7 5444.6 115.261 61.47 73.99 0.00784 -0.0374 1219
260.000 25.66381 0.00183 11.091469 381.6304 6178.9 6182.8 118.189 62.51 75.23 0.01611 -0.0365 1197
270.000 25.37343 0.00178 10.655341 367.0860 6932.2 6936.2 121.056 63.67 76.64 0.03124 -0.0355 1174
280.000 25.08296 0.00174 10.243859 352.2092 7703.1 7707.1 123.870 64.93 78.19 0.05755 -0.0344 1150
290.000 24.79141 0.00170 9.853992 336.9709 8493.3 8497.4 126.641 66.26 79.86 0.10127 -0.0332 1125
300.000 24.49774 0.00166 9.482996 321.3576 9304.1 9308.2 129.375 67.63 81.62 0.17102 -0.0319 1100
310.000 24.20083 0.00162 9.128357 305.3698 10136.0 10140.1 132.078 69.02 83.47 0.27820 -0.0305 1073
320.000 23.89946 0.00159 8.787728 289.0200 10988.9 10993.2 134.756 70.42 85.39 0.43730 -0.0291 1045
J30.000 :.u.~n:l~ 0.001:57 8.4:58879 272.3316 111362.13 111367.1 131.412 71.81 87.39 0.66602 -0.0274 1016
337.668 23.35181 0.00155 8.213357 259.3256 12546.6 12550.9 139.437 72.86 88.97 0.90139 -0.0261 994

337.668 0.03813 0.94648 0.003714 25.3476 45152.8 47810.0 243.856 46.35 58.99 0.90139 13.2285 317
340.000 0.03779 0.94835 0.003643 25.6460 45261.4 47942.4 244.288 45.86 58.18 0.89873 12.6317 318
350.000 0.03646 0.95506 O.OO33Y1 26.84J7 457J2.0 4lS~1l.3 24~.9J·1 44.YI "./3:5 0.90:529 10.4444 323
360.000 0.03526 0.96017 0.003199 27.9469 46189.1 49063.1 247.492 44.04 54.64 0.91081 8.7550 328
370.000 0.03416 0.96418 0.003043 28.9868 46640.1 49606.3 248.980 43.94 54.07 0.91554 7.4302 333
380.000 0.03315 0.96740 0.002914 29.9821 47089.3 50145.8 250.419 44.10 53.89 0.91966 6.3767 338
390.000 0.03221 0.97004 0.002802 30.9447 47539.4 50684.9 251.820 44.43 53.97 0.92330 5.5283 342
4UU.UUU U.UJ134 U.'}"!1-1-1- U.UU1-1U;:' 31.882:5 47991.3 :512.2:5.7 Z:53.189 44.89 :54.22 0.926:54 4.837:5 346
41.0.000 0.03051 0.97406 0.002615 32.8011 48449.3 51769.8 254.532 45.42 54.60 0.92946 4.2696 350
420.000 0.02974 0.97562 0.002535 33.7047 48911.1 52318.1 255.854 46.02 55.08 0.93210 3.7988 354
430.000 0.02901 0;97697 0.002462 34.5963 49378.7 52871.6 257.156 46.66 55.62 0.93451 3.4054 358
440.000 0.02832 0.97813 0.002395 35.4781 49852.3 53430.7 258.441 47.34 56.21 0.93673 3.0746 362
450.000 0.02766 0.97915 0.002332 36.3520 50332.4 53995.9 259.711 48.04 56.84 0.93877 2.7945 366
460.000 0.02703 0.98005 0.002274 37.2194 50819.2 54567.6 260.968 48.75 57.50 0.94067 2.5561 370
470.000 0.02643 0.98085 0.002219 38.0814 51312.9 55145.9 262.212 49.48 58.18 0.94244 2.3521 373
480.000 0.02587 0.98157 0.002168 38.9388 51813.8 55731.2 263.444 50.21 58.87 0.94409 2.1767 377
490.000 0.02532 0.98221 0.002119 39.7925 52321.8 56323.4 264.665 50.95 59.58 0.94564 2.0252 381
500.000 0.02480 0.98279 0.002073 40.6429 52836.9 56922.6 265.875 51.69 60.29 0.94707 1.8938 384
510.000 0.02430 0.98333 0.002029 41.4907 53359.4 57529.1 267.076 52.44 61.01 0.94845 1.7794 388
515.000 0.02406 0.98358 0.002008 41.9136 53623.4 57835.0 267.673 52.81 61.37 0.94911 1. 7277 389
520.000 0.02382 0.98381 0.001987 42.3361 53889.2 58142.8 268.268 53.18 61.73 0.94975 1.6794 391
530.000 0.02336 0.98426 0.001947 43.1796 54426.3 58763.7 269.451 53.92 62.45 0.95099 1.5916 395
540.000 0.02292 0.98468 0.001909 44.0214 54970.7 59391. 8 270.625 54.65 63.17 0.95216 1.5144 398
560.000 0.02208 0.98542 0.001838 45.7010 56081.2 60669.5 272.948 56.11 64.60 0;95435 1.3858 405
580.000 0.02131 0.98608 0.001772 47.3762 57220.4 61975.7 275.240 57.55 66.02 0.95634 1.2842 411
600.000 0.02059 0.98666 0.001711 49.0484 58387.9 63310.0 277.501 58.96 67.41 0.95817 1.2030 418
620.000 0.01991 0.98718 0.001654 50.7181 59583.0 64671.9 279.734 60.34 68.78 0.95986 1.1373 424
640.000 0.01928 0.98765 0.001601 52.3861 60805.4 66061.0 281.939 61.69 70.12 0.96142 1.0836 431
660.000 0.01869 0.98809 0.001552 54.0528 62054.4 67476.6 284.117 63.02 71.44 0.96287 1.0392 437
680.000 0.01813 0.98849 0.001505 55.7186 63329.5 68918.2 286.269 64.31 72.72 0.96422 1.0021 443
700.000 0.01761 0.98886 0.001461 57.3836 64630.0 70385.3 288.395 65.57 73.98 0.96548 0.9708 449
720.000 0.01711 0.98920 0.001420 59.0480 65955.4 71877.2 290.496 66.80 75.21 0.96667 0.9441 455
740.000 0.01664 0.989.52 0.001381 60.7121 67305.0 73393.3 292.573 68.01 16.40 0.96118 0.9211 461
760.000 0.01620 0.98983 0.001345 62.3760 68678.4 74933.1 294.626 69.18 77.57 0.96883 0.9010 467
780.000 0.01578 0.99011 0.001310 64.0396 70074.9 76496.1 296.656 70.32 78.71 0.96981 0.8834 472
800.000 0.01538 0.99039 0.001277 65.7032 71493.9 78081.5 298.663 71.44 79.83 0.97075 0.8677 478

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

860 ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

T Z 8PI8T 8PI8p E H S Cv Cp f/P J1. W

K moill bar/K bar/(mol!l) J/mol J/mol J/(mol·K) J/(mol·K) J/(mol·K) K/bar m/s
1.50000 bar
171;,.'\90 1R.nR97 o .00.~hd 1h ~9d?98 50~ 07"'~ _1 1 L1 ? 89 980 59 dO 71 18 0.00000 -0.0397 1171
180.000 28.08595 0.00357 16.010031 496.0467 342.5 347.8 91.744 59.26 71.05 0.00000 -0.0397 1362
190.000 27.76656 0.00342 15.198363 480.7342 1102.0 1107.4 95.577 59.03 70.87 0.00001 -0.0398 1342
200.000 27.45342 0.00329 14.459723 466.0801 1840.4 1845.9 99.206 58.95 70.85 0.00004 -0.0398 1322
210.000 27.14584 0.00316 13.783955 451.8636 2564.7 2570.2 102.664 59.05 71.04 0.00014 -0.0396 1302
'20.000 '6.84308 0.00305 13.162639 437.8997 32&1.1 32&6.8 105.978 59.36 71.44 0.00039 -0.0393 1282
230.000 26.54441 0.00295 12.588721 424.0332 3995.9 4001.5 109.169 59.87 72.07 0.00102 -0.0388 1262
240.000 26.24906 0.00286 12.056231 410.1351 4714.0 4719.7 112.257 60.58 72.93 0.00241 -0.0382 1241
250.000 25.95623 0.00278 11.560042 396.0989 5440.2 5445.9 115.259 61. 47 73.99 0.00530 -0.0374 1219
260.000 25.66508 0.00270 11.095769 381.8415 6178.3 6184.1 118.187 62.51 75.23 0.01089 -0.0365 1197
270.000 25.37476 0.00263 10.659554 367.2983 6931.6 6937.5 121.053 63.67 76.64 0.02112 -0.0355 1174
280.000 25.08434 0.00257 10.247999 352.4230 7702.4 7708.4 123.868 64.93 78.19 0.03891 -0.0344 1150
290.000 24.79285 0.00251 9.858073 337.1867 8492.7 8498.7 126.639 66.26 79.85 0.06846 -0.0332 1126
300.000 24.49926 0.00245 9.487033 321.5755 9303.4 9309.5 129.373 67.63 81.62 0.11562 -0.0319 1100
310.000 24.20243 0.00240 9.132365 305.5900 10135.2 10141.4 132.076 69.02 83.46 0.18807 -0.0306 1073
320.000 23.90114 0.00236 8.791722 289.2429 10988.1 10994.4 134.753 70.42 85.39 0.29562 -0.0291 1046
330.000 23.59404 0.00232 8.462877 272.5573 11861. 9 11868.2 137.409 71. 81 87.38 0.45023 -0.0274 1017
340.000 23.27960 0.00228 8.143672 255.5648 12755.9 12762.3 140.048 73.17 89.45 0.66590 -0.0257 987
347.975 23.02245 0.00225 7.894590 241.8190 13483.0 13489.5 142.142 74.24 91.16 0.89210 -0.0241 962
3-17.975 0.05541 0.93562 0.005676 25.4290 45367.3 48074.3 241.531 49.87 64.22 0.89210 11 .2880 319
350.000 0.05497 0.93774 0.005565 25.7225 45474.3 48203.2 241.943 49.23 63.17 0.88932 10.8731 320
360.000 0.05295 0.94647 0.005119 27.0613 45982.8 48815.7 243.670 47.25 59.69 0.89703 9.0538 326
370.000 0.05116 0.95307 0.004788 28.2683 46470.0 49401.9 245.277 46.28 57.74 0.90347 7.6129 331
380.000 0.04955 0.95822 0.004527 29.3877 46945.9 49973.4 246.801 45.87 56.66 0.90896 6.4628 336
390.000 0.04807 0.96233 0.004313 30.4-154 47416.5 50537.0 248.266 45.81 56.13 0.91371 5.5366 341
400.000 0.04671 0.96567 0.004132 31.4578 47885.5 51091.1 249.684 45.99 55.94 0.91187 4.7836 345
410.000 0.04544 0.96841 0.003976 32.4360 48355.3 51656.6 251.066 46.32 55.99 0.92155 4.1662 349
420.000 0.04425 0.91071 0.003838 33.3878 48827.7 52217.5 252.417 46.75 56.22 0.92485 3.6560 353
430.000 0.04314 0.97265 0.003714 34.3188 49303.9 52781. 3 253.744 47.21 56.56 0.92182 3.2313 357
440.000 0.04208 0.97430 0.003602 35.2331 49784.7 53349.1 255.049 47.85 57.00 0.93052 2.8755 361
450.000 0.04109 0.97572 0.003500 36.1340 50270.9 53921.6 256.336 48.47 57.51 0.93298 2.5756 365
460.000 0.04014 0.97695 0.003406 37.0239 50762.9 54499.4 257.606 49.12 58.06 0.93525 2.3214 369
470.000 0.03925 0.97803 0.003319 37.9047 51261.0 55083.0 258.861 49.79 58.66 0.93734 2.1050 373
480.000 0.03839 0.97897 0.003237 38.7779 51765.6 55672.7 260.102 50.49 59.29 0.93928 1. 9198 376
490.000 0.03758 0.97981 0.003161 39.6449 52276.9 56268.8 261. 331 51.19 59.93 0.94109 1.7607 380
500.000 0.03680 0.98056 0.003089 40.5066 52794.8 56871. 3 262.549 51.90 60.60 0.94276 1.6235 384
510.000 0.03605 0.98124 0.003021 41.3638 53319.8 57480.7 263.756 52.62 61.28 0.94435 1.5047 387
515.000 0.03569 0.98155 0.002989 41. 7910 53584.9 57787.9 264.355 52.98 61.62 0.94511 1.4513 389
520.000 0.03534 0.98185 0.002957 42.2172 53851.8 58096.8 264.952 53.34 61.96 0.94585 1.4014 391
530_000 0.03465 0_98240 0.002896 43.0674 54390.8 58719.9 266.139 54.06 62.65 0.IM726 1 3115 394
540.000 0.03399 0.98290 0.002838 43.9149 54936.8 59349.9 267.317 54.78 63.35 0.94860 1.2328 398
560.000 0.03275 0.98380 0.002729 45.6031 56050.1 60630.8 269.646 56.21 64.74 0.95108 1.1032 404
580.000 0.03159 0.98456 0.002630 47.2843 57191.4 61939.4 271.942 57.62 66.12 0.95333 1.0024 411
600.000 0.03052 0.98523 0.002538 48.9604 58360.5 63275.5 274.206 59.02 67.49 0.95538 0.9233 418
620.000 0.01Q51 O.QR:<iRl 0.007.453 50 _"17r. 595'\7.0 64';38.9 ?7".441. nO.39 hR. R4 0.95717 0.81106 424
640.000 0.02858 0.98634 0.002373 52.3019 60780.5 66029.1 278.648 61. 73 70.17 0.95902 0.8104 430
660.000 0.02770 0.98682 0.002300 53.9691 62030.3 67445.6 280.828 63.05 71.47 0.96063 0.7700 436
680.000 0.02687 0.98726 0.002230 55.6347 63306.1 68887.9 282.980 64.33 72.75 0.96214 0.7370 443
700.000 0.02609 0.98766 0.002165 57.2991 64607.1 70355.4 285.107 65.59 74.00 0.96355 0.7099 449
720.000 0.02536 0.98803 0.002104 58.9627 65932.9 71847.7 287.209 66.82 75.22 0.96486 0.6875 455
740.000 0.02467 0.98838 0.002046 60.6257 67282.9 73364.2 289.287 68.02 76.42 0.96610 0.6687 461
760.000 0.02401 0.98871 0.001992 62.2882 68656.6 74904.2 291.340 69.19 77 .58 0.96727 0.6529 466
780.000 0.02339 0.98901 0.001940 63.9504 70053.2 76467.3 293.370 70.33 78.72 0.96837 0.6394 472
800.000 0.02279 0.98930 0.001891 65.6125 71472.4 78052.9 295.377 71.44 79.83 0.96941 0.6279 478

J. Phys. Chern. Ref. Data, Vol. is, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 861

Table 17. Properties of methanol along isobars - Continued

T f' Z aPlaT aPlof' E H S Cv Cp flP J1. W

K molll bar/K bar/(mol/!) J/mol J/mol J/(mol'K) J/(mol·K) J/(mol·K) Klbar mls
2.00000 bar
175.590 28.22996 0.00485 16.400202 503.3056 -1. 4 5.6 89.978 59.40 71.18 0.00000 -0.0397 1371
180.000 28.08696 0.00476 16.015821 496.2752 342.1 349.2 91.742 59.26 71.05 0.00000 -0.0397 1362
190.000 27.76760 0.00456 15.203895 480.9584 1101.6 1108.8 95.575 59.02 70.87 0.00001 -0.0398 1342
200.000 27.45449 0.00438 14.465028 466.3009 1840.0 1847.3 99.204 58.94 70.85 0.00003 -0.0398 1322
210.000 27.14694 0.00422 13.789060 452.0820 2564.3 2571.6 102.662 59.05 71.03 0.00010 -0.0396 1302
220.000 26.84422 0.00407 13.167567 438.1165 3280.7 3288.2 105.975 59.36 71.44 0.00030 -0.0393 1282
230.000 26 . .54.559 0.00394 12 . .593493 424.2490 3995.4 4002.9 109.167 59.87 72.07 0.00076 -0.0388 1262
240.000 26.25028 0.00382 12 .060865 410.3506 4713.5 4721.1 112.255 60.58 72.93 0.00181 -0.0382 1241
250.000 25.95749 0.00371 11.564556 396.3147 5439.6 5447.3 115.257 61.46 73.99 0.00398 -0.0374 1220
260.000 25.66639 0.00360 11.100179 382.0581 6177.7 6185.5 118.185 62.50 75.23 0.00817 -0.0365 1197
270.000 25.37612 0.00351 10.663874 367.5161 6931.0 6938.8 121.051 63.67 76.64 0.01585 -0.0355 1175
280.000 25.08576 0.00342 10.252245 352.6425 7701.8 7709.8 123.866 64.92 78.19 0.02920 -0.0344 1151
290.000 24.79434 0.00335 9.862259 337.4081 8492.0 8500.0 126.636 66.25 79.85 0.05139 -0.0332 1126
300.000 24.50081 0.00327 9.491173 321.7991 9302.7 9310.8 129.370 67.62 81.61 0.08678 -0.0319 1100
310.000 24.20406 0.00321 9.136475 305.8161 10134.4 10142.7 132.073 69.02 83.46 0.14116 -0.0306 1074
320.000 23.90287 0.00314 8.795818 289.4716 10987.3 10995.6 134.751 70.41 85.38 0.22189 -0.0291 1046
330.000 23.59.587 0.00309 8.466977 272.7888 11860.9 11869.4 137.407 71.80 87.38 0.33794 -0.0274 1017
340.000 23.28156 0.00304 8.147795 255.7994 12754.9 12763.5 140.045 73.17 89.45 0.49981 -0.0257 987
350.000 22.95821 0.00299 7.836132 238.5414 13668.5 13677 .2 142.670 74.51 91.60 0.71929 -0.0237 956
355.992 22.75931 0.00297 7.652066 228.0880 14225.1 14233.9 144.237 75.30 92.94 0.88364 -0.0225 937
355.992 0.07298 0.92589 0.007819 25.3708 45510.4 48250.9 239.793 53.03 69.14 0.88364 9.9754 321
360.000 0.07178 0.93080 0.007491 26.0057 45740.3 48526.4 240.610 51.55 66.63 0.88250 9.2951 323
370.000 0.06911 0.94074 0.006853 27.4367 46276.3 49170.4 242.375 49.27 62.53 0.89088 7.8053 329
380.000 0.06675 0.94827 0.006382 28.7152 46786.7 49782.8 244.010 48.07 60.16 0.89788 6.6007 334
390.000 0.06464 0.95416 0.006013 29.8911 47282.9 50376.9 245.553 47.49 58.78 0.90384 5.6238 339
400.000 0.06272 0.95555 0.005713 30.9944 47771.4 50960.4 247.031 47.30 55.01 0.90897 4.8270 344
410.000 0.06095 0.96266 0.005461 32.0441 48256.7 51538.3 248.458 47.36 57.64 0.91346 4.1728 348
420.000 0.05930 0.96579 0.005245 33.0530 48741.4 52114.1 249.846 47.61 57.55 0.91743 3.6321 353
430.000 0.05777 0.96840 0.005056 34.0303 49227.7 52689.9 251.201 47.98 57.66 0.92097 3.1823 357
440.000 0.05633 0.97060 0.004888 34.9827 49716.8 53267.7 252.530 48.44 57.91 0.92415 2.8059 361
450.000 0.05497 0.97246 0~004737 35.9149 50210.0 53848.5 253.835 48.96 58.27 0.92702 2.4891 365
460.000 0.05368 0.97406 0.004599 36.8310 50707.8 54433.3 255.120 49.54 58.71 0.92965 2.2212 369
470.000 0.05247 0.97544 0.004473 37.7336 51210.9 55022.8 256.388 50.15 59.21 0.93205 1.9935 372
480.000 0.05131 0.97664 0.004357 38.6252 51719.8 55617.5 257.640 50.79 59.75 0.93427 1.7991 376
490.000 0.05021 0.97770 0.004249 39.5077 52234.7 56217.9 258.878 51.45 60.33 0.93632 1.6325 380
500.000 0.04916 0.97862 0.004148 40.3824 52755.8 56824.2 260.103 52.13 60.94 0.93820 1.4891 383
510.000 0.04816 0.97945 0.004053 41.2507 53283.5 57436.8 261.316 52.82 61.57 0.93998 1.3654 387
515.000 0.04767 0.97983 0.004007 41.6827 53549.9 57745.5 261.919 53.16 61.90 0.94083 1.3099 389
520.000 0.04719 0.98018 0.003963 42.1135 53817.9 58055.7 262.518 53.51 62.22 0.94166 1.2582 390
530.000 0.04627 0.98084 0.003879 42.9716 54359.0 58681.2 263.710 54.21 62.88 0.94323 1.1651 394
540.000 0.04539 0.98144 0.003799 43.8257 54906.8 59313.3 264.891 54.91 63.54 0.94471 1.0840 397
560.000 0.04372 0.98248 0.003650 45.5243 56023.1 60597.7 267.226 56.31 64.89 0.94744 0.9510 404
580.000 0.04218 0.98335 0.003515 47.2127 57166.8 61908.9 269.527 57.71 66.24 0.94990 0.8486 411
600.000 0.04074 0.98410 0.003390 48.8937 58337.8 63247.1 271. 795 59.08 67.58 0.95214 0.7690 417
620.000 0.03940 0.98475 0.003275 50.5691 59535.7 64612.1 274.033 60.44 68.91 0.95419 0.7066 424
640.000 0.03814 0.98532 0.003168 52.2403 60760.3 66003.5 276.242 61.77 70.22 0.95608 0.6573 430
660.000 0.03697 0.98584 0.003069 53.9084 62011.1 67421.0 278.423 63.08 71.52 0.95783 0.6181 436
680.000 0.03587 0.98630 0.002976 55.5742 63287.6 68864.0 280.577 64.36 72.78 0.95946 0.5867 442
700.000 0.03483 0.98673 0.002889 57.2382 64589.2 70332.1 282.704 65.61 74.02 0.96097 0.5614 448
720.000 0.03384 0.98712 0.002807 58.9010 65915.5 71824.8 284.807 66.83 75.24 0.96239 0.5409 454
740.000 0.03292 0.98748 0.002730 60.5629 67265.8 73341.6 286.884 68.03 76.43 0.96373 0.5242 460
760.000 0.03204 0.98782 0.002657 62.2241 68639.7 74881.8 288.938 69.20 77 .59 0.96498 0.5105 466
780.000 0.03121 0.98814 0.002587 63.8849 70036.6 76445.1 290.968 70.34 78.73 0.96617 0.4991 472
800.000 0.03042 0.98845 0.002522 65.5454 71456.0 78030.8 292.975 71.45 79.84 0.96729 0.4896 478

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

1iI,~' ' HOBERT D. GOODWIN

1,'i'l,- 1/, l'ropnt.ies of methanol along isobars ~ Continued

_e ••••••• _ _ _ _ _ •_ _ ~

'/ ~ a rIOT BPIBp E H S Cv Cp flP J.L W

K moll I bar/K bar/(molll) J/mol J/mol Jl(mol·K) J/(mol·K) J/(mo!·K) Klbar m/s
3.00000 bar
175.590 28.23195 0.00728 16.412009 503.7666 -2.2 8.5 89.974 59.40 71.18 0.00000 -0.0397 1372
180.000 28.08897 0.00714 16.027378 496.7315 341.3 352.0 91.738 59.26 71.05 0.00000 -0.0397 1363
190.000 27.76968 0.00684 15.214936 481.4060 1100.8 1111.6 95.571 59.02 70.87 0.00001 -0.0398 1343
200.000 27.45664 0.00657 14.475616 466.7418 1839.2 1850.1 99.200 58.94 70.85 0.00002 -0.0398 1323
210.000 27.14915 0.00633 13.799248 452.5180 2563.4 2574.4 102.658 59.05 71.03 0.00007 -0.0396 1303
220.000 26.84651 0.00611 13.177402 438.5492 3279.8 3291.0 105.971 59.35 71.44 0.00020 -0.0393 1283
230.000 26.54795 0.00591 12.603016 424.6799 3994.4 4005.7 109.163 59.87 72.07 0.00051 -0.0388 1263
240.000 26.25272 0.00573 12.070114 410.7810 4712.5 4723.9 112.251 60.57 72.92 0.00121 -0.0382 1242
250.000 25.96001 0.00556 11.573565 396.7456 5438.5 5450.1 115.252 61.46 73.98 0.00266 -0.0374 1220
260.000 25.66901 0.00541 11.108979 382.4907 6176.6 6188.3 118.180 62.50 75.23 0.00546 -0.0366 1198
270.000 25.37884 0.00527 10.672496 367.9511 6929.7 6941.6 121.047 63.66 76.64 0.01059 -0.0355 1175
280.000 25.08859 0.00514 10.260717 353.0807 7700.5 7712.5 123.861 64.92 78.18 0.01950 -0.0344 1151
290.000 24.79730 0.00502 9.870611 337.8501 8490.6 8502.7 126.631 66.25 79.85 0.03432 -0.0332 1127
300.000 24.50391 0.00491 9.499434 322.2456 9301.2 9313.4 129.365 67.62 81.61 0.05795 -0.0320 1101
310.000 24.20733 0.00481 9.144674 306.2675 10132.8 10145.2 132.068 69.01 83.46 0.09426 -0.0306 1075
320.000 23.90632 0.00472 8.803988 289.9283 10985.6 10998.1 134.745 70.41 85.38 0.14816 -0.0291 1047
330.000 23.59953 0.00463 8.475154 273.2511 11859.1 11871.8 137.401 71.79 87.37 0.22564 -0.0275 1018
340.000 23.28547 0.004:56 8.1:56018 2:56.l..6rt n'/~:l.'J 12765.8 140.039 73.16 89.44 0.33371 -0.0257 988
350.000 22.96240 0.00449 7.844446 239.0162 13666.3 13679.4 142.663 74.50 91.59 0.48024 -0.0238 957
360.000 22.62836 0.00443 7.538260 221.5382 14598.7 14612.0 145.277 75.80 93.84 0.67367 -0.0216 925
368.021 22.35093 0.00439 7.295020 207.3847 15360.2 15373.6 147.368 76.83 95.73 0.86859 -0.0197 898
308.021 0.10786 0.90900 U.012466 25.0594 45680.4 48461. 9 237.276 58.54 78.16 0.86859 8.2721 323
370.000 0.10689 0.91229 0.012148 25.4375 45817.4 48623.9 237.741 57.42 76.21 0.86829 8.0166 324
380.000 0.10253 0.92609 0.010878 27.1520 46423.3 49349.3 239.678 53.72 69.48 0.87861 6.8064 331
390.000 0.09880 0.93641 0.009975 28.6341 46986.1 50022.6 241.429 51.63 65.51 0.88715 5.7956 336
400.000 0.09552 0.94438 0.009292 29.9636 47523.8 50664.6 243.055 50.45 63.08 0.89435 4.9567 341
410.000 0.U92:57 U.'J~06'J 0.008751 31.1865 48046.5 51287.3 244.594 49.83 61.58 0.90052 4.2606 346
420.000 0.08988 0.95576 0.008309 32.3314 48560.6 51898.3 246.067 49.58 60.68 0.90586 3.6816 351
430.000 0.08741 0.95991 0.007937 33.4175 49070.5 52502.4 247.489 49.59 60.19 0.91053 3.1981 355
440.000 0.08512 0.96334 0.007617 34.4582 49578.8 53103.1 248.870 49.77 59.99 0.91467 2.7927 360
450.000 0 .. 08299 0.96620 0.007338 35.4630 50087.8 53702.9 250.218 50.07 59.99 0.91836 2.4512 364
460.000 0.08098 0.96861 0.007091 36.4391 50598.9 54303.5 251.538 50.48 60.15 0.92168 2.1623 368
470.000 0.07909 0.97066 0.006869 37.3919 51113.2 54906.3 252.835 50.95 60.43 0.92468 1.9169 372
480.000 0.07730 0.97241 0.006668 38.3256 51631.5 55512.4 254.111 51.48 60.79 0.92742 1.7076 375
490.000 0.07561 0.97393 0.006484 39.2436 52154.5 56122.4 255.369 52.04 61.22 0.92992 1.5285 379
500.000 0.07400 0.97524 0.006315 40.1483 52682.6 56736.9 256.611 52.64 61. 71 0.93220 1.3746 383
510.000 0.07246 0.97639 0.006158 41.0420 53216.3 57356.6 257.838 53.26 62.24 0.93433 1.2421 386
515.000 0.07172 0.97691 0.006083 41.4853 53485.4 57668.5 258.446 53.58 62.51 0.93534 1.1827 388
520.000 0.07099 0.97739 0.006012 41.9264 53755.9 57981.7 259.052 53.90 62.79 0.93632 1.1275 390
530.000 0.06959 0.97828 0.005875 42.8029 54301.6 58612.6 260.254 54.55 63.38 0.93817 1.0282 393
540.000 0.06825 0.97907 0.005746 43.6726 54853.5 59249.3 261.444 55.21 63.98 0.93990 0.9419 397
560.000 0.06572 0.98041 0.005510 45.3957 55976.3 60541.2 263.793 56.55 65.22 0.94306 0.8012 404
580.000 0.06338 0.98150 0.005298 47.1017 57125.1 61858.3 266.104 57.89 66.49 0.94588 0.6935 410
600.000 0.06121 0.98241 0.005104 48.7950 58300.1 63201.0 268.380 59.23 67.78 0.94842 0.6106 417
620.000 0.05919 0.98317 0.004927 50.4788 59501.2 64569.5 270.623 60.55 69.06 0.95074 0.5462 423
640.000 0.05730 0.98383 0.004763 52.1555 60728.3 65963.6 272.836 61.86 70.34 0.95285 0.4960 430
660.000 0.05553 0.98441 0.004611 53.8268 61981.1 67383.1 275.020 63.15 71.61 0.95481 0.4567 436
680.000 0.05387 0.98492 0.004470 55.4941 63259.1 68827.7 277.177 64.42 72.85 0.95662 0.4258 442
700.000 0.05231 0.98538 0.004338 57.1583 64562.0 70297.0 279.306 65.66 74.08 0.95830 0.4014 448
720.000 0.05084 0.98580 0.004214 58.8203 65889.2 71790.7 281.410 66.87 75.28 0.95988 0.3821 454
740.000 0.04944 0.98619 0.004097 60.4806 67240.3 73308.1 283.489 68.06 76.46 0.96136 0.3668 460
760.000 0.04812 0.91:16.54 0.003987 62.1398 68614.9 74848.8 285.543 69.22 77.61 0.96274 0.3546 466
780.000 0.04687 0.98687 0.003883 63.7980 70012.2 76412.4 287.573 70.35 78.74 0.96405 0.3450 472
800.000 0.04569 0.98719 0.003784 65.4558 71432.0 77998.3 289.581 71.46 79.85 0.96529 0.3373 477

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 863
Table 17. Properties of methanol along isobars - Continued

T p Z 3PI3T 3?13p E H S Cu Cp j/P J1. W

K molll bar/K bar/(moI/I) limol llmol Jl(mo!·K) ll(mol·K) ll(mo!·K) K/bar m/s
4.00000 bar
175.590 28.23393 0.00970 16.423783 -2.9 11.3 89.970 59.39 71.18 0.00000 -0.0397 1373
180.000 28.09099 0.00951 16.038902 497.1869 340.6 3~4.9 91. '/34 ~9.2~ '/l.U~ U.UUUUU -U.0397 1364
190.000 27.77175 0.00912 15.225946 481.8526 1100.1 1114.5 95.567 59.02 70.87 '0.00000 -0.0398 1343
200.000 27.45878 0.00876 14.486173 467.1817 1838.4 1853.0 99.196 58.93 70.85 0.00002 -0.0398 1323
210.000 27.15136 0.00844 13.809406 452.9531 2562.5 2577.3 102.654 59.04 71.03 0.00005 -0.0396 1304
220.000 26.84879 0.00814 13.187208 438.9810 3278.9 3293.8 105.967 59.35 71.44 0.00015 -0.0393 1284
230.000 26.55030 0.00788 12.612511 425.1099 3993.4 4008.5 109.158 59.86 72.07 0.00038 -0.0388 1263
240.000 26.25515 0.00763 12.079336 411.2104 4711.4 4726.7 112.247 60.57 72.92 0.00091 -0.0382 1243
250.000 25.96253 0.00741 11.582547 397.1756 5437.5 5452.9 115.248 61.45 73.98 0.00200 -0.0374 1221
260.000 25.67162 0.00721 11.117753 382.9223 6175.4 6191.0 118.176 62.49 75.23 0.00410 -0.0366 1199
270.000 25.38156 0.00702 10.681091 368.3852 6928.5 6944.3 121.042 63.65 76.63 0.00795 -0.0356 1176
280.000 25.09142 0.00685 10.269163 353.5180 7699.2 7715.1 123.856 64.91 78.18 0.01465 -0.0345 1152
290.000 24.80026 0.00669 9.878936 338.2913 8489.2 8505.4 126.627 66.24 79.84 0.02578 -0.0333 1128
300.000 24.50702 0.00654 9.507667 322.6912 9299.7 9316.0 129.360 67.61 81.60 0.04353 -0.0320 1102
310.000 24.21059 0.00641 9.152846 306.7179 10131.2 10147.8 132.063 69.00 83.45 0.07081 -0.0306 1075
320.000 23.90977 0.00629 8.812131 290.3840 10983.9 11000.6 134.740 70.40 85.37 0.11129 -0.0291 1048
330.000 23.60319 0.00618 8.483302 273.7125 11857.3 11874.2 137.395 71.79 87.36 0.16949 -0.0275 1019
340.000 23.28936 0.00608 8.164211 256.7351 12750.9 12768.1 140.033 73.15 89.43 0.25066 -0.0257 989
350.000 22.96658 0.00598 7.852728 239.4899 13664 .1 13681.5 142.657 74.49 91.57 0.36072 -0.0238 958
360.000 22.63287 0.00590 7.546684 222.0189 14596.3 14614.0 145.270 75.79 93.82 0.50600 -0.0216 926
370.000 22.28592 0.00583 7.243812 204.3662 15547.2 15565.2 147.876 77 .06 96.19 0.69302 -0.0192 892
377.122 22.02922 0.00579 7.028683 191.7062 16236.0 16254.1 149.729 77.94 97.97 0.85521 -0.0173 867
377.122 0.14265 0.89427 0.017557 24.6277 45769.4 48573.4 235.429 63.35 86.55 0.85521 7.1656 324
380.000 0.14067 0.90001 0.016839 25.2513 45986.5 48830.1 236.114 61.43 82.99 0.85828 6.8650 326
390.000 0.13463 0.91625 0.014916 27.1566 46643.0 49614.1 238.154 56.96 74.59 0.86980 5.8866 333
400.000 0.12955 0.92837 0.013566 28.7800 47245.4 50333.0 239.975 54.35 69.59 0.87930 5.0506 339
410.000 0.12513 0.93772 0.012555 30.2187 47815.4 51012.1 241.653 52.80 66.46 0.88729 4.3440 344
420.000 0.12120 0.94510 0.011763 31.5282 48365.5 51665.9 243.230 51.91 64.46 0.89411 3.7491 349
430.000 0.11764 0.95104 0.011121 32.7435 48903.5 52303.7 244.731 51.45 63.19 0.89999 3.2483 354
440.000 0.11438 0.95588 0.010587 33.8875 49434.3 52931.3 246.175 51.29 62.41 0.90513 2.8260 358
450.000 0.11138 0.95988 0.010132 34.976.3 49961.6 53553.0 247.572 51.33 61.98 0.90966 2.4688 363
460.000 0.10858 0.96320 0.009738 36.0215 50487.7 54171. 7 248.932 51.53 61.80 0.91368 2.1659 367
470.000 0.10596 0.96600 0.009392 37.0318 51014.6 54789.6 250.261 51.84 61.81 0~91728 1.9081 371
480.000 0.10350 0.96837 0.009084 38.0136 51543.6 55408.3 251.564 52.23 61.96 0.92053 1.6880 375
490.000 0.10118 0.97039 0.008807 38.9721 52075.7 56029.1 252.844 52.69 62.22 0.92348 1.4995 378
500.000 0.09898 0.97213 0.008555 39.9111 52611.5 56652.8 254.105 53.20 62.56 0.92614 1. 3374 382
510.000 0.09689 0.97363 0.008324 40.8340 53151.9 57280.4 255.348 53.75 62.97 0.92860 1.1978 386
515.000 0.09588 0.97430 0.008216 41.2902 53423.9 57595.8 255.963 54.03 63.19 0.92976 1.1353 388
520.000 0.09490 0.97493 0.008112 41.7433 53697.2 57912.4 256.575 54.32 63.43 0.93088 1.0771 390
530.000 0.09300 0.97607 0.007915 42.6410 54247.9 58549.1 257.788 54.92 63.92 0.93298 0.9725 393
540.000 0.09118 0.97707 0.007731 43.5289 54804.1 59191.0 258.988 55.54 64.45 0.93494 0.8817 397
560.000 0.08778 0.97873 0.007397 45.2809 55934.2 60491.3 261.352 56.80 65.58 0.93849 0.7337 403
580.000 0.08463 0.98005 0.007100 47.0080 57088.5 61814.8 263.674 58.09 66.77 0.94162 0.6207 410
600.000 0.08172 0.98113 0.006832 48.7166 58267.9 63162.4 265.959 59.39 67.99 0.94442 0.5338 417
620.000 0.07902 0.98201 0.006589 50.4113 59472.4 64534.7 268.209 60.68 69.23 0.94694 0.4666 423
640.000 0.07649 0.98276 0.006365 52.0956 60702.2 65931. 7 270.426 61.96 70.47 0.94924 0.4144 430
660.000 0.07412 0.98339 0.006159 53.7719 61957.1 67353.6 272 .614 63.23 71.71 0.95136 0.3738 436
680.000 0.07190 0.98395 0.005968 55.4422 63236.8 68800.0 274.773 64.48 72.93 0.95331 0.3420 442
700.000 0.06981 0.98444 0.005789 57.1079 64541.1 70270.6 276.904 65.71 74.14 0.95512 0.3172 448
720.000 0.06784 0.98488 0.005622 58.7702 65869.4 71765.3 279.009 66.91 75.32 0.95680 0.2977 454
740.000 0.06598 0.98527 0.005465 60.4300 67221.4 73283.5 281.089 68.09 76.49 0.95838 0.2825 460
760.000 0.06422 0.98564 0.005318 62.0878 68596.5 74824.8 283.144 69.24 77 .64 0.95987 0.2707 466
780.000 0.06256 0.98597 0.005178 63.7443 69994.4 76388.8 285.175 70.37 78.76 0.96127 0.2615 471
800.000 0.06097 0.98629 0.005046 65.3998 71414.5 77974.9 287.183 71.48 79.86 0.96259 0.2543 477

J. Phys. Chern. Ref. Data, Vol. 16, No. 4.1987

864 ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

T p Z 8PI8T 8PI8p E H S Cu Cp flP IL W

K moll! bar/K bar/(mol/I) J/mol J/mol J/(mol·K) J/(mo!·K) J!(mo!·K) K/bar m/s
6.00000 bar
0.01455 16.447232 505.1437 -4.3 16.9 &9.961 59.3& 71.1& 0.00000 -0.0397 1374
180.000 28.09500 0.01427 16.061854 498.0949 339.1 360.5 91.726 59.24 71.05 0.00000 -0.0397 1365
190.000 21.11~90 0.01367 1:5.241872 452.7432 1095.~ 1120.1 9:5.~~9 ~9.01 70.57 0.00000 -0.0395 1345
200.000 27.46306 0.01314 14.507198 468.0589 1836.7 1858.6 99.188 58.93 70.85 0.00001 -0.0398 1325
210.000 27.15577 0.01265 13.829636 453.8205 2560.8 2582.9 102.646 59.03 71.03 0.00003 -0.0396 1305
220.000 26.85334 0.01222 13.206736 439.8419 3277 .1 3299.4 105.959 59.34 71.44 0.00010 -0.0393 1285
230.000 26.55500 0.01182 12.631420 425.9671 3991.5 4014.1 109.150 59.85 72.07 0.00026 -0.0388 1265
240.000 26.26001 0.01145 12.097698 412.0665 4709.4 4732.2 112.238 60.56 72.92 0.00061 -0.0382 1244
250.000 25.96756 0.01112 11.600432 398.0329 5435.3 5458.4 115.239 61.44 73.98 0.00134 -0.0374 1222
260.000 25.67684 0.01081 11.135222 383.7827 6173.2 6196.5 118.167 62.48 75.22 0.00274 -0.0366 1200
270.000 25.38698 0.01053 10.698204 369.2505 6926.1 6949.7 121.033 63.64 76.63 0.00532 -0.0356 1177
280.000 25.09707 0.01027 10.285977 354.3897 7696.6 7720.5 123.847 64.90 78.17 0.00980 -0.0345 1154
290.000 24.80616 0.01003 9.895509 339.1707 8486.5 8510.7 126.617 66.23 79.83 0.01725 -0.0333 1129
300.000 24.51321 0.009&1 9.524056 323.5794 9296.& 9321.3 129.350 67.60 81.59 0.02912 -0.0320 1104
310.000 24.21710 0.00961 9.169111 307.6158 10128.1 10152.9 132.053 68.99 83.44 0.04736 -0.0306 1077
320.000 23.91664 0.00943 8.828335 291.2924 10980.5 11005.6 134.729 70.39 85.35 0.07443 -0.0291 1049
330.000 23.61049 0.00926 8.499515 274.6322 11853.6 11879.0 137.384 71.77 87.34 0.11334 -0.0275 1021
340.000 23.29714 0.00911 8.180509 257.6668 12746.9 12772.7 140.022 73.13 89.40 0.16762 -0.0258 991
350.000 22.97492 0.00897 7.869200 240.4344 13659.8 13685.9 142.645 74.47 91.55 0.24120 -0.0238 960
360.000 22.64186 0.00885 7.563432 222.9771 14591.6 14618.1 145.257 75.77 93.79 0.33833 -0.0217 928
370.000 22.29568 0.00875 7.260960 205.3393 15542.0 15568.9 147.861 77.04 96.15 0.46336 -0.0193 894
380.000 21. 93364 0.00866 6.959348 187.5642 16511.1 16538.5 150.462 78.26 98.66 0.62057 -0.0165 859
390.000 21.55235 0.00859 6.655855 169.6911 17500.1 17527.9 153.061 79.44 101. 36 0.81399 -0.0133 822
390.836 21.51948 0.00858 6.630302 168.1936 17583.7 17611.6 153.279 79.54 101.60 0.83191 -0.0130 818

390.836 0.21255 0.86868 0.028929 23.6315 45831.9 48654.7 232.706 71.68 102.32 0.83191 5.7522 324
400.000 0.20261 0.89042 0.025055 25.8990 46576.6 49537.9 234.884 64.83 88.45 0.85151 5.0777 332
410.000 0.19386 0.90790 0.022200 27.9274 47279.6 50374.5 236.953 60.38 79.63 0.86354 4.4123 339
420.000 0.18653 0.92114 0.020154 29.6618 47924.8 51141.5 238.803 57.64 74.17 0.87355 3.8307 345
430.000 0.18017 0.93148 0.018607 31.1975 48533.9 51864.2 240.506 55.92 70.62 0.88202 3.3284 350
440.000 0.17453 0.93970 0.017389 32.5911 49119.9 52557.7 242.102 54.85 68.26 0.88927 2.8971 355
450.000 0.16945 0.94636 0.016401 33.8792 49691.0 53231. 9 243.617 54.24 66.68 0.89554 2.5276 360
460.000 0.16482 0.95182 0.015579 35.0862 50252.7 53893.1 245.072 53.93 65.64 0.90102 2.2112 365
470.000 0.16055 0.95634 0.014881 36.2297 50808.8 54546.0 246.476 53.85 64.99 0.90585 1.9398 369
480.000 0.15659 0.96011 0.014278 37.3225 51362.1 55193.9 247.841 53.93 64.62 0.91013 1.7068 373
490.000 0.15288 0.96329 0.013751 38.3743 51914.7 55839.2 249.172 54.14 64.47 0.91396 1.5063 377
500.000 0.14941 0.96598 0.013283 39.3922 52467.9 56483.1 250.474 54.44 64.48 0.91738 1.3334 381
510.000 0.14613 0.96828 0.012864 40.3823 53023.2 57129.1 251.753 54.82 64.61 0.92050 1.1839 385
515.000 0.14456 0.96930 0.012670 40.8683 53301.8 57452.4 252.383 55.03 64.71 0.92196 1;1169 387
520.000 0.14303 0.97025 0.012486 41. 3489 53581.3 57776.2 253.009 55.26 64.84 0.92335 1.0544 389
530.000 0.14009 0.97194 0.012141 42.2959 54143.1 58426.1 254.248 55.74 65.15 0.92595 0.9420 392
540.000 0.13729 0.97341 0.011824 43.2262 54709.0 59079.4 255.469 56.25 65.52 0.92834 0.8442 396
560.000 0.13206 0.97581 0.011260 45.0462 55854.8 60398.3 257.867 57.36 66.39 0.93260 0.6845 403
580.000 0.12726 0.97766 0.010770 46.8242 57021.4 61736.1 260.215 58.53 67.40 0.93629 0.5623 410
600.000 0.12284 0.97910 0.010336 48.5707 58210.3 63094.7 262.518 59.73 68.48 0.93954 0.4682 416
620.000 0.11874 0.98026 0.009946 50.2936 59422.3 64475.6 264.782 60.96 69.61 0.94243 0.3954 423
640.000 0.11492 0.98119 0.009594 51.9985 60658.1 65879.3 267.010 62.19 70.77 0.94504 0.3388 429
660.000 0.11135 0.98196 0.009272 53.6896 61917.7 67306.3 269.206 63.41 71 ;93 0.94741 0.2948 435
680.000 0.10800 0.98261 0.008975 55.3702 63201.2 68756.7 271.370 64.63 73.11 0.94958 0.2604 442
700.000 0.10486 0.98316 0.008700 57.0426 64508.4 70230.5 273.507 65.82 74.27 0.95158 0.2336 448
720.000 0.10189 0.98364 0.008444 58.7089 65839.1 71727.5 275.615 67.01 75.43 0.95344 0.2127 454
740.000 0.09910 0.98406 0.008205 60.3704 67192.9 73247.6 277.697 68.17 76.57 0.95517 0.1965 460
760.000 0.09645 0.98443 0.007981 62.0282 68569.6 74790.2 279.754 69.30 77.69 0.95679 0.1839 465
780.000 0.09395 0.98477 0.007769 63.6834 69968.6 76355.2 281.786 70.42 78.80 0.95832 0.1743 471
800.000 0.09157 0.98509 0.007570 65.3365 71389.6 77942.0 283.795 71.51 79.88 0.95976 0.1670 477

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 865
Table 17. Properties of methanol along isobars - Continued

T p Z aplaT aPiap E H S Cv Cp liP It W

K molll bar/K bar/(molll) Jlmol J/mo} Jl(mol·K) J/(mol·K) J/(mol·K) K/bar m/s

8.00000 bar
175.590 28.24185 0.01940 16.470551 506.0571 -5.7 22.6 89.953 59.38 71.18 0.00000 -0.0397 1375
180.000 28.09902 0.01902 16.084678 498.9992 337.7 366.1 91.718 59.23 71.05 0.00000 -0.0397 1366
190.000 27.78004 0.01823 15.269676 483.6300 1096.9 1125.7 95.551 59.00 70.87 0.00000 -0.0398 1346
200.000 27.46732 0.01751 14.528105 468.9324 1835.1 1864.2 99.180 58.92 70.85 0.00001 -0.0398 1326
210.000 27.16018 0.01687 13.849753 454.6843 2559.1 2588.5 102.637 59.02 71.03 0.00003 -0.0396 1306
220.000 26.85788 0.01628 13.226154 440.6992 3275.2 3305.0 105.950 59.33 71.44 0.00007 -0.0393 1286
230.000 26.55969 0.01575 12.650220 426.8207 3989.6 4019.7 109.141 59.84 72.07 0.00019 -0.0388 1266
240.000 26.26486 0.01526 12.115955 412.9190 4707.4 4737.8 112.230 60.55 72.92 0.00046 -0.0382 1245
250.000 25.97258 0.01482 11.618212 398.8865 5433.1 5464.0 115.231 61.43 73.97 0.00101 -0.0375 1224
260.000 25.68204 0.01441 11.152588 384.6395 6170.9 6202.0 118.158 62.47 75.22 0.00207 -0.0366 1202
270.000 25.39239 0.01403 10.715214 370.1122 6923.7 6955.2 121.024 63.63 76.62 0.00401 -0.0356 1179
280.000 25.10271 0.01369 10.302689 355.2578 7694.1 7725.9 123.838 64.89 78.17 0.00738 -0.0345 1155
290.000 24.81205 0.01337 9.911978 340.0464 8483.7 8516.0 126.608 66.22 79.83 0.01298 -0.0333 1131
300.000 24.51938 0.01308 9.540341 324.4639 9293.8 9326.5 129.341 67.59 81.58 0.02191 -0.0320 1105
310.000 24.22360 0.01281 9.185270 308.5100 10124.9 10158.0 132.043 68.98 83.42 0.03563 -0.0306 1079
320.000 23.92350 0.01257 8.844431 292.1971 10977 .1 11010.5 134.719 70.37 85.34 0.05600 -0.0292 1051
330.000 23.61776 0.01235 8.515616 27~.54!Sl 11lS~U.U IllSlSJ.lS 137.373 71. 7~ 57.32 0.05~27 -0.0276 1023
340.000 23.30489 0.01214 8.196691 258.5945 12743.0 12777.3 140.010 73.12 89.38 0.12610 -0.0258 993
350.000 22.98322 0.01196 7.885549 241.3748 13655.5 13690.3 142.632 74.45 91.52 0.18144 -0.0239 962
360.000 22.65081 0.01180 7.580050 223.9310 14586.8 14622.1 145.244 75.75 93.76 0.25450 -0.0218 930
370.000 22.30540 0.01166 7.277968 206.3079 15536.7 15572.6 147.847 77 .02 96.11 0.34854 -0.0194 896
380.000 21.94427 0.01154 6.976893 188.5492 16505.3 16541.8 150.446 7 IS. :l4 ~lS.61 U.46677 -0.0166 561
390.000 21.56410 0.01144 6.674127 170.6948 17493.5 17530.6 153.045 79.41 101.30 0.61224 -0.0134 824
400.000 21.16070 0.01137 6.366511 152.7781 18503.5 18541.3 155.647 80.53 104.23 0.78773 -0.0096 785
401.258 21.10805 0.01136 6.327290 150.5212 18632.2 18670.1 155.975 80.67 104.62 0.81206 -0.0091 780
401.258 0.28333 0.84632 0.041697 22.5845 45817.4 4!S64U.9 23U.007 1!S.'1H 111.35 0.81206 4.8:564 323
410.000 0.26922 0.87169 0.035714 25.1081 46622.8 49594.4 232.906 70.67 99.40 0.83819 4.3579 331
420.000 0.25654 0.89298 0.031165 27.4327 47405.7 50524.0 235.150 64.98 87.57 0.85192 3.8273 339
430.000 0.24616 0.90899 0.027971 29.3846 48110.9 51360.7 237.121 61.42 80.32 0.86330 3.3523 346
440.000 0.23732 0.92143 0.025594 31.0884 48767.7 52138.7 238.912 59.13 75.59 0.87289 2.9339 352
450.000 0.22959 0.93130 0.023747 32.6163 49393.1 52877.6 240.574 57.64 72.40 0.88107 2.5689 357
460.000 0.22269 0.93928 0.022265 34.0142 49997.6 53590.0 242.141 56.70 70.22 0.88813 2.2519 362
470.000 0.21645 0.94581 0.021045 35.3126 50588.2 54284.2 243.634 56.13 68.72 0.89426 1.9773 367
480.000 0.21074 0.95121 0.020020 36.5331 51169.7 54966.0 245.070 55.84 67.70 0.89965 1.7395 371
490.000 0.20546 0.95571 0.019143 37.6914 51745.8 55639.4 246.459 55.76 67.04 0.90441 1.5336 376
500.000 0.20056 0.95950 0.018382 38.7993 52318.7 56307.6 247.810 55.82 66.65 0.90862 1.3550 380
510.000 0.19597 0.96270 0.017713 39.8658 52890.7 56973.0 249.128 56.01 66.46 0.91241 1.1999 384
515.000 0.19378 0.96412 0.017407 40.3857 53176.8 57305.2 249.776 56.14 66.43 0.91417 1.1302 386
520.000 0.19166 0.96543 0.017118 40.8978 53463.2 57637.3 250.418 56.28 66.43 0.91583 1.0651 388
530.000 0.18759 0.96776 0.016584 41. 9011 54037.3 58301.9 251.684 56.63 66.52 0.91893 0.9476 391
540.000 0.18374 0.96977 0.016101 42.8800 54613.9 58967.9 252.930 57.03 66.70 0.92176 0.8451 395
560.000 0.17658 0.97300 0.015256 44.7789 55777.1 60307.5 255.366 57.96 67.29 0.92672 0.6771 402
580.000 0.17007 0.97545 0.014536 46.6167 56957.1 61661.1 257.741 59.00 68.09 0.93096 0.5479 409
600.000 0.16408 0.97733 0.013910 48.4090 58156.4 63032.0 260.065 60.11 69.02 0.93463 0.4480 416
620.000 0.15855 0.97879 0.013357 50.1669 59376.7 64422.3 262.344 61.26 70.03 0.93785 0.3704 423
640.000 0.15342 0.97995 0.012861 51.8984 60618.9 65833.5 264.585 62.43 71.09 0.94072 0.3099 429
660.000 0.14862 0.98089 0.012412 53.6097 61883.7 67266.4 266.789 63.61 72.19 0.94331 0.2626 435
680.000 0.14414 0.98165 0.012003 55.3054 63171.3 68721.4 268.961 64.78 73.31 0.94566 0.2255 441
700.000 0.13993 0.98227 0.011626 56.9890 64481.8 70198.8 271.102 65.95 74.43 0.94781 0.1965 448
720.000 0.13597 0.98280 0.011276 58.6631 65815.2 71698.7 273.215 67.11 75.55 0.94980 0.1738 453
740.000 0.13224 0.95326 0.0109~2 60.3298 67171.1 73220.8 27~.300 65.2~ 76.66 0.95165 0.1~61 4~9
760.000 0.12871 0.98365 0.010648 61.9909 68549.5 74765.2 277.359 69.37 77.76 0.95337 0.1423 465
780.000 0.12536 0.98400 0.010363 63.6476 69949.8 76331. 3 279.393 70.48 78.85 0.95498 0.1317 471
800.000 0.12219 0.98431 0.010094 65.3010 71371.9 77919.1 281.403 71.56 79.92 0.95651 0.1236 477

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

/li'/, ROBERT D. GOODWIN

Tdh.k 17. Properties of methanol along isobars - Continued

., ,. ...... ~." .......
Z (JPI(JT 8PI8p E }{ S Cu Cp flP J.I. W
K molll bar/K bar/(mollI) J/mol J/mol J/(mol·K) J/(mol·K) J/(rnol·K) Klbar rnls
10.00000 bar
175.590 28.24580 0.02425 16.493741 506.9668 -7.2 28.2 89.945 59.37 71.18 0.00000 -0.0397 1377
180.000 28.10302 0.02378 16.107377 499.8998 336.2 371.8 91.710 59.22 71.05 0.00000 -0.0397 1368
190.000 27.78417 0.02278 15.291359 484.5133 1095.4 1131.4 95.542 58.99 70.87 0.00000 -0.0398 1347
200.000 27.47159 0.02189 14.548896 469.8024 1833.5 1869.9 99.172 58.91 70.85 0.00001 -0.0398 1327
210.000 27.16457 0.02108 13.869756 455.5445 2557.3 2594.1 102.629 59.01 71.03 0.00002 -0.0396 1308
220.000 26.86241 0.02035 13.245462 441.5529 3273.4 3310.7 105.942 59.32 71.43 0.00006 -0.0393 1288
230.000 26.56437 0.01969 12.668914 427.6708 3987.7 4025.3 109.133 59.83 72.06 0.00016 -0.0388 1267
240.000 26.26970 0.01908 12.134106 413.7679 4705.3 4743.4 112.221 60.54 72.91 0.00037 -0.0382 1247
250.000 25.97759 0.01852 11.635889 399.7366 5431.0 5469.5 115.222 61.42 73.97 0.00081 -0.0375 1225
260.000 25.68724 0.01801 11.169851 385.4927 6168.6 6207.5 118.150 62.46 75.21 0.00166 -0.0366 1203
270.000 25.39779 0.01754 10.732123 370.9702 6921.3 6960.6 121.015 63.62 76.62 0.00322 -0.0356 1180
280.000 25.10833 0.01711 10.319299 356.1222 7691.5 7731.3 123.829 64.88 78.16 0.00592 -0.0345 1157
290.000 24.81792 0.01671 9.928346 340.9185 8481.0 8521.3 126.598 66.20 79.82 0.01042 -0.0333 1132
300.000 24.52553 0.01635 9.556523 325.3447 9290.9 9331. 7 129.331 67.57 81.57 0.01759 -0.0320 1107
310.000 24.23007 0.01601 9.201324 309.4005 10121.8 10163.1 132.033 68.96 83.41 0.02860 -0.0307 1080
320.000 23.93033 0.01571 8.860420 293.0980 10973.7 11015.5 134.708 70.36 85.32 0.04494 -0.0292 1053
330.000 23.62500 0.01543 150531607 276.4601 11846.3 118815.6 137.362 71.74 57.31 0.06543 -0.0276 1024
340.000 23.31261 0.01517 8.212758 259.5184 12739.0 12781.9 139.998 73.10 89.36 0.10118 -0.0258 995
350.000 22.99149 0.01495 7.901778 242.3111 13651.2 13694.7 142.620 74.43 91.49 0.14559 -0.0239 964
360.000 22.65972 0.01474 7.596540 224.8808 14582.1 14626.2 145.231 75.73 93.72 0.20420 -0.0218 931
370.000 22.31507 0.01457 7.294837 207.2723 15531.5 15576.3 147.833 76.99 96.07 0.27964 -0.0194 898
380.000 21.95455 0.01442 6.9942151 189.5296 16499.5 16545.1 150.431 18.21 9lS.56 0.31449 -0.0161 863
390.000 21.57579 0.01429 6.692229 171.6936 17487.0 17533.4 153.028 79.38 101.23 0.49119 -0.0135 826
400.000 21.17375 0.01420 6.385561 153.7984 18496.1 18543.3 155.629 80.50 104.15 0.63198 -0.0098 788
409.774 20.75343 0.01414 6.077726 136.2724 19506.5 19554.7 158.181 81.53 107.32 0.79484 -0.0054 748
409.774 0.35531 0.82605 0.055683 21.5425 45763.7 4857lS. I /..29.0U9 1:15.26 U1.97 U. '/941:14 4.U46 322
410.000 0.35473 0.82695 0.055404 21.6259 45798.5 48617.5 228.937 84.92 131.17 0.81149 4.2147 322
420.000 0.33308 0.85974 0.045881 24.8028 46789.6 49791.9 231. 773 74.37 106.50 0.82955 3.7564 332
430.000 0.31671 0.88316 0.039801 27.2982 47626.0 50783.5 234.109 68.13 93.01 0.84422 3.3255 . 341
440.000 0.30345 0.90079 0.035547 29.3832 48373.5 51669.0 236.148 64.16 84.71 0.85639 2.9337 347
450.000 0.29226 0.91450 0.032389 31.1948 49065.5 52487.1 237.988 61.56 79.27 0.86664 2.5839 354
460.000 0.28253 0.92541 0.029943 32.8123 49720.8 53260.2 239.688 59.82 75.57 0.87538 2.2750 359
470.000 0.27391 0.93424 0.027987 34.2857 50351.3 54002.2 241.285 58.68 72.99 0.88291 2.0040 364
480.000 0.26614 0.94148 0.026382 35.6487 50965.1 54722.5 242.802 57.95 71.18 0.88946 1.7670 369
490.000 0.25906 0.94747 0.025038 36.9250 51567.5 55427.6 244.257 57.52 69.92 0.89519 1.5600 374
500.000 0.25255 0.95248 0.023893 38.1319 52162.4 56122.1 245.661 57.32 69.06 0.90023 1.3794 378
510.000 0.24650 0.95669 0.022903 39.2822 52752.9 56809.6 247.023 57.29 68.49 0.90473 1.2217 382
515.000 0.24364 0.95855 0.022456 39.8394 53047.1 57151.6 247.690 57.32 68.30 0.90679 1.1505 384
520.000 0.24086 0.96026 0.022036 40.3859 53341.0 57492.7 248.349 57.38 68.16 0.90875 1.0840 386
530.000 0.23557 0.96330 0.021268 41.4509 53928.5 58173.4 249.646 57.58 68.01 0.91236 0.9635 390
540.000 0.23059 0.96590 0.020581 42.4833 54516.6 58853.3 250.917 57.86 67.99 0.91563 0.8580 394
560.000 0.22140 0.97006 0.019399 44.4693 55698.6 60215.3 253.395 58.60 68.27 0.92131 0.6842 402
580.000 0.21308 0.97318 0.018411 46.3740 56893.0 61586.1 255.800 59.50 68.84 0.92608 0.5498 409
600.000 0.20548 0.97555 0.017565 48.2181 58103.5 62970.2 258.146 60.51 69.60 0.93017 0.4454 416
620.000 0.19848 0.97738 0.016827 50.0163 59332.5 64370.9 260.443 61.58 70.49 0.93372 0.3639 422
640.000 0.19199 0.97880 0.016173 51.7794 60581.7 65790.2 262.696 62.68 71.45 0.93685 0.3000 429
660.000 0.18596 0.97992 0.015586 53.5154 61852.0 67229.4 264.910 63.81 72.48 0.93964 0.2499 435
680.000 0.18033 0.98082 0.015055 55.2302 63144.1 68689.5 267.090 64.95 73.53 0.94215 0.2103 441
700.000 0.17505 0.98155 0.014569 56.9285 64458.2 70171.0 269.237 66.09 74.61 0.94444 0.1792 447
720.000 0.17008 0.98215 0.014122 58.6138 65794.4 71674.0 271.354 67.22 75.69 0.94653 0.1547 453
740.000 0.16~40 0.91526:5 0.013707 60.21>89 6n~:l.·1 7J1915.6 :l7j .44:l 61>.j4 76.77 U.94~47 U.IJ~:5 4:59
760.000 0.16098 0.98307 0.013321 61.9561 68532.8 74744.9 275.504 69.45 77.85 0.95028 0.1204 465
780.000 0.15679 0.98343 0.012960 63.6169 69934.7 76312.5 277.540 70.54 78.92 0.95196 0.1087 471
800.000 0.15282 0.98375 0.012621 65.2729 71357.9 77901.4 279.551 71.61 79.97 0.95355 0.0997 476

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 867

Table 17. Properties of methanol along isobars - Continued

T Z aplaT aPlap E H S Cu Cp flP J.L W

K molll bar/K bar/(molll) llmol J/mol J/(mol·K) J/(mol·K) J/(mol·K) K/bar m/s
12.00000 bar
175.590 28.24974 0.02910 16.516805 507.8729 -8.6 33.9 89.937 59.36 71.18 0.00000 -0.039T 1378
180.000 28.10702 0.02853 16.129951 500.7969 334.8 377 .4 91.702 59.22 71.05 0.00000 -0.0397 1369
190.000 27.78829 0.02734 15.312924 485.3930 1093.9 1137.0 95.534 58.98 70.87 0.00000 -0.0398 1349
200.000 27.47584 0.02626 14.569573 470.6688 1831.8 1875.5 99.163 58.90 70.85 0.00001 -0.0398 1329
210.000 27.16896 0.02530 13.889650 456.4012 2555.6 2599.8 102.621 59.00 71.03 0.00002 -0.0396 1309
220.000 26.86694 0.02442 13.264663 442.4031 3271.6 3316.3 105.934 59.31 71.43 0.00005 -0.0393 1289
230.000 26.56905 0.02362 12.687503 428.5173 3985.7 4030.9 109.125 59.82 72.06 0.00013 -0.0388 1269
240.000 26.27453 0.02289 12.152155 414.6133 4703.3 4749.0 112.213 60.53 72.91 0.00031 -0.0382 1248
250.000 25.98259 0.02222 11.653464 400.5832 5428.9 5475.0 115.213 61.41 73.97 0.00068 -0.0375 1227
260.000 25.69242 0.02161 11.187015 386.3424 6166.3 6213.0 118.141 62.45 75.21 0.00139 -0.0366 1205
270.000 25.40317 0.02104 10.748932 371.8248 6918.9 6966.1 121.006 63.61 76.61 0.00269 -0.0356 1182
280.000 25.11394 0.02052 10.335810 356.9831 7688.9 7736.7 123.820 64.87 78.15 0.00495 -0.0345 1158
290.000 24.82378 0.02005 9.944615 341. 7871 8478.3 8526.6 126.589 66.19 79.81 0.00871 -0.0333 1134
300.000 24.53167 0.01961 9.572604 326.2219 9288.0 9336.9 129.321 67.56 81.56 0.01470 -0.0320 1108
310.000 24.23652 0.01921 9.217277 310.2873 10118.7 10168.2 132.022 68.95 83.40 0.02391 -0.0307 1082
320.000 23.93714 0.0188'1 8.876305 293.9952 10970.4 11020.5 134.698 70.34 RA:i.11 0.01757 -0.0292 1054
330.000 23.63222 0.01851 8.547490 277 .3684 11842.7 11893.5 137.351 71.72 87.29 0.05720 -0.0276 1026
340.000 23.32030 0.01820 8.228714 260.4384 12735.1 12786.5 139.987 73.08 89.34 0.08458 -0.0259 996
350.000 22.99973 0.01793 7.917889 243.2435 13646.9 13699.0 142.608 74.42 91.47 0.12169 -0.0240 965
360.000 22.66860 0.01769 7.612908 225.8267 14577.4 14630.3 145.217 75.71 93.69 0~17067 -0.0219 933
370.000 22.32470 0.01747 7.311570 208.2323 15526.3 15580.1 1117.819 76.97 96.03 0.2337? -0.01<)" <)00
380.000 21. 96538 0.01729 7.011532 190.5055 16493.7 16548.4 150.416 78.19 98.51 0.31298 -0.0168 865
390.000 21.58740 0.01714 6.710164 172.6875 17480.5 17536.1 153.011 79.35 101.17 0.41050 -0.0136 828
400.000 21.18671 0.01703 6.404420 154.8134 18488.7 18545.3 155.610 80.46 104.07 0.52815 -0.0099 790
410.000 20.75801 0.01696 6.090586 136.9079 19521.7 19579.5 158.219 81.51 107.29 0.66764 -0.0054 749
417.033 20.43600 0.01693 5.862507 1211.3020 20265.9 20324.6 160.064 8?. '-1 10Q.R'- 0.77<)74 -0.0017 719
417.033 0.42869 0.80730 0.070743 20.5263 45687.4 48486.6 227.593 91.03 146.36 0.77974 3.7500 320
420.000 0.41908 0.81998 0.066105 21.6873 46044.0 48907.4 228.388 86.63 134.82 0.80627 3.6368 324
430.000 0'.39329 0.85343 0.054923 24.9172 47066.5 50117.7 231.240 76.31 109.97 0.82466 3.2601 334
440.000 0.37379 0.87755 0.047687 27.4750 47931.8 51142.2 233.598 70.06 96.13 0.83966 2.9031 342
450.000 0.35802 0.89583 0.042582 29.6208 48705.5 52057.3 235.657 66.02 87.51 0.85215 2.5756 350
460.000 0.34473 0.91014 0.038772 31.4886 49420.9 52901.9 237.515 63.31 81.79 0.86269 2.2806 356
470.000 0.33321 0.92157 0.035812 33.1572 50097.6 53698.9 239.230 61.48 77 .85 0.87170 2.0178 361
480.000 0.32301 0.93086 0.033439 34.6767 50747.7 54462.7 240.839 60.24 75.07 0.87947 1.7854 367
490.000 0.31384 0.93850 0.031490 36.0812 51379.5 55203.0 242.366 59.42 73.10 0.88623 1.5806 372
500.000 0.30550 0.94485 0.029857 37.3948 51998.5 55926.4 243.829 58.92 71.69 0.89212 1.4005 376
510.000 0.29783 0.95017 0.028465 38.6353 52609.0 56638.1 245.239 58.65 70.70 0.89735 1.2424 381
515.000 0.29422 0.95251 0.027843 39.2324 52912.1 56990.7 245.927 58.58 70.34 0.89974 1.1707 383
520.000 0.29073 0.95466 0.027263 39.8159 53214.1 57341.6 246.605 58.55 70.03 0.90199 1.1035 385
530.000 0.28411 0.95846 0.026211 40.9470 53816.0 58039.6 247.935 58.59 69.61 0.90614 0.9815 389
540.000 0.27791 0.96171 0.025280 42.0367 54416.5 58734.4 249.234 58.74 69.37 0.90987 0.8742 393
560.000 0.26655 0.96689 0.023701 44.1163 55618.4 60120.4 251.755 59.27 69.31 0.91628 0.6967 401
580.000 0.25634 0.97075 0.022403 46.0934 56828.0 61509.3 254.192 60.03 69.64 0.92161 0.5586 408
600.000 0.24705 0.97367 0.021307 47.9941 58050.3 62907.6 256.562 60.92 70.22 0.92612 0.4507 415
620.000 0.23853 0.97590 0.020362 49.8371 59288.6 64319.3 258.877 61.91 70.97 0.93000 0.3661 422
640.000 0.23067 0.97762 0.019534 51.6357 60545.1 65747.3 261.144 62.95 71.84 0.93338 0.2994 428
660.000 0.22337 0.97896 0.018798 53.4000 61821.3 67193.4 263.369 64.03 72.78 0.93636 0.2468 435
680.000 0.21657 0.98003 0.018136 55.1373 63118.1 68659.0 265.557 65.13 73.78 0.93903 0.2051 441
700.000 0.21020 0.98087 0.017534 56.8535 64436.0 70144.8 267.710 66.24 74.80 0.94145 0.1721 447
720.000 0.201122 0.98156 0.016983 58.5529 65775.2 71651.3 269.&32 67.34 75.85 0.94365 O.14"Q 4"1
740.000 0.19859 0.98212 0.016475 60.2391 67136.0 73178.7 271.924 68.44 76.89 0.94567 0.1252 459
760.000 0.19327 0.98258 0.016003 61. 9148 68518.1 74727.1 273.989 69.53 77.94 0.94755 0.1089 465
780.000 0.18824 0.98297 0.015564 63.5821 69921.6 76296.4 276.027 70.60 78.99 0.94929 0.0961 471
800.000 0.18347 0.98331 0.015152 65.2429 71346.1 77886.6 278.039 71.66 80.03 0.95093 0.0861 476

J. Phys. Chern. Ref. Data, VoJ.16, No.4, 1987

868 ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

T p Z aPlaT 3PI3p E H S Cv Cp j/P IJ. W

K molll bar/K bar/(mol/l) Jlmol J/mo! J/(mol·K) Jl(mol·K) J/(mol·K) K/bar m/s

15.00000 bar
175.590 28.25564 0.03636 16.551170 509.2255 -10.7 42.4 89.925 59.35 71.18 0.00000
180.000 28.11.300 0.03565 16.16358.5 502.1358 332.6 38.5.9 91.689 59.20 71.0.5 0.00000 -0.0397 1371
190.000 27.79447 0.03416 15.345052 486.7059 1091.5 1145.5 95.522 58.97 70.87 0.00000 -0.0398 1351
200.000 27.48220 0.03282 14.600377 471.9618 1829.4 1884.0 99.151 58.88 70.85 0.00000 -0.0398 1331
210.000 27.17552 0.03161 13.919285 457.6798 2553.0 2608.2 102.609 58.99 71.03 0.00001 -0.0396 1311
220.000 26.87371 0.03051 13.293265 443.6719 3268.9 3324.7 105.921 59.30 71.43 0.00004 -0.0393 1291
230.000 26.57604 0.02951 12.715192 429.7806 3982.9 4039.3 109.112 59.81 72.06 0.00010 -0.0388 1271
240.000 26.28175 0.02860 12.179038 415.8749 4700.2 4757.3 112.200 60.52 72.91 0.00025 -0.0382 1250
250.000 25.99006 0.02777 11.679641 401.8465 5425.6 5483.3 115.200 61.40 73.96 0.00054 -0.0375 1229
260.000 25.70017 0.02700 11.212575 387.6103 6162.9 6221.3 118.128 62.43 75.20 0.00112 -0.0366 1207
270.000 25.41123 0.02629 10.773962 373.1000 6915.3 6974.3 120.993 63.59 76.60 0.00216 -0.0356 1184
280.000 25.12233 0.02565 10.360394 358.2678 7685.1 7744.8 123.806 64.85 78.14 0.00398 -0.0345 1160
290.000 24.83254 0.02505 9.968833 343.0832 8474.2 8534.6 126.575 66.18 79.80 0.00700 -0.0333 1136
300.000 24.54085 0.02450 9.596541 327.5311 9283.6 9344.8 129.307 67.54 81.55 0.01182 -0.0321 1110
310.000 24.24617 0.02400 9.241017 311.6108 10114.0 10175.9 132.007 68.93 83.38 0.01922 -0.0307 1084
320.000 23.94733 0.02354 8.899940 295.3342 10965.3 11028.0 134.682 70.32 85.29 0.03020 -0.0292 1057
JJU.UUO 23.643U1 0.02312 8.571117 278.7239 11837.3 11900.7 137.335 71.70 87.26 0.04597 -0.0277 1028
340.000 23.33179 0.02274 8.252441 261. 8113 12729.2 12793.5 139.969 73.06 89.31 0.06797 -0.0259 999
350.000 23.01202 0.02240 7.941839 244.6349 13640.4 13705.6 142.589 74.39 91.43 0.09779 -0.0241 968
360.000 22.68184 0.02209 7.637224 227.2377 14570.4 14636.5 145.198 15.68 93.64 0.13714 -0.0220 936
370.000 22.33905 0.02183 7.336423 209.6646 15518.5 15585.7 147.798 76.94 95.91 0.18779 -0.0196 903
380.000 21.98106 0.02160 1.037127 191. 9611 16485.1 16553.3 150.393 78.15 98.44 0.25147 -0.0169 868
390.000 21.60470 0.02141 6.736164 174.1695 17470.9 17540.3 152.986 19.31 101.08 0.32981 -0.0138 832
400.000 21.20599 0.02127 6.432361 156.3261 18417.7 18548.5 155.583 80.41 103.96 0.42432 -0.0102 794
410.000 20.77980 0.02118 6.120323 138.4578 19509.1 19581.3 158.188 81.45 107.14 0.53638 -0.0057 753
420.000 20.31924 0.02114 5.796058 120.5764 20570.4 20644.2 160.811 82.43 110.77 0.66735 -0.0003 711
426.307 20.00682 0.02115 5.582525 109.2816 21258.1 21333.1 162.480 83.02 113.39 0.76031 0.0039 682

426.307 0.54169 0.78124 0.095091 19.0671 45547.9 48317.0 225.175 98.77 167.61 0.76031 3.2202 317
430.000 0.52482 0.19943 0.086808 20.6817 46038.1 48896.3 226.860 92.50 149.38 0.79390 3.1111 322
440.000 0.48984 0.83704 0.011360 24.2089 47161.2 50223.5 229.916 80.91 119.48 0.81376 2.8154 334
450.000 0.46400 0.86402 0.061494 26.9783 48096.8 51329.6 232.404 73.87 103.17 0.82995 2.5289 342
460.000 0.44343 0.88445 0.054586 29.2883 48924.5 52307.2 234.550 69.28 93.08 0.84385 2.2615 350
470.000 0.42629 0.90044 0.049458 31.2897 49683.6 53202.4 236.477 66.17 86.38 0.85521 2.0169 357
480.000 0.41156 0.91324 0.045490 33.0700 50397.0 54041.6 238.245 64.01 81.15 0.86491 1.7963 363
490.000 0.39861 0.92365 0.042323 34.6849 51078.7 54841.1 239.896 62.52 18.45 0.87328 1.5988 368
500.000 0.38704 0.93224 0.039731 36.1119 51138.0 55613.5 241.456 61.50 76.07 0.88052 1.4230 373
510.000 0.37657 0.93939 0.037568 37.5576 52381.7 56365.1 242.945 60.83 74.34 0.88689 1.2671 378
515.000 0.37167 0.94251 0.036613 38.2188 52699.2 56735.1 243.667 60.59 73.66 0.88979 1.1959 380
520.000 0.36698 0.94539 0.035731 38.8616 53014.5 57101.9 244.377 60.41 73.09 0.89251 1.1289 383
530.000 0.35813 0.95046 0.034149 40.0986 53639.8 57828.1 245.760 60.19 72.20 0.89748 1.0067 387
540.000 0.34991 0.95477 0.032770 41. 2800 54260.2 58546.9 247.104 60.12 71.59 0.90192 0.8986 391
560.000 0.33501 0.96162 0.030474 43.5097 55494.1 59971.5 249.695 60.33 70.98 0.90948 0.7182 399
580.000 0.32176 0.96671 0.028627 45.6034 56727.9 61389.7 252.184 60.85 70.91 0.91567 0.5765 407
600.000 0.30981 0.97053 0.027097 47.5963 57968.8 62810.5 254.593 61.57 71.21 0.92083 0.4650 414
620.000 0.29892 0.97344 0.025801 49.5129 59221. 8 64239.9 256.936 62.42 71.75 0.92521 0.3768 421
640.000 0.28892 0.97567 0.024680 51.3108 60490.0 65681.8 259.225 63.37 72.46 0.92897 0.3068 428
660.000 0.27966 0.97740 0.023695 53.1830 61775.5 67139.0 261.468 64.37 73.28 0.93226 0.2511 434
680.000 0.27106 0.97876 0.022818 54.9593 63079.7 68613.4 263.668 65.41 74.17 0.93517 0.2067 441
700.000 0.26303 0.97982 0.022029 56.7072 64403.6 70106.3 265.832 66.46 75.12 0.93777 0.1712 447
720.000 0.25551 0.98067 0.021312 58.4324 65747.8 71618.5 267.962 67.53 76.10 0.94012 0.1428 453
740.000 0.24M3 0.98135 0.020654 60.1395 67112.5 73150.5 270.061 6S.59 77.10 0.94227 0.1202 459
760.000 0.24175 0.98190 0.020048 61.8320 68497.9 74702.5 272 .130 69.66 78.11 0.94424 0.1021 465
780.000 0.23545 0.98236 0.019485 63.5128 69903.9 76274:8 274.172 70.71 79.12 0.94607 0.0877 470
800.000 0.22947 0.98273 0.018960 65.1842 71330.5 77861.3 276.187 71.75 80.13 0.94777 0.0763 476

J. Phys. Chern. Ref. Data, VoL is, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 869

Table 17. Properties of methanol along isobars - Continued

T p Z aPlaT aPlap E H S Cu Cp flP J.I. W

K molll bar/K bar/(molll) llmol J/mol J/(mol·K) J!(mo!·K) J!(mol·K) K/bar m/s
20.00000 bar
175.590 28.26544 0.04847 16.607837 511.4623 -14.3 56.5 89.904 59.32 71.18 0.00000 -0.0397 1383
180.000 28.12294 0.04752 16.219047 504.3500 328.9 400.0 91.669 59.18 71.05 0.00000 -0.0397 1374
190.000 27.80472 0.04553 15.398029 488.8771 1087.7 1159.6 95.502 58.94 70.86 0.00000 -0.0398 1354
200.000 27.49277 0.04375 14.651167 474.1000 1825.3 1898.1 99.131 58.86 70.84 0.00000 -0.0398 1334
210.000 27.18642 0.04213 13.968146 459.7938 2548.7 2622.3 102.588 58.97 71.02 0.00001 -0.0396 1314
220.000 26.88495 0.04067 13.340419 445.7697 3264.3 3338.7 105.901 59.27 71.43 0.00003 -0.0393 1294
230.000 26.58764 0.03934 12.760836 431. 8693 3978.1 4053.3 109.091 59.79 72.05 0.00008 -0.0389 1274
240.000 26.29374 0.03812 12.223349 417.9607 4695.2 4771.3 112.179 60.49 72.90 0.00019 -0.0382 1253
250.000 26.00247 0.03700 11. 722781 403.9351 5420.3 5497.2 115.179 61.37 73.95 0.00041 -0.0375 1232
260.000 25.71304 0.03598 11.254694 389.7067 6157.3 6235.0 118.106 62.41 75.19 0.00084 -0.0366 1210
270.000 25.42459 0.03504 10.815201 375.2083 6909.3 6987.9 120.970 63.57 76.59 0.00164 -0.0356 1187
280.000 25.13625 0.03418 10.400889 360.3919 7678.7 7758.3 123.783 64.82 78.13 0.00301 -0.0346 1164
290.000 24.84707 0.03338 10.008720 345.2261 8467.4 8547.9 126.551 66.15 79.78 0.00530 -0.0334 1139
300.000 24.55607 0.03265 9.635954 329.6956 9276.4 9357.9 129.282 67.51 81.52 0.00894 -0.0321 1114
310.000 24.26216 0.03198 9.280096 313.7991 10106.3 10188.7 131.982 68.90 83.35 0.01453 -0.0308 1088
320.000 23.96419 0.03137 8.938831 297.5481 10957.0 11040.5 134.656 70.29 85.25 0.02283 -0.0293 1061
330.000 23.66088 0.03081 8.609980 280.9650 11828.3 11912.8 137.307 71.66 87.22 0.03475 -0 ..0277 1033
340.000 23.35081 0.03030 8.291451 264.0811 12719.4 12805.1 139.940 73.02 89.25 0.05136 -0.0260 1003
350.000 23.03237 0.02984 7.981195 246.9350 13629.8 13716.7 142.559 74.35 91.37 0.07389 -0.0242 973
360.000 22.70373 0.02943 7.677155 229.5699 14558.7 14646.8 145.165 75.64 93.57 0.10362 -0.0221 941
370.000 22.36277 0.02907 7.377202 212 .0313 15505.7 15595.1 147.763 76.89 95.88 0.14187 -0.0198 908
380.000 22.00695 0.02876 7.079085 194.3657 16470.8 16561.7 150.355 78.09 98.32 0.18996 -0.0172 873
390.000 21.63321 0.02851 6.780314 176.6165 17454.9 17547.3 152.945 79.24 100.93 0.24913 -0.0141 837
400.000 21.23772 0.02832 6.478037 158.8223 18459.7 18553.8 155.537 80.33 103.77 0.32050 -0.0105 800
410.000 20.81559 0.02819 6.168838 141.0129 19488.4 19584.5 158.137 81. 36 106.89 0.40513 -0.0062 760
420.000 20.36026 0.02813 5.848408 123.2050 20546.3 20644.5 160.753 82.31 110.44 0.50404 -0.0009 718
430.000 19.86258 0.02816 5.510974 105.3952 21641.3 21742.0 163.397 83.21 114.61 0.61833 0.0058 673
438.942 19.37067 0.02829 5.188105 89.4391 22661.5 22764.7 165.799 83.98 119.19 0.73461 0.0136 629
438.942 0.73886 0.74169 0.139578 16.8273 45280.8 47987.7 223;262 109.80 202.89 0.73461 2.6201 311
440.000 0.73037 0.74851 0.135316 17.3952 45442.2 48180.6 223.363 107.48 194.31 0.76787 2.5975 313
450.000 0.66914 0.79885 0.106840 21. 7755 46846.3 49835.2 227.086 91.09 143.77 0.79145 2.3903 327
460.000 0.62737 0.83351 0.089895 25.0709 47950.3 51138.2 229.946 81.55 119.22 0.81116 2.1779 338
470.000 0.59561 0.85928 0.078479 27.7562 48894.8 52252.7 232.345 75.42 104.82 0.82687 1.9721 346
480.000 0.56995 0.87926 0.070212 30.0464 49742.0 53251.1 234.449 71.25 95.50 0.84009 1.7785 354
490.000 0.54839 0.89518 0.063930 32.0595 50525.2 54172.2 236.349 68.34 89.11 0.85137 1.5999 361
500.000 0.52977 0.90811 0.058987 33.8677 51264.0 55039.3 238.102 66.27 84.57 0.86103 1.4370 367
510.000 0.51336 0.91876 0.054989 35.5188 51971.8 55867.8 239.736 64.80 81.27 0.87025 1.2896 372
515.000 0.50582 0.92340 0.053263 36.2962 52316.8 56270.8 240.522 64.23 79.96 0.87404 1. 2215 375
520.000 0.49867 0.92764 0.051686 37.0461 52657.0 56667.7 241.290 63.76 78.84 0.87758 1.1570 378
530.000 0.48536 0.93509 0.048907 38.4736 53325.9 57446.6 242.774 63.04 77 .03 0.88401 1.0381 383
540.000 0.47318 0.94141 0.046534 39.8193 53983.1 58209.8 244.202 62.58 75.69 0.88970 0.9316 387
560.000 0.45149 0.95140 0.042686 42.3182 55275.3 59705.1 246.922 62.19 74.02 0.89927 0.7515 396
580.000 0.43256 0.95878 0.039686 44.6220 56552.7 61176.3 249.504 62.28 73.22 0.90697 0.6078 404
600.000 0.41574 0.96433 0.037266 46.7821 57827.1 62637.9 251.982 62.70 73.00 0.91328 0.4931 412
620.000 0.40057 0.96854 0.035262 48.8340 59106.2 64099.0 254.378 63.33 73.16 0.91853 0.4013 419
640.000 0.38677 0.97178 0.033563 50.8026 60395.0 65566.1 256.707 64.09 73.58 0.92298 0.3276 426
660.000 0.37408 0.97428 0.032097 52.7060 61697.1 67043.5 258.980 64.96 74.18 0.92679 0.2683 433
680.000 0.36236 0.97622 0.030812 54.5579 63014.6 68534.1 261.205 65.89 74.90 0.93011 0.2204 439
700.000 0.35145 0.97775 0.029670 56.3687 64349.4 70040.0 263.388 66.86 75.71 0.93303 0.1817 446
720.000 0.34127 0.97895 0.028644 58.1465 65702.4 71562.8 265.532 67.85 76.58 0.93564 0.1504 452
740.000 0.33172 0.97991 0.027713 59.8975 67074.3 73103.4 267.643 68.86 77 .49 0.93799 0.1250 458
760.000 0.32274 0.98067 0.026862 61.6267 68465.6 74662.4 269.722 69.88 78.42 0.94013 0.1044 464
780.000 0.31427 0.98128 0.026078 63.3382 69876.4 76240.4 271.771 70.89 79.37 0.94209 0.0877 470
800.000 0~30626 0.98178 0.025352 65.0351 71307.0 77837.4 273.792 71.90 80.33 0.94390 0.0742 476

J. PhY5!;. Chem. Ref. Data, Vol. 16, No.4, 1987

II : j I
HOUI.::rn O. GOODWIN

i.II,1<: Ii. Properties of' methanol along isobars - Continued

I' Z aPlaT oPlup E H S Cv Cp j!P J1. W

K m01l1 bar/K bar/(molll) J/mol J/mol Jl(mol·K) J/(mol·K) J/(mol·K) K/bar m/s
25.00000 bar
175.590 28.27519 0.06056 16.663768 513.6781 -17.8 70.6 89.884 59.30 71.18 0.00000 -0.0397 1387
180.000 28.13283 0.05938 16.273788 506.5434 325.3 414.2 91.649 59.16 71.05 0.00000 -0.0397 1377
190.000 27.81492 0.05689 15.450315 491.0276 1083.8 1173.7 95.481 58.92 70.86 0.00000 -0.0398 1357
200.000 27.50330 0.05466 14.7012n 476.2176 1821.3 1912.2 99.110 58.84 70.84 0.00000 -0.0398 1337
210.000 27.19727 0.05265 14.016362 461. 8873 2544.4 2636.4 102.567 58.95 71.02 0.00001 -0.0396 1317
220.000 26.89614 0.05081 13.386947 447.8471 3259.8 3352.8 105.880 59.25 71.42 0.00002 -0.0393 1297
230.000 26.59919 0.04915 12.805869 433.9375 3973.3 4067.3 109.070 59.76 72.05 0.00006 -0.0389 1277
240.000 26.30568 0.04763 12.267061 420.0260 4690.2 4785.2 112.157 60.47 72.89 0.00015 -0.0383 1257
250.000 26.01482 0.04623 11.765333 406.0032 5415.0 5511.1 115.158 61.35 73.95 0.00033 -0.0375 1235
260.000 25.72583 0.04495 11. 296230 391.7824 6151.6 6248.8 118.084 62.38 75.18 0.00068 -0.0366 1213
270.000 25.43788 0.04378 10.855862 377.2960 6903.3 7001.6 120.948 63.54 76.58 0.00132 -0.0357 1191
280.000 25.15008 0.04270 10.440808 362.4952 7672 .4 7771.8 123.760 64.80 78.11 0.00243 -0.0346 1167
290.000 24.86151 0.04170 10.048028 347.3482 8460.7 8561.2 126.528 66.12 79.76 0.00427 -0.0334 1143
300.000 24.57118 0.04079 9.674784 331.8390 9269.2 9371.0 129.258 67.48 81.50 0.00721 -0.0322 1118
310.000 24.27804 0.03995 9.318584 315.9661 10098.5 10201.5 131.957 68.87 83.32 0.01172 -0.0308 1092
320.000 23.98094 0.03918 8.977119 299.7404 10948.7 11053.0 134.629 70.26 85.22 0.01840 -0.0294 1065
.'BO.OOO 1.'LI\7Rfi1 0.03&4& &.64&222 283.1842 11819.3 11924.9 137.280 71.63 87.17 0.02801 -0.0278 1037
340.000 23.36966 0.03784 8.329817 266.3287 12709.8 12816.7 139.912 72.98 89.20 0.04140 -0.0261 1007
350.000 23.05252 0.03727 8.019875 249.2123 13619.3 13727.7 142.528 74.30 91.30 0.05955 -0.0243 977
360.000 22.72540 0.03675 7.716369 231. 8786 14547.2 14657.2 145.133 75.59 93.49 0.08350 -0.0223 946
370.000 22.38622 0.03630 7.417210 214.3735 15493.0 15604.7 147.728 76.83 95.78 0.11432 -0.0200 913
380.000 22.03252 0.03591 7.120:102 196.7;1,H 16t156.7 16570.2 150.318 78.03 98.20 0.15307 0.0174 879
390.000 21.66132 0.03559 6.822929 179.0359 17439.1 17554.5 152.904 79.18 100.79 0.20073 -0.0144 843
400.000 21.26896 0.03534 6.522651 161.2884 18441.8 18559.4 155.492 80.26 103.58 0.25822 -0.0109 806
410.000 20.85073 0.03517 6.216112 143.5345 19468.0 19587.9 158.087 81.27 106.65 0.32640 -0.0067 766
420.000 20.40042 0.03509 5.899258 125.7951 20522.7 20645.2 160.697 82.20 110.12 0.40608 -0.0015 725
430.000 19.909;12 0.03512 5.566732 108.0735 21613.3 21738.9 163.331 83.07 114.17 0.4')815 0.0049 680
440.000 19.36511 0.03529 5.210945 90.3449 22751.4 22880.5 166.008 83.90 119.16 0.60369 0.0135 632
449.304 18.79329 0.03561 4.848795 73.7798 23868.0 24001.0 168.560 84.72 125.26 0.71519 0.0243 583

449.304 0.94865 0.70544 0.188012 14.8153 44993.3 47628.6 221.147 119.02 238.14 0.71519 2.2179 304
450.000 0.94004 0.71079 0.183804 15.2369 45107.5 47767.0 221.081 117.28 230.19 0.75010 2.2065 305
460.000 0.84887 0.77002 0.141971 20.1237 46727.3 49672.4 225.267 97.90 161.84 0.77653 2.0549 322
470.000 0.78992 0.80988 0.118048 23.7318 47956.1 51120.9 228.383 86.88 131.11 0.79739 1.8921 334
480.000 0.74636 0.83930 0.102216 26.6491 48987.7 52337.3 230.947 79.82 113.60 0.81452 1.7299 344
490.000 0.71183 0.86205 0.090872 29.1257 49901.6 53413.7 233.168 75.01 102.43 0.82896 1.5741 352
500.000 0.68322 0.88019 0.082313 31.2949 50738.3 54397.4 235.156 71.62 94.81 0.84124 1.4279 359
510.000 0.65878 0.89494 0.075613 33.2375 51522.2 55317.1 236.967 69.17 89.38 0.85304 1.2926 366
515.000 0.64777 0.90131 0.072778 34.1410 51899.2 55758.6 237.829 68.21 87.26 0.85777 1.2292 369
520.000 0.63743 0.90712 0.070218 35.0062 52268.2 56190.2 238.663 67.40 85.43 0.86219 1.1686 372
530.000 0.61847 0.91730 0.065778 36.6378 52986.7 57029.0 240.262 66.12 82.48 0.87019 1.0557 377
540.000 0.60139 0.92588 0.062056 38.1587 53685.2 57842.2 241.783 65.20 80.27 0.87722 0.9534 382
560.000 0.57156 0.93940 0.056156 40.9430 55041.6 59415.6 244.645 64.14 77 .35 0.88894 0.7777 392
580.000 0.54605 0.94939 0.051676 43.4698 56366.4 60944.8 247.329 63.79 75.74 .0.89825 0.6352 401
600.000 0.52371 0.95688 0.048142 45.8087 57676.8 62450.4 249.882 63.87 74.94 0.90579 0.5198 409
620.000 0.50382 0.96259 0.045269 48.0064 58983.9 63946.0 252.335 64.26 74.69 0.91200 0.4264 417
640.000 0.48586 0.96698 0.042875 50.0957 60294.8 65440.3 254.707 64.85 74.79 0.91717 0.3506 424
660.000 0.46948 0.97038 0.040839 52.1001 61614.4 66939.5 257.014 65.57 75.15 0.92156 0.2890 431
680.000 0.45443 0.97304 0.039077 54.0371 62946.2 68447.7 259.265 66.39 75.69 0.92533 0.2387 438
700.000 0.44050 0.97513 0.037529 55.9200 64292.6 69968.0 261.469 67.27 76.35 0.92860 0.1977 445
720.000 0.42754 0.97678 0.036152 57.7592 65655.0 71502.5 263.630 68.19 77.11 0.93149 0.1641 451
740.000 0.41542 0.97809 0.034')15 59.5627 67034.7 73052.7 265.754 69.15 77.92 0.93406 0.1365 457
760.000 0.40406 0.97914 0.033793 61.3369 68432.4 74619.7 267.843 70.11 78.78 0.93637 0.1139 463
780.000 0.39336 0.97998 0.032766 63.0869 69848.6 76204.1 269.901 71.09 79.67 0.93848 0.0954 469
800.000 0.38326 0.98066 0.031821 64.8169 71283.6 77806.5 271. 929 72.06 80.57 0.94040 0.0801 475

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 871

Table 17. Properties of methanol along isobars - Continued

T p Z oP/oT oP/op E H S Cv Cp flP J1. W

K moll! barlK bar/Cmolll) llmoi llmol J/(mo!'K) 11(mol·K) J/(mol·K) K/bar m/s
30.00000 bar
175.590 28.28491 0.07265 16.718990 515. -21.3 84.7
180.000 28 14268 o 07123 16.327834 508.7165 321.7 428.3 91.628 59.14 71.05 0.00000 -0.0397 1381
190.000 27.82508 0.06825 15.501934 493.1580 1080.0 1187.8 95.461 58.90 70.86 0.00000 -0.0398 1360
200.000 27.51377 0.06557 14.750774 478.3153 1817.2 1926.3 99.090 58.82 70.84 0.00000 -0.0398 1340
210.000 27.20807 0.06315 14.063957 463.9611 2540.2 2650.4 102.547 58.93 71.02 0.00001 -0.0396 1321
220.000 26.90728 0.06095 13.432870 449.9047 3255.3 3366.8 105.859 59.23 71.42 0.00002 -0.0393 1301
230.000 26.61069 0.05895 12.850312 435.9860 3968.6 4081.3 109.049 59.74 72.04 0.00005 -0.0389 1280
240.000 26.31755 0.05713 12.310196 422.0716 4685.2 4799.1 112.136 60.45 72.89 0.00013 -0.0383 1260
250.000 26.02711 0.05545 11.807315 408.0514 5409.7 5524.9 115.136 61. 33 73.94 0.00028 -0.0375 1239
260.000 25.73856 0.05392 11.337206 393.8382 6146.0 6262.6 118.062 62.36 75.17 0.00057 -0.0367 1217
270.000 25.45109 0.05251 10.895966 379.3636 6897.4 7015.2 120.926 63.52 76.56 0.00111 -0.0357 1194
280.000 25.16383 0.05121 10.480172 364.5783 7666.1 7785.3 123.737 64.77 78.09 0.00204 -0.0346 1171
290.000 24.87586 0.05002 10.086780 349.4499 8453.9 8574.5 126.504 66.09 79.74 0.00359 -0.0335 1147
300.000 24.58620 0.04892 9.713054 333.9620 9262.0 9384.1 129.234 67.46 81. 48 0.00606 -0.0322 1121
310.000 24.29381 0.04791 9.356503 318.1124 10090.9 10214.4 131.932 68.84 83.29 0.00984 -0.0309 1096
320.000 23.99756 0.04699 9.014827 301. 9119 10940.5 11065.5 134.603 70.22 85.18 0.01546 -0.0294 1069
330.000 23.69619 0.04614 8.685868 285.3823 11810.4 11937.0 137.253 71.60 57.13 0.023:52 -0.0279 1041
340.000 23.38835 0.04537 8.367564 268.5547 12700.1 12828.4 139.883 72.95 89.15 0.03477 -0.0262 1012
350.000 23.07249 0.04468 8.057907 251.4675 13608.8 13738.8 142.498 74.26 91.24 0.05000 -0.0244 981
360.000 22.74686 0.04406 7.754897 234.1645 14535.7 14667.6 145.101 75.55 93.41 0.07010 -0.0224 950
370.000 22.40942 0.04352 7.456483 216.6921 15480.4 15614.3 147.694 76.79 95.69 0.09596 -0.0201 918
350.000 22.05775 0.04305 7.160517 199.0953 16442.5 16;575.5 1;50.250 77 .95 91:1.09 0.12547 -0.0176 554
390.000 21.68907 0.04266 6.864656 181.4289 17423.5 17561. 8 152.864 79.11 100.65 0.16847 -0.0146 848
400.000 21.29973 0.04235 6.566258 16.3.7259 18424.2 18565.1 155.448 80.18 103.40 0.21671 -0.0112 811
410.000 20.88527 0.04214 6.262217 146.0244 19448.0 19591. 6 158.038 81.18 106.42 0.27392 -0.0071 772
420.000 20.43977 0.04203 5.948704 128.3491 20499.5 20646.2 160.641 82.10 109.81 0.34078 -0.0021 731
430.000 19.95513 0.04205 5.620731 110.7090 21586.0 21736.3 163.267 82.94 113.75 0.41805 0.0041 688
440.000 19.41962 0.04223 5.271359 93.0892 22718.4 22872.8 165.932 83.73 118.55 0.50663 0.Q123 641
450.000 18.81489 0.04262 4.890067 75.4341 23913.0 24072.4 168.661 84.56 124.85 0.60771 0.0234 589
458.156 18.24894 0.04316 4.543417 60.9183 24951.1 25115.5 170.963 85.41 132.03 0.70045 0.0362 542
458.156 1.17299 0.67139 0:239684 13.0043 4469.5 . .5 47253.1 219.282 126.84 273.94 0.70045 1.9291 296
460.000 1.14148 0.68716 0.225071 14.1834 45079.7 47707.9 219.886 121.49 247.58 0.73955 1.9089 300
470.000 1.02325 0.75025 0.173416 19.1947 46810.4 49742.3 224.263 101.48 171.81 0.76645 1. 7917 318
480.000 0.94828 0.79270 0.143978 22.9151 48111.4 51275.0 227.493 90.04 138.33 0.78795 1.6622 331
490.000 0.89351 0.82412 0.124488 25.9371 49197.9 52555.5 230.136 82.65 119.32 0.80582 1.5308 341
500.000 0.85046 0.84852 0.110507 28.5110 50156.2 53683.7 232.417 77 .55 107.15 0.52090 1.4021> 3;50
510.000 0.81502 0.86805 0.099947 30.7705 51031.1 54711. 9 234.440 73.95 98.88 0.83524 1.2812 358
515.000 0.79940 0.87642 0.095574 31. 8090 51445.3 55198.1 235.389 72.54 95.68 0.84099 1.2233 361
520.000 0.78492 0.88401 0.091672 32.7968 51847.4 55669.5 236.300 71.32 92.95 0.84634 1.1674 365
530.000 0.75875 0.89725 0.085006 34.6433 52622.2 56576.1 238.029 69.39 88.59 0.85598 1.0621 371
540.000 0.73559 0.90835 0.079516 36.3471 53366.6 57444.9 239.653 67.97 85.33 0.86442 0.9654 377
560.000 0.69597 0.92578 0.070996 39.4277 54793.4 59.104.0 242.672 66.19 80.97 0.87841 0.7966 387
580.000 0.66278 0.93861 0.064676 42.1854 56169.2 60695.6 245.466 65.34 78.43 0.88944 0.6572 397
600.000 0.63417 0.94826 0.059785 44.7099 57517.9 62248.5 248.099 65.08 77 .01 0.89829 0.5429 406
620.000 0.60899 0.95562 0.055873 47.0600 58854.5 63780.7 250.612 65.22 76.31 0.90551 0.4492 414
640.000 0.58647 0.96130 0.052658 49.276J 60188.6 65303.9 2.:53.030 6.5.61 70.015 0.91147 0.3724 422
660.000 0.56610 0.96572 0.049958 51.3879 61526.8 66826.2 255.373 66.19 76.19 0.91648 0.3094 429
680.000 0.54748 0.96919 0.047647 53.4163 62873.6 68353.2 257.652 66.90 76.54 0.92073 0.2575 436
700.000 0.53034 0.97193 0.045637 55.3777 64232.1 69888.9 259.878 67.69 77 .05 0.92439 0.2148 443
720.000 0.51445 0.97411 0.043866 57.2845 65604.6 71436.0 262.057 68.54 77.68 0.92759 0.1795 450
740.000 0.49%5 0.97585 0.042287 59.1465 GG992.5 72996.7 264.193 69.44 n.40 0.93040 o. 1~03 4~6
760.000 0.48581 0.97724 0.040864 60.9716 68397.1 74572.3 266.296 70.36 79.17 0·.93291 0.1260 462
780.000 0.47281 0.97837 0.039571 62.7659 69819.0 76164.0 268.363 71.29 80.00 0.93517 0.1059. 468
800.000 0;46057 0.97927 0.038388 64.5346 71258.6 77772.4 270.399 72.23 80.85 0.93722 0.0893 474

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

872 ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

T p Z JPlaT JPIJp E H S Cv Cp j!P J1. W

K molll bar/K bar/(molll) J/mol J/mol J/(mol·K) J/(mol·K) J/(mol·K) K/bar mls

40.00000 bar
175.590 28.30421 0.09680 16.827399 520.2067 -28.4 113.0 89.823 59.25 71.18 0.00000 -0.0397 1396
180.000 28.16225 0.09490 16.433930 513.0051 314.5 456.5 91.588 59.10 71.05 0.00000 -0.0397 1387
190.000 27.84527 0.09093 15.603259 497.3618 1072.4 1216.1 95.420 58.86 70.86 0.00000 -0.0398 1366
200.000 27.53459 0.08736 14.847897 482.4538 1809.2 1954.5 99.049 58.78 70.84 0.00000 -0.0398 1347
210.000 27.22953 0.08413 14.157363 468.0519 2531.7 2678.6 102.506 58.89 71.01 0.00001 -0.0397 1327
220.000 26.92941 0.08120 13.522985 453.9633 3246.4 3394.9 105.818 59.19 71.41 0.00002 -0.0393 1307
230.000 26.63352 0.07854 12.937510 440.0262 3959.1 4109.3 109.008 59.70 72.03 0.00004 -0.0389 1287
.l4U.UUU 26.34113 U.U761U n.39481U 426.1U:>9 401:>.2 48:l"/. U 1 L!.U94 OU.4U 72.'lS7 0.00010 -O.OJ'lSJ lZ66
250.000 26.05149 0.07387 11.889653 412.0910 5399.2 5552.7 115.094 61.28 73.92 0.00021 -0.0376 1245
260.000 25.76382 0.01182 11.411548 397.8926 6134.9 6290.2 118.019 62.32 75.15 0.00044 -0.0361 1223
270.000 25.47731 0.06994 10.974579 383.4414 6885.6 7042.6 120.882 63.47 76.54 0.00085 -0.0357 1201
280.000 25.19111 0.06821 10.557309 368.6868 7653.6 7812.3 123.692 64.72 78.06 0.00156 -0.0347 1178
290.000 24.90431 0.06661 10.162692 353.5953 8440.6 8601.2 126.458 66.04 79.70 0.00274 -0.0335 1154
300.000 24.61596 0.06515 9.787990 338.1494 9247.8 9410.3 129.186 67.40 81.43 0.00462 -0.0323 1129
310.000 24.32504 0.06380 9.430718 322.3460 10075.7 10240.1 131. 882 68.78 83.24 0.00750 -0.0310 1103
320.000 24.03044 0.06256 9.088588 306.1951 10924.2 11090.6 134.552 70.16 85.11 0.01178 -0.0296 1076
330.000 23.73097 0.06143 8.759459 289.7179 11792.9 11961.4 137.199 71.53 87.05 0.01792 -0.0281 1048
340.000 23.42529 0.06040 8.441297 272.9451 12681.1 12851.9 139.826 72.88 89.05 0.02647 -0.0264 1020
350.000 23.11191 0.05947 8.132130 255.9150 13588.1 13761.2 142.438 74.19 91.12 0.03806 -0.0246 990
360.000 22.78916 0.05864 7.830007 238.6716 14513.1 14688.6 145.037 75.46 93.27 0.05335 -0.0227 959
370.000 22.45508 0.05790 7.532945 221.2621 15455.5 15633.7 147.626 76.69 95.51 0.07302 -0.0205 927
380.000 22.10743 0.05727 7.238886 203.7356 16415.3 16596.2 150.207 77 .87 97.87 0.09775 -0.0180 893
390.000 21.74348 0.05673 6.945613 186.1400 17392.8 17576.8 152.784 78.99 100.37 0.12816 -0.0152 859
400.000 21.35993 0.05631 6.650660 168.5200 18389.7 18577.0 155.360 80.05 103.06 0.16484 -0.0119 822
410.000 20.95262 0.05600 6.351178 150.9151 19408.7 19599.6 157.941 81.02 105.98 0.20834 -0.0079 784
420.000 20.51619 0.05583 6.043727 133.3561 20454.2 20649.2 160.531 81.90 109.23 0.25918 -0.0032 745
430.000 20.04341 0.05582 5.723937 115.8619 21532.9 21732.5 163.142 82.70 112.96 0.31795 0.0026 702
440.000 19.52406 0.05600 5.385925 98.4333 22654.7 22859.6 165.785 83.42 117.44 0.38535 0.0102 657
450.000 18.94273 0.05644 5.021153 81.0429 23834.2 24045.4 168.483 84.14 123.16 0.46228 0.0202 608
460.000 18.27390 0.05723 4.615947 63.6119 25093.8 25312.7 171. 271 85.04 131.18 0.54996 0.0345 553
470.000 17.46876 0.05860 4.144906 45.9498 26472.4 26701.4 174.220 86.52 144.11 0.64988 0.0567 488
472.860 17.20025 0.05915 3.991362 40.7987 26898.1 27130.7 175.111 87.18 149.59 0.68093 0.0657 467

472.860 1.67517 0.60734 0.351805 9.8575 44075.9 46463.7 215.996 139.34 350.91 0.68093 1.5437 278
480.000 1.49059 0.67239 0.277186 14.3471 45785.7 48469.2 219.879 118.38 234.07 0.73103 1.4965 297
490.000 1.34182 0.73170 0.220566 18.9028 47473.5 50454.5 223.976 101.80 171.84 0.75701 1.4143 315
500.000 1.24392 0.77350 0.186078 22.4679 48790.5 52006.1 227.113 91.66 141.46 0.77828 1.3236 328
510.000 1.17139 0.80529 0.162406 25.4496 49908.9 53323.7 229.709 84.84 123.36 0.79758 1.2307 339
515.000 1.14120 0.81857 0.153099 26.7852 50418.6 53923.6 230.881 82.24 116.84 0.80551 1.1845 344
520.000 1.11403 0.83047 0.145016 28.0384 50903.3 54493.9 231.983 80.02 111.45 0.81286 1.1390 349
530.000 1.06671 0.85095 0.131652 30.3418 51814.6 55564.5 234.021 76.51 103.11 0.82631 1.0508 357
540.000 1.02650 0.86790 0.121042 32.4280 52667.0 56563.8 235.890 73.90 97.05 0.83775 0.9673 364
560.000 0.96071 0.89422 0.105233 36.1197 54254.1 58417.7 239.264 70.47 89.07 0.85656 0.8160 377
580.000 0.90803 0.91347 0.093999 39.3501 55742.7 60147.8 242.301 68.55 84.35 0.87125 0.6866 388
600.000 0.86409 0.92792 0.085589 42.2543 57174.6 61803.8 245.109 67.56 81.49 0.88292 0.5773 398
620.000 0.82637 0.93899 0.079041 44.9177 58574.7 63415.2 247.745 67.17 79.79 0.89312 0.4857 408
640.000 0.79329 0.94757 0.073784 47.3972 59958.4 65000.7 250.262 67.17 78.85 0.900,79 0.4091 416
660.000 0.76381 0.95432 0.069456 49.7330 61335.9 66572.8 252.682 67.46 78.43 0.90714 U.34:52 424
680.000 0.73722 0.95966 0.065819 51.9543 62714.4 68140.2 255.022 67.93 78.36 0.91247 0.2917 432
700.000 0.71299 0.96392 0.062707 54.0831 64098.8 69709.0 257.296 68.54 78.55 0.91699 0.2470 439
720.000 0.69073 0.96734 0.060004 56.1362 65492.6 71283.5 259.514 69.25 78.93 0.92087 0.2095 446
740.000 0.67015 0.97011 0.057626 58.1266 66898.2 72867.0 261.683 70.03 79.44 0.92424 0.1779 453
760.000 0.65101 0.97235 0.055511 60.0647 68317.5 74461.8 263.810 70.85 80.05 0.92720 0.1514 460
780.000 0.63313 0.97418 0.053609 61.9590 69751.7 76069.5 265.898 71. 71 80.73 0.92983 0.1290 466
800.000 0.61635 0.97567 0.051886 63.8163 71201.7 77691.5 267.951 72.58 81.47 0.93218 0.1101 472

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 873

Table 17. Froperties of methanol along· isobars - Continued

T p Z aPlaT aPlap E H S Cv Cp liP 11 W

K molll bar/K bar/(mollD llmol J/mol J/(mol'K) J/(mo!·K) J/(mol·K) K/bar m/s
50.00000 bar
89.783 .21 71.18
180.000 28.18167 0.11855 16.537512 517.2210 307.3 484.8 91. 548 59.07 71.05 ().OOOO() -0.0197 B9~
190.000 27.86530 0.11358 15.702183 501.4938 1064.9 1244.3 95.380 58.83 70.86 0.00000 -0.0398 1373
200.000 27.55523 0.10912 14.942696 486.5206 1801;2 1982.7 99.009 58.74 70.83 0.00000 -0.0398 1353
210.000 27.25080 0.10508 14.248523 472.0712 2523.3 2706.8 102.465 58.85 71.01 0.00000 -0.0397 1333
220.000 26.95134 0.10142 13.610917 457.9504 3237.5 3423.0 105.777 59.15 71.40 0.00001 -0.0394 1313
230.000 26.65614 0.09809 13.022578 443.9950 3949.8 4137.3 108.967 59.66 72.02 0.00003 -0.0389 1293
240.000 26.36449 0.09504 12.477339 430.0686 4665.3 4854.9 112 .053 60.36 72.86 0.00008 -0.0383 1272
250.000 26.07564 0.09225 11.969948 416.0590 5388.7 5580.5 115.051 61.24 73.90 0.00017 -0.0376 1251
260.000 25.78883 0.08969 11.495866 401.8748 6123.9 6317.7 117.976 62.27 75.13 0.00036 -0.0367 1230
270.000 25.50326 0.08733 11.051184 387.4467 6873.9 7069.9 120.838 63.43 76.51 0.00069 -0.0358 1207
280.000 25.21808 0.08517 10.632448 372.7223 7641.2 7839.4 123.647 64.68 78.03 0.00127 -0.0347 1184
290.000 24.93243 0.08317 10.236603 357.6673 8427.4 8628.0 126.412 65.99 79.66 0.00223 -0.0336 1160
300.000 24.64535 0.08134 9.860913 342.2628 9233.8 9436.6 129.138 67.35 81.38 0.00375 -0.0324 1136
310.000 24.35586 0.07965 9.502896 326.5050 10060.6 10265.9 131. 833 68.73 83.18 0.00610 -0.0311 1110
320.000 24.06288 0.07810 9.160273 310.4029 10908.0 11115.8 134.501 70.11 85.05 0.00957 -0.0297 1084
330.000 23.76524 0.07668 8.830921 293.9771 11775.5 11985.9 137.145 71.47 86.97 0.01455 -0.0282 1056
340.000 23.46164 0.07539 8.512828 277.2577 12662.4 12875.5 139.770 72.81 88.95 0.02150 -0.0266 1028
350.000 23.15066 0.07422 8.204055 260.2831 13567.8 13783.7 142.379 74.12 91.00 0.03091 -0.0248 998
360.000 22.83067 0.07317 7.902694 243.0972 14490.9 14709.9 144.975 75.38 93.13 0.04331 -0.0229 968
370.000 22.49983 0.07224 7.606824 225.7480 15431.1 15653.4 147.559 76.61 95.34 0.05927 -0.0208 936
380.000 22.15597 0.07143 7.3144.58 208.2849 16388.3 16614.0 1.50.13.5 77.78 97.66 0.07932 -0.0184 903
390.000 21.79654 0.07074 7.023493 190.7579 17362.8 17592.2 152.706 78.88 100.11 0.10399 -0.0156 869
400.000 21.41845 0.07019 6.731612 173.2140 18356.1 18589.5 155.275 79.92 102.73 0.13374 -0.0125 833
410.000 21.01785 0.06978 6.436183 155.6962 19370.5 19608.4 157.846 80.87 105.57 0.16902 -0.0087 796
420.000 20.58983 0.06954 6.134083 138.2403 20410.4 20653.2 160.425 81. 73 108.69 0.21026 -0.0042 757
430.000 20.12790 0.06948 5.821439 120.8727 21481.9 21730.3 163.021 82.48 112.24 0.25793 0.0013 716
440.000 19.62306 0.06965 5.493179 103.6062 22594.1 22848.9 165.645 83.15 116.43 0.31261 0.0083 672
450.000 19.06217 0.07011 5.142221 86.4334 23760.1 24022.4 168.315 83.78 121.67 0.37506 0.0174 625
460.000 18.42440 0.07095 4.757802 69.3137 24999.5 25270.9 171.062 84.53 128.79 0.44628 0.0301 574
470.000 17.67278 0.07240 4.321528 52.1423 26343.9 26626.8 173.940 85.73 139.63 0.52753 0.0488 514
480.000 16.72747 0.07490 3.795234 34.6521 27853.8 28152.8 177.066 88.21 159.52 0.62012 0.0803 442
484.902 16.13408 0.07687 3.477009 25.7501 28695.3 29005.2 178.773 90.48 177.94 0.66990 0.1065 397

484.902 2.27337 0.54552 0.477972 7.1480 43403.2 45602.6 213.001 148.78 448.65 0.66990 1.3003 259
490.000 2.02675 0.60553 0.390710 10.7973 44993.9 47460.9 216.612 130.08 298.73 0.70419 1.2798 278
500.000 1.76904 0.67987 0.301024 15.9071 47043.8 49870.2 221.485 109.75 200.76 0.73290 1.2244 301
510.000 1.61527 0.72999 0.250093 19.8016 48554.3 51649.7 224.995 97.84 159.58 0.75798 1.1591 317
515.000 1.55697 0.74998 0.231621 21.4824 49202.3 52413.7 226.487 93.53 146.58 0.76828 1.1245 324
520.000 1.50670 0.76754 0.216161 23.0334 49801.7 53120.2 227.853 89.95 136.41 0.77778 1.0893 330
530.000 1.42341 0.79713 0.191641 25.8308 50892.5 54405.2 230.300 84.38 121.57 0.79498 1.0185 340
540.000 1.35617 0.82116 0.172993 28.3167 51879.9 55566.8 232.473 80.31 111. 34 0.80962 0.9488 350
560.000 1.25181 0.85784 0.146392 32.6301 53657.6 57651.8 236.268 74.96 98.43 0.83355 0.8173 365
580.000 1.17238 0.88438 0.128272 36.3331 55274.6 59539.5 239.582 71.86 90.97 0.85213 0.7000 378
600.000 1.10842 0.90423 0.115108 39.6154 56798.9 61309.8 242.580 70.08 86.42 0.86723 0.5981 390
620.000 1.05492 0.91944 0.105096 42.5912 58268.0 63007.7 245.357 69.14 83.59 0.87977 0.5106 400
640.000 1.00896 0.93128 0.097209 45.3346 59705.0 64660·.6 247.982 68.74 81.85 0.88931 0.4361 410
660.000 0.96865 0.94063 0.090822 47.8969 61124.6 66286.4 250.484 68.72 80.84 0.89716 0.3729 419
680.000 0.93277 0.94810 0.085530 50.3150 62537.0 678.97.4 252.890 68.97 80.33 0.90369 0.3193 427
700.000 0.90041 0.95410 0.081060 52.6163 63949.0 69502.0 255.216 69.40 80.18 0.90919 0.2738 435
720.000 0.87096 0.95897 0.077224 54.8215 65365.5 71106.2 257.476 69.96 80.29 0.91386 0.2352 443
740.000 0.84393 0.96293 0.073684 56.9470 66790.0 72714.6 259.679 70.62 80.58 0.91788 0.2024 450
760.000 0.81896 0.96618 0.070941 59.0056 68225.1 74330.4 261. 834 71.35 81.01 0.92137 0.1744 457
780.000 0.79575 0.96886 0.068321 61.0076 69672 .6 75955.9 263.945 72 .13 81.55 0.92443 0.1506 463
800.000 0.77409 0.97107 0.065966 62.9615 71133.8 77593.0 266.017 72.94 82.17 0.92714 0.1302 470

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

874 ROBERT D. GOODWIN

Table -17. Properties of methanol along isobars - Continued

T p Z 3PI3T 3PI3p E H S Cv Cp flP J1 W

K molll bar/K bar/(mol/I) J/mol J/mol J/(mo!'K) J/(mo!·K) J/(mo!'K) K/bar mls

60.00000 bar
175.590 28.34235 0.14500 17.036685 528.6584 -42.2 169.4 89.743 59.17 71.17 0.00000 -0.0397 1408
180.000 28.20092 0.14216 16.638737 521.3688 300.2 513.0 91.507 59.03 71.05 0.00000 -0.0397 1399
190.000 27.88516 0.13620 15.798833 505.5577 1057.3 1272.5 95.340 58.79 70.86 0.00000 -0.0398 1378
200.000 27.57570 0.13085 15.035320 490.5204 1793.3 2010.9 98.968 58.71 70.83 0.00000 -0.0398 1359
210.000 27.27190 0.12600 14.337578 476.0235 2514.9 2734.9 102.425 58.81 71.00 0.00000 -0.0397 1339
220.000 26.97308 0.12161 13.696805 461.8706 3228.7 3451.1 105.736 59.12 71.40 0.00001 -0.0394 1319
230.000 26.67857 0.11760 13.105652 447.8967 3940.5 4165.4 108.925 59.62 72.02 0.00003 -0.0389 1299
240.000 26.38764 0.11395 12.557917 433.9641 4655.5 4882.9 112.011 60.32 72.85 0.00007 -0.0383 1278
250.000 26.09957 0.11060 12.048316 419.9590 5378 .4 5608.2 115.009 61.20 73.89 0.00015 -0.0376 1257
260.000 25.81359 0.10752 11.572292 405.7892 6112.9 6345.3 117.933 62.23 75.11 0.00030 -0.0368 1236
270.000 25.52894 0.10469 11.125914 391.3838 6862.3 7097.3 120.794 63~38 76.49 0.00058 -0.0358 1214
280.000 25.24477 0.10209 10.705719 376.6893 7628.9 7866.5 123.602 64.63 78.00 0.00107 -0.0348 1191
290.000 24.96023 0.09969 10.308647 361.6701 8414.4 8654.8 126.366 65.95 79.62 0.00189 -0.0337 1167
300.000 24.67440 0.09749 9.931960 346.3067 9219.9 9463.0 129.091 67.30 81.34 0.00318 -0.0325 1142
310.000 24.38630 0.09546 9.573176 330.5938 10045.8 10291.8 131.784 68.68 83.13 0.00516 -0.0312 1117
320.000 24.09488 0.09359 9.230028 314.5398 10892 .1 11141.1 134.450 70.05 84.98 0.00810 -0.0298 1091
330.000 23.79901 0.09188 8.900406 298.1645 11758.4 12010.5 137.092 71.41 86.89 0.01232 -0.0283 1064
340.000 23.49743 0.09033 8.582318 281.4976 12643.8 12899.2 139.715 72.75 88.86 0.01819 -0.0268 1035
350.000 23.18876 0.08891 8.273854 264.5770 13547.7 13806.4 142.321 74.05 90.89 0.02614 -0.0251 1006
360.000 22.87144 0.08764 7.973144 247.4467 14469.0 14731.3 144.913 75.31 92.99 0.03662 -0.0232 976
370.000 22.54370 0.08651 7.678319 230.1550 15407.2 15673.3 147.493 76.52 95.17 0.05011 -0.0211 945
380.000 22.20347 0.08553 7.387462 212.7523 16361.9 16632.1 150.064 77 .69 97.46 0.06705 -0.0188 912
390.000 21.84835 0.08469 7.098563 195.2896 17333.5 17608.1 152.629 78.78 99.86 0.08789 -0.0161 878
400.000 21.47543 0.08401 6.809435 177.8160 18323.2 18602.6 155.191 79.80 102.42 0.11302 -0.0130 843
410.000 21.08113 0.08349 6.517626 160.3772 19333.4 19618.0 157.753 80.74 105.17 0.14282 -0.0095 807
420.000 20.66095 0.08316 6.220280 143.0133 20367.9 20658.3 160.322 81.57 108.18 0.17766 -0.0052 769
430.000 20.20899 0.08304 5.913925 125.7567 21432.7 21729.6 162.904 82.29 111.57 0.21794 0.0000 729
440.000 19.71730 0.08318 5.594130 108.6292 22536.0 22840.3 165.510 82.90 115.51 0.26416 0.0066 687
450.000 19.17450 0.08363 5.254905 91.6381 23689.9 24002.8 168.155 83.47 120.35 0.31695 0.0150 642
460.000 18.56324 0.08451 4.887553 74.7686 24911. 7 25234.9 170.866 84.10 126.75 0.37720 0.0263 593
470.000 17.85450 0.08599 4.478156 57.9684 26228.0 26564.0 173.687 85.10 136.10 0.44599 0.0425 537
480.000 16.99180 0.08848 4.000947 41.1047 27685.0 28038.1 176.704 87.12 151.87 0.52450 0.0678 472
490.000 15.83053 0.09303 3.393647 23.7988 29388.1 29767.1 180.134 91. 88 186.50 0.61342 0.1156 388
495.144 14.95826 0.09743 2.966333 14.2967 30466.0 30867.1 182.285 97.02 233.22 0.66280 0.1682 327

495.144 3.02263 0.48217 0.627531 4.6913 42612.2 44597.3 210.014 156.09 611.01 0.66280 1.1323 239
500.000 2.60580 0.55386 0.501206 8.5303 44525.5 46828.1 214.435 135.55 352.39 0.68598 1.1189 263
510.000 2.21406 0.63908 0.379020 13.8952 46849.4 49559.3 219.851 113.83 221. 39 0.71625 1.0778 290
515.000 2.09367 0.66927 0.341921 16.0236 47723.8 50589.6 221.863 106.87 192.59 0.72919 1.0537 300
520.000 1.99734 0.69480 0.312742 17.9327 48495.4 51499.4 223.623 101.33 172 .43 0.74103 1.0280 308
530.000 1.84927 0.73627 0.269236 21.2835 49834.9 53079.4 226.632 93.05 145.83 0.76223 0.9736 322
540.000 1.73792 0.76894 0.238006 24.1907 50995.6 54448.0 229.193 87.18 129.04 0.78022 0.9172 334
560.000 1.57604 0.81764 0.195711 29.1303 53002.6 56809.6 233.488 79.61 109.26 0.80981 0.8056 353
580.000 1.45983 0.85228 0.168198 33.2956 54765.9 58875.9 237.116 75.23 98.35 0.83240 0.7014 368
600.000 1.36978 0.87804 0.148802 36.9439 56391.9 60772.1 240.329 72.62 91.78 0.85062 0.6079 381
620.000 1.29651 0.89774 0.134368 40.2213 57935.7 62563.6 243.260 71.10 87.66 0.86563 0.5258 393
640.000 1.23485 0.91311 0.123190 43.2202 59429.6 64288.5 245.999 70.30 85.04 0.87716 0.4545 403
660.000 1.18167 0.92528 0.114264 46.0028 60894.0 65971.5 248.590 69.98 83.39 0.88661 0.3930 413
680.000 1.13495 0.93504 0.106958 48.6133 62342.1 67628.7 251.064 69.99 82.41 0.89445 0.3402 422
700.000 1.09328 0.94294 0.100852 51.0843 63783.1 69271.2 253.445 70.24 81.90 0.90101 0.2949 431
720.000 1.05570 0.94938 0.095662 53.4405 65223.6 70907.0 255.750 70.66 81. 73 0.90657 0.2560 439
740.000 1.02147 0.95468 0.091184 55.7009 66668.0 72541. 9 257.990 71.21 81.80 0.91131 0.2225 446
760.000 0.99006 0.95905 0.087270 57.8807 68119.8 74180.0 260.174 71.85 82.05 0.91540 0.1938 454
780.000 0.96104 0.96267 0.083811 59.9921 69581.5 75824.7 262.310 72.55 82.44 0.91896 0.1690 461
800.000 0.93408 0.96570 0.080725 62.0448 71054.8 77478.2 264.403 73.30 82.93 0.92209 0.1476 468

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 875

Table 17. Properties of methanol along isobars - Continued

T p Z 8plaT JPlop E H S . Cu Cp f/P Il W

K molll bar/K bar/(mol!l) J/mol l/mol J/(mol·K) ll(mol·K) Jl(mol·K) K/bar m/s
70.CXX)()() bar
175.590 28.36119 0.16906 17.137853 532.7856 -49.1 197.7 89.703 59.14 71.17 0.00000 -0.0397 1414
180.000 28.22003 0.16574 16.737750 525.4531 293.2 541.2 91.467 59.00 71.05 0.00000 -0.0397 1405
190.000 27.90486 0.15879 15.893363 509.5586 1049.9 1300.7 95.300 58.76 70.85 0.00000 -0.0398 1384
200.000 27.59600 0.15254 15.125901 494.4571 1785.4 2039.1 98.928 58.68 70.83 0.00000 -0.0398 1364
210.000 27.29282 0.14689 14.424657 479.9130 2506.6 2763.1 102.384 58.78 71.00 0.00000 -0.0397 1345
220.000 26.99464 0.14176 13.780774 465.7280 3219.9 3479.2 105.696 59.08 71.39 0.00001 -0.0394 1325
230.000 26.70080 0.13709 13.186856 451.7355 3931.2 4193.4 108.884 59.59 72.01 0.00002 -0.0389 1305
240.000 26.41058 0.13282 12.636664 437.7964 4645.7 4910.8 111.969 60.29 72.84 0.00006 -0.0383 1284
250.000 26.12327 0.12891 12.124885 423.7956 5368.1 5636.0 114.967 61.16 73.87 0.00013 -0.0376 1263
260.000 25.83812 0.12532 11.646943 409.6398 6102.0 6373.0 117.890 62.19 75.09 0.00026 -0.0368 1242
270.000 25.55436 0.12202 11 .198886 395.2566 6850.8 7124.7 120.751 63.34 76.46 0.00051 -0.0359 1220
280.000 25.27118 0.11898 10.777243 380.5916 7616.7 7893.7 123.558 64.59 77.97 0.00094 -0.0348 1197
290.000 24.98773 0.11618 10.378944 365.6080 8401.4 8681.6 126.320 65.90 79.59 0.00164 -0.0337 1173
300.000 24.70311 0.11360 10.001250 350.2850 9206.1 9489.4 129.044 67.26 81.29 0.00277 -0.0325 1149
310.000 24.41636 0.11123 9.641683 334.6165 10031.1 10317.8 131.736 68.63 83.07 0.00450 -0.0313 1124
320.000 24.12647 0.10905 9.297982 318.6100 10876.3 11166.5 134.400 70.00 84.92 0.00705 -0.0299 1098
330.000 23.83232 0.10705 8.968048 302.2844 11741.4 12035.1 137.040 71.36 86.82 0.01072 -0.0285 1071
340.000 23.53270 0.10522 8.649909 285.6690 12625.6 12923.0 139.660 72.69 88.77 0.01583 -0.0269 1043
350.000 23.22626 0.10357 8.341678 268.8012 13527.9 13829.3 142.263 73.99 90.78 0.02274 -0.0252 1014
360.000 22.91151 0.10207 8.041522 251.7249 14447.5 14753.0 144.851 75.24 92.86 0.03185 -0.0234 984
370.000 22.:,\R674 0.10074 7.747616 2.14.4&&7 1:<;3&3.6 1:'i693.:<; 147.42& 76.4:'\ 95.01 0.04357 -0.0214 953
380.000 22.25000 0.09957 7.458108 217.1437 16335.9 16650.5 149.994 77.60 97.26 0.05830 -0.0191 921
390.000 21.89898 0.09858 7.171059 199.7414 17304.7 17624.4 152.554 78.69 99.62 0.07640 -0.0165 888
400.000 21.53096 0.09775 6.884404 182.3331 18291.1 18616.2 155.109 79.70 102.12 0.09824 -0.0136 853
410.000 21.14260 0.09712 6.595844 164.9666 19297.2 19628.3 157.663 80.61 104.80 0.12413 -0.0101 818
420.000 20.72975 0.09670 6.302745 147.6854 20326.7 20664.4 160.221 81.42 107.71 0.15440 -0.0061 780
430.000 20.28704 0.09651 6.001964 130.5267 21385.1 21730.2 162.791 82.11 110.94 0.18941 -0.0011 741
440.000 19.80734 0.09660 5.689584 113.5195 22480.3 22833.7 165.380 82.69 114.67 0.22957 0.0050 700
450.000 19.28071 0.09703 5.360458 96.6819 23623.1 23986.2 168.003 83.19 119.17 0.27548 0.0128 657
460.000 18.69248 0.09791 5.007396 80.0175 24829.3 25203.8 170.682 83.73 124.98 0.32788 0.0231 610
470.000 18.01919 0.09941 4.619502 63.5071 26121.8 26510.3 173.454 84.57 133.21 0.38777 0.0374 558
480.000 17.21874 0.10186 4.178276 47.0918 27537.8 27944.3 176.387 86.28 146.30 0.45620 0.0585 499
490.000 16.19913 0.10607 3.645887 30.6162 29149.6 29581.8 179.628 90.24 171. 31 0.53390 0.0938 425
500.000 14.65187 0.11492 2.907027 13.5390 31177.5 31655.3 183.656 100.48 245.86 0.61947 0.1756 321
504.058 13.48576 0.12385 2.419183 5.7834 32376.6 32895.7 186.072 110.33 390.80 0.65461 0.2777 252
504.058 4.06854 0.41053 0.822814 2.3807 41533.1 43253.6 206.621 161.77 1027.75 0.65461 1.0001 217
510.000 3.17553 0.51985 0.596519 7.4102 44428.7 46633.0 213.363 135.27 378.13 0.67191 0.9934 254
515.000 2.86317- 0.57096 0.509308 10.3155 45803.6 48248.4 216.515 123.30 281.27 0.68829 0.9786 270
520.000 2.65512 0.60978 0.450233 12.7417 46884.1 49520.5 218.970 114.65 232.00 0.70332 0.9611 283
530.000 2.37727 0.66820 0.371636 16.7822 48603.4 51547.9 222.835 102.59 179.77 0.72871 0.9212 302
540.000 2.19035 0.71179 0.320062 20.1573 49997.3 53193.2 225.914 94.49 151.69 0.75015 0.8772 317
560.000 1.94118 0.77448 0.254823 25.7383 52285.6 55891.6 230.824 84.39 121. 88 0.78515 0.7845 340
580.000 1. 77439 0.81806 0.214628 30.3532 54216.3 58161. 3 234.810 78.61 106.56 0.81185 0.6935 358
600.000 1.65051 0.85015 0.187186 34.3502 55954.6 60195.7 238.257 75.14 97.60 0.83328 0.6089 373
620.000 1.55261 0.87460 0.167204 37.9131 57579.1 62087.7 241.354 73.04 92.01 0.85084 0.5328 386
640.000 1.47198 0.89368 0.151982 41.1534 59133.7 63889.2 244.215 71. 83 88.41 0.86443 0.4654 397
660.000 1.40360 0.90882 0.139982 44.1445 60645.2 65632.4 246.899 71.21 86.08 0.87557 0.4064 408
680.000 1.34430 0.92099 0.130264 46.9379 62130.9 67338.0 249.445 71.00 84.60 0.88479 0.3551 417
700.000 1.29201 0.93089 0.122220 49.5710 63602.3 69020.2 251.884 71.07 83.71 0.89250 0.3105 426
720.000 1.24528 0.93900 0.115439 52.0719 65067.8 70689.0 254.235 71 ..15 ILl. 24 O.RQRQQ 0.2719 4.1.'i
740.000 1.20304 0.94569 0.109631 54.4626 66533.1 72351.6 256.513 71.79 83.07 0.90453 0.2383 443
760.000 1.16453 0.95125 0.104591 56.7600 68002.4 74013.4 258.729 72.33 83.14 0.90928 0.2092 451
780.000 1.12916 0.95590 0.100165 58.9780 69478.9 75678.2 260.891 72.96 83.37 0.91339 0.1840 458
800.000 1.09646 0.95979 0.096239 61.1278 70964.9 77349.0 263.006 73.65 83.73 0.91698 0.1620 465

J. Phy~_ Ch9m. Ref. Data, Vol. 16, No.4, 1987

 ROBERT D. GOODWIN

Table ]7. Pro~rties of methanol along isobars - Continued

;; aplaT aPla(, E H S CtJ Cp j/P fJ. W

III1.J/J bar/K bar/CmaI/I) J/moi ]Imol ]1(moI·K) ]1(moi·K) J/(mol·K) K/bar m/s

75.00000 bar
175.590 28.37055 O. ]8107 17.187638 534.8267 -52.6 2] 1. 8 89.683 59.12 71.17 0.00000 -0.0397 1417
180.000 28.22952 0.17752 16.786468 527.4725 289.7 555.3 91.447 58.98 71.05 0.00000 -0.0397 1408
190.000 27.91465 0.17007 15.939873 511.5365 1046.2 1314.9 95.280 58.74 70.85 0.00000 -0.0398 1387
200.000 27.60610 0.16338 15.170463 496.4031 1781.5 2053.2 98.908 58.66 70.83 0.00000 -0.0398 1367
210.000 27.30322 0.15732 14.467492 481.8354 2502.5 2777.2 102.364 58.76 71.00 0.00000 -0.0397 1347
220.000 27.00536 0.15183 13.822075 467.6342 3215.6 3493.3 105.675 59.06 71. 39 0.00001 -0.0394 1328
230.000 26.71184 0.14682 13.226792 453.6324 3926.6 4207.4 108.864 59.57 72.00 0.00002 -0.0389 1308
240.000 26.42197 0.14225 12.675387 439.6900 4640.9 4924.8 111.949 60.27 72.83 0.00006 -0.0384 1287
250.000 26.13504 0.13806 12.162530 425.6913 5363.0 5649.9 114.946 61.15 73.87 0.00012 -0.0376 1266
260.000 25.85030 0.13421 11.683637 411.5424 6096.6 6386.8 117.869 62.17 75.08 0.00025 -0.0368 1245
270.000 25.56698 0.13067 11. 234748 397.1702 6845.1 7138.4 120.729 63.33 76.45 0.00048 -0.0359 1223
280.000 25.28428 0.12741 10.812383 382.5198 7610.6 7907.3 123.536 64.57 77.96 0.00088 -0.0349 1200
290.000 25.00]37 0.12441 10.413472 367.5537 8395.0 8695.0 126.297 65.88 79.57 0.00155 -0.0337 1177
300.000 24.71734 0.12165 10.035272 352.2508 9199.2 9502.7 129.021 67.23 81. 27 0.00261 -0.0326 1152
310.000 24.43126 0.11910 9.675308 336.6043 10023.8 10330.7 131. 712 68.61 83.05 0.00423 -0.0313 1127
320.000 24. ]4212 0.11676 9.331321 320.6213 10868.5 11179.2 134.375 69.98 84.89 0.00663 -0.0300 1101
330.000 23.84880 0.11462 9.001217 304.3203 1]733.0 12047.5 137.014 71.33 86.78 0.01008 -0.0285 1074
340.000 23.55014 0.11266 8.683032 287.7303 12616.5 12935.0 139.633 72.66 88.72 0.01488 -0.0270 1047
350.000 23.24479 0.11087 8.374893 270.8885 13518.1 13840.7 142.234 73.96 90.73 0.02138 -0.0253 1018
360.000 22.93129 0.10927 8.074980 253.8387 14436.8 14763.9 144.821 75.21 92.79 0.02995 -0.0235 988
370.000 22.60797 0.10784 7.781490 236.6295 15371.9 15703.7 147.395 76.41 94.94 0.04096 -0.0215 957
380.000 22.27291 0.10658 7.492599 219.3123 16323.1 16659.8 149.960 77.56 97.17 0.05480 -0.0193 926
390.000 21.92388 0.10550 7.206406 201.9390 17290.6 17632.7 152.516 78.64 99.51 0.07181 -0.0167 892
400.000 21.55822 0.10460 6.920895 184.5617 18275.3 18623.2 155.068 79.64 101. 98 0.09233 -0.0138 858
410.000 21.17271 0.10391 6.633836 167.2291 19279.5 19633.7 157.619 80.55 104.62 0.11666 -0.0105 823
420.000 20.76334 0.10344 6.342693 149.9863 20306.6 20667.8 160.172 81.35 107.48 0.14511 -0.0065 786
430.000 20.32500 0.10321 6.044468 132.8724 21362.0 21731.0 162.735 82.03 110.65 0.17800 -0.0017 747
440.000 19.85092 0.10327 5.735459 115.9194 22453.2 22831.0 165.316 82.58 114.27 0.21575 0.0043 707
450.000 19.33177 0.10369 5.410874 99.1499 23590.9 23978.9 167.929 83.06 118.62 0.25890 0.0118 664
460.000 18.75398 0.10456 5.064125 82.5744 24790.0 25189.9 170.594 83.56 124.18 0.30817 0.0217 618
470.000 18.09630 0.10606 4.685470 66.1861 26071.8 26486.3 173.344 84.34 131.94 0.36449 0.0351 568
480.000 17.32181 0.10849 4.258948 49.9503 27470.3 27903.3 176.241 85.93 144.02 0.42889 0.0546 511
490.000 16.35450 0.11256 3.753930 33.7725 29047.6 29506.2 179.411 89.61 166.05 0.50208 0.0858 441
500.000 14.97642 0.12046 3.090594 17.3671 30966.6 31467.4 183.212 98.83 221.43 0.58288 0.1490 348
508.107 12.45096 0.14258 2.102576 2.5998 33531.7 34134.1 188.418 122.60 679.94 0.64742 0.3780 212

508.107 4.86000 0.36529 0.956279 1.2721 40712.5 42255.7 204.402 163.99 1710.36 0.64742 0.9334 203
510.000 4.12584 0.42869 0.804646 3.4496 42391.7 44209.5 208.336 151.26 713.58 0.64820 0.9454 225
515.000 3.43822 0.50943 0.635917 7.2139 44515.6 46697.0 213.192 133.49 371.75 0.66690 0.9397 252
520.000 3.09559 0.56037 0.544773 10.0505 45892.9 48315.7 216.315 122.32 282.56 0.68362 0.92.67 269
530.000 2.69704 0.63105 0.435951 14.5440 47901.2 50682.1 220.828 107.73 202.94 0.71139 0.8935 292
540.000 2.45141 0.68142 0.369330 18.1878 49447.3 52506.8 224.242 98.30 165.69 0.73467 0.8551 309
560.000 2.1-1191 0.75203 0.288707 24.1051 51902.3 55403.8 229.515 86.80 129.01 0.77247 0.7713 334
580.000 1.94309 0.80039 0.240595 28.9422 53926.1 57785.9 233.699 80.29 111.02 0.80126 0.6867 353
600.000 1.79878 0.83579 0.208315 33.1073 55724.8 59894.3 237.271 76.38 100.69 0.82433 0.6067 369
620.000 1.68646 0.86269 0.185075 36.8062 57392.1 61839.3 240.455 74.00 94.28 0.84319 0.5337 382
640.000 1.59497 0.88367 0.167512 40.1610 58978.5 63680.7 243.380 72.58 90.16 0.85784 0.4685 394
660.000 1.51803 0.90033 0.153751 13.2510 60514.4 65455.1 246.111 71. 81 87.47 0.86985 0.4109 405
680.000 1.45176 0.91374 0.142670 46.1313 62019.5 67185.6 248.695 71.49 85.72 0.87978 0.3605 415
700.000 1.39363 0.92465 0.133534 48.8415 63506.6 68888.2 251.163 71.47 84.63 0.88808 0.3165 424
720.000 1. 34191 0.93361 0.125862 51.4116 64985.0 70574.0 253.538 71.69 84.01 0.89507 0.2781 433
740.000 ] .29536 0.94103 0.119314 53.8646 66461.0 72250.9 255.836 72.07 83.73 0.90102 0.2447 44]
760.000 1.25305 0.91720 0.1136-19 56.2186 67939.4 73924.8 258.068 72.57 83.70 0.90611 0.2156 449
780.000 1.21430 0.95237 0.108689 58.4880 69423.5 75599.9 260.243 73.17 83.85 0.91052 0.1902 457
800.000 1.17856 0.95672 0.104300 60.6848 70916.1 77279.8 262.370 13.83 84.15 0.91436 0.1680 464

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 877

Table 17. Properties of methanol along isobars - Continued

T p Z 8plaT 8?18p E H S Cu Cp flP fL W

K molll bar/K bar/(molll) J/mol llmoi J/(mol·K) J/(mol·K) J/(mol·K) K/bar m/s

80.94644 bar
175.590 28.38165 0.19535 17.246177 537.2352 -56.6 228.6 89.659 59.11 71.17 0.00000 -0.0397 1420
180.000 28.24077 0.19152 16.843752 529.8554 285.5 572.1 91.424 58.96 71.05 0.00000 -0.0397 1411
190.000 27.92625 0.18348 15.994559 513.8702 1041.8 1331.6 95.256 58.72 70.85 0.00000 -0.0398 1391
200.000 27.61805 0.17625 15.222855 498.6988 1776.8 2069.9 98.884 58.64 70.82 0.00000 -0.0398 1371
210.000 27.31553 0.16972 14.517851 484.1030 2497.6 2793.9 102.340 58.74 71.00 0.00000 -0.0397 1351
220.000 27.01804 0.16379 13.870626 469.8827 3210.4 3510.0 105.651 59.04 71.38 0.00001 -0.0394 1331
230.000 26.72492 0.15839 13.273734 455.8697 3921.2 4224.1 108.840 59.55 72.00 0.00002 -0.0389 1311
240.000 26.43546 0.15345 12.720896 441.9232 4635.2 4941.4 111. 924 60.25 72.83 0.00005 -0.0384 1291
250.000 26.14897 0.14892 12.206769 427.9269 5356.9 5666.5 114.921 61.13 73.86 0.00011 -0.0377 1270
260.000 25.86471 0.14477 11.726753 413.7860 6090.3 6403.2 117.844 62.15 75.07 0.00023 -0.0368 1248
270.000 25.58191 0.14095 11.276878 399.4268 6838.3 7154.7 120.703 63.30 76.44 0.00045 -0.0359 1226
280.000 25.29978 0.13743 10.853659 384.7936 7603.5 7923.4 123.510 64.55 77 .94 0.00083 -0.0349 1204
290.000 25.01750 0.13419 10.454019 369.8483 8387.4 8711.0 126.271 65.86 79.55 0.00145 -0.0338 1180
300.000 24.73417 0.13120 10.075217 354.5691 9191.1 9518.4 128.993 67.21 81.25 0~00244 -0.0326 1156
310.000 24.44887 0.12845 9.714776 338.9487 10015.1 10346.2 131.683 68.58 83.02 0.00396 -0.0314 1131
320.000 24.16059 0.12592 9.370440 322.9934 10859.3 11194.3 134.345 69.95 84.85 0.00620 -0.0300 1105
330.000 23.66627 0.12360 9.040123 306.721:5 11723.1 12062.3 136.963 71.30 36.74 0.00943 -0.0236 1079
340.000 23.57072 0.12148 8.721869 290.1615 12605.8 12949.3 139.600 72.63 88.67 0.01391 -0.0271 1051
350.000 23.26664 0.11955 8.413818 273.3502 13506.5 13854.4 142.200 73.92 90.66 0.01998 -0.0255 1022
·360.000 22.95460 0.11781 8.114168 256.3315 14424.2 14776.9 144.785 75.17 92.72 0.02799 -0.0237 993
370.000 22.63296 0.11626 7.821140 239.1538 15358.2 15715.9 147.357 76.37 94.85 0.03828 -0.0217 962
380.000 22.29981 0.11489 1.~32939 221.8689 16308.0 16611.0 149.919 11.~1 91.06 0.0::5120 -0.019~ 931
390.000 21.95314 0.11371 7.247706 204.5293 17273.9 17642.6 152.472 78.59 99.37 0.06710 -0.0170 898
400.000 21.59021 0.11273 6.963481 187.1875 18256.7 18631. 7 155.020 7.9.59 101. 82 0.08626 -0.0141 864
410.000 21.20799 0.11196 6.678109 169.8936 19258.6 19640.3 157.566 80.49 104.41 0.10899 -0.0108 829
420.000 20.80263 0.11143 6.389163 152.6940 20283.0 20672 .1 160.114 81.27 107.22 0.13556 -0.0070 792
430.000 20.36930 0.1111~ 6.093797 13:5.6302 21334.9 21732.3 162.670 61.93 110.31 0.16626 -0.0023 754
440.000 19.90161 0.11118 5.788543 118.7372 22421.7 22828.4 165.242 82.47 113.82 0.20154 0.0034 715
450.000 19.39089 0.11157 5.468976 102.0421 23553.5 23971.0 167.843 82.92 118.00 0.24185 0.0107 673
460.000 18.82472 0.11243 5.129129 85.5626 24744.5 25174.5 170.491 83.38 123.29 0.28790 0.0200 628
470.000 18.18409 0.11391 4.760402 69.3036 26014.7 26459.9 173.218 84.08 130.56 0.34056 0.0327 579
480.000 17.43706 0.11632 4.349235 53.2522 27394.4 27858.7 176.077 85.56 141.63 0.40081 0.0505 524
490.000 16.52177 0.12026 3.871207 37.3637 28936.8 29426.7 179.175 88.98 160.97 0.46935 0.0779 459
500.000 15.28299 0.12740 3.270779 21.5146 30764.1 31293.7 182.787 97.40 203.84 0.54519 0.1276 374
510.000 12.91577 0.14780 2.309992 5.1555 33479.5 34106.3 188.284 124.15 440.58 0.61832 0.2933 238
515.000 4.66372 0.40534 0.889090 2.9586 42150.1 43885.7 207.439 149.41 782.03 0.64017 0.8824 219
520.000 3.81552 0.49069 0.698513 6.6544 44413.7 46535.2 212.556 132.78 394.68 0.65947 0.8836 248
530.000 3.14880 0.58337 0.528603 11. 8670 46963.0 49533.7 218.274 114.21 240.07 0.69053 0.8595 279
540.000 2.80108 0.64364 0.437051 15.8810 48739.8 51629.6 222.197 102.96 185.74 0.71609 0.8275 299
560.000 2.39882 0.72473 0.333363 22.2241 51423.6 54798.0 227.964 89.68 138.34 0.75726 0.7539 327
580.000 2.15455 0.77907 0.274131 27.3267 53567.5 57324.5 232.402 82.28 116.64 0.78856 0.6767 347
600.000 1.98239 0.81850 0.235268 31.6873 55442.3 59525.6 236.132 77 .84 104.51 0.81357 0.6020 364
620.000 1.85088 0.84838 0.207675 35.5426 57162.4 61535.8 239.422 75.11 97.07 0.83398 0.5328 378
640.000 1. 74518 0.87165 0.187026 39.0284 58787.8 63426.1 242.425 73.46 92.29 0.84990 0.4702 391
660.000 1.65718 0.89012 0.170969 42.2313 60353.7 65238.3 245.214 72.51 89.15 0.86295 0.4145 402
680.000 1.58198 0.90501 0.158109 45.2105 61882.3 66999.1 247.843 72.06 87.08 0.87375 0.3653 412
700.000 1.51644 0.91714 0.147562 48.0088 63388.5 68726.5 250.347 71.95 85.75 0.88276 0.3221 422
720.000 1.45844 0.92713 0.138743 50.6579 64882.5 70432.7 252.751 72.09 84.95 0.89035 0.2842 431
740.000 1.40647 0.93541 0.131245 53.1822 66371.5 72126.9 255.072 72.40 84.52 0.89680 0.2510 440
760.000 1.35941 0.94232 0.124781 55.6010 67860.9 73815.4 257.324 72.86 84.37 0.90232 0.2220 448
780.000 1.31646 0.94811 0.119140 57.9295 69354.3 75503.1 259.516 73.41 84.43 0.90709 0.1966 456
800.000 1.27696 0.95300 0.114164 60.1804 70854.8 77193.6 261.6:56 14.03 84.66 0.91124 0.1143 463

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

HiH ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

l' p Z oPlaT aPlop E H S Cv cp flP jJ. W

K molll bar/K bar/(maI/I) Jlmol J/mol J/(mo!·K) J/(mo!·K) J/(mo!·K) K/bar mls
85.()()()OO bar
175.590 28.38918 0.20508 17.285677 538.8656 -59.4 240.0 89.643 59.09 71.17
1150.000 215.241541 0.20106 16.1515240.3 :5:31.46154 2152.7 :55.3 .6 91.407 55.95 71.05 0.00000 -0.0397 1413
190.000 27.93413 0.19262 16.031456 515.4497 1038.8 1343.1 95.240 58.71 70.85 0.00000 -0.0398 1393
200.000 27.62616 0.18503 15.258204 500.2524 1773.7 2081.4 98.868 58.63 70.82 0.00000 -0.0398 1373
210.000 27.32389 0.17816 14.551825 485.6376 2494.3 2805.3 102.324 58.73 70.99 0.00000 -0.0397 1353
220.000 27.02666 0.17194 13.903378 471.4042 3206.9 3521.4 105.635 59.03 71.38 0.00001 -0.0394 1333
230.000 26.73380 0.16626 13.305398 457.3835 3917.5 4235.4 108.823 59.54 71.99 0.00002 -0.0390 1313
240.000 26.44462 0.16108 12.751592 443.4342 4631.3 4952.7 111.908 60.24 72.82 0.00005 -0.0384 1293
250.000 26.15843 0.15633 12.236603 429.4395 5352.8 5677.7 114.904 61.11 73.85 0.00011 -0.0377 1272
260.000 25.87449 0.15196 11.755834 415.3044 6085.9 6414.4 117.826 62.14 75.06 0.00022 -0.0368 1251
270.000 25.59204 0.14795 11.305283 400.9536 6833.7 7165.9 120.686 63.29 76.43 0.00043 -0.0359 1229
280.000 25.31030 0.14425 10.881484 386.3320 7598.6 7934.4 123.492 64.53 77 .93 0.00079 -0.0349 1206
290.000 25.02843 0.140%5 10.481349 371.4008 8382.2 8721.9 126.252 65.84 79.54 0.00139 -0.0338 1183
300.000 24.74558 0.13771 10.102135 356.1376 9185.7 9529.2 128.974 67.19 81.23 0.00234 -0.0326 1159
310.000 24.46080 0.13482 9.741366 340.5348 10009.3 10356.8 131.664 68.56 83.00 0.00379 -0.0314 1134
320.000 24.17311 0.13216 9.396788 324.5984 10853.0 11204.7 134.325 69.93 84.83 0.00594 -0.0301 1108
330.000 23.88145 0.12972 9.066319 308.3462 11716.4 12072.3 136.962 71. 28 86.71 0.00903 -0.0287 1081
340.000 23.58465 0.12749 8.748009 291.8064 12598.6 12959.0 139.579 72.61 88.64 0.01333 -0.0272 1054
350.000 23.28142 0.12546 8.440006 275.0158 13498.7 13863.8 ]42.177 73.90 90.62 0.01915 -0.0255 1025
360.000 22.97036 0.12363 8.140520 258.0180 14415.7 14785.8 144.761 75.15 92.67 0.02681 -0.0237 996
370.000 22.64985 0.12199 7.847785 240.8616 15348.9 15724.2 147.331 76.34 94.79 0.03667 -0.0218 966
380.000 22.31806 0.12054 7.560028 223.5983 16297.9 16678.7 149.891 77 .48 96.98 0.04904 -0.0196 934
390.000 21.97287 0.11930 7.275418 206.2810 17262.7 17649.5 152.443 78.56 99.28 0.06426 -0.0171 902
400.000 21.61176 0.11826 6.992026 188.9627 18244.2 18637.5 154.988 79.55 101.70 0.08261 -0.0143 868
410.000 21.23172 0.11744 6.707748 171.6941 19244.6 19645.0 157.531 80.44 104.28 0.10437 -0.0111 833
420.000 20.82902 0.11686 6.420223 154.5227 20267.1 20675.2 160.075 81.22 107.04 0.12981 -0.0073 797
430.000 20.39898 0.11655 6.126702 137.4911 21316.7 21733.4 162.627 81. 87 110.08 0.15923 -0.0027 759
440.000 19.93547 0.11655 5.823863 120.6364 22400.6 22826.9 165.193 82.40 113.53 0.19300 0.0029 720
450.000 19.43024 0.11692 5.507502 103.9885 23528.6 23966.1 167.786 82.83 117.60 0.23161 0.0099 678
460.000 18.87155 0.11777 5.172023 87.5690 24714.4 25164.8 170.424 83.26 122.72 0.27572 0.0190 634
470.000 18.24172 0.11924 4.809493 71.3896 25977.1 26443.0 173.135 83.92 129.69 0.32617 0.0311 586
480.000 17.51165 0.12162 4.407688 55.4489 27345.1 27830.5 175.970 85.32 140.17 0.38392 0.0480 533
490.000 16.62695 0.12548 3.945416 39.7268 28866.6 29377 .8 179.026 88.60 158.05 0.44966 0.0733 470
500.000 15.46058 0.13225 3.377879 24.1656 30645.4 31195.2 182.537 96.63 195.40 0.52250 0.1165 390
510.000 13.51448 0.14832 2.557061 8.5852 33083.0 33711. 9 187.450 120.72 333.39 0.59310 0.2273 272
515.000 10.22909 0.19406 1.655381 0.6916 35975.8 36806.8 193.562 147.29 2097.44 0.61932 0.5570 175
520.000 4.57868 0.42938 0.853143 4. i335 43022.2 44878.7 209.182 141.17 577 .94 0.64239 0.8480 229
530.000 3.52010 0.54796 0.605403 10.0143 46236.8 48651.5 216.379 118.86 275.40 0.67608 0.8357 269
540.000 3.06974 0.61672 0.490130 14.3235 48218.3 50987.2 220.751 106.21 202.32 0.70330 0.8082 291
560.000 2.58654 0.70579 0.366837 20.9797 51082.1 54368.4 226.906 91.64 145.33 0.74682 0.7411 322
580.000 2.30586 0.76440 0.298776 26.2664 53314.7 57001.0 231.530 83.62 120.69 0.77983 0.6688 343
600.000 2.11224 0.80666 0.254845 30.7587 55244.0 59268.2 235.372 78.82 107.22 0.80616 0.5977 361
620.000 1.96628 0.83858 0.223961 34.7178 57001.5 61324.4 238.738 75.86 99.03 0.82763 0.5311 376
640.000 1.85005 0.86342 0.201004 38.2898 58654.2 63248.7 241.795 74.05 93.78 0.84443 0.4703 389
660.000 1.75393 0.88313 0.183243 41.5667 60241.0 65087.2 244.625 72.99 90.32 0.85819 0.4159 400
680.000 1.67224 0.89903 0.169074 44.6108 61786.0 66869.0 247.285 72.44 88.02 0.86958 0.3676 411
700.000 1.60136 0.91200 0.157492 47.4666 63305.5 68613 .5 249.814 72.26 86.53 0.87909 0.3250 421
720.000 1.53885 0.92268 0.147834 50.1675 64810.3 70333.9 252.238 72.35 85.59 0.88710 0.2876 430
740.000 1.48301 0.93155 0.139645 52.7386 66308.3 72039.9 254.576 72.63 85.07 0.89390 0.2546 439
760.000 1.43258 0.93896 0.132600 55.1999 67805.2 73738.6 256.841 73.04 84.84 0.89972 0.2258 447
780.000 1.38665 0.94519 0.126465 57.5673 69305.1 75435.0 259.044 73.57 84.84 0.90473 0.2004 455
800.000 1.34450 0.95045 0.121064 59.8538 70811.2 77133.2 261.194 74.17 85.01 0.90910 0.1781 462

J. Phys. Chem_ Ref_ Data. Vol. 16, No_ 4,1987

 THERMODYNAMIC PROPERTIES OF METHANE 879
Table 17. Properties of methanol along isobars - Continued

T p Z JFIJT JPI(Jp E H S Cv Cp liP J.L W

K molll bar/K bar/(moIl}) J/mol 3/mol J/(mol·K) J/(mol·K) J/(mol·K) K/bar m/s

90.00000 bar
175.590 28.39844 0.21708 17.333960 540.8644 -62.8 254.2 89.623 59.08 71.17 0.00000 -0.0397 1426
180.000 28.25780 0.21281 16.929654 533.4459 279.2 597.7 91.388 58.94 71.05 0.00000 -0.0397 1416
190.000 27.94381 0.20388 16.076556 517.3858 1035.1 1357.2 95.220 58.70 70.85 0.00000 -0.0398 1396
200.000 27.63614 0.19584 15.301408 502.1566 1769.8 2095.5 98.848 58.61 70.82 0.00000 -0.0398 1376
210.000 27.33417 0.18857 14.593348 487.5182 2490.2 2819.4 102.304 58.71 70.99 0.00000 -0.0397 1356
220.000 27.03724 0.18198 13.943405 473.2687 3202.6 3535.5 105.615 59.02 71.38 0.00001 -0.0394 1336
230.000 26.74470 0.17597 13.344092 459.2385 3912.9 4249.5 108.803 59.52 71.99 0.00002 -0.0390 1316
240.000 26.45587 0.17048 12.789099 445.2857 4626.5 4966.7 111.887 60.22 72.82 0.00005 -0.0384 1296
250.000 26.17005 0.16545 12.273056 431.2928 5347.8 5691. 7 114.883 61.10 73.84 0.00010 -0.0377 1275
260.000 25.88650 0.16083 11.791352 417.1643 6080.6 6428.3 117.805 62.12 75.05 0.00021 -0.0369 1254
270.000 25.60448 0.15658 11.339981 402.8242 6828.1 7179.6 120.664 63.27 76.42 0.00041 -0.0359 1232
280.000 25.32321 0.15266 10.915467 388.2169 7592.6 7948.0 123.470 64.51 77 .91 0.00075 -0.0349 1209
290.000 25.04186 0.14905 10.514722 373.3030 8375.9 8735.3 126.230 65.82 79.52 0.00132 -0.0338 1186
300.000 24.75958 0.14573 10.134999 358.0595 9178.9 9542.4 128.951 67.17 81.21 0.00223 -0.0327 1162
310.000 24.47544 0.14266 9.773823 342.4784 10002.1 10369.8 131.640 68.54 82.97 0.00361 -0.0314 1137
320.000 24.18847 0.13985 9.428943 326.5651 10845.4 11217.4 134.300 69.91 84.80 0.00566 -0.0301 1111
330.000 23.89761 0.13726 9.098279 310.3370 11708.2 12084.8 136.936 71.26 86.67 0.00860 -0.0287 1085
340.000 23.60172 0.13489 8.779890 293.8220 12589.7 12971.1 139.552 72.58 88.60 0.01268 -0.0272 1057
350.000 23.29954 0.13274 8.471934 277.0567 13489.1 13875.4 142.149 73.87 90.57 0.01822 -0.0256 1029
360.000 22.98966 0.13079 8.172633 260.0844 14405.3 14796.8 144.731 75.12 92.61 0.02551 -0.0239 1000
370.000 22.67052 0.12905 7.880239 242.9538 15337.6 15734.6 147.300 76.31 94.71 0.03488 -0.0219 970
380.000 22.34032 0.12751 7.593004 225.7168 16285.4 16688.3 149.857 77.45 96.90 0.04665 -0.0198 938
390.000 21.99698 0.12618 7.309124 208.4265 17248.9 17658.0 152.406 78.52 99.18 0.06112 -0.0173 906
400.000 21.63807 0.12506 7.026715 191.1364 18229.0 18644.9 154.949 79.50 101.57 0.07857 -0.0146 872
410.000 21.26065 0.12418 6.743727 173.8980 19227.5 19650.8 157.488 80.39 104.11 0.09926 -0.0114 838
420.000 20.86115 0.12354 6.457877 156.7599 20247.7 20679.2 160.028 81.16 106.84 0.12345 -.0.0077 802
430.000 20.43505 0.12319 6.166526 139.7663 21294.6 21735.0 162.573 81. 80 109.82 0.15142 -0.0032 765
440.000 19.97653 0.12315 5.866514 122.9563 22375.0 22825.5 165.133 82.31 113.17 0.18353 0.0023 726
450.000 19.47778 0.12350 5.553889 106.3628 23498.4 23960.5 167.716 82.72 117.12 0.22025 0.0090 685
460.000 18.92786 0.12432 5.223463 90.0119 24678.1 25153.6 170.342 83.12 122.04 0.26221 0.0178 642
470.000 18.31054 0.12578 4.868018 73.9222 25932.0 26423.5 173.035 83.74 128.68 0.31021 0.0293 595
480.000 17.59973 0.12813 4.476727 58.1040 27286.7 27798.1 175.843 85.06 138.51 0.36518 0.0452 543
490.000 16.74850 0.13190 4.031576 42.5601 28785.1 29322.5 178.852 88.18 154.89 0.42781 0.0683 483
500.000 15.65509 0.13829 3.497259 27.2864 30514.3 31089.2 182.260 95.84 187.29 0.49730 0.1055 407
510.000 13.99689 0.15164 2.778522 12.2974 32758.6 33401.6 186.771 118.22 281.65 0.56497 0.1835 302
515.000 12.46065 O. i6868 2.235059 5.0139 34418.6 35140.9 190.244 133.76 464.23 0.59080 0.3012 233
520.000 6.93380 0.30021 1.229301 1.0159 39708.0 41006.0 201.557 151.28 1760.16 0.61983 0.7354 192
530.000 4.08829 0.49956 0.722024 7.6787 45198.9 47400.3 213.768 124.88 340.16 0.65805 0.8046 255
540.000 3.44446 0.58196 0.565183 12.4093 47521.3 50134.2 218.885 110.28 227.44 0.68743 0.7838 282
560.000 2.83383 0.68210 0.411932 19.4842 50643.0 53818.9 225.594 94.04 154.77 0.73390 0.7246 316
580.000 2.50098 0.74622 0.331326 25.0043 52993.4 56592.0 230.466 85.25 125.96 0.76902 0.6580 339
600.000 2.l.n79 U.791.U",5 U.2!sU41~ 2Y.6~8!S ~4993.2 58944.4 234.453 80.01 110.67 0.79699 0.5913 357
620.000 2.11238 0.82650 0.245075 33.7435 56798.4 61059.0 237.914 76.77 101.50 0.81977 0.5278 373
640.000 1. 98215 0.85328 0.219029 37.4189 58485.6 63026.2 241.039 74.76 95.64 0.83763 0.4695 386
660.000 1.87537 0.87453 0.199003 40.7841 60098.6 64897.7 243.920 73.56 91.78 0.85228 0.4167 398
680.000 1.78522 0.89167 0.183105 43.9053 61664.3 66705.7 246.620 72.91 89.20 0.86441 0.3696 409
100.000 1.70742 0.90:567 0.170161 46.8297 632UU.3 68471.4 249.179 72.65 87.49 0.87453 0.3278 419
720.000 1.63910 0.91721 0.159405 49.5920 64718.7 70209.5 251.628 72.67 86.40 0.88306 0.2909 428
740.000 1.57829 0.92680 0.150310 52.2187 66228.0 71930.4 253.986 72.90 85.75 0.89030 0.2583 437
760.000 1.52355 0.93483 0.142508 54.7307 67734.4 73641.6 256.268 73.27 85.42 0.89649 0.2296 446
780.000 1.47383 0.94159 0.135730 57.1444 69242.4 75348.9 258.485 73.76 85.34 0.90182 0.2044 454
1500.000 1.421531 0.94731 0.129777 ::>9.4'/33 '/U7::>::>.3 77U:>6.4 260.647 74.34 85.44 0.90645 0.1821 461

J. Phys. Chern. Ref. Datat Vol. 16, No. 4t 1987

880 ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

T p Z BPIBT BPIBp E H S Cu Cp flP J1. W

K molll bar/K bar/(moI/I) J/mol J/mol J/(mol·K) J/(mol·K) J/(mol·K) Klbar mls
100.()()()()() bar
175.590 28.41686 0.24104 17.429123 544.8225 -69.5 282.4 89.583 59.05 71.17 0.00000 -0.0397 1431
180.000 28.27648 0.23630 17.022775 537.3614 272.3 625.9 91. 348 58.91 71.05 0.00000 -0.0397 1422
190.000 27.96306 0.22637 16.165438 521.2189 1027.8 1385.4 95.180 58.67 70.85 0.00000 -0.0398 1401
200.000 27.65598 0.21744 15.386548 505.9261 1762.1 2123.7 98.808 58.58 70.82 0.00000 -0.0398 1381
210.000 27.35460 0.20937 14.675166 491.2405 2482.0 2847.6 102.264 58.68 70.99 0.00000 -0.0397 1361
220.000 27.05829 0.20204 14.022267 476.9585 3194.0 3563.6 105.575 58.99 71.37 0.00001 -0.0394 1342
210.000 26.7/i/i~9 0.19S1/i 13.,n0320 <162.9092 3903 9 <1277.5 108.762 59.49 71.98 0.00002. -0.0390 1322
240.000 26,47824 0.18926 12.862979 448.9492 4617.0 4994.6 111.846 60.19 72.80 0.00004 -0.0384 1301
250.000 26.19313 0.18367 12.344846 434.9598 5337.7 5719.5 114.842 61.06 73.83 0.00010 -0.0377 1281
260.000 25.91037 0.17853 11.861291 420.8441 6070.0 6455.9 117.763 62.09 75.03 0.00019 -0.0369 1259
270.000 25.62919 0.17381 11.408291 406.5252 6816.9 7207.1 120.621 63.24 76.40 0.00038 -0.0360 1238
280.000 25.34884 0.16945 10.982357 391.9462 7580.8 7975.3 123.426 64.48 77 .89 0.00069 -0.0350 1215
290.000 25.06852 0.16544 10.580394 377.0666 8363.3 8762.2 126.185 65.79 79.49 0.00121 -0.0339 1192
300.000 24.78736 0.16174 10.199650 361.8622 9165.5 9569.0 128.905 67.13 81.17 0.00204 -0.0327 1168
310.000 24.50448 0.15833 9.837652 346.3240 9987.8 10395.9 131. 592 68.50 82.93 0.00330 -0.0315 1143
320.000 24.21891 0.15519 9.492151 330.4566 10830.1 11243.0 134.251 69.86 84.74 0.00517 -0.0302 1118
330.000 23.92963 0.15230 9.161078 31-1.2763 11691. 8 12109.7 136.885 71.21 86.60 0.00785 -0.0289 1092
340.000 23.63553 0.14966 8.842502 297.8105 12572.2 12995.3 139.498 72.53 88.51 0.01159 -0.0274 1064
350.000 23.33537 0.14726 8.534600 281.0951 13470.1 13898.7 142.093 73.82 90.47 0.01664 -0.0258 1036
360.000 23.02781 0.14508 8.235617 264.1731 14384.7 14819.0 144.672 75.06 92.49 0.02329 -0.0241 1007
370.000 22.71133 0.14313 7.943841 247.0931 15315.1 15755.4 147.237 76.25 94.57 0.03184 -0.0222 977
380.000 22.38422 0.14140 7.657562 229.9072 16260.8 16707.5 149.790 77.38 96.72 0.04258 -0.0201 947
390.000 22.04448 0.13989 7.375040 212.6692 17221.8 17675.4 152.334 78.44 98.96 0.05578 -0.0177 915
400.000 21.68981 0.13863 7.094454 195.4330 18198.9 18659.9 154.871 79.42 101.31 0.07170 -0.0150 882
410.000 21.31745 0.13761 6.813865 178.2520 19193.9 19663.0 157.403 80.29 103.79 0.09057 -0.0120 848
420.000 20.92406 0.13686 6.531125 161.1763 20209.8 20687.7 159.934 81.05 106.43 0.11263 -0.0084 812
430.000 lO.50547 0.136>10 6.2>13792 1>1>1.2530 21251. 3 21739.0 162.469 81.67 109.30 0.13815 0.0041 776
440.000 20.05638 0.13629 5.948988 127.5247 22325.0 22823.6 165.015 82.15 112.51 0.16745 0.0010 738
450.000 19.56978 0.13657 5.643191 111.0293 23439.9 23950.9 167.581 82.52 116.22 0.20096 0.0074 698
460.000 19.03609 0.13735 5.321897 94.8000 24608.1 25133.4 170.183 82.87 120.79 0.23926 0.0155 656
470.000 18.44146 0.13876 4.979047 78.8661 25846.0 26388.2 172.844 83.40 126.85 0.28311 0.0260 611
480.000 17.76458 0.14105 4.605968 63.2551 27176.8 27739.7 175.603 84.59 135.61 0.33336 0.0402 562
490.000 16.96951 0.14464 4.189201 47.9989 28635.9 29225.2 178.532 87.47 149.69 0.39067 0.0598 506
500.000 15.98664 0.15047 3.705286 33.1516 30288.4 30913.9 181.784 94.61 175.63 0.45442 0.0889 438
510.000 14.64550 0.16102 3.104954 18.8588 32314.7 32997.5 185.842 115.27 236.82 0.51690 0.1365 347
515.000 13.68816 0.17061 2.725002 12.0716 33573.8 34304.3 188.472 127.39 296.47 0.54125 0.1846 296
520.000 12.2<1182 0.18894 2.240221 5.8697 35228.-1 36045.3 191.830 119.26 425.93 0.57055 0.2917 245
530.000 6.09756 0.37216 1.094676 3.1115 42163.5 43803.5 206.594 136.36 685.35 0.62048 0.7078 220
540.000 4.40804 0.50527 0.759048 8.5846 45881.0 48149.6 214.731 118.45 304.97 0.65537 0;7314 262
560.000 3.38954 0.63363 0.516836 16.6041 49698.4 52648.6 222.926 98.76 177.17 0.70813 0.6898 304
580.000 2.92152 0.70978 0.404293 22.6227 52318.6 55741.5 228.360 88.43 137.53 0.74744 0.6341 331
600.000 2.62738 0.76294 0.336612 27.6076 54471.3 58277.4 232.659 82.32 117.99 0.77864 0.5756 351
620.000 2.41709 0.80256 0.290894 31.9401 56377.2 60514.4 236.322 78.52 106.63 0.80400 0.5184 367
640.000 2.25541 0.83322 0.257791 35.8154 58136.5 62570.3 239.587 76.13 99.47 0.82400 0.4646 382
660.000 2; 12508 0.85752 0.232657 39.3490 59803.7 64509.5 242.572 74.66 94.76 0.84042 0.4153 394
680.000 2.01647 0.87713 0.212897 42.6163 61411. 7 66370.9 245.352 73.81 91.59 0.85402 0.3707 406
700.000 1.92371 0.89316 0.19693<1 45.6699 62981.6 68179.9 247.97<1 73.39 89_45 0.86538 0.3307 416
720.000 1.84295 0.90640 0.183755 48.5478 64527.7 69953.8 250.474 73.29 88.04 0.87496 0.2951 426
740.000 1. 77158 0.91743 0.172676 51.2792 66060.0 71704.7 252.873 73.42 87.13 0.88309 0.2634 435
760.000 1. 70773 0.92668 0.163219 53.8863 67585.8 73441.5 255.189 73.72 86.60 0.89003 0.2353 444
780.000 1.65003 0.93450 0.155041 56.3870 69110.2 75170.7 257.435 74.15 86.36 0.89601 0.2104 452
800.000 1.59745 0.94113 0.147888 58.7958 70637.3 76897.3 259.620 74.67 86.33 0.90120 0.1883 460

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 881

Table 17. Properties of methanol along isobars - Continued

T Z aPiaT aPlaf' E H S Cv Cp [IP J1. W

K molil bar/K bar/(mol/I) J/mol limol J/(mol·K) J/(mol·K) J/(mol·K) K/bar mls
120.00000 bar
175.590 28.45331 0.28888 17.614181 552.5914 -82.9 338.9 89.504 59.00 71.17 0.00000 -0.0397 1442
180.000 28.31343 0.28319 17.203836 545.0448 258.6 682.4 91.269 58.85 71.05 0.00000 -0.0397 1432
190.000 28.00116 0.27128 16.338255 528.7389 1013.3 1441.9 95.101 58.61 70.85 0.00000 -0.0398 1412
200.000 27.69523 0.26056 15.552073 513.3194 1746.8 2180.1 98.729 58.53 70.81 0.00000 -0.0398 1392
210.000 27.39501 0.25087 14.834198 498.5389 2465.9 2903.9 102.184 58.63 70.98 0.00000 -0.0397 1372
220.000 27.09991 0.24208 14.175524 484.1917 3177 .0 3619.8 105.495 58.93 71.36 0.00001 -0.0394 1352
230.000 26.80926 0.23406 13.568424 470.1035 3886.0 4333.6 108.682 59.43 71.96 0.00002 -0.0390 1332
240.000 26.52243 0.22674 13.006485 456.1282 4598.1 5050.6 1il.765 60.13 72.78 0.00004 -0.0384 1312
250.000 26.23874 0.22002 12.484255 442.1446 5317.8 5775.2 114.760 61.00 73.80 0.00008 -0.0377 1292
260.000 25.95748 0.21385 11.997059 428.0536 6049.0 6511. 3 117.680 62.03 75.00 0.00017 -0.0369 1270
270.000 25.67795 0.20817 11 .540848 413.7760 6794.7 7262.1 120.536 63.17 76.35 0.00032 -0.0360 1249
280.000 25.39940 0.20294 11.112103 399.2523 7557.4 8029.8 123.339 64.41 77 .83 0.00059 -0.0351 1227
290.000 25.12104 0.19811 10.707715 384.4399 8338.5 8816.2 126.096 65.72 79.42 0.00104 -0.0340 1204
300.000 24.84207 0.19366 10.324925 369.3125 9139.2 9622.2 128.814 67.06 81.09 0.00175 -0.0329 1180
310.000 24.56160 0.18955 9.961256 353.8589 9959.8 10448.3 131.498 68.42 82.83 D.00284 -0.0317 1156
320.000 24.27874 0.18577 9.614466 338.0817 10800.1 11294.4 134.154 69.78 84.63 0.00445 -0.0304 1131
330.000 23.99250 0.18229 9.282498 321.9957 11G59.7 12159.9 136.784 71.13 86.47 0.00675 0.0291 1105
340.000 23.70181 0.17910 8.963443 305.6263 12537.6 13043.9 139.393 72.44 88.35 0.00995 -0.0277 1078
350.000 23.40553 0.17618 8.655509 289.0085 13432.9 13945.6 141.983 73.72 90.28 0.01428 -0.0261 1050
360.000 23.10239 0.17353 8.356982 272.1844 14344.4 14863.8 144.556 74.95 92.26 0.01998 -0.0245 1022
370.000 22.79097 0.17115 8.066206 255.2022 15271.3 15797.8 147.114 76.13 94.29 0.02731 -0.0227 993
350.000 22.46968 0.16903 7.781544 238.1139 16212.8 16746.9 149.659 77.25 96.39 0.03650 -0.0207 962
390.000 22.13673 0.16717 7.501350 220.9741 17169.0 17711.1 152.194 78.30 98.57 0.04780 -0.0184 931
400.000 21. 79000 0.16559 7.223931 203.8381 18140.5 18691.2 154.719 79.26 100.83 0.06143 -0.0159 899
410.000 21.42704 0.16429 6.947510 186.7611 19128.8 19688.8 157.238 80.11 103.19 0.07758 -0.0130 866
420.000 2i.04492 0.16329 6.670167 169.7963 20136.7 20706.9 159.753 80.84 105.69 0.09646 -0.0097 832
430.000 20.64005 0.16262 6.389770 152.9947 21168.5 21749.9 162.268 81.43 108.36 0.11830 -0.0058 797
440.000 20.20796 0.16232 6.103884 136.4042 22230.0 22823.8 164.789 81. 87 111. 30 0.14338 -0.0011 760
450.000 19.74291 0.16245 5.809630 120.0700 23329.4 23937.2 167.325 82.18 114.63 0.17208 0.0045 722
460.000 19.23734 0.16310 5.503491 104.0346 24477.3 25101.1 169.886 82.44 118.63 0.20491 0.0116 683
470.000 18.68082 0.16438 5.180991 88.3407 25687.7 26330.1 172 .491 82.85 123.77 0.24252 0.0206 641
480.000 18.05835 0.16650 4.836182 73.0341 26979.3 27643.8 175.171 83.85 130.99 0.28568 0.0321 596
490.000 17.34693 0.16980 4.460740 58.1734 28378.3 29070.1 177.978 86.41 142.11 0.33501 0.0473 546
500.000 16.50821 0.17485 4.042263 43.8490 29927.5 30654.4 181.019 92.93 161.30 0.39006 0.0673 487
510.000 15.47047 0.18292 3.560832 30.2361 31736.9 32512.6 184.631 112.17 201.53 0.44444 0.0925 411
515.000 14.83394 0.18892 3.286580 23.8087 32765.9 33574.9 186.784 122.67 228.85 0.46601 0.1117 372
520.000 14.07427 0.19720 2.981895 17.7593 33920.0 34772.7 189.093 120.90 252.33 0.49229 0.1465 340
530.000 11.87753 0.22927 2.252007 7.7544 36747.7 37758.0 194.777 121.23 366.94 0.54324 0.2744 270
540.000 8.27636 0.32293 1.470372 4.1300 41044.4 42494.3 203.627 125.03 537.72 0.58921 0.4995 235
560.000 4.85028 0.53136 0.806397 11.2352 47469.6 49943.7 217.208 107.17 244.95 0.65657 0.6133 283
580.000 3.90430 0.63734 0.587884 18.3175 50833.0 53906.6 224.172 94.22 166.01 0.70457 0.5813 317
600.000 3.40495 0.70645 0.471870 24.0192 53350.1 56874.4 229.199 86.54 134.51 0.74252 0.5375 341
620.000 3.07666 0.75661 0.398249 28.8656 55481.3 59381.6 233.307 81.73 117.72 0.77287 0.4915 360
640.000 2.83674 0.79496 0.346941 33.1374 57396.2 61626.5 236.873 78.65 107.54 0.79701 0.4465 376
660.000 2;64995 0.82521 0.308995 36.9939 59178.4 63706.8 240.076 76.69 100.94 0.81688 0.4039 389
680.000 2.49825 0.84957 0.279735 40.5341 60875.0 65678.4 243.021 75.47 96.50 0.83339 0.3644 402
700.000 2.37125 0.86950 0.256455 43.8244 62515.4 67576.0 245.772 74.77 93.46 0.84722 0.3283 413
720.000 2.26246 0.88600 0.237471 46.9117 64118.9 69422.8 248.374 74.45 91.36 0.85890 0.2956 423
740.000 2.16759 0.89978 0.221680 49.8306 65698.7 71234.8 ~50.857 74.40 89.94 0.86882 0.2661 433
760.000 2.08368 0.91138 0.208325 52.6074 67264.4 73023.5 253.243 74.56 89.00 0.87730 0.2396 442
780.000 2.00859 0.92121 0.196871 55.2628 68822.8 74797.2 255.546 74.87 88.43 0.88460 0.2159 451
800.000 1.94073 0.92959 0.186928 57.8134 70379.1 76562.3 257.781 75.29 88.13 0.89093 0.1946 459

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

882 ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

T p Z aPlaT apia!, E H S Cv Cp j/P J1 W

K molll bar/K bar/(mollJ) J/mol J/mol J/(mol·K) J/(mol·K) J!(mol·K) K/bar mls
150.00000 bar
175.590 28.50705 0.36042 17.879908 563.9155 -102.6 423.6 89.387 58.93 71.18 0.00000 -0.0397 1457
180.000 28.36791 0.35331 17.463822 556.2419 238.3 767.1 91.151 58.78 71.05 0.00000 -0.0397 1448
190.000 28.05732 0.33842 16.586344 539.6915 991. 9 1526.5 94 . .983 58.54 70.84 0.00000 -0.0398 1427
200.000 27.75306 0.32502 15.789621 524.0810 1724.2 2264.7 98.611 58.46 70.81 0.00000 -0.0398 1407
210.000 27.45455 0.31291 15.062389 509.1584 2442.1 2988.5 102.066 58.55 70.97 0.00000 -0.0397 1387
220.000 27.16120 0.30191 14.395362 494.7119 3152.0 3704.2 105.376 58.85 71.35 0.00001 -0.0394 1368
230.000 26.87238 0.29189 13.780799 480.5633 3859.7 4417.8 108.562 59.36 71.94 0.00001 -0.0390 1348
240.000 26 .~HI74Ci 0.215273 13.2121156 466.j627 4j70.3 :5134.:5 111.644 60.0:5 72.7j 0.00003 -0.035:5 1325
250.000 26.30580 0.27432 12.683993 452.5852 5288.6 5858.8 114.637 60.92 73.76 0.00007 -0.0378 1307
260.000 26.02672 0.26660 12.191485 438.5283 6018.2 6594.5 117.556 61.94 74.95 0.00014 -0.0370 1286
270.000 25.74954 0.25949 11.730572 424.3097 6762.2 7344.7 120.410 63.09 76.29 0.00027 -0.0361 1265
280.000 25.47355 0.25293 11.297680 409.8658 7522.9 8111. 8 123.211 64.32 77.76 0.00050 -0.0352 1243
290.000 25.19800 0.24688 10.889691 395.1512 8302.1 8897.3 125.965 65.62 79.33 0.00088 -0.0342 1220
300.000 24.92212 0.24130 10.503826 380.1363 9100.5 9702.4 128.679 66.97 80.98 0.00147 -0.0331 1197
310.000 24.64509 0.23614 10.137603 364.8066 9918.7 10527.3 131. 360 68.32 82.70 0.00238 -0.0319 1173
320.000 24.36605 0.23138 9.788783 349.1617 10756.3 11371.9 134.011 69.68 84.47 0.00373 -0.0307 1149
330.000 24.08407 0.22699 9.455323 333.2135 11612.8 12235.7 136.636 71.01 86.28 0.00565 -0.0294 1124
J4U.UUU 2J.7Y818 0.222Y6 1}.135338 316.9851 12487.4 13117.7 139.238 72.32 88.13 0.00832 -0.0280 1097
350.000 23.50731 0.21927 8.827069 300.5093 13378.8 14016.9 141.821 73.59 90.01 0.01194 -0.0266 1071
360.000 23.21030 0.21591 8.528854 283.8266 14286.0 14932.2 144.386 74.82 91.94 0.01669 -0.0250 1043
370.000 22.90587 0.21287 8.239100 266.9840 15207.8 15862.7 146.934 75.98 93.91 0.02280 -0.0233 1014
380.000 22.59260 0.21014 7.956254 250.0333 16143.7 16807.6 149.469 77 .09 95.94 0.03046 -0.0214 985
390.000 22.26889 0.20773 7.678780 233.0291 17093.3 17766.9 151.990 78.12 98.02 0.03987 -0.0194 955
400.000 21.93291 0.20564 7.405129 216.0281 18057.0 18740.9 154.500 79.06 100.16 0.05121 -0.0171 924
410.000 21.58256 0.20388 7.133705 199.0869 19036.3 19731.3 157.001 79.89 102.39 0.06465 -0.0144 892
420.000 21.21538 0.20247 6.862837 182.2619 20033.4 20740.4 159.495 80.58 104.70 0.08037 -0;0115 859
430.000 20.82842 0.20143 6.590722 165.6076 21052.1 21772.3 161.984 81.13 107.13 0.09855 -0.0080 826
440.000 20.41812 0.20081 6.315375 149.1772 22097.7 22832.3 164.473 81.52 109.74 0.11943 -0.0039 791
450.000 19.98009 0.20065 6.034550 133.0218 23177.3 23928.0 166.969 81.76 112.62 0.14334 0.0010 756
460.000 19.50872 0.20103 5.745641 117.1919 24300.0 25068.9 169.479 81.94 115.98 0.17070 0.0069 719
470.000 18.99676 0.20206 5.445538 101. 7394 25477.4 26267.0 172.018 82.22 120.18 0.20208 0.0142 681
480.000 18.43445 0.20388 5.130422 86.7207 26724.4 27538.0 174.608 83.04 125.91 0.23815 0.0233 640
490.000 17.80819 0.20675 4.795478 72.2044 28059.9 28902.3 177.287 85.32 134.53 0.27947 0.0345 596
500.000 17.09817 0.21103 4.434473 58.2843 29513.0 30390.3 180.133 91.39 149.09 0.32573 0.0480 544
510.000 16.27398 0.21737 4.039225 45.1055 31162.2 32083.9 183.420 109.81 179.46 0.37174 0.0618 479
515.000 15.80477 0.22165 3.825554 38.8659 32065.0 33014.1 185~316 119.63 197.26 0.39022 0.0708 447
520.000 15.28632 0.22696 3.599210 32.9190 33035.7 34017.0 187.248 116.84 204.41 0.41283 0.0870 423
530.000 14.05182 0.24224 3.103003 22.1953 35104.6 36172 .1 191.353 112.99 229.44 0.45774 0.1325 375
540.000 12.44034 0.26855 2.549385 13.8105 37471.4 38677.1 196.037 111.48 275.68 0.50187 0.2045 326
560.000 8.29275 0.38848 1.516732 8.2706 43369.0 45177.8 207.850 110.16 336.66 0.58166 0.4078 280
580.000 5.85181 0.53154 0.987548 13.1985 48226.4 50789.7 217.709 100.20 225.35 0.64249 0.4865 304
600.000 4.79149 0.62753 0.743385 19.5885 51481.9 54612.5 224.187 91.49 165.21 0.68977 0.4740 332
620.000 4.19102 0.69430 0.603843 25.2137 54022.4 57601.5 229.078 85.67 136.71 0.72795 0.4438 354
640.000 3.78832 0.74410 0.512474 30.1215 56202.2 60161.7 233.154 81. 81 120.69 0.75730 0.4099 372
660.000 3.49162 0.78286 0.447614 34.4886 58172.5 62468.5 236.706 79.26 110.71 0.78213 0.3759 387
680.000 3.25977 0.81388 0.399041 38.4471 60010.7 64612.3 239.908 77.60 104.10 0.80285 0.3433 401
700.000 3.07117 0.83918 0.361238 42.0879 61762.1 66646.3 242.857 76.56 99.57 0.82028 0.3127 413
nu.uuu 2.':.11321 0.86010 U.330':.l48 45.4753 63455.2 68604.1 245.616 75.':.17 96.40 0.83505 U.2844 424
740.000 2.77795 0.87760 0.306113 48.6555 65108.8 70508.5 248.226 75.70 94.17 0.84763 0.2584 434
760.000 2.66010 0.89237 0.285365 51.6632 66736.5 72375.3 250.715 75.68 92.61 0.85842 0.2347 444
780.000 2.55598 0.90491 0.267759 54.5248 68347.5 74216.1 253.106 75.84 91.54 0.86772 0.2131 453
800.000 2.46292 0.91562 0.252622 57.2613 69949.0 76039.3 255.415 76.14 90.84 0.87578 0.1935 461

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 883

Table 17. Properties of methanol along isobars - Can ti n ued

T Z .J1'/i)T ()P/,J" E 11 S Cv CI, liP JL W

K mol/l barlK bar/(mall!) J/mol J/mol J/(mo!·K) J/(mo!·K) J/(mo!·K) K/bar m/s

200.00000 bur
175.590 28.59431 0.41909 18.295887 582.0513 ·134.8 564.7 89.193 58.83 71.18
180.000 28 .15637 () 469"1 17.R70770 'i74. 1 f,7'i ?:O'i.4 90R.2 90.9'58 58.68 71.05 0.00000 -0.0397 1472
190.000 28.14848 0.44976 16.974561 557.2099 957.1 1661.7 94.790 58.44 10.84 0.00000 -0.0398 1451
200.000 21.84692 0.43190 16.161243 541.2801 1687.6 2405.8 98.417 58.35 70.80 0.00000 -0.0398 1431
210.000 21.55114 0.41575 15.419235 526.1169 2403.5 3129.4 101.811 58.45 70.95 0.00000 -0.0397 1411
220.000 27.26058 0.40108 14.738996 511.4998 3111. 3 3845.0 105.180 58.75 71.32 0.00000 -0.0395 1392
230.000 26.97464 0.38771 14.112606 497.2445 3816.9 4558.3 108.365 59.25 71. 91 0.00001 -0.0391 1372
240.000 26.69274 0.37548 13.533392 483.1946 4525.3 5274.6 111.445 59.94 72.71 0.00003 -0.0385 1352
250.000 26.41427 0.36426 12.995698 469.2196 5241.2 5998.4 114.437 60.81 73.71 0.00006 -0.0379 1332
260.000 26.13860 0.35395 12.494689 455.2113 5968.3 6733.4 117.353 61.83 74.88 0.00012 -0.0371 1311
270.000 25.86509 0.34444 12.026197 441.0822 6709.6 7482.8 120.204 62.97 76.20 0.00022 -0.0363 1290
280.000 25.59308 0.33567 11.586599 426.7635 7467.4 8248.9 123.001 64.20 77.65 0.00041 -0.0354 1269
290.000 25.32186 0.32757 11.172715 412.2037 8243.4 9033.2 125.751 65.50 79.19 0.0007] -0.0344 1247
300.000 25.05073 0.32008 10.781748 397.3682 9038.3 9836.7 128.460 66.83 80.82 0.00120 -0.0333 1224
310.000 24.77895 0.3]315 10.411200 382.2374 9852.7 10659.8 131.135 68.18 82.50 0.00193 -0.0322 1201
320.000 24.50571 0.30674 1(). 058826 366.8054 10686.1 11502.2 133.778 69.53 84.23 0.00302 -0.0311 1177
330.000 24.23021 0.30083 9.722596 351.0795 11538.0 12363. ~ 136.396 70.S6 86.00 0.00-157 -0.0299 1153
340.000 23.95154 0.29538 9.400M8 335.0782 12407.3 13242.3 138.989 72.16 87.79 0.00672 -0.0286 1127
350.000 23.66878 0.29037 9.091262 318.8303 13292.9 14137.9 141.561 73.42 89.61 0.00963 -0.0273 1102
360.000 23.38090 0.28578 8.792832 302.3731 14193.4 15048.8 144.113 74.63 91.47 0.01345 -0.0258 1075
370.000 23.08681 0.28160 8.503839 285.7509 15107.8 15974.1 146.648 75.78 93.35 0.01835 -0.0243 1048
J80.00() 22.78529 0.27782 8.222826 269.0136 16035.2 16912.9 149.166 76.87 95.27 0.02449 0.0226 1020
390.000 22.47501 0.27443 7.948383 252.2151 16975.0 17864.9 151.668 77.88 97.22 0.03203 -0.0207 991
400.000 22.15448 0.27144 7.679119 235.4121 17927.4 18830.2 154.156 78.79 99.21 0.04112 -0.0187 961
410.000 21.82201 0.26885 7.413644 218.6626 18893.5 19810.0 156.631 79.59 101.24 0.05188 -0.0164 931
420.000 21.47570 0.26668 7.150544 202.0247 19875.2 20806.5 159.094 80.26 103.30 0.06446 -0.0139 900
430.000 21.11333 0.26495 6.888355 185.5563 20875.6 21822.9 161.547 80.76 105.42 0.07901 -0.0110 869
440.000 20.73231 0.26369 6.625537 169.3144 21899.3 22864.0 163.993 81.09 107.63 0.09572 -0.0076 837
450.000 20.32959 0.26294 6.3604·39 153.3552 22952.3 23936. J 166.435 81.26 109.99 0.11487 -0.0037 804
460.000 19.90146 0.26276 6.091254 137.7344 24042.2 25047.2 168.881 81.34 112.63 0.13680 0.0010 771
470.000 19.44343 0.26322 5.815981 122.5088 25178.5 26207.2 171.338 81.51 115.83 0.16199 0.0066 737
480.000 18.9-1990 0.26445 5.532363 107.7384 26372.6 27428.0 173.8::12 82.16 120.13 0.19099 0.0132 701
490.000 18.41377 0.26660 5.237837 93.4907 27638.4 28724.5 176.361 84.21 126.61 0.22429 0.0211 662
500.000 17.82595 0.26988 4.929486 79.8464 28996.0 30118.0 179.017 89.94 137.83 0.26171 0.0298 617
510.000 17.17451 0.27462 4.604048 66.9102 30509.1 31673.6 182.030 107.85 162.62 0.29914 0.0374 561
515.000 16.82022 0.27769 4.433842 60.7502 31320.4 32509.5 183.742 117.31 176.22 0.31434 0.0417 533
520.000 16. ·14382 0.28131 -1.258083 5-1.8253 32177. ·1 33393.7 185.-1-15 11-1.07 177.67 0.33298 0.0498 516
530.000 15.61362 0.29068 3.888558 43.7965 33916.9 35197.9 188.881 108.87 183.93 0.37049 0.0701 480
540.000 14.65956 0.30386 3.494418 34.1148 35724.3 37088.6 192.419 105.15 195.09 0.40831 0.0970 444
560.000 12.31144 0.34890 2.659964 20.3187 39696.1 41320.6 200.110 101.10 229.76 0.48330 0.1752 379
580.000 9.66978 0.42889 1.908451 15.4554 44086.9 46155.2 208.592 98.60 244.78 0.55179 0.2707 346
600.000 7.62881 0.52552 1.392613 17.3210 48120.5 50742.1 216.362 94.19 209.62 0.61027 0.3329 346
620~000 6.35885 0.61013 1.077552 21.7876 51385.0 54530.2 222.559 89.23 170.95 0.65907 0.3516 360
640.000 5.55547 0.67654 0.879448 26.9523 54066.4 57666.4 227.552 85.19 144.70 0.69714 0.3432 377-
660.000 5.00422 0.72831 0.745735 31.9464 56385.7 60382.4 231.734 82.25 128.13 0.72934 0.3242 394
680.000 4.59746 0.76943 0.649647 36.5696 58479.3 62829.5 235.393 80.20 117.33 0.75615 0.3017 408
700.000 4.:28079 0.80273 0.5772-13 -10.8230 60-126.2 65098.2 n8.68) 78.S) 110.00 0.77908 0.2787 ~)1
720.000 4.02447 0.83014 0.520694 44.7523 62274.3 67243.9 241.706 77 .93 104.87 0.79861 0.2563 433
740.000 3.810M 0.85298 0.475282 48.4068 64054.3 69302.5 244.527 77 .42 101.20 0.81534 0.2351 444
760.000 3.62876 0.87221 0.437995 51.8292 65787.1 71298.6 247.189 77 .19 98.55 0.82975 0.2153 454
780.000 3.47078 0.88853 0.406821 55.0550 67487.1 73249.5 249.723 77 .18 96.64 0.84222 0.1970 463
800.000 3.33174 {).902~7 0.380359 58.1127 69161.9 75167.8 252.152 77.33 95.27 0.85305 0.1801 472

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

1111·1 ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

T Z op/aT oP/op E H S Cv Cp flP J1. W

K molll bar/K bar/(molll) limo} llmol ll(mol·K) ll(mo}·K) J/(mo}·K) K/bar m/s
250.00000 bar
175.590 28.67895 0.59709 18.684114 599.4411 -166.0 705.8 89.002 58.75 71.18 0.00000 -0.0396 1505
180.000 28.54217 0.58525 18.250526 591.3469 173.4 1049.3 90.767 58.60 71.05 0.00000 -0.0397 1495
190.000 28.23688 0.56045 17.336742 573.9804 923.4 1808.8 94.599 58.36 70.84 0.00000 -0.0398 1474
200.000 27.93791 0.53812 16.507814 557.7275 1652.0 2546.8 98.226 58.27 70.79 0.00000 -0.0398 1454
210.000 27.64473 0.51793 15.7518.81 542.3172 2366.0 3270.4 101.680 58.37 70.94 0.00000 -0.0397 1434
220.000 27.35682 0.49959 15.059189 527.5225 3071.9 3985.8 104.988 58.66 71.30 0.00000 -0.0395 1414
230.000 27.07361 0.48287 14.421619 513.1517 3775.4 4698.8 108.172 59.16 71.88 0.00001 -0.0391 1394
240.000 26.79455 0.46757 13.832356 499.0428 4481.8 5414.8 111.251 59.85 72.67 0.00002 -0.0386 1375
250.000 26.51906 0.45353 13.285627 485.0599 5195.4 6138.1 114.240 60.72 73.66 0.00005 -0.0380 1355
260.000 26.24656 0.44061 12.776503 471.0896 5920.1 6872.6 117.154 61.74 74.81 0.00010 -0.0372 1334
270.000 25.97643 0.42871 . 12.300738 457.0391 6658.9 7621.3 120.003 62.87 76.12 0.00019 -0.0364 1314
280.000 25.70807 0.41771 11.854652 442.8345 7414.0 8386.4 122.796 64.10 77 .55 0.00036 -0.0355 1293
290.000 25.44082 0.40754 11.435025 428.4195 8187.0 9169.6 125.542 65.40 79.07 0.00062 -0.0346 1271
300.000 25.17402 0.39813 11.039015 413.7536 8978.8 9971.8 128.247 66.73 80.67 0.00104 -0.0336 1249
310.000 24.90698 0.38942 10.664113 398.8123 9789.6 10793.3 130.916 68.08 82.32 0.00167 -0.0325 1226
320.000 24.63898 0.38136 10.308063 383.5846 10619.1 11633.8 133.554 69.42 84.02 0.00261 -0.0314 1203
330.000 24.36926 0.37389 9.968833 368.0729 11466.8 12492.6 136.164 70.74 85.74 0.00394 -0.0303 1179
340.000 24.09703 0.36700 9.644575 352.2909 12331.4 13368.8 138.749 72.03 87.49 0.00579 -0.0291 1155
350.000 23.82143 0.36064 9.333591 336.2630 13211.7 14261.1 141.311 73.28 89.26 0.00828 -0.0278 1130
360.000 23.54158 0.35479 9.034310 320.0227 14106.3 15168.3 143.853 74.49 91.05 0.01155 -0.0265 1104
370.000 23.25649 0.34943 8.745258 303.6111 15014.1 16089.0 146.375 75.63 92.86 0.01575 -0.0251 1078
380.000 22.96513 0.34455 8.465044 287.0754 15933.9 17022.5 148.879 76.70 94.69 0.02100 -0.0235 1051
390.000 .22.66635 0.34014 8.192337 270.4678 16865.2 17968.2 151.365 77.70 96.54 0.02744 -0.0219 1024
400.000 22.35890 0.33620 7.925846 253.8435 17807.9 18926.0 153.834 78.60 98.40 0.03519 -0.0201 995
410.000 22.04140 0.33272 7.664309 237.2603 18762.8 19897.0 156.287 79.38 100.27 0.04437 -0.0181 967
420.000 21.71229 0.32972 7.406471 220.7767 19731.5 20882.9 158.725 80.01 102.15 0.05510 -0.0158 937
430.000 21.36984 0.32722 7.151068 204.4516 20716.8 21886.7 161.148 80.49 104.04 0.06751 -0.0133 908
440.000 21.01205 0.32522 6.896813 188.3435 21722.7 22912.5 163.559 80.78 105.95 0.08176 -0.0105 878
450.000 20.63666 0.32378 6.642371 172.5102 22754.6 23966 .1 165.960 80.91 107.94 0.09809 -0.0072 847
460.000 20.24102 0.32293 6.386346 157.0090 23819.3 25054.4 168.355 80.94 110.10 0.11681 -0.0034 816
470.000 19.82204 0.32274 6.127263 141.8979 24924.9 26186.1 170.751 81.03 112,68 0.13832 0.0011 784
480.000 19.37608 0.32329 5.863544 127.2363 26081.2 27371.5 173.161 81.59 116.14 0.16311 0.0063 751
490.000 18.89878 0.32469 5.593507 113.0873 27299.9 28622.7 175.606 83.53 121.48 0.19163 0.0123 716
500.000 18.38494 0.32709 5.315364 99.5212 28597.6 29957.4 178.143 89.11 131.10 0.22374 0.0188 675
510.000 17.82832 0.33069 5.027268 86.6201 30032.9 31435.1 181.003 106.80 153.62 0.25598 0.0241 623
515.000 17.53170 0.33302 4.878920 80.4493 30796.4 32222.4 182.620 116.14 165.71 0.26915 0.0269 598
520.000 17.22151 0.33576 4.727422 74.4840 31598.0 33049.6 184.212 112.74 165.35 0.28531 0.0322 583
530.000 16.55592 0.34267 4.414327 63.2388 33197.8 34707.8 187.371 107.14 166.73 0.31802 0.0447 554
540.000 15.82235 0.35192 4.087277 53.0435 34813.0 36393.1 190.525 102.87 170.80 0.35137 0.0603 524
560.000 14.12273 0.38019 3.398073 36.5956 38176.7 39946.9 196.985 97.28 185.87 0.41920 0.1022 467
580.000 12.15169 0.42662 2.708041 26.5917 41784.6 43841.9 203.818 94.25 202.57 0.48516 0.1568 422
600.000 10.18379 0.49209 2.108757 23.0461 45486.8 47941.6 210.759 91.93 203.56 0.54638 0.2118 399
620.000 8.57829 0.56534 1.657569 24.1903 48932.6 51846.9 217.146 89.17 184.87 0.60079 0.2492 395
640.000 7.41731 0.63340 1. 341257 27.5268 51943.2 55313.7 222.661 86.24 162.27 0.64541 0.2662 402
660.000 6.58683 0.69164 1.119501 31.7541 54569.9 58365.4 227.361 83.70 143.74 0.68365 0.2675 412
680.000 5.97605 0.73991 0.959898 36.2970 56912.2 61095.5 231.442 81.71 130.05 0.71591 0.2585 424
700.000 5.50929 0.77967 0.840983 40.7954 59055.3 63593.1 235.064 80.28 120.26 0.74365 0.2444 436
720.000 5.13935 0.81258 0.749411 45.0997 61059.7 65924.1 238.349 79.29 113.24 0.76743 0.2282 448
740.000 4.83702 0.84003 0.676873 49.1662 62966.7 68135.1 241.379 78.67 108.14 0.78791 0.2115 459
760.000 4.58373 0.86312 0.618046 52.9957 64804.5 70258.5 244.211 78.33 104.40 0.80561 0.1951 469
780.000 4.36721 0.88268 0.569398 56.6054 66593.0 72317.4 246.885 78.21 101.63 0.82099 0.1795 479
800.000 4.17905 0.89937 0.528504 60.0173 68346.3 74328.6 249.431 78.27 99.58 0.83439 0.1648 488

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 885

Table 17. Properties of methanol along isobars - Continued

T p Z oPloT oPlof' E H 5 Cv Cp liP IJ. W

K molll bar/K bar/(mollI) J/mo! J/mo! J/(mo!·K) J/(mol·K) J!(mol·K) K/bar m/s
bar
175.590 28.76121 0.71446 19.049619 616.2358 -196.2 846.8 88.814 58.68 71.18 0.00000 -0.0396 1527
l~U.UUU :l~.62:5:5:5 0.70026 18.608021 607.9302 142.4 1190.4 90.579 58 . .54 71.0.5 0.00000 -0.0397 1517
190.000 28.32278 0.67050 17.677600 590.1511 890.6 1949.8 94.411 58.30 70.84 0.00000 -0.0398 1496
200.000 28.02630 0.64371 16.833885 573.5693 1617.4 2687.9 98.038 58.21 70.79 0.00000 -0.0398 1475
210.000 27.73562 0.61948 16.064752 557.9052 2329.7 3411 .3 101.491 58.30 70.93 0.00000 -0.0397 1455
220.000 27.45023 0.59747 15.360226 542.9242 3033.7 4126.6 104.799 58.60 71.28 0.00000 -0.0395 1435
230.000 27.16962 0.57740 14.712017 528.4284 3735.3 4839.5 107;982 59.09 71.86 0.00001 -0.0391 1416
240.000 26.89323 0.55902 14.113172 514.2503 4439.6 5555.1 111.059 59.78 72.64 0.00002 -0.0387 1396
250.000 26.62055 0.54216 13 .557807 500.2486 5151.1 6278.1 114.047 60.65 73.61 0.00005 -0.0380 1376
260.000 26.35100 0.52664 13.040899 486.3050 5873.6 7012.1 116.959 61.66 74.76 0.00009 -0.0373 1356
270.000 26.08403 0.51233 12.558132 472.3219 6609.9 7760.1 119.805 62.80 76.05 0.00018 -0.0365 1336
280.000 25.81905 0.49910 12.105765 458.2204 7362.5 8524.4 122.596 64.03 77 .46 0.00032 -0.0357 1315
290.000 25.55545 0.48686 11.680533 443.9393 8132.7 9306.6 125.338 65.32 78.96 0.00056 -0.0348 1294
300.000 25.29261 0.47552 11 .279567 429.4332 8921.5 10107.6 128.039 66.64 80.54 0.00093 -0.0338 1272
310.000 25.02991 0.46501 10.900326 414.6724 9729.1 10927.6 130.703 67.99 82.17 0.00150 -0.0328 1250
320.000 24.76666 0.45527 10.540536 399.6405 10555.1 11766.4 133.336 69.33 83.83 0.00234 -0.0318 1228
330.000 24.50217 0.44624 10.198169 384.3354 11398.8 12623.2 135.939 70.65 85.52 0.00354 -0.0307 1204
340.000 24.23571 0.43788 9.871377 368.7660 12259.1 13496.9 138.517 71.93 87.23 0.00519 -0.0295 1181
350.000 23.96653 0.43014 9.558475 352.9520 13134.6 14386.4 141.071 73.18 88.95 0.00742 -0.0284 1157
360.000 23.69381 0.42301 9.257910 336.9229 14024.0 15290.1 143.604 74.37 90.69 0.01033 -0.0211 1132
370.000 23.41668 0.41645 8.968243 320.7159 14925.8 16206.9 146.115 75.51 92.43 0.01407 -0.0258 1106
380.000 23.13422 0.41044 8.688122 304.3754 15838.9 17135.7 148.606 76.58 94.18 0.01874 -0.0244 1080
390.000 22.84545 0.40497 8.416270 287.9506 16762.7 18075.9 151.078 77 .56 95.94 0.02447 -0.0229 1054
400.000 22.54929 0.40003 8.151465 271.4952 17696.9 19027.3 153.531 78.45 97.70 0.03136 -0.0212 1027
410.000 22.24456 0.39562 7.892527 255.0654 18642.0 19990.7 155.965 79.21 99.45 0.03951 -0.0194 999
420.000 21.92997 0.39174 7.638305 238.7192 19599.6 20967.6 158.381 79.83 101.18 0.04903 -0.0175 971
430.000 21.60412 0.38840 7.387663 222.5153 20572.1 21960.8 160.779 80.28 102.88 0.06004 -0.0153 943
440.000 21.26540 0.38562 7.139467 206.5123 21563.2 22974.0 163.161 80.56 104.57 0.07268 -0.0128 914
450.000 20.91206 0.38342 6.892575 190.7686 22577.8 24012.4 165.528 80.66 106.28 0.08717 -0.0100 885
460.000 20.54208 0.38184 6.645827 175.3420 23622.1 25082.6 167.883 80.65 108.11 0.10378 -0.0068 856
470.000 20.15321 0.38093 6.398033 160.2900 24703.7 26192.3 170.232 80.70 110.26 0.12288 -0.0031 826
480.000 19.74286 0.38074 6.147968 145.6708 25831. 2 27350.7 172.585 81.21 113.16 0.14492 0.0012 795
490.000 19.30807 0.38137 5.894376 131.5440 27015.0 28568.8 174.962 83.08 117.79 0.17028 0.0060 762
500.000 18.84548 0.38292 5.635979 117.9729 28270.2 29862.1 177.416 88.57 126.48 0.19889 0.0112 725
510.000 18.35124 0.38552 5.371507 105.0267 29653.0 31287.8 180.172 106.16 147.77 0.22768 0.0155 675
515.000 18.09094 0.38727 5.236615 98.8120 30385.6 32043.9 181.728 115.43 159.10 0.23949 0.0177 651
520.000 17.82109 0.38936 5.099769 92.7837 31152.6 32836.0 183.253 111. 96 157.86 0.25397 0.0215 638
530.000 17.25038 0.39465 4.819774 81.3348 32669.8 34408.9 186.249 106.19 157.06 0.28341 0.0303 612
540.000 16.63439 0.40168 4.530946 70.7863 34180.4 35983.9 189.197 101.69 158.29 0.31359 0.0409 586
560.000 15.25203 0.42244 3.928707 52.8945 37247.4 39214.4 195.070 95.49 165.74 0.37580 0.0683 535
580.000 13.67581 0.45489 3.311975 40.1205 40443.3 42637.0 201.075 91.84 176.63 0.43801 0.1035 490
600.000 12.00388 0.50097 2.727233 32.9104 43754.6 46253.8 207.197 89.58 183.69 0.49826 0.1425 458
620.000 10.43203 0.55786 2.226185 30.5504 47035.5 49911.2 213.175 87.74 180.15 0.55445 0.1772 442
640.000 9.12213 0.61803 1.831545 31.6175 50108.0 53396.7 218.719 85.82 167.42 0.60270 0.2006 438
660.000 8.10470 0.67453 1.534085 34.5869 52891.4 56593.0 223.639 83.97 152.34 0.64535 0.2116 442
680.000 7.32415 0.72447 1.310901 38.2858 55408.2 59504.2 227.993 82.35 139.25 0.68173 0.2136 449
700.000 6.71636 0.76745 1.141140 42.3593 57713.5 62180.2 231.873 81.08 128.78 0.71354 0.2090 458
720.000 6.23299 0.80400 1.009515 46.5629 59858.4 64671.5 235.384 80.15 120.71 0.74105 0.1999 467
740.000 5.83969 0.83496 0.905295 50.7302 61884.3 67021.6 238.604 79.53 114.58 0.76489 0.1885 477
760.000 5.51267 0.86121 0.821093 54.7724 63822.6 69264.6 241.596 79.16 109.94 0.78560 0.1760 487
780.000 5.23552 0.88355 0.751818 58.6506 65696.5 71426.6 244.405 79.00 106.42 0.80366 0.1633 496
800.000 4.99673 0.90263 0.693905 62.3530 67523.2 73527.1 247.064 79.01 103.76 0.81944 0.1508 505

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

ldii IlLlll1 HID, (~OOJ)WIN

I', up'r flIC~, 01 meLila [lui along isobars - Continued

;.; :J/'l'(J'J' apia" E H S Ct! Cp j/P Il W

r. moll] bar/K bar/(mollJ) llmol limo! Jl(mo!·K) Jl(mo!·K) J/(mol·K) K/bar m/s

350.00000 bar
175.590 28.84128 0.83122 19.396102 632.5473 -225.7 987.8 88.629 58.63 71.19 O.OOO()() -0.0396 1548
180.000 28.70673 0.81466 18.946881 624.0286 112.2 1331.4 90.393 58.49 71.05 0.00000 -0.0397 1538
190.000 US .40639 0.77994 UL0006J 9 60:'5.1\3J6 5:'515.5 2090.9 94.2Z:5 :58.24 70.84 0.00000 -0.0398 1:516
200.000 28.11232 0.74870 17.142814 588.9144 1583.9 2828.9 97.852 58.15 70.78 0.00000 -0.0398 1495
210.000 27.82405 0.72043 16.361090 572.9887 2294.4 3552.3 101.306 58.25 70.92 0.00000 -0.0398 1475
220.000 27.54108 0.69475 15.645257 557.8122 2996.6 4267.5 104.612 58.54 71.27 0.00000 -0.0395 1455
230.000 27.26293 0.67132 14.986875 543.1816 3696.4 4980.2 107.795 59.04 71.84 0.00001 -0.0392 1436
240.000 26.98909 0.64988 14.378849 528.9234 4398.8 5695.6 110.871 59.73 72.61 0.00002 -0.0387 1416
250.000 26.71906 0.63019 13.815192 514.8918 5108.2 6418.2 113.858 60.59 73.57 0.00004 -0.0381 1396
260.000 26.45229 0.61206 13.290792 500.9635 5828.6 7151. 7 116.768 61.60 74.71 0.00009 -0.0374 1376
270.000 26.18827 0.59533 12.801262 487.0364 6562.7 7899.1 119.612 62.74 75.98 0.00017 -0.0366 1356
280.000 25.92643 0.57987 12.342804 473.0268 7312.8 8662.8 122.400 63.96 77.38 0.00030 -0.0358 1336
290.000 25.66621 0.56555 11.912108 458.8687 8080.4 9444.1 125.139 65.25 78.87 0.00052 -0.0349 1315
300.000 25.40704 0.55228 11.506269 444.5122 8866.4 10244.0 127.836 66.58 80.42 0.00087 -0.0340 1294
310.000 25.14831 0.53996 11.122722 429.9224 9671.0 11062.7 130.496 67.92 82.02 0.00139 -0.0330 1272
320.000 24.88940 0.52853 10.759181 415.0785 10493.7 11899.9 133.124 69.25 83.66 0.00217 -0.0320 1250
330.000 24.62967 0.51792 10.413593 399.9725 11333.8 12754.9 135.722 70.57 85.32 0.00327 -0.0310 1228
340.000 24.36845 0.50807 10.084121 384.6093 12190.1 13626.4 138.293 71. 85 86.99 0.00478 -0.0299 1205
350.000 24.10505 0.49895 9.769080 369.0040 13061.3 14513.3 140.840 73.09 88.67 0.00683 -0.0288 1181
360.000 23.83872 0.49051 9.466932 353.1815 13945.8 15414.0 143.363 74.28 90.36 0.00950 -0.0276 1157
370.000 23.56869 0.48272 9.176255 337.1753 14842.3 16327.3 145.865 75.41 92.05 0.01292 -0.0264 1133
380.000 23.29413 0.47556 8.895728 321.0261 15749.4 17251.9 148.345 76.47 93.74 0.01720 -0.0251 1108
390.000 23.01418 0.46900 8.624109 304.7803 16666.5 18187.3 150.805 77 .45 95.42 0.02243 -0.0237 1082
400.000 22.72789 0.46303 8.360223 288.4890 17593.1 19133.1 153.243 78.33 97.09 0.02872 -0.0222 1056
410.000 22.43424 0.45765 8.102947 272.2066 18529.7 20089.9 155.661 79.08 98.73 0.03616 -0.0206 1029
420.000 22.13215 0.45285 7.851201 255.9897 19477.7 21059.1 158.058 79.69 100.34 0.04485 -0.0188 1002
430.000 21.82043 0.44864 7.603932 239.8962 20439.1 22043.1 160.435 80.13 101.90 0.05489 -0.0169 975
440.000 21.49776 0.44503 7.360111 223.9842 21417.6 23045.7 162.792 80.39 103.41 0.06641 -0.0147 948
450.000 21.16273 0.44203 7.118718 208.3118 22417.7 24071.5 165.131 80.47 104.91 0.07962 -0.0123 920
460.000 20.81374 0.43967 6.878737 192.9366 23445.1 25126.7 167.453 80.44 106.48 0.09476 -0.0096 892
470.000 20.44906 0.43799 6.639153 177.9155 24507.1 26218.6 169.764 80.46 108.31 0.11218 -0.0064 864
480.000 20.06674 0.43703 6.398947 163.3054 25611. 6 27355.8 172.072 80.94 110.83 0.13228 -0.0028 835
490.000 19.66463 0.43687 6.157098 149.1635 26768.3 28548.1 174.397 82.77 114.97 0.15544 0.0013 804
500.000 19.24036 0.43757 5.912597 135.5484 27991.2 29810.3 176.787 88.21 123.05 0.18159 0.0056 768
510.000 18.79133 0.43924 5.664463 122.5216 293,35.4 31197.9 179.468 105.74 143.56 0.20795 0.0094 720
515.000 18.55666 0.44048 5.538746 116.2492 30045.8 31931.9 180.981 114.97 154.44 0.21878 0.0112 698
520.000 18.31475 0.44201 5.411789 110.1489 30788.4 32699.5 182.458 111. 46 152.68 0.23208 0.0141 686
530.000 17.80773 0.44601 5.153811 98.5027 32249.3 ' 34214.8 185.345 105.60 150.67 0.25916 0.0208 662
540.000 17.26742 0.45145 4.890012 87.6631 33691.6 35718.5 188.159 100.98 150.38 0.28703 0.0287 638
560.000 16.01818 0.46753 4.345184 68.7647 36577.0 38753.8 193.618 94.48 153.96 0.34495 0.0485 591
580.000 14.74442 0.49224 3.785575 54.1954 39526.6 41900.4 199.199 90.49 161.04 0.40382 0.0736 548
600.000 13.30906 0.52715 3.235676 44.4578 42563.4 45193.1 204.771 88.03 167.80 0.46224 0.1021 514
620.000 11.87615 0.57170 2.731167 39.3520 45631.8 48578.9 210.304 86.37 169.70 0.51837 0.1302 491
640.000 10.56999 0.62227 2.300159 37.9787 48622.5 51933.8 215.639 84.97 164.77 0.56837 0.1531 479
660.000 9.46651 0.67375 1.950965 39.2126 51440.4 55137.7 220.570 83.65 155.14 0.61372 0.1681 476
680.000 8.57311 0.72208 1.675766 42.0168 54048.6 58131.1 225.046 82.44 144.27 0.65327 0.1749 479
700.000 7.85731 0.76535 1.459977 45.5428 56461.3 60915.8 229.084 81.42 134.49 0.68833 0.1756 484
720.000 7.27819 0.80330 1.289270 49.3454 58713.1 63522.0 232.758 80.64 126.43 0.71891 0.1722 491
740.000 6.80273 0.83621 1.152485 53.3001 60838.1 65983.1 236.130 80.09 119.94 0.74571 0.1657 499
760.000 6.40625 0.86460 1.041323 57.2901 62865.0 68328.5 239.259 79.76 114.81 0.76915 0.1572 507
780.000 6.07050 0.88902 0.949680 61.2318 64817.1 70582.7 242.186 79.60 110.78 0.78975 0.1476 515
800.000 5.78205 0.91004 0.873088 65.0741 66712.2 72765.5 244.950 79.60 107.63 0.80775 0.1376 524

J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 887
Table 17. Properties of methanol along isobars - Continued

T p Z aplaT aPlap E H S CtJ Cp f/P J1. W

K molll bar/K bar/(molll) llmol limo! 11(mo!·K) J/(mo!·K) J/(mo!·K) K/bar m/s
400.00000 bar

175.590 28.91935 0.94740 19.726358 648.4605 -254.3 1128.8 88.445 58.59 71.19 0.00000 -0.0396 1568
180.000 28.78585 0.92848 19.269848 639.7263 82.8 1472.4 90.210 58.45 71.06 0.00000 -0.0397 1557
190.000 28.48790 0.88881 18.308429 621.1054 827.8 2231.9 94.043 58.20 70.84 0.00000 -0.0398 1535
200.000 28.19616 0.85311 17.437132 603.8454 1551.3 2969.9 97.669 58.11 70.78 0.00000 -0.0398 1515
210.000 27.91021 0.82081 16.643334 587.6494 2260.1 3693.3 101.122 58.21 70.91 0.00000 -0.0398 1494
220.000 27.62957 0.79146 15.916663 572.2686 2960.6 4408.3 104.429 58.50 71.26 0.00000 -0.0395 1474
230.000 27.35378 0.76468 15.248507 557.4928 3658.6 5120.9 107.610 59.00 71.82 0.00001 -0.0392 1455
240.000 27.08237 0.74016 14.631659 543.1442 4359.1 5836.1 110.686 59.68 72.58 0.00002 -0.0387 1435
250.000 26.81484 0.71764 14.060009 529.0711 5066.7 6558.4 113.671 60.55 73.54 0.00004 -0.0381 1416
260.000 26.55071 0.69691 13.528376 515.1467 5785.0 7291.5 116.580 61.56 74.66 0.00008 -0.0375 1396
270.000 26.28945 0.67776 13.032299 501.2640 6516.9 8038.4 119.422 62.69 75.93 0.00016 -0.0367 1376
280.000 26.03055 0.66006 12.567924 487.3350 7264.8 8801.4 122.208 63.91 77 .31 0.00028 -0.0359 1356
290.000 25.77349 0.64365 12.131898 473.2891 8030.0 9582.0 124.944 65.20 78.78 0.00049 -0.0350 1335
300.000 25.51771 0.62844 11.721279 459.0717 8813.4 10380.9 127.638 66.53 80.31 0.00082 -0.0341 1315
310.000 25.26265 0.61430 11.333473 444.6435 9615.1 11198.4 130.294 67.86 81.90 0.00132 -0.0332 1294
320.000 25.00773 0.60117 10.966179 429.9787 10434.7 12034.3 132.917 69.20 83.51 0.00204 -0.0323 1272
330.000 24.75237 0.58897 10.617335 415.0651 11271.5 12887.5 135.510 70.51 85.14 0.00308 -0.0313 1250
340.000 24.49592 0.57763 10.285084 399.9018 12124.2 13757.1 138.075 71.79 86.78 0.00450 -0.0302 1228
350.000 24.23776 0.56710 9.967752 384.5001 12991.4 14641.7 140.616 73.03 8~L42 0.00641 -0.0292 1205
360.000 23.97721 0.55734 9.663806 368.8803 13871.5 15539.7 143.132 74.21 90.07 0.00892 -0.0281 1182
370.000 23.71357 0.54831 9.371836 353.0719 14763.0 16449.8 -145.625 75.34 91. 71 0.01211 -0.0269 1158
380.000 23.44609 0.53997 9.090538 337.1118 15664.8 17370.8 148.095 76.40 93.34 0.01610 -0.0257 1133
390.000 23.17398 0.53230 8.818697 321.0431 16575.8 18301.9 150.543 77.37 94.96 0.02098 -0.0244 1108
400.000 22.89642 0.52529 8.555170 304.9141 17495~7 19242.7 152.969 78.24 96.55 0.02685 -0.0231 1083
410.000 22.61252 0.51891 8.298876 288.7771 18424.7 20193.7 155.373 78.99 98.11 0.03377 -0.0216 1058
420.000 22.32134 0.51316 8.048782 272.6866 19364.1 21156.2 157.754 79.59 99.61 0.04185 -0.0200 1032
430.000 22.·02184 0.50804 7.803897 256.6993 20316.0 22132.4 160.112 80.02 101.05 0.05119 -0.0183 1005
440.000 21.71294 0.50356 7.563259 240.8723 21283.5 23125.8 162.448 80.26 102.43 0.06191 -0.0164 979
450.000 21.39344 0.49972 7.325932 225.2630 22271. 1 24140.9 164.763 80.33 103.76 0.07418 -0.0142 952
460.000 21.06206 0.49655 7.090998 209.9284 23284.4 25183.5 167.058 80.28 105.12 0.08826 -0.0118 926
470.000 20.71739 0.49407 6.857553 194.9248 24329.9 26260.7 169.337 80.29 106.71 0.10445 -0.0091 899
480.000 20.35792 0.49232 6.624706 180.3080 25415.5 27380.3 171.608 80.74 108.93 0.12315 -0.0060 871
490.000 19.98200 0.49135 6.391583 166.1332 26550.2 28552.0 173.890 82.54 112.72 0.14470 -0.0025 841
500.000 19.58785 0.49121 6.157328 152.4561 . 27747.6 29789.6 176.231 87.96 120.36 0.16904 0.0013 806
510.000 19.17360 0.49198 5.921129 139.3331 29061.7 31147.9 178.853 105.45 140.36 0.19361 0.0048 760
515.000 18.95832 0.49274 5.802061 132.9975 29755.2 31865.1 180.334 114.66 150.93 0.20372 0.0065 739
520.000 18.73726 0.49376 5.682232 126.8226 30479.5 32614.3 181.776 111.13 148.83 0.21615 0.0087 728
530.000 18.27685 0.49665 5.439990 114.9861 31898.7 34087.3 184.582 105.21 146.04 0.24148 0.0139 705
540.000 17.79046 0.50078 5.193927 103.8889 33291.9 35540.3 187.301 100.52 144.83 0.26762 0.0201 683
560.000 16.73389 0.51338 4.689828 84.1939 36052.0 38442.4 192.578 93.86 146.11 0.32224 0.0353 639
580.000 15.56426 0.53293 4.173503 68.3131 38836.6 41406.6 197.779 89.67 150. "- O ..~781Ci 0.0544 598
600.000 14.30316 0.56058 3.658474 56.7053 41680.6 44477.2 202.975 87.05 156.28 0.43489 0.0763 563
620.000 13.00947 0.59645 3.168002 49.4182 44568.5 47643.2 208.147 85.38 159.78 0.49033 0.0989 537
640.000 11.76830 0.63875 2.726458 45.9277 47439.1 50838.0 213.228 84.16 158.96 0.54097 0.1191 520
660.000 10.65407 0.68417 2.348456 45.3645 50217.6 53972.0 218.051 83.16 153.85 0.58793 0.1346 511
680.000 9.70211 0.72920 2.035902 46.8415 52851.7 56974.5 222.540 82.26 146.18 0.62976 0.1441 509
700.000 8.91018 0.77133 1.782026 49.6009 55326.1 59815.4 226.659 81.49 137.94 0.66736 0.1483 511
720.000 8.25608 0.80931 1.576596 53.0589 57651.6 62496.5 230.438 80.88 130.37 0.70056 0.1478 516
740.000 7.71261 0.84293 1.409425 56.7563 59851.7 65038.0 233.921 80.44 123.99 0.72992 0.1446 522
760.000 7.25578 0.87242 1.272046 60.5645 61950.5 67463.4 237.156 80.17 118.74 0.75578 0.1393 5i9
780.000
800.000
6.86715
6.53266
0.89816
0.92054
1.157958
1.062190
64.4173
68.2548
63969.4 69794.2
65925.2 72048.3
240.183 80.06 114.4R fl. 77 fl." 1 0.1315 536
243.037 80.07 111.06 0.79868 0.1248 543

J. Phys. Chem. Ref. Data, Vol. 16. No_ 4,1987

888 ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

T p Z 8PlaT 8PI8p E H S Cu Cp f/P J.I. W

K molil bar/K bar/Cmol/I) J/mol J/mol J/(mol·K) J/(mol·K) J/(mol·K) Klbar mls

500.00000 bar
175.590 29.06998 1.17812 20.346375 679.3417 -309.3 1410.7 88.086 58.54 71.20 0.00000 -0.0396 1605
180.000 28.93854 1.15448 19.876121 670.1685 26.5 1754.3 89.852 58.39 71.07 0.00000 -0.0397 1595
190.000 28.64516 1.10492 18.886114 650.6793 768.4 2513.9 93.684 58.15 70.84 0.00000 -0.0398 1572
200.000 28.35791 1.06030 17.989348 632.7106 1488.7 3251.9 97.311 58.06 70.78 0.00000 -0.0398 1551
210.000 28.07638 1.01994 17.172742 615.9482 2194.3 3975.2 100.764 58.15 70.91 0.00000 -0.0398 1530
220.000 27.80016 0.98325 16.425558 600.1297 2891.6 4690.1 104.070 58.44 71.24 0.00000 -0.0396 1510
230.000 27.~25154 0.94977 1~.135593 ;:)5~.0334 3~M.2 ;:)402.:i 107.2;:)0 :55.94 71.79 0.00001 -0.0392 1491
240.000 27.26197 0.91911 15.105284 570.4707 4283.2 6117.3 110.324 59.62 72.54 0.00002 -0.0388 1471
250.000 26.99912 0.89093 14.518447 556.2820 4987.2 6839.1 113.308 60.48 73.48 0.00004 -0.0382 1452
260.000 26.73983 0.86497 13.973024 542.3309 5701.7 7571.6 116.213 61.49 74.58 0.00008 -0.0376 1432
270.000 26.48367 0.84099 13.464426 528.5024 6429.7 8317.6 119.053 62.62 75.83 0.00015 -0.0369 1413
280.000 26.23015 0.81879 12.988691 514.7005 7173.3 9079.5 121. 834 63.85 77.19 0.00027 -0.0361 1393
290.000 25.97880 0.79821 12.542376 500.8460 7934.1 9858.7 124.566 65.13 78.63 0.00046 -0.0353 1373
300.000 25.72913 0.77909 12.122471 486.8760 8712.7 10656.0 127.254 66.45 80.13 0.00077 -0.0344 1353
310.000 25.48066 0.76131 11.726326 472.7420 9509.2 11471.5 129.904 67.79 81.68 0.00123 -0.0335 1333
320.000 25.23286 0.74476 11.351595 458.4096 10323.4 12304.9 132.519 69.12 83.25 0~00190 -0.0327 1312
JJU.UUV 24.n~:z:z u.nI)J~ 1U.1)1)611l7 443.1l:5n 111:54.2 131:5:5.3 13:5.103 70.43 84.83 0.00285 -0.0317 1291
340.000 24.73720 0.71500 10.658231 429.0754 12000.3 14021.6 137.658 71.70 86.41 0.00416 -0.0308 1270
350.000 24.48824 0.70163 10.336035 414.0657 12860.4 14902.2 140.187 72.94 88.00 0.00591 -0.0298 1248
360.000 24.23776 0.68919 10.028071 398.8402 13732.7 15795.6 142.690 74.12 89.57 0.00819 -0,0289 1226
370.000 23.98517 0.67762 9.732935 383.4195 14615.7 16700.3 145.169 75.24 91.13 0.01110 -0.0278 1203
380.000 23.72986 0.66689 9.449349 367.8332 15508.0 17615.1 147.622 76.29 92.67 0.01473 -0.0268 1180
390.000 23.47117 0.65695 9.176126 352.1172 16408.6 18538.9 150.052 77.25 94.18 0.01916 -0.0256 1157
400.000 23.20843 0.64778 8.912162 336.3136 17316.9 19471.3 152.457 78.11 95.65 0.02447 -0.0245 1133
410.000 22.94093 0.63935 8.656425 320.4690 18233.1 20412.7 154.836 78.85 97.07 0.03073 -0.0232 1109
420.000 22.66794 0.63164 8.407944 304.6335 19158.2 21363.9 157.190 79.44 98.41 0.03803 -0.0219 1085
430.000 22.38866 0.62465 8.165802 288.8600 20094.0 22327.3 159.518 79.86 99.66 0.04645 -0.0205 1060
440.000 22.10228 0.61836 7.929122 273.2029 21043.5 23305.7 161.820 80.09 100.82 0.05611 -0.0189 1035
450.000 21. 80791 0.61278 7.697069 257.7172 22010.8 24303.5 164.096 80.14 101.90 0.06716 -0.0173 1011
460.000 21.50463 0.60792 7.468838 242.4580 23001.1 25326.1 166.346 80.08 102.96 0.07983 -0.0154 986
470.000 21.19148 0.60377 7.243657 227.4801 24020.6 26380.0 168.575 80.06 104.20 0.09441 -0.0133 961
480.000 20.86742 0.60038 7.020779 212.8372 25076.6 27472.7 170.790 80.49 106.02 0.11125 -0.0109 935
490.000 20.53138 0.59775 6.799488 198.5823 26177.6 28612.9 173.007 82.26 109.33 0.13067 -0.0081 907
500.000 20.18224 0.59593 6.579099 184.7674 27336.4 29813.8 175.274 87.64 116.40 0.15262 -0.0050 875
510.000 19.81884 0.59496 6.358962 171.4432 28606.3 31129.2 177.811 105.09 135.72 0.17480 -0.0011 831
515.000 19.63144 0.59480 6.248800 164.9811 29275.3 31822.2 179.245 114.28 145.91 0.18394 -0.0002 810
~20.000 19.44V04 0.:59489 6.1J1S41S1 1~1l.66U7 21)973.3 32545.3 18U.636 11U.72 143.4U U.19518 V.UUD /SUO
530.000 19.04469 0.59578 5.917130 146.4701 31334.1 33959.5 183.330 104.75 139.68 0.21815 0.0047 780
540.000 18.63174 0.59770 5.694468 134.9221 32660.0 35343.6 185.921 100.00 137.39 0.24193 0.0087 760
560.000 17.74979 0.60500 5.244148 113.9572 35254.9 38071.9 190.881 93.18 136.07 0.29195 0.0187 720
580.000 16.79126 0.61748 4.787406 96.1677 37829.0 40806.7 195.681 88.80 137.82 0.34401 0.0311 682
600.000 15.76310 0.63583 4.328552 81.9053 40423.6 43595.5 200.399 85.99 141.23 0.39744 0.0454 647
620.000 14.68789 0.66036 3.877359 71.3596 43052.0 46456.1 205.070 84.22 144.77 0.45113 0.0608 618
640.000 13.60521 0.69063 3.447754 64.4235 45700.3 49375.4 209.713 83.07 146.87 0.50177 0.0759 596
660.000 12.56312 0.72526 3.053529 60.6584 48334.1 52314.0 214.234 82.30 146.58 0.55025 0.0893 580
680.000 11.60279 0.76219 2.703771 59.4273 50912.5 55221.8 218.581 81. 74 143.87 0.59486 0.0998 571
700.000 10.74776 0.79931 2.401260 60.0799 ~3404.9 58057.0 222.693 81.31 139.47 0.63590 0.1069 :567
720.000 10.00328 0.83495 2.143763 62.0551 55796.6 60795.0 226.552 81.00 134.28 0.61309 0.1101 566
740.000 9.36216 0.86801 1.926258 64.9050 58087.1 63427.8 230.160 80.78 129.05 0.70657 0.1114 568
760.000 8.81138 0.89800 1.742771 68.2898 60284.9 65959.4 233.537 80.67 124.21 0.73649 0.1098 572
780.000 8.33669 0.92480 1.587510 71.9638 62402.5 68400.0 236.706 80.66 119.96 0.76323 0.1064 577
800.000 7.92479 0.94854 1.455368 75.7051 64453.1 70762.4 239.697 80.75 116.39 0.78695 0.1020 583

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 889
Table 17. Properties of methanol along isobars - Continued

T p Z aPlaT aPlap E H S Cll Cp flP 11 W

K molll bar/K bar/(molll) l/mol llmol J/(mol·K) ll(mol·K) J/(mol·K) K/bar m/s
600.00000 bar
175.590 29.21402 1.40677 20.922116 .2610 -361.5 1692.4 87.737 58.52 71.21 0.00000 0.0395 1641
180.000 29.08456 1.37842 20.439063 699.6379 -26.9 2036.0 89.502 58.37 71.08 0.00000 -0.0396 1630
190.000 28.79555 1.31897 19.422379 679.2511 712.0 2795.7 93.335 58.12 70.85 0.00000 -0.0398 1607
200.000 28.51256 1.26546 18.501826 660.5413 1429.4 3533.8 96.962 58.03 70.78 0.00000 -0.0398 1585
210.000 28.23522 1.21704 17.663897 643.1776 2132.1 4257.1 100.415 58.12 70.90 0.00000 -0.0397 1564
220.000 27.96316 1.17302 16.897513 626.8836 2826.2 4971.9 103.720 58.41 71.23 0.00000 -0.0396 1544
230.000 27.69600 1.13284 16.193492 611.4264 3517.7 5684.1 106.900 58.91 71.77 0.00001 -0.0392 1524
240.000 27.43334 1.09604 15.544153 596.6079 4211.6 6398.7 109.973 S9.S9 12.S1 0.00002 -0.0388 lS0S
250.000 27.17478 1.06221 14.943019 582.2595 4912.2 7120.1 112.955 60.45 73.44 0.00004 -0.0383 1485
260.000 26.91992 1.03102 14.384584 568.2370 5623.2 7852.0 115.859 61.46 74.52 0.00008 -0.0377 1466
270.000 26.66835 1.00220 13.864134 554.4178 6347.6 8597.4 118.695 62.59 75.75 0.00015 ·0.0370 1447
280.000 26.41965 0.97551 13.377600 540.6980 7087.4 9358.4 121.474 63.81 77 .09 0.00026 -0.0362 1427
290.000 26.17338 0.95073 12.921457 526.9913 7844.1 10136.5 124.201 65.09 78.51 0.00045 -0.0354 1408
300.000 25.92912 0.92770 12.492623 513.2268 8618.5 10932.5 126.885 66.41 79.98 0.00075 -0.0346 1388
310.000 25.68641 0.90625 12.088392 499.3480 9410.5 11746.3 129.529 67.75 81.50 0.00119 -0.0338 1369
nu.uuu ~!:I.44480 0.886~7 11.7063T.3 485.3124 10219.7 12577.8 132.138 69.08 83.03 0.00184 -0.0330 1349
330.000 25.20382 0.86763 11. 344441 471.0899 11045.3 13425.9 134.715 70.38 84.57 0.00275 -0.0321 1329
340.000 24.96301 0.85024 11.000698 456.6626 11885.8 14289.3 137.262 71.66 86.11 0.00399 -0.0313 1308
350.000 24.72187 0.83400 10.673439 442.0234 12739.7 15166.7 139.782 72.89 87.65 0.00566 -0.0304 1287
360.000 24.47991 0.81885 10.361121 427.1758 13605.3 16056.3 142.274 74.06 89.16 0;00783 -0.0295 1266
370.0UO 24.23660 0.80471 lU.U62346 412.1J:l6 144lS1.1 16'J~6.7 144."l4U 7!:1.1lS 'JU.66 U.UlU!:I'J -U.UllS::J Ll4.5
380.000 23.99142 0.79154 9.775836 396.9149 15365.4 17866.3 147.181 76.23 92.12 0.01402 -0.0276 1223
390.000 23.74382 0.77929 9.500418 381.5515 16257.3 18784.3 149.595 77 .19 93.55 0.01819 -0.0266 1201
400.000 23.49324 0.76791 9.235006 366.0775 17156.1 19710.0 151.983 78.05 94.93 0.02319 -0.0256 1178
410.000 23.23909 0.75738 8.978594 350.5331 18061.7 20643.6 154.343 78.78 96.24 0.02908 -0.0245 1156
420.000 22.98075 0.74766 8.730248 334.9636 18975.1 21585.9 156.676 79.36 97.46 0.03593 -0.0234 1133
430.000 22.71761 0.73873 8.489087 319.4171 19897.9 22539.1 158.980 79.77 98.57 0.04382 -0.0222 1109
440.000 22.44899 0.73058 8.254283 303.9441 20833.1 23505.8 161. 255 80.00 99.57 0.05286 -0.0209 1086
450.000 22.17423 0.72319 8.025055 288.5964 21784.4 24490.3 163.500 80.04 100.47 0.06320 -0.0196 1063
460.000 21. 89261 0.71657 7.800659 273.4269 22756.9 25497.6 165.717 79.97 101.33 0.07505 -0.0181 1039
470.000 21.60340 0.71071 7.:;80391 2:>IL4879 237:56.6 26:;33.9 167.909 79.94 102.33 0.08M7 -0.0164 1016
480.000 21.30584 0.70563 7.363581 243.8319 24790.4 27606.5 170.081 80.36 103.87 0.10440 -0.0144 991
490.000 20.99914 0.70132 7.149587 229.5093 25866.4 28723.7 172.250 82.11 106.86 0 ..12255 -0.0122 965
SOO.OOO 20.68254 0.69782 6.937807 215.5705 26997.2 29898.2 174.464 87.48 113.58 0.14307 -0.0094 934
510.000 20.35521 0.69514 6.727675 202.0638 28235.7 31183.3 176.942 104.91 132.48 0.16381 -0.0061 892
:51:5.000 20. HH28 0.69411 6.623061 19:5.4873 28887.:; 311S,s9.7 178.342 114.09 142.44 0.1723,s -0.0047 872
520.000 20.01638 0.69331 6.518664 189.0363 29567.2 32564.8 179.699 110.52 139.69 0.18287 -0.0037 863
530.000 19.66529 0.69237 6.310299 176.5337 30888.2 33939.3 182.317 104.52 135.43 0.20440 -0.0014 844
540.000 19.30125 0.69237 6.102167 164.6003 32169.4 35278.0 184.823 99.74 132.53 0.22672 0.0015 826
560.000 18.53209 0.69535 5.685349 142.6125 34657.9 37895.5 189.583 92.86 129.81 0.27385 0.0085 788
580.000 17.70644 0.70268 5.266827 123.3993 37100.9 40489.5 194.135 88.40 129.98 0.32327 0.0173 752
600.000 16.82679 0.71476 4.847579 107.2455 39540.8 43106.5 198.562 85.51 131.95 0.37452 0.0276 718
620.000 15.90340 0.73187 4.431612 94.3493 41999.2 45772.0 202.913 83.68 134.70 0.42672 0.0388 688
640.000 14.95622 0.75390 4.026318 84.7520 44480.3 48492.0 207.239 82.51 137.23 0.47689 0.0503 663
660.000 14.01343 0.78024 3.640629 78.2777 46971.9 51253.5 211.488 81.79 138.70 0.52588 0.0612 643
680.000 13.10571 0.60974 3.283221 74.5424 49450.7 54028.9 21;5.637 81.3:5 138.00 0.:57197 0.0708 629
700.000 12.25870 0.84095 2.959977 73.0418 51892.2 56786.6 219.637 81.09 136.97 0.61528 0.0783 620
720.000 11.48815 0.87243 2.673189 73.2629 54276.4 59499.2 223.460 80.95 134.17 0.65523 0.0835 615
740.000 10.79949 0.90298 2.422079 74.7545 56592.6 62148.5 227.090 80.91 130.70 0.69184 0.0864 613
760.000 10.19041 0.93177 2.203888 77.1493 58837.7 64725.6 230.528 80.94 127.02 0.72504 0.0873 614
780.000 9.65412 0.95531 2.014910 50.1602 61014.7 67229.7 233.150 81.04 123.43 0.7:5:504 0.0665 617
800.000 9.18198 0.98240 1. 851216 83.5682 63130.0 69664.5 236.862 81. 21 120.12 0.78191 0.0843 621

J. Phys. Chern. Ref. Data, Vol. 16, No. 4,1987

890 ROBERT D. GOODWIN

Table 17. Properties of methanol along isobars - Continued

T p Z 3FlaT of/op E Ii S Cu CT' jlF J.L W

K mol/l bar/K bar/(mollI) llmol llmol Jl(mol'K) Jl(mol·K) J/(mol·K) K/bar m/s
700.00000 bar
175.590 29.35217 1.63351 21.461791 738.4729 -410.9 1973.9 87.395 58.51 71.23 0.00000 -0.0395 1674
180.000 29.22462 1.60044 20.966685 728.3860 -77 .6 2317.6 89.161 58.37 71.09 0.00000 -0.0396 1663
190.000 28.93983 1.53113 19.924932 707.0726 658.6 3077 .4 92.994 58.12 70.86 0.00000 -0.0397 1640
200.000 28.66092 1.46873 18.981991 687.5894 1373.2 3815.5 96.622 58.03 70.79 0.00000 -0.0398 1617
210.000 28.38758 1.41226 18.123978 669.5898 2073.0 4538.9 100.075 58.12 70.90 0.00000 -0.0397 1596
220.000 28.11946 1.36092 17.339492 652.7837 2764.3 5253.7 103.380 58.41 71. 22 0.00000 -0.0396 1576
230.000 27.85622 1.31405 16.619091 636.9269 3452.8 5965.7 106.559 58.90 71.75 0.00001 -0.0393 1556
240.000 27.59749 1.27110 15.954884 621.8120 4143.7 6680.2 109.632 59.59 72.49 0.00002 -0.0388 1536
250.000 27.34292 1.23162 15.340217 607.2618 4841.2 7401.3 112.612 60.44 73.40 0.00004 -0.0383 1517
260.000 27.09214 1.19521 14.769442 593.1249 5549.1 8132.8 115.514 61.45 74.48 0.00008 -0.0377 1497
270.000 26.84477 1.16155 14.237719 579.2710 6270.1 8877.7 118.349 62.58 75.69 0.00015 -0.0370 1478
280.000 26.60044 1.13036 13.740887 565.5900 7006.4 9638.0 121.125 63.80 77 .01 0.00027 -0.0363 1459
290.000 26.35875 1.10138 13.275337 551.9883 7759.5 10415.2 123.850 65.08 78.41 0.00045 -0.0356 1440
300.000 26.11930 1.07443 12.837914 538.3877 8530.0 11210.0 126.529 66.40 79.86 0.00075 -0.0348 1421
310.000 25.88171 1.04932 12.425860 524.7249 9317.9 12022.6 129.169 67.73 81.35 0.00119 -0.0340 1402
320.000 25.64555 1.02589 12.036737 510.9498 10122.9 12852.4 131.773 69.06 82.85 0.00182 -0.0332 1383
330.000 25. HOJj2 1.00Jj01 11 ..66838-1 Jj97.0lJj5 109Jj3.7 13698.5 13-1.3-1-1 70.36 8Jj.36 0.00272 -0.032Jj 1363
340.000 25.17588 0.98355 11.318873 482.9233 11779.3 14559.7 136.885 71.64 85.87 0.00394 -0.0316 1344
350.000 24.94151 0.96443 10.986478 468.6310 12627.8 15434.4 139.396 72.86 87.36 0.00557 -0.0308 1324
360.000 24.70686 0.94655 10.669644 454.1431 13487.7 16320.9 141.880 74.04 88.83 0.00769 -0.0300 1303
370.000 24.47147 0.92982 10.366962 439.4644 14357.1 17217.6 144.336 75.16 90.27 0.01037 -0.0291 1283
380.000 24.23490 0.91419 10.077152 424.6082 15234.7 18123.1 146.765 76.20 ?1.67 0.01370 -0.0283 1262
390.000 23.99666 0.89959 9.799042 409.5957 16119.1 19036.2 149.167 77.16 93.04 0.01775 -0.0274 1241
400.000 23.75626 0.88598 9.531558 394.4552 17009.8 19956.4 151.540 78.01 94.34 0.02258 -0.0265 1220
410.000 23.5132( 0.87331 9.273707 379.2205 17906.6 20883.6 153.885 78.74 95.56 0.02826 -0.0255 1198
420.000 23.26700 0.86153 9.024568 363.9308 18810.2 21818.8 156.201 79.33 96;69 0.03485 -0.0246 1176
430.000 23.01708 0.85063 8.783284 348.6289 19722.4 22763.7 158.485 79.73 97.69 0.04244 -0.0235 1154
440.000 22.76294 0.84058 8.549056 333.3610 20645.9 23721.0 160.739 79.95 98.57 0.05113 -0.0225 1132
450.000 22.50400 0.83136 8.321131 318.1751 21584.3 24694.8 162.960 79.99 99.33 0.06106 -0.0213 1110
460.000 22.23969 0.82295 8.098802 303.1209 22542.5 25690.1 165.151 79.91 100.04 0.07242 -0.0201 1088
470.000 21.96944 0.81535 7.881404 288.2483 23526.4 26712.7 167.313 79.88 100.87 0.08548 -0.0187 1065
480.000 21.69264 0.80855 7.668308 273.6074 24542.8 27769.7 169.452 80.29 102.22 0.10055 -0.0171 1042
490.000 21.40870 0.80256 7.458918 259.2476 25599.6 28869.3 171. 585 82.04 104.99 0.11793 -0.0152 1017
500.000 21.11701 0.79737 7.252678 245.2172 26708.9 30023.8 173.758 87.40 111.45 0.13759 -0.0127 987
510.000 20.81697 0.79300 7.049061 231.5630 27923.6 31286.3 176.191 104.82 130.08 0.15744 -0.0094 946
515.000 20.66364 0.79113 6.948082 224.8911 28562.6 31950.2 177.568 113.99 139.88 0.16562 -0.0080 928
520.000 20.50800 0.78947 6.847581 218.3302 29228.8 32642.1 178.899 110.42 136.97 0.17570 -0.0073 919
530.000 20.18952 0.78679 6.647793 205.5626 30520.6 33987.7 181.462 104.41 132.36 0.19632 -0.0057 901
540.000 19.86104 0.78499 6.449297 193.3016 31769.3 35293.8 183.907 99.62 129.08 0.21773 -0.0036 884
560.000 19.17238 0.78415 6.054864 170.4569 34182.6 37833.7 188.525 92.71 125.47 0.26304 0.0016 848
580.000 18.43985 0.78718 5.662365 150.0885 36535.0 40331.1 192.908 88.22 124.65 0.31076 0.0081 813
600.000 17.66418 0.79436 5.271332 132.4479 38868.7 42831.5 197.137 85.30 125.64 0.36056 0.0159 780
620.000 16.85048 0.80586 4.883186 117.7242 41208.7 45362.9 201.269 83.43 127.66 0.41172 0.0245 749
640.000 16.00964 0.82168 4.501480 106.0096 43566.4 47938.8 205.366 82.25 129.98 0.46147 0.0335 723
660.000 15.15843 0.84152 4.131626 97.2582 45941.1 50559.0 209.397 81.55 131.96 0.51070 0.0425 700
680.000 14.31766 0.86473 3.779899 91.2645 48321.6 53210.7 213.362 81.15 133.08 0.55772 0.0508 683
700.000 13.50836 0.89035 3.452016 87.6856 50692 .1 55874.1 217.225 80.97 133.10 0.60259 0.0578 670
720.000 12.74771 0.91727 3.151922 86.1043 53035.7 58526.9 220.964 80.93 132.05 0.64462 0.0634 662
740.000 12.04664 0.94442 2.881327 86.0995 55339.3 61150.1 224.558 80.99 130.16 0.68369 0.0673 657
760.000 11.40964 0.97090 2.639952 87.2954 57594.4 63729.6 227.998 81.13 127.73 0.71956 0.0696 654
780.000 10.83611 0.99608 2.426122 89.3798 59797.8 66257.7 231.282 81.32 125.06 0.75231 0.0704 654
800.000 10.32222 1.01953 2.237380 92.1034 61950.3 68731. 8 234.414 81.56 122.37 0.78196 0.0699 656

J. Phys. Chern. Ref. Data, Vol. 16, No.4, 1987

 THERMODYNAMIC PROPERTIES OF METHANE 891

6. Acknowledgments 22E. U. Franck and R. Deul, "Dielectric behavior of methanol and related
polar fluids at high pressures and temperatures," Faraday Discuss. Chem.
The following individuals have given invaluable assis- Soc. 66, 191 (1978).
tance. Frank R. Williamson contributed expertise in litera- 23H. F. Gibbard and J. L. Creek, "Vapor pressure ofrnethanol from 288.15
to 337.65 K," J. Chem. Eng. Data 19,308 (1974).
ture searches. Robert D. McCarty contributed his least- 24R. D. Goodwin, "Modification of the nonanalytic equation of state for the
squares program which provides for constraints. James F. limit oflow densities," J. Res. Natl. Bur. Stand. (U.S.) 83, 325 (1978).
Ely indicated the numerical integration technique used here, 25R. D. Goodwin, "The nonanalytic equation of state for pure fluids applied
to propane," in Equations of State in Engineering and Research, Advances
and the method for computing fugacities. Appreciation to
in Chemistry Series, No. 182, edited by K. C. Chao and R. L. Robinson
Karen A. Bowie is expressed for devotion in preparing the (The American Chemical Society, Washington, DC, 1979).
final manuscript. Support of the U.S. Department of Energy, 26R. D. Goodwin, "Carbon monoxide thermophysical properties from 68 to
Division of Chemical Sciences, is gratefully acknowledged. 1000 K at pressures to 100 MPa," J. Phys. Chem. Ref. Data 14, 849
(1985).
27K. R. Hall and P. T. Eubank, "Empirical description of the liquid-vapor
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J. Phys. Chem. Ref. Data, Vol. 16, No.4, 1987