Form 5-492
Form 5-492
2
System Considerations for Refrigerant
Blends with Temperature Glide
Theory and Practical Retrofit Guidance for Low and Medium
Temperature Refrigeration
3
Because having little or no glide Saturation pressure temperature 1.2 TEMPERATURE GLIDE AND
is favorable for heat exchanger relationships for R507 (an THE PRESSURE-ENTHALPY
design, zeotropes with low glide azeotrope), R404A (a low-glide DIAGRAM
have been more widely used in zeotrope) and R407A (a high-glide
the past. In the case of blends zeotrope) are shown below. This is a Temperature glide and subcooling
such as R404A or R408A that have useful way to visualize temperature and superheat calculations can
only around 1°F temperature glide, and some of the differences also be visualized on a pressure-
glide, there is very little effect on between these refrigerant types. enthalpy (P-h) diagram. Figure 2
heat exchanger performance. The focus is on typical medium is a P-h diagram for R407A, and
Even ignoring glide introduces temperature refrigeration illustrates the refrigeration cycle
only a small error into superheat evaporator range, from 10 to 30°F. and proper calculations for a high-
and subcooling calculation. With glide refrigerant. As with all P-h
the current movement toward On this plot, temperature glide is diagrams, the liquid saturation line
more environmentally-friendly the horizontal distance (meaning at forms the left side of the saturation
refrigerants, many blends with fixed pressure) between the bubble dome, and the vapor saturation line
significantly higher temperature point and dew point lines of the forms the right side of the dome.
glide (on the order of 10°F) are zeotropic blends. Azeotropic R507 The lines of constant temperature
commonly being used, and more has a single saturation line, and has (or isotherms) slope downward
are being introduced to the market. no glide. R404A has just over 1°F left-to-right in the saturated region,
These include but are not limited to glide, while R407A has over 10°F showing that R407A is a zeotrope,
R407A, R407C, R407F, R448A, and temperature glide. having temperature glide. For a pure
R449A. With high-glide zeotropic refrigerant or azeotrope, these lines
refrigerants, care must be taken would have no slope: no change
to use bubble point to calculate in temperature at a given pressure
subcooling, and dew point to during phase change. Subcooling
calculate superheat. and superheat are always calculated
from the nearest saturation state.
85
R507 Saturated
80 R404A Bubble Point R507 – Single P-T Relationship, No Glide
R404A Dew Point
R407A Bubble Point
75 R407A Dew Point
Pressure (psia)
70
R404A Temperature Glide ~1.1°F
65
55
10 12 14 16 18 20 22 24 26 28 30
Saturation Temperature (°F)
4
T = 80°F T = 100°F T = 120°F T = 140°F
T = 20°F T = 40°F T = 60°F T = 160°F
T = -20°FT = 0°F
T = -40°F Liquid Saturation R407A P-h Diagram
(Bubble Point)
Liquid Subcooling =
Bubble Point Temp. @Phigh
Vapor Saturation
– Liquid Temp. (Dew Point)
Phigh Condensing
Discharge Superheat =
Discharge Gas Temp.
Pressure (psia)
Compression
Plow
Evaporating
Suction Superheat =
Suction Gas Temp.
Isotherm’s with slope in the saturated
– Dew Point Temp. @Plow
region shows that the refrigerant is
zeotropic, and thus has temperature glide
q = 0.3 q = 0.4 q = 0.6 q = 0.7 q = 0.9 q=1
q = 0.1 q = 0.2 q = 0.5 q = 0.8
5
The calculated numbers can be checked with the P-h diagram, by scaling
them with the isotherms. In the case of liquid subcooling, that process
extends from the bubble point, leftward into the subcooled liquid region.
It extends from the 100°F isotherm to the 80°F isotherm, confirming our
calculation of 20°F subcooling.
6
1.3 SUPERHEAT CONTROL WITH GLIDE
The thermostatic expansion valve (TEV) has only one function in the
system: to meter the proper amount of refrigerant to the evaporator coil
by controlling superheat at the bulb location. In order to do this, the TEV
is located at the coil inlet. However, conditions at the coil outlet indicate
whether the TEV is working properly. For zeotropic refrigerants, superheat
is calculated based on dew point, the closest saturation condition at the
evaporator outlet. It follows naturally that superheat is also controlled
based on this condition. This means the vapor pressure or dew point of the
refrigerant is used to control the TEV. The following diagram and explanation
of the fundamental operation of TEVs is excerpted from Sporlan Bulletin
10-9, Thermostatic Expansion Valves: Theory of Operation, Application,
and Selection.
3
Pressure
e
2+
The diaphragm is the actuating member of the valve.
rc
Fo
e
rc
Its motion is transmitted to the pin and pin carrier
ng
Fo
si
ng
ni
lo
assembly by means of one or two pushrods, allowing 3 Spring
C
Pressure pe
the pin to move in and out of the valve port. The O Refrig .
Curve 2
superheat spring is located under the pin carrier, and
a spring guide sets it in place. On externally adjustable
valves, an external valve adjustment permits the spring 1
2
Closing Force
pressure to be altered.
7
Based on the characteristics of high-glide zeotropic blends, we see the
evaporator pressure referred to is in fact vapor pressure or dew point.
Considering the three pressures acting on a TEV, P1 (bulb pressure) and P2
(vapor pressure) are acting on opposite sides of the same diaphragm. TEVs
are designed for these two pressures to be very close to one another. These
will then be the fundamental forces acting to position the pin in the port,
producing the best superheat response. Since each of these two similar
pressures is acting on the same area, only a small amount of additional
force (via spring pressure, P3) is needed to fine tune the balance through
adjustment. This is illustrated in the above figure by the small size of P3 in
comparison to the other two forces. The stroke of the valve is relatively very
small, and the force the spring needs to provide is very small, so the spring
constant is low. The adjustment assembly is typically designed to provide
8-12 full rotations from minimum to maximum design spring force. This
allows for virtually infinite tuning, but only within the design range of the
spring. It follows that the thermostatic element charge should be designed
to be close to the vapor pressure (dew point) of a zeotropic refrigerant to
provide the best TEV performance.
8
100
90
R404A Dew Point
80 R407A Dew Point
70 R407F Dew Point
Pressure (psia)
60
50
40
30
20
10
0
-40 -30 -20 -10 0 10 20 30 40
compare to R404A and R22 from During the early stage of The vapor pressures of R407A and
the standpoint of TEV thermostatic thermostatic charge development, R407F are similar to one another,
charges and volumetric capacity. Sporlan engineers will compare but both are significantly lower
the vapor pressure-temperature than R404A. Is there an existing
2.1 THERMOSTATIC relationship of the new refrigerant refrigerant that may be a better
CHARGES FOR HIGH-GLIDE to that of a refrigerant with match, for which thermostatic
ALTERNATES existing thermostatic charges. charges have already been
If they are a close match, that designed? Figure 4 adds R22 to the
Let’s relate the design and is a strong indication that an same chart.
operational characteristics of existing thermostatic charge will
TEVs to some of the high-glide also function well with the new The saturation curve of R22 is a
refrigerants. Over the past few refrigerant. Figure 3 compares much closer match to the vapor
decades, many different refrigerants the vapor pressure-temperature pressure curves of R407A and R407F.
have been used. Sporlan has relationships of R407A and R407F Consider typical low and medium
developed thermostatic charges with R404A, across the normal evaporator operating temperatures
to function properly with most ranges of low and medium of -20°F and 20°F:
of these. Since the charge in the temperature refrigeration.
thermostatic element does not
function as a heat transfer fluid,
we are primarily concerned that its TEMPERATURE VAPOR PRESSURE (PSIA)
°F R404A R407A R407F R22
pressure-temperature relationship
is close to the vapor pressure- -20 30.7 23.2 24.4 24.9
temperature relationship of the 20 70.0 57.0 59.8 57.8
system refrigerant.
9
100
90
R404A Dew Point
80 R407A Dew Point
70 R407F Dew Point
Pressure (psia)
R22 Saturated
60
50
40
30
20
10
0
-40 -30 -20 -10 0 10 20 30 40
R22 saturation pressure varies by less than +/- 1 psi at -20°F, and by +/- 2 psi at 20°F. This indicates thermostatic
charges for R22 will likely be applicable to R407A and R407F. However, the vapor pressure of R404A exceeds those of
R407A and R407F on average by 7 psi at -20°F and nearly 12 psi at 20°F.
Figure 5 is the same chart as above, but the vapor pressure curves of R407A and R407F are replaced with those of
R448A and R449A. It should be noted that in Figure 5, the dew point curve of R448A lies directly under that of R449A.
Though it may appear that it was omitted, these two are instead so similar they cannot be distinguished at the scale
presented.
100
90
R404A Dew Point
80 R448A Dew Point
70 R449A Dew Point
Pressure (psia)
R22 Saturated
60
50
40
30
20
10
0
-40 -30 -20 -10 0 10 20 30 40
10
The saturation curve of R22 appears to be an even closer match to the vapor
pressure curves of R448A and R449A. Looking more closely at the -20°F and
20°F points:
We find a variation of only +0.4 psi at -20°F, and -1.5 psi at 20°F for R22.
R404A vapor pressure exceeds those of R448A and R449A by 6 psi at -20°F
and by 11 psi at 20°F. These straightforward comparisons strongly indicate
that thermostatic charges designed for R22 will function well for R407A,
R407F, R448A, and R449A throughout the range of low and medium
temperature refrigeration applications. An extensive program of charge
characteristic testing performed in the Sporlan Engineering Lab confirmed
both low and medium temperature thermostatic charges for R22 are also the
best choice for R407A, R407F, R448A, and R449A.
What is the effect of using thermostatic charges designed for R404A with
these refrigerants? We have established that small variations in vapor
pressure from one refrigerant to another, around 5% or less, pose no issue
with TEV adjustment or operation. What if that variation is on the order of
20%? From the TEV balance equation (P1 = P2 + P3), if P1 becomes much
larger than P2, P3 must increase to compensate. However, we also know
that:
a) P3 should be kept small so that P1 and P2 are the fundamental forces
acting to position the pin;
b) By adjusting P3 very high the design range of the spring may be
exceeded;
c) The TEV will not be operating in its effective design range, where it will
provide the best superheat response.
11
Let’s look at the NRE of some of the alternates, using 90°F saturated liquid,
and saturated vapor at -20°F and 20°F, calculated by NIST Refprop 9.1. We
will compare with R22 and R404A.
Using NRE, we will calculate the required mass flow of each refrigerant per
ton (12,000 Btu/hr) capacity.
There is quite significant variation in mass flow required per ton capacity at
the same conditions for these refrigerants. The mass flow of R407F is very
close to that of R22, and both are ~32% lower than R404A. The mass flow of
R407A, R448A, and R449A are similar, and are ~23% lower than R404A, but
still ~12% higher than R22.
Mass flow per ton is divided by liquid and vapor density to determine
the liquid volumetric flow and vapor volumetric flow per ton for each
refrigerant, at low and medium temperature system operating conditions.
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MEDIUM TEMP VOLUMETRIC FLOW PER TON (ft3/min)
(20/100) R404A R407A R407F R448A R449A R22
Vapor 2.65 2.87 2.71 2.81 2.82 2.66
Liquid 0.064 0.046 0.042 0.047 0.048 0.039
This comparison highlights the differences on the liquid side, and the
similarities on suction side of the system. The lower liquid density of R404A
in comparison with R22, along with higher mass flow requirements means
that an R404A liquid side valve must flow an even greater volume than a
simple mass flow comparison of these two would indicate. R407A, R407F,
R448A, and R449A are again in the middle, around 30% lower than R404A
and 20% higher than R22. On the suction side of the system, the refrigerants
are a much closer match. Suction volumetric flow of R404A and R22 are
very similar, with R407A, R407F, R448A, and R449A being 4 – 10% higher
than both at medium temperature and 9 – 17% higher at low temperature
conditions.
The valve sizing and selections in all the subsequent sections of this
document are carried out with Version 5.09.15 of the Sporlan Selection
Program. This is proprietary software that employs the NIST Refprop DLL for
all refrigerant property calculations. Flow and loading calculations are based
on experimentally determined valve characteristics, and results have been
experimentally validated. In the following sections, results that are outside
the normally accepted range are highlighted in red.
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use in selecting TEVs. We will use a 1 ton (12,000 Btu/hr) load, and assume
a 3 circuit evaporator with 3/16” OD, 18” long distributor tubes. From this
a nozzle is sized for R404A, then that nozzle size is applied to the alternate
refrigerants. The selection program will calculate tube ΔP, nozzle ΔP, and
distributor total ΔP. Distributor total ΔP is then subtracted from system high-
to-low ΔP to obtain ΔP across the TEV, the driving force for flow across the
TEV.
For a given distributor orifice size, the total pressure drop across it for the
alternates is lower by 10 – 15 psi at low temperature conditions, and 8 – 12
psi at medium temperature conditions. While these lower distributor ΔP’s
are still adequate for the function of the distributor, there is more ΔP across
the TEV for R407A, R407F, R448A, and R449A. Using the R404A distributor
ΔP, a TEV is selected for R404A. The same TEV (same port size, pin angle,
and stroke) is then applied to the alternate refrigerants, employing their
distributor ΔP’s, in order to compare sizing.
From this comparison, we see that a TEV and distributor sized properly for
R404A may be oversized for the alternates. Percent loading for R407F
reduces approximately 25%, the others reduce approximately 20%. While
14
there are no hard rules that apply to all TEVs on all systems, loadings below
50% begin to become a concern. Mass and volumetric flow requirements for
R407A, R407F, R448A, and R449A are lower, yet there is greater ΔP across the
TEV, to drive flow higher. Keep in mind the TEV is sized at a nominal
condition. Under low-load conditions, the TEV will be even more oversized.
When thermostatic charge is also considered (as discussed in Section 2.1),
there is a high risk that existing R404A TEVs will provide poor superheat
control when retrofitted to R407A, R407F, R448A, or R449A. There is also a
high risk of liquid flood back.
Replacement of TEVs may be the best choice in most retrofits from R404A
to R407A, R407F, R448A, or R449A. Most existing distributors will perform
acceptably well. Sizing of existing R404A distributors and TEVs should be
checked before replacement.
With a distributor orifice sized for R22, total pressure drop for the alternates
is higher by 4 – 11 psi at both low and medium temperature conditions. Yet
because of their significantly greater total high-to-low side ΔP, there is still
as much as 47 - 49 psi greater ΔP across the TEV at both low and medium
temperature conditions. Using the R22 distributor ΔP, a TEV is selected for
R22. The same TEV (same port size, pin angle, and stroke) is then applied to
the alternate refrigerants, in order to compare sizing.
15
LOW TEMP R22 TEV SELECTION: FBVE-2
(-20/100) R22 R407A R407F R448A R449A
Dist ΔP (psi) 38 49 43 48 49
TEV ΔP (psi) 148 180 197 186 181
TEV % loading 66 70 60 68 69
With a TEV and distributor sized properly for R22, percent loading changes
little for the alternates. Percent loading for R407F is somewhat lower at both
medium and low temperature conditions, but well within an acceptable
range. Loadings for R407A, R448A, and R449A are just 2 – 4% percent higher
at low temperature conditions. At medium temperature conditions, loading
with R448A and R449A increases by 6 – 8%. All these would be considered
within an acceptable range. Coupled with the knowledge that thermostatic
charges for R22 are the proper choice for these refrigerants as well, there is
a high likelihood that existing R22 TEVs and distributors will provide good
superheat control when retrofitted to R407A, R407F, R448A, or R449A. Sizing
should be checked to confirm this.
If a solenoid valve is too small, there will be more pressure drop across it
than is desired. This causes loss of subcooling in a liquid line. If there is very
little subcooling, liquid can flash across the valve. A general guideline is that
the pressure drop should be no greater than 1°F of saturation (bubble point)
drop for the system refrigerant. For all the refrigerants in our discussion, 1°F
of saturation is 3.0 – 3.5 psi at 100°F.
For TEVs and distributors, we used 1 ton (12,000 Btu/hr) loads in our
comparisons. This is appropriate because there is typically one TEV per case
or unit cooler in a system. Often one solenoid valve will control flow on a
system branch supplying liquid to a few or several cases or unit coolers. For
solenoid comparisons, we will size for a two ton (24,000 Btu/hr) load at low
temperature conditions (-20°F evaporator, 100°F condensing) and a four ton
(48,000 Btu/hr) load at medium temperature conditions (20°F evaporator,
16
100°F condensing). A liquid line solenoid valve will be selected for R404A,
then that valve will be applied to R407A, R407F, R448A, and R449A to see
the effect on sizing. Selecting a solenoid valve for R404A that will have ΔP
greater than 1 psi, but less than 3.5 psi:
An E6 liquid line solenoid valve is selected for the R404A low temperature
system, with 1.3 psi ΔP. This is on the low end of the preferred range, so what
if the next smaller size E5 is selected instead? ΔP would be 4.2 psi instead,
with 117% loading. In this case, either would likely function without issue.
Usually the lower ΔP would be chosen for an actual system, so the E6 will be
used for comparison. As shown in the table above, that choice results in low
ΔP for all the alternate refrigerants. The situation is different for the medium
temperature system with a four ton load. An E8 solenoid valve is chosen
for R404A, with 2.6 psi ΔP. When applied with the alternate refrigerants,
ΔP’s from 1.2 to 1.5 psi are calculated. These are obviously lower, but still
acceptable.
17
MEDIUM TEMP R22 LL SOLENOID SELECTION: E6
(20/100) R22 R407A R407F R448A R449A
Flow (lbm/min) 11.4 12.8 11.6 12.5 12.6
Sol ΔP (psi) 1.8 2.4 2.0 2.4 2.5
Sol % loading 84 89 79 88 89
An E5 liquid line solenoid valve is selected for the R22 low temperature
system, with 1.6 psi ΔP. This would be common choice in an actual system.
As shown in the table above, that selection results in ΔP’s from 1.8 to 2.3 psi
for the alternate refrigerants. The E5 would function well, without excessive
ΔP for the alternate refrigerants. Results for the medium temperature system
mirror the low temperature system. An E6 solenoid valve is selected for R22,
with 1.8 psi ΔP. When applied with the alternate refrigerants, ΔPs of 2.0 to 2.5
psi are calculated, again well within an acceptable range.
18
EPRs are sometimes used to control individual loads, but are more often
used to control suction pressure on a system branch or circuit with multiple
loads. For this reason, we will size for a two ton (24,000 Btu/hr) load at low
temperature conditions (-20°F evaporator, 100°F condensing) and a four ton
(48,000 Btu/hr) load at medium temperature conditions (20°F evaporator,
100°F condensing). We will assume the suction header is running at -25°F
saturated for the low temperature system, and at 17°F for the medium
temperature system. In an actual system, it would be typical to have 5°F
difference on a low temperature header and 3°F on a medium temperature
header. Sporlan offers EPRs with three different modes of operation: direct
acting, internally piloted, and externally piloted. Our comparison will
consider the externally piloted type, because it is the most common in this
application.
The suction vapor volumetric flow of R404A and R22 is about the same for
a given capacity under like conditions. Does that result in the selection of
the same EPR? When using the low temperature system parameters already
discussed, the Sporlan selection program gives the following results for
R404A and R22:
19
While percent loading varies some, the same SORIT-12 is chosen for both.
For medium temperature conditions:
A SORIT-15 is chosen for both, and loading is again within a few percent
difference. Let’s examine how these EPRs may function with the alternate
refrigerants, starting with the low temperature example from above.
Sizing for all the alternates is acceptable, with percent loading falling in
between that of R404A and R22 for most, and R407A being slightly higher.
For the medium temperature condition and load:
20
Sizing for the alternates is acceptable at medium temperature conditions
as well, with little variation from that of R404A or R22. When retrofitting an
existing low or medium temperature R404A or R22 system to R407A, R407F,
R448A, or R449A, existing evaporator pressure regulator valve sizing will
likely be acceptable. It is good practice to check EPR sizing for confirmation.
While externally piloted EPRs were used in this example, there are many
internally piloted EPRs in use today, particularly on loop-piped systems.
The function of internally piloted EPRs can be more dependent on proper
sizing than externally piloted ones. Thus, they may be more sensitive to a
refrigerant retrofit. If a retrofit is to be performed on a system with internally
piloted EPRs, sizing must be checked with the alternate refrigerant to ensure
that sizing guidelines will not be exceeded. The manufacturer of the valve
will be able to provide guidance on how the existing valve may function with
an alternate refrigerant, and whether or not replacement is recommended.
As with mechanical EPRs, EEPRs for R404A and R22 are acceptable for the
alternates. When retrofitting an existing low or medium temperature R404A
or R22 system to R407A, R407F, R448A, or R449A, existing electric evaporator
pressure regulator valve sizing will likely be acceptable. It is good practice to
check EEPR sizing for confirmation.
21
If a solenoid valve is too small, there will be more pressure drop across it
than is desired. In a suction line, pressure drop is a system inefficiency – it
causes the compressor to operate at a lower suction pressure than it would
otherwise. For the refrigerants in this exercise, 1.7 – 2.0 psi of drop is 3°F of
saturation at -20°F, and 2.1 – 2.6 psi of drop is 2°F saturation at 20°F. Because
of this, suction solenoid valves with no greater than 3°F saturation drop
at low temperature conditions, and no greater than 2°F saturation drop at
medium temperature conditions should be selected. Within this range, the
suction solenoid valve will function reliably without causing excessive loss of
system efficiency. These valves are then applied to the alternate refrigerants.
An E25 solenoid valve is chosen for both the two ton low temperature
load, and the four ton medium temperature load with R22 or R404A. When
applied to the alternate refrigerants, the goal of maintaining at least 1 psi
ΔP to ensure operation of the solenoid valve was met, while not excessively
reducing system efficiency. Saturation drop was acceptable for all
refrigerants at both medium and low temperature conditions.
5 SUMMARY
There are several other areas that must be considered when
performing a refrigerant retrofit. Among the most important of
these are filter changes, oil changes, and replacement of elastomeric seals.
This section will touch on these but not cover them exhaustively. There are
many good refrigerant retrofit guides that cover these topics in detail.
22
to HFC/POE oil are known to cause contamination deposits to dislodge and
move through the system, so filter changes are a very important step in any
retrofit of an R22 system. Filter manufacturers provide guidelines on filter
changes for system cleanup and for normal operation.
New filter-driers or cores will also help ensure the system is dry as possible,
benefiting system startup and operation. When the system is re-started
following a retrofit, liquid line moisture indicators should be reviewed after
24 hours of operation. If moisture is still indicated in the system, change the
filter-driers or cores again. This process should be repeated until the system
is indicated dry.
There will normally be little concern with the size of liquid or suction filters
when retrofitting from either R404A or R22 to R407A, R407F, R448A, or
R449A. Filters are usually selected with some amount of additional capacity.
It is good practice check the size of filter-driers, to confirm there will be both
adequate flow capacity and moisture removal capability in relation to the
size of the system. All Sporlan filter-driers, cores, and suction filters are fully
compatible with these alternate refrigerants.
An R404A system will already have POE oil instead of mineral oil. When
retrofitting to any of these alternates, a change of oil types is not necessary.
It is still good practice to change oil in conjunction with a retrofit, in order to
remove as many contaminants from the system as possible. The cleaner the
system is, the more efficiently and reliably it will operate. In this situation
of a POE-for-POE change, multiple oil changes (as may be necessary with
a mineral-to-POE change) are likely unnecessary, unless there is severe oil
contamination.
When retrofitting an R404A system, the seals are not exposed to different
refrigerant and oil types after the retrofit. However, the existing seals will
likely have been in place for a number of years. Pulling a deep vacuum
on the system will still alter the set the seals have taken from being under
internal pressure, and cause small amounts of refrigerant the seals have
absorbed over time to begin to release from them. While the risk of leaks
may be less for an HFC-to-HFC (or HFO) and POE-to-POE retrofit, it is
23
nonetheless best practice to change the elastomeric seals. Minimizing
external refrigerant leaks benefits both the system’s owner and the
environment.
TEV
Replace with R22
(Thermostatic Not Compatible N/A Compatible N/A Don't replace
element**
Element)
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© 2017 Parker Hannifin Corporation Form 5-492 / 22017