SAFETY DATA SHEET

According to CLASS Regulations 2013

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier
Product name Zirc 1+, Zirc 5+ & Zirc BW
Other means of identification Prepared Opacifier based on Zirconium Silicate
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses As additive for frits and glaze, engobs, serigraphy, ceramic paste
and microfusion.
1.3. Details of the supplier of the safety data sheet
Supplier: Zircon Minerals Malaysia Sdn. Bhd.
6A-A, Jalan Waja 14, Kaw. Perindustrian TPG
42500 Teluk Panglima Garang, Selangor, Malaysia
Tel: +60 331231256
Email: [email protected]
1.4. Emergency telephone number +60 331231256

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture
Classification according to CLASS Regulations 2013, Malaysia (GHS)
Physical hazards Not classified
Health hazards Specific Target Organ Toxicity - Repeated Exposure, Category 2
Environmental hazards Not classiffied
This product is classified as hazardous based on criteria above.
2.2. Label elements

Pictogram
Signal word Warning
Hazard statements H373: May cause damage to lung through prolonged or repeated
exposure
P260: Do not breathe dust
P314: Get medical advice/attention if you feel unwell
P501: Dispose of contents/containers in accordance with local
regulation
2.3. Other hazards Unknown

1 SDS Date: 9/10/2018

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Mixtures

Crystalline Silica/Silicon Dioxide 1.0 - 2.5%

CAS number: 14808-60-7
Classification (GHS)
STOT RE 1 - H372

The Full Text for Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures
Inhalation Move the exposed person to fresh air at once.
Ingestion Immediately rinse mouth and drink plenty of water. Keep person under observation. If person
becomes uncomfortable seek hospital and bring these instructions.
Skin contact Remove contaminated clothes and rinse skin thoroughly with water.
Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and
open eyelids widely. If irritation persists: Seek medical attention and bring along these
instructions.
4.2. Most important symptoms and effects, both acute and delayed
Respiratory tract effect.
4.3. Indication of any immediate medical attention and special treatment needed
General Get medical attention if any discomfort continues

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media
Suitable extinguishing media The product is non-combustible. Use fire-extinguishing media
appropriate for surrounding materials.
Unsuitable extinguishing media Not known.
5.2. Special hazards arising from the substance or mixture
Specific hazards No unusual fire or explosion hazards noted.
Hazardous combustion Oxides of carbon. Thermal decomposition or combustion may
liberate carbon products oxides and/or other toxic gases or vapours
5.3. Advice for firefighters
Protective actions during Cool containers exposed to heat with water spray and remove them
firefighting from the fire area if can be done without risk. Keep up-wind to avoid
flames. Control run-off water by containing and keep it out of
sewers and watercourses.
Special protective equipment Use appropriate protective equipment for surrounding materials.
for firefighters

2 SDS Date: 9/10/2018

SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
For personal protection, see section 8.
6.2. Environmental precautions
Not regarded as dangerous for the environment. Avoid discharge into drains or watercourses or onto
the ground.
6.3 Methods and material for containment and cleaning up
Remove spillage with vacuum cleaner or carefully sweep into closed container or similar. Avoid
generation and spreading of dust.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling
Observe good chemical hygiene practices. Use mechanical ventilation in case of handling which
causes formation of dust. Avoid eating, drinking and smoking when using the product.
7.2. Conditions for safe storage, including any incompatibilities
Store at moderate temperatures in dry, well-ventilated area. No particular incompatibilities known.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters
Occupational exposure limits according to USECHH Regulations 2000, Malaysia
Respirable crystalline silica
Long-term exposure limit (8-hour TWA): PEL 0.1 mg/m3
8.2. Exposure controls

Protective equipments
Appropriate engineering Provide adequate ventilation. Use engineering controls to reduce air
controls contamination to permissible exposure level.
Respiratory protection No specific recommendation. Respiratory protection must be used if
the airborne contamination exceeds the recommended occupational
exposure limit.
Hand protection Chemical-resistant, impervious gloves complying with an approved
standard should be worn if a risk assessment indicates skin contact
is possible.
Eye/face protection Use tight-fitting, chemical splash goggles or face shield if dust is
generated.

3 SDS Date: 9/10/2018

 Other skin and body protection Wear appropriate clothing to prevent reasonably probable skin
contact.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
Appearance Solid - powder.
Colour White / off-white.
Odour Odourless.
pH Not determined.
Solubility Insoluble in water.
Initial boiling point and range Not relevant.
Melting point 1700°C
Relative density 4.6
Flash point (°C) Not applicable.
Evaporation rate Not applicable.
Flammability Not applicable.
Vapour pressure Not applicable.
Auto-ignition temperature Not applicable.
Decomposition temperature Not applicable.
Explosive properties Not applicable.
Viscosity Not applicable.
9.2. Other information
None.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity
No specific reactivity hazards associated with this product.
10.2. Chemical stability
No particular stability concerns.
10.3. Possibility of hazardous reactions
Not known.
Hazardous Polymerisation Will not polymerise.
10.4. Conditions to avoid
No specific conditions are likely to result in a hazardous situation.
10.5. Incompatible materials
Materials To Avoid No specific, or groups of materials are likely to react to produce a
hazardous situation.

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10.6. Hazardous decomposition products
Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides and/or other
toxic gases or vapours.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects
Toxicological effects No information available.
Inhalation Prolonged and/or massive exposure to respirable crystalline silica-
containing dust may cause silicosis, a nodular pulmonary fibrosis
caused by deposition in the lungs of fine respirable particles of
crystalline silica.
Skin contact Prolonged contact may cause redness, irritation and dry skin.
Eye contact May cause temporary eye irritation.

SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity
This product is not anticipated to cause adverse effects to animal or plant life if released to the
environment in small quantities.
12.2. Persistence and degradability
Not applicable
12.3. Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility: Not known.
12.5. Results of PBT and vPvB assessment
Not applicable.
12.6. Other adverse effects
Not available.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
Reuse or recycle products wherever possible. Dispose of waste to licensed waste disposal site in
accordance with the requirements of the local Waste Disposal Authority. Avoid the spillage or runoff
entering drains, sewers or watercourses. Packaging can recycled or reused after cleaning.

SECTION 14: TRANSPORT INFORMATION

General The product is not covered by international regulation on the
transport of dangerous goods (IMDG, IATA, ADR/RID).
14.1. UN number

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 Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Not Environmentally Hazardous Substance/Marine Pollutant.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
This Safety Data Sheet is prepared according to CLASS Regulations 2013 and Industry Code of Practice
on Chemical Classification and Hazard Communication 2014, Malaysia.
15.2. Chemical Safety Assessment
No chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION

Key literature references Industrial Minerals Association - Europe
and sources for data
Prepared date 01/06/2017
Revision 0
Hazard statements in full H372 : Causes damage to organs (Respiratory system, lungs)
through prolonged or repeated exposure if inhaled.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in a process. Such information is, to the best of the company's knowledge and
belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its
accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information
for his own particular use.

6 SDS Date: 9/10/2018