EDEXCEL IGCSE (9-1) CHEMISTRY
REVISION BOOKLET
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Carboxylic Acid
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Carboxylic Acids have the general formula CnH2n+1COOH
Carboxylic acids are a homologous series of hydrocarbons which contain an -COOH group.
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Carboxylic acids have names which end in “oic acid”. Examples are methanoic acid, ethanoic acid.
Carboxylic acids all contain an -COOH functional group attached to a hydrocarbon
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chain
The four simplest carboxylic acids are methanoic acid, ethanoic acid, propanoic acid and
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butanoic acid.
Methanoic acid
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Displayed formula:
Molecular formula: CH₂O₂
Structural formula: HCOOH
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Ethanoic acid
Displayed formula:
Molecular formula: C₂H₄O₂
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Structural formula: CH₃COOH
Propanoic acid
Displayed formula:
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Molecular formula: C₃H₆O₂
Structural formula: CH₃CH₂COOH
Butanoic acid
Displayed formula:
Molecular formula: C₄H₈O₂
Structural formula: CH₃CH₂CH₂COOH
● Instructor : MH. Swopneel | Edexcel High Achiever
● Instructor : MH. Swopneel | Edexcel High Achiever
● Dilute carboxylic acids react with metals in the same way as other dilute acids
(e.g. hydrochloric acid) only more slowly. ( we get salt + hydrogen here as well)
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For example, dilute ethanoic acid reacts with magnesium with fizzing to produce a salt
and hydrogen, leaving a colourless solution of magnesium ethanoate:
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magnesium + ethanoic acid → magnesium ethanoate + hydrogen
Mg (s) + 2CH₃COOH (aq) → (CH₃COO)₂Mg (aq) + H₂ (g)
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● Dilute carboxylic acids react with metal carbonates as they do with other acids, to
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give salt, carbon dioxide and water. (we get salt + carbon dioxide + water here as well)
For example, dilute ethanoic acid reacts with sodium carbonate with a lot of fizzing to
produce a salt, carbon dioxide and water, leaving a colourless solution of sodium
ethanoate:
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sodium carbonate + ethanoic acid → sodium ethanoate + carbon dioxide + water
Na₂CO₃ (s) + 2CH₃COOH (aq) → 2CH₃COONa (aq) + CO₂ (g) + H₂O (l)
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As can be seen in the examples above the charge on the ethanoate ion is -1.
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Vinegar is an aqueous solution containing ethanoic acid (CH₃COOH).
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● Instructor : MH. Swopneel | Edexcel High Achiever