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GHG Inventory Guidance for Fugitive Emissions

This document provides guidance on calculating scope 1 greenhouse gas emissions from fugitive sources, including: 1. Refrigeration and air conditioning equipment, and fire suppression systems. Emissions occur from leaks and releases over the equipment lifetime. 2. Purchased industrial gases that are directly released. It describes several calculation methods - a screening method, method for purchased gases, material balance method, and simplified material balance method - to estimate emissions based on the type and availability of activity data. The choice of emission factors to use with each method is also covered. Guidance is provided on ensuring completeness, performing uncertainty assessments, documentation, and quality assurance/control of the inventory.
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0% found this document useful (0 votes)
63 views20 pages

GHG Inventory Guidance for Fugitive Emissions

This document provides guidance on calculating scope 1 greenhouse gas emissions from fugitive sources, including: 1. Refrigeration and air conditioning equipment, and fire suppression systems. Emissions occur from leaks and releases over the equipment lifetime. 2. Purchased industrial gases that are directly released. It describes several calculation methods - a screening method, method for purchased gases, material balance method, and simplified material balance method - to estimate emissions based on the type and availability of activity data. The choice of emission factors to use with each method is also covered. Guidance is provided on ensuring completeness, performing uncertainty assessments, documentation, and quality assurance/control of the inventory.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Greenhouse Gas Inventory Guidance

Direct Fugitive Emissions from


Refrigeration, Air Conditioning, Fire
Suppression, and Industrial Gases

December 2023
The U.S. EPA Center for Corporate Climate Leadership’s (The Center) GHG guidance is based on The Greenhouse Gas
Protocol: A Corporate Accounting and Reporting Standard (GHG Protocol) developed by the World Resources Institute
(WRI) and the World Business Council for Sustainable Development (WBCSD). The Center’s GHG guidance is meant to
extend upon the GHG Protocol to align more closely with EPA-specific GHG calculation methodologies and emission
factors, and to support the Center’s GHG management tools.

For more information regarding the Center for Corporate Climate Leadership, visit [Link]/climateleadership.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance ii
Table of Contents

Table of Contents
Introduction ............................................................................................................................. 1
Greenhouse Gases Included ..................................................................................................... 1

Manufacturing vs. Use Phase Emissions.................................................................................... 2

Methods for Calculating Emissions ........................................................................................... 3


Screening Method .................................................................................................................... 4
2.1.1 Refrigeration and Air Conditioning Equipment Screening.................................................. 4
2.1.2 Fire Suppression Equipment Screening ............................................................................. 5

Method for Purchased Gases.................................................................................................... 5

Material Balance Method ......................................................................................................... 6

Simplified Material Balance Method......................................................................................... 8

Choice of Activity and Emission Factors ..................................................................................10


Screening Method ...................................................................................................................10
Method for Purchased Gases...................................................................................................11
Material Balance Method ........................................................................................................12

Simplified Material Balance Method........................................................................................12

Completeness ..........................................................................................................................14

Uncertainty Assessment ..........................................................................................................15

Documentation .......................................................................................................................16

Inventory Quality Assurance and Quality Control (QA/QC) .....................................................17

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance iii
Fugitive Emissions Guidance Section 1: Introduction

Introduction
An important category of scope 1 direct greenhouse gas (GHG) are fugitive emissions, which result from the direct release
to the atmosphere of GHG compounds from various types of equipment and processes. This guidance document focuses
on several fugitive emissions sources that are common for organizations in many sectors: refrigeration and air conditioning
systems, fire suppression systems, and the purchase and release of industrial gases.

Historically, air conditioning and refrigeration equipment utilized various Ozone Depleting Substances (ODSs), primarily
chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs). However, in accordance with the Clean Air Act
Amendments of 1990 (Title VI) and the Montreal Protocol, these ODSs are being phased out of manufacture and use in
the United States.

Hydrofluorocarbons (HFCs) and, to a lesser extent, perfluorocarbons (PFCs) are used as substitutes for the regulated ODSs.
In addition, some air conditioning and refrigeration systems use non-halogenated refrigerants such as ammonia, carbon
dioxide (CO2), propane, or isobutane. Also, some fire suppression equipment, which historically used ozone-depleting
halons, use carbon dioxide (CO2), inert gases, and other substances.

Emissions from the refrigeration and air conditioning sector result from the manufacturing process, from leakage and
service over the operational life of the equipment, and from disposal at the end of the useful life of the equipment. These
gases’ global warming potential (GWP) is typically greater than 1,000 times that of CO2, so their potential impact on
climate change can be significant. By the same token, any reductions of these gases can have a large potential benefit.

This guidance document addresses the following emissions from owned or leased sources that are within an
organization’s inventory boundary:

• Emissions from users of refrigeration and air conditioning equipment including household refrigeration, domestic air
conditioning and heat pumps, mobile air conditioning, chillers, retail food refrigeration, cold storage warehouses,
refrigerated transport, industrial process refrigeration, and commercial unitary air conditioning systems.
• Emissions from fixed and portable fire suppression equipment.
• Direct emissions from purchased industrial gases. These gases can be used in processes such as manufacturing,
testing, or laboratory applications.

This document does not address fugitive emissions within the supply chain (e.g., refrigerated shipping vessels), or
emissions from aerosols, solvent cleaning, foam blowing, or other applications.

Greenhouse Gases Included


The emissions sources addressed by this guidance document could result in emissions of any GHG compound.

Ozone depleting substances include numerous compounds such as CFCs, HCFCs, and halons, all of which are GHGs. As
mentioned, these ODSs are being phased out of production due to their ozone depleting properties. However, some
entities may still use these substances directly or in blends within refrigeration, air conditioning, or fire suppression
equipment.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 1
Fugitive Emissions Guidance Section 1: Introduction

It is customary to exclude CFCs, HCFCs, and halons from GHG inventories because they are regulated and are being phased
out by the Clean Air Act. These substances are also excluded from GHG inventories because their global warming impact is
complicated by the fact that they deplete stratospheric ozone, which is a GHG. The GHG Protocol allows for reporting of
these ODSs as separate memo items on an organization’s GHG inventory. They are reported as total release of gases, but
no GWP values are applied, and they do not contribute to an organization’s total CO2-equivalent emissions inventory.
Therefore, organizations that currently use ODSs and switch to HFCs or PFCs may show an increase in their overall GHG
emissions inventory. Documenting the use of these ODSs will help communicate the reasons for this increase.

Manufacturing vs. Use Phase Emissions


This document only applies to scope 1 GHG emissions resulting from operations at the reporting organization’s facilities.
For refrigeration, air conditioning, and fire suppression equipment, these emissions may take place during installation, use,
or disposal. Refrigerants and fire suppressants may be released from equipment leaks during normal operation or from
catastrophic leaks. Also, when equipment is installed, repaired, or removed, refrigerants and fire suppressants may be
released if proper recovery processes are not used. Fire suppressants are also emitted to extinguish fires. Emissions that
occur during the manufacturing or disposal of equipment or purchased gases are scope 3 indirect emissions and are not
included in an organization’s scope 1 emissions.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 2
Fugitive Emissions Guidance Section 2: Methods for Calculating Emissions

Methods for Calculating Emissions


Most organizations will have emissions from refrigeration and air conditioning equipment in one form or another.
However, the potential emissions sources and level of data available may differ greatly. For instance, a supermarket chain
with large refrigeration systems may have on-site storage of refrigerants and track detailed data concerning refrigerant
use, while an industrial organization may simply use air conditioning in its office space and not track detailed data on
refrigerant use. Often organizations whose core business does not include the use of this type of equipment exclude the
associated GHG emissions from their GHG inventory as not material. However, the materiality of a source can only be
established after it has been assessed. This does not necessarily require a rigorous quantification of all sources, but at a
minimum, an estimate based on available data should be developed for all sources of emissions.1

Four methods with varying levels of accuracy and required data collection are outlined in this guidance to calculate GHG
emissions. Organizations may calculate fugitive GHG emissions from refrigeration and air conditioning equipment, fire
suppression systems, or purchased industrial gases with one of the following methods.

Section 2.1 describes a preliminary Screening Method to estimate emissions from refrigeration, air conditioning, and fire
suppression equipment based on the type of equipment used and emission factors. This method requires the least actual
data collection and is not applicable for quantifying emissions from purchased gases. It is recommended that this method
be used only as a screening tool because the emissions factors used in the approach are highly uncertain. Emission factors
vary between individual pieces of equipment and vary over time. Even if the amount of refrigerant added to a piece of
equipment has been tracked carefully, allowing the previous leak rate of that equipment to be established, that leak rate
can change after a leak is repaired or as the equipment ages. If emissions from this equipment are determined to be
significant when compared to an organization’s other emission sources (e.g., stationary combustion, mobile sources), then
one of the other methods should be applied to calculate emissions more accurately.

Section 2.2 describes a Method for Purchased Gases which applies to an organization that purchases, uses, and releases
industrial gases. If an organization maintains an inventory of industrial gases or uses equipment that contains a charge of
an industrial gas, similar to a charge of refrigerant in air conditioning equipment, it is recommended that one of the
material balance methods be used.

Section 2.3 describes a Material Balance Method of calculating emissions from the installation, operation, and disposal of
refrigeration and air conditioning equipment. This method is recommended for organizations that maintain their own
equipment and requires available data on the total inventory of refrigerants at the beginning and end of the reporting
period, purchases during the reporting period, and changes in total equipment refrigerant capacity. This material balance
method can also be used to calculate emissions from fire suppression equipment.

Section 2.4 describes a Simplified Material Balance Method that is appropriate for entities that do not maintain and track a
stock of refrigerants, and that have not retrofitted equipment to use a different refrigerant during the reporting period.
This method is recommended for organizations that have contractors service their refrigerant-containing equipment. This
method tracks emissions from equipment installation, operation, and disposal. The method requires data on the quantity
of refrigerant: (a) used to fill new equipment during installation, (b) used to service equipment, and (c) recovered from

1
See Chapter 1 of the GHG Protocol for more on materiality and significance of emissions sources.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 3
Fugitive Emissions Guidance Section 2: Methods for Calculating Emissions

retiring equipment, as well as the total refrigerant capacities of new and retiring equipment. If notified in advance of the
need for this information, the service contractor should be able to provide it.

Screening Method
The method relies on the use of emission factors which are equipment specific. Therefore, this document provides two
different methods, one for refrigeration and air conditioning equipment and a second for fire suppression equipment. This
method is not applicable for quantifying emissions from purchased gases.

2.1.1 Refrigeration and Air Conditioning Equipment Screening


Under this approach, an organization multiplies the amount of
refrigerant in the equipment by an emission factor for the specific type Equation 1: Estimating Emissions
of equipment and emission event. The disadvantage to using this from Installation
approach is that emission factors are highly uncertain. Therefore, this
Emissions from Installation = CN × (k/100)
method is proposed as a screening test only. Consequently, if an
organization determines that emissions from refrigeration and air where:
conditioning equipment may be significant, it is recommended that CN = amount of refrigerant charged into
one of the other methods then be used. Estimating emissions with the the new piece of equipment
Screening Method requires the following steps: k = assembly losses in percent of
amount charged
Step 1: Perform an inventory of equipment.
Determine the number and types of refrigeration and air conditioning
equipment (by equipment category, see Section 3.1) including the Equation 2: Estimating Emissions
types of refrigerants used and the total refrigerant capacity of each from Operation
piece of equipment.
Emissions from Operation = C × (x/100) x T
Step 2: Determine installation emissions. where:
Identify any new equipment that was installed during the reporting C = refrigerant capacity of the piece of
period and was charged on-site. Emissions from equipment that was equipment
charged at the manufacturer are not the responsibility of the reporting x = annual leak rate in percent of
organization for equipment use (see Section 1.2). For each new piece capacity
of equipment, use Equation 1 to estimate installation emissions. T = time in years used during the
reporting period (e.g., 0.5 if used only
Step 3: Determine operating emissions.
during half of the reporting period and
This step estimates losses from equipment leaks and service losses
over the life of the equipment. For all pieces of equipment, use then disposed)
Equation 2 to estimate operating emissions.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 4
Fugitive Emissions Guidance Section 2: Methods for Calculating Emissions

Step 4: Determine disposal emissions.


Equation 3: Estimating Emissions from
Identify any pieces of equipment that were disposed of during the
reporting period. For each piece of disposed equipment, use Equation 3 Disposal
to estimate disposal emissions. Emissions from Disposal =
CD × (y/100) × (1 – z/100)
Step 5: Determine total emissions. where:
Add the emissions from each piece of equipment for each type of CD = refrigerant capacity of the piece of
emission (installation, operation, and disposal) to get total emissions. equipment being disposed of
Calculate separate totals for each type of refrigerant used. Multiply the y = percent of the capacity remaining at
emissions of each refrigerant by the refrigerant’s GWP to calculate CO 2 disposal
equivalent emissions. GWP values are available in EPA’s GHG Emission z = percent of refrigerant recovered
Factors Hub. Section 3.1 provides default emission factors and
describes the different categories of equipment for which there are default factors.

2.1.2 Fire Suppression Equipment Screening


Fire suppression equipment can be divided into two broad categories, fixed and portable equipment. This Screening
Method provides an emission factor for each type of equipment. Under this approach, the organization multiplies the
capacity of the equipment by an emission factor for fixed or portable equipment. If an organization determines that
emissions from fire suppression equipment may be significant, it is recommended that one of the other methods then be
used. Estimating emissions with the Screening Method requires the following steps:

Step 1: Perform an inventory of equipment.


Determine the number and types of fire suppression equipment, by gas type, and the fire suppressant capacity of each
piece of equipment.

Step 2: Determine total emissions.


Add the capacities of each portable unit for each gas and of each fixed unit for each gas and multiply the total capacity by
the appropriate emission factor. Emissions from fixed systems are assumed to be 2.5 percent (0.025) of the total capacity
of the units for each gas. Emissions from portable equipment are assumed to be 3.5 percent (0.035) of the total capacity
of the units for each gas. The emission factors provided for this Screening Method are as provided in the Inventory of U.S.
Greenhouse Gas Emissions and Sinks. Multiply the emissions of each fire suppressant by its GWP from the GHG Emission
Factors Hub to calculate CO2 equivalent emissions.

Method for Purchased Gases


Industrial gases are sometimes used in processes such as manufacturing, testing, or laboratory uses. For example, CO2 gas
is often used in welding operations. These gases are typically released to the atmosphere after use. Any use and release of
the seven major GHGs (CO2, CH4, N2O, PFCs, HFCs, SF6, and NF3) is required to be included in the GHG inventory. This
method is not recommended if the organization maintains an inventory of industrial gases or uses equipment that
contains a charge of an industrial gas, similar to a charge of refrigerant in air conditioning equipment. In these situations, it
is recommended that one of the material balance methods be used.

Step 1: Determine purchases of industrial gases.


Determine whether any GHGs are used in processes such as those mentioned above. If so, collect the mass of each gas
purchased. If data are not available in mass units, the organization may need to convert from volume to mass using the
density of the specific gas. This method assumes that all gas purchased in the reporting period is used and released during

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 5
Fugitive Emissions Guidance Section 2: Methods for Calculating Emissions

the reporting period. If the organization makes a bulk purchase and plans on using the gas over multiple years, divide the
bulk amount by the expected years of usage and consider that to be the purchase amount for the current reporting
period, as well as the applicable future reporting periods.

Step 2: Calculate emissions.


Sum the amount of gas purchased for each gas type. Multiply the total by the appropriate GWP from the GHG Emission
Factors Hub to calculate CO equivalent emissions.
2

Material Balance Method


The Material Balance Method tracks emissions of Equation 4: Material Balance of Refrigerant
refrigerants2 from equipment through a mass balance IB + P + CB = IE + S + CE + Emissions
analysis. Releases of refrigerants can be calculated based where:
on the inventory (in storage, not in operating IB = refrigerant in inventory (in storage, not in operating
equipment), purchases and sales of refrigerants, as well equipment) at the beginning of reporting period
as changes in total refrigerant capacity of equipment P = refrigerant purchased or otherwise acquired during
during the emissions reporting period. the reporting period
CB = total refrigerant capacity of equipment at the
The inventory should be tracked at the facility level by
beginning of the reporting period
type of refrigerant. Equation 4 shows the basic principles
involved in this approach. IE=refrigerant in inventory (in storage, not in operating
equipment) at the end of reporting period
Equation 4 can be rewritten to calculate emissions more S= refrigerant sold or otherwise disposed of during the
easily as shown in Equation 5. reporting period
CE = total refrigerant capacity of equipment at the end of
Equation 5 should be applied to each type of refrigerant the reporting period
used. Calculating emissions with the Material Balance
Method requires the following steps for each type of refrigerant:

Step 1: Calculate the change in inventory (IB - IE). Equation 5: Calculating Refrigerant Emissions with the
Subtract the amount of refrigerant in inventory at the Material Balance Method
end of the reporting period from the inventory at the Emissions = (IB - IE) + P - S + (CB - CE)
beginning of the reporting period to calculate the change
in inventory. The inventory of refrigerants is defined as the total stored on site in cylinders or other storage. This does not
include refrigerants contained within equipment.

Step 2: Determine purchases and other acquisitions (P).


Purchases and other acquisitions may include refrigerant: (a) purchased from producers or distributors, (b) provided by
manufacturers with or inside equipment, (c) added to equipment by contractors or other service personnel (but not if that
refrigerant is from the organization’s inventory), and (d) returned after off-site recycling or reclamation.

Step 3: Determine sales and disbursements (S).

2
The term “refrigerant” is used in this section, but this method can also apply to fire suppressants or industrial gases.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 6
Fugitive Emissions Guidance Section 2: Methods for Calculating Emissions

Sales and disbursements may include refrigerant: (a) in containers or left in equipment that is sold or disposed of, (b)
returned to suppliers, and (c) sent off-site for recycling, reclamation, or destruction. The amount of refrigerant left in
equipment should be the actual amount, which may be less than the total capacity.

Step 4: Calculate the change in capacity (CB - CE).


The change in capacity is the net change to the total equipment volume for a given refrigerant during the reporting period.
Note that “total capacity” refers to the full and proper charge of the equipment rather than the actual charge, which may
reflect leakage. Because the material balance is performed for each refrigerant individually, retrofitting of equipment to
use a different refrigerant will represent a change in capacity for the old and the new refrigerant. If the beginning and
ending total capacity values are not known, the change in capacity can be assumed to equal the capacity of retired units
minus the capacity of new units installed. If an organization only installs equipment during the reporting period, CE will be
greater than CB. The reverse is true for an organization that only disposes of equipment during the reporting period.

Step 5: Calculate emissions.


Once the previous four steps have been completed, GHG emissions for each type of refrigerant and blend may be
quantified using Equation 5. Multiply the emissions of each refrigerant by the refrigerant’s GWP from the GHG Emission
Factors Hub to calculate CO2 equivalent emissions.

Section 3.3 describes in more detail the type of data that is used in determining emissions.

It may be illustrative to describe how the installation or disposal of equipment impacts the Material Balance Method’s
calculation. If equipment is installed, the refrigerant capacity of that equipment is included in both term P as an acquisition
and in term CE as capacity at the end of the year. As a result, the installation has no net impact on emissions.

If equipment is disposed, the refrigerant capacity of that equipment is included in term CB, as capacity at the beginning of
the year, and the actual amount of refrigerant contained in the equipment upon disposal is included in term S as a
disposition. If the amount of refrigerant contained in the equipment upon disposal equals its refrigerant capacity, the
disposal will have no net impact on emissions. If the actual amount is less than the capacity, the difference is assumed to
represent emissions.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 7
Fugitive Emissions Guidance Section 2: Methods for Calculating Emissions

Simplified Material Balance Equation 6: Calculating Refrigerant Emissions


Method with the Simplified Material Balance Method
The Simplified Material Balance Method is a simplified version Emissions = (PN - CN) + PS + (CD - RD)
of the Material Balance Method described above. In the where:
simplified method, there are fewer flows of refrigerant3 to PN = purchases of refrigerant used to charge new
consider. This method is appropriate for entities that do not equipment (omitted if the equipment has
maintain and track a stock of refrigerants, and that have not been pre-charged by the manufacturer)
retrofitted equipment to use a different refrigerant during the CN = total refrigerant capacity of the new
reporting period. This method requires information on the equipment (omitted if the equipment has
quantity of refrigerant: been pre-charged by the manufacturer)
PS = purchases of refrigerant used to service
(a) used to fill any new equipment installed during the equipment
reporting period, (b) used to service equipment, and (c)
CD = total refrigerant capacity of retiring
recovered from any equipment retired during the reporting equipment
period. It also requires information on the total refrigerant
RD = refrigerant recovered from retiring
capacity of installed and retired equipment. This method can
be summarized by Equation 6.

Equation 6 should be applied to each type of refrigerant used. Calculating emissions with the Simplified Material Balance
Method requires the following steps for each type of refrigerant:

Step 1: Calculate installation emissions (PN - CN).


This step is only necessary if the reporting entity installed any new equipment during the reporting period that was not
pre-charged by the equipment supplier. Emissions are calculated by taking the difference between the amount of
refrigerant used to charge the equipment and the total capacity of the equipment. The difference is assumed to represent
emissions.

Step 2: Determine operating emissions (PS).


Operating emissions result from equipment leaks and service losses. It is assumed that the amount of refrigerant
purchased to service equipment is replacing the same amount that was emitted during operation.

Step 3: Calculate disposal emissions (CD - RD).


This step is only necessary if the organization disposed of equipment during the reporting period. Emissions are calculated
by taking the difference between the total capacity of the equipment disposed and the amount of refrigerant recovered.
The difference is assumed to represent emissions.

Step 4: Calculate emissions.


Emissions for each type of refrigerant and blend are calculated by summing the results of the first three steps. Multiply the
emissions of each refrigerant by the refrigerant’s GWP from the GHG Emission Factors Hub to calculate CO2 equivalent
emissions.

3
The term “refrigerant” is used in this section, but this method can also apply to fire suppressants or industrial gases.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 8
Fugitive Emissions Guidance Section 2: Methods for Calculating Emissions

Section 3.4 describes in more detail the type of data that is used in determining emissions.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 9
Fugitive Emissions Guidance Section 3: Choice of Activity and Emission Factors

Choice of Activity and Emission Factors


Required data for all emission estimation methods can come from inventory records, purchase records, repair reports,
service records, and disposal records.

Screening Method
The Screening Method requires organizations to determine the following information:

• Type of Equipment
• Number of Units
• Refrigerant or Fire Suppressant Used
• Total Refrigerant or Fire Suppressant Charge for the Equipment (lb.)

For refrigeration and air conditioning equipment, additional information is required:

• Assembly Emission Factor (%)


• Annual Leakage Rate (%)
• Percent of Capacity Remaining at Disposal (%)
• Recovery Efficiency (%)

The Screening Method is based on the Tier 2 approach from the 2006 Intergovernmental Panel on Climate Change (IPCC)
Guidelines for National Greenhouse Gas Inventories.

The IPCC guidelines also include a table of emission factors for the different phases of the equipment’s life by equipment
type. The IPCC table provides ranges of values for the different emission factors, the percent remaining at disposal, and
the recovery efficiency. However, since this method is intended as a screening approach, it is recommended that the
upper end of the ranges be used. These values are provided in Table 1. The ranges in capacity are provided only for
reference; organizations should use the actual capacity of their equipment.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 10
Fugitive Emissions Guidance Section 3: Choice of Activity and Emission Factors

Table 1: Default Emission Factors for Refrigeration/Air Conditioning Equipment Type of Equipment
Installation Refrigerant
Emission Operating Remaining at Recovery
Type of Equipment Factor Emissions Disposal Efficiency
Capacity K X (% of y z
(kg) (% of capacity) capacity/yr.) (% of capacity) (% of remaining)

Domestic Refrigeration 0.05–0.5 1 0.5 80 70


Stand-alone Commercial
Applications 0.2–6 3 15 80 70

Medium & Large Commercial 50–2,000 3 35 100 70


Refrigeration
Transport Refrigeration 3–8 1 50 50 70
Industrial Refrigeration including 10–10,000 3 25 100 90
Food Processing and Cold Storage
Chillers 10–2,000 1 15 100 95
Residential and Commercial A/C
including Heat Pumps 0.5-100 1 10 80 80

Mobile Air Conditioning -


Maritime 5-6,500 0.5 40 50 50

Mobile Air Conditioning - Railway 10-30 0.5 20 50 50


Mobile Air Conditioning - Buses 4-18 0.5 20 50 50
Mobile Air Conditioning - Other 0.5-2 0.5 20 50 50

Source: 2019 Refinement to the 2006 IPCC Guidelines for National Greenhouse Gas Inventories, Chapter 7: Emissions of Fluorinated Substitutes
for Ozone Depleting Substances, Table 7.9, Default Estimates for Charge, Lifetime, and Emission Factors for Refrigeration and Air-Conditioning
Systems.

Method for Purchased Gases


For quantifying emissions from purchased gases, this method requires data that should be available from purchase
records. The Method for Purchased Gases requires organizations to collect the following data:

• Type of gas purchased


• Amount of gas purchased
• Purpose for the gas

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 11
Fugitive Emissions Guidance Section 3: Choice of Activity and Emission Factors

Material Balance Method


The recommended approach for organizations that maintain their own refrigerant-containing equipment is to calculate
emissions based on the Material Balance Method. This method requires data that should be available from purchase and
service records. The Material Balance Method requires organizations to collect the following data:

• Refrigerant inventory (in storage, not in operating equipment) at beginning of year


• Refrigerant inventory (in storage, not in operating equipment) at end of year
• Refrigerant purchased from producers or distributors in bulk
• Refrigerant provided by manufacturers with or inside of equipment
• Refrigerant added to equipment by contractors
• Refrigerant returned after off-site recycling or reclamation
• Sales of bulk refrigerant to other entities
• Refrigerant left in equipment that is sold to other entities or disposed of
• Refrigerant returned to suppliers
• Refrigerant sent off-site for recycling or reclamation
• Refrigerant sent off-site for destruction
• Refrigerant capacity at beginning of year (in operating equipment, not storage)

• Refrigerant capacity at end of year (in operating equipment, not storage)

If beginning and ending capacity values are not known, the following information can be used:

• Refrigerant capacity of new equipment using this refrigerant


• Refrigerant capacity of equipment that is retrofitted to use this refrigerant
• Refrigerant capacity of retiring or sold equipment that used this refrigerant
• Refrigerant capacity of equipment that is retrofitted away from this refrigerant to a different refrigerant

Note: “Refrigerant capacity” refers to the full and proper charge of the equipment rather than to the actual charge, which
may reflect leakage.

Simplified Material Balance Method


The Simplified Material Balance Method is the recommended approach for equipment users who have contractors service
their equipment. If notified in advance of the need for this information, the contractor should be able to provide it. This
method requires organizations to collect the following data:

• Refrigerant used to fill new equipment


• Refrigerant purchased to charge new equipment

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 12
Fugitive Emissions Guidance Section 3: Choice of Activity and Emission Factors

• Refrigerant capacity of new equipment using this refrigerant


• Refrigerant purchased to service equipment
• Refrigerant capacity of retiring equipment
• Refrigerant recovered from retiring equipment

Note: “Refrigerant capacity” refers to the full and proper charge of the equipment rather than to the actual charge, which
may reflect leakage.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 13
Fugitive Emissions Guidance Section 4: Completeness

Completeness
Forr an organization’s GHG inventory to be complete, it must include all emission sources within the organization’s
inventory boundaries. See Chapter 3 of the GHG Protocol for detailed guidance on setting organizational boundaries and
Chapter 4 of the GHG Protocol for detailed guidance on setting operational boundaries of the inventory.

On an organizational level, an organization’s inventory should include emissions from all applicable facilities or fleets of
vehicles. Completeness of organization-wide emissions can be checked by comparing the list of sources included in the
GHG emissions inventory with those included in other emission’s inventories, environmental reporting, financial reporting,
etc.

At the operational level, an organization should include all GHG emissions from the sources included in their GHG
inventory. Possible GHG emission sources are stationary fuel combustion, combustion of fuels in mobile sources,
purchases of electricity, and process or fugitive emissions. Organizations may refer to this guidance document for
calculating fugitive GHG emissions from air conditioning and refrigeration equipment, as well as fire suppression
equipment and industrial gases, and to the Center’s Guidance documents for calculating emissions from other sources.

When calculating emissions from this equipment use, organizations should include all applicable sources of refrigerant
emissions. If a third party is used for any component of refrigerant tracking, the third party should provide any necessary
information. For the Screening Method, all pieces of equipment of all different types need to be accounted for. For the
Material Balance Methods, all activities and different types of refrigerants or blends should be tracked.

As described in Chapter 1 of the GHG Protocol there is no materiality threshold set for reporting emissions. The materiality
of a source can only be established after it has been assessed. This does not necessarily require a rigorous quantification
of all sources, but at a minimum, an estimate based on available data should be developed for all sources.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 14
Fugitive Emissions Guidance Section 5: Uncertainty Assessment

Uncertainty Assessment
There is some level of uncertainty associated with all methods of calculating GHG emissions. It is recommended that
organizations attempt to identify the areas of highest uncertainty in their emissions calculations and consider options for
improving the quality of this data in the future.

The Screening Method for estimating emissions is highly uncertain. Factors vary between individual pieces of equipment
and over time. Even if the amount of refrigerant added to a particular piece of equipment has been tracked carefully,
allowing the previous leak rate of that equipment to be established, that leak rate can change after the leak is repaired or
as the equipment ages.

The major uncertainty introduced in the material balance approaches occurs with recently installed equipment.
Equipment can leak for two or more years before needing a recharge, so emissions over this period are not detected until
after they occur. Despite this minor drawback, the material balance approaches provide a highly accurate estimate of
emissions.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 15
Fugitive Emissions Guidance Section 6: Documentation

Documentation
To ensure that emissions calculations are transparent and verifiable, the documentation sources listed in Table 2 should
be maintained. These documentation sources should be collected to ensure accuracy and transparency, and should also
be included in the organization’s Inventory Management Plan (IMP).

Table 2: Documentation Sources

Data Documentation Source


Inventory at Beginning and End of Year Stock inventory documentation

Purchases Purchase receipts; delivery receipts; contract

Nameplate Capacity of equipment Delivery receipts of equipment; records of physical inspection of


nameplates; shipping or disposal records of equipment
Amounts Charged to Equipment Repair records; repair invoices; daily reports

Amounts Recovered from Equipment Repair records; repair invoices; daily reports; disposal records

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 16
Fugitive Emissions Guidance Section 7: Inventory Quality Assurance and Quality Control (QA/QC)

Inventory Quality Assurance and Quality


Control (QA/QC)
Chapter 7 of the GHG Protocol provides general guidelines for implementing a QA/QC process for all emissions
calculations. For the use of refrigeration and air conditioning equipment, the following items must be addressed:

• Care should be taken that releases are not double counted (e.g., from reporting both refrigerant blend and individual
blend component use).
• Verify that your inventory is complete. Because the GWP values of fluorinated compounds are so large (particularly
when compared to carbon dioxide and methane), failure to account for even relatively small releases of fluorinated
compounds can introduce significant errors. Also, tracking specific GHGs separately is important, because of the
differing GWP values.

U.S. EPA Center for Corporate Climate Leadership – GHG Inventory Guidance 17

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