SAFT Li-Ion
SAFT Li-Ion
Authors:
Franck Poirier, Business Development Specialist – Saft Space & Defence Division
Louis D’Ussel, Torpedo Product Manager – Saft Space & Defence Division
A Saft industry white paper page 2
Louis D'Ussel joined Saft in France in 1980 initially as a development engineer for missile batteries
and then later for torpedoes. He moved to the US to develop Li-ion batteries for the automotive
industry (electric and hybrid vehicles).
In 2000, Louis returned to France as product manager for torpedo applications with responsibility
for sales to torpedo OEMs.
A Saft industry white paper page 3
Summary
This white paper has been produced by Saft, world specialist in the design and manufacture of high-
tech batteries, to outline the various battery technologies currently available to power electrically
propelled lightweight and heavyweight exercise torpedoes (LWTs and HWTs).
The paper discusses how rechargeable lithium-ion (Li-ion) battery technology offers significant
advantages over secondary Silver-Zinc (Ag-Zn) technology. Saft expects to see Li-ion established as
the preferred battery technology to meet the requirements of navies worldwide. Although the initial
purchase cost is currently higher than for secondary Ag-Zn batteries, the reusability of Li-ion
batteries will ensure low lifecycle costs, as each battery can be used for a much higher number of
exercises. The reduction in associated maintenance and logistic costs will also provide a
considerably more cost-effective solution.
A Saft industry white paper page 4
List of contents
Introduction ......................................................................................................................................................................5
Conclusion ......................................................................................................................................................................20
Appendices.....................................................................................................................................................................21
About Saft ................................................................................................................................................................................ 21
Saft torpedo experience ................................................................................................................................................... 21
Saft underwater vehicle experience ............................................................................................................................ 25
Note: all photographs and illustrations used in this white paper are courtesy of Saft, except where
credited.
A Saft industry white paper page 5
1 Introduction
Lightweight torpedoes (LWTs), typically 324 mm (12.75”) in diameter, are intended for anti
submarine warfare, where they are deployed from fixed or rotary wing aircraft, or from surface
vessels.
Heavyweight torpedoes (HWTs), typically 533 mm (21”) in diameter, are mainly intended for anti
surface ship warfare, and are usually launched by submarines.
During sea tests and training exercises, navies conduct a number of test firings of electrically
propelled LWT and HWT training and exercise torpedoes equipped with dummy warheads. These
torpedoes require an onboard battery system to power the electric propulsion system as well as
other electronic control and guidance circuits. The battery must provide realistic performance,
comparable to the combat version, so may be called upon to propel the torpedo at speeds over 45
knots.
The use of primary (non-rechargeable) batteries that can only be used once results in a significant
additional cost for a sea trial each time a torpedo is fired. This means there is a growing demand
for rechargeable battery systems that can be reused many times.
A Saft industry white paper page 6
Ag-Zn batteries have a high energy and power density. In torpedo applications, rechargeable
batteries are used for exercises and primary batteries for combat.
For reasons of safety and performance, the batteries are only activated, by electrolyte injection, at
the last minute.!They can have a shelf life of over eight years.
AgO-Al batteries have high energy density and power consistent with torpedo range and speed, and
provide twice the power and energy of the standard Ag-Zn reaction at the same volume and weight.
Various active materials can be used for the positive electrode: lithium cobalt oxide, lithium nickel
oxide, lithium aluminium oxide, lithium manganese oxide, or lithium iron phosphate. Doped nickel
oxide (NCA) offers the best cycling capability and service life for professional and defence
applications.!
Large and medium-sized Li-ion batteries have been developed in cylindrical and near-prismatic
shapes, with various energy–power trade-offs, from 150 Wh/kg with full discharge in 2 hours to
65 Wh/kg with full discharge in 15 seconds. Other notable properties of Li-ion batteries include:
• a faradic efficiency close to 100%
• sealed maintenance-free construction
• long calendar life (over 10 years at ambient temperature)
• low self-discharge (under 5% per year)
• operating temperature range from –40 °C to +60 °C
• charge level can be gauged directly by measuring voltage.
A Saft industry white paper page 8
Even in cases where maximum speed is required (around 50 knots/93 km/h), Ag-Zn is still
suitable for DM2A4 torpedoes (as used by the German navy, for example) due to the large volume
available for the energy section. However, for the WASS/DCNS’s Black Shark, AgO-Al technology
provides a more compact energy section.
Saft has sold several cell stacks to DCNS for the F21 and the Black Shark for export markets.
4 Why lithium-ion?
Li-ion technology offers two main advantages for exercise torpedo applications.
First, it has one of the highest volumetric and gravimetric energy densities of all rechargeable
chemistries. So in practical terms, it can store a lot of energy/power in a compact, lightweight
package.
Second, the Li-ion electrode manufacturing process enables the design to be adapted to suit the
required power-to-energy ratio. This ranges from very thin electrodes (a few µm) for ultra-high
power applications with a power to energy ratio of 100:1, to thick electrodes for pure energy
applications with 1:1 power-to-energy ratio.
Figure 1: Comparison of battery performance for rechargeable Ag-Zn versus two types of Li-ion cell.
Figure 1 shows the power and energy density capability of bare Li-ion cells suitable for torpedo
propulsion compared with rechargeable Ag-Zn. It is possible to manufacture even more energetic
cells, but they lack power capability, while more powerful cells will lack energy content.
A Saft industry white paper page 10
The Saft demonstration systems are based on the company’s VL range of cylindrical Li-ion cells,
which include the latest developments in cell design, housing, connections and electronic devices
for safety, cycle and calendar life, reliability and cost. These cells are available in high energy VLE,
medium range VLM, high power VLP and very high power VLV versions and, as shown in Figures 2
and 3, the choice of cell for a specific application involves a trade-off between energy and power.
Torpedo Li-ion battery system demonstrators for LWT & HWT models (developed with
DCNS).
A Saft industry white paper page 11
Figure 3: Power-to-energy ratio and density for a range of Saft cylindrical industrial Li-ion cells, from
the high-energy VL45E to the high-power VL7P.
The trade-off between energy and power is best illustrated by considering some typical application
scenarios.
Battery systems must be protected against external abuses and internal failures. External abuses
include shocks, fire, short-circuit, overcharge and water immersion (such as when water enters the
torpedo tube). Internal failures could be short-circuit, individual cell failure (for example, from venting
or fire). In the event of a venting fire, the battery must be designed to ensure the non-contamination
of both the other cells and the whole battery compartment.
In comparison with secondary (rechargeable) Ag-Zn batteries a Li-ion battery is, at the current
state of the market, slightly more expensive. However, Ag-Zn batteries can only provide 10 charge/
discharge cycles within a period of 12 months from first use, while Li-ion can support over 50
cycles over an extended lifetime – so the total cost of ownership (TCO) advantages are clear. In
both cases, Li-ion technology will provide a much more cost-effective way to perform sea trials.
Figure 5 illustrates a typical TCO scenario. With Ag-Zn rechargeable battery technology, the navy
needs to buy a complete battery system in the first year, which comprises a battery tray and
auxiliary components, the cells and the silver metal. A new set of cells must be purchased every
year: the battery tray is reusable and the silver metal is recovered from the old set of cells to be
used in the new set.
By comparison, using Li-Ion battery technology, the navy would need to buy a complete system in
the first year, but no additional expense is incurred throughout the life of the battery.
A further advantage of Li-ion cells is that they are sealed for life and totally maintenance-free. Their
condition can be monitored simply and effectively via the integral battery management system
(BMS). This dramatically reduces torpedo maintenance costs. By contrast, maintenance for Ag-Zn
involves removal of the battery from the torpedo hull and then disassembly of the battery itself for
electrolyte topping, connection cleaning and recharging – a process that can take up to seven days.
A Saft industry white paper page 16
The sealed design of Li-ion cells can also simplify the battery system design process, compared with
Ag-Zn technology, as it offers the flexibility for horizontal or vertical mounting as required, making
optimum use of the available space. This provides a further advantage for users during the handling
of the torpedo as the actual positions of the cells is less critical.
A Saft industry white paper page 17
When constructing a Li-ion battery it is recommended that cells are placed in parallel strings (to
develop the required capacity) and then connected in series to achieve the required voltage. This
reduces the overall cost, as a single BMS can be used; otherwise a BMS is needed for each parallel
string.
In Saft Li-ion batteries, each parallel cell group is connected with a Gemplus electronics card that
provides:
• 16 A/D channels
• voltage and temperature measurement
• cell balancing
• voltage redundant threshold detection
• communication with the BMS.
For protection against overcharge, the battery and individual cells must be protected by a
redundant electronic system based on voltage measurement.
An electronic system is also required to protect the battery and cells against over-discharge. This
will cause an over-discharged cell to end up in a short circuit condition, but there is no risk attached
to this as it is already discharged.
Only a very low-impedance short-circuit may damage the battery, resulting in overheating. So
battery short circuit protection is provided by a fuse.
The only protection against mechanical damage to individual cells such as from bullets or shrapnel
is the torpedo casing. It is desirable therefore to insulate individual cells to avoid cross-
contamination (the avalanche effect) in case of fire or overheating. This can be achieved by placing
cells in insulated tubes. This only increases weight slightly while significantly improving safety.
The whole battery system must be protected against the ingress of seawater.
A Saft industry white paper page 19
LiFePO4 cells also offer increased safety at the electrochemistry level – in particular they have good
thermal stability that can limit the effects of severe abuse.
Saft has developed two LiFePO4 cells for power and very high power military applications – VL10Fe
and VL25Fe. Energy cells using this chemistry are under development.
LiFePO4 technology is, however, still evolving and has not yet solved the challenge of calendar life at
elevated temperature. However, navies have less need for storage at higher temperatures than
many other users, especially when it comes to torpedoes. There are also some practical challenges
to overcome, specifically in developing an optimized capacity gauge and in balancing cell-to-cell
capacity. Today’s techniques, such as coulomb counting or more traditional resistive balancing, do
work very well either at high or low states of charge. Currently, LiFePO4 offers slightly lower energy
density than nickel-based Li-ion, for either LWT or HWT applications. At the same time, LiFePO4
offers higher abuse tolerance, and it is the customer who must decide on the trade-off between
these two parameters.
A Saft industry white paper page 20
10 Conclusion
As things stand today, rechargeable Li-ion battery systems represent the most promising solution
for both LWT and HWT torpedoes when performance, calendar life and TCO are taken into
consideration.
Navies throughout the world are placing an ever increasing emphasis on achieving optimum TCO
for their exercise torpedo batteries. Li-ion battery technology enables them to address this issue by
offering:
• Low life-cycle costs through increased reusability
• Performance comparable to combat torpedoes
• Long service life
• Long calendar life
• Safe operation and ease of handling
• Reduced maintenance and logistic costs.
A Saft industry white paper page 21
11 Appendices
The company operates at the forefront of innovation, developing and delivering advanced solutions
for critical applications that are highly dependent upon integrated technology. As the next
generation of intelligent defence systems takes shape, Saft is actively engaged in supporting major
international companies leading this change.
11.2.1 Battery contracts for the German, Norwegian and Korean navies
In 2006 Saft was awarded three major new contracts for Ag-Zn torpedo batteries for the German,
Norwegian and South Korean navies. The contracts, fulfilled by Saft’s specialized production facility
in Poitiers, France, include: rechargeable batteries for the German navy’s DM2A3 and DM2A4
training exercise torpedoes; primary batteries for the Norwegian navy’s DM2A3 combat torpedoes;
and reserve batteries for the South Korean navy’s SUT combat torpedoes.
Immediately following the qualification process, the German navy had an urgent requirement for
1044 Ag-Zn cells to be delivered before the end of the year. Saft won the competitive tender with
its 120 SHV cells and the contract was agreed in October 2005. Thanks to its dedicated
production facilities in Poitiers, Saft was able to respond to this demanding manufacturing schedule
and delivered the cells on time.
The 120 SHV Ag-Zn cell has a 120 Ah capacity and a nominal voltage of 1.5 V, and is designed
according to the German Military Standard VG 95 284-120. The German Military’s qualification
process has confirmed the successful completion of production of this cell by Saft in Poitiers. The
same cells are also used worldwide for the exercise batteries of the SST4/SUT and the MK 24
(Tigerfish) torpedo systems.
A Saft industry white paper page 22
Qualification tests on this battery type, to verify its production by Saft in Poitiers, were carried out by
the German BWB in cooperation with the Norwegian and German Navies. After delivering test
batteries in 2005, Saft achieved qualification in 2006.
The Saft DM2A3 combat battery is a very compact, remotely activated primary battery, with the
latest safety features. Even in the event of an unintended activation, the battery will discharge itself
safely to avoid any security issues. This provides additional safety for staff when the battery (inside a
torpedo) is handled or stored onboard a submarine.
The DM2A3 battery is the most advanced in Saft’s range of combat batteries, which also includes
batteries for the SST4/SUT torpedoes manufactured by ATLAS Elektronik GmbH.
The PB47 battery is certified by ATLAS Elektronik Gmbh to power the propulsion and electronic
systems of the SST4/SUT torpedoes. The battery is activated by a pyrotechnic device, ignited by an
external electrical signal.
A Saft industry white paper page 23
Saft PB47 batteries are being used successfully by several navies worldwide, especially in Asia,
South America and Europe.
In implementing this licensing agreement with Sebang Hi Tech, Saft is consolidating a long
partnership in South Korea that started with the same company in 1992, with a licensing
agreement for BSO technology.
11.2.5 Contract for the Australian navy’s EuroTorp lightweight MU90 torpedoes
Saft has been awarded a multi-million Euro contract by DCNS, the French naval defence systems
group, to supply Al-AgO seawater-activated propulsion batteries for the EuroTorp lightweight MU90
torpedoes currently being produced for a number of NATO navies.
The MU90 is a new generation torpedo designed to combat modern, deep-diving submarines
carrying advanced countermeasures, and Saft’s unique Al-AgO battery technology makes a major
contribution to its exceptional speed and agility by delivering the optimum combination of high
power and excellent endurance.
The project for the Australian navy is EuroTorp’s latest export contract for the MU90 torpedo.
Winning the contract for the battery systems consolidated Saft’s position as a major supplier to the
torpedo market contract, and follows previous orders from DCNS for MU90 propulsion batteries
for the French navy, as well as similar orders for batteries for the Black Shark heavyweight
torpedoes for the navies of Chile, Malaysia and Portugal.
A Saft industry white paper page 24
EuroTorp has designed the MU90 to be fast and agile, while ensuring range and diving capabilities
comparable to those of current-generation heavyweight torpedoes. Its skewed multi-blade electric
pump-jet propulsor is powered by a Saft Al-AgO battery, capable of delivering twice as much energy
and power as conventional Ag-Zn batteries of the same mass and volume. The Al-AgO technology,
which is unique to Saft, also has the advantage of a maintenance-free storage life of up to 12 years.
The Saft battery provides the MU90 with extremely long endurance, and it is capable of operating
without any degradation in water depths in excess of 1,000 m and as shallow as 25 m, while
retaining navigation capability in water depths as low as 3 m.
Other navies that use the MU90 include those of Denmark, France, Germany, Italy and Poland.
The Black Shark advanced dual-purpose, long-range, wire guided and self-homing torpedo is, from a
propulsion point of view, a heavyweight version of the EuroTorp MU90/IMPACT lightweight torpedo
that already uses a Saft Al-AgO battery system. The battery powers an electric propulsion system,
comprising an electronically controlled high-RPM brushless motor, driving a skewed, multi-blade,
pump-jet propulsor, capable of propelling the 6.3 m long, 0.53 m diameter torpedo at speeds in the
region of 50 knots for more than 10 minutes. The battery also powers the onboard electronic
control, guidance and countermeasures systems.
A Saft industry white paper page 25
The Black Shark battery system is an upgraded version of the MU90 battery system. It is activated
by seawater, uses dissolved sodium-dioxide powder as the electrolyte, and incorporates an
advanced closed-loop electrolyte recirculation system.
This new order for the ‘Guerre des Mines’ AUV follows the success of the Li-ion battery systems
that Saft has supplied previously for GESMA’s Redermor-3 experimental Unmanned Underwater
Vehicle (UUV) platform and ECA’s Daurade AUV.
The 135 V, 23 kWh battery system, which is identical to the battery installed on Daurade, will
power the propulsion and electronics systems on ‘Guerre des Mines’. It is based on Saft MP
176065 Li-ion cells, and Saft is supplying it as a fully integrated, turnkey system, including
mechanical assembly, an electronic control management system for the monitoring of charge and
discharge voltages and cell temperatures, and EMC filtering.
11.3.2 Li-ion battery power for BAe Systems’ Talisman autonomous underwater vehicle
Saft has been chosen by BAe Systems to supply Li-ion batteries for its Talisman ‘M’ AUV. The
vehicle was unveiled in 2007 and is designed to meet the growing demand from navies for
independent vehicles that can undertake a variety of often dangerous tasks, including dealing with
mines.
Talisman ‘M’ is approximately 4.5 m long by 1.7 m wide, weighs around 1,000 kg, can carry
payloads of 500 kg or more and can operate at depths of up to 300 m. Propulsion and manoeuvre
control is provided by four Seaeye SMS ducted-fan thrusters which drive it at speeds of up to 5
knots. The thrusters enable it to hover, move vertically and turn in its own length. The vehicle is
designed to operate with a high degree of accuracy throughout its autonomous missions.
A Saft industry white paper page 27
In its basic configuration, Saft’s Li-ion power system can deliver up to 24 hours of continuous
operation to the Talisman. In a recent development, the batteries can be recharged on the surface
by an integral miniature 3hp diesel engine, extending its range and performance significantly.
Redermor’s power is drawn from a 260 V onboard battery. When designing the new version, the
Redermor-3, GESMA selected Saft’s Li-ion technology in order to drastically reduce the size of the
battery while maintaining the same performance as the current battery system. GESMA also
required an easy-to-operate and maintenance-free subsystem. The reduced size enables the
operator to increase the equipment payload or to add another high-power battery pack to
effectively double its endurance.
A Saft industry white paper page 28
[Link] @[Link]
Saft
[Link]
Saft torpedo battery white paper – March 2009