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Forensic Chemistry: History and Practices

1. The historical background of forensic chemistry discusses how poisons were used in ancient times and how arsenic and hemlock were popular poisons for the Romans. The Marsh test, developed in 1836, was the first reliable analysis that could scientifically show arsenic in a victim's body. 2. Important figures in the development of forensic chemistry include Orfila in 1813, considered the father of modern toxicology, James Marsh who used toxicology in a jury trial in 1836, and Edmund Locard who established the first police crime lab in 1910. 3. Forensic chemists analyze physical evidence from crime scenes to identify unknown substances and match samples in order to solve crimes. They test drugs and
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0% found this document useful (0 votes)
43 views5 pages

Forensic Chemistry: History and Practices

1. The historical background of forensic chemistry discusses how poisons were used in ancient times and how arsenic and hemlock were popular poisons for the Romans. The Marsh test, developed in 1836, was the first reliable analysis that could scientifically show arsenic in a victim's body. 2. Important figures in the development of forensic chemistry include Orfila in 1813, considered the father of modern toxicology, James Marsh who used toxicology in a jury trial in 1836, and Edmund Locard who established the first police crime lab in 1910. 3. Forensic chemists analyze physical evidence from crime scenes to identify unknown substances and match samples in order to solve crimes. They test drugs and
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd

1.

Historical Background of Forensic Chemistry

Poisons were employed by early Egyptians and ancient Greeks and Romans. Democritus
was probably the first chemist to study poisons. Poisons were used for murder and
execution. Arsenic and Hemlock were two popular poisons of Ancient Roman times. The
Marsh test, developed in 1836, was the first reliable analysis that could show scientifically
that arsenic was present in the body of a victim. 70 to 180 mg of arsenic is enough to kill an
adult. Although arsenic targets different enzymes, like cyanide, it interferes with energy-
related processes of cell mitochondria. Arsenic has long been used as a poison, but
historically people could not prove its presence in a corpse. Wikipedia contributors. (2023).
Forensic chemistry. Wikipedia. [Link]

2. Men Behind Forensic Chemistry

1813 Mathiew Orfila, a Spaniard who became professor of medicinal/forensic chemistry at


University of Paris, published Traite des Poisons Tires des Regnes Mineral, Vegetal et
Animal, ou Toxicologie General l. Orfila is considered the father of modern toxicology. He
also made significant contributions to the development of tests for the presence of blood in a
forensic context and is credited as the first to attempt the use of a microscope in the
assessment of blood and semen stains.
1836 James Marsh, an Scottish chemist, was the first to use toxicology (arsenic detection)
in a jury trial.1851 Jean Servais Stas, a chemistry professor from Brussels, Belgium, was the
first to successfully identify vegetable poisons in the body.
1910 Edmund Locard, professor of forensic medicine at the University of Lyons, France,
established the first police crime laboratory.
1960 Lucas, in Canada, described the application of gas chromatography to the
identification of petroleum products in the forensic laboratory and discussed potential
limitations in the brand identity of gasoline.
1976 Zoro and Hadley in the United Kingdom first evaluated chromatograph-mass
spectrometry for forensic purposes. Bryant. (2023). Forensic Chemistry.
[Link]

3. Practice of Forensic Chemistry

Non-biological trace evidence obtained at crime scenes is analyzed by forensic chemists in


attempt to identify unknown compounds and match samples to recognized substances. They
also test drugs/controlled substances recovered from crime scenes and individuals in order
to identify and, in some cases, quantify these materials. [Link]. (2017,
July 14).Forensicchemist|[Link].[Link]
forensic-science/forensic-chemist/

Forensic chemists analyze physical evidence and samples for clues to solve crimes.
Versatility and patience are key qualities for this job. Forensic chemists spend hours
rigorously applying analytical techniques to evidence and meticulously documenting each
step. Evans-Nguyen, K. (2021). Forensic chemistry. American Chemical Society.
4. Duties and Responsibilities of Forensic Chemist

Forensic chemists are scientists who use chemistry and other scientific disciplines to help
solve crimes. They may analyze blood, hair, fibers, soil, or other substances found at a crime
scene in order to determine if they contain any clues about what happened there.

Forensic chemists commonly work with police officers and detectives to provide them with
information that can be used as evidence in court. This might include anything from DNA
analysis results to chemical composition analyses of physical evidence found at the scene of
a crime. Career Insights. (2023). What does a forensic chemist do? CLIMB.
[Link]

Forensic chemists have a wide range of responsibilities, which can include:

 Performing research in order to develop new methods for testing drugs or other
substances
 Collecting samples from crime scenes and analyzing them to determine their
chemical composition
 Conducting examinations of physical evidence such as DNA samples, fibers, hair
samples, or blood samples for use in court cases

 Reviewing existing scientific literature on topics relevant to their work

 Reviewing laboratory testing procedures and making recommendations for


improvements
 Collecting samples for toxicology testing, which involves analyzing blood samples for
alcohol content or screening urine samples for drugs such as cocaine or marijuana
 Examining evidence to determine whether it has been contaminated or altered in any
way
 Obtaining samples from crime scenes using specialized equipment such as swabs or
vials
 Testing samples using chromatography, spectrometry, or other laboratory equipment
to identify compounds and their concentrations

5. Six Golden Rules in the Practice of Forensic Chemistry

The six golden rules in the practice of forensic chemistryare;

1) Go slowly
2) Be thorough
3) Take notes
4) Consult others
5) Use imagination
6) Avoid complicated theories
1. Go slowly : good work cannot be hurried, thereforetake all the time necessary to make
the case complete,nomatter how urgent it may appear or how pressingothersmay be for the
result ; it is generally possible to adjournacase if the work cannot be finished in time.

2. Be thorough : make a careful and minute examina-tion of everything and do not be


satisfied with aqualitativeanalysis if a quantitative one be possible ; it always paysto do too
much rather than too little and it is difficult toforesee what will or will not be required in Court.

3. Take notes : keep a full, neat and clear record ofeverything seen and done.

4. Consult others : many cases will lead the expertinto paths with which he is not familiar,
and when thishappens he should consult those who are most likely [Link] an expert
knows his subject thoroughly, orunlesshe consults others, he may go seriously astray ; thus
adoctor,who found salt in an Egyptian mummy, reported it to bethat of a person who had
been drowned in salt water,appar-ently quite in ignorance of the very readily
ascertainedfactthat crude natron, which contains a large percentage ofsalt,and at a later
date, salt itself were commonly used inancientEgypt in connection with the preservation of
the [Link] chemist too who thought that the ancient Egyptiansused quicklime as a body
preservative, because hefounda small amount of carbonate of lime in a mummy,
wasevidently unaware of the extent to which limestone andlimestone dust occur in Egypt
and that burial in tombscut in the limestone rock was very common. Anotherexpert,who had
not made himself familiar with the methods ofusing liquid fuel under a boiler, but who had
evidentlyheardof the use of compressed air in that connection, thoughtthat compressed air
was forced into the oil in the feedtank.

5. Use imagination : this is somewhat hazardous advice,since an exj)ert with a vivid and
uncontrolledimaginationis a most dangerous person ; a disciplined imagination,how-ever,
which enables inferences and deductions (to beverifiedor discarded at a later stage) to be
made from slenderandincomplete premises is often very useful. In writing thereport the
imagination must be kept well in hand andtheexpert should remember that what to him may
bemerelya helpful working hypothesis is liable to be taken byothersfor more than its true
worth and to be adopted by themasa final explanation.

6. Avoid complicated theories : the simplest explana-tion is the most likely to be the right
[Link]. Communication of the Results. The results of thework carried out will generally be
communicated in theform of a written report, which may be sujjplementedata later date by
oral evidence. Both the written reportandthe oral evidence therefore will be [Link]
written report should commence with anenumerationof the articles received for examination,
the date ofreceiptand from whom received and should state how theywerepacked and
whether they were securely fastened or notandwhether sealed, and if so a description of the
sealsshould beadded. A brief but sufficient record of all the significantfacts noted during the
examination of the article shouldthen be given, followed by a summary of
theconclusionsdrawn from the observed facts and from these alone,theconclusions,
however, being kept quite distinct from thefacts and the whole being expressed in plain and
non-technical language. The conclusions arrived at should begiven very definitely and
without ambiguity, vague andinconclusive opinions being useless.
References

1.)Wikipedia contributors. (2023). Forensic chemistry. Wikipedia.


[Link]

2.)Bryant.(2023).ForensicChemistry.[Link]
[Link]

3.)[Link].(2017,July14).Forensicchemist|
[Link].[Link]
chemist/

4.)Evans-Nguyen, K. (2021). Forensic chemistry. American Chemical Society.

5.)The six golden rules in the practice of forensic chemistry are. (n.d.). Scribd.
[Link]
Forensic-Chemistry-Are
FORENSIC CHEMISTRY AND TOXICOLOGY
(FORENSIC 102)

ASSIGNMENT

DARLO, MARK RANIEL R.


BS-CRIMINOLOGY 3B

August 25, 2023

Common questions

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The collaboration between forensic chemists and law enforcement is crucial as it provides scientifically robust evidence that can directly influence the outcome of criminal investigations and trials. By analyzing physical evidence and interfacing with detectives, forensic chemists help ensure that scientifically backed conclusions underpin criminal justice processes, thereby enhancing the accuracy of verdicts and fostering trust in the judicial system .

Modern technological tools like chromatography and spectrometry have greatly enhanced forensic chemists' capabilities by enabling precise analysis and identification of complex substances. These tools allow for the accurate detection and quantification of chemical compounds, thereby improving the reliability of criminal evidence analyses and contributing to higher rates of solving cases .

Edmund Locard's establishment of the first police crime laboratory in 1910 transformed forensic investigations by institutionalizing scientific methods and forensic evidence analysis in law enforcement. This development allowed for more systematic and scientific scrutiny of crime scene evidence, thereby improving the accuracy and reliability of criminal investigations and judicial outcomes .

Forensic chemists face challenges when applying analytical techniques to non-biological trace evidence due to the complexity and diversity of such materials. They must identify small amounts of substances and match them to known compounds, often with incomplete or contaminated samples, while carefully documenting analyses to withstand judicial scrutiny. This requires precision and often innovative techniques to ensure accurate and court-admissible results .

The Marsh test, developed in 1836, was revolutionary in forensic toxicology as it provided the first reliable method to scientifically confirm the presence of arsenic in a victim's body. Prior to this, it was almost impossible to prove arsenic poisoning despite its known historical use as a poison. This development significantly impacted forensic investigations by enabling the detection of arsenic in a legal context for the first time .

The historical use of poisons, especially prevalent among ancient Egyptians, Greeks, and Romans, necessitated advancements in forensic chemistry to detect and prove poisoning cases. This need fostered the development of methods like the Marsh test and propelled individuals such as Mathiew Orfila to create foundational works in toxicology, significantly shaping forensic science to respond to and mitigate criminal use of poisons .

The 'six golden rules' serve as strategic guidelines for forensic chemists to ensure accuracy, thoroughness, and reliability in their investigations. These principles, which emphasize thoroughness, patience, clear documentation, consultation, imaginative yet cautious approaches, and simplicity in theories, are crucial for maintaining the integrity and credibility of forensic analyses and for the safe and judicial application of scientific evidence in court .

Gas chromatography significantly advanced forensic chemistry by allowing for the detailed identification of complex mixtures, such as petroleum products. Introduced by Lucas in the 1960s, it enabled forensic scientists to discern subtle differences and identify specific brands, although with some limitations. This precision improved forensic analyses by providing more reliable and detailed chemical identifications in investigations .

The principle of 'avoiding complicated theories' aligns with Occam's razor, which suggests that the simplest explanation is often the correct one. This principle is significant in forensic chemistry as it helps avoid overcomplicating findings beyond the evidence, ensuring that conclusions drawn are clear, defendable, and less prone to erroneous interpretations. By adhering to this guideline, forensic chemists provide more reliable and judicially sound evidence .

Mathiew Orfila, considered the father of modern toxicology, made seminal contributions to forensic chemistry by publishing a treatise on poisons and toxicology. He developed tests for detecting the presence of blood in forensic investigations and was the first to apply a microscope in the evaluation of blood and semen stains, enhancing the reliability of evidence analysis in forensic contexts .

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