3 BOTSWANA EXAMINATIONS COUNCIL. Botswana General Certificate of Secondary Education 44 ut < CANDIDATE NAME CENTRE CANDIDATE NUMBER NUMBER CHEMISTRY 0570/03, Paper 3 October/November 2018 ‘4 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required READ THESE INSTRUCTIONS FIRST Write your Centre number, candidate number and name in the spaces provided at the top of this page. Write in dark blue or black pen. You may use a soft pencil for any diagrams, graphs or rough working, Do not use staples, paper clips, highlighters, glue or correction fluid, Answer all questions Write your answers in the spaces provided on the question paper. ‘Show your working for any calculations. You may use a calculator. ‘The number of marks is given in brackets | ] at the end of each question or part question, A copy of the Periodic Table is printed on page 16. For Examiner's Use aloln eolalo Total This document consists of 16 printed pages. BEC 2018 [Turn overa 2 1 (a) Choose from the following substances to answer the questions below. carbon dioxide copper(II) sulphate ethanol ethane iron(I1) chloride iron(IIl) hydroxide magnesium silver water zinc oxide Each substance can be used once, more than once or not at all Name a substance which (i) will turn aqueous acidified potassium chromate(VI) from orange to green, (ii) is a molecule made of only 8 atoms, (iii) is a neutral oxide, (iv) is a metal that can displace lead from aqueous lead(Il) nitrate, (v) forms a dirty green precipitate with acqueous sodium hydroxide, (vi) is a gas that causes global warming, (b) Draw a ‘dot’ and ‘cross’ diagram to show bonding in carbon dioxide. Show all electrons. BEC 2018 os700s/0N/I8 (1 1] a} (1 sen U1] 3) [Total 9]5 4 ies 2. The table shows some information about dilute acids X and Y of the same concentration. ] i | colour with Universal acid pH value cater or 5 Y ciranenseentftirovreow red (a) Complete the table to predict the colour of the Universal Indicator in acid X and the pH value of acid Y. [2] {b) Acid X and acid Y react with the same mass of magnesium ribbon. (i) Give two common observations that would be made when each of the acids is reacted with magnesium ribbon. 1 2 ie (ii) Using an observation given in (b)() give a difference between what is observed with each of these different acids when reacted with magnesium ribbon. 1] (iii) Explan your answer to (b)(ii). BEC 2018, os7onv0mNrs~ 5 (c) Heartbum is a common symptom of indigestion. A patient with heartburn was given medicine which has a label shown. Each 15ml suspension contains: * aluminium hydroxide, aluminium oxide * magnesium sulphate, magnesium oxide * alcohol (i) Suggest how the medicine relieves the heartbum. ) Ethanol is an alcohol that can be used in making medicine, Give two other uses of ethanol, Be BEC 2018 057000N/18 ~ B) (2) [Total: 12] [Turn overA 6 lexan ss 3 The graph shows the heating curves for naphthalene and wax. et 400 4 350 - Temperature /°C | i PPS] te t naphthalene eBEcz018 os7onvOINNS{a) Use the graph to determine (i) the melting point of naphthalene, (ii)_ the physical state of wax after it was heated for 240 seconds. (b) (i) Using part X on the graph, what conclusion can be made about the purity of wax? Give a reason for your answer in (bX). (c) Wax and naphthalene are obtained from the fractions of crude oil Name the separation technique by which wax and naphthalene are obtained from the fractions. (4) Icosane, CzsHss, is one of the substances found in wax. It is not very useful as a fuel (i) State the homologous series to which icosane belongs. (ii) Suggest a reason why icosane is not very useful as a fuel. (e) A process is used to convert icosane into more useful compounds. (i) Name the process that is used to convert icosane into more useful compounds. (li) State two conditions needed for the process in (d) © BEC 2018 os700sONNE examiners fl i a [1] (1 (1) [2] [Turn over(f) One of the compounds obtained from icosane is an isomer of C,H. The structural formula is shown. Hh H-G—C=o—G—-H Jeside a Isomer 4 (i) Draw the other two structural isomers of C,He. ca) Draw the structure of the repeat unit of a polymer that will be obtained in polymerisation of isomer 1 (2) (iii) Suggest one disadvantage of disposing of the type of polymer in (e){ii). 10} [Total: 15) ee BEC 2018 os7ana/01N/8 |e ap4 The table shows some information about copper, graphite, magnesium chloride and hydrogen 10 chloride electrical conductivity substance | melting point/°C type of structure insolid | in liquid copper 1085 v v graphite 4027 v v | giant molecular structure magnesium| 24g | fy treet chloride m4 x % hydrogen ; ee 114.2 x x simple molecular (a) Complete the table by filing in the type of structure for copper and magnesium chloride. (b) Explain why (i) graphite conducts electricity even though it has a giant molecular structure, (ii) hydrogen chloride has a much lower melting point than graphite. BEC 2018 Key: ¥ conducts X does not conduct (2) [2] [2] evamters os700s/0IN/18{c) Graphite is an allotrope of carbon. (i) What is meant by the term alfotrope? (ii) Name another allotrope of carbon, (ii) Give one use of the allotrope in (c’ USE oes PROpSHY cssscascsivnzenrescavcsr i BEC 2018 osronsomne and the property associated with the use. examiners eo (] i [Total: 10] [Turn over12 & Two experiments were set-up to electrolyse aqueous copper(II) sulphate. In experiment A copper electrodes were used and in experiment B carbon electrodes were used. = Experiment A bubbles of gas copper electrodes aqueous copper(II) ‘sulphate Experiment B carbon electrodes (a) State and explain what happens to the concentration of copper(II) ions in experiments A and B. concentration in experiment A ‘explanation concentration in experiment B explanation (1 [1] ~ 10] {b) Bubbles of gas form in experiment B when hydroxide ions, OH”, are discharged in a reaction at the electrode. Write a balanced equation for this reaction. nec 2018 0570030118 (2 \exarinrs ‘ise13 {c) Experiment A is modified as shown. connecting wire zinc metal copper metal aqueous copper(II) sulphate (i) Onthe diagram, use an arrow to show the direction of the flow of electrons. (il) Explain why the electrons flow in this direction BEC 2018 07003018 examiners a ~ (2) [Total: 9] [Turn over14 Iron is extracted from iron ore, haematite, in the blast furnace. Haematite contains iron(Ill) oxide, FezOs. (a) Name the other two raw materials needed for extraction of iron {4 (b) In an experiment to determine the percentage by mass of iron(II!) oxide in haematite, iron extracted from 5.00g of the ore was completely reacted with 275m? of 0.400mol/ dm? hydrochloric acid. ‘The equation for the reaction is Fe(s) + 2HClaq) ———> FeCh(aq) + H,(aq). (i) Calculate the number of moles of acid in 275 cm’ of 0.400mol/dm* hydrochloric acid. moles of acid=.. moles [2] (ii) Use your answer to (b)(i) and the equation to calculate the number of moles of iron that reacted with the acid. moles of iron=...... moles [2] (iii) The equation for the extraction of iron from iron(Ill) oxide, FezOs, is shown. Fe,0s) + 3CO(g) ——> 2Fe(l) + 3CO,(g) Use your answer to (b)(ii) and the equation to calculate the number of moles of iron(II) oxide contained in the ore sample. moles Of iron(II) OXIdE =...cssseensieeenneeee moles — [1] BEC 2018 os7ons/0INI8 exes15 {iv) Use your answer to (bil) to calculate the mass of iron(ill) oxide, Fe,Os, in the ore sample. mass of iron(II) oxide =. 3) {v) Use your answer to (b)(iv) to calculate the percentage of Fe;Os in 5.00g of the ore. % of FezO3 1 {c) The reaction for the extraction of iron from iron(III) oxide is redox. The equation for the reaction is Fe,03 + 3CO—»2Fe + 3CO, Identify the type of reaction that takes place when CO is converted to CO. and when Fe,Os reacts to form Fe. Explain your answers using oxidation numbers. (i) COis converted to CO., type of reaction Explanation .. el (ii) Fe20; is converted to Fe type of reaction . Explanation ...... 2) (Total: 15] examiners emission reproduce lem wre Prd cary owned malotl protec by conyigit is ncuided has been sought and cleared where pose Every Feasanabie eer nas been age by te pubiser (BEC) fo race copyright holders, but any tems eaung clearance have unwetingy bean cluded ha publisher wil be please to make amends athe earles osabie op porunty, © BEC 2018 os7oewonuis(7) ainssasd pue aimjesedusoy wiooi ye ,tup pz St $26 Aue Jo B/0\ UO Jo eUwINIOA ay, ‘Sjuewe]3 Oy} JO 8/Ge{ poled eyL 1a3HS viva os700vONII8 nec 2018