Liquid Propellant
Liquid Propellant
Liquid-Propellant
Rocket Engines
8.1 INTRODUCTION
Liquid propellants have been used for a long time in rocket engines due to
their higher specific impulse. They were first conceived way back in 1915
by Robert Goddard, who demonstrated the launching of a liquid rocket
engine using liquid oxygen and gasoline as propellants on March 26, 1926,
whose flight lasted for only 2.5 s covering a distance of 56 m. Although
dubbed an unsuccessful event by some critics, it importantly demonstrated
that it is possible to design and develop a liquid-propellant rocket engine
(LPRE). Subsequently, LPREs underwent significant improvements that
outweigh the performance of typical solid-propellant rockets. Hence, they
currently find wide application in various propulsive devices such as space-
craft, missiles, retro-rockets, and gas-generating systems. It can easily pro-
vide thrust levels ranging from a few Newton to several hundred Newton.
It is preferred in interplanetary mission and other important areas due to
its efficiency, reliability, and cost-effectiveness over other chemical propul-
sive systems.
A liquid rocket engine employs liquid propellants that are fed, either
through pressurized tanks or by using a pump, into a combustion chamber.
261
262 ◾ Fundamentals of Rocket Propulsion
8.2 BASIC CONFIGURATION
The main components of a typical liquid-propellant rocket engine, shown
in Figure 8.1, consist of thrust chamber, injector, igniter, combustion
chamber, nozzle, propellant tank, propellant feed system, and cooling sys-
tem [1]. The combustion chamber along with nozzle is commonly known
as the thrust chamber. It houses injectors and igniter, which atomizes the
liquid propellants, mixes and ignites, leading to the combustion of liquid
propellants. The main function of the combustion chamber is to produce
high-temperature and high-pressure gas due to burning of liquid propel-
lants. Hence, it must have arrays of propellant injectors that can produce
fine spray such that both fuel and oxidizer can be vaporized and mixed
Liquid-Propellant Rocket Engines ◾ 263
Liquid O2 Fuel
Gas Turbine
gear
2
Exhaust
Fuel
LOX pump
pump
Gas generator
Injector head
Igniter
Spray
Nozzle
well for combustion to take place within a shorter zone of the combustion
chamber. In order to have better quality spray requisite average droplet
size and distribution, propellant must be fed into the injectors at high pres-
sure. For this purpose, the propellant feed system needs to be designed
and developed properly. Several propellant feed systems have been devel-
oped, which will be discussed in subsequent sections. Of course, the pro-
pellant must be stored in high-pressure tank, particularly in small rocket
engine. However, turbo-pumps are used to feed high-pressure propellants
in larger LPRE. The function of ignition system is to provide certain initial
ignition energy for initiation of combustion. Of course, in certain liquid
propellants known as hypergolic propellants, there is no need to have an
ignition system. As high temperature is required to produce high thrust,
264 ◾ Fundamentals of Rocket Propulsion
8.3 TYPES OF LIQUID-PROPELLANT
ROCKET ENGINES
Several types of liquid-propellant rocket engine have evolved from the time
of its inception way back in 1926. Based on single liquid or two liquids, it
can be broadly classified into two types: (1) monopropellant rocket engine
and (2) bipropellant rocket engine [2–5].
Regulatory valve
Propellant
Gas tank
Fuel line
Fuel
Gas generator
Turbine
Shaft
Cooling system
Nozzle
Pump
Oxidizer
Control valve
Thrust chamber
Example 8.1
A monopropellant rocket engine is to be designed to produce thrust
of 55 N with specific impulse of 169 s using hydrazine fuel. If the
mass flux through the hydrazine catalytic bed is 220 kg/m2s, deter-
mine the diameter of this bed.
Solution
The mass flow rate of hydrazine propellant can be determined as
F 55
=
m = = 0.572 kg/s
I sp g 169 ´ 9.81
m 0.572
Ab = = = 0.0026 m2
²
m 220
4 ´ 0.0026
Db = = 0.056 m
3.14
OX
OX
F
mixing of fuel and oxidizer does take place in a narrow zone of combustion
chamber as shown in Figure 8.4. The gaseous or liquid or, both, gaseous
and liquid propellants undergo complex chemical reactions with several
intermediate products, liberating large amount of heat within a narrow
zone of combustion chamber. Depending on the droplet size of the spray,
several liquid droplets move with gas across entire combustion zone even
till the end of combustion chamber, making the flow to be inherently two-
phased in nature. During the early stage of the two-phase flow, droplets
moving at velocity of 50–100 m/s can cause drag to gas flow, but subse-
quently accelerate the gas flow due to both vaporization of droplets and
heat release caused by burning of fuel. Besides this, turbulent diffusion
of active species such as H, OH, and H2 makes the flow more complex
and difficult to handle analytically. The occurrence of recirculation zone
and turbulent vortices of gas around the injector augments the mixing and
heat transfer, which helps vaporization and combustion. Note that the pro-
cesses are so complex that they would not be occurring sequentially as
described. Rather, some of these processes occur simultaneously. Besides
this, it is difficult to decide which process has the greatest influence on the
combustion of propellants.
The combustion in the liquid rocket engine is quite dynamic because
the flame front moves across the entire mass, which might be caused due
to intense turbulence level in the gases of the combustion chamber. The
residence time of both fuel and oxidizer is quite small, that is, even less
than 10 ms. The heat release rate per unit volume in typical rocket engine is
Liquid-Propellant Rocket Engines ◾ 269
1000 MW/m3, which is even 100 times compared to typical aerogas turbine
combustor in aircraft, because the higher rate of heat release during the
combustion of propellant takes place at high-pressure and high-tempera-
ture conditions (see Table 8.1) prevailing in rocket engine. The droplet size
range for rocket engines is higher as compared to aerogas turbine combus-
tor. Hence, in the case of rocket engine, diameter and length of combustion
chamber is chosen judiciously such that most of the droplets are at least
vaporized in the combustion chamber itself. In contrast, complete com-
bustion of droplets takes place within the initial portion of combustion
chamber length of aerogas turbine engine as later portion of combustion
chamber is used to ensure uniform temperature at its exit.
We will now explore how different phases take place in the combus-
tion chamber for two types of liquid propellants, namely, (1) hypergolic
and (2) nonhypergolic. In case of hypergolic propellant combustion, injec-
tors are designed such that both fuel and oxidizer are mixed in the liquid
phase itself as they can react easily in the liquid phase to produce certain
amount of heat while undergoing exothermic chemical reactions. For
example, certain hypergolic propellants like triethylamine (fuel) and nitric
acid (oxidizer) or xylidine and nitric acid can be mixed in liquid phase to
form stable solution even at low temperature and pressure. The heat liber-
ated during liquid phase exothermic reactions is utilized to vaporize the
liquid fuel–oxidizer mixture and hot gases are produced quickly, which
helps in initiating chemical reactions in gaseous phase without any aid of
external ignition energy. Hence, actual combustion between both fuel and
oxidizer will take place leading to formation of burnt gas that mixes with
other vapor. This intense mixing of fuel and oxidizer in gaseous phase can
270 ◾ Fundamentals of Rocket Propulsion
Hypergolic propellant
Mixing in
liquid phase Atomization of
F and OX
Chemical
reactions Vaporization Flame
in gas
phase
Group
droplets
Reactions
Vaporized in vapor Droplets
reaction in gas phase
phase
Premixed flame
Combustion products
(a)
Nonhypergolic
propellant
Spray forming
of droplets
Primary Heterogeneous
atomization mixing of liquid
and gas phase
Vaporization of
secondary
atomization Droplet
combustion and
spray combustion
Gas phase
mixing
Gas phase
diffusion flame
Premixed
flame
Combustion
products
(b)
Hence, exothermic reactions that occur during the gas phase reactions are
used to vaporize the liquid propellants such that they can be converted
into gaseous phase before being ignited for sustenance of combustion pro-
cess. That means, the combustion processes will be influenced by the heat
release rate and physical properties of liquid propellants. Although there
might be liquid phase mixing as shown in Figure 8.5b during atomization
process, but there would not be any chemical reactions in the liquid phase.
During this process, some of the liquid-propellant droplets can get vapor-
ized into gas phase. This vaporization process can be influenced by heat
release from both homogeneous and heterogeneous combustion processes,
as some of the liquid fuel droplets can be floated as single droplet or cluster
of droplets or cluster of group droplets. When vaporized fuel from a single
or group of droplets comes in contact with gaseous oxidizer, diffusion flame
272 ◾ Fundamentals of Rocket Propulsion
vv trg vv
Specific volume, v
Specific volume, v D
tlc
A B
ti trg
tr
(a) Time, t (ms) (b) Time, t (ms)
FIGURE 8.6 Variation of specific volume with time for (a) hypergolic and
(b) nonhypergolic combustion.
t r = t i + t rg (8.3)
274 ◾ Fundamentals of Rocket Propulsion
Vc = L* At ; Vc = Lc Ac (8.4)
where
Lc is the combustor chamber length
Ac is the combustion chamber cross-sectional area
L*
= f1 ( t i ) + f 2 ( t rg ) (8.5)
C*
mg
t rg = (8.6)
m
mg r g V r g L*C *
t rg = = = (8.7)
m m
Pc
Liquid-Propellant Rocket Engines ◾ 275
Pc
f 2 ( t rg ) = × t rg (8.8)
r g C *2
By assuming the specific heat ratio γ to remain constant across the entire
combustion zone up to the throat of the nozzle, we can have
Pc
= G2 (8.9)
r g C *2
Then, we can have a simple expression for the characteristic length L*,
which is given by
L*
= G2t rg (8.10)
C*
Vc = L* At = G2t rg At (8.11)
Note that for design of liquid-propellant rocket engine, the specific heat
ratio γ can be considered as 1.25; then we can evaluate the combustion
chamber volume Vc easily by knowing the residence time in gas phase trg.
For most cases, experimental studies indicate that the residence time in
gas phase trg varies from 2 × 10−3 to 7 × 10−3 s. But in order to evaluate
the volume accurately, we need to evaluate f1(ti). But this residence time
function f1(ti) is dependent on the injection system. In other words, it is
dependent on the injection pressure drop across fuel ΔPF and oxidizer
ΔPox, and chamber pressure, turbulence level, type of injector and its
arrangement, and type of propellants used in liquid-propellant rocket
engine. It is quite difficult to develop a general expression for f1(ti),
and this is not yet possible. However, experimental data can be used
for design purposes. Besides this, the characteristic length L* can be
obtained experimentally. As mentioned earlier, characteristic length L*
is dependent on the nature of propellant, as evident from the experimen-
tal data shown in Table 8.2.
276 ◾ Fundamentals of Rocket Propulsion
which we can derive the static pressure ratio with assumption of Rayleigh
flow [6,7], given as follows:
P2 1 + gM12
= (8.12)
P1 1 + gM22
Then the total pressure ratio between stations (1) and (2) can be derived
easily as
g
é g - 1 2 ù g -1
1+ M2 ú
Pt 2 1 + gM12 ê 2
= ê ú (8.13)
Pt1 1 + gM22 ê g - 1 2 ú
1+ M1
ë 2 û
g
é g - 1 2 ù g -1
1+ M2 ú
P2 1 Pt 2 êë 2 û
= ; = (8.14)
P1 1 + gM22 Pt1 1 + gM22
g +1
Ac A2 1 é 2 æ g - 1 2 ö ù 2( g -1)
= * = 1+ M2 ÷ ú (8.15)
At A M2 êë g + 1 çè 2 øû
Assuming the specific heat ratio γ to be around 1.25 for typical liquid-
propellant combustion, we can determine the exit Mach number M2 for typ-
ical set of the cross-sectional area ratio εc = A2/At, as shown in Figure 8.7. It
can be noted that Mach number decreases with increase in the cross-sectional
area ratio εc. In contrast, both static and total pressure ratios increase with the
cross-sectional area ratio εc. Although it is prudent to use the cross-sectional
area ratio εc = A2/At = 1 corresponding to straight nozzle, the cross-sectional
area (contraction) ratio εc between 1.2 and 4 is used routinely.
278 ◾ Fundamentals of Rocket Propulsion
1.0 1.0
0.9
0.8
0.8
P2/P1
0.6
P2/P1
M2
M2
0.7
0.4
0.6
0.2
0.5
0.4 0.0
1 2 3 4 5 6
Ac/At
FIGURE 8.7 Variation of Mach number, M2, static and total pressure ratios with
cross-sectional area ratio εc for γ = 1.2.
Injector Injector
Throat Throat
Nozzle Nozzle
FIGURE 8.8 Various shapes of combustion chamber: (a) spherical, (b) near
spherical, and (c) cylindrical.
Example 8.2
In a liquid-propellant rocket engine, propellant is injected into its
combustion chamber at pressure of 6 MPa and temperature of 3800 K.
If the residence time happens to be 0.7 ms, determine the length of
cylindrical combustion chamber. Assume that instantaneous com-
bustion occurs, which produces flow with Mach number of 0.3. Take
γ = 1.2 and MW of product gas = 25.
Solution
The theoretical characteristic velocity of this engine can be deter-
mined as
g +1 1.2 +1
æ 2 ö g -1 æ 2 ö 1.2 -1
as G = g ç ÷ = 1. 2 ç = 0.649
ç ( g + 1) ÷ ç (1.2 + 1) ÷÷
è ø è ø
Pc 6 ´ 106 ´ 25
rg = = = 4.75 kg/m3
RTc 8314 ´ 3800
g +1
Ac 1 é 2 æ g - 1 2 ö ù 2( g -1)
= 1+ M2 ÷ ú
At M2 êë g + 1 çè 2 øû
1.2 +1
1 é 2 æ 1. 2 - 1 2 ö ù 2(1.2 -1)
=
0.3 êë 1.2 + 1 çè
1 +
2
( 0 . 3 ) ÷ú = 2.07
øû
Vc Vc At A L* A
Lc = = = L* t = * C * t
Ac At Ac Ac C Ac
= 0.29 ´ 10-3 ´ 1732 ´ 2.07 = 1.04 m
Pressure spike
Time (ms)
the acoustic or below acoustic range, caused due to the positive feedback
between the heat release rate during the process of propellant combustion
and flow field disturbance. Figure 8.9 indicates a typical variation of cham-
ber pressure with time of a liquid rocket engine. A liquid rocket engine is
considered to be operated under stable condition, although there will be
random fluctuations in pressure, as shown in Figure 8.9, however, with
lower limits around its mean value. There might be some instances when
a single large amplitude, as shown in Figure 8.9, known as pressure spike
occurs during its operation. If this pressure fluctuation happens to inter-
act with the natural frequency of the feed system or the acoustic frequency
of the combustion chamber, it may lead to the formation of periodic pres-
sure oscillations at certain characteristic frequency. These oscillations may
be amplified or maintained or dampened out by the combustion process.
These sustained oscillations during combustion process in the combustion
chamber are often termed as combustion instability. By carrying out the fast
Fourier transform (FFT) analysis of pressure time history, it can be found
out during combustion instability phase that the pressure fluctuations have
several definite frequencies. In other words, the combustion instabilities
have more natural acoustic frequencies, which can cause several detrimen-
tal effects. As discussed in Chapter 9, depending on the range of frequency,
combustion instability can be broadly classified into three kinds: (1) LFI, (2)
IFI, and (3) HFI. When combustion instability occurs below 400 Hz, then
it is termed as low frequency instability (LFI). This is also known as chug-
ging/system instability, which mainly results due to coupling between the
combustion and propellant feed system. Intermediate frequency instability
282 ◾ Fundamentals of Rocket Propulsion
(IFI) is likely to occur in the frequency range of 400–1000 Hz, which is also
known as buzzing/entropy wave. This frequency is believed to be caused
due to pressure fluctuations in injector and manifold caused by flow eddies,
mechanical vibrations of engine, and propellant feed system resonance.
Beyond 1000 Hz, it is known as high frequency instability (HFI), which is
attributed to the coupling between the pressure oscillation and heat release
rate. This is often termed as screaming/screeching. Recall that based on the
predominant acoustic mode, combustion instabilities can be classified into
various types. Generally, three predominant modes, namely, longitudinal
(axial), transverse, and radial modes, and their combinations in different
frequency ranges can occur during the combustion processes in the liquid
rocket engine. We will discuss these modes in liquid rocket engine in subse-
quent sections. Note that sizable combustion oscillations, either periodic or
random, are considered to be detrimental for the overall performance and
life of the liquid rocket engine, because pressure oscillation of 10% about its
mean value can cause a thrust oscillation of 10%–100% of the mean thrust.
Such oscillations can have a coupling with other portions of vehicle and can
develop abnormal stresses on engine components and thus spoil the normal
operation of other onboard systems. The form of self-excited combustion
instability that is linked to the structure of rocket engine is often termed as
POGO, which occurs mainly in large vehicles in the range of a few hertz to
1000 Hz, particularly close to burnout time. That is why, pressure oscillations
in liquid rocket engines greater than its mean value by 5% is considered to be
a serious concern to the designer, which must be avoided at any cost.
We have learnt that low-frequency combustion instability is not deadly
but need to be attended to as it affects the performance of the rocket engine
and is accompanied with chugging sound. The combustion efficiency
decreases by as much as 20% due to the occurrence of low-frequency insta-
bility (LFI). This is mainly caused by the phase difference between feed
system response and combustion chamber pressure oscillation. Hence, it
can be controlled by isolating the pressure oscillation in the combustion
chamber such that it cannot be sensed by the feed system. One way of
accomplishing this is to increase the pressure drop across the injector. The
frequency and the amplitude of this low-frequency instabilities are depen-
dent on the characteristic length L*, the chamber pressure Pc, and the pres-
sure difference across injector ΔPi. Experimentally, it has been observed
that both amplitude and frequency decrease with increase in the charac-
teristic length L*. But with an increase in chamber pressure, amplitude of
instability decreases accompanied with an enhancement in its frequency.
Liquid-Propellant Rocket Engines ◾ 283
dm
=m
g -m
n (8.16)
dt
where the first term dm/dt in Equation 8.16 represents the rate of mass
accumulation in combustion chamber, m g is the mass generation due
to propellant burning, and m n is the mass flow rate leaving through the
nozzle. Recall that certain residence time tr is required before complete
combustion of propellant. Hence, the gas mass flow rate m g generated dur-
ing combustion corresponds to the mass flow rate of propellant m p that is
injected before time (t − tr). Hence, Equation 8.16 can be written as
dm
=m
p ,( t -t r ) - m
n (8.17)
dt
p = Cd Ai 2r ( Pi - Pc )
m (8.18)
where
Pi is the injection pressure
Pc is the chamber pressure
284 ◾ Fundamentals of Rocket Propulsion
where
Pc is the chamber pressure
At is the throat area
C* is the characteristic velocity
dm d ( PcVc /RTc ) é AP
= = Cd Ai 2r ( Pi - Pc ) ù - t * c (8.20)
dt dt ë û t -t r C
as
)
RTc At G2C *
= * (8.21)
*
L Vc C * L
é Pc ¢ ù
RTc
Vc
é
{ (
êëCd Ai 2r Pi - Pc + Pc
¢
)} ùúû t -t r
=
RTc Pc At
Vc C *
ê1 - ú
ë Pi - Pc û t -tr
Note that Cd Ai 2r ( Pi - Pc ) = Pc At / C * for steady state flow condition.
(8.22)
dPc G2C * æç é P¢ ù ö
= * Pc ê1 - c ú - Pc ÷ (8.23)
dt L ç
è ë Pi - Pc û t -tr ÷
ø
Note that L*/(Γ2C*) is the nondimensional time, which can be considered
as residence time tr of propellant in the combustion chamber. Using the
residence time and expanding root term in Equation 8.23, we can get
Liquid-Propellant Rocket Engines ◾ 285
dPc Pc é 1 æ Pc ¢ öù Pc
= ê1 - ç ÷ú - (8.24)
dt t r êë 2 è Pi - Pc ø úû t -tr t r
dPc Pc Pc (1 + b ) Pc
= éë1 - by ùû t -t - ; b= (8.25)
dt t r r tr 2 ( Pi - Pc )
dy y byt -tc
+ + = 0; as Pc = Pc + Pc¢ = Pc (1 + y ) (8.26)
dt t r tr
y = Ae (
a +iw)t
(8.27)
Note that the growth constant α is less than zero, pressure perturbation
decreases with time. In contrast for α > 0, the amplitude of pressure oscilla-
tions grows with time. Of course for α = 0 the amplitude of pressure oscil-
lations remains constant with time.
By solving Equation 8.27, we can derive expression for combustion
delay time tC and residence time tr corresponding to the stable condition
(α = 0) as
p - tan -1 b2 - 1
tC = (8.28)
w
b2 - 1
tr = (8.29)
w
tC
=
(
p - tan -1 b2 - 1 ) (8.30)
tr b2 - 1
286 ◾ Fundamentals of Rocket Propulsion
tC
>
(
p - tan -1 b2 - 1 ) (8.31)
tr b2 - 1
In other words, for this condition the combustion instability can occur
when ( DPi / Pc ) < 1/2. Note that this injection pressure drop, ΔPi, depends
on the chamber pressure and feed line pressure. In order to avoid the bulk
mode of combustion instability, pressure drop across injector ΔPi must
be less than half of the average chamber pressure. This is known as the
Summerfield criterion for combustion stability which can be rewritten for
fuel and oxidizer streams of bipropellant rocket engine as
Example 8.3
In a liquid-propellant rocket engine, propellant is injected into its
combustion chamber of 0.5 m length at pressure of 1.2 MPa with pres-
sure drop of 0.4 MPa. If the combustion delay time and residence time
happen to be around 12 and 4.5 ms, respectively, determine its fre-
quency of oscillation. Is it subjected to combustion instability or not?
Solution
We know that for stable combustion bulk mode, the criterion is given
by Equation 8.30:
tC
=
(
p - tan -1 b2 - 1
=
) (
p - tan -1 (1.118
= 2.06
)
tr b2 - 1 1.118
Liquid-Propellant Rocket Engines ◾ 287
Pc 1. 2
b= = = 1.5; b2 - 1 = 1.52 - 1 = 1.118;
2 ( Pi - Pc ) 2 ´ 0.4
t C 12
= = 2.67
t r 4. 5
p - tan -1 b2 - 1 w
w= = 191.58 rad/s; f = = 30.51 Hz
tC 2p
8.6.2.1 Chemical Method
In this method, chemical additives are used to dampen the heat release
profile in the combustion chamber by a factor of 2 or more. The type of
additives is specific to the propellant. Besides this, this chemical addi-
tive can augment the droplet shattering, and thus alters the heat release
profile to dampen the combustion oscillations. It has an advantage that
no changes in hardware are called for to control combustion instabilities,
unlike in other methods.
8.6.2.2 Aerodynamic Method
The combustion instability can be minimized by changing the prevailing
aerodynamic of the combustion chamber, which can be carried out by the
288 ◾ Fundamentals of Rocket Propulsion
8.6.2.3 Mechanical Method
In this method, several mechanical fixtures, namely, baffles, acoustic
dampers, ablative liners, and so on are devised to prevent high-frequency
oscillations in liquid-propellant combustion chamber. Generally, baffles at
the injector head, as shown in Figure 8.10, are provided to dampen the
destructive mode of combustion oscillations. Besides this, they can prevent
the higher mode of oscillations to derive energy from the mean flow to sus-
tain their further growth. These are mainly designed on the assumptions
Baffles
Baffle/spoke
Hub
(a) (b)
FIGURE 8.10 Types of baffles: (a) radial and (b) hub and spoke.
Liquid-Propellant Rocket Engines ◾ 289
that highest heat release rate (chemical reactions zone) that drives the
combustion oscillations occurs near the injector face. It is believed that it
minimizes the coupling between the heat release rate and acoustic oscil-
lations and thus reduces the amplification of gas dynamic forces within
combustion chamber. Hence, the depth of the baffles must be selected such
that they can cover the heat release zone. As they are placed in the highest
heat release zone, they must be strong enough to resist the thermal load
even under pressure oscillations conditions. But the depth of the baffles
should be such that individual compartments of combustion zone must
not be created with their own acoustic characteristics. Note that odd num-
ber of baffles is being used by most designers as even number of baffles
can enhance standing modes of combustion instability. Generally, baffles
are more effective for both radial and tangential modes of oscillations. The
transverse acoustic modes of oscillations can be minimized by provid-
ing certain number of radial baffles with sufficient depth along the axis
of the combustion chamber. During the transverse mode of combustion
oscillations, acoustic energy is being lost due to high-velocity turbulent
flow at the tips of baffles. Based on empirical design, several possible baf-
fles, shown in Figure 8.10, have been evolved, which are being deployed
in rocket engines. In order to avoid radial modes of oscillations, circular
baffles with radial blades can be employed such that standing waves can
be interrupted easily. Based on experimental studies, certain guidelines
for baffle design have been developed particularly for number of baffles
and their depths. It has been observed that the spinning tangential mode
of oscillation can be eliminated using a two-bladed baffle, while first and
second tangential modes can be avoided using three-blade baffle design.
A periodically arranged four-blade baffle can be deployed to reduce second
tangential mode of oscillations. The blade depth of 15%–30% of the cham-
ber diameter with lower sizes with large diameter LPR engine is preferred
to dampen oscillations.
Another way of dampening the combustion oscillation is to absorb the
energy in the combustion chamber. Generally, artificial acoustic absorbers
such as acoustic liners and discrete cavities are devised, which can be used
along the wall of the combustor or near the injector. It can be noted that
cavities are being used routinely particularly at the corner of the injector
face as pressure antinode exists for almost all resonant modes of vibration,
including longitudinal, tangential, radial, and combination of these oscil-
lations and velocity oscillations attains a minimum value.
290 ◾ Fundamentals of Rocket Propulsion
8.7 IGNITION SYSTEMS
The combustion of liquid propellants in the thrust chamber can be ini-
tiated by a suitable ignition system. Several ignition systems for both
thrust chamber and gas generator have been designed and developed
over the years for successful applications in rocket engines. Proper selec-
tion of ignition system depends on the nature and phase of propellants,
need for restart, system safety, altitude relight capability, weight, and space
considerations. For example, with regard to hypergolic propellants, bet-
ter mixing of propellants can be good enough to ignite them. But in case
of bipropellant, rapid, reliable ignition of incoming propellants must be
ensured before propellants are accumulated in the combustion chamber.
Otherwise, if ignition delay is too large, ignition of accumulated propellant
can lead to explosion. Note that proper ignition of liquid propellants in the
thrust chamber is dependent on proper selection of the ignition method,
quality of design, and integrity of ignition system.
As mentioned earlier, the main function of igniter is to supply requi-
site but sufficient amount of heat energy to initiate the chemical reactions
in the main propellant. Generally, igniter draws its energy from the lim-
ited stored energy onboard with the rocket engine to initiate combustion.
Besides, it is essential to have flow of propellant during ignition. Generally,
the starting propellant flow rate is kept lower than the full flow rate, which
not only smoothens the ignition process but also prevents an excessive
accumulation of unignited propellants. As a result, a quite different fuel/
oxidizer mixture ratio around stoichiometric condition is maintained for
successful ignition of propellant mixture, because initial vaporization and
mixing of propellants happen to be poor due to low starting injection
velocity of propellant. It is essential that once propellant is ignited, it must
remain on combustion mode as it acts as pilot ignition source for fresh
propellant entering into the thrust chamber. Although several igniters have
been devised and used in various liquid-propellant rocket engines, we will
restrict our discussion to the following five types of igniters: (1) catalytic
igniter, (2) hypergolic igniters, (3) spark plug and spark-torch igniters, and
(4) resonance igniters.
H2 Hypergolic slug
O2
H2 Oxidizer
(a) (b)
Electrode
Resonator cavity
Insulator H2 O2
Sonic orifice
Ground electrode
(c) (d) Torch outlet
FIGURE 8.11 Types of igniter: (a) catalytic, (b) hypergolic, (c) spark plug, and
(d) resonance.
8.8 COOLING SYSTEMS
We know that heat release in the case of rocket engine is quite high, in
the order of 30,000 MW/m3. As a result, temperature in the range of
3000–3500 K prevails in the combustion chamber of liquid-propellant
engine, which is much higher than the melting temperature of most avail-
able metal alloys used for rocket engines. Recall that strength of wall mate-
rials decreases at high temperature, which is likely to fail structurally under
high temperature and pressure condition. Of course one can use thicker
wall to circumvent the problem of heating which is allowed in rocket
design as it is essential to minimize the mass of vehicle at particular oper-
ating condition. Hence, cooling system is used to lower the wall tempera-
ture of combustion chamber and nozzle. The most vulnerable part of the
rocket engine is the throat of the nozzle where heat transfer rates are one
order of magnitude higher than the exit portion of exhaust nozzle. Several
methods such as (1) regenerative cooling, (2) film/sweat cooling, and (3)
ablative cooling have been adopted for cooling of rocket engines, which are
discussed in the following.
8.8.1 Regenerative Cooling
This is the most widely used cooling system for liquid-propellant rocket
engine. In this case, liquid fuel/oxidizer is employed as a coolant, which
Liquid-Propellant Rocket Engines ◾ 295
Liquid fuel
F Fuel
Ox Ox
F Fuel
Liquid fuel
Graphite
F F Carbon
Ox Film Ox phenolic
F F
Porous wall
(c) (d) Silica phenolic
FIGURE 8.12 Schematic of cooling system: (a) regenerative cooling, (b) film
cooling, (c) transpiration cooling, and (d) ablative cooling.
8.8.2 Film/Sweat Cooling
In this film cooling process, a thin film of coolant is formed on the inner
side wall of the thrust chamber, as shown in Figure 8.12b, which acts as
an insulating layer. Note that the coolant on the film absorbs heat from
the hot gases due to both sensible and latent heat absorption. As a result,
296 ◾ Fundamentals of Rocket Propulsion
the temperature of film is much lower than that of the hot combustion
products. This is an effective way to protect the wall of the thrust cham-
ber from hot gases by directing the cooling air into boundary layer to
provide a protective cool film along the surface. In certain practical sys-
tems, injectors are designed such that fuel-rich mixture layer prevails
near the inner wall of the thrust chamber. The temperature of this fuel-
rich mixture layer is much lower than that of the oxidizer-rich mixture
in the core of thrust chamber. Besides this, fuel-rich mixture as film
layer is preferred over oxidizer-rich mixture as oxidation of metal can be
reduced drastically.
The effect of film cooling is dependent on the coolant mass flow rate,
velocity of coolant, number of rows of cooling holes, and so on. If too
much coolant is injected into boundary layer or its velocity is too high,
then the coolant may penetrate into the boundary layer, defeating the
main purpose of using film cooling. In order to overcome this problem,
sweat/transpiration cooling method, shown in Figure 8.12c, can be used,
in which the cooling air is forced through porous walls of thrust chamber
into boundary layer to form relatively cool, insulating film. This is consid-
ered to be the most efficient cooling technique, but it is not being used in
practice due to nonavailability of suitable porous materials that can with-
stand high-temperature and high-pressure gases in the thrust chamber.
Note that the pores should be small to enhance cooling rate. However,
this can lead to pore blockage due to soot particles or foreign material.
It is also more economical as only 1.5%–2% of the total coolant (fuel/
oxidizer) mass flow rate can reduce, the blade temperature in the range of
200°C–300°C.
8.8.3 Ablative Cooling
In this cooling system, insulating material that melts and vaporizes at
high temperature is used on the combustion gas side walls of the thrust
chamber. As a result, lower wall temperature as compared to combus-
tion product gas temperature is maintained, as its temperature remains
almost constant corresponding to melting point. This kind of cooling, in
which thermal erosion is used to maintain low temperature, is known as
ablative cooling (see Figure 8.12d). Besides this, ablative material being
good thermal insulator allows low rate of heat transfer to the outer struc-
ture. Some ablative composite materials from epoxies, unsaturated poly-
ester, phenolic resin along with silica and carbon fibers are produced for
use in rocket engines. Two popular composites, namely, carbon phenolic
Liquid-Propellant Rocket Engines ◾ 297
and silica phenolic, which ablate around 1400 K, are being used in rocket
engines. However, silica phenolic is being preferred in current times
due to its higher thermal insulating characteristics and higher oxidation
resistance. The inner wall of the thrust chamber is lined with a layer of
ablative composites, as shown in Figure 8.12d, which protects it from
high-temperature hot gases in the thrust chamber. The ablative cooling
system is being used in solid propellant and low chamber pressure liquid
propellant short-duration rocket engines.
Hot gas
Ttg
Vg2
2CP Tg
Twc Tc
Twh
Coolant
∆L
Twa - Tg
RF = (8.33)
Ttg - Tg
For subsonic flow, RF is equal to 1.0, while for supersonic flow, RF will be
less than 1.0. Note the supersonic flow prevails in the exhaust nozzle for
rocket engine. For Mach number 4.0, RF is found out to be 0.91 [4]. At the
throat of rocket engine, sonic condition prevails, as flow is considered to be
Adiabatic wall
(Q = 0)
Ttg
Twa
T Vg2
2CP
Tg
æ 2 ö æ 2 ö
Tg* = Ttg çç ÷÷ = 3000 ç ÷ = 2666 K (8.34)
g
è g + 1 ø è 1.25 + 1 ø
( )
Twa = Tg* + RF Ttg - Tg* = 2970 K (8.35)
The difference between Twa and Ttg happens to be within 1% error, which
falls within experimental error. Hence, we can assume Twa to be equal to
Ttg at the throat of nozzle.
By considering one-dimensional steady flow heat transfer, we can deter-
mine convection heat transfer rate per unit as H ²g , given as follows:
where
hg is the heat transfer coefficient of hot gas
Twa is the wall temperature under adiabatic condition
Twh is the well temperature on hot gas side
Besides, heat transfer from the hot gases to the well can also take place due
to radiative heat transfer mode. Note that same amount of heat transferred
from hot gas to the wall due to both radiative convection heat transfer
modes will be transferred to cold side of wall due to heat conduction under
steady-state condition. By considering one-dimensional heat transfer due
to conduction through the wall, we can determine H w² as
dT kw (Twh - Twc )
H w² = -kw = (8.37)
dx DL
where
kw is the thermal conductivity of wall
Twc is the wall temperature on the coolant side
ΔL is the wall thickness
300 ◾ Fundamentals of Rocket Propulsion
As the coolant flows through the coolant passage, heat has to transfer from
wall to the coolant due to convection. This convective heat transfer rate per
unit area due to convection of coolant H c² can be determined as
H c² = hc (Twc - Tc ) (8.38)
where
Tc is the coolant (liquid) temperature on free stream side
hc is the convective heat transfer coefficient of coolant
H r² = e g sTg4 (8.39)
where
εg is the emissivity of gas considering complexities of geometry and gas
properties
σ is the Stefan–Boltzmann constant (5.687 × 10−8 W/m2 ⋅ K4)
Tg is the gas temperature
H ² = H ²g + H r² = H w² = H c² (8.40)
Liquid-Propellant Rocket Engines ◾ 301
DL DL DL H ²
Twh = H w² + Twc = H ² + Twc = H ² + + Tc (8.42)
kw kw kw hc
H ² =
(Twa - Tc ) + H r² /hg (8.43)
1 DL 1
+ +
hg kw hc
( )
H ² Ag = H ²g + H r² Ag = H w² Aw = H c² Ac (8.44)
where
Ag is the gas side area
Aw is the effective wall area
Ac is the effective coolant side area
H ² =
(Twa - Tc ) + H r² /hg (8.45)
1 Ag DL Ag
+ +
hg Aw kw Ac hc
We need to determine the heat transfer coefficient for both hot gas and
coolant flow. The empirical relationship for Nusselt number Nu from the
302 ◾ Fundamentals of Rocket Propulsion
heat transfer literature that can be used for hot gas flow can be expressed in
terms of Reynolds number Re and Prandtl number Pr as follows:
0. 8 0. 4
hg D g æ rVD ö æ mC p ö
Nu g = = 0.026Re 0g.8 Prg0.4 = 0.026 ç ÷ ç ÷ (8.46)
kg è m øg è k øg
where
D is the local diameter of combustion chamber/nozzle
k is the thermal conductivity
μ is the viscosity
ρ is the density
V is the flow velocity
Cp is the specific heat corresponding to gas
Note that fluid properties are dependent on the gas temperature, which
is generally evaluated at average film temperature Tf between Tg and Twh
(Tf = 0.5(Tg + Twh)). The coolant side heat transfer coefficient can be evalu-
ated by using empirical relation, as given in the following:
0. 8 0.33
hD æ rVD ö æ mC p ö
Nuc = c c = 0.023Rec0.8 Prc0.33 = 0.023 ç ÷ ç ÷ (8.47)
kc è m øc è k øc
where
D is the local hydraulic diameter of combustion chamber/nozzle
k is the thermal conductivity
μ is the viscosity
ρ is the density
V is the flow velocity
Cp is the specific heat corresponding to coolant
value of Re and Pr. Hence, designer can choose coolant with higher spe-
cific heat to have maximum heat transfer. Generally, hydrogen is chosen
in rocket engine as coolant as it has higher specific heat. Recall that maxi-
mum heat transfer rate per unit area occurs at the throat of the nozzle;
hence, higher coolant flux can be used to augment the heat transfer coef-
ficient by choosing proper cross-sectional area of the coolant passage.
The density of coolant being constant, coolant velocity is to be increased
by decreasing cross-sectional area of the coolant passage at the throat
region. Generally, coolant velocity in the range of 15–25 m/s is used in
throat region.
Example 8.4
The combustion chamber with 0.45 m diameter of a liquid propel-
lant engine is cooled by regenerative cooling to maintain its outer
wall temperature at 300 K. The temperature and the pressure of com-
bustion chamber are maintained constant at 3000 K and 0.75 MPa,
respectively. The heat loss due to gas radiation happened to be 25%
of total heat loss. If the wall thickness happens to be 5.2 mm with
thermal conductivity of 21 W/m ⋅ K, determine inner wall tempera-
ture under steady-state condition. Consider Re = 106 , Pr = 0.73 ,
kg = 0.17 W/m ⋅ K.
Solution
We know by Equation 8.40, the heat flux through the wall can be
expressed as
H
As H r = w , then from Equation A we can have
4
4
H w = hg (Ttg - Twh ) (B)
3
Ttg - Twh
H w = (C)
é DL 4 ù
ê1 + k 3 hg ú
ë w û
304 ◾ Fundamentals of Rocket Propulsion
kg 0.17
( ) (0.73)
0. 8
0.026 ( Re ) ( Pr ) =
0. 8 0. 4 0. 4
hg = 0.026 106
D 0.45
= 546.44 W/m2 × s
3
Ttg - Twh
=
4h g
=
( 0.75/546.44 ) = 0.85 (D)
Ttg - TwC é 3 DL ù é 0.75 5.2 ´ 10-3 ù
ê + ú ê + ú
ë 4hg kw û ë 546.44 21 û
REVIEW QUESTIONS
1. What are the differences between liquid-propellant and solid-
propellant rocket engines?
2. What are the advantages of liquid-propellant engine over solid-
propellant rocket engine?
3. What are the disadvantages of liquid-propellant engine over solid-
propellant rocket engine?
4. What is a monopropellant rocket engine? How is it different from
bipropellant rocket engine? What are its applications?
5. What is hypergolic propellant combustion? How is it different from
nonhypergolic propellant combustion?
6. Define combustion delay time? How is it different from chemical
delay time?
7. Define chemical delay time? How can it be determined for liquid
propellant?
8. What do you mean by characteristic length L*? How is it different
from combustion chamber length?