Catalysts
Catalysts
www.tib-chemicals.com
BASIC CHEMICALS | INORGANIC SPECIALTY CHEMICALS | COATING SYSTEMS
INORGANIC
BASIC CHEMICALS SPECIALTY CHEMICALS COATING SYSTEMS
Construction Chemicals
These products include acids and Based on the elements tin, zinc, Polyurethane- and epoxy-based
zinc- and sulphur-based chemicals copper, nickel and bismuth, these coating systems to prevent corrosion
for chemical companies, the metal- special chemicals are used for of pipelines and valves, water treat-
working industry, hot-dip galvanising, electroplating in the electronics and ment facilities and power plants.
electroplating, the textile and metalworking industries, as copper Thermal Curing Systems, such as
plastics industries, water treatment compounds in the automotive and hot dip coatings for electroplating
and production of foods and chemical industries, as catalysts and tool manufacturing, as well as
beverages. for producing resins, coatings and stoving varnishes for the packaging
paints, and as chromate reducers for industry. Bitumen Specialties for
building materials. use in building construction, civil
engineering and road paving.
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TIB KAT ® – THE TRADEMARK FOR HIGH-QUALITY CATALYSTS
Today’s catalysts have to meet increasingly complex In serving our customers, at TIB Chemicals we
requirements for a vast range of applications. Besides consistently strive to live up to this reputation.
enabling specific reaction profiles for individual And looking ahead, we want to be the partner of choice
applications, they also have to comply with strict rules for developing catalysts to meet your special wishes and
on environmental compatibility and low toxicity. adapting them to meet your changing requirements.
1. ESTERISATION
2. TRANSESTERISATION / POLYCONDENSATION
3. URETHANE FORMATION
What all of the reactions shown have in common is that The catalysts listed on the following pages include a
they are catalysed by Lewis acids. Many metals exhibit wide range of Lewis acids of different strengths. They let
Lewis acid properties. Most TIB catalysts are based on you find the one with the most appropriate activity for a
tin, bismuth, zinc or sulphonic acids. given reaction profile.
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TIB KAT ® – THE RIGHT SOLUTION FOR EVERY REQUIREMENT
With the existing portfolio of TIB KAT ® types the Our expertise and many years of experience superbly
possibilities of current applications and properties are qualify us to support you, as our customer, in developing
far from exhausted new applications of your own.
TIB KAT 129 Stannous octoate TIB KAT 716 Bismuth carboxylate
TIB KAT P 129 TK 129 plasticiser blend TIB KAT 716 LA Bismuth carboxylate
TIB KAT 160 Stannous oxalate TIB KAT 716 XLA Bismuth carboxylate
TIB KAT 162 Stannous chloride, anhydrous TIB KAT 718 Modified bismuth catalyst
TIB KAT 188 Stannous oxide TIB KAT 720 Bismuth carboxylate
TIB Blend 98 SnCl2 dihydrate on silica vehicle TIB KAT 789 Bismuth oxide
TIB KAT 208 Dioctyltin di - (2 - ethylhexanoate) sol. TIB KAT MSA 70 Methanesulphonic acid 70 %
TIB KAT 214 Dioctyltin dithioglycolate TIB KAT MSA 99 Methanesulphonic acid 99 %
TIB KAT 216 Dioctyltin dilaurate (DOTL) TIB KAT SP Modified methanesulphonic acid
TIB KAT 217 Dioctyltin oxide blend TIB KAT MP Blocked methanesulphonic acid
TIB KAT 218 Dibutyltin dilaurate (DBTL) TIB KAT HES 70 Hydroxyethanic acid 70 %
TIB KAT P 218 DBTL - plasticiser blend TIB KAT SSSA Na - sulposuccinate
TIB KAT 220 Monobutyltin tris - (2 - ethylhexanoate) TIB KAT S40 Sulphosuccinic acid 40 %
TIB KAT 223 Dioctyltin dineodecanoate TIB KAT S70 Sulphosuccinic acid 70 %
TIB KAT 233 Dibutyltin diacetate (DBTA) TIB KAT 616 Zinc neodecanoate
TIB KAT 233 S Modified dibutyltin diacetate (DBTA) TIB KAT 620 Zinc octoate
TIB KAT 248 Dibutyltin oxide (DBTO) TIB KAT 623 Zinc acetylacetonate
TIB KAT 248 LC Dibutyltin oxide, special (DBTO) TIB KAT 634 Zinc oxalate
TIB KAT 250 Monobutyltin dihydroxychloride TIB KAT 635 Zinc acetate
TIB KAT 405 TIB KAT 218 - silane blend TIB KAT K15 Potassium octoate / DEG
TIB KAT 410 TIB KAT 232 - plasticiser blend TIB KAT 804 Copper oleate
TIB KAT 417 Dioctyltin oxide blend TIB KAT 808 Copper naphthenate
TIB KAT 422 Dioctyltin - silane blend TIB KAT 812 Cer octoate
TIB KAT 423 Dioctyltin - silane blend TIB KAT 815 Iron acetylacetonate
TIB KAT 424 TIB KAT 248 - plasticiser blend TIB KAT 816 Zirconium octoate
TIB Si 2000 OH - fct., activ. polydimethylsiloxane TIB Tinex T Synthetic amorphous silicic acid
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TIB KAT ® FOR OLEOCHEMISTRY
Sustainability: oleochemicals are closely tied to this TIB KAT ® catalysts let you achieve especially high
concept. These chemicals based on renewable raw reaction activity and yields. The resulting products
materials are playing an increasingly important role in contain extremely low by-product concentrations and
our lives today. are visually very attractive.
Ester surfactants
Lubricant esters
Cosmetic esters
Solvent esters
Plasticisers:
ESTERISATION PRODUCTS
TIB KAT 160 High activity, easy to remove, wide range of uses
TIB KAT SP For low reaction temperatures, good final product colours, easy to remove
TRANSESTERISATION PRODUCTS
TIB KAT 232 Octyltin - based catalyst with wide range of uses, with more favourable toxicological profile than TIB KAT 248
TIB KAT
Liquid catalyst, highly active, soluble in ester
233 / 233 S
Organotin catalysts
Sulphonic acids
Zinc catalysts
Metal soaps
Titanates
CATALYST REMOVAL
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TIB KAT ® FOR BINDERS
The complex properties of modern coatings are largely The quality of a catalyst depends on its catalytic activity,
determined by the binders they contain. Besides but also on various other factors. TIB KAT ® stands for
influencing the attributes of the resins, binders also effective catalysts which help minimise unwanted by-
affect usability. The use of high-quality binders also products while improving the colour of the final product
permits the manufacture of paints and coatings which and preventing turbidity.
are able to withstand a variety of environmental
conditions.
Polyester resins
Polycarbonates
PET glycolosis
Polylactides
polyesters
POLYESTER RESINS
TIB KAT 162 Lower residual polyol activity than with isocyanates
TIB KAT
Wide range of uses, suitable for polyesters with low and medium molecular weights
248 / 248 LC
TIB KAT 250 Low start temperatures (160 °C), high activity
Extremely efficient catalyst, especially for polyesters with low and medium
TIB KAT 256
molecular weights
Silicone - modified
Water - reducible
Short - oil alkyds
alkyd resins
alkyds
alkyds
ALKYD RESINS
TIB KAT
Wide range of uses, causes only minimal turbidity with soy oils
248 / 248 LC
TIB KAT 251 Does not change drying times of air - drying alkyds
TIB KAT 256 Very good substitute for lead oxide, excellent for IPA - and TA - based formulations
TIB KAT 635 Good colours, especially with medium - and long - oil alkyds
Polyester synthesis,
two - stage process
Stabiliser,
UNSATURATED POLYESTERS
TIB KAT
Wide range of uses
248 / 248 LC
TIB KAT K15 Substitute for cobalt octoate, enables low colour values
TIB KAT SSSA Monomer for alkyd and polyester resins, no amines required
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TIB KAT ® FOR PAINTS AND COATINGS
Modern paints and coatings have to meet diverse As the expectations that these products have to meet
requirements – and so do the catalysts used to have increased, so have the requirements for catalysts.
produce them. The utilisation and curing times of paints and coatings
are determined by the catalysts used to make them.
Automotive paints have to satisfy enormous aesthetic The TIB KAT ® types meet these requirements, in addition
demands. And both they and the paints used on buildings to providing other benefits. For example, the TIB KAT ®
and for industrial applications need to be weather- and range includes not only high-quality zinc-based catalysts,
UV-resistant. Long life is essential, as is the ability to but also newly developed bismuth- and zinc-based
withstand heat, cold, ice and snow. catalysts which have a lower toxicological potential, thus
making them suitable for a wider spectrum of
applications.
PU powder coatings
Uretdione - blocked
powder coatings
powder coatings
Blocked PU
Silicone
POWDER COATINGS
TIB KAT P 216 Low toxicity, TIB KAT P 218 on special silica vehicle
UPE
DRYERS / ADDITIVES
TIB KAT 812 Especially suited for lower temperatures and high ambient humidity
2K water - borne
Electrophoretic
PU dispersions
PU high solids
PU systems
Isocyanates
coatings
POLYURETHANE
TIB KAT 220 Long pot life, recommended for forced drying
TIB KAT 616 Long pot life, recommended for forced drying
TIB KAT 620 Standard type, for long processing and drying times
TIB KAT
High activity, improved shelf life and colourfastness, alternative to DBTL
716 / 716 LA
TIB KAT 815 Only for systems in which colour plays no role
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TIB KAT ® FOR ADHESIVES AND SEALANTS
Modern adhesives and sealants are now indispensable We have developed and optimised special TIB KAT ® ty-
in a vast range of applications spanning nearly all pes for a wide spectrum of applications. They decisively
sectors of industry. Long ago they began replacing improve the usability and other attributes of adhesives
screws, bolts, rivets and other mechanical fasteners and sealants.
for a multitude of uses.
Supplementing the widely used standard catalysts, TIB
Adhesives and sealants are employed in automotive has developed corresponding dioctyltin catalysts with
manufacturing and the aerospace industry, as well as reduced toxicity. For MS- and silane-terminated
in building construction and shipbuilding. They need to polymers, we offer special silane blends which meet the
be flexible and easy to apply, and have to provide lasting demanding requirements of these modern systems.
protection against environmental conditions.
Silane - terminated
polyolefines (XPE)
Silane - modified
Silicone resins
1K MS silyl
2K MS silyl
polymers
SILICONES & SILANE -
MODIFIED POLYMERS
TIB KAT 216 Low toxicity, standard catalyst for XPE tubing and pipes
TIB KAT 217 Enables low adhesion values, slow catalyst for MS silyl systems
TIB KAT 226 Very fast-acting catalyst, excellent for 1 K MS silyl formulations
TIB KAT 226 V80 Remains liquid at lower processing temperatures for 1 K MS silyl
TIB KAT 229 Low toxicity, DOT alternative to TIB KAT 233
TIB KAT
Greater activity than DBTL
233 / 233 S
TIB KAT 417 Enables low adhesion values, faster than TIB KAT 217
PU elastomers
PU adhesives
PU cast resin
PU hot melts
and sealants
PU flooring
systems
POLYURETHANES
TIB KAT 214 Low toxicity, especially suited for flooring systems
TIB KAT 229 Low toxicity, DOT alternative to TIB KAT 233
TIB KAT
Bismuth - based alternative to DBTL
716 / 716 LA
RTV sealants,
RTV sealants,
alkoxy curing
oxime curing
Cast resin
systems
RTV SILICONES
TIB KAT 217 Standard catalyst for oxime - and alkoxy - curing RTV systems
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TIB KAT ® FOR POLYMER PROCESSING
Plastics processing calls for considerable expertise TIB offers selected additives which are tailor -made to
and high - quality additives. meet the special requirements of plastics processing.
For producing thermoplastic vulcanisates, example, we
The additives that go into many plastic compounds are offer TIB Blend 98, a cross -linking catalyst based on
indispensable ingredients – they serve to stabilise, tin(II)chloride which exhibits excellent flowability and a
colour or extend the properties of the polymers. low tendency to clump. This translates into easy
dispensing and problem -free operation of production
equipment.
Silane - terminated
vulcanisates (TPV)
ABS, ABS / PVC
Other polymers
Thermoplastic
Thermoplastic
polyurethanes
Polylactides
polymers
blends
PVC
POLYMER PROCESSING
TIB BLEND 98 Crosslinking catalyst as free - flowing, nonclumping powder which is easy to dose
TIB KAT 129 Polymerisation catalyst for delactides or ring - opening polymerisation of lactones
TIB KAT 162 Crosslinking catalyst for EPDM / PP / phenolic resin systems
TIB KAT 214 Octyltin mercaptide, excellent stability when exposed to light and heat
TIB KAT 616 Zinc - based heat stabilizer for Ca - and Zn - based stabiliser formulations
TIB KAT 620 Zinc - based heat stabilizer for Ca - and Zn - based stabiliser formulations
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TIB KAT ® – GLOBAL PRESENCE
Canada
USA
MÉXIKO
Venezuela
Colombia
Brazil
Chile
Argentina
Japan
Israel Iran
China
Egypt India
Vietnam
Thailand
Philippines
Singapore
Malaysia
Indonesia
New Zealand
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TIB KAT ® – REGULATORY STATUS
EINECS / ELINCS
EINECS / ELINCS
NEPA / IECSC
NEPA / IECSC
New Zealand
New Zealand
South Korea
South Korea
ENCS / MITI
ENCS / MITI
DSL / NDSL
DSL / NDSL
ECL / TCCL
ECL / TCCL
Philippines
Philippines
Australien
Australien
Canada
Canada
PICCS
PICCS
ERMA
ERMA
Japan
Japan
China
China
TSCA
TSCA
AICS
AICS
USA
USA
EU
EU
INORGANIC TIN CATALYSTS ORGANOTIN CATALYSTS
EINECS / ELINCS
NEPA / IECSC
NEPA / IECSC
New Zealand
New Zealand
South Korea
South Korea
ENCS / MITI
ENCS / MITI
DSL / NDSL
DSL / NDSL
ECL / TCCL
ECL / TCCL
Philippines
Philippines
Australien
Australien
Canada
Canada
PICCS
PICCS
ERMA
ERMA
Japan
Japan
China
China
TSCA
TSCA
AICS
AICS
USA
USA
EU
EU
ZINC - BASED CATALYSTS SULPHONIC ACID CATALYSTS
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GERMANY
EUROPE
Benelux Poland
Gilbert Tas Dr. Klaus Ströhle Donauchem Polska Sp. Z.o.o. Olga Pronkina
Tel. +32 543 344 85 Tel. +44 182 731 41 51 Ul. Topolowa 15 Tel. +7 495 225 - 44 - 40
Fax +32 543 308 54 Fax +44 182 731 41 52 62 – 090 Rokietnica k / Poznan Fax +7 495 550 - 66 - 26
[email protected] [email protected] Tel. +48 618 429 349 [email protected]
www.l-i.co.uk Fax +48 616 465 405 www.nortex.chem.ru
[email protected]
Finland
OY Flinkenberg AB Italy / Spain / Switzerland / Greece Czech Republic / Slovakia
Mikkelänkallio 3 TIB Chemicals AG Portugal Donauchem Urseta
FIN - 02771 Espoo Fabrizio Scesa Horquim Representacões, Lda. Za Žoskou 377
Tel. +39 037 39 75 - 224 / -213 Rua Central da Camposa, 1255 288 02 Nymburk
Veli Laamanen Fax +39 037 39 75 - 260 4425 - 322 Folgosa Maia Czech Republik
Tel. +358 985 991 344 Mobile +39 348 254 18 50 Portugal
Fax +358 859 913 04 [email protected] Libor Kríž
veli.laamanen@flinkenberg.fi Tel. +420 317 070 218
Gilberto Marinho Fax +420 317 070 230
Norway / Sweden / Denmark Tel. +351 229 670 496 / 982 www.donauchem.cz
France Eidsvik Agentur Ltd Fax +351 229 673 287
TIB Chemicals AG Rødtvedtveien 16 [email protected]
Hervé Luneau 0955 Oslo www.horquim.pt Turkey
Tel. +33 130 620 007 Norwegen Renk Kimya
[email protected] Danismanlikl ve, Temilcilik Ltd. Sti.
Arne Eidsvik Russia / Belarus / Kazakhstan Tütüncü Mehmet Efendi
Tel. +47 - 944 983 46 Nortex Ltd Cad. Nergis, Apt. Nr. 27 / 14
United Kingdom Fax +47 - 220 656 99 Dzerginskoe shosse, 9 Göztepe, Istanbul 34270
Lawrence Industries [email protected] 140054, Kotelniki
PO Box 3000 Moskow region Ferah Emre
Tamworth, Staffordshire B 79 7Xj Russia Tel. +90 216 369 34 96
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[email protected]
AMERICAS
ASIA
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