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7. AB2 is 10% dissociated in water to A2+ and
LIQUID SOLUTION
1. When 9.45 g of ClCH2COOH is added to 500 mL B–. The boiling point of a 10.0 molal aqueous
solution of AB2 is _______oC. (Round off to the
of water, its freezing point drops by 0.5°C. The
dissociation constant of ClCH2COOH is Nearest Integer).
[Given : Molal elevation constant of water
x × 10–3. The value of x is ________.
Kb = 0.5 K kg mol–1 boiling point of pure water
(Rounded off to the nearest integer)
= 100oC]
Kf(H O) = 1.86K kgmol-1 
 2  8. At 363 K, the vapour pressure of A is 21 kPa
2. C6H6 freezes at 5.5°C. The temperature at which and that of B is 18 kPa. One mole of A and
a solution 10 g of C4H10 in 200 g of C6H6 freeze 2 moles of B are mixed. Assuming that this
is _______ °C. (The molal freezing point solution is ideal, the vapour pressure of the
depression constant of C6H6 is 5.12°C/m.) mixture is ________ kPa. (Round of to the

3. 1 molal aqueous solution of an electrolyte A2B3 Nearest Integer).

9. The oxygen dissolved in water exerts a partial
is 60% ionised. The boiling point of the solution
pressure of 20 kPa in the vapour above water.
at 1 atm is _______ K. (Rounded-off to the
The molar solubility of oxygen in water is
nearest integer)
_______ × 10–5 mol dm–3.
[Given Kb for (H2O) = 0.52 K kg mol–1]
(Round off to the Nearest Integer).
4. If a compound AB dissociates to the extent of
[Given : Henry's law constant
75% in an aqueous solution, the molality of the
= KH = 8.0 × 104 kPa for O2.
solution which shows a 2.5 K rise in the boiling
Density of water with dissolved oxygen
point of the solution is ______ molal.
= 1.0 kg dm–3]
(Rounded-off to the nearest integer)
10. A 1 molal K4Fe(CN)6 solution has a degree of
[Kb = 0.52K kg mol–1]
5. 224 mL of SO2(g) at 298 K and 1 atm is passed dissociation of 0.4. Its boiling point is equal to
that of another solution which contains
through 100 mL of 0.1 M NaOH solution. The
18.1 weight percent of a non electrolytic solute
non-volatile solute produced is dissolved in
A. The molar mass of A is_____ u. (Round off
36 g of water. The lowering of vapour pressure
to the Nearest Integer).
of solution (assuming the solution is dilute)
[Density of water = 1.0 g cm–3]
 
P(H2O)  24 mm of Hg is x × 10–2 mm of Hg,
11. 2 molal solution of a weak acid HA has a
the value of x is ______. (Integer answer) freezing point of 3.885°C. The degree of
6. When 12.2 g of benzoic acid is dissolved in 100 g dissociation of this acid is _____ × 10–3.
of water, the freezing point of solution was found (Round off to the Nearest Integer).
to be –0.93°C (Kf (H2O) = 1.86K kg mol–1). The [Given : Molal depression constant of
number (n) of benzoic acid molecules associated water = 1.85 K kg mol–1 Freezing point of pure
(assuming 100% association) is ____. water = 0°C]

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12. A solute a dimerizes in water. The boiling point 18. Of the following four aqueous solutions, total
of a 2 molar solution of A is 100.52ºC. The number of those solutions whose freezing point
percentage association of A is.____. is lower than that of 0.10 M C2H5OH is
(Round off to the Nearest integer) ________ (Integer answer)
[Use : Kb for water = 0.52 K kg mol–1 (i) 0.10 M Ba3(PO4)2
Boiling point of water = 100°C] (ii) 0.10 M Na2SO4
13. Which one of the following 0.06 M aqueous (iii) 0.10 M KCl
solutions has lowest freezing point ? (iv) 0.10 M Li3PO4
(1) Al2(SO4)3 (2) C6H12O6 19. 83 g of ethylene glycol dissolved in 625 g of
(3) KI (4) K2SO4 water. The freezing point of the solution is
14. CO2 gas is bubbled through water during a soft _______K. (Nearest integer)
drink manufacturing process at 298 K. If CO2 [Use : Molal Freezing point depression constant
exerts a partial pressure of 0.835 bar then x m of water = 1.86 K kg mol–1]
mol of CO2 would dissolve in 0.9 L of water. Freezing Point of water = 273 K
The value of x is ________ . Atomic masses : C : 12.0 u, O : 16.0 u, H : 1.0 u]
(Nearest integer)
20. 1 kg of 0.75 molal aqueous solution of sucrose
(Henry's law constant for CO 2 at 298 K is can be cooled up to –4°C before freezing. The
1.67 × 10 3 bar) amount of ice (in g) that will be separated out is
15. When 3.00 g of a substance 'X' is dissolved in ________ . (Nearest integer)
100 g of CCl4, it raises the boiling point by [Given : Kf(H2O) = 1.86 K kg mol–1]
0.60 K. The molar mass of the substance 'X' is 21. 40 g of glucose (Molar mass = 180) is mixed
–1
________ g mol . (Nearest integer). with 200 mL of water. The freezing point of
[Given Kb for CCl4 is 5.0 K kg mol–1] solution is _____ K. (Nearest integer)
16. 1.46 g of a biopolymer dissolved in a 100 mL [Given : Kf = 1.86 K kg mol–1 ; Density of
water at 300 K exerted an osmotic pressure of water = 1.00 g cm–3; Freezing point of
2.42 × 10–3 bar. water = 273.15 K]
22. Which one of the following 0.10 M aqueous
The molar mass of the biopolymer is _____
solutions will exhibit the largest freezing point
× 104 g mol–1.
depression ?
(Round off to the Nearest Integer)
(1) hydrazine (2) glucose
[Use : R = 0.083 L bar mol–1 K–1]
(3) glycine (4) KHSO4
17. When 400 mL of 0.2M H2SO4 solution is mixed
23. 1.22 g of an organic acid is separately dissolved
with 600 mL of 0.1 M NaOH solution, the
in 100 g of benzene (Kb = 2.6 K kg mol–1) and
increase in temperature of the final solution is 100 g of acetone (Kb = 1.7 K kg mol–1). The
_____ × 10–2 K. (Round off to the nearest acid is known to dimerize in benzene but
integer). remain as a monomer in acetone. The boiling
[Use : H+ (aq) + OH–(aq) H2O : point of the solution in acetone increases by
H = – 57.1 kJ mol–1] 0.17°C. The increase in boiling point of solution
Specific heat of H2O = 4.18 J K–1 g–1 in benzene in °C is x × 10–2. The value of x is
density of H2O = 1.0 g cm–3 _______.(Nearest integer)
Assume no change in volume of solution on [Atomic mass : C = 12.0, H = 1.0, O= 16.0]
mixing.

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SOLUTION 3. Official Ans. by NTA (375)
1. Official Ans. by NTA (36) Sol. Tb = iKbm
 +
Sol. ClCH2COOH  ClCH2COO + H = (1 + 4) × 0.52 × 1
i = 1 + (2 –1)  = 3.4 × 0.52 × 1 = 1.768
 i=1+
Tb = 1.768 + 373.15 = 374.918 K
Tf = ikfm
= 375K
  9.45  
 
0.5  1   1.86    94.5   Hence answer is (375)
  500  
  4. Official Ans. by NTA (3)
  1000  
5 1.28 Sol.  = 0.75, n = 2
1   
3.72 3.72 i = 1 –  + n = 1 – 0.75 + 2 × 0.75 = 1.75
32
 Tb = ikbm
93
ClCH2COOH  ClCH2 COO + H
 + or, 2.5 = 1.75 × 0.52 × m

C–C C C 2.5

or, m =  2.74
1.75  0.52
 C 2 C2 0.1
Ka   C  0.2  nearest integer answer will be 3
C  C 1  500 / 1000
0.2  32 / 93 0.2   32 
2 2
5. Official Ans. by NTA (24)
Ka  
1  32 / 93 93  61 Sol.(1)SO2 + 2NaOH  Na2SO3 + H2O
= 0.036
Ka = 36 × 10
–3 224 10mmol 5mmol
0.0821  298 (L.R.) (i  3)
2. Official Ans. by NTA (1)
Sol. Pure Solvent : C6H6 () = 9.2 m mol
s 0

Given : Tf  5.5C P = P . Xsolvent

Kf  5.12 C / m 2
= 24 
(2  15  10 3 )
10g : Solute is non dissociative
= 23.82
200 g C6H6 P = 0.18 torr = 18 × 10–2 torr.
 Tf = kf × m
Sol.(2) SO2 + NaOH  NaHSO3
 10 
  9.2 10 –
  T  T   5.12   58  mol
f
0
f
'

 200  – 0.8 9.2

  kg
 1000  0
P = P . Xsolute
5.12  5  10
 5.5  Tf' 
58 (1.6  18.4)
= 24 ×
2020
 Tf'  1.086 C 1C
= 0.2376 = 23.76 × 10–2

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6. Official Ans by NTA (2) 9. Official Ans. by NTA (25)

Sol. Tf = i × kf × m Official Ans. by ALLEN (1389)

12.2 Sol. P = KH · x
0 – (–0.93) = i × 1.86 ×  1000
122  100 n O2
3 4 3
or, 20 × 10 = (8 × 10 × 10 ) ×
0.93 n O2  n water
i  0.5
1.86
1 nO2 nO
1  1 1  or,   2
i = 1   1    1    1  1 4000 n O2  n water n water
n  2 n 

n=2 Means 1 mole water (= 18 gm = 18 ml)

7. Official Ans. by NTA (106) dissolves
2+ –
Sol. AB2  A + 2B 1
moles O 2 . Hence, molar solubility
4000
t=0 a 0 0
t = t a –a a 2a  1 
 4000 
=   1000  1 mol dm 3
nT = a –a+a+2a
18 72
 = a (1 + 2) –5 –3 –3
= 1388.89 × 10 mol dm  1389 mol dm
so i = 1 + 2
10. Official Ans. by NTA (85)
Now Tb = i × m × Kb + 4–
Sol. K4 Fe(CN)6  4K + Fe(CN)6
Tb = (1 + 2) × m × Kb
Initial conc. 1 m 0 0
 = 0.1 m = 10 Kb = 0.5
Final conc. (1 – 0.4)m 4 × 0.4 0.4m
Tb = 1.2 × 10 × 0.5
= 0.6 m = 1.6 m
=6
Effective molality = 0.6 + 1.6 + 0.4 = 2.6m
So boiling point = 106
For same boiling point, the molality of another
8. Official Ans. by NTA (19)
solution should also be 2.6 m.
Sol. Given PA0  21kPa  PB0  18kPa
Now, 18.1 weight percent solution means 18.1
 An Ideal solution is prepared by mixing 1 gm solute is present in 100 gm solution and
mol A and 2 mol B.
hence, (100 – 18.1 =) 81.9 gm water.
1 2
 XA = and XB = 18.1 / M
3 3 Now, 2.6 =
81.9 / 1000
 Acc to Raoult's low
 Molar mass of solute, M = 85
PT  XA PA0  XBPB0
11. Official Ans. by NTA (50)
1  2 
 PT    21     18  Sol. Tf = (1 + ) Kf.m
3  3 
 = 0.05 = 50 × 10–3
 PT = 7 +12 = 19 KPa

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12. Official Ans. by NTA (100) 16. Official Ans. by NTA (15)
Sol.  = CRT ;  = osmotic pressure
Sol. Tb = Tb – Tb0
C = molarity
100.52 – 100 T = Temperature of solution
let the molar mass be M gm / mol
= 0.52ºC
2.42 × 10–3 bar
   1.46g 
i = 1  
 2  Mgm / mol  0.083  bar
=   
    300K 
 Tb = i Kb × m 0.1  mol  K 
  M = 15.02 × 104 g/mol
  17. Official Ans. by NTA (2)
0.52 = 1    0.52  2
 2 ALLEN Ans. (82)
400  0.2
=1 Sol. n H    2  0.16
1000
So, percentage association = 100%. 600  0.1
n OH –   0.06 (L.R)
13. Official Ans. by NTA (1) 1000
Now, heat liberated from reaction
Sol. Tf – Tf' = i Kf.m = heat gained by solutions
For minimum Tf' or, 0.06 × 57.1 × 103
= (1000 × 1.0) × 4 .18 × T
'i' should be maximum.  T = 0.8196 K
Al2(SO4)3 i=5 = 81.96 ×10–2 K  82 × 10–2 K
C6H12O6 i=1 18. Official Ans. by NTA (4)
Sol. As 0.1 M C2H5OH is non-dissociative and rest
KI i=2
all salt given are electrolyte so in each case
K2SO4 i=3 effective molarity > 0.1 so each will have lower
14. Official Ans. by NTA (25) freezing point.

Sol. From Henry's law 19. Official Ans. by NTA (269)

Sol. kf = 1.86 k. kg/mol
Pgas = [Link]
Tfo = 273 k
n(CO2 ) solvent : H2O(625 g)
0.835 = 1.67 × 103 ×
0.9  1000  CH2  CH 2 
18 Solute : 83 g  | |   Non dissociative
 
n(CO2) = 0.025  OH OH 
solute
Millimoles of CO2 = 0.025 × 1000 = 25
 Tf = kf × m
15. Official Ans. by NTA (250) 83 / 62
  Tfo  Tf1   1.86 
Sol. Tb = Kb × molality 624 / 1000
1.86  83  1000 154380
 3/ M   273 – Tf1 = 
0.60 = 5    62  625 38750
 100 /100   273 – Tf1  4
M = 250  Tf1  259 K

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20. Official Ans. by NTA (518) 23. Official Ans. by NTA (13)

Sol. Let mass of water initially present = x gm Sol. With benzene as solvent
Tb = i Kb m
Mass of sucrose = (1000 - x) gm
1 1.22 / Mw
Tb   2.6  …(1)
1000  x 
 moles of sucrose =  
2 100 /1000
 342 
With Acetone as solvent
 1000  x  Tb = i Kb m
 
0.75 =  342   x  1000  x 1.22 / Mw
 x  1000 342  0.75 0.17 = 11.7 …(2)
 1000  100 /1000
 
(1) / (2)
256.5 x = 106 – 1000x
1 1.22 / M w
 2.6 
x = 795.86 gm Tb 2 100 /1000

0.17 1.22 / Mw
1  1.7 
moles of sucrose = 0.5969 100 /1000

New mass of H2O = a kg 0.26

Tb 
2
0.5969
 4   1.86  a = 0.2775 kg Tb = 13 × 10–2
a
x = 13
ice separated = (795.86 – 277.5) = 518.3 gm

21. Official Ans. by NTA (271)

40
mol
180 10
Sol. molality molal
0.2Kg 9

10
Tf Tf Tf ' 1.86
9

10
Tf ' 27315  1.86
9

= 271.08 K

271 K (nearest-integer)

22. Official Ans. by NTA (4)

Sol.  Van't Hoff factor is highest for KHSO4

 colligative property (Tf) will be highest for

KHSO4