PRACTICEPROBLEMS 8 = §) Single Cy) anic Compound COMLAMS 200 C6 66" | 47.43% Nand the rest was oxygen. Its molar ma 120 pmol. The molecular formula ofthe compound is (AY CUNO (RB) CUNO, (©) CHAN O (D) CHN,O, QI The perventage composition o compound is found to be C 85.7% and HT the compound is 56, The molecular formula of the compound is WCH,, (By cu, 14.3%, Vapour density of COC, (D)CM, Q3__Inagascous reaction ofthe ype, aA + BB» eC + dD) «which is wrong, (A)alitre of A combines with b litre of B to give Cand D (B)amole of A combines with b mole of B to give C and D (C)agofA combines with b g of B to give C and D (D) molecules of A combines with b molecules of B to give Cand D. CX wrat isthe volume of CO, obtained at STP when 168 gof MgCO, ), is heated. (Ay 2 (B)22.4 (C)33.6 (D) 44.8 S200 gof calcium carbonate on being strongly heated yieldsa residue weighing (A)56g (B) 112g (C) 178g (D) 28g Q6 Volume of oxygen at STP required to bum completely 22 g of propane, C,H, ? (A)22.4L (B)44.8L (C)56L (D) 1.2L Q.7__ Mass of calcium carbide, CaC,, would be needed to produce 150 gof acetylene, C,H, by using excess of water? (A) 369.2 (B) 184.6 (C) 276.9 (D) 923 Qs One mole of potassium chlorate is thermally decomposed and excess of aluminium is burnt in the ‘gaseous product(Oxygen). How many mole of aluminium oxide are formed: (A) (B)1.5 (C)2 (D)3 Q9 The volume of chlorine at STP required to liberate all the Bromine and iodine present in | mole of Kland2 moles of MBr,. (A) 22.4 (B) 56. (C) 44.8 (D) Q.10 The empirical formula of a compound is CH,O. Ifthe vapour density of the compound is 30. then the formula of the compound can be (A)HCOOCH, = (B)CH,COCH, —(C) CH,CHO (D) None of these QA 27g Al will react completely with (A) 4g of 0, (B)8 gol, (C)27 p00, (D) 24 gof 0, Q12 C+C0,—42c0 20 mf of CO, is passed over red hot coke. The volume of CO evolved is nines OUND) (C) 60 (D) 10 Scanned with CamScanneron. y:hydiagen. 32 BONY Pinal formula gry ‘ gompountiy (CMO (D) None of these (ay CLO Caleium, Carbon AyCHO = mass ratio. [Link] r anudNiteggen inthe mas ratio. [Link] 14, The emp QA Acortain compound contanns ommpoane ts rina o (D) CaCN, + CCN), (AV CaCN (BY CAEN CE CHeM red and the volume of CO, voxygen required and the volume of CO, fi [Link] US mofmstunets completely atthe yoeme FOE “NN wisn the same conditions are (B) Lomi, Smt (C)Sml, 1S ml (D) 10 ml, 10 m1 (AS mt. 10m! bustion gives 8.8 gm of CO, and Sum of water. The empircg ampound on ¢ Q.16 3,0 gms ofan ons formula ofthe compound is ~ SN «ACH, (BCH, (D) CH, LOAF 10ml ofa gascous hydro carbon on combustion OCH, (D)CHy (A) CH, (B) CH ass of hydrocarbon is 112g, Me Q.18 | mole of CH, requires 12 moles of O, forcombustion. If molecular m: lecular formula of CH, is (A) CoHyy (B) CsHy (©) Gy (D) C.H, ‘One or more than one type Q.19 Which ofthe following requires six times their volume of oxygen for complete combustion? (A)n-butane (B) I-butene (C)2-butene (D) cyclobutane 5Q,28 IL of CO, is passed over hot coke. The volume becomes 1.4 L. The product contains : (A)0.6LCO (B)[Link], (C)[Link], (D)0.8LCO Q.21 Whats the maximum amount of NalO, that can be produced by 12.8 g of HI GHI + 2HNO, —> 31, + 2NO + 4H,0 31, + 6NaOH —> NalO, + SNal + 3H,O (A)3.3g (B)33g (C) 0.33 g (D) None Linked comprehension type Passage - 1 Empirical formula is the simplest formula of the compound which gives the atomic ratio of various element’ present in one molecule of the compound, However, the molecular formula of the compound gives number of atoms of various elements present in one molecule of the compound. Molecular formula (Empirical formula) n Molecular mass ‘mpirical formula mass y have sri e ‘A compound may have same empirical and molecular formula, Both these formulae are calculated ¥S" percentage composition of constituent elements, Scanned with CamScannera Q.22 Which of the following represents the formula ofa substance which contains 50% Oxy (A)N,O (B) CO, (C) NO, (D) CH OH 3Q43 Anoxide of iodine (1 = 127) contains 25.4 y of iodine and 8 g of oxygen. Its formula could be: (AVI, (B)1,0 (C) 1,0, (D)1,0 Q24 10 gofhydrofluoric acid gas occupies 5.6 litres of volumeat STP. Ifthe empirical formula of the gas is HP, then its molecular formula in the gaseous state will be: (A) HE (BHF, (CHE (DIE, Fy Matrix match type ‘ Q.25 Column-I (Gaseous Reaction) Column-Il (STP Condition) (A) Ny +3H, > 2NH, Otmet 0 Lmot (p) 4.16 * 10? mol Product was formed (B) Has 2C > CH (q) 5 * 10° mol Product was formed t (C)C+ 0, Co, (1) 6.25 * 107 mol Product was formed S68 (227LatstPy (D) 2H, +0, > 2H,0 oe Integer type Q.26 0.1 moles of Hydrocarbon on complete combustion produced 17.6 gms of CO, How many carbon atoms are present in each molecule of the hydrocarbon. (s) 6.67 * 10? mol Product was formed Q.27 A gaseous hydrocarbon on combustion produces four times its volume of CO, by consuming six times its volume of oxygen. The ratio of grams atoms of hydrogen and carbon in that hydrocarbon is. Scanned with CamScannerPRACTICE PROBLEMS A) ‘[Link]: QL Weight oreart J: Limes 5 . Q.6 Q7 Q8 bondio ed (AYS3.0kg (B) 167.2ke (€) 250.8 kg, (D) 125.9 kg Mass of magnesium sulphide made from 2g ofMg and 2p of sulphur (Mg = 24) (A) L75 (B)3.5 (C)7.0 (D) 10.5 Number of moles of C formed, equation A +2B—3¢ if8 moles of [Link] 10 moles of B are allowed to react according to given (A) 24 moles. (B) 15 moles (C)7.5 moles (D) 12 moles Amount ofoxygen required for combustion of | kg ofa mixture of butane and isobutane is: (A) 1 8kg (B)2.7kg (C)4.5ke (D) 3.58 kg 4 gofearbon was heated with 8 g of sulphur. How much carbon disulphide (C reaction is complete. What will be the % purity? (A) 70.2% (B) 79.2% (C) 90 % (D) 90.2% will be formed when the The hydrated salt Na,CO; -x HO undergoes 63% loss in mass on heating and becomes anhydrous, The 12COs-x Hy value of x is (A)3 (B)S (C)7 (D) 10 When 10 ml of hydrogen and 12.5ml of chlorine are allowed to react the final mixture contains under the same condtions (A) 22.5 ml of HCI (B) 12.5 mlof HCI (C)20 ml of HCl and 2.5 ml of chlorine (D) 20 ml of HClonly Calculate the number of oxygen atoms required to combine with 7g of N, to form N,O, when 80% of N, is converted to N,O,. (A) 2.3 x 10" (B) 3.6 x 10” (C) 1.8 x 10" (D) 5.4 x 10" What will be the volume of CO, at NTP obtained on heating 10 grams of (90% pure) limestone (A) 22.4 litre (B)2.016 litre (C) 2.24 litre (D) 20.16 litre When a sample of Baking soda is strongly ignited in a crucible it suffered loss in weight of3.1g. The mass of baking soda is (A) 16.8¢ (B)8.4g A.10 gof sample of mixture of CaC/, and NaCT is treated with Na,CO, to precipitate C CaCO. is heated to convert all Ca to CaO, Final mass of CaO is 1.62 g . The % by original mixture is (A)3.21% (C) 16g (D)4.2 g CaCO,. This. safCaCl, (8) 6.72% (C) 32.1% (9) 67.2% Scanned with CamScannerQe wt a, 1 FeCl, ty > BaSC jon is FeSO); * B Quz_ React y; mole of FeCl? How mam Jes of BaCl isnceded to produce moles of BaCl, y (C) jmole (D)2 moles (A) § moles (p) 4 mole an calculate mole of CO, formed 2s of, than calculate mo! s ed and remain ed with 8 moles of, MBM ls, 5 moles of CH, isburt Seat Tinting agen" coos _ 14 (AO (B) Puce uenhe As7e12 Qua and nitric oxide was exploded with excess of H,. If38 mlofy. Nowy ixture of nitrous oxide 60 ml of mix hy gasin mixture. All measurements are made at constant P& 7 -ASsun formed. Calculate the volume of eae! [Link] liquid state. The equation given below are : Qu N\O+Hy—9N,+H,0 3 2NO+2H, —>N2+2H,0 (A) NO=44ml,N,O = 16m (B) NO =30ml,N,O =30ml (C) NO=40ml,N,O =20ml (D) NO=15ml,N,O = 45 ml Q.15_ How many gofrnitric acid can be prepared from 50 g of KNO, of 80% purity? (A) 24.95 g (B)29.45 g (C) 2.945 g (D) None of these Q.16 The mineral haematite is Fe,O,. Haematite ore contains unwanted material called gangue in additions Fe,0,, If5.0 kg of ore contains 2.78 kg of Fe, what is percentage purity of Fe,0,? (A) 97.34% (B) 74.93% (C) 79.43% (D) 43.79% Q.17_ A 100ml misture of CO and CO, is passed through a tube containing red hot charcoal. The volumes: becomes 160 ml. Select correct statement(s) : (A) mole fraction % of CO, in the mixture in 60 (B) mole fraction % of CO in the mixture in 40 (C) The mixture contains 40 ml of C (D) The mixture contains 40 ml of CO Passage - 1 10 moles of SO, and 4 moles of O, are mi Presence of Pt catalyst, Following reacti 280, (g) +0, ied inaclosed vessel of volume 2 litres. The mixtureis heat! ion takes place : (g) > 2SO,(g). Assuming the Teactioy n proceeds t i QU8 Select the comect statement; ‘© completion. (A)SO, is the limiting reagent (B)O, is the limit; (C) Both $0, andO, are limiting 2 Sthe limiting reagent (D) Cannot be predicted Scanned with CamScannerQ.19 Number of moles of SO, formed in the reaction will be: (Ay 10. (B)4 (Cs (D) 14 Q.20. Number of moles ofeveess reactant rem, (Ard (By? (C6 (D)8 Matrixmatch type Q.21 Column-I (Reaction) Column-II (Amount of Product) (A) Ny +311, —>2NH, (p) 0.5 moles ' lag 6g (B) 2H, + 0; —+2H,0 (q) 1 mole 2moles Imole (C) so, + 0, —2s0, (r)2 moles O.5moles 2mole (D) H)+ 1, —>2HI (s)36g 2g 1272 (17g patsy 13 Q.22 12 grams ofa mixture of Sand and Calcium Carbonate on strong heating produced 7.6 grams of residue. How many grams of Sand is presentin the mixture? Let mass of sand =x g. Q.23 _Ozoneis getting converted into oxygen in a chamber. The Average molecular weight of the mixture is40. If 10% of ozone is decomposed. What is y? Q24 PH; —>4p43H, (ey w 26) If 10x % of phosphine decomposed, the volume increases by 30%. The volume of xis Q25__ Sgofcrystalline salt rendered anhydrous by lossing 1.89g of water on heating, The formula weight ofthe anhydrous salt is 160, Find the number of water molecules of crystrallisation ? OXIDATION NUMBER OR OXIDATION STATE Oxidation state ofan element ina particular species (atoms, molecules or ions) is the number of electrons gained or lost by that element during its change from free state into that species. For example, the oxidation State of Na in NaCl is +1, of calcium in Ca,(PO,), is +2, of chlorine in Cl, is zero. Oxidation no. is given positive s electrons are lost and oxidation no. is given negative signif electrons are gained. Oxidation no. represents real charge in case ‘of simple ions like Na’,Cl-, However, in covalent compounds it renrecente inant ~ Scanned with CamScannerWw] . (C] . [5] PRACTICE PROBLEMS -3 (Dp) 2. [A] 3. [Cc] 4, [Cc] 7. [A] 8. [A] 9. - DP) 12. [B] 13. [B] 14, - [A] 17. [D] 18. [B] 19. - (Al 22. [D] 23. [C] 24. . [A-s;B-piC-g:D-r] 26. [4] 27. [A] 2. [By 3. [B] 4, (D] 7. [C] 8. [B] 9. - (C] 12. [C] 13. [A] 14, 17. [ABD] 18. [B] 19. . [A-gt;B-rs;C- p;D-q] 22. [2] 23. [D] [B] [D] [BCD] 2) [D] fA] (c] (4) 5. 10. 15. . [CD] 10. 15, 20. 24, [B] [A] [BB] [B] (Al (B] 4) Scanned with CamScanner