SAFETY DATA SHEET according to Regulation (EC) No.

1907/2006

MAXFORCE FORTE RB0,05 1/12

Version 2 / IND Revision Date: 31.01.2023
102000028655 Print Date: 31.01.2023

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Trade name MAXFORCE FORTE RB0,05
Product code (UVP) 81740917

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use Insecticide

1.3 Details of the supplier of the safety data sheet

Supplier Bayer CropScience Limited
Bayer House, Central Avenue
Hiranandani Estate
400607 Thane (W)
Maharashtra
India
Telephone +91-22-25311826 / 25311234

Telefax +91-22-25455116

1.4 Emergency telephone no.

Indian Emergency Number 022-25311885 (24 hours/day)
Global Incident Response +1 (760) 476-3964 (Company 3E for Bayer AG, Crop Science Division)
Hotline (24h)

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures, as amended.
Acute aquatic toxicity: Category 1
H400 Very toxic to aquatic life.
Chronic aquatic toxicity: Category 1
H410 Very toxic to aquatic life with long lasting effects.
2.2 Label elements
Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures, as amended.
Hazard label for supply/use required.
Hazardous components which must be listed on the label:
• Fipronil
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Signal word: Warning

Hazard statements
H410 Very toxic to aquatic life with long lasting effects.
EUH208 Contains 1,2-benzisothiazolin-3-one, reaction mass of 5-chloro-2- methyl-2H-isothiazol-
3-one and 2-methyl-2H-isothiazol-3- one (3:1). May produce an allergic reaction.
Precautionary statements
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local regulation.
2.3 Other hazards
No additional hazards known beside those mentioned.
Fipronil: This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This
substance is not considered to be very persistent and very bioaccumulative (vPvB).

Ecological information: The substance/mixture does not contain components considered to

have endocrine disrupting properties according to REACH Article 57(f)
or Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.

Toxicological information: The substance/mixture does not contain components considered to

have endocrine disrupting properties according to REACH Article 57(f)
or Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures
Chemical nature
Bait (ready for use) (RB)
Fipronil 0,05%
Hazardous components
Hazard statements according to Regulation (EC) No. 1272/2008
Name CAS-No. / Classification Conc. [%]
EC-No. / REGULATION (EC) No
REACH Reg. No. 1272/2008
Fipronil 120068-37-3 Acute Tox. 3, H301 0.05
Acute Tox. 3, H311
Acute Tox. 2, H330
STOT RE 1, H372
Aquatic Acute 1, H400
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Aquatic Chronic 1, H410

1,2-Benzisothiazol-3(2H)- 2634-33-5 Acute Tox. 4, H302 >= 0.005 –
one 01-2120761540-60-0003 Skin Irrit. 2, H315 <= 0.05
Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Acute 1, H400
reaction mass of 5-chloro- 55965-84-9 Acute Tox. 3, H301 >= 0.0015 –
2- methyl-2H-isothiazol-3- Acute Tox. 2, H310 < 0.06
one and 2-methyl-2H- Acute Tox. 2, H330
isothiazol-3- one (3:1) Skin Corr. 1C, H314
Eye Dam. 1, H318
Skin Sens. 1A, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Sucrose 57-50-1 Not classified >= 1.0
01-2119491293-35-xxxx
Further information
1,2-Benzisothiazol- 2634-33-5 M-Factor: 10 (acute)
3(2H)-one
reaction mass of 5- 55965-84-9 SCL: Skin Corr. 1C; H314: SCL >= 0.6 %
chloro-2- methyl-2H-
isothiazol-3-one and 2-
methyl-2H-isothiazol-3-
one (3:1)
reaction mass of 5- 55965-84-9 SCL: Skin Irrit. 2; H315: SCL 0.06 - < 0.6 %
chloro-2- methyl-2H-
isothiazol-3-one and 2-
methyl-2H-isothiazol-3-
one (3:1)
reaction mass of 5- 55965-84-9 SCL: Eye Dam. 1; H318: SCL >= 0.6 %
chloro-2- methyl-2H-
isothiazol-3-one and 2-
methyl-2H-isothiazol-3-
one (3:1)
reaction mass of 5- 55965-84-9 SCL: Eye Irrit. 2; H319: SCL 0.06 - < 0.6 %
chloro-2- methyl-2H-
isothiazol-3-one and 2-
methyl-2H-isothiazol-3-
one (3:1)
reaction mass of 5- 55965-84-9 SCL: Skin Sens. 1A; H317: SCL >= 0.0015 %
chloro-2- methyl-2H-
isothiazol-3-one and 2-
methyl-2H-isothiazol-3-
one (3:1)
For the full text of the H-Statements mentioned in this Section, see Section 16.

Particle characteristics
This substance/ mixture does not contain nanoforms
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SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

General advice Move out of dangerous area. Remove contaminated clothing
immediately and dispose of safely.
Inhalation Move to fresh air. Call a physician or poison control center
immediately.
Skin contact Wash off thoroughly with plenty of soap and water, if available with
polyethyleneglycol 400, subsequently rinse with water. If symptoms
persist, call a physician.
Eye contact In case of eye contact, remove contact lens and rinse immediately with
plenty of water, also under the eyelids, for at least 15 minutes. Get
medical attention if irritation develops and persists.
Ingestion Do NOT induce vomiting. Call a physician or poison control center
immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms Symptoms and hazards refer to effects observed after intake of
significant amounts of the active ingredient(s)., The following
symptoms may occur:, Restlessness, anxiety, Tremors
4.3 Indication of any immediate medical attention and special treatment needed
Treatment There is no specific antidote. Carefully monitor the respiratory
functions. In case of convulsions, a benzodiazepine (e.g. diazepam)
should be given according to standard regimens. Oxygen or artificial
respiration if needed. Keep respiratory tract clear. In case of ingestion
gastric lavage should be considered in cases of significant ingestions
only within the first 2 hours. However, the application of activated
charcoal and sodium sulphate is always advisable. Symptoms of
poisoning may appear several hours later. Keep under medical
supervision for at least 48 hours.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable Water spray, Carbon dioxide (CO2), Foam, Dry powder
Unsuitable High volume water jet
Hazchem Code 3Z

5.2 Special hazards arising In the event of fire the following may be released:, Carbon monoxide
from the substance or (CO), Nitrogen oxides (NOx), Sulphur oxides, Hydrogen chloride (HCl),
mixture Hydrogen fluoride
5.3 Advice for firefighters
Special protective In the event of fire and/or explosion do not breathe fumes. Wear self-
equipment for firefighters contained breathing apparatus and protective suit.
Further information Contain the spread of the fire-fighting media. Do not allow run-off from
fire fighting to enter drains or water courses.
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SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Precautions Avoid contact with spilled product or contaminated surfaces. Use
personal protective equipment.

6.2 Environmental Do not allow to get into surface water, drains and ground water.
precautions
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up The nature of this product, when contained in commercial packs,
makes spillage unlikely. However, if significant amounts are spilled
nevertheless, the following advice is applicable. Soak up with inert
absorbent material (e.g. sand, silica gel, acid binder, universal binder,
sawdust). Collect and transfer the product into a properly labelled and
tightly closed container.
Additional advice Check also for any local site procedures.

6.4 Reference to other Information regarding safe handling, see section 7.

sections Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. No specific precautions required when
handling unopened packs/containers; follow relevant manual handling
advice. Avoid contact with skin, eyes and clothing.
Advice on protection Keep away from heat and sources of ignition.
against fire and explosion
Hygiene measures Avoid contact with skin, eyes and clothing. Keep working clothes
separately. Remove soiled clothing immediately and clean thoroughly
before using again. Wash hands immediately after work, if necessary
take a shower. Smoking, eating and drinking should be prohibited in the
application area.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage Store in original container. Store in a place accessible by authorized
areas and containers persons only. Keep containers tightly closed in a dry, cool and well-
ventilated place.
Advice on common storage Keep away from food, drink and animal feedingstuffs.
Suitable materials Use of Bulk packaging at formulation site for temporary transport only!
Polyethylene film within an outer package
7.3 Specific end use(s) Refer to the label and/or leaflet.
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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components CAS-No. Control parameters Update Basis
Fipronil 120068-37-3 0.035 mg/m3 OES BCS*
(TWA)
*OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard"
8.2 Exposure controls
Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the
following recommendations would apply.
Respiratory protection Respiratory protection is not required under anticipated
circumstances of exposure.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.

Hand protection Please observe the instructions regarding permeability and

breakthrough time which are provided by the supplier of the gloves.
Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion, and the
contact time.
Wash gloves when contaminated. Dispose of when contaminated
inside, when perforated or when contamination on the outside cannot
be removed. Wash hands frequently and always before eating,
drinking, smoking or using the toilet.
Material Nitrile rubber
Rate of permeability > 480 min
Glove thickness > 0.4 mm
Protective index Class 6
Directive Protective gloves complying with EN
374.
Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection Wear standard coveralls and Category 3 Type 4 suit.
If there is a risk of significant exposure, consider a higher protective
type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Form gel
Colour brown
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Odour weak, characteristic

Odour Threshold No data available
Melting point/range No data available
Boiling Point No data available
Flammability No data available
Upper explosion limit No data available
Lower explosion limit No data available
Flash point Not relevant
Auto-ignition temperature No data available

Self-accelarating No data available

decomposition temperature
(SADT)
pH 5 - 7 (1 %) (23 °C) (deionized water)
Viscosity, dynamic No data available
Viscosity, kinematic No data available
Water solubility No data available

Partition coefficient: n- No data available

octanol/water

Vapour pressure No data available

Density ca. 1.18 g/cm³ (20 °C)
Relative density No data available
Relative vapour density No data available
Assessment nano particles This substance/ mixture does not contain nanoforms

Particle size No data available

9.2 Other information

Explosivity No data available

Oxidizing properties No data available
Evaporation rate No data available
Other physico-chemical Further safety related physical-chemical data are not known.
properties

SECTION 10: STABILITY AND REACTIVITY

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10.1 Reactivity Stable under normal conditions.

10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of No hazardous reactions when stored and handled according to

hazardous reactions prescribed instructions.

10.4 Conditions to avoid Extremes of temperature and direct sunlight.

10.5 Incompatible materials Store only in the original container.

10.6 Hazardous No decomposition products expected under normal conditions of use.

decomposition products

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on hazard classes as defined in regulation (EC) No 1272/2008

Acute oral toxicity LD50 (Rat) > 2,000 mg/kg

Acute inhalation toxicity
Inhalation is no relevant route of exposure for this formulation. No
volatility, no aerosols under normal conditions.
Acute dermal toxicity LD50 (Rat) > 2,000 mg/kg
Skin corrosion/irritation Slight irritant effect - does not require labelling. (Rabbit)
Serious eye damage/eye Slight irritant effect - does not require labelling. (Rabbit)
irritation
Respiratory or skin Skin: Non-sensitizing. (Guinea pig)
sensitisation OECD Test Guideline 406, Buehler test
Assessment STOT Specific target organ toxicity – single exposure
Fipronil: Based on available data, the classification criteria are not met.
Assessment STOT Specific target organ toxicity – repeated exposure
Fipronil caused specific target organ toxicity in experimental animal studies in the following organ(s):
Liver. Fipronil caused neurobehavioral effects and/or neuropathological changes in animal studies.
Assessment mutagenicity
Fipronil was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.
Assessment carcinogenicity
Fipronil caused an increased incidence of tumours in rats in the following organ(s): Thyroid. The
mechanism that triggers tumours in rodents and the type of tumours observed are not relevant to
humans.
Assessment toxicity to reproduction
Fipronil caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the
parent animals. The reproduction toxicity seen with Fipronil is related to parental toxicity.
Assessment developmental toxicity
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Fipronil did not cause developmental toxicity in rats and rabbits.

Aspiration hazard
Based on available data, the classification criteria are not met.
11.2 Information on other hazards

Endocrine disrupting properties

Assessment The substance/mixture does not contain components considered to have
endocrine disrupting properties according to REACH Article 57(f) or
Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 0.25 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient fipronil.
Toxicity to aquatic EC50 (Daphnia magna (Water flea)) 0.19 mg/l
invertebrates Exposure time: 48 h
The value mentioned relates to the active ingredient fipronil.

LC50 (Mysidopsis bahia (mysid shrimp)) 0.14 µg/l

Exposure time: 96 h
The value mentioned relates to the active ingredient fipronil.

Chronic toxicity to aquatic NOEC (Mysidopsis bahia (mysid shrimp)): 0.0077 µg/l
invertebrates Exposure time: 28 d
The value mentioned relates to the active ingredient fipronil.

Toxicity to aquatic plants EC50 (Desmodesmus subspicatus (green algae)) 0.068 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient fipronil.
12.2 Persistence and degradability
Biodegradability Fipronil:
Not rapidly biodegradable
Koc Fipronil: Koc: 427 - 1278
12.3 Bioaccumulative potential
Bioaccumulation Fipronil: Bioconcentration factor (BCF) 321
Does not bioaccumulate.
12.4 Mobility in soil
Mobility in soil Fipronil: Slightly mobile in soils
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment Fipronil: This substance is not considered to be persistent,
bioaccumulative and toxic (PBT). This substance is not considered to be
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very persistent and very bioaccumulative (vPvB).

12.6 Endocrine disrupting properties
Assessment The substance/mixture does not contain components considered to have
endocrine disrupting properties according to REACH Article 57(f) or
Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.
12.7 Other adverse effects
Additional ecological No other effects to be mentioned.
information

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product In accordance with current regulations and, if necessary, after
consultation with the site operator and/or with the responsible authority,
the product may be taken to a waste disposal site or incineration plant.
Contaminated packaging Dispose of as unused product.
Legal basis
Waste key in accordance with Schedule I of the Hazardous Waste Rules, 2008 as amended (India
- EP Act):
29.1Process wastes/residues
29.3Date-expired and off-specification pesticides

SECTION 14: TRANSPORT INFORMATION

ADR/RID/ADN
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FIPRONIL SOLUTION)
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Environm. Hazardous Mark YES
Hazard no. 90
Hazchem Code 3Z
Tunnel Code -

This classification is in principle not valid for carriage by tank vessel on inland waterways. Please
refer to the manufacturer for further information.

IMDG
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FIPRONIL SOLUTION)
14.3 Transport hazard class(es) 9
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14.4 Packaging Group III

14.5 Marine pollutant YES

IATA
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FIPRONIL SOLUTION )
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Environm. Hazardous Mark YES

14.6 Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
No transport in bulk according to the IBC Code.

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Further information
WHO-classification: III (Slightly hazardous)

Labeling according to Insecticide Rules 1971 as amended. (INDIA)

Class III: Moderately toxic
Colour: bright blue
Danger!
Keep out of the reach of children.

SECTION 16: OTHER INFORMATION

Text of the hazard statements mentioned in Section 3

H301 Toxic if swallowed.
H302 Harmful if swallowed.
H310 Fatal in contact with skin.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
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Abbreviations and acronyms

ADN European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by
Road
ATE Acute toxicity estimate
CAS-Nr. Chemical Abstracts Service number
Conc. Concentration
EC-No. European community number
ECx Effective concentration to x %
EINECS European inventory of existing commercial substances
ELINCS European list of notified chemical substances
EN European Standard
EU European Union
IATA International Air Transport Association
IBC International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicals in Bulk (IBC Code)
ICx Inhibition concentration to x %
IMDG International Maritime Dangerous Goods
LCx Lethal concentration to x %
LDx Lethal dose to x %
LOEC/LOEL Lowest observed effect concentration/level
MARPOL MARPOL: International Convention for the prevention of marine pollution from ships
N.O.S. Not otherwise specified
NOEC/NOEL No observed effect concentration/level
OECD Organization for Economic Co-operation and Development
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
TWA Time weighted average
UN United Nations
WHO World health organisation

The information contained within this Safety Data Sheet is in accordance with the guidelines
established by Regulation (EU) 1907/2006 and Regulation (EU) 2020/878 amending Regulation (EU)
No 1907/2006 and any subsequent amendments. This data sheet complements the user's
instructions, but does not replace them. The information it contains is based on the knowledge
available about the product concerned at the time it was compiled. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The required
information complies with current EEC legislation. Addressees are requested to observe any additional
national requirements.

Reason for Revision: The following sections have been revised: Section 3: Composition /
Information on Ingredients. Section 9: Physical and Chemical
Properties. Section 11: Toxicological Information.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.