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Xylene Safety Data Sheet (MSDS)

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0% found this document useful (0 votes)
35 views28 pages

Xylene Safety Data Sheet (MSDS)

Uploaded by

張楷泓
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

SAFETY DATA SHEET

Xylene

Version 6.2 Revision Date 12.05.2023 Print Date 17.05.2023

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Xylene

Product code : Q5891, Q9151, Q9156, Q9306, T1404

CAS-No. : 1330-20-7

Other means of identification : Reaction Mass of Ethylbenzene and Xylenes (REACH)

Manufacturer or supplier's details


Supplier :
SHELL EASTERN CHEMICALS (S)
A REGISTERED BUSINESS OF SHELL EASTERN
TRADING (PTE) LTD (UEN:198902087C)
9 North Buona Vista Drive , #07-01
The Metropolis Tower 1
Singapore 138588
Singapore
Telephone : +65 6384 8269
Telefax : +65 6384 8454
Contact for Safety Data :
Sheet

Emergency telephone : +800 2537 8747 ( ALERT SGS- toll Free) or +65 6542 9595
number (ALERT SGS)

Recommended use of the chemical and restrictions on use


Recommended use : Solvent., Raw material for use in the chemical industry.

Restrictions on use : This product must not be used in applications other than the
above without first seeking the advice of the supplier.

2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 3
Aspiration hazard : Category 1
Acute toxicity (Oral) : Category 5
Acute toxicity (Dermal) : Category 4
Acute toxicity (Inhalation) : Category 4
Skin corrosion : Category 2
Eye irritation : Category 2A
Specific target organ toxicity - : Category 2
repeated exposure
Specific target organ toxicity - : Category 3 (Respiratory system)

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single exposure
Long-term (chronic) aquatic : Category 3
hazard
GHS label elements
Hazard pictograms :

Signal word : Danger

Hazard statements : PHYSICAL HAZARDS:


H226 Flammable liquid and vapour.
HEALTH HAZARDS:
H303 May be harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H373 May cause damage to organs (Auditory system) through
prolonged or repeated exposure if inhaled.
ENVIRONMENTAL HAZARDS:
H401 Toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements :
Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
P273 Avoid release to the environment.

Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P370 + P378 In case of fire: Use appropriate media to
extinguish.
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P331 Do NOT induce vomiting.

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P302 + P352 IF ON SKIN: Wash with plenty of water and soap.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
P312 Call a POISON CENTER/doctor if you feel unwell.

Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Disposal:
P501 Dispose of contents and container to appropriate waste
site or reclaimer in accordance with local and national
regulations.

Other hazards which do not result in classification


May form flammable/explosive vapour-air [Link] material is a static [Link] with
proper grounding and bonding, this material can still accumulate an electrostatic [Link]
sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air-
vapour mixtures can [Link] may cause drowsiness and dizziness.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Substance

Hazardous components
Chemical name CAS-No. Classification Concentration (%
w/w)
Xylene 1330-20-7 Flam. Liq.3; H226 > 80
Asp. Tox.1; H304
Acute Tox.5; H303
Acute Tox.4; H312
Acute Tox.4; H332
Skin Corr.2; H315
Eye Irrit.2A; H319
STOT RE2; H373
STOT SE3; H335
Aquatic Chronic3;
H412
Ethylbenzene 100-41-4 Flam. Liq.2; H225 < 20
Acute Tox.5; H303

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Asp. Tox.1; H304
Skin Irrit.2; H315
Eye Irrit.2A; H319
Acute Tox.4; H332
STOT SE3; H335
STOT RE2; H373
Aquatic Chronic3;
H412
For explanation of abbreviations see section 16.

4. FIRST-AID MEASURES

General advice : DO NOT DELAY.


Keep victim calm. Obtain medical treatment immediately.

If inhaled : Call emergency number for your location / facility.


Remove to fresh air. Do not attempt to rescue the victim
unless proper respiratory protection is worn. If the victim has
difficulty breathing or tightness of the chest, is dizzy, vomiting,
or unresponsive, give 100% oxygen with rescue breathing or
Cardio-Pulmonary Resuscitation as required and transport to
the nearest medical facility.

In case of skin contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.

In case of eye contact : Immediately flush eye(s) with plenty of water.


Remove contact lenses, if present and easy to do. Continue
rinsing.
Transport to the nearest medical facility for additional
treatment.

If swallowed : Call emergency number for your location / facility.


If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical
facility: fever greater than 101° F (38.3°C), shortness of
breath, chest congestion or continued coughing or wheezing.

Most important symptoms : Respiratory irritation signs and symptoms may include a
and effects, both acute and temporary burning sensation of the nose and throat, coughing,
delayed and/or difficulty breathing.
Skin irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blisters.
Eye irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blurred vision.
Ingestion may result in nausea, vomiting and/or diarrhoea.

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If material enters lungs, signs and symptoms may include
coughing, choking, wheezing, difficulty in breathing, chest
congestion, shortness of breath, and/or fever.
The onset of respiratory symptoms may be delayed for
several hours after exposure.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical
facility: fever greater than 101° F (38.3°C), shortness of
breath, chest congestion or continued coughing or wheezing.
Breathing of high vapour concentrations may cause central
nervous system (CNS) depression resulting in dizziness, light-
headedness, headache, nausea and loss of coordination.
Continued inhalation may result in unconsciousness and
death.
Auditory system effects may include temporary hearing loss
and/or ringing in the ears.

Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.

Notes to physician : IMMEDIATE TREATMENT IS EXTREMELY IMPORTANT!


Call a doctor or poison control center for guidance.
Potential for chemical pneumonitis.
Potential for cardiac sensitisation, particularly in abuse
situations. Hypoxia or negative inotropes may enhance these
effects. Consider: oxygen therapy.
Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.

Unsuitable extinguishing : Do not use water in a jet.


media

Specific hazards during : Clear fire area of all non-emergency personnel.


firefighting Hazardous combustion products may include:
A complex mixture of airborne solid and liquid particulates and
gases (smoke).
Carbon monoxide.
Unidentified organic and inorganic compounds.
Flammable vapours may be present even at temperatures
below the flash point.
The vapour is heavier than air, spreads along the ground and
distant ignition is possible.
Will float and can be reignited on surface water.

Specific extinguishing : Standard procedure for chemical fires.


methods Keep adjacent containers cool by spraying with water.

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Special protective equipment : Proper protective equipment including chemical resistant
for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Observe all relevant local and international regulations.


protective equipment and Notify authorities if any exposure to the general public or the
emergency procedures environment occurs or is likely to occur.
Local authorities should be advised if significant spillages
cannot be contained.

: Avoid contact with skin, eyes and clothing.


Isolate hazard area and deny entry to unnecessary or
unprotected personnel.
Do not breathe fumes, vapour.
Do not operate electrical equipment.

Environmental precautions : Shut off leaks, if possible without personal risks. Remove all
possible sources of ignition in the surrounding area. Use
appropriate containment to avoid environmental
contamination. Prevent from spreading or entering drains,
ditches or rivers by using sand, earth, or other appropriate
barriers. Attempt to disperse the vapour or to direct its flow to
a safe location for example by using fog sprays. Take
precautionary measures against static discharge. Ensure
electrical continuity by bonding and grounding (earthing) all
equipment.
Monitor area with combustible gas indicator.

Methods and materials for : For small liquid spills (< 1 drum), transfer by mechanical
containment and cleaning up means to a labeled, sealable container for product recovery or
safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
For large liquid spills (> 1 drum), transfer by mechanical
means such as vacuum truck to a salvage tank for recovery or
safe disposal. Do not flush away residues with water. Retain
as contaminated waste. Allow residues to evaporate or soak
up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely

Ventilate contaminated area thoroughly.


If contamination of site occurs remediation may require
specialist advice.

Additional advice : For guidance on selection of personal protective equipment


see Section 8 of this Safety Data Sheet.
For guidance on disposal of spilled material see Section 13 of
this Safety Data Sheet.

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7. HANDLING AND STORAGE

General Precautions : Avoid breathing of or direct contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Section 8 of this Safety Data Sheet.
Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Ensure that all local regulations regarding handling and
storage facilities are followed.

Advice on safe handling : Avoid inhaling vapour and/or mists.


Avoid contact with skin, eyes and clothing.
Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks.
Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols.
Bulk storage tanks should be diked (bunded).
When using do not eat or drink.

The vapour is heavier than air, spreads along the ground and
distant ignition is possible.

Avoidance of contact : Strong oxidising agents.

Product Transfer : Even with proper grounding and bonding, this material can still
accumulate an electrostatic charge. If sufficient charge is
allowed to accumulate, electrostatic discharge and ignition of
flammable air-vapour mixtures can occur. Be aware of
handling operations that may give rise to additional hazards
that result from the accumulation of static charges. These
include but are not limited to pumping (especially turbulent
flow), mixing, filtering, splash filling, cleaning and filling of
tanks and containers, sampling, switch loading, gauging,
vacuum truck operations, and mechanical movements. These
activities may lead to static discharge e.g. spark formation.
Restrict line velocity during pumping in order to avoid
generation of electrostatic discharge (≤ 1 m/s until fill pipe
submerged to twice its diameter, then ≤ 7 m/s). Avoid splash
filling. Do NOT use compressed air for filling, discharging, or
handling operations.

Refer to guidance under Handling section.

Storage
Conditions for safe storage : Refer to section 15 for any additional specific legislation
covering the packaging and storage of this product.

Other data : Storage Temperature:


Ambient.

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Bulk storage tanks should be diked (bunded).


Locate tanks away from heat and other sources of ignition.
Cleaning, inspection and maintenance of storage tanks is a
specialist operation, which requires the implementation of
strict procedures and precautions.
Must be stored in a diked (bunded) well- ventilated area, away
from sunlight, ignition sources and other sources of heat.
Keep away from aerosols, flammables, oxidizing agents,
corrosives and from other flammable products which are not
harmful or toxic to man or to the environment.
Electrostatic charges will be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical
continuity by bonding and grounding (earthing) all equipment
to reduce the risk.
The vapours in the head space of the storage vessel may lie
in the flammable/explosive range and hence may be
flammable.

Packaging material : Suitable material: For containers, or container linings use mild
steel, stainless steel., For container paints, use epoxy paint,
zinc silicate paint.
Unsuitable material: Avoid prolonged contact with natural,
butyl or nitrile rubbers.

Container Advice : Do not cut, drill, grind, weld or perform similar operations on or
near containers.

Specific use(s) : Not applicable

See additional references that provide safe handling practices


for liquids that are determined to be static accumulators:
American Petroleum Institute 2003 (Protection Against
Ignitions Arising out of Static, Lightning and Stray Currents) or
National Fire Protection Agency 77 (Recommended Practices
on Static Electricity).
IEC/TS 60079-32-1: Electrostatic hazards, guidance

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Components with workplace control parameters


Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
Xylene 1330-20-7 PEL (long 100 ppm SG OEL
term) 434 mg/m3
Xylene PEL (short 150 ppm SG OEL
term) 651 mg/m3
Xylene 1330-20-7 TWA 100 ppm OSHA Z-1
435 mg/m3
Xylene TWA 20 ppm ACGIH

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Xylene STEL 150 ppm OSHA P0
655 mg/m3
Xylene TWA 100 ppm OSHA P0
435 mg/m3
Ethylbenzene 100-41-4 PEL (long 100 ppm SG OEL
term) 434 mg/m3
Ethylbenzene PEL (short 125 ppm SG OEL
term) 543 mg/m3
Ethylbenzene 100-41-4 TWA 20 ppm ACGIH
Ethylbenzene TWA 100 ppm NIOSH REL
435 mg/m3
Ethylbenzene ST 125 ppm NIOSH REL
545 mg/m3
Ethylbenzene TWA 100 ppm OSHA Z-1
435 mg/m3
Biological occupational exposure limits
Component CAS-No. Control Biological Sampling Permissible Basis
parameters specimen time concentratio
n
Xylene 1330-20-7 methylhippu Urine 1.5.g/g SG BTLV
ric acid creatinine

Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and
samples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or
contact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
[Link]
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
[Link]
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
[Link]
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
[Link]
L'Institut National de Recherche et de Securité, (INRS), France [Link]

Engineering measures : The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
Use sealed systems as far as possible.
Adequate explosion-proof ventilation to control airborne
concentrations below the exposure guidelines/limits.
Local exhaust ventilation is recommended.
Firewater monitors and deluge systems are recommended.
Where material is heated, sprayed or mist formed, there is
greater potential for airborne concentrations to be generated.
Eye washes and showers for emergency use.

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General Information:
Always observe good personal hygiene measures, such as
washing hands after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard
contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product.
Ensure appropriate selection, testing and maintenance of
equipment used to control exposure, e.g. personal protective
equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or
maintenance.
Retain drain downs in sealed storage pending disposal or
subsequent recycle.

Personal protective equipment


Protective measures
Personal protective equipment (PPE) should meet recommended national standards. Check with
PPE suppliers.

Respiratory protection : If engineering controls do not maintain airborne


concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are unsuitable (e.g. airborne
concentrations are high, risk of oxygen deficiency, confined
space) use appropriate positive pressure breathing apparatus.
If air-filtering respirators are suitable for conditions of use:
Select a filter suitable for organic gases and vapours [Type A
boiling point >65°C (149°F)].
Where air-filtering respirators are suitable, select an
appropriate combination of mask and filter.

Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. Longer term protection: Viton.
Incidental contact/Splash protection: Nitrile rubber. Suitability
and durability of a glove is dependent on usage, e.g.
frequency and duration of contact, chemical resistance of
glove material, dexterity. Always seek advice from glove
suppliers. Contaminated gloves should be replaced.

For continuous contact we recommend gloves with

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breakthrough time of more than 240 minutes with preference
for > 480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Glove thickness should be typically greater than 0.35 mm
depending on the glove make and model.

Personal hygiene is a key element of effective hand care.


Gloves must only be worn on clean hands. After using gloves,
hands should be washed and dried thoroughly. Application of
a non-perfumed moisturizer is recommended.

Eye protection : Wear goggles for use against liquids and gas.
Wear full face shield if splashes are likely to occur.

Skin and body protection : Wear chemical resistant gloves/gauntlets and boots. Where
risk of splashing, also wear an apron.
Wear antistatic and flame-retardant clothing.

Hygiene measures : Wash hands before eating, drinking, smoking and using the
toilet.
Launder contaminated clothing before re-use.
Do not ingest. If swallowed, then seek immediate medical
assistance.

Environmental exposure controls


General advice : Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.
Information on accidental release measures are to be found in
section 6.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid.

Colour : colourless
Odour : aromatic
Odour Threshold : 0.27 ppm

pH : Not applicable
Melting point/freezing point : < -25 °C / -13 °F

Boiling point/boiling range : Typical 136 - 145 °C / 277 - 293 °F


Flash point : Typical 23 - 27 °C / 73 - 81 °F
Method: Abel

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Evaporation rate : 13.5


Method: DIN 53170, di-ethyl ether=1

0.76
Method: ASTM D 3539, nBuAc=1

Flammability (solid, gas) : Not applicable

Upper explosion limit : 7.1 %(V)

Lower explosion limit : 1 %(V)

Vapour pressure : 4.5 kPa (50 °C / 122 °F)

0.8 - 1.2 kPa (20 °C / 68 °F)

0.2 kPa (0 °C / 32 °F)

Relative vapour density : 3.7


Relative density : 0.86 - 0.87Method: ASTM D4052

Density : Typical 870 kg/m3 (15 °C / 59 °F)


Method: ASTM D4052

Solubility(ies)
Water solubility : estimated value(s) 0.2 g/l
Partition coefficient: n- : log Pow: 3.16
octanol/water Method: Literature data.

Auto-ignition temperature : estimated value(s) 432 - 530 °C / 810 - 986 °F

Viscosity
Viscosity, dynamic : ca. 0.9 mPa.s (20 °C / 68 °F)
Method: ASTM D445

Viscosity, kinematic : < 0.9 mm2/s (20 °C / 68 °F)


Method: ASTM D445

Explosive properties : Not classified

Oxidizing properties : Not applicable

Surface tension : Typical 28.7 mN/m, 20 °C / 68 °F, ASTM D-971

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Conductivity : Low conductivity: < 100 pS/m


The conductivity of this material makes it a static
accumulator., A liquid is typically considered nonconductive if
its conductivity is below 100 pS/m and is considered semi-
conductive if its conductivity is below 10,000 pS/m., Whether a
liquid is nonconductive or semi-conductive, the precautions
are the same., A number of factors, for example liquid
temperature, presence of contaminants, and anti-static
additives can greatly influence the conductivity of a liquid
Particle size : Data not available

Molecular weight : 106 g/mol

10. STABILITY AND REACTIVITY

Reactivity : The product does not pose any further reactivity hazards in
addition to those listed in the following sub-paragraph.

Chemical stability : No hazardous reaction is expected when handled and stored


according to provisions Stable under normal conditions of use.

Possibility of hazardous : Reacts with strong oxidising agents.


reactions
Conditions to avoid : Avoid heat, sparks, open flames and other ignition sources.

In certain circumstances product can ignite due to static


electricity.

Incompatible materials : Strong oxidising agents.

Hazardous decomposition : Hazardous decomposition products are not expected to form


products during normal storage.
Thermal decomposition is highly dependent on conditions. A
complex mixture of airborne solids, liquids and gases
including carbon monoxide, carbon dioxide, sulphur oxides
and unidentified organic compounds will be evolved when this
material undergoes combustion or thermal or oxidative
degradation.

11. TOXICOLOGICAL INFORMATION

Basis for assessment : Information given is based on product testing.


Unless indicated otherwise, the data presented is
representative of the product as a whole, rather than for
individual component(s).

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Information on likely routes of : Inhalation is the primary route of exposure although
exposure absorption may occur through skin contact or following
accidental ingestion.

Acute toxicity
Product:
Acute oral toxicity : LD 50 Rat, male and female: > 2,000 mg/kg
Method: EC Directive 92/69/EEC B.1 Acute Toxicity (Oral)
Remarks: Based on available data, the classification criteria
are not met.

Acute inhalation toxicity : LC 50 Rat, male: 6350 ppm


Exposure time: 4 h
Test atmosphere: vapour
Method: Test(s) equivalent or similar to Directive 67/548/EEC,
Annex V, B.2.
Remarks: Harmful if inhaled.

Acute dermal toxicity : LD 50 Rabbit, male: > 2,000 mg/kg


Method: Literature data
Test substance: m-xylene
Remarks: Based on available data, the classification criteria
are not met.
Information given is based on data obtained from similar
substances.

Components:
Xylene:
Acute oral toxicity : LD 50 Rat, male and female: > 2,000 mg/kg
Method: EC Directive 92/69/EEC B.1 Acute Toxicity (Oral)
Remarks: Based on available data, the classification criteria
are not met.

Acute inhalation toxicity : LC 50 Rat, male: 6350 ppm


Exposure time: 4 h
Test atmosphere: vapour
Method: Test(s) equivalent or similar to Directive 67/548/EEC,
Annex V, B.2.
Remarks: Harmful if inhaled.

Acute dermal toxicity : LD 50 Rabbit, male: > 2,000 mg/kg


Method: Literature data
Test substance: m-xylene
Remarks: Based on available data, the classification criteria
are not met.
Information given is based on data obtained from similar
substances.

Ethylbenzene:
Acute oral toxicity : LD50 Rat: > 2000 - 5000 mg/kg

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Remarks: May be harmful if swallowed.

Acute inhalation toxicity : LC50 : > 10 - 20 mg/l


Remarks: Harmful if inhaled.

Acute dermal toxicity : LD50 Rabbit: > 5000 mg/kg


Remarks: Low toxicity

Skin corrosion/irritation
Product:
Species: Rabbit
Method: Literature data
Remarks: Causes skin irritation.

Components:
Xylene:
Species: Rabbit
Method: Literature data
Remarks: Causes skin irritation.

Ethylbenzene:
Remarks: Causes skin irritation.

Serious eye damage/eye irritation


Product:
Species: Rabbit
Method: Acceptable non-standard method.
Remarks: Causes serious eye irritation.

Components:
Xylene:
Species: Rabbit
Method: Acceptable non-standard method.
Remarks: Causes serious eye irritation.

Ethylbenzene:
Remarks: Causes serious eye irritation.

Respiratory or skin sensitisation


Product:
Species: Mouse
Method: Test(s) equivalent or similar to OECD Test Guideline 429
Remarks: Based on available data, the classification criteria are not met.

Components:

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Xylene:
Species: Mouse
Method: Test(s) equivalent or similar to OECD Test Guideline 429
Remarks: Based on available data, the classification criteria are not met.

Ethylbenzene:
Remarks: Not a sensitiser.
Based on available data, the classification criteria are not met.

Germ cell mutagenicity


Product:
Genotoxicity in vitro : Method: Test(s) equivalent or similar to Directive 67/548/EEC,
Annex V, B.10
Remarks: Based on available data, the classification criteria
are not met.
: Method: Test(s) equivalent or similar to Directive 67/548/EEC,
Annex V, B.19
Remarks: Based on available data, the classification criteria
are not met.
: Test species: MouseMethod: OECD Test Guideline 478
Remarks: Based on available data, the classification criteria
are not met.
Germ cell mutagenicity- : This product does not meet the criteria for classification in
Assessment categories 1A/1B.

Components:
Xylene:
Genotoxicity in vitro : Method: Test(s) equivalent or similar to Directive 67/548/EEC,
Annex V, B.10
Remarks: Based on available data, the classification criteria
are not met.
: Method: Test(s) equivalent or similar to Directive 67/548/EEC,
Annex V, B.19
Remarks: Based on available data, the classification criteria
are not met.
: Test species: MouseMethod: OECD Test Guideline 478
Remarks: Based on available data, the classification criteria
are not met.
Germ cell mutagenicity- : This product does not meet the criteria for classification in
Assessment categories 1A/1B.

Ethylbenzene:
: Remarks: Not mutagenic.
Carcinogenicity
Product:
Species: Rat, (male and female)

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Application Route: Oral
Method: Test(s) equivalent or similar to Directive 67/548/EEC, Annex V, B.32
Remarks: Based on available data, the classification criteria are not met.

Carcinogenicity - : This product does not meet the criteria for classification in
Assessment categories 1A/1B.

Components:
Xylene:
Species: Rat, (male and female)
Application Route: Oral
Method: Test(s) equivalent or similar to Directive 67/548/EEC, Annex V, B.32
Remarks: Based on available data, the classification criteria are not met.

Carcinogenicity - : This product does not meet the criteria for classification in
Assessment categories 1A/1B.

Ethylbenzene:

Remarks: Limited evidence of carcinogenic effect, Causes cancer in laboratory animals.

Material GHS/CLP Carcinogenicity Classification


Xylene No carcinogenicity classification.
Ethylbenzene No carcinogenicity classification.

Material Other Carcinogenicity Classification


Xylene IARC: Group 3: Not classifiable as to its carcinogenicity to
humans
Ethylbenzene IARC: Group 2B: Possibly carcinogenic to humans

Reproductive toxicity

Product:
: Species: Rat
Sex: male and female
Application Route: Inhalation

Method: Acceptable non-standard method.


Remarks: Based on available data, the classification criteria
are not met.

Effects on foetal : Species: Rat, female


development Application Route: Inhalation
Method: Test(s) equivalent or similar to OECD Test Guideline
414
Remarks: Based on available data, the classification criteria

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are not met.

Reproductive toxicity - : This product does not meet the criteria for classification in
Assessment categories 1A/1B.

Components:
Xylene:
: Species: Rat
Sex: male and female
Application Route: Inhalation

Method: Acceptable non-standard method.


Remarks: Based on available data, the classification criteria
are not met.

Effects on foetal : Species: Rat, female


development Application Route: Inhalation
Method: Test(s) equivalent or similar to OECD Test Guideline
414
Remarks: Based on available data, the classification criteria
are not met.

Reproductive toxicity - : This product does not meet the criteria for classification in
Assessment categories 1A/1B.

Ethylbenzene:

Remarks: Not a developmental toxicant., Based on available


data, the classification criteria are not met., Does not impair
fertility.

STOT - single exposure


Product:
Exposure routes: Inhalation
Target Organs: Respiratory Tract
Remarks: High concentrations may cause central nervous system depression resulting in
headaches, dizziness and nausea; continued inhalation may result in unconsciousness.

Components:
Xylene:
Exposure routes: Inhalation
Target Organs: Respiratory Tract
Remarks: High concentrations may cause central nervous system depression resulting in
headaches, dizziness and nausea; continued inhalation may result in unconsciousness.,
Inhalation of vapours or mists may cause irritation to the respiratory system., May cause
respiratory irritation.

Ethylbenzene:

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Remarks: Inhalation of vapours or mists may cause irritation to the respiratory system.

STOT - repeated exposure


Product:
Exposure routes: Inhalation
Target Organs: Auditory system
Remarks: May cause damage to organs or organ systems through prolonged or repeated
exposure., Harmful: danger of serious damage to health by prolonged exposure through
inhalation., Solvent abuse and noise interaction in the work environment may cause hearing
loss.

Components:
Xylene:
Exposure routes: Inhalation
Target Organs: Auditory system
Remarks: May cause damage to organs or organ systems through prolonged or repeated
exposure., Harmful: danger of serious damage to health by prolonged exposure through
inhalation., Solvent abuse and noise interaction in the work environment may cause hearing
loss.

Ethylbenzene:
Remarks: Harmful: danger of serious damage to health by prolonged exposure through
inhalation., Auditory system: prolonged and repeated exposures to high concentrations have
resulted in hearing loss in rats. Solvent abuse and noise interaction in the work environment may
cause hearing loss., Kidney: can cause kidney damage., Liver: can cause liver damage., Central
nervous system: repeated exposure affects the nervous system.

Repeated dose toxicity


Product:
Rat, male and female:
Application Route: Oral
Method: Test(s) equivalent or similar to OECD Test Guideline 408
Target Organs: No specific target organs noted
Remarks: Over exposures of humans to xylene or xylene solvent mixtures produced
predominately central nervous system (CNS) effects with less common effects reported to the
lung, gastrointestinal tract, liver, kidney and heart.
Available animal and human results in auditory system provide limited evidence that xylenes
may induce decrements in human hearing, and it was unclear if these changes were temporary
or permanent.

Rat, male:
Application Route: Inhalation
Test atmosphere: vapour
Method: Literature data
Target Organs: Auditory system
Remarks: Over exposures of humans to xylene or xylene solvent mixtures produced
predominately central nervous system (CNS) effects with less common effects reported to the
lung, gastrointestinal tract, liver, kidney and heart.

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Available animal and human results in auditory system provide limited evidence that xylenes
may induce decrements in human hearing, and it was unclear if these changes were temporary
or permanent.

Components:
Xylene:
Rat, male and female:
Application Route: Oral
Method: Test(s) equivalent or similar to OECD Test Guideline 408
Target Organs: No specific target organs noted
Remarks: Over exposures of humans to xylene or xylene solvent mixtures produced
predominately central nervous system (CNS) effects with less common effects reported to the
lung, gastrointestinal tract, liver, kidney and heart.
Available animal and human results in auditory system provide limited evidence that xylenes
may induce decrements in human hearing, and it was unclear if these changes were temporary
or permanent.

Rat, male:
Application Route: Inhalation
Test atmosphere: vapour
Method: Literature data
Target Organs: Auditory system
Remarks: Over exposures of humans to xylene or xylene solvent mixtures produced
predominately central nervous system (CNS) effects with less common effects reported to the
lung, gastrointestinal tract, liver, kidney and heart.
Available animal and human results in auditory system provide limited evidence that xylenes
may induce decrements in human hearing, and it was unclear if these changes were temporary
or permanent.

Aspiration toxicity
Product:
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which
can be fatal.

Components:
Xylene:
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which
can be fatal.

Ethylbenzene:
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which
can be fatal.

Further information
Product:
Remarks: Classifications by other authorities under varying regulatory frameworks may exist.

Components:

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Xylene:
Remarks: Classifications by other authorities under varying regulatory frameworks may exist.

Ethylbenzene:
Remarks: Classifications by other authorities under varying regulatory frameworks may exist.

12. ECOLOGICAL INFORMATION

Basis for assessment : Incomplete ecotoxicological data are available for this product.
The information given below is based partly on a knowledge of
the components and the ecotoxicology of similar products.
Unless indicated otherwise, the data presented is
representative of the product as a whole, rather than for
individual component(s).Incomplete ecotoxicological data are
available for this product. The information given below is
based partly on a knowledge of the components and the
ecotoxicology of similar products.

Ecotoxicity
Product:
Toxicity to fish (Acute : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.6 mg/l
toxicity) Exposure time: 96 h
Method: Information given is based on data obtained from
similar substances.
Remarks: Toxic
LL/EL/IL50 > 1 <= 10 mg/l

Toxicity to crustacean (Acute : EC50 (Daphnia magna (Water flea)): 3.82 mg/l
toxicity) Exposure time: 48 h
Method: Information given is based on data obtained from
similar substances.
Remarks: Toxic
LC/EC/IC50 >1 - <=10 mg/l

Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (algae)): 2.2 mg/l


plants (Acute toxicity) Exposure time: 72 h
Method: Information given is based on data obtained from
similar substances.
Remarks: Toxic
LC/EC/IC50 >1 - <=10 mg/l

Toxicity to fish (Chronic : NOEC: > 1.3 mg/l


toxicity) Exposure time: 56 d
Species: Oncorhynchus mykiss (rainbow trout)
Method: Literature data.
Remarks: NOEC/NOEL > 1.0 - <= 10 mg/l

Toxicity to crustacean : NOEC: 0.96 mg/l


(Chronic toxicity) Exposure time: 7 d
Species: Ceriodaphnia dubia (Water flea)
Method: Other guideline method.
Remarks: NOEC/NOEL > 0.1 - <=1.0 mg/l

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Toxicity to microorganisms : EC50 (Activated sludge): > 157 mg/l


(Acute toxicity) Exposure time: 3 h
Method: Information given is based on data obtained from
similar substances.
Remarks: Practically non toxic:
LL/EL/IL50 > 100 mg/l

Components:
Xylene :
Toxicity to fish (Acute : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.6 mg/l
toxicity) Exposure time: 96 h
Method: Information given is based on data obtained from
similar substances.
Remarks: Toxic
LL/EL/IL50 > 1 <= 10 mg/l

Toxicity to crustacean (Acute : EC50 (Daphnia magna (Water flea)): 3.82 mg/l
toxicity) Exposure time: 48 h
Method: Information given is based on data obtained from
similar substances.
Remarks: Toxic
LC/EC/IC50 >1 - <=10 mg/l

Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (algae)): 2.2 mg/l


plants (Acute toxicity) Exposure time: 72 h
Method: Information given is based on data obtained from
similar substances.
Remarks: Toxic
LC/EC/IC50 >1 - <=10 mg/l

Toxicity to microorganisms : EC50 (Activated sludge): > 157 mg/l


(Acute toxicity) Exposure time: 3 h
Method: Information given is based on data obtained from
similar substances.
Remarks: Practically non toxic:
LL/EL/IL50 > 100 mg/l

Toxicity to fish (Chronic : NOEC: > 1.3 mg/l


toxicity) Exposure time: 56 d
Species: Oncorhynchus mykiss (rainbow trout)
Method: Literature data.
Remarks: NOEC/NOEL > 1.0 - <= 10 mg/l

Toxicity to : NOEC: 0.96 mg/l


crustacean(Chronic toxicity) Exposure time: 7 d
Species: Ceriodaphnia dubia (Water flea)
Method: Other guideline method.
Remarks: NOEC/NOEL > 0.1 - <=1.0 mg/l

Ethylbenzene :
Toxicity to fish (Acute : Remarks: Toxic
toxicity) LC/EC/IC50 >1 - <=10 mg/l

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Toxicity to crustacean (Acute : Remarks: Toxic


toxicity) LC/EC/IC50 >1 - <=10 mg/l

Toxicity to algae/aquatic : EC50 : Remarks: Toxic


plants (Acute toxicity) LC/EC/IC50 >1 - <=10 mg/l

Toxicity to microorganisms : Remarks: Harmful


(Acute toxicity) LC/EC/IC50 >10 - <=100 mg/l

Toxicity to fish (Chronic : Remarks: NOEC/NOEL > 0.1 - <=1.0 mg/l


toxicity)
Persistence and degradability
Product:
Biodegradability : Biodegradation: 87.8 %
Exposure time: 28 d
Method: Information given is based on data obtained from
similar substances.
Remarks: Readily biodegradable.

Remarks: Not Persistent per IMO criteria., International Oil


Pollution Compensation (IOPC) Fund definition: “A non-
persistent oil is oil, which, at the time of shipment, consists of
hydrocarbon fractions, (a) at least 50% of which, by volume,
distills at a temperature of 340ºC (645ºF) and (b) at least 95%
of which, by volume, distils at a temperature of 370ºC (700ºF)
when tested by the ASTM Method D-86/78 or any subsequent
revision thereof."

Components:
Xylene :
Biodegradability : Biodegradation: 87.8 %
Exposure time: 28 d
Method: Information given is based on data obtained from
similar substances.
Remarks: Readily biodegradable.

Ethylbenzene :
Biodegradability : Remarks: Readily biodegradable.
Oxidises rapidly by photo-chemical reactions in air.
Not Persistent per IMO criteria.
International Oil Pollution Compensation (IOPC) Fund
definition: “A non-persistent oil is oil, which, at the time of
shipment, consists of hydrocarbon fractions, (a) at least 50%
of which, by volume, distills at a temperature of 340ºC (645ºF)
and (b) at least 95% of which, by volume, distils at a
temperature of 370ºC (700ºF) when tested by the ASTM
Method D-86/78 or any subsequent revision thereof."

Bioaccumulative potential
Product:

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Bioaccumulation : Species: Oncorhynchus mykiss (rainbow trout)
Exposure time: 56 d
Bioconcentration factor (BCF): 29
Method: Literature data.
Remarks: Does not bioaccumulate significantly.

Partition coefficient: n- : log Pow: 3.16Method: Literature data.


octanol/water
Components:
Xylene :
Bioaccumulation : Species: Oncorhynchus mykiss (rainbow trout)
Exposure time: 56 d
Bioconcentration factor (BCF): 29
Method: Literature data.
Remarks: Does not bioaccumulate significantly.

Partition coefficient: n- : log Pow: 3.16Method: Literature data.


octanol/water
Ethylbenzene :
Bioaccumulation : Remarks: Does not bioaccumulate significantly.

Mobility in soil
Product:
Mobility : Remarks: Floats on water., If it enters soil, it will adsorb to soil
particles and will not be mobile.
Components:
Xylene :
Mobility : Remarks: Floats on water., If it enters soil, it will adsorb to soil
particles and will not be mobile.
Ethylbenzene :
Mobility : Remarks: If the product enters soil, one or more constituents
will or may be mobile and may contaminate groundwater.,
Floats on water.
Other adverse effects
Product:
Results of PBT and vPvB : The substance does not fulfill all screening criteria for
assessment persistence, bioaccumulation and toxicity and hence is not
considered to be PBT or vPvB.

Components:
Xylene :
Results of PBT and vPvB : The substance does not fulfill all screening criteria for
assessment persistence, bioaccumulation and toxicity and hence is not
considered to be PBT or vPvB.
Ethylbenzene :
Additional ecological : In view of the high rate of loss from solution, the product is
information unlikely to pose a significant hazard to aquatic life.

13. DISPOSAL CONSIDERATIONS

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Disposal methods
Waste from residues : Recover or recycle if possible.
It is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to
determine the proper waste classification and disposal
methods in compliance with applicable regulations.
Waste product should not be allowed to contaminate soil or
ground water, or be disposed of into the environment.
Do not dispose into the environment, in drains or in water
courses.
Do not dispose of tank water bottoms by allowing them to
drain into the ground. This will result in soil and groundwater
contamination.
Waste arising from a spillage or tank cleaning should be
disposed of in accordance with prevailing regulations,
preferably to a recognised collector or contractor. The
competence of the collector or contractor should be
established beforehand.

Waste, spills or used product is dangerous waste.

Disposal should be in accordance with applicable regional,


national, and local laws and regulations.
Local regulations may be more stringent than regional or
national requirements and must be complied with.

MARPOL - see International Convention for the Prevention of


Pollution from Ships (MARPOL 73/78) which provides
technical aspects at controlling pollutions from ships.

Contaminated packaging : Drain container thoroughly.


After draining, vent in a safe place away from sparks and fire.
Residues may cause an explosion hazard. Do not puncture,
cut or weld uncleaned drums.
Send to drum recoverer or metal reclaimer.
Comply with any local recovery or waste disposal regulations.

14. TRANSPORT INFORMATION

International Regulations
ADR
UN number : 1307
Proper shipping name : XYLENES
Class : 3
Packing group : III
Labels : 3
Hazard Identification Number : 30
Environmentally hazardous : no
IATA-DGR

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UN/ID No. : UN 1307
Proper shipping name : XYLENES
Class : 3
Packing group : III
Labels : 3
IMDG-Code
UN number : UN 1307
Proper shipping name : XYLENES
Class : 3
Packing group : III
Labels : 3
Marine pollutant : no
Maritime transport in bulk according to IMO instruments
Pollution category : Y
Ship type : 2
Product name : Xylene (Mixed Isomers)
Special precautions for user
Remarks : Special Precautions: Refer to Section 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.

Additional Information : This product may be transported under nitrogen blanketing.


Nitrogen is an odourless and invisible gas. Exposure to
nitrogen enriched atmospheres displaces available oxygen
which may cause asphyxiation or death. Personnel must
observe strict safety precautions when involved with a
confined space entry. Transport in bulk according to Annex II
of Marpol and the IBC Code

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or


mixture
Local Regulations

Workplace Safety and Health Act & Workplace This product is subject to the SDS, Labelling,
Safety and Health (General Provision) PEL and other requirements in the Act/
Regulations Regulations.

Fire Safety Act and Fire Safety (Petroleum & This product is subject to the requirements in
Flammable Materials) Regulations the Act/ Regulations.

Maritime and Port Authority of Singapore This product is subject to the requirements of
(Dangerous Goods, Petroleum and Explosives) this regulation.
Regulations

Environmental Protection and Management Act This product is not subject to the requirements
and Environmental Protection and in the Act/Regulations.

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Management (Hazardous Substances)
Regulations
The regulatory information is not intended to be comprehensive. Other regulations may apply to
this material.

Other international regulations


The components of this product are reported in the following inventories:
AIIC : Listed
DSL : Listed
IECSC : Listed
ENCS : Listed
KECI : Listed
NZIoC : Listed
PICCS : Listed
TSCA : Listed
TCSI : Listed

16. OTHER INFORMATION

Full text of H-Statements


H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H303 May be harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Full text of other abbreviations
Acute Tox. Acute toxicity
Aquatic Chronic Long-term (chronic) aquatic hazard
Asp. Tox. Aspiration hazard
Eye Irrit. Eye irritation
Flam. Liq. Flammable liquids
Skin Corr. Skin corrosion
Skin Irrit. Skin irritation
STOT RE Specific target organ toxicity - repeated exposure
STOT SE Specific target organ toxicity - single exposure

Abbreviations and Acronyms

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land
of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with

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x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer;
IATA - International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from
Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable
Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC -
New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and
Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent,
Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical
Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC)
No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition
Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG -
Transportation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations
Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very
Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System

Further information
Training advice : Provide adequate information, instruction and training for
operators.

Other information : A vertical bar (|) in the left margin indicates an amendment
from the previous version.

Sources of key data used to : The quoted data are from, but not limited to, one or more
compile the Safety Data sources of information (e.g. toxicological data from Shell
Sheet Health Services, material suppliers’ data, CONCAWE, EU
IUCLID date base, EC 1272 regulation, etc).

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.

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