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Conducted by Field Work Centre, Thondaimanaru.
FWC
4th Term Examination - 2021

,urhadtpay; II 02 E II B
Gr -13 (2021)
Chemistry II

Part – II B

g
 Answer any two questions from this part.

or
5) a) When 1 mol each of the gases A, B, and C were introduced into a closed, rigid container at , the

pressure was found to be . When the temperature was raised to , gas A decomposed

.
partically to give B and C gases. When an equilibrium was attained, the number of moles of A, B and

i.
on
C were found to be 0.5 mol, 2 mol and 1.5 mol respectively.

Formulate a balanced chemical equation for the decomposition of A using a suitable calculation.

ii. Determine the partial pressures of A, B and C at equilibrium.

ee
iii. Calculate the value of K at .

iv. Hence, deduce the value of K C for the reaction. (Assume that at 500K, RT = 4000 J )
.b

v. When the temperature is decreased to , assume that the gas C is converted to solid, and the

volume of solid is negligible. During this, a new equilibrium without any change in the

stoichiometry is established and the total pressure of the system at this equilibrium is
w

. Find the K value for the new equilibrium at .

w

vi. If the volume of the equilibrium system in part (V) above is halved, how will the equilibrium be

shifted?
w

b) Using the following thermochemical data at , calculate the following for the reaction

H H

i. Standard enthalpy change

ii. Standard entropy change.

Grade - 13 (2021) 4th Term - 2021 F.W.C 1 Chemistry ; – II B

 iii. Hence, predict whether the reaction will take place spontaneously at .

Standard bond dissociation enthalpy of H – H = J

Standard bond dissociation enthalpy of O = O = J

Standard bond dissociation enthalpy of O – H = J

compound J K
H + 188..8
H + 130.7
+ 205.1

g
c) When 1 mole of is introduced into a closed vessel of volume at , the following

or
equilibrium is established.

.
The change in Gibbs energy during the course of the above reaction is given below.

on
Gibbs free energy (G)

GA
ee
GB
R

A Extent of reaction
0.4 0
.b

(1mol)

i. Identify the sign of G corresponding to the points P, Q and R and mention whether the
reaction is spontaneous / non – spontaneous / equilibrium
w

G spontaneous / non – spontaneous / equilibrium

w

P
Q
R
w

ii. Write the relationship between and K relevant to the points P, Q and R using >, < or = signs.

P : C KC Q : KC
C

R : C KC

iii. Find K for the reaction at .

Grade - 13 (2021) 4th Term - 2021 F.W.C 2 Chemistry ; – II B

6) a) At , of a H H is taken in a titration flask and is titrated againt a

H in a burette using a suitable indicator.

(At , K of H OH is )
i. Calculate the pH of the initial H H

ii. Find the pH of the solution in the titration flask when of NaOH solution is added.
iii. Find the volume of the NaOH solution when the equivalence point is attained.
iv. Calculate the pH at the equivalence point.
v. Indicating the volume of NaOH added in X – axis and the pH of the solution in the titration flask

g
at y – axis, draw a graph. Indicate the pH at the equivalence point in your graph.

or
b) It was planned to determine the relative atomic mass of magnesium experimentally using the molar
volume value of H .

.
i. Draw the experimental setup of the apparatus used for this purpose in which magnesium and

ii.
on
dilute HCl are used
The results obtained in the experiment are given below.
room temperature =
ee
atmospheric pressure =
Saturated vapour pressure of water =
Volume of H gas formed =
.b

Mass of the piece of Mg = 0.05 g

Using the above values, calculate the relative atomic mass of Mg.
w

7)a)
i. At , calculate the pH of a weak base B of concentration
w

(At K of B is , K )
ii. Suppose that the above mentioned weak base B is titrated against HCl solution.
w

I. Write the balanced equation that takes place during the titration.
II. Considering the hydrolysis reaction of the salt formed at the equivalence point, show that the pH
C
of the solution at this stage can be given by the expression H K ( )

(Here, c denotes the initial concentration of the salt formed)

iii. Hence, calculate the pH at the equivalence point.

Grade - 13 (2021) 4th Term - 2021 F.W.C 3 Chemistry ; – II B

 b) I. 3d element A forms a complex ion B in aqueous solution. The chemical formula of B is
[ H ] . B undergoes the following reactions.

conc. HCl

B excess H exposed to air

R (red – brown solution)

dil H s Excess H T
(pink coloured precipitate)

g
i. Identify the element A
ii. What is the oxidation state of A in the complex ion B?

or
iii. State the values of m and n
iv. Write the formulae of P, Q, R, S and T and mention the colours of P, Q, and T

.
on
II. P, Q and R are three complex compounds each having a coordination sphere of octahedral geometry.
Their molecular formulae are (not in the order)
When water / H
I H H H
is added separately into the aqueous solutions of the above
compounds, the observations in the H
ee
layer are given below.

compound observation
P No change
.b

Q Violet colour
R Orange colour.
w

i. Deduce the structures of P, Q and R.

Write the chemical reactions (Considering ions only) relevant to the colours obtained in H
w

ii.
layer.
water / H
w

iii. S is another isomer of R and it does not give any observation with . Write a
possible structure of S.
iv. Mention a test to identify the anion present in S.

Grade - 13 (2021) 4th Term - 2021 F.W.C 4 Chemistry ; – II B

 Part – C
Answer only two questions.
8) a) Given below is a reaction scheme for the synthesis of compound W using H H as the only
organic starting compound. Complete the reaction scheme by drawing the structure of compounds
P, Q, R, S, T, U, V and writing the appropriate reagents A, B, C, D, E, F and G selected only from
those given in list below.
H
|
W = H H H H H
| | |
H H H

g
List of Reagents
Mg, dry ether> dilute H > Li H > > dilute NaOH, conc. H > heat> H > Ni

or
(powder) and H

H H D E R F G
S T U V

.
H
on H
|
H
H H
|
| |
H H
H H
ee
.b

R
b) Show how would you carry out the following conversion is not more than (7) steps.
Cl Cl
w

CN
w

c) H
| K H
H P
w

|
H

i) Identify P
ii) Give the mechanism of the above reaction

Cl

d)(i) Phenyl chloride undergoes the nucleophile substitution reaction yes / No. Remove incorrect
word in this statement.

(ii) Explain your answer.

Grade - 13 (2021) 4th Term - 2021 F.W.C 5 Chemistry ; – II B

9)a)(i) To complete the following flow chart identify the species and write the molecular formula.

precipitate> liquid / aqueous Gas

Solid >
solution>
The symbols give in the box are used to represent solid, precipitate, aqueous solution and gas.

White solid Salt

A

Heat

g
Colour colour

or
less basic neutral
less acidic gas
gas
B gas C D

Metal oxide

.
E

Metal
F
on Inert
behaviour
gas
neutral
gas
D
nH
ee
G

colour
Blue solution less acid amphoteric Liquid
H Dl
gas I
.b

Q + Dl
w

Yellow N
White needle crystal
precipitate

Colourless solution acid gas Cool

w

O P
M
Clear solution
w

heat

L
White precipitate

Black solid
i H
Mono basic acid K

Grade - 13 (2021) 4th Term - 2021 F.W.C 6 Chemistry ; – II B

 b) Conform the presence of and ions in the waste water released from the factory. The

following procedure was made to calculate the concentration of and present in the
waste water.
of the above waste water was taken into the beaker, it was allowed to react with

I solution. After the reaction solution of was

required to react completely with remaining I . Other sample of waste water of was

allowed to react completely with of I solution. Then this solution was

acidify with dil H and excess solution was added to it. When excess solution was

g
added, white precipitate was obtained. The above precipitate was filtrate and it was dried until the

or
constant mass obtained. Mass of the above precipitate was 3.728g calculate the concentration of

and in the waste water.

(Ba = 137, S = 32, O = 16)

.
on
10) A) A is a 3d element which form acidic, basic and amphoteric oxides. The colour of aqueous solution
of A in its lowest oxidation state is pink. A has a wide range of oxidation states in its compounds.
i. Identify the element A.
ee
ii. Give the electronic configuration of ion of the element A.
iii. Write the balanced equation for the reaction when conc. HCl is added to an aqueous solution of
.
.b

iv. Write the formulae of the oxide form by A and mention the oxidation states of A in them and
also their acidic, basic, amphoteric nature.
w

v. Give two oxo anions of A and their names.

vi. Write the balanced chemical equation of the reaction of the above oxo anion which has highest
w

oxidation state in A with conc. HCl.

vii. Give two uses of A.
w

viii. Write the molecular formula and the colour of the product formed when ammonia solution is
added to an aqueous solution of ions.

Grade - 13 (2021) 4th Term - 2021 F.W.C 7 Chemistry ; – II B

 B) P, Q and R are three complex ions. They can be either positive or negative ions. Each one of the
ligands X, Y and Z coordinates to the central cation with more than one. Each complex ion has a
coordination sphere in which only one type of ligand (X, Y and Z) is coordinated to the central
cation. Of the complex ion P, Q and R only two have a coordination sphere of octahedral geometry.
The description of the above complex ion and their relevant colours are given below.
1) The central cation is coordinated to more than one ligand X to form a green colour solution.
2) The central cation is coordinated to more than one ligand Y to form a blue colour solution.
3) The central cation is coordinated to more than one ligand Z to form a yellow colour solution.

g
i. Identify the Ligands X, Y and Z.

or
ii. Give the structures of complex ions P, Q and R formed with the above mention ligands.
iii. Give the IUPAC names of the complex ions P, Q and R.
iv. Identify two octahedral shaped complex ions and write the structures of that complex ions.

.
v. Draw the shape of the complex ions mentioned above.
on
vi. Write the chemical formula of the species formed by the above central metal ion with NaOH
and mention it colour.
vii. Write the balanced equation for the formation of the complex ion in the reaction of the
ee
complex ion having the ligand with Y.
.b
w
w
w

Grade - 13 (2021) 4th Term - 2021 F.W.C 8 Chemistry ; – II B