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Microbial Biotechnology: Energy ® Generation Approach = from the Environmental Waste Charles Rashama @, Grace N. Ijoma ©, and Tonderayi S. Matambo © 1 Introduction Landiills that form part of the sanitation supply chain in the terminal stages of han- dling municipal solid wastes (MSW) are a commonplace infrastructure across the globe, While providing this crucial service, landfills unfortunately generate signifi- cant greenhouse gas (GHG) emissions, mainly in the form of methane and carbon dioxide, arising from the biological degradation of organic components of the land- filled waste. Landiills are ranked the third largest source of anthropogenic methane (CH) contributing about 11% of the global CH, generation (Singh et al., 2018). Landiill gas (LFG) can fortunately be recovered and used as a fuel. In a time when Oil Importing Developing Countries (OIDCs) continue struggling to meet their energy demands with many of them still strongly relying on the polluting and fast depleting fossil derived fuels, Landiill gas recovery and its utilization provides an ‘opportunity to abate pollution while addressing energy deficiency. Overreliance on fossil fuels is counterproductive toward reaching the sustainable development goals (SDGs) such as climate change, clean energy, sanitation, health, etc. As such, piv- otal toward sustainability is a consideration that provides for appropriate design and ‘management of LFG recovery systems, which will ensure a holistic approach in addressing several SDGs. The sustainability concept is premised on three pillars namely the environment, economics, and social aspects (Purvis et al, 2019). This chapter reviews key considerations in sustainably developing LFG-to-energy proj ects. The considerations to be discussed will cover project stages and plant areas such as gas generation predictions, gas extraction and collection systems, gas ‘upgrading and utilization technologies, and project decommissioning decisions. ©. Reshams (29): G.N. Homa TS. Matambo Institue forthe Development of Energy for African Sustainability (DEAS), Florida, South Africa (© The Authors), under exclusive license to Springer Nature Switzerland AG 2023 bi R.A Bhatet al. (eds), Microbial Bioremediation, hups:doi. org/10-1007/978-2-081-18017-0_11 192 .Rashama etl 2 Landfill Gas: Production, Properties, and Sustainability 2.1 Microbial Production of Biogas The approach that uilizes landiill for waste management encourages the prolifera tion and abundance of anaerobic microorganisms and their favored metabolic path- ways. Landfills are designed to hold MSW and in most cases the waste is covered ‘with soil (sanitary landfill) as the waste accumulate. Surface waste partially covered by soil may harbor microorganisms that can thrive on oxygen, thereby allowing some aspects of aerobic decomposition. However, as more soil is piled on the MSW, lover time during the active lifecycle of the landfill for waste dumping, its often the ccase that anaerobic conditions overtake with the creation of anoxic conditions. This arises as a consequence of the complete sealing through the burial of the MSW. The autochthonous soil microorganisms that have adapted to anoxic conditions (micro- aerophilic bacteria and obligate anaerobes) proliferate and dominate the degrada- tion process. In the soil, microorganisms degrade organic compounds through consortia activities, These consortia-based interspecific activities encourage the production of an array of enzymes. It is beneficial to microorganisms in the degra- dation process as one species may not necessarily possess all enzymes for the deg: radation of certain compounds but in the community, concerted decomposition is more efficiently achieved with the collective effort by several species of microor- ganisms mostly comprising of bacteria, rhizospheric organisms including strepto- ‘myces and fungi, Some of the commonly existing soil microroorganisms are (then list the microorganisms given in the text) Serratia marcescens, Bacillus subtilis, B. cereus, B. thuringiensis, B. anthracis, Glutamicibacter arilaitensis, Xanthomonas, Erwinia, Pseudomonas, Proteus, Ralstonia, Escherichia, Staphylococcus, Caulobacter, Neisseria Nocardia, Actinobiospora, Nocardiopsis, Streptomyces, Streptoverticillium, Streptosporangium, and Microbiospora as well as Rhizoctonia solani, Fusarium oxysporum, Sclerotium rolfsii, Pythium ultimum (Budi etal, 2000; Felse & Panda, 2000; Someya et al,, 2000; Aarti et al, 2020). In this process of anaerobic digestion (AD), the first set of metabolic activities is hydrolytic involving the production of enzymes that primarily function for organic matter decomposition and nutrient cycling (Rehman et al., 2019). Examples of such enzymes include beta- glucosidase which degrades carbon compounds to glucose that is used as an energy source by microorganisms. Similarly, different enzymes including lipases, prote- ses, and esterases collectively involved in fluorescein diacetate hydrolysis and deg- radation of all organic matter to achieve nutrient recycling also function in hydrolysis (Prosser et al, 2011). Although hydrolysis is an important step of AD, itis a rather rate-limiting step in the overall process as the complex compounds that are being degraded usually pro- duce toxic by-products in the form of heterocyclic compounds and some non- desirable volatile fatty acids (VFAs) which require further degradation steps Microbial Biotechnology: Energy Generation Approach from the Environmental Waste 193 (Boliere etal, 2018; Wang et al, 2018; Yap et al, 2018). As a result, these mono meric compounds and volatile fatty acids including lactic acid, pyruvie acid, formic acid, and acetic acid undergo the second step of acidogenesis in which organisms such as Clostridium sp., B. subtilis, Pseudomonas stutzeri, Streptococcus sp., Lysinibacillus fusiformis, and Buryribacterium sp. (Wainana et al., 2019; Steven etal, 2020) achieve acidogenesis via oxidation; metabolites are then taken through to acetogenesis where microorganisms such as Acetobacterium, Acetoanaerobium, Acetogenium, Butyribacterium, Clostridium, Eubacteriun, and Pelobacter partci- pate inthis third step. However, in situations where varied metabolites have to be degraded to acetates, then organisms such as Syntrophobacter wolinii degrades pro- pionate, Synmrophomonas wolfei degrades butyrate, and Synirophus buswelii degrades benzoate, depending on the type of organic acids that are present (Borja, 2011; Swiatek etal, 2019). This process converts the avids to acetate and Hs, which ae the necessary substrates fr the last step, methanogenesis, where organisms such as Methanoculleus sp., Methanobacterium sp., Methanobrevibacter sp., and Methanosarcina sp. are responsible forthe production of methane and COs (Serrano Silva et al, 2014; Laiq Ur Rehman et al, 2019). As time progresses, landfill gas production subsides due to substrate depletion, without new MSW inputs on the site. But with most buried organic wastes, biogas production can span slightly over atime period averaging 40 years from landfill closure date. A typical landfill facility layout demonstrating the involvement of microorganisms in biomass degradation to produce landfill gas is shown in Fig. 1, ‘Methane ‘Greenhouse gas Compactor removal of air-creates anaerobic environment ‘Anaerobe microbial le Fig. 1 Organic waste landil with microbes degrading biomass to gas 194 .Rashama etl 2.2. Biogas and Landfill Gas Energy Properties Biogas is an energy cartier due to its methane component which is combustible to produce heat or light. The carbon dioxide which makes the other fraction in biogas is a nuisance in biogas energy applications asi is principally a suppressant for fuel combustion, Pure methane has an energy density of 37.78 Mim’ (Jingura & Kamusoko, 2017). Biogas can also be combusted in an internal engine to provide motive power for vehicles or electrical generator ses. In the case of electrical gen- crator sets, the biogas can be combusted to enable the conversion of the engine ‘mechanical power to electricity. The higher the proportion of methane versus the carbon dioxide inthe gas, the higher will be the energy density of the biogas. Carbon dioxide and other gases in the biogas dilute the methane fraction and this is thero- fore undesirable. Landfill gas as an energy carrer is considered inferior to biogas, due to low methane content and higher impurity levels. Other impurities, although normally in small quantities, that can be detected in these gases include hydrogen sulfide, siloxanes, nitrogen, hydrogen, and water vapor. Commercial technologies are available on the market for biogas upgrading to remove contaminants and increase the methane content though this comes at @ cost to biogas end users (Sun et al, 2015; Singhal, 2017). Table | outlines a few property variations between landfill and anaerobic digester gas (biogas). This information illustrates that LFG ‘may be used in similar energy applications as biogas though the upgrading require- ‘ments in cases where this is required for the two bioenergy carriers may slightly vary depending on source, substrate, and pollutant limits acceptable for each spe- cific application ‘Table 1 Comparison of biogas and landil gas characteristics Biogas Tmmplication on Tend Characteristic operations _|LPG operations | project sustuinability | References Feedstock | Nearly ‘Composition | Unreliable gas output | Levis and vanability constant and | changes more | prediction in landills | Barlaz 2011) ean be often and results in gas wastage manipulated | difficult to | (aring) or costs elated ‘control to equipment oversizing Methane (55-70 40-70 Higher concentrations | Rajaram al. composition infer high calorie value ® which improves project ‘Carbon dioxide | 30-85 30-60 Reduces caloric value | Rajaram etl component (%) ofthe gis. High eoatent_| (2012); Sitorus increases puiication | and Panjsitan costs 2013) Hydrogen | 200-4000 | 800 Cordes heat exchange | Rajaram eal. sulfide (ppm) ‘equipment or engines. | 2012); Sitorus Generates GHGs on | and Panjsitan ‘combustion (2013) Metal ad Vay across | Toxicity to human beings | Cullen and ‘components lands and clogging engine | Feldmann wen) nozzles 1997) Microbial Biotechnology: Energy Generation Approach from the Environmental Waste 195 2.3 The Sustainability Aspects of Recovering Landfill Gas for Energy Use While developing LFG recovery systems, it is important to address sustainability aspects. The concept of sustainability emanated feom the desire to protect the envi- ronment inthe wake of rapid economic developments that took place in many coun- teies during the first and second industrial revolutions peaking in the late nineteenth century. Generally, sustainability evaluates any development on the economie met- its, environmental harm that may affect future generations’ potential to benefit from current resources as well as the current ethical and social acceptability of the pro- cess oF project (United Nations, 2020). This concept gained widespread attention around 1900 prompting the United Nations (UN) to develop a set of seventeen (17) time-bound goals referred to a the Sustainable Development Goals (SDGs). These goals commenced in 2015 and are targeted to reach maturity by 2030. These SDGs are aimed at fostering a focused approach among countries for addressing the Sub- ject of sustainability. Moreover, SDGs involve all economies and encompass a broader scope of development covering poverty, economy, environment,and social dimensions as opposed tothe narrower predecessor goals (Millennium Development Goals (MDGs)). The MDGs focused more on ending poverty in developing nations with very limited scope to involve developed economies. The eight (8) MDGs were formulated in 2000 and expired in 2015 when SDGs came into effect. The use of LLFG as fuel contributes both directly or indirectly, in addressing some of the SDGs as depicted by the connecting lines between LFG activities and the SDGs affected by each activity in a hierarchy form of Fig. 2 Objective sbGs Landfill gas Activities Gas use in cooking Gas use in CHP engines Gas use in vehicles Gas use in central heating <—~(=- (cossionstaenen ‘emission abatement Digestate recycling Fig. 2 Contribution of land gas recovery activities int the sustainability space. WASIT stands for water, sanitation, nd health, CHP stands fr combined heat and power. Te number in brackets denotes the SDG number allocated by the United Nations 196 Rash etal. ‘There are many approaches and tools used to evaluate a development project’s sustainability. These approaches were reviewed by Ness et al. (2007) who pointed out thtee broad classifications of these methods as the indicators, product assess- ‘ment, and the integrated assessment (Ness et al., 2007). The integrated assessment which covers both qualitative and quantitative attributes of a project appears to be ‘more suitable for the LFG biogas development context and will therefore be adopted in discussing sustainability issues in this chapter, Coneisely, the social, economic, and cnvironmental dimensions of the key activities in LFG development for energy tse will be the central theme of discussion in this chapter. 3 Landfill Gas Capturing and Usage: General Process Description Although there are a few variants to the process flow diagrams (PED) for LFG extraction and processing, the basic one is described by Liu etal. (2017) as depicted in Fig. 3, Briefly explained, gas extraction involves sucking out the gas from a land- fill, by creating a vacuum using a blower that will be connected to perforated pipes. Along the gas conveyance pipes, water vapor condenses and is knocked out. The gas is then directed to the processing units where pollutants like hydrogen sulfide, car- bbon dioxide, and sometimes siloxanes as well as volatile metals are removed. The Fig.3. Schematic diagram depicting landfill gas recovery for energy use Microbial Biotechnology: Energy Generation Approach from the Environmental Waste 197 extent of gas processing depends on the intended final gas utilization, Processed gas is directed to various end uses. I there is excess gas supply than consumption, flar- ing facilities are incorporated on the gas delivery piping to cater for system over- pressure (Liu et al, 2017). 4 Landfill Gas Quantification Models To design and operate a sustainable LFG recovery system the potential amount of LRG that is likely to be generated and collected from a landfill must be estimated carefully since this is an important input for the Feasibility study (Majdinasab et al 2017), Test wells can be drilled on a land6fll to gather and estimate LFG production potential as well as collection efficiency data but this process is expensive and time- consuming. Gas output predictions are therefore achieved through empirical, math- ematical, and numerical modeling approaches, There are more than twenty (20) LFG generation projection models and modeling approaches in existence that have been developed and applied across the globe with additional eight (8) models that are country-specific (Rajaram et al, 2012) ‘The abundance of LFG generation prediction models is dictated by variability in the composition of wastes landiilled, climate conditions, differences in landfill ‘management practices such as leachate recirculation ratios, cover designs, etc. The ‘most popular models however are the LandGEM, IPCC, and the country-specific models (Gollapalli & Kota, 2018). The LandGEM model was developed for American conditions though it can be modified and adapted for use in other coun- tries across the globe, most likely with limited adjustments, The model is therefore ‘widely accepted in America and the Latin American region. The IPCC model which is more flexible in terms of accommodating variable conditions is currently the most preferred model by international development agents for clean develop- ‘ment mechanism (CDM) funding requirements under the Kyoto Protocol arrange- ments. The eight country-specific models that were developed by the Global Methane Initiative (GMI) have the combined attributes of the LandGEM and the IPCC. These country-specific LFG output prediction models factored regional local conditions and are therefore popular in the regions or countries for which they were specifically designed for. Table 2 highlights common aspects which affect accuracies in most LFG models. Aspects of sustainability in LEG develop- ment project for energy recovery are also highlighted in the same table. It isnot the intention of this chapter to discuss detailed technical differences, assumptions held, and application suitability of the various LFG projection models. Majdinasab ct al. (2017) and Rajaram et al, (2012) reviewed the development of the various LFG models, comparing their relative differences, advantages, and disadvantages so these sources can he consulted to better understand this subject (Rajaram et al, 2012; Majdinasab et al., 2017). 198 Rash et ‘Table 2 Landi! gas modeling variables and considerations that affect sustainability ‘Modeling [Tafuence on modeling and key variable | considerations Sustainability aspoctafected | Reference "Amount of | Available waste quantities | Cost -Overestimating gas___|Scarlat ea. waste change with lifestyle and output affects plant sizing with | (2015) changing demographics. possibilities ofa big Securing accurate data on waste underutilized plant ‘quantities i a problem ‘Underestimations of gs outputs Particularly in developing | will also imply inedequate ‘countries. Consider these | exploitation ofthe resources challenges to make reasonable_| with possible excess methane adjustments on LEG model | escaping into the atmosphere as forecass [GHG or fared. ‘Composition | Waste compositions change | Cost - Incomplete wage of ga | Mou etal cof waste | inconsistently in mosteases. | generated because of undersized | (2015); Foodstuff waste degrades fast | unis or vice versa CChakima and shortening the lanl lifespan, | Environmenta/social — Mathur Lignocellulosic behave ‘Compliance relies on 2016) otherwise while organics do | understanding the complete not degrade, Make informed | degradation of waste estimates of these ste-speciic | components ‘compositional issues in ‘modeling and it would be beter to be conservative on high methane-yielding components ‘Moisture | Moisture atfcts LEG Degradation rates affect project | Chakma and content” | generation rates, Local rainfall lifespan hence costing. Mathur pattern, runoff seepage contol | Leachates come with 2016); {nto the landill and leachates | environmental tigation costs | Gupta and recirculation rates mast be and socal unrest from affected | Para considered during LFG communities. 016) modeling “Temperature | Anaerobic digestion proveeds Inaccurate projections due to | Chaka and reasonably well at temperatures | non-consieraton of Mathur herween 30 and 40°C-1F | temperature will affect the | 2016); Vu factions im local project economics and etal. 2017) temperatures are anticipated, | potentially if outputs then this should be Tactred in underestimated the excess ‘modeling LFG mode! output, | generation will be released 3s Site-specific rather than default | GHG into atmosphere values in the model are always recommended ‘Age of te | Landil gas production rates | Poorly tined record inputs will | Rada etal Tsai! | and eumaative amount is time | affect anticipated gas volumes | 2015) dependent soit is important to factor in landfill agezlated considerations in the interpretation ofthe model outputs. leading to mismatched and ‘unnecessarily costly designs. (continued) Microbial Biotechnology: Energy Generation Approach from the Environmental Waste 199 Table 2 (continued) ‘Modeling | Tofuence on modeling and key variable | considerations Sustainability aspoct affected | Reference ‘Oxygen | Consider airinfiraton caused | If oxygen effects are not Rachor and ingress into | by aggressive operation of | accounted forespecially in| Gebert landill | eolletion (vacuum) systems | shallow depth andl, the isk. | 2013) and uncovered landills. Aix | of overestimating methane gas Feduces methanogenesis hence | generation is high and will affect the projected methane ges | project financials negauvely outputs. Some ofthe organics will also be degraded scrobically without methane generation if er ititration is high while some methane is oxidized by methanotzophs 5 Landfill Gas Extraction and Collection Major components of a gas extraction system include the extraction wells, header and distribution piping, moisture removal equipment, and blowers for vacuum cre- ation, Different options for each piece or components of equipment and the ultimate plant design exist on the market. The selection criteria for these units ought to con- sider the fitness for purpose, cost-effectiveness, and improvement of the energy project sustainability attributes. Some of the recommended key considerations are briefly discussed in Table 3 with emphasis placed on the sustainability impact of each consideration 6 Landfill Gas Purification Technologies ‘The gas processing section objectives include removal of pollutants such as hydro- gen sulfide, siloxanes, and other non-methane organic compounds (NMOCs) which are detrimental to the end-user equipment or the health of gas users (Kaparaju & Rinlala, 2013), Processing also improves the calorific value of the LFG gas by removing the non-combustible components such as carbon dioxide. The choice of equipment and technologies applicable to LEG gas upgrading depends on the intended final wilization of the gas. It may nat be economically sustainable to incur high purification costs for low Btu applications (boilers, furnaces, micro-turbines) where energy efficiency may be poor or minimal equipment damage is expected from gas contaminants (Kaparaju & Rintala, 2013), Some of the gas purification technologies and considerations to make as well as their implications on project sustainability are briefly discussed below. Rash et 200 usuruona pue xodo YBIH ado, ‘uo aus nq ode 2sras5u7 augur dns $83 pur 03 aa] ‘pon 201 “Microbial Biotechnology: Bnerey Generation Approach from the Environmental Waste (ponunuo>) ‘pus um suoreiedo aes pur oom | 30) Aressatr ng p09 24 | ‘ue uonrpuos Sunjom poo uy suoumnsu yo sours -aroudsoune| ‘901 atau posonooarun | qemu senuoiod ary sournemop at sours a4 809 Ket yogi | By st uapanqraxo wy ssor2qo9 0 euro ar aod a 90H ‘woneesin 1 Kps09 am sojaurppojog3309 28807 | Tibi ove Jo foiuo9 S503 pT Popuouuioso1 L101 enbo.o 559) sas Hutsey rrusiew Zee Pareoduoout ag ose deus soi Jo osneog ruotew Suse an suns sq dugg pa 809 vo uspuedap | spjse2 20] popuotato: sgaoq sour] ‘son Bnseo!o0, 3ng BuOF00 st ywamady|d asa aint aq we HNO addons sey usta ase x04 Sq 30) TOP pov Suyon suunsnipe ound st20044 101291109 DAT Rash et 2m ue souruoyrew yon) | Dep ovo] 8 anrs Keur uontodo pus woneyesut "ets “uonsojs fan sumesneew (6102)| ons ansuado fqpuou ame) oxy ys Baryon pu wpUadap sondns wre pusvamey | auauidin pausisap-mosnd saamuynurm mus WoRIOgEIOD | sono (102) suors4s Saypuey Trp pussuaoy.| aesuopuos paureureu ood ‘syesuapeos| 102)| Ka pastoxduios 2g we pr our (ew auor7eq| uonezT Argedeo pus Kayes | stTURYDOUT WBHUTE qpIM SUEIP s¥esuapHOD| _Aajgedeo pus ssouUTE WeNsAS | eeHNs SuPUEHE (1102) vues, Dae Suz pose aid ayn Jo suorsuounp| sod ur apesupu03| {0 moy 293 motte 0 yesw3puen pu #8330 hangar 1 Kydnaodo yo afeuceape ae), soy oresuapuos ue “roo sores wornpaud = suo note poe ado a nid ud 9p ee eT ‘soon ‘worn SgeUSNS ‘Bua wisoq, ‘suormapIsues Kay ‘war uORSEN (ponuno>) ¢ qa, Microbial Biotechnology: Energy Generation Approach from the Environmental Waste 203 6.1 Moisture and Particulates Removal Moisture cause rusting and reduce LFG calorific value. Adverse effects also arise from particulates that may block gas nozzles in end-use equipment. Knockout pots, moisture separators, mist eliminators, direct cooling as well as compression fol- lowed by cooling are equipment and techniques that have been traditionally used to remove moisture and at times concurrently entrapping the particulates as well, More advanced and efficient but possibly expensive absorption and adsorption technolo- gies for moisture removal also exist with filters also employed for particulates removal where high particulate loads cannot be adequately addressed by basic entrapment in condensate, 6.2 Hydrogen Sulfide Removal (Combustion of H,S in intemal engines impacts on engine components’ corrosion as well as the safety of people when acidic sulfur oxides are produced. Arising from this are engine repair costs, environmental litigation claims from acid rain-related damages, and social issues such as workers’ moral, health, and safety which are all project sustainability components to consider when developing LEG projects. Iron sponge and use of microorganisms that consume H,S have been employed in man- aging its removal from LFG (Sun et al, 2015). 6.3 Siloxanes Removal Siloxanes in LFG emanate from household and industrial wastes and they endanger the combustion engine components by forming silicon dioxide (SiO,). This SiO: reduces equipment efficiencies and is difficult to reverse once formed. The SiO; formation is more detrimental when LFG is used in engines and turbines than in thermal applications such as boiler furnaces. Therefore, the decision to undertake the expensive adsorptive, absorptive, or eryogenie condensation to mention a few treatments (Ruiling ct al., 2017) for siloxane removal must be based on a cost- benefit analysis to be performed before project implementation, 6.4 Carbon Dioxide Removal High-grade fuel applications like compressed natural gas and microbial cells require high methane content and ultrapure gases so CO; removal becomes paramount. Most gas cleaning technologies however remove a number of contaminants 208 Rash etal. simultaneously, using principles such as surface adsorption (molecular sieves), ‘membrane separation, or a solvent treatment system (Sun et al., 2015). Technology choice for solvents used to depend on solvent's selective affinity for either CO;, HO, oF HS matched with considerations forthe level of contaminants in the gas as well as the end user contaminant acceptable limits, Solvents commonly employed fare organic amine-based, such as methyl diethanolamine (MDEA), methyl ethanolamine-diethanolamine adsorption (MEA-DEA), and diglycolamine (DGA), Alternatively, hot potassium carbonate, propylene carbonate, and sclexol have also been used. These technologies are generally expensive and must be used for high ‘market value product applications, 7 Potential Landfill Gas Utilization Landfill gas utilization depends on a number of factors including the quality of the LFG, the amounts of LFG generated, cost of the utilization technology as well as competition from other resources used for similar application. However, the most dominant factor is the quality or purity of LFG with the broad LFG quality grades being low, medium, and high. The LEG applications compatible with each specific LEG grade are depicted in Fig. 4 Low-grade LFG is used after moisture removal only from the raw landfill gas and no extra processing steps. However medium-gradc LFG is produced by removing sulfur, siloxanes, volatile organic compounds as well as mercaptines and moisture Fig. 4 Different andl gas utilizations based on quality ofthe gas Microbial Biotechnology: Enerey Generation Approach from the Environmental Waste 205 from the raw landfill gas, Common low-grade LFG applications involve thermal units such as boilers, furnaces, driers, and kilns where the damaging LFG is not in direct contact with the major equipment. Infrared heating, leachate evaporation, and microturbines have also been reported to employ low-grade LFG, Medium-grade LEG finds applications in thermal equipment just like the low-grade LFG, and can also be used for electricity generation in gas turbines, reciprocating engine, and combined heat as well as power (CHP) units, High-grade LFG is distinguished from ow and medium grades LFG by less pollutant load and a higher calorific value. High-grade LEG is produced by removing carbon dioxide from the medium-grade LFG. Key considerations in LFG utilizations that may impact on sustainability are depicted in Fig. 5 (bulleted points in textbox). One major consideration for any LFG ‘grade utilization is proximity to the gas generation site since pipeline transportation and the subsequent pressures required are a costly that increases with distance (Hoo ctal., 2018). + High equipment compromise safety sand increase ‘maintenance bills, 4 End user proximity iskey asitis costly trangport ow quality ga for Fig. Sustainability considerations for different landil gas uilizaion options 206 .Rashama etl 8 Costing and Financing of Landfill Gas Recovery Projects The economic evaluation of a landiill project follows a S-step process involving costing (capital and operating), revenue calculations, economic feasibility caleula- tions, selection of best design and finally choosing a suitable financing option. The Landiill Gas Energy Cost Model (LEGcost-Web) is a web-based tool useful in per- forming LFG economic feasibility studies which was developed by the Landfill Methane Outreach Program (LMOP) of the U.S. Environmental Protection Agency At each stage of the economic evaluation process, some key considerations with a {ew of them highlighted below affect the overall project sustainability 8.1 Capital and Operating Costs Capex and Opex values for the project are collected at this stage. Various equipment and end-use technologies must be considered with actual suppliers’ quotations to censure that the most advantageous option is finally selected. Preliminary evaluation ccan be based on typical costs while the detailed feasibility study must apply project- specific values. Each technology must be evaluated considering also its non- ‘monetary merits and demerits with possibilities of economies of scale also explored. 8.2 Revenue Calculations Alll revenue streams including sales of gas, electricity, and utilities (in the case of steam and hot water from CHP) engines must be considered. Other revenues from various schemes like premium pricing, tax credits, GHG credit trading, incentive payments, or Kyoto protocol mechanisms (Clean Development Mechanism (CDM) and Joint Implementation (JD) can also be incorporated in the evaluations where applicable. 83 Economic Feasibility Study This phase of the project must consider the cost of capital, economic inflation, risk sensitivities, and price uncertainties. These including the revenue and capital cost components collected above are used to deduce internal rates of return (IRR), net present values (NPV), payback periods (PBP), and annual cash flows thet form the basis of economic feasibility of the project. Microbial Biotechnology: Energy Generation Approach from the Environmental Waste 207 8.4 Selecting the Best Design At this stage, the successful projects based on economic feasibility are further sub- jected to sensitivity analysis and non-price factors to test their robustness against these factors. Risk factors are weighed at this stage and the most advantageous option is chosen. The use of experienced developers in factoring these non-price factors especially around the risk of poor gas prediction modeling may be helpful at this stage. Other factors to consider include political risk, equipment reliabilities, availability of electricity or utilities off-takers and construction materials availabil- ity, The United Nations Convention for Climate Change (UNFCCC) provides {guidelines and tools for investment analysis and economic feasibility studies respec- Lively for projects targeting CDM certification 85 Choosing the Financing Option There are many financing mechanisms and instruments for LEG projects around the globe and a choice of the best available one or mix of them must be chosen for each specific project. The various funding options have conditions and requirements to bbe met therefore expert advice and thorough searches for the best option may be requited. Some of the funding options to consider are the Kyoto protocol mecha- nisms, Bank finance (Multilateral, sub-regional, national and local) then private investors, and leasing arrangements (Sell and lease back, lease pass-through). Grant ‘opportunities and internal resources can also be used to fund LFG development projects, The detailed advantages and disadvantages of each of these funding oppor- tunities should be explored with the help of experienced Finance practitioners to make the best selection, 9 Decisions on Decommissioning When LFG generation dwindles with the lifespan of a landfill, a period is reached when it would not be best economic practice to extract the gas for energy uses. Issues of reliability and quality of gas arise, and the project must be decommis- sioned. Hsieh etal. (2008) described what they called a sustainable landfill whereby ‘on decommissioning the landiil is fist subjected to aerobic conditions by pumping air into the wells to facilitate rapid composting of residual organies prior to mining the landfill (Hsieh et al., 2008). The mining is done to recover resources (compost is used for soil conditioning and undecomposed materials are recycled) and also to rouse the land space. Ifthe landfill is not composted and mined, then landfill after- care strategies must be put in place until the landfill is deemed safe for human health and the environment (Laner et al., 2012). The different landfill aftercare options and considerations that may affect sustainability are reported in Table 4, 208 ‘Table 4 Landi aftercare options and thei sustana c. ity. Laner ea, 2012) Rashama etl “Afiereare ‘Sustainability srengs oF lltemative | Specific description __| shortcomings References ‘Timeframe | Regulations will stipulate |The developervowner knows what | Laner eta based When a developeriowner | is expected of them so can budget | (2012): Chu ‘can abandon the landil | beforchand but society is @a16 ‘vulnerable to any chemical, biological, or physical land status that my thresten human health andthe environment ater the developer abandons project. Landi pos-

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