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1 Identification
Product identifier
Trade name: SPECTRUM YELLOW SY313
Article number: SY-313
CAS Number:
51274-00-1
Application of the substance / the preparation
Pigment
Coloring agent for cementitious materials.
Uses advised against :
Food additive as per 21 CFR 73.200
Ingredient for pharmaceutic preparations as per 21 CFR 173.1200
Ingredient for cosmetic preparations as per 21 CFR 73.2250
Applications where there is a direct or indirect contact with foodstuffs
Coloring agent for articles and materials as intended use in toys according to ASTM F963-16.
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Cathay Industries Asia - Pacific Ltd.
Suite 901A, 9/F, ChinaChem Golden Plaza
77th Mody Road, Tsimatshui East, Kowloon
Hong Kong SAR
(P.R.CHINA)
Information department:
Product Safety Department
[email protected]
Emergency telephone number:
Emergency Telephone of CATHAY INDUSTRIES ASIA - PACIFIC Ltd.: +852 2721 22570
Chemtrec at 1-800-424-9300.
2 Hazard(s) identification
Classification of the substance or mixture
The substance is not classified according to the Globally Harmonized System (GHS).
Label elements
GHS label elements Void
Hazard pictograms Void
Signal word Void
Hazard statements Void
According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 :
Potential Health Effects
Inhalation Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
Skin May cause mechanical irritation (abrasion).
Eyes May irritate the eyes by mechanical effect.
Ingestion No known significant effects or critical hazards.
Routes of exposure
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact.
Classification system:
NFPA ratings (scale 0 - 4)
Health = 1
0 Fire = 0
1 0 Reactivity = 0
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HMIS-ratings (scale 0 - 4)
HEALTH *1 Health = *1
FIRE 0 Fire = 0
REACTIVITY 0 Reactivity = 0

Results of PBT and vPvB assessment

PBT: Not applicable.
vPvB: Not applicable.
3 Composition/information on ingredients
Chemical characterization: Substances
CAS No. Description
51274-00-1 Iron hydroxide oxide yellow
Additional information:
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
* 4 First-aid measures
Description of first aid measures
General information: Remove severely contaminated clothing and clean before reuse.
After inhalation:
Loosen tight clothing such as a collar, tie, belt or waistband.
If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention.
If necessary, restore normal breathing through standard first aid measures.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Continue to rinse for at least 10 minutes.
In the event of any complaints or symptoms, avoid further exposure.
After eye contact:
Check for and remove any contact lenses.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Continue to rinse for at least 10 minutes.
Get medical attention if irritation occurs.
After swallowing:
Rinse mouth with water, give subject liquids to drink and do not induce vomiting.
Never give anything by mouth to an unconscious person.
If vomiting occurs, the head should be kept low so that vomit does not enter the lungs.
If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.
In case of inhalation: Dust may cause irritation to the respiratory tract.
In case of skin contact: May cause mechanical irritation (abrasion).
In case of eye contact: May irritate the eyes by mechanical effect.
In case of ingestion: No known significant effects or critical hazards.
Over-exposure signs/symptoms :
Eye contact : No specific data.
Inhalation : Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
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Skin contact : No specific data.
Ingestion : No specific data.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Protection of first-aiders: No special measures required.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents: Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
Not considered flammable but packaging, i.e. paper bags, wooden pallets, and plastic wrap will burn.
Advice for firefighters
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.
No action shall be taken involving any personal risk or without suitable training.
Protective equipment:
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA) with a full face-piece operated in positive pressure mode.
Wear fully protective suit.
Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
No action shall be taken involving any personal risk or without suitable training.
Keep away unnecessary and unprotected personnel.
Put on appropriate personal protective equipment (see Section 8).
Avoid formation of dust.
Ensure adequate ventilation
Hazard of slipping on spilt product.
Environmental precautions:
Prevent seepage into sewage system, workpits and cellars.
Do not allow product to reach sewage system or any water course.
Keep contaminated washing water and dispose of appropriately.
Inform respective authorities in case of seepage into water course or sewage system.
Even at low concentration, the product renders the discharge in liquid effluent highly visible.
Methods and material for containment and cleaning up:
Small spill
Ensure adequate ventilation.
Stop leak if without risk.
Pick up and arrange disposal without creating dust.
Sweep up and shovel.
Keep in suitable, closed containers for disposal.
Dispose of via a licensed waste disposal contractor.
Large spill
Ensure adequate ventilation.
Avoid creating dusty conditions and prevent wind dispersal.
Stop leak if without risk.
Move containers from spill area.
Pick up and arrange disposal without creating dust.
Sweep up and shovel.
Dispose of via a licensed waste disposal contractor.
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Following product recovery, flush area with water.
Clean the affected area carefully; suitable cleaners are:
Warm water and cleansing agent
Absorb in vermiculite, dry sand or earth and place into containers.
Keep in suitable, closed containers for disposal according to local regulations (see section 13).
See section 1 for emergency contact information and section 13 for waste disposal.
Reference to other sections
No dangerous substances are released.
See Section 1 for emergency contact information.
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
Substance is not listed.
PAC-2:
Substance is not listed.
PAC-3:
Substance is not listed.
* 7 Handling and storage
Handling:
Precautions for safe handling
Open and handle receptacle with care.
Prevent formation of dust.
Provide suction extractors if dust is formed.
Ensure good ventilation/exhaustion at the workplace.
Any deposit of dust which cannot be avoided must be regularly removed.
Information about protection against explosions and fires:
The product is not flammable.
Plastic wrap from palletized packages may bear significant static charge which can cause flash fire if near
combustibles.
Conditions for safe storage, including any incompatibilities
Storage: Store in accordance with local regulations.
Requirements to be met by storerooms and receptacles:
Keep in the original container or an approved alternative made from a compatible material.
Pigments should not be stored in outside areas exposed to the weather.
Containers that have been opened must be carefully resealed and kept upright to prevent leakage.
Do not store in unlabelled containers.
Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from incompatible materials (see section 10).
Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Protect from humidity and water.
Storage duration (months) : 60
Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.
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* 8 Exposure controls/personal protection

Recommended monitoring procedures :
If this product contains ingredients with exposure limits, personal, workplace procedures atmosphere
monitoring may be required to determine the effectiveness of the ventilation or other control measures
and/or the necessity to use respiratory protective equipment.
Additional information about design of technical systems:
Mechanical ventilation may be required to maintain exposure levels below limits.
Control parameters
Components with limit values that require monitoring at the workplace:
CAS: 51274-00-1 Iron hydroxide oxide yellow
ACGIH TLV Short-term value: 10 mg/m³
8 hours
OSHA PEL Short-term value: 5 mg/m³
8 hours (Total dust)
Ingredients with biological limit values:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Handle in accordance with good industrial hygiene and safety practice.
Ensure that proper housekeeping measures are in place.
Keep away from foodstuffs, beverages and feed.
Do not eat, drink, smoke or sniff while working.
Wash hands before breaks and at the end of work.
Vacuum clean contaminated clothing. Do not blow or brush off contamination.
Do not inhale dust / smoke / mist.
Ensure that washing facilities are available at the work place.
Wash contaminated clothing before reusing.
Breathing equipment:
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product
and the safe working limits of the selected respirator.
Dust-protection mask.
For nuisance exposures use type P95 (US) particle respirator.
For a higher level of protection use type OV/AG/P99 (US) respirator cartridges.
Use respirators and components tested and approved under appropriate government standards such as
NIOSH.
Protection of hands:
Gloves impervious to dust.
Wash and dry hands.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Use equipment for hands protection tested and approved under appropriate government standards such
as NIOSH.
Material of gloves
No special glove composition is required.
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
(Contd. on page 6)

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Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to
be observed.
Eye protection:
Use safety glasses with side-shields or goggles to protect against airborne dust.
Use equipment for eye protection tested and approved under appropriate government standards such as
NIOSH.
Body protection: Protective work clothing
Limitation and supervision of exposure into the environment
Emissions from ventilation or work process equipment should be checked to ensure they comply with the
requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering
modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder
Color: Dark yellow
Particle shape: Acicular.
Odor: Odorless
pH-value (100 g/l) at 25°C (77 °F): 3,0 - 8,0 (ISO 787-9)
Change in condition
Melting point/Melting range: > 1000°C (>1,832 °F)
Flash point: Not applicable.
Flammability (solid, gaseous): Product is not flammable.
Decomposition temperature: > 180°C (>356 °F) (DTA)
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Oxidizing properties No oxidizing properties.
Vapor pressure: The product is a non-volatile solid.
Specific gravity at 20°C (68 °F): c.a. 4,2 g/cm³ (35.05 lbs/gal) (ISO 787-10)
Bulk density at 20°C (68 °F): 350 - 500kg/m³ (ISO 787-11)
Relative density (Water = 1) Not determined.
Vapor density (air = 1) The product is a non-volatile solid.
Evaporation rate The product is a non-volatile solid.
Solubility in / Miscibility with
Water at 20°C (68 °F): <0,000001g/l
Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
Iron content (as Fe2O3) : > 86% (BS1014)
Heating loss at 110ºC : < 1,0% (ISO 787-2)
Other information No further relevant information available.
(Contd. on page 7)

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* 10 Stability and reactivity

Reactivity No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability
No decomposition if used and stored according to specifications (see Storage, Section 7).
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications (see Storage, Section 7).
Thermal decomposition: > 180 °C
Loss of constitutional water on heating.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid
Excess heat.
Situations which cause dusting.
Incompatible materials: No further relevant information available.
Hazardous decomposition products: No dangerous decomposition products known.
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
CAS: 51274-00-1 Iron hydroxide oxide yellow
Oral LD50 >10,000 mg/kg (Rat (male))
Inhalative LC0/4hr. >4 mg/lit (rat)
Repeated dose toxicity :
CAS: 51274-00-1 Iron hydroxide oxide yellow
Inhalative NOAEC 4.7 mg/m3 (rat) (OECD 413)
read-across based on grouping of substances (category approach)
10.1 mg/m3 (Rat (male)) (OECD 412)
Read-across based on grouping of substances (category approach)
NOAEL >195.7 mg/m3 (rat) (OECD 412)
Irritation / Corrosion :
CAS: 51274-00-1 Iron hydroxide oxide yellow
Irritation of skin In vivo (rabbit)
Not irritating
Irritation of eyes In vivo (rabbit)
Not irritating
Sensitisation :
CAS: 51274-00-1 Iron hydroxide oxide yellow
Sensitization In vivo skin sensitization (Guinea pig) (Maurer optimisation test)
Not sensitizing
Genetic toxicity :
CAS: 51274-00-1 Iron hydroxide oxide yellow
In vitro mammalian chromosome aberration test (Hamster) (OECD 473)
Negative (read-across based on grouping of substances
(category approach))
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Reverse mutation assay (Ames test) (Salmonella typhimurium) (OECD 471)
Negative (read-across based on grouping of substances
(category approach))
In vitro mammalian cell gene mutation assay (Hamster) (OECD 476)
Negative (read-across based on grouping of substances
(category approach))
Primary routes of exposure
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact.
However, ingestion is not likely to be a primary route of occupational exposure.
Potential acute health effects : Health injuries are not known or expected under normal use.
Health conditions aggravated by exposure : Asthma, Respiratory disorders.
Inhalation : No known significant effects or critical hazards.
Ingestion : Expected to be a low ingestion hazard for usual industrial handling.
Skin : No known significant effects or critical hazards.
Primary irritant effect:
on the skin: May cause mechanical irritation (abrasion).
on the eye: May irritate the eyes by mechanical effect.
by inhalation: Dust may cause irritation to the respiratory tract.
Skin sensitization : This product is not expected to cause skin sensitization.
Respiratory sensitization : This product is not expected to cause respiratory sensitization.
Specific target organ toxicity
Single exposure (Globally Harmonized System) No significant effects or critical hazards.
Repeated exposure Inhalation - May cause respiratory irritation.
Subacute to chronic toxicity:
Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
Prolonged inhalation of iron oxide dust is known to produce condition given as siderosis. On X-rays it
appears to be pneumoconiosis and it is not associated with pulmonary fibrosis or disability unless there is
concurrent exposure to other fibrosis-producing materials such as silica.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
Substance is not listed.
NTP (National Toxicology Program)
Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.
Potential chronic health effects
Carcinogenicity No known significant effects or critical hazards.
Mutagenicity
No data available to indicate product or any components present at greater than 0.1% are mutagenic or
genotoxic.
Teratogenicity No known significant effects or critical hazards.
Developmental effects This product is not expected to cause reproductive or developmental effects.
Fertility effects No known significant effects or critical hazards.
Aspiration hazard : Based on available data, the classification criteria are not met.
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* 12 Ecological information
Aquatic toxicity:
Short- term toxicity :
CAS: 51274-00-1 Iron hydroxide oxide yellow
EC0/96 hr. (static) >10,000 mg/lit (Bacteria)
LC50/48 h (static) >100 mg/lit (Daphnia magna) (OECD 202)
LC0/96 hr. (static) >100,000 mg/lit (fish) (OECD 203)
Persistence and degradability Based on previous experience, this product is inert and non-degradable.
Behavior in environmental systems:
Bioaccumulative potential
Bioaccumulation is unlikely to be significant because of the low water-solubility of this product.
Mobility in soil Insoluble. Expected to remain on soil surface.
Ecotoxical effects:
Remark:
The product does not contain heavy metals in concentrations of concern for waste water.
The product does not release nitrogen which can contribute to eutrophication.
The product does not contain phosphates or organophosphorus compounds.
Behavior in sewage processing plants:
Remark:
The product is easily emovable from water by physico-chemical processes.
Incidental down-the-drain disposal of small quantities of product will not affect the performance of
wastewater treatment systems.
Additional ecological information:
General notes: Generally not hazardous for water
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Dispose of in accordance with local, state, and federal regulations.
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Contact waste processors for recycling information.
Incineration or landfill should only be considered when recycling is not feasible.
Hazardous waste :
This product is not considered as hazardous waste per 40 CFR 261.24 or 261.33. However, the user
should consult with the state regulatory agency before disposing of the material.
Disposal should be made in accordance with federal, state and local regulations.
Waste disposal key:
As sold, this product is not classified as a RCRA hazardous waste as defined by 40CFR261.
It is the responsibility of the user to determine RCRA classification of any product containing this iron
oxide.
Uncleaned packagings:
Recommendation:
The generation of waste should be avoided or minimized wherever possible.
Dispose of packaging according to regulations on the disposal of packagings.
Packaging can be reused or recycled after cleaning.
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Paper bags may be incinerated or disposed of in an appropriate landfill in accordance with national and
local laws.
Recommended cleansing agent: Water, if necessary with cleansing agents.
Special precautions :
Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff
and contact with soil, waterways, drains and sewers.
14 Transport information
UN-Number
DOT, ADR, ADN, IMDG, IATA Void
UN proper shipping name
DOT, ADN, IMDG, IATA Void
ADR Void
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class Void
Packing group
DOT, ADR, IMDG, IATA Void
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information: Not dangerous according to the above specifications.
Keep dry.
Keep separated from foodstuffs.
UN "Model Regulation": Void
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
Substance is not listed.
CERCLA Hazardous Substances
Substance is not listed.
Hazard Communication Standard (HCS)
Substance is not listed.
SARA 302 Components : Substance is not listed.
Section 313 (Specific toxic chemical listings):
Substance is not listed.
Sara (311, 312) hazard Class : No SARA Hazards.
TSCA (Toxic Substances Control Act):
Substance is listed.
Volatile Organic Compounds (VOC) : None.
Ozone Depleting Substances (ODS) :
This product neither contains nor was manufactured with a Class I or Class II ozone depleting substance
as defined by 40 CFR 82, Subpart A, Appendices A and B.
Clean Air Act – Hazardous Air Pollutants (HAP)
Substance is not listed.
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Clean Water Act – Priority Pollutants (PP)
This product is not listed as a Priority Pollutant under the CWA.
Resource Conservation and Recovery Act (RCRA):
This product is not a hazardous waste as defined by 40 CFR 261.33
Proposition 65
Chemicals known to cause cancer:
Substance is not listed.
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
Chemicals known to cause developmental toxicity:
Substance is not listed.
Massachusetts Right To Know :
CAS: 51274-00-1 Iron hydroxide oxide yellow
California Right To Know : Substance is not listed.
Minnesota Right To Know :
Substance is not listed.
New Jersey Right-to-Know List:
CAS: 51274-00-1 Iron hydroxide oxide yellow
New Jersey Special Hazardous Substance List:
Substance is not listed.
Pennsylvania Right-to-Know List:
CAS: 51274-00-1 Iron hydroxide oxide yellow
Pennsylvania Special Hazardous Substance List:
Substance is not listed.
Rhode Island Right to know :
Substance is not listed.
Florida Right To Know : Substance is not listed.
Michigan Critical Materials Register : Substance is not listed.
Cancerogenity categories
EPA (Environmental Protection Agency)
Substance is not listed.
IARC (International Agency for Research on Cancer) Substance is not listed.
TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
Hazard pictograms Void
Signal word Void
Hazard statements Void
National regulations:
Chemical Weapons Convention List Schedule I : Not listed.
Chemical Weapons Convention List Schedule II : Not listed.
Chemical Weapons Convention List Schedule III : Not listed.
U.S. Department of Homeland Security This product does not contain chemicals regulated under DHS.
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16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Department issuing SDS: Product safety department.
Contact: Mr. Kwok
Date of preparation / last revision 09/06/2017 / 9
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
NOAEL : Non Observed Adverse Effects Level
LOAEL : Lowest observed adverse effect level
EC50 : Maximal effective concentration, 50 percent
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
LC0 : Lethal concentration, 0 percent
NOAEC : No Observed Adverse Effect Concentration
NOEC : No Observed Effect Concentration
EC0 : Maximal effective concentration, 0 percent
* Data compared to the previous version altered.

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