Metal Foam Manufacturing and Processing Review
Metal Foam Manufacturing and Processing Review
Abstract Metal foam recently has grabbed a significant amount of interest due
to its promising prospects in fulfilling the crisis led by steel and its counterparts.
The recent studies indicated commercialization of metal foam which is disrupted
mainly because of high cost and lack of design knowledge. Industries had expressed
the need of more detailed studies, in order to the amicability of the material to
machining, joining and other manufacturing processes. Thus, this article, in brief,
clubs all the major processing routes of metal foams along with their limitations. It
also discusses how secondary processing methods can contribute in tailoring metal
foam for different applications. The article shall help future researchers to bridge the
existing gaps which restricts metal foam utility in concerned industries.
1 Introduction
Metal foams are cellular materials, wherein voids are introduced in a solid base
metal, to acquire desired properties. With time, the material emerged as a potential
solution for various applications due to its low density coupled with extraordinary
mechanical, structural and physical properties [1]. They are porous cellular structure
containing air voids within the solid base metal. The material displays high strength-
to-weight ratio and potential to absorb shock and noise. The structural reaction of
these materials remains same under compressive loads, because the material exhibits
plateau stress under such loads. Its potential of acoustic absorption makes it ideal
for soundproof construction. The material is also ideal for heat exchangers owing to
its substantial surface area and higher cell wall conduction. To have such a unique
combination of features within a single conventional material seems non-viable [2, 3].
With time, the material has emerged as a potential solution for various structural and
© The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2023 127
U. S. Dixit et al. (eds.), Advances in Forming, Machining and Automation, Lecture Notes
in Mechanical Engineering, [Link]
128 A. Changdar and S. S. Chakraborty
functional applications. Aluminium-based metal foams out of the rest were exploited
the most, and its utilization is expected to rise in near future [4, 5].
The material is classified based on its cellular topology as shown in Fig. 1, and
most of its significant properties depend on the same. Foams in which cells are
interconnected are known as open cell, whereas when the cells are separated by
distinct cell wall, it is known as closed cell [3]. The understanding of the classification
is significant as it determines the kind of application, a metal foam is suited for.
ASTM standard D2662 quantifies the porosity percentage of closed cell and open
cell foams. Closed cell metal foams owing to its lightweight and high stiffness are
ideal for structural applications. However, open cell foams due its reticulated structure
and larger surface area are mostly applicable in functional areas, like filters and heat
exchangers.
Metallic foams exhibit a certain number of unique properties, difficult to obtain
using other materials. The structural properties of these materials are of great signifi-
cance, and its uniqueness lies in the stress–strain response mainly under compression.
These materials do not display catastrophic failure, when under deformation. Instead,
the material exhibits plateau stress under compressive deformation, because of cell
collapse and densification. The reason behind such deformation behaviour is owing
to the fact that elastic modulus due to cell collapse obtained during initial loading is
less than the actual elastic modulus (E). Apart from this, the deformation character-
istics of these materials also depend on the relative density and the ductility of the
base metal.
Instead of such wide bandwidth of prospective applications, several factors exist,
which can challenge the usability and market growth of aluminium metal foams and
its sandwich panels (Banhart et al. 2017). A recent survey suggested, the two major
reason which restricts the widespread application of these materials are high cost
and a lack of design knowledge. The survey also suggested for increase in literature
investigating the amicability of the material to machining and joining process [6,
7]. Growth of aviation and automotive industries has been very prominent due to
rapid urbanization and globalization of late. These industries mostly rely on metals
and alloys for manufacturing components. The recent tendency of these industries
to reduce material weight from their value chains has led to the advent of many
State-of-the-Art Manufacturing of Metal Foams and Processing … 129
(a) (b)
85%
78%
2010 2030
Year
Fig. 2 a Multiple applications of metallic foam, b survey result on lightweight material usage of
aviation and automotive industries
lightweight materials. The current design intent of most industries is biased towards
the use of lightweight materials with a wide span of properties. Metal foam, thus
stands out to be an ideal material of choice for such industries due its multifunctional
capabilities as shown Fig. 2a. Market reports suggest usage of lightweight material
share for aviation industries may increase by 10%. However, in automotive industries:
a rise up to 70% in 2030 is expected as shown in Fig. 2b. Thus, it is very important to
reduce the existing knowledge gap between these materials and industries, in order
to scale up its industrial adoption and usability.
Currently, existing processing methods lack the potential to generate parts tailored
to industrial requirement. Thus, a more economical way is to process metal foam
in bulk in generic shapes like slabs and plates, using available processing methods.
Subsequently, the material in their generic form is shaped as desired by introducing a
secondary manufacturing process route like forming, welding or cutting. But under-
going conventional manufacturing processes stand out to be challenging for these
materials due to their fragility under tensile stresses, and several alternative secondary
manufacturing processes like laser or thermal forming of these materials are gaining
popularity. Therefore, it can be well-anticipated that a proper process route defini-
tion in order to generate practical parts and components out of these materials is
of great significance. Currently, several literatures exist enveloping process mecha-
nisms and applications of the material. But a single article confronting all the process
routes along with its limitations and describing the possible secondary manufacturing
process routes hardly exists.
Henceforth, this article clubs the major processing routes of metal foams along
with their limitations. As the properties of metal foam mostly depends on its struc-
ture, a reliable fabrication process for continuous production is of prior importance.
Unavailability of such a process is the major drawback of the material and thus
imposes limitations to its full-fledged industrial adoption [1, 3]. The article also
discusses the further processing methods of metal foams, which includes forming,
welding and cutting. These processes are quite significant when it comes to tailoring
130 A. Changdar and S. S. Chakraborty
of foam/foam sandwich as per desired application. When a foam core is covered with
the sheet of the similar material at top and bottom, it makes a foam sandwich.
Though metal foam’s widespread application was realized very recently, the history
of metal foam dates back to twentieth century. Since then, the methodologies and
materials used for processing of foam underwent many adaptations, as proclaimed
in the existing literature. With advancement of technologies and to obtain tailored to
application properties, fabrication of metal foams has evolved to next level. Irrespec-
tive of ongoing advances, extensive adoption of metal foam is impeded due to inade-
quacy of production methodologies to process variety of materials in highly effective
and economical method [8–10]. The current advancements in processing approaches
are quite convincing and certainly show a promise to conquer the existing hindrances
in the way of widespread acceptance of metal foam. An exhaustive representation of
processing methodologies on porous material is shown in Fig. 3.
Metal
● Chemical vapour
vapour
deposition
Liquid-state foaming being a traditional method has been studied a lot and detailed
understanding of the process can be found in adequate literature. The liquid-state
foaming is usually classified as, direct and indirect foaming [10–12] (Tianjian 2002).
metallic foams using this method known as DUOCEL. Advantages of this process
include fabrication of complex shaped foam structures by preforming the polymer
foam. The sense of controlled manufacturing is predominant in this method as the
pore morphology and density of the metallic foam is determined by polymer foam
precursor. Other than aluminium, this process is also capable of producing foams of
copper and magnesium which certainly make this process more reliable compared to
direct foaming process. Indirect foaming can also be established, by casting molten
metal around hollow spheres of low density, and the same can also be done using
organic and inorganic granules. The vice versa of the aforementioned method is also
possible, wherein the granules are either washed away using proper treatment after
casting or are allowed to remain within the cast as to form syntactic foam. This
process is also capable of processing diversified materials like aluminium, magne-
sium, zinc, lead and tin. Mould as desired can be designed as to obtain functional
shaped metal foam and porosity up to 98%. Osprey process is another method of
liquid-state processing also known as spray forming. This process allows processing
of different distinct metals and alloys. Metallic melt is atomized, and a spray of fast
flying little metal droplets is made. The resulting droplets are collected to create a
dense deposit on a substrate. The process results in formation of dense deposit in
generic shapes like billet and sheet. The materials usually exhibit low oxide content
with better grain size [11, 13]. Some of the examples of metal foams produced by
various liquid-state processes are illustrated in Fig. 4.
Fraunhofer processing method developed at Fraunhofer Institute, Germany,
follows powder metallurgical route for development of metal foam. The processing
technique involves heating of foaming agent and metal powder mixture at a temper-
ature exceeding melting temperature of the base metal, hence, it can be categorized
under liquid-state foaming. The manufacturing process starts with the mixing of
metal dyes: basic metallic powder or metallic powder mixes using a blowing agent,
and the mixture is compacted to produce a compact, semi-finished item. In principle,
the compaction could be carried out by any method that makes sure that the blowing
agent is inserted into the metallic matrix with no previously occurring porosities.
Selection of the compaction technique (hot uniaxial or isostatic compression, pole
extrusion or powder rolling) is dependent upon the necessary form of the precursor
substance. The production of this precursor needs to be performed very carefully
since any remaining porosity or other flaws will cause bad results in additional
processing. The precursor is further heated to temperatures comparable to melting
point of the base metal as a result blowing agent start decomposing. The released
gas as a result starts expanding the precursor material which consequently results in
formation of metallic foam. The foaming agent depends on the sintering and melting
temperature of matrix material. For example, TiH2 and ZrH2 are used to foam Al
and Zn, respectively, MgCO3 and SrCO3 can be used for foaming steels, BaCO3 for
copper, and PbCO3 ·Pb (OH)2 and MgH2 for Pb. The decomposition speed, heating
rate and also the firmness of cell wall construction ascertain the final density of the
foam generated. This method occasionally also includes heating of the compacted
metal powder mixture with additives as to activate exothermic reaction to melt the
mix. Overall, the process is very flexible and versatile and can foam a wide range of
State-of-the-Art Manufacturing of Metal Foams and Processing … 133
materials in near net shape. Proper selection of blowing agent and process parame-
ters allows foaming several metals like aluminium, aluminium base alloys, tin, zinc
and brass. On more judicious selection of parameters materials like, lead and gold
can also be foamed. Aluminium foams processed using the method are termed as
“Foaminal” and “Alulight”. More detailed understanding of liquid-state processing
is described in several literatures with its current applications and state-of-the-art
innovations [8, 9] (Banhart 2013).
Liquid-state forming with progression of time has evolved a lot and even
gained capabilities of processing near net shape products. Aluminium foams are
the most commercialized product of these processes. However, processing foams
of other materials using these processes hardly crossed the prototype stage. Even
processing aluminium foams with virtue of these processes faces many challenges,
and aluminium melt being less viscous needs to be stabilized using various additives
as to ensure porosity. Additives like BaO3 , SiO2 , SiC, Ca and Al2 O3 along with some
other materials are added in the melt to manipulate the surface tension and decrease
the viscosity to obtain desired morphology of the foam. Though powder metallurgical
replication process by Fraunhofer exhibits a prominent promise but high production
cost and limited commercialization has certainly been the barrier to its extensive
growth. Owing to fact that metal foam still lacks widespread commercialization,
development of more reliable processing techniques is still a research issue of many
134 A. Changdar and S. S. Chakraborty
like tungsten, copper, nickel, titanium and iron. Porosity up to 75% can be achieved
and foam morphologies can be controlled by selection of proper process parameters.
Another method is to sinter hollow metal spheres together to form porous structures.
The metallic spheres are either obtained by electro-deposition or chemical deposi-
tion of an individual metal onto polymer spheres that are eliminated in a next step,
or from coating polymer spheres (e.g., of polystyrene) using a binder/metal powder
and then sintering the alloy to acquire a dense metallic shell while the polystyrene is
eliminated. There are many other processes to obtain the hollow metallic spheres and
can be found in the existing literature. The obtained hollow spheres are subsequently
joined together by sintering into desired open cell or closed cell configuration. Tita-
nium, nickel and Inconel foams have been processed using this method. More recent
template-based methods include deposition of metal films around bubbles such as
dynamic hydrogen bubble template (DHBT). The process is gaining increased atten-
tion for processing of battery electrodes and catalysis owing to higher surface area of
processed foams. The field is very new and a few available literature [13, 15] should
be referred for in-depth understanding of the process. Figure 5 illustrates few of the
foams developed by solid-state foaming methods.
Intrinsic porosity methods include gas entrapment technique, wherein, adequate
metal powders are compressed in a dense precursor material while a gas is entrapped
within it. The precursor material is then heated which leads to expansion of the metal
due to the internal pressure created by the entrapped gas which leads to formation of
pores. The process is popularly known as Kearns process after the name of Michael
Kearns who was the inventor and was first to apply the same at Boeing the US-
based aerospace company. Boeing implemented it by filling titanium powder into a
Fig. 6 Diagrammatic representation of pros and cons of various metal foam processing methods
metal can that was outgassed after evacuation. The can was again introduced with
pressurized inert gas (Argon) at about 3–5 ATM and then sealed. The structure was
densified by applying hot isostatic pressing at a temperature of 950 °C and 1000 ATM
for 4 h. The argon gas was entrapped during the compaction and forms uniformly
dispersed pores when the compacted material is finally annealed at a temperature of
1240 °C for 65 h. The process is even capable of processing near net shape products
and has been widely used for processing commercially pure titanium and its alloys.
The other method of intrinsic porosity formation is very new and still have a long
way to go. In this process, pores are created in the powder materials unlike other
methods, where pores are created in between the powder particles. It is achieved by
mixing of metal powders thoroughly with oxides and then subsequent reduction of
those oxides leads to formation of steam which starts expanding. The process is very
new but many processing routes are being suggested for commercialization of this
process and can be found in dedicated literature [12, 13, 15]. Figure 6 schematically
illustrates the pros and cons of various foaming methods in processing metal foams.
Additive manufacturing technique offers a unique podium for generating, near net
shape porous structures, for biomedical and aerospace applications. According to
the ASTM standard F2792, it is defined as “the process of joining materials to make
objects from 3D model data, usually layer upon layer, as opposed to subtractive
138 A. Changdar and S. S. Chakraborty
Fig. 7 Schematic
representation of a powder
bed fusion process.
Reprinted with permission
from Changdar and
Chakraborty [1]
Powder metallurgical route and additive manufacturing as discussed above are the
two processes capable enough, to manufacture metal foam components in near net
shape, while both the process offers flexibility in terms of foam structure and choice of
the base metal, but are limited to small parts and tiny production volumes. Moreover,
both the process involves high production cost, and are mostly limited to laboratory
trials till date. A more practical approach of manufacturing metal foam is further
processing of metal foams produced initially in the form of sheets and slabs. The
foams can be further processed into the desired aesthetics either by cutting, joining
State-of-the-Art Manufacturing of Metal Foams and Processing … 139
Capability of a material to form into desired shapes is very crucial to establish its
firm foothold in industries. It has been reported that metal foams can resist frac-
ture at severe deformation, which indicates their capabilities of getting formed into
desired shape. Several studies successfully attempted forming of wide range of metal
foams which include, aluminium foam (Alporas), porous nickel and lotus-type porous
copper, plates. Cold extrusion was also applied to process porous metal by applying
solid phase bonding of dissimilar metal wires. Though the possibility of mechan-
ical forming exists but its yet not versatile. Studies revealed that corrugation of cell
walls during mechanical forming leads to the formation of curvature at extrados.
The curvature instigates development of very high tensile stresses, which eventually
exceeds the tensile strength of metal foam [22]. Inability of metal foams to withstand
such tensile stresses leads to its failure [1, 23, 24]. Limitations of mechanical forming
of metal foam instigated utilization of laser forming, for bending metal foams. The
process, utilizes non-uniform heating by laser to form a material by inducing non
uniform strain within it. It eliminates the threat of mechanical stresses due to hard
tooling instead relies on thermal stresses to produce the requisite deformation [1].
The recent studies are also affirmative and suggest that the process is capable of
developing large bending deformations in the foam, without any detrimental effect
on its structural robustness [3].
the same [26]. Advanced joining methods like friction stir welding (FSW) and laser
welding were found to produce better results in joining metal foams as compared
to conventional methodologies. FSW was found to join metal sheets and foam at a
single pass if the thickness of the foam was maintained within desired limits. On
the other hand, laser welding due to its capabilities of confining heat input within a
narrow region, stand out to be the most versatile process for welding metal foams.
Laser welding process was found to offer the feasible solution to welding of metal
foams on cautiously selecting the process parameters [1].
4 Conclusions
The article enlisted the currently existing processing routes available for metal foams
along with their prospects and limitations. The major insights exhibited by the article
are as follows:
● Processes like additive manufacturing and powder metallurgical methods are
capable of producing near net shape parts of metal foam, but their large-scale
production prospects are limited due to low volume productivity and high cost.
Products out of these processes are ideal for biomedical applications, dental
implants or other sophisticated applications requiring less volume of part supply
and high quality and precision.
● Solid-state processing of metal foam is gaining popularity as they are capable of
developing controlled morphology metal foam and at standard volumes. Chemical
vapour deposition (CVD) has already been applied for generating nickel foams
at large volumes and are being applied by aerospace and automobile industries.
● Liquid-state processing is the most commercialized process, with least control
over the morphology of the pores. The process is capable of producing metal foams
at large volumes in generic shapes very cheaply. Currently, this processing method
is the only sustainable method for large volume production. In order make the
State-of-the-Art Manufacturing of Metal Foams and Processing … 141
Acknowledgements Financial support from the Science and Engineering Research Board (SERB)
under project grant (no. ECR/2017/002505) is gratefully acknowledged.
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