Science, Technology, Engineering and Mathematic Schools

Second Term Exam

2016 – 2017

Subject : Chemistry Grade : 11

Time: 120 minutes

Instructions
 Use Blue ink, ballpoint pen or pencil.
 Answer all questions.
 Answer the questions in the spaces provided – there may be more space
than you need.
 You need to ensure that you fill in the entire box like the example:

Information
 You can use the BLANK PAGE at the end of the questions as draft papers.
 Candidates may use a scientific calculator.

Advice
 Read each question carefully before you start to answer it.
 Keep an eye on the time. Try to answer every question.
 If you do not know the answer to a question, go on to the next question.
You may come back to the skipped question later if you have time.
 Check your answers if you have time at the end.
 1 LO : 8

What is the oxidation number of phosphorous in the compound Ca3(PO4)2 ?

A- +3
B- +2
C- +5
D- -5

2 LO : 8

What is the oxidation number of carbon in ( C2O4 )2-

A- +4
B- +3
C- -3
D- -2

3 LO : 8

( P2O7 ) is a poly atomic ion, What is the oxidation number of this ion?
[ if you know that the oxidation number of phosphorous in the ion is +5 ]
A- -4
B- +4
C- +5
D- +3

4 LO : 8
In the following reaction :
The circuited chlorine atoms are ………
A- Oxidized
B- Reduced
C- not change
D- Oxidizing agent

5 LO : 8
In the following unbalanced chemical equation :
Fe(OH)2 + O2 + H2O  Fe(OH)3
If 1 mole of O2 oxidizes Fe(OH)2, how many moles of Fe(OH)3 can be formed?
A- 2
B- 3
C- 4
D- 6

Chemistry _ G : 11 Page 2 of 17
 6 LO : 8

Questions 6-8 :
In this electrolytic cell :
The following substances were used as
electrolytes ( labelled Z in the diagram )
[ Molten wax – mercury – molten sodium
chloride – distilled water – aqueous solution
of hydrochloric acid ]
In how many of these tests would the bulb light?
A- 2
B- 5
C- 3
D- 4

7 LO : 8

In the previous cell :

If copper II sulphate solution used as ( Z ) , which of the following
observation would be expected ?
A- The weight of the anode increases
B- The weight of the cathode increases
C- Bubbles of gas produced at cathode
D- The temperature of the solution rises

8 LO : 8

Back to question 6 :
Which one of the following would cause the bulb to glow brighter ?
A- Move ( X) and (Y) closer together
B- Push ( X ) and ( Y ) dipper in the solution
C- Increase the current flowing
D- Increase the surface area of both ( X ) and ( Y )

9 LO : 8

Which of the following reactions represents a non-redox reaction

A- 2FeSO4  Fe2O3 + SO2 + SO3
B- Na2CO3 + 2HCl  2NaCl + H2O + CO2
C- ZnSO4 + Mg  MgSO4 + Zn
D- NH4NO3  N2 + H2O

Chemistry _ G : 11 Page 3 of 17
 10 LO : 8

In the electrolysis of lead II bromide , Which equation represents the

reaction occurs at the anode
A- Pb  Pb2+ + 2e-
B- Br- + e-  Br
C- Pb2+ + 2e-  Pb
D- 2Br-  Br2 +2e-

11 LO : 8

The main difference between the primary and secondary cell is that
A- primary cell can be recharged and a secondary cell cannot
B- secondary cell can be recharged and a primary cell cannot
C- primary cell has an unlimited shelf life and a secondary cell doesn’t
D- primary cell produces DC voltage, while secondary cell produces AC voltage

12 LO : 8

Questions 12 -14 :

Which of the following statements are true about the spontaneously running
electrochemical cell shown?
Use the following information and assume standard conditions:
Ag+(aq) + e- → Ag(s) E°red = + 0.80 V
Ni2+(aq) + 2e- → Ni(s) E°red = – 0.28 V
I. Nickel is the cathode.
II. Silver is the anode.
III. Electrons flow from nickel to silver.
A- I only
B- II only
C- III only
D- All are true

Chemistry _ G : 11 Page 4 of 17
 13 LO : 9

In question 12 :
What is the standard cell potential of the electrochemical cell shown?
A- + 0.52 V
B- – 0.52 V
C- – 1.08 V
D- + 1.08 V

14 LO : 9

In question 12 :
What is the diagram which can represent this galvanic cell ?
A- Ni / Ni2+ // Ag2+/Ag
B- Ni / Ni2+ // 2Ag+/2Ag
C- Ag /Ag 2+// Ni 2+/ Ni
D- 2Ag / 2Ag+ // Ni2+ / Ni

15 LO : 9
The following reactions are spontaneous as written.
Fe(s) + Cd2+ (aq) → Fe2+(aq) + Cd(s)
Cd(s) + Sn2+(aq) → Cd2+(aq) + Sn(s)
Sn(s) + Pb2+(aq) → Sn2+(aq) + Pb(s)
Which of the following pairs will react spontaneously?
I. Sn(s) + Fe2+(aq)
II. Cd(s) + Pb2+(aq)
III. Fe(s) + Pb2+(aq)
A- I only
B- II only
C- II and III
D- III only

16 LO : 8
If a copper sample containing some zinc impurities needed to be purified
by electrolysis, the anode and the cathode must be which of the
following?
Anode Cathode
A- Pure copper Pure zinc
B- Pure zinc Pure copper
C- Impure copper sample Pure copper
D- Pure copper Impure copper sample

Chemistry _ G : 11 Page 5 of 17
 17 LO : 9
If 0.06 faraday are passed through an electrolytic cell containing a
solution of In3+ ions, What is the maximum number of moles of indium
metal that could be deposited at the cathode ?
A- 0.18 mole
B- 0.02 mole
C- 0.03 mole
D- 0.06 mole

18 LO : 9
What occurs during the operation of a voltaic cell (Galvanic) based on
the following reaction?
Ni(s) + Pb2+(aq) → Ni2+(aq) + Pb(s)
External circuit Ion movement in solution
A- electrons move from Ni to Pb Pb2+(aq) move away from Pb(s)
B- electrons move from Ni to Pb Pb2+(aq) move toward Pb(s)
C- electrons move from Pb to Ni Ni2+(aq) move away from Ni(s)
D- electrons move from Pb to Ni Ni2+(aq) move toward Ni(s)

19 LO : 9
The cathode is the pole which is :
Charge Process occurs
A- Positive pole in galvanic cell Where reduction occurs
B- Negative pole in the galvanic cell Where reduction occurs
C- Negative pole in the electrolytic cell Where oxidation occurs
D- Positive pole in electrolytic cell Where reduction occurs

20 LO : 9
Question 20, 21 :
In an experiment to plate a Jug by a layer of silver
How many minutes are necessary to deposit 21.9 g
of silver from silver nitrate by passing an electric
current 10 ampere ( Ag = 108)

A- 19.5 min
B- 32.6 min
C- 1.9 min
D- 3 min

Chemistry _ G : 11 Page 6 of 17
 21 LO : 9

In the previous question:

After half an hour , it was found that 3.24g of silver metal deposit on
the jug what is the current intensity that passes through the circuit
A- 2.3 ampere
B- 3 ampere
C- 10 ampere
D- 1.6 ampere

22 LO : 10

Formaldehyde , acetic acid , lactic acid , and glucose all of them are
molecules have the same empirical formula ( CH2O ) , with different
molecular masses which are 30 , 60 , 90 , 180 respectively , the number of
empirical units in order will be : ( C=12 , H = 1 , O = 16 )

A- 1,2,3,6
B- 3,6,9,18
C- 1,3,6,9
D- 2,3,4,5

23 LO : 10

How many moles of water produced from burning of one mole of methyl
cyclo-hexane?

A- one mole of water

B- three moles of water
C- six moles of water
D- seven moles of water

24 LO : 10

The number of organic compounds produced by the thermal

decomposition of butane is:
A- 4
B- 5
C- 6
D- 7

Chemistry _ G : 11 Page 7 of 17
 25 LO : 10

How many structural isomers does C4H10 have?

A- two
B- five
C- three
D- four

26 LO :10

What is the kind of organic compounds that general formula refers to ?

R – COO-R*
A- Esters
B- Ethers
C- Acids
D- Ketones

27 LO : 10

To which group of organic reactions does hydrogenation belong ?

A- elimination
B- substitution
C- addition
D- condensation

28 LO : 10

What is the IUPAC name for the following compound?

A- 1,3-pentamethylpropane
B- 2,2,4-trimethylpentane
C- 2,4,4-trimethylpentane
D- 1,1,3,3-tetramethylbutane

Chemistry _ G : 11 Page 8 of 17
 29 LO : 10

What is the better IUPC name for the following compound ?

A- 1,2,di methyl butene

B- 1,1,2,2 tetra methyl ethene
C- 2,3 di methyl 2 ethene
D- 2,3 di methyl 2 butene

30 LO : 10

Which of the following is not identical to the others?

A- A
B- C
C- D
D- B

31 LO : 10

The IUPAC name for the following compound is :

A- 1-methyl hexyl cyclo-pentane

B- 1-cyclopentyl- 2-methyl heptane.
C- 2-cyclo- pentyl heptane
D- 1-pentyl ethyl cyclopentane.

32 LO : 10

When two identical atoms are on the same side, the molecule is
A- structural
B- rigid
C- cis
D- trans

Chemistry _ G : 11 Page 9 of 17
 33 LO : 10

A student gave a molecule the following name :

[2-methyl- 4-tert- butyl pentane]
What is the correct (IUPAC) name of the molecule ?
A- 1-sec- butyl-1,2,2- trimethylpentane .
B- 2,4,5,5-tetramethyl hexane
C- 2,2,3,5-tetramethyl hexane
D- 2-tert- bytyl-4- methyl pentane

34 LO : 10

Question 34, 35 :
What is the type of hybridization in the numbering carbon atom 1,2& 3
respectively?

A- SP , SP2 , SP3
B- SP3 . SP2 , SP
C- SP2 , SP3 , SP
D- SP , SP3 , SP2

35 LO : 10

In question 34 :
In the previous compound how many  bonds and  bonds in the compound ?

A- 6,4
B- 15  , 4 
C- 11  , 4 
D- 8,4

36 LO : 10

What is the suitable classification for this alcoholic compound ?

A- Monohydric primary alcohol

B- Monohydric secondary alcohol
C- Trihydric tertiary alcohol
D- Monohydric tertiary alcohol

Chemistry _ G : 11 Page 10 of 17
 37 LO : 10

Hexane and 2-methylpentane two compounds can be described as …….

A- Geometric isomers
B- Structural isomers
C- Optical isomers
D- Same compound

38 LO : 11

Which of the following compounds forms, by hydrolysis, a secondary alcohol?

A- n–butyl chloride
B- sec–butyl chloride
C- neo-pentyl chloride
D- tert-butyl chloride

39 LO : 11

What is the process of converting long chain hydrocarbon which is less

used into shorter chain hydrocarbon more used by rising the
temperature and pressure in existence of catalyst ?
A- Polymerization
B- Cracking
C- Condensation
D- Addition

40 LO : 10

Which of following compounds is chiral (has optical isomers) ?

A- 2,4-dimethylpentane
B- 4-methlheptane
C- 2-mehtylhexane
D- None of these is chiral

41 LO : 10
What is the expected product from adding HBr to propene ?
A- 1 bromo-propane
B- 2 bromopropane
C- 1,2 di bromo propane
D- A miture of 1bromo and 2 bromo propane

Chemistry _ G : 11 Page 11 of 17
 42 LO : 10

The boiling point of any alcohol is much higher than that of

corresponding alkane . This is primarily due to ……..
A- The difference in molar masses between them
B- The hydrogen bonding in alcohol
C- The significant molecular size difference between alcohol and alkane.
D- The carbon oxygen double bond in alcohol molecule

43 LO : 10

Which molecule is a ketone ?

A- CH3CH2OCH 3
B- CH3CH2COCH3
C- CH3CH2COOCH3
D- CH3CH2OH

44 LO : 11

How are the hydrocarbons produced at the top of the fractional

distillation column , different from those produced form lower down ?
A- They have shorter chains and lower boiling point .
B- They have shorter chains and higher boiling point
C- They have longer chains and lower boiling point
D- They have longer chains and higher boiling point

45 LO : 10

Carbon atom a unique atom , its unique properties causes the formation
of enormous number of compounds forming organic chemistry ,
What makes carbon element is a unique element ?
A- Elemental carbon comes in two forms, diamond and graphite
B- Carbon forms covalent bonds rather than ionic bonds
Carbon can bond to itself to form straight chains, branched chains and
C- rings.

Carbon forms four bonds, although the ground state configuration

D-
would

Chemistry _ G : 11 Page 12 of 17
 46 LO : 11

Which of the following compounds reacts with an aqueous solution of

sodium hydroxide?
A- benzene
B- propanol
C- phenol
D- acetylene

47 LO : 11

Paraffin is a solid at room temperature because it is composed of alkanes with :

A- high molecular masses
B- low molecular masses
C- strong London dispersion forces
D- Both (a) and (c)

48 LO : 10
In this group of chemical reactions ,state whether each of the following
reactions is a substitution, an addition, an elimination, or a
rearrangement reaction ?

a)

b)

c)

d)

I II III IV
a rearrangement rearrangement addition rearrangement
b addition addition rearrangement Elimination
C Elimination Substitution Substitution rearrangement
d Substitution Elimination Elimination addition
A- I
B- IV
C- II
D- III

Chemistry _ G : 11 Page 13 of 17
 49 LO : 11

In which of the following reactions a C-C bond is broken?

A- C6H5–CH3 + 3H2  C6H11–CH3
B- C6H5–NO2 + 3H2  C6H5–NH2 + 2H2O
C- C6H5–CH3 + H2  C6H6 + CH4
D- 6CH3–CHO + H2  CH3–CH2–OH

50 LO : 10
The correct IUPAC name of the following compound is :

A- 2-ethyl- 3,5-dimethylheptane
B- 3,4,4-trimethyloctane
C- 6-ethyl- 5,5-dimethylheptane
D- 5,5,6-trimethyloctane

Chemistry _ G : 11 Page 14 of 17
 List of data, formulae and relationships

"[Click here to type List of data, formulae and relationships]"

Chemistry _ G : 11 Page 15 of 17
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Chemistry _ G : 11 Page 17 of 17