CHEMISTRY

15.02.2024
1. The molal freezing point constant for water is 1.86K. molality . If 34.2 g of cane sugar
are dissolved in 100g of water, the solution will freeze at.
1) -0.186 C 2)1.86 C 3)-3.92 C 4)2.42 C
2. The relationship between osmotic pressure at 273 K when 10gm glucose ( ), 10gm urea ( ) and
10g sucrose ( ) are dissolved in 250 ml of water is
1) > > 2) > > 3) > > 4) > >
3. Blood cells retain their normal shape in solution which are
1) isotonic to blood 2) hypotonic to blood
3) hypertonic to blood 4) equinormal to blood
4. Which statement is incorrect about osmotic pressure ( ), volume (V) & temperature (T)?

1) if T is constant 2) T, if V is constant
3) V, if T is constant 4) V is constant, if T is constant
5. The Osmotic pressure of a dilute solution is given by

1) 2) V=nRT 3) 4) =
6. What is the volume of a solution containing 2g mole of sugar that will give rise to an osmotic
pressure 1 atm. At STP
1) 4.48 lit 2) 0.448 lit 3) 44.8 lit 4) 448 lit
7. In a solvent 50% of benzoic acid dimerises while rest ionises, determine molar mass of acid which
Is observed and also its van't Hoff factor.
1) 1.5 2) 1.25 3) 1 4) 2
8. 0.5 M aqueous solution of glucose is isotonic with
1) 0.5 M KCl solution 2) 0.5 M solution
3) 0.5 M urea solution 4) 1 M solution of sucrose
9. Van't Hoff factor (i) for an aqueous solution of an electrolyte is
1) Zero 2) Greater than 1 3) Equal to one 4) ≤ 0
10. Which salt shows maximum osmotic pressure in its 1M solution.
1) 2) 3) 4) MgCl₂
11. Lowering of vapour pressures of equimolar solution of glucose, sodium chloride and barium nitrate
are in the order.
1) 2) Glucose =NaCl = Ba
3) Ba > NaCl > Glucose 4) NaCl > Ba > Glucose
12. 156.75.2g of C6H5OH (phenol) is dissolved in 960g of a solvent of = 14K If the
depression in freezing point is 7K, then find the percentage of phenol that dimerizes.
1) 50 2) 80 3) 30 4) 40
13. Two solutions marked as A and B are separated through semipermeable membrane as below.
The phenomenon undergoing
 1) Nat moves from solution A to solution (B)
2) Both and moves from solution (A) to solution (B)
3) Both and moves from solution (B) to (A)
4) Solvent molecules move from solution (A) to (B)
14. A solution contains non volatile solute of molecular mass M₂. Which of the following can be used
to calculate the molecular mass of solute in terms of osmotic pressure? (m₂ - mass of solute, V –
volume of solution, π - osmotic pressure)

1) 2)

3) 4)
15. Which of the following plots does not represent the behaviour of an ideal binary liquid solution
1) Plot of versus (Mole fraction of A in A liquid phase) is linear
2) Plot of versus is linear
3) Plot versus (or ) is linear
4) Plot versus is non linear
16. In the reaction the Equivalent weight of the acid is
1) 49 2) 98 3) 32.6 4) 36.5
17. 100 ml of ethyl alcohol [d = 0.92 g/ml] and 900 ml of water [d = 1 g/ml] are mixed to form 1
Lit solution. The Molarity and molality of the resulting solution are
1) 2M and 2m 2) 2M and 2.22m 3) 2.2M and 1.1 m 4) 2M and 1m
18. S-I: Reverse osmosis is used to purify sea water.
S-II: Solvent molecules membrane if high pressure (>π) is applied on solution side.
19. (A): Isotonic solutions must have same elevation in boiling point.
(R): Osmotic pressure, π = iCRT
Column I Column II
(A) Raoult's law (P)
(B) Henry's law (Q) π = CRT
(C) Elevatoin of boiling point (R)
(D) Depression in freezing point (S)
(E) Osmotic pressure (T)
1) A - (r), B - (t), C - (s), D - (p), E - (q) 2) A - (t), B - (r), C - (q), D - (s), E - (p)
3) A- (p), B - (t), C - (r), D - (q), E - (s) 4) A- (s), B - (p), C - (q), D - (r), E - (t)
20. 6.02 × 1020 molecules of urea are present in 100 mL of its solution. The concentration of solution is:
1) 0.01M 2) 0.001 M 3) 0.1 M 4) 0.02 M
21. Which of the following is dependent on temperature?
1) molarity 2) mole fraction
3) weight percentage 4) molality
22. For an ideal solution, the correct option is
1) S = 0 at constant T and P 2) V≠0 at constant T and P
3) Η = 0 at constant T and P mix 4) G = 0 at constant T and P mix
23. Which of the following aqueous solutions will conduct an electric current quite well?
1) Sugar 2) Glycerol 3) Pure water 4) HCl
24. Oxidation state of phosphorus is + 3 in
1) Orthophosphorus acid 2) Orthophosphoric acid
3) Pyrophosphoric acid 4) Metaphosphoric acid
25. The reducing strength of oxyacid of the Phosphorus depends on
1) The number of H-atoms directly attached to P
 2) The number of H-atoms attached to oxygen atom
3) The number of O-atoms attached to P- atoms
4) The number of P-atoms
26. What are 'A' and 'B' in the reactions, in respective order?

2) 3) 4)
27. Nitrolim is
1) C 2) CaCN₂ +Graphite 3) CaNCN 4)
28. Which of the following is/are CORRECT from the given below?
(I) Brown ring test for nitrate depends on the ability of Fe2+ to reduce nitrate to nitric oxide
(II) Red phosphorus is much less reac- tive than white phosphorus
(III) Red phosphorus readily catches fire in air to give white fumes
(IV) White phosphorus is a translucent white waxy solid
1) I, II, III and IV 2) I, II, and III 3) II, III and IV 4) I, II and IV
29. Which of the following is correct regarding brown ring complex?
1) It is paramagnetic, contains 3 unpaired electrons
2) Oxidations state of iron is +1

3) Formula is
4) All are correct
30. The correct order of bond angle of
1) 2)
3) 4)
31. Among the following ions, overlap is present in
1) 2) 3) 4)
32. Which of the following reaction is incorrect?
1) 2)
3) 4)
33. Statement-I: White phosphorous is stored under water
Statement-II: white phosphorus is highly reactive and catches fire spontaneously in air
34. Assertion: Cr, Al, Fe and Ni are passive with concentrated Nitric acid
Reason: The film of oxide layer is formed which prevents further action of concentrated Nitric acid
on metal
35. Column-I Column-II
(Oxide of nitrogen) (Property, structure)
a) NO2 p) Acidic, paramagnetic
b) N2O q) Contains N-N linkage,
c) N2O5 r) Contains N-O-N linkage
d) N2O3 s) Blue solid, acidic oxide
a b c d a b c d
1) p q r s 2) p r q s
3) s q r p 4) s r q p
36. In which one of the following compounds does sulphur have the least oxidation number
1) SO2 2) H2So4 3) Na2S2O3 4) Na2S4O6
3
37. In which of the following central atom makes use of sp hybrid orbirals
1) SO2 2) SO3 3) H2Se 4) H2O
38. Hg sticks to the surface of glass when it comes into contact with
1) H2O 2) HNO3 3) Grease 4) O3
39. The final acid obtained during the manufacture of H2SO4, by contact process is
1) H2SO4 (conc.) 2) H2SO4(dil) 3) HCl 4) H2S2O7
40. Oxygen is more electronegative than Sulphur, yet H2S is acidic while H2O in neutral. This is because
1) water is a highly associated compound
2) H-S bond is weaker than H-O bond
3) H2 is a gas while H2O is a liquid
4) The molecular weight of H2S is more than that of H2O
41. Oxygen gas can be prepared from solid KMnO4 by:?
1) Treating the solid with H2 gas 2) Strongly heating the solid
3) Dissolving the solid in dil. H2SO4 4) Dissolving solid in dil HCl
42. Identify the correct sequence of increasing number of bonds in structure of the following
molecules
i) H2S2O6 ii) H2SO3 iii) H2S2O5
1) i, ii, iii 2) ii, iii, i 3) ii, i, iii 4) i, iii, ii
43. Assertion (A): S2 is paramagnetic like O2
Reason (R): S2 contains two unpaired electrons in the antibonding orbitals
1) Both (A) and (R) are true and (R) is the correct explanation of (A)
2) Both (A) and (R) are true and (R) is not the correct explanation of (A)
3) (A) is true but (R) is false
4) (A) is false and (R) is true
44. Hot concentrated sulphuric acid is a moderately strong oxidizing agent. Which of the following
reactions does not show oxidizing behavior?
1) 2)
3) 4)
45. In which pair of ions both species contain S-S bond?
1) 2) 3) 4)
46. which is the correct thermal stability order of H2E (E=O, S, Se, Te and Po)
1) H₂S < H₂O < H₂Se < H₂Te < H₂Po 2) H₂O < H₂S < H₂Se < H₂Te < H₂Po
3) H₂Po < H₂Te < H₂Se < H₂S < H₂O 4) H2Se < H2 Te <H2Po <H2O <H2S
47. Charring of carbohydrates on treatment which conc. H2SO4 is due to
1) Oxidation 2) Dehydration 3) Reduction 4) Hydration
48.