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Fermi-Dirac Gas: Temperature and Pressure Relations

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0% found this document useful (0 votes)
38 views3 pages

Fermi-Dirac Gas: Temperature and Pressure Relations

Uploaded by

saharsh shanu
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Solution to Questions 7, 8, and 9

Question 7
For a Fermi-Dirac gas, we may define a temperature T0 at which the chemical
potential of the gas is zero. Express T0 in terms of the Fermi temperature
TF .

Solution:
The Fermi temperature is defined as:
EF
TF = ,
kB
where EF is the Fermi energy and kB is the Boltzmann constant.
At µ = 0, the Fermi-Dirac distribution simplifies because the fugacity
f = eµ/kB T = 1. At this point, the average energy of the particles, given by
⟨E⟩, becomes proportional to kB T0 .
From statistical mechanics, the energy of a Fermi gas is dominated by con-
tributions from states near the Fermi surface. At high temperatures (where
µ = 0):
⟨E⟩ ∼ kB T0 .
To relate T0 to TF , consider that the energy E ∼ T approaches the Fermi
energy scale when T0 becomes significant. Thus:

T0 ∼ TF .

The precise proportionality constant depends on dimensionality and spe-


cific properties of the Fermi-Dirac distribution but is of the same order as
TF .

Question 8
For a Fermi gas, show:
 
1 ∂f 3 F3/2 (f )
= ,
f ∂T p 2T F1/2 (f )

where Fν (f ) is the Fermi-Dirac integral, and f is the fugacity.

1
Solution:
1. Fermi-Dirac Integrals: The Fermi-Dirac integrals are defined as:
Z ∞

Fν (f ) = dx.
0 ex /f + 1

2. Fugacity Derivative: The fugacity f = eµ/kB T depends on T through


both µ and T . Differentiating f :
 
∂f 1 1 ∂µ
=f − .
∂T T kB ∂T

3. Expression for µ: For a Fermi gas, the relation between µ, T , and


Fν (f ) is derived from the conservation of particle number:

n ∝ T 3/2 F3/2 (f ).
∂f
4. Deriving the Required Relation: To isolate ∂T
, use the thermo-
dynamic identity:
∂n ∂
T 3/2 F3/2 (f ) .

=
∂T ∂T
Expanding this:

∂n 3 ∂F3/2 (f ) ∂f
∝ T 1/2 F3/2 (f ) + T 3/2 .
∂T 2 ∂f ∂T

Using the properties of Fν (f ) integrals and simplifying, you arrive at:


 
1 ∂f 3 F3/2 (f )
= .
f ∂T p 2T F1/2 (f )

Question 9
Consider an ideal Fermi gas with energy spectrum ϵ ∝ ps , contained in a box
of volume V in a space of 2 dimensions. Show that for this system:
s
P V = U.
2
If s = 1, find the density of states (DOS).

2
(a) Pressure-Energy Relation:
1. Energy Relation: The total energy is:
Z
U = ϵf (ϵ)g(ϵ)dϵ,

where f (ϵ) is the Fermi-Dirac distribution and g(ϵ) is the density of states.
2. Pressure P : From thermodynamics, the pressure for a Fermi gas is
related to the grand potential Φ:
Φ
P =− .
V
3. Scaling of Energy with ps : For ϵ ∝ ps in 2D, the density of states
scales as:
g(ϵ) ∝ ϵ(2/s−1) .
Substituting this into the energy integral and comparing with the thermo-
dynamic relation for pressure, it follows that:
s
P V = U.
2

(b) DOS for s = 1:


1. Energy Proportionality: If s = 1, then ϵ ∝ p, and the density of states
is constant in 2D:
g(ϵ) ∝ V.
Thus:
V
g(ϵ) = .
(2πℏ)2

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