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Isopentyl Alcohol and Acetic Acid Data

The document provides physical property data for several chemicals including acetic acid, isoamyl alcohol, isoamyl acetate, water, and sulfuric acid. It lists molecular weight, boiling point, density, heat capacity, enthalpy of vaporization, Gibbs free energy, entropy, pH, and heat of formation for each chemical. It also gives solubility information and Antoine equation parameters for vapor pressure calculations over a range of temperatures.

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0% found this document useful (0 votes)
134 views5 pages

Isopentyl Alcohol and Acetic Acid Data

The document provides physical property data for several chemicals including acetic acid, isoamyl alcohol, isoamyl acetate, water, and sulfuric acid. It lists molecular weight, boiling point, density, heat capacity, enthalpy of vaporization, Gibbs free energy, entropy, pH, and heat of formation for each chemical. It also gives solubility information and Antoine equation parameters for vapor pressure calculations over a range of temperatures.

Uploaded by

Bradley Hambly
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Appendix

A Physical Property Data[1][2][3][15][27]

37

MW (g/mol) BP (C) (g/mL) Cp (J/mol-K) Hvap(kJ/mol) G (J/kmol) S (J/mol-K) pH Hf (kJ/mol)

C2H4O acetic acid 60.05 118.1 1.049 123.1 23.7 -0.000003746 159.8 2 -484

C5H12O isoamyl alcohol 88.15 132 0.81 209.97 44.07 -0.00000145 ----- 7 -356

C7H14O isoamyl acetate 130.18 142 0.876 248.5 48 ----- ----- 7 -558.69

H2O water 18.02 100 1 75.3 40.65 -0.00002731 70 7 -285.83

H2SO4 sulfuric acid 98.08 270 1.84 136.65 509 ----- 156.9 Acidic -----

acetic acid isoamyl alcohol isoamyl acetate water sulfuric acid

Solubility cold and hot water, diethyl ether Acetone methanol, diethyl ether, cold and hot water methanol, diethyl ether, acetone partially in hot or cold water N/A cold water, ethyl alcohol

a 4.68206 7.1776 5.08047 4.6543

Antoine's
b 1642.54 1314.56 1932.043 1435.264 c -39.764 168.16 -28.698 -64.848

T (K) 290-391 310-411 314-367 256-373

38

Works Cited
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39

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Lee, Ming-Jer, Shao-Ling Chen, Chen-Hui Kang, and Ho-mu Lin. "Simultaneous Chemical and Phase Equilibria for Mixtures of Acetic Acid, Amyl Alcohol, Amyl Acetate, and Water." Industrial Engineering Chemistry 39 (2000): 4383-391. Print.

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Product Safety Assessment Primary Amyl Acetate DOW. Web. 06 Dec. 2011. Quilter, M.G. The Production of Isoamyl Acetate from Amyl Alcohol by Saccharomyces cerevisiae. Journal of the Institute of Brewing. Vol. 109, No. 1, 2003.

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40

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Wang, Lijun, Youwei Cheng, and Xi Li. "Liquid-Liquid Equilibria for the Acetic Acid+Water+Amyl Acetate and Acetic Acid+Water+2-Methyl Ethyl Acetate Ternary System." Journal of Chemical and Engineering Data52.6 (2007): 2171-173. Print.

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[29]

nidari-Plazl, P. Theoretical and Experimental Studies of Enzyme-Catalyzed Isoamyl Acetate Synthesis with Ionic Liquid at the Microreactor Scale. Department of Chemistry and Chemical Technology. University of Ljubljana.

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