Assignment-2 Q1. For a face centered cubic lattice, the miller indices for the first bragg’s peak(smallest bragg angle) are: [GATE 2012] (a) 002 (b) 111 (c) 001 (d) 110 Q2. A plane of spacing ‘d’ shows first order Bragg diffractiy ingle 8. A plane of spacing 2d 013] (a) shows Bragg diffraction at 20 e (b) shows Bragg diffraction as (c) 001 (d) 002 Q4. The X-ray powder pattern of NaCl shows an intense cone at 8 = 15.87°. Using X-rays of wavelength 1.54 x 10° cm. The spacing between the planes (in A) of NaCl crystal is (a) 1.41 (b) 2.82 (c) 4,23 (d) 5.63 Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com gasoosta72Q5. The angle between the two planes represented by the Miller indices (1 1 0) and (1 1 1) ina simple cubic lattice is: (a) 30° (b) 45° (c) 60° (d) None of these [NET Dee. 2012] Q6. Assuming ‘a’ to be the unit cell length of a cube, the value of d220 is: a5 os () V2a Q7. X-rays of Cuk,, (wavelength 154 pm) até diffta of atomic planes in a crystal in the following.n @ separation of the layers in the crystals is 404 pm. Find a a along which the first-or (a)79° ) 45° (c) Le (d) None of the above Q8. Consider an orthorhombic unit cell of dimensions a = 450 pm, b = 650 pm, and c = 400 pm. The perpendicular distance between the (1 1 0) planes is: (a) 650 pm (b) 450 pm (c) 370 pm (d) 500 pm Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com gasoosta72Q9. The condition for complete destructive interference of monochromatic X-rays of wavelength diffracting from successive crystal planes of interplanar spacing d is: (a) X=2dsin® (b)k=4d sin (c) A= 2d cosO (d) 4 = 4d cosO Q10. Crystal A diffracts from (1 1 1) and (2 0 0) planes but not from (1 1 0) plane, while the crystal B diffracts from (1 1 0) and (2 0 0) planes but not from the (1 1 1) plane. From the above,we conclude that (a) A has fee lattice while B has bcc lattice © (b) A has bcc lattice while B fcc lattice (c) A an (d) [NET Dec. 2012] QI. The densi metal is 0.53 g cm” and the separation of the (100) pl etal is 350 pm. Determine the structure of the lattice. G' mass of Lithium = 6.94 g mol". (a) SCC (b) BCC (c) FCC (d) Diamond Q12. Calculate the ratio of the spacings of the 100, 110 and 111 planes of a cubic crystal. od 1 ee - 7 Oley Oly ORG 1 (d) None of these Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com gasoosta72Q13. The inter planar distance (A) for a (100) plane in a cubic structure with the lattice parameter of 4A is: [NET June 2013] (a) 1 (b) 2 (c)4 (d)8 Q14. The second order Bragg diffraction from the 100 planes of a cubic crystal is equivalent to (a) The second order diffraction from the 200 planes. (b) First order diffraction from the 200 planes. (c) First order diffraction from the 400 planess (d) First order diffraction from the 100 pl: -6 pm. The value of d333 ) 108.5 pm (d) 625.6 pm (110) planes in a cubic unit cell with [NET June 2014] (c) 7.35A (d) 2.45A Q17. A solid consisting of only X atoms has a close-packed structure with X-X distance of 160 pm. Assuming it to be a closed-packed structure of hard spheres with radius equal to half of the X-X bond length, the number of atoms in | cm’ would be [NET Dec. 2014] (a) 6.023 x 10°” (b) 3.45 x 10° (c) 6.02 x 107! (d) 3.8 x 107! Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com gasoas1872Q18. The distance between two successive (110) planes in a simple cubic lattice with lattice parameter ‘a’ is (a) V2a (b) V3 a (c) 2V2a Os [GATE 2015] Q19. Silver crystallizes in face-centered cubic structure. The 2" order diffraction angle of a beam of X-ray (4 = 1A) of (111) plane ofthe crystal is 30°. Therefore, the unit cell length of the uld be (a)a=3.151A (b) a= 3.2734 (c) a=3.034A (d) a= 3.464 [NET June 2015] into a crystal of ultra puri a p-type semiconductor? (a)C (d) Na Q21. For a sim i stal, X-ray diffraction shows intense reflecti c 8; and 02 which are assigned to [1 0 1] and [1 1 1] pla ectively, the ratio is [NET Dec. 2015] (a) 1.5 (b) 1.22 (c) 0.82 (d) 0.67 Q22. In a cubic crystal, the plane [100] is equally inclined to the planes [NET June 2016] (a) [010] and [011] (b) [010] and [110] (c) [001] and [101] (d) [110] and [011] Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com PereQ23. For a simple cubic lattice, the ratio between the unit cell length and the separation of two adjacent parallel crystal planes can NOT have a value of [NET June 2016] (a) 51? (b) 7!? (c) 111 (d) 131? Q24. The angle at which the first order Bragg reflection is observed from (110) plane in a simple cubic unit cell of side 3.238A, when chromium Kg radiation of wavelength 2.29A is used, i (a) 30° (b) 45° (c) 60° 2013] Q25. An element exists in two crystallogi ications with FCC and 's of the FCC and BCC their unit cells (a) Vece : (b) 2Vpce : Vecc (c) Vace : 2Vec (d) Vace : V2Vece [NET Dec. 2013] Q26. The sin* 6 values obtained from X-ray powder diffraction pattern of a solid are 2x, 4x, 6x, 8x where x is equal to 0.06. The wavelength of X-ray used to obtain this pattern is 1.54A. The unit cell and the unit cell length, respectively are (a) BCC, 3.146A (b) FCC, 3.146A (c) SCC, 6.281A (d) BCC, 1.544A [NET Dec. 2016] Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com PereQ27. In a cubic unit cell, identify the Miller plane (111) [TIFR 2017] (b) Q28. For a FCC lattice, which of the following statements is ect? (d) None of these (a) h, k, 1 values are all odd or all even (b) h, k, 1 values are all even (c) h, k, 1 values are all odd lane in a simple cubic lattice (©) 3 (d)4 (a) 74% of volume of unit cell. (b) 80% of volume of unit cell. (c) 68% of volume of unit cell. (d) 90% of volume of unit cell. [TIFR 2017] Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com gasoosta72Q31. For a simple cubic crystal lattice, the angle between the [2 0 1] plane and the xy plane is [NET Dee. 2015] (a) less than 30° (b) between 30° and 45° (c) between 45° and 60° (d) greater than 60° Linked Answer Type for Q.32 and Q.33 Calcium metal crystallizes in a fec lattice with edge length of 0,556 nm. Q32. Calculate the density of the metal if it Contai s 0. defects if it contains 0.2% Schottky (a) 1.5 gem? (b) 2.5 g em* (c) 3.5 ¥ (d) 4.5 gem? Q34. Cons -type semiconductor whose Ey = 0, E.= 2.0eV and Eq = 1.98eV. The correct statement among the following is (a) Er = 1 eV and is independent of T (b) E¢ = 1.99 eV and remains independent of T (c) Er = 1.99 eV and increases towards 2.0 eV with increase of T (d) Er = 1.99 eV and decreases with increase of T. [NET Dec. 2011] Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com gasoosta72Q35. When Si is doped with a Group V element, (a) donor levels are created close to the valence band (b) donor levels are created close to the conduction band. (c) acceptor levels are created close to the valence band (d) acceptor levels are created close to the conduction band T 014] Q36. X-ray diffraction does not give any structurg, r (a) metallic solids (b) ionic (c) molecular solids olids [NET Dec. 2014] tist wants to replace a few of the s. Which of the following statements aterial? (b) The resulting material will NOT have a cubic diamond structure (c) The resulting material will be a defective diamond as it will be p- doped (d)The resulting material can be characterized as n-doped diamond. [TIFR 2016] Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com gasoas1872Q38. The band structure in an n-type semiconductor is — 2 2 ed i a a I I sul Iv (a)I (b) I (c) Il 8 2011) Q39. Band theory predicts that magnesiumsis r. However, in practice it acts as a conductor due [GATE 2010] (a) increases with increasing temperature (b) decreases with increasing temperature (c) is independent of temperature (d) shows oscillatory behavior with temperature [GATE 2015] Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com jpsnces ietsQ41. The defect that results when electrons are trapped in an ionic crystal lattice in place of an anion vacancy is known as: (a) Frenkel defect (b) Schottky defect (c) F-Center (d) Dislocations Q42. If NaCl is doped with 10° mol% SrCh, what is the concentration of cation vacancies? (a) 6.02 x 10°mol" (b) 6.02 x 10'8mol! (c) 6.02 x 10°8mor! (a) 6.02 x 10;mo crystalline solid increases with (b) Metal (d) Semimetal Q45. By X-ray diffraction methods, the unit length of NaCl is observed to be 0.5627 nm. The density of NaCl is found to be 2.164 g cm*. Calculate the percentage of Na* and CI ions missing. (a) 1% (b) 0.8% (c) 2% (d) 1.8% Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com gasoosta72Q46. The composition of a sample of wurtzite is Feo93 O1.00. What percentage of the iron is present in the form of Fe(III)? (a) 11.5% (b) 52.5% (c) 68% (d) 74% Q47. Analysis shows that nickel oxide has the formula Nio.»s0. What fraction of the nickel exist as Ni?*and Ni** ions? (a) 96 and 4 (b) 4 and 96 (c) 86 and 14 (d) 14 and 86 Linked Answer Type for Q.48 and Q.49 tant. Find the density ) 15 (d) 52.5 g m°, identify the type of point defect (b) Metal excess defects (d) Frenkel Q50. Which one of the following statements is INCORRECT? (a) Frenkel defect is a cation vacancy and a cation interstitial (b) Frenkel defect is an anion vacancy and a cation interstitial (c) Density of a solid remains unchanged in case of Frenkel defects. (d) Density of a solid decreases in case of Schottky defects.[GATE 2015] Gi chemistry @ichemistry.ontine —[~] jchemistry001ggmail.com Pere