ay Lai eleawipied Me “ abermendes aie in metal and! nen mebole + Metahe ase Re one shiek have ake erdeney f Jesirg te &. Nia —> Ala* +e> we —> Ke +e Nen ~ metals asic Re one hich -Rave he send erey of gnrng Re & 4 e —)h- Ch ey Doasbach» Rete’ dincoverty of metabtoid iF {aed A 4 ‘ j Prout py HypetResia He asimphy | Godlee: Shah oll’ ten sdernensy arte te up of Rydowgen » ge ast con Gi thot 1 ap cloning =n» (ato seth eet fomie. ascight ef Ho! ¥ aohere 9 = res ef Haba V8) 3 =~ ie Ademricis stude io valid a‘ 5 ee th aps ed opel Ue oe eo etd an Jt be e " y ‘ged ie ae Bien fae fae) tas? Ho fone better andl a ved te Dott asin Ke Be cane, ro alt a i occuty the.is stude io valid a‘ 5 ee th aps ed opel Ue oe eo etd an Jt be e " y ‘ged ie ae Bien fae fae) tas? Ho fone better andl a ved te Dott asin Ke Be cane, ro alt a i occuty the.mn > CENERAL ORGANTC CHEMISTRY — G Ce iti — ay dag o C paste SS ch | <9 EDT 1 defisione € Conbaiwion | fo by Luatng — susie by #9 7 ai Neagsdg + Bathe —> 2 NaCl + Bases Se 7 Reeds affects {ee — rw intirwadiake ak all. ‘ J 7 steallve fon voy shonk Hine aa —e q Reryym<— pe Ina nm one type of eabocation rn Ren aunie Unie it Y a ipl came Gira als dical Chen ol) 2 ifpuren | nek nadica WCH= CH, +0t SUH PHO eM “> ceswived by £° wovewnurk $501 content ~Fonmation De inbuwuaditts oceun- f \ —Wz Nitrune JTNTER rae [suasrraTe] +[REAGENT He ie stable Lean ctabole Ae (mutncoctive won suackive, a 1 ftnibiakes 1x MATOR PRODUCT MawoR PRODUCT FI Orlov waver gnitiaken D-I> COnillrdnai| reaction - € dur Sifjvaree in = en thaw 60's from en stable intermediate = mone than 50%. " \ poten of +H oo bord. OG — Eh, a ih at eet piotron ate Gaeta duc to angle strainSOME IMPORTANT POINTS 4) fre Radiol + frre Radical 4 Gonloon- 4s" 292 2p* (9.22 ch + Sane t= 1 i P (2s42p) — Bond fonmation potcibl.. Voeank ontital ete. 1 ] Ground State a es Pr eee nadicol C= [He] [4] [F [1 ]a | Cxcited State ~ Bond fornabion possible Now 4P GRIGNARD REAHENT 3) Canbamion + free Radéoak Ht 42° He + 2H 1 crMg % Bond ferumation inipocsible at eet seit — Righty Stable D Gotions {ree Radiote mae sale = Nets Neon = Rona and fonunation impossible H +N —3 & hake, ~y7 > Nable Os Y Pe 21Pr® + [weet] 7 aun ataliny OR Cur Lit Not pa ate da radical @ Sownet of Norilo ound Geoutncalty Paogint G cormuy-houre Cyuthuris RHgx oly Ng Sooug one ay neagtak Ratda tao G Conbaonylic acid dunivakives Pa wale Ha 900 CARBOCATION FORMATION ee: Natl OCtUR IN— Athy tnodion of oo Radical Ateotrol, SN*, alretroplullic *AKE: a bay ane teadaney of addition mth. . Wurst Waond fioln. 4 dinsertialien quer CMD Goch? cnet - aa CARGENE seat? & w + ty-x + ONe snens LS e-em + UNax- ae CH, + CO. EH, At otanb + Canbocabion 14> Fast Radical *£ > Cookanion q He + taken 2. tern 22> Anion ck ae a ‘ ee fe Neat + wet ae % . * etn wen beimaun WYK ler +2nat CD an oo : fadtanacorttint To pail -aumine tet. x (arent Hivenpraduel ngltt © - cote 8 Se betle 22 ina single onli tel Majon fredtek a es i a a SU SSL se ‘usw. So NETRENE Unitek Canlaere peti eParein diffywnt ont cali ae si -* = Linen - tesa gs fh man bromawide degradation duce Lp tu. — himde Ren he ot Sen Sebi Debosmita Saha Flt Gee tentius Re - ld ypenuck ~ ales unding® mearriaunquanire -~ Ponwraunt dicplaceuint bond elaekruon dus to aiff in Luetoomagativity 3 4+ always exit in pain (47,2) a ee 2+ ADDITIVE in natww and it ne Bontc Abunatt ieee disuetion. Ay ee Strung + Bante Sra ha a celine ret be ant 7 Q Aeidic Skruagttr o€ ve + Boate ‘ea tha he nes 3: Acidic: Stamps th Seal % Boaie Stoangtia ckability ef enjugale t Boat eth—0— Hoe Y ac 3 Tyduckive fuck Cee ee ee Se eee Aa oy, pete » Pre = G: Aft qigonbonds Inductive _ De 2 = R-N#, Ng affack te neo Ae hn = 5 Pune $F : BS 2 pace ” rs, * af feck = ALKYL Guour> bows +1 Ht (oo g oo % eh Lon Gla é Bape . neann er (00H soon. (ecru o oe Crust) . tae 0 appl ae. iene Nulowie Suceinie oid aK has 50> 00 Qe =v Cnonged bowoup Wor +E + oak A cee ae be love ttronged Gowmup hoo =I aed, 5 & 1H us H20 - peat 44+ Gouskun-et Effie — 1: eect * Adepie. kk s = ‘dE ehys tu, 2 OH = fips D-H, > NAP D> nibs CH, — COOH bee ae i) aie HESCH NH; POH = 7 Oy Guutirie acid ve ae i) iu Z di Fir fay ive p—Hl00)—eN) “to «most acidic rea tina a ass or eee a 43: ° > ovolit old i dey ejexobaso- erg ic 7 5 —[Link]-> jaleenate | quik Mg =bH,> Wn >-6> (ed). + Sksonaest acid in wosld = HOLOg . jus WOR Gorignandl — > ee: coou os Pia Natives Reas eink CH, Cee ) Hs . COOu Coo pa es ee 2 Soda a c D Debosmita Saha ae = often 9 an iv oe is okCamportant Nevep Reactions) —17._furkulsJern Reackon —> Nod with us Acatme) [Maivty—s ABN Toirdes] RoX + Nol —» R-T + Nox [x =< 6a]. Neacl/NaBr fasmad 8 ppt Indyaudme: Ufoeibbtes da. forwod Reach atcadn, to i 27. Swartz Reachon—» (Meathre Pornide = Ag Hgafi., cofs, blz) Shs BAt ASE —- cha Ft Aggs ( Maint, pail flumdes) 22, Warde Fiasig Reackon —> QNa with doy atten) (Sets kK + Na + ex SY, egisk +Nax [rindect attyh ihabie & Ant tolite ) AD. Foth'g Reachen —> C Nat Qty ether) [Meinty Arf Hal'des ] ey 4 LAGHSX t2Nea 266s + 2Nas, a “SX kobbe's Resckon >» (Nooti [corr ) CEledaophile —» Co) i Bice SH got C Bledaephilic Baubshtudion a) I 4) Red ine CS Tothahgdanny benatcauid ] cin Le saline Aid, Phenenide. jn > Phenal] (dues of Reodivity of Est) kahic , a Hed ae “Caiman Reachion a» Gchels-+ a4. Naoki) ( oledaphtle rec.) oe “al weyers aaa Cay, ol se hpi i oa Nase CG Samabinle a Baba hbe bored dadaae ta 1 mafesesued aby As ea ——titebenide tes Beata th gait GS al Gms oie RES oe ae —(enttSesdny “ens pmantdey a ee 1p. Hefbewann Hypsbsamida. Dassadabin Genllones iC anna sis My ton oe ooo attest) Ark Gesee tales phase, frm cocb mah cobon of + sewide “fe NeFnogen edema. Amine forwred corrloin 1 tesa C thon Bin Aroida. Raton + ey +Neo—> BNUa + Nateg-t 2NaBa$ 2H, 0 Emailing Burbstenied. 2°93 3° dent shewdtis Reacher, RoNH, 4 chedg + 2KoH > R-Nc +3Kelt 34,0 Li Greepaite Teas) 19). Bordrnensen'5. Readton— > ( GrrcJa (Heh CG. Baz [Het ) COUN) Ke) Anh, x ————» Go | HIS, ge ae eS ile Ole isha + Nae Con, @ on is faust Hon tstlanern & Bale genera Reschn > (HBF4 /O) 24 = Bf. Ad-F + BPs + No AyNaed ay rte a Noe aS olden — Bowsmen chaNho + cages 8 oy Nh + osDero ——y Dat Ho T_ cpeup Jp Asc + Dch, grup an | both Reduckene J. (3), _Welf-Kishner Reduchen —? CNH-Nka + kon [ = ‘ol EG Scco _NKacNh ue 2. = Heo. SCSNNK —_—— 14). Coonnirnsals Reachien —> Cume- ime: Naot) i pasties 24 5 onvdafin= Reduchen.Hokuder ep ACEC Y C= 0-H < o-N > > Ni[Weng] torn h 1H St pe Loungth ol ANd Molt class Bere clan, MM nmi dik un wd | Nes Cha 12 903 # polonoiolynt bora > fetotonuictray clom aS 6-2-1 [6] p= 188 He dipottnement _ a ao ; Sp = 120 Ly % i Se 6-1 BY Sp9 > 10URR [For ven Lone pr ‘ « = 6-4-1(2) Bae ta *< ac < @ ( <= es Fas C618) planes (20! - HF bowen bree PPP howe # bdo} = on utith poral J © flake = 90 s ¢ - Sle & ae Fajars Rate = « Tr 40 faboure 8 Cocicit n Elocamsen ee} Teta or ee oe aad chara! HD eds ‘Aine peace? | Far plane| o chasigt on cen Pa aon ¢ Ge | LF cation of dame bg han 2 ALG AOrgRthen Vatener cleenon & NOr N02 1G] OF > II — CHyeto9's | ademente wutth (n-Yans* HGH; Hee bat, , < BFg 2120 ee a ee lyy O03 So. 7 UGS polantzirg than One LU ag yogeiome > 18 obes gi confipeovaten HE Sela > octer seek Jottow Bend riety LOR Ebae + ee [eae dig too Metrutle inion chapel « Leu Joniation high e- gain | yy_e—> U+OH- Dar) Ser |OM> MacHic Hex cHarcue @ enthaiphy — grubelpy. | on > +0 bay, “W27 be Cone igs 29x 220] KTH bo) s é cling hau e clensy T toed yeh by 2°, ode abou 9 Y aint Grit 7% bas RIE aS *\e pm] Ce= 34pm Ley & dys; up alte poulble Spry WS Wotpatithe} fons. Ant of €2fe PSY Pais auiar bond F boTget F Us aken wicuesal yuLhich ee oes yeas, # Molecstan orbital H atone otth/I0h 2 y H meticulten otibilel7 i daa | + TERT. A vborangmotodee , Fantiborsliy faping jscucest #ybe ee total envigy of io moliculan ereditee Heiman same % Mar of ee aberginal atinre orbital HE (onatiion of combination) Crap = 1 2pq) ce eae Gena than napa 9 2py. # apo NE> 613 é chis L628 Ze" 28 < ©2p2 < (mIpx= N2py) < & (pret opy) LS po Hf Bond oxdin - 1 LN, Wa] H He, 1 Wy don't eube BeUSTaAp a= = Sopp FP alt odd e ane paua rout Hu intewnuclter wacept ioe’ 9 [ke~ Bond p. 4one-p FEIN? # ISL 67158 eas C*ls¢ a F Siy3e30 goat Caapa anzey ceaga < FPosifi0n Gees Hf Spd 2 Ariat eg Quah eae ete Teguateue alli tere", 1 ALB axe wt dlr tC oO ge . oie Pf = a Shape 1 René a Bonk 3 WaneeneXEEX)! 1 pytamidat. 2 T- shape 1 su Mae 2 Aqua planner 1 Square pyriamidoe ie © kineax (SP 0 Txigonat Plannerfs¢ 0 Ttwahidnal se) 0 Bugohet bipyramal 0 pttahednatesprary oO fentagonat bipyta- ie “espa ot Spid?- cynial i Ydda Rat ag Ped, mar.=F ma’bond lon een SS Sp ‘pe “7 pico bond= sicteways our 4b hyduuctesation of atomre dhberat Singer ousitelsy Ru vA cliggoent Qnoxgy Ayu haw fee —owilap to expiiel of dame enugy) dame 4ame may Pg Shape envegy mm Inkent: Haepryewraizauen) \C Ce euler 4 Ziapomad aoe ora : rot with ‘Payperdiation ape Bre FF Type of moticulancrbited- vied Te & 9 non FONE SDF Oe men, eymeny SYRIA be sisipm ""{ Bex ated eae ay CH foapm Pi 2 HHS Spr > 29x 220] KTH bo) s é cling hau e clensy T toed yeh by 2°, ode abou 9 Y aint Grit 7% bas RIE aS *\e pm] Ce= 34pm Ley & dys; up alte poulble Spry WS Wotpatithe} fons. Ant of €2fe PSY Pais auiar bond F boTget F Us aken wicuesal yuLhich ee oes yeas, # Molecstan orbital H atone otth/I0h 2 y H meticulten otibilel7 i daa | + TERT. A vborangmotodee , Fantiborsliy faping jscucest #ybe ee total envigy of io moliculan ereditee Heiman same % Mar of ee aberginal atinre orbital HE (onatiion of combination) Crap = 1 2pq) ce eae Gena than napa 9 2py. # apo NE> 613 é chis L628 Ze" 28 < ©2p2 < (mIpx= N2py) < & (pret opy) LS po Hf Bond oxdin - 1 LN, Wa] H He, 1 Wy don't eube BeUSTaAp a= = Sopp FP alt odd e ane paua rout Hu intewnuclter wacept ioe’ 9 [ke~ Bond p. 4one-p FEIN? # ISL 67158 eas C*ls¢ a F Siy3e30 goat Caapa anzey ceaga < FPosifi0n Gees Hf Spd 2 Ariat eg Quah eae ete Teguateue alli tere", 1 ALB axe wt dlr tC oO ge . oie Pf = a Shape 1 René a Bonk 3 WaneeneXEEX)! 1 pytamidat. 2 T- shape 1 su Mae 2 Aqua planner 1 Square pyriamidoe ie © kineax (SP 0 Txigonat Plannerfs¢ 0 Ttwahidnal se) 0 Bugohet bipyramal 0 pttahednatesprary oO fentagonat bipyta- ie “espa ot Spid?- cynial i Ydda Rat ag Ped, mar.MRE three awe! «Soha + ree phy i ‘PPen that mom id Wsleal Manet? distctoutos 1 staton ap Silty > “Btianedrae hecnmoa tinea one | Unevmmety H Asks = Tuponat & bioysiamital ! WAts ® 1 F Cone ! ' # > wtearcliane Otetuat Lore pail # Parner in buating Jorie CK LE Polax bond inmotcute but it bp can haw xvi0 pole Meonunk [ey H> # 8B +H; > 68 Nig : = ge => ese Sos eer Re et le Thea Bw chang ih eh 48 ftom Sp? &?