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GCE

Specimen Papers with Mark Schemes

Edexcel Advanced Subsidiary GCE

in Chemistry (8080)
First Examination 2003
Edexcel Advanced GCE in Chemistry (9080)
First Examination 2003
December 2002

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Contents

Question Papers Page

Unit Test C1 1
Unit Test C2 11
Unit Test C3B 23
Unit Test C4 33
Unit Test C5 45
Unit Test C6B 61
Unit Test C3A 69
Unit Test C6A 79

Mark Schemes Page

Unit Test C1 87
Unit Test C2 91
Unit Test C3B 97
Unit Test C4 103
Unit Test C5 111
Unit Test C6B 117
Unit Test C3A 123
Unit Test C6A 129

General guidance on marking 135

Periodic Table 137

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6241.01
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Chemistry
Advanced Subsidiary
Unit Test C1 Question Leave
Number Blank
Specimen Paper
1

Time: 1 hour 2

4
Materials required for examination Items included with question papers
None None
5

Instructions to Candidates
In the boxes above, write your centre number, candidate number, your surname, initial(s)
and signature and the paper reference number.
The paper reference is shown above.
Show all the steps in any calculations and state the units.
You may use a calculator.
Answer ALL the questions in the spaces provided in this question paper.

Information for Candidates

The total mark for this paper is 60. The marks for the various parts of questions are shown in
round brackets, e.g. (2).
A Periodic Table is printed on the back cover of this question paper.

Advice to Candidates
You are reminded of the importance of clear English and careful presentation in your answers.

Total

Turn over
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Edexcel Foundation is a registered charity. © 2001 Edexcel

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1
1. (a) (i) Complete the electronic configuration of a sulphur atom.

1s2 ...............................................................................................................................
(1)
34
(ii) Deduce the number of neutrons and protons in the nucleus of an atom of S.

Neutrons ………………….. .Protons………………………

(2)
(b) (i) Define the term first electron affinity. .

.....................................................................................................................................

.....................................................................................................................................
(3)
(ii) The following equation represents the change occurring when the second electron affinity of
sulphur is measured.

S- (g) + e- → S2- (g)

Explain why the second electron affinity of an element is endothermic.

.................................................................................................................................

.................................................................................................................................
(2)
Total 8 marks

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2. (a) Iron has several isotopes. One of them has the electronic configuration [Ar]3d6 4s2 , an
atomic number of 26 and a mass number of 56.

(i) Which of these pieces of information would be the most use in helping a chemist
decide on the likely chemical reactions of iron?

.................................................................................................................................
(1)
(ii) What are isotopes?

.................................................................................................................................

.................................................................................................................................
(2)
(b) The relative atomic mass of a sample of iron may be found by using a mass
spectrometer to determine the isotopic composition.

(i) The diagram below represents a low-resolution mass spectrometer in which four
areas have been identified. State what happens in each of these areas.

Area A.............................................................................................................................

Area B.............................................................................................................................

Area C ............................................................................................................................

Area D ............................................................................................................................
(4)

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(ii) In such a determination the following isotopic composition was found. blank

Isotope Percentage composition

54
Fe 5.80
56
Fe 91.6
57
Fe 2.20
58
Fe 0.40

Calculate the relative atomic mass of this sample of iron, giving your answer to
two decimal places.

(2)
Total 9 marks

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3. (a) When the Group 2 element calcium is added to water, calcium hydroxide and
hydrogen are produced.

Ca(s) + 2H2 O(l) → Ca(OH)2 (aq) + H2 (g)

(i) Calculate the volume, in cm3 , of hydrogen that would be collected if 0.17 g of
calcium were used.
(Assume that the molar volume of a gas is 24 000 cm3 at the temperature and
pressure of the experiment.)

(2)
(ii) How many molecules of hydrogen gas would this volume contain?
(Assume Avogadro’s number, L, = 6.0 x 1023 mol-1)

(1)
(b) State the trend in solubility of the hydroxides of the Group 2 elements as the atomic
mass of the metal increases.

........................................................................................................................................
(1)
(c) (i) Write an equation to represent the change occurring when the first ionisation
energy of calcium is measured.

.....................................................................................................................................
(2)
(ii) State and explain the trend in the first ionisation energy of the Group 2 elements.

....................................................................................................................................

....................................................................................................................................
(4)
Total 10 marks

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4. (a) Boron forms the chloride BCl 3 . Draw a dot-and-cross diagram for BCl 3 .

(1)
(b) (i) Draw the shape of the BCl 3 molecule.

(1)
(ii) Explain why BCl 3 has this shape.

........................................................................................................................................

........................................................................................................................................
(2)
(c) (i) The B-Cl bond is polar due to the different electronegativity of the atoms. Explain
what is meant by the term electronegativity.

.....................................................................................................................................
(2)
(ii) The B-Cl bond is polar. Explain why BCl 3 is not a polar molecule.

....................................................................................................................................

....................................................................................................................................
(2)
Total 8 marks

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5. (a) Hydrogen sulphide is produced when concentrated sulphuric acid is added to solid blank
sodium iodide, but sulphur dioxide is produced when concentrated sulphuric acid is
added to solid sodium bromide.
(i) Complete the following table:

Oxidation number of sulphur

Compound Formula
in compound

Sulphuric acid H2 SO4

Hydrogen sulphide H2 S

Sulphur dioxide SO2

(3)
(ii) Use your answers to part (a)(i) to suggest which of the ions, iodide or bromide,
has the greater reducing power.

.................................................................................................................................

.................................................................................................................................
(2)
(b) (i) Write an ionic half-equation to show the oxidation of chloride ions, Cl -, to
chlorine, Cl 2 .

.................................................................................................................................
(1)
(ii) Write an ionic half-equation to show the reduction of chlorate(I) ions, OCl -, to
chloride ions, in acidic conditions.

.................................................................................................................................
(2)
(iii) Bleach is a solution of chlorate(I) ions and chloride ions. Combine the two ionic
half-equation above to produce an equation which shows the effect of adding
acid to bleach. Include state symbols.

.................................................................................................................................

..................................................................................................................................
(2)
Total 10 marks

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6. (a) The table below shows the melting temperatures of the elements of period 3. blank

Na Mg Al Si P S Cl Ar

m.p./
o 98 650 660 1410 44 119 -101 -189
C

(i) Explain why the melting temperature of sodium is so much lower than that of
magnesium or of aluminium.

.................................................................................................................................

.................................................................................................................................
(3)
(ii) Phosphorus exists as P4 , sulphur as S8 . Explain the difference in the melting
temperature of these substances.

.................................................................................................................................

.................................................................................................................................
(2)
(b) State the structure of, and type of bonding in, the following substances. Draw labelled
diagrams to illustrate your answers.

(i) Graphite

Structure ..................................................................................................................

Bonding ...................................................................................................................

Diagram:

(4)

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(ii) Sodium chloride blank

Structure ..................................................................................................................

Bonding ...................................................................................................................

Diagram:

(3)
(c) (i) Explain why graphite is able to conduct electricity in the solid state.

....................................................................................................................................

....................................................................................................................................
(2)

(ii)Explain why sodium chloride conducts electricity in the liquid state.

.................................................................................................................................

.................................................................................................................................
(1)
Total 15 marks

TOTAL FOR PAPER: 60 MARKS

END

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BLANK PAGE

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Centre Surname Initial(s)
Paper Reference (complete below)
No.
Candidate Signature
No. /
Paper Reference(s) Examiner’s use only

6242.01
Edexcel GCE Team Leader’s use only

Chemistry
Advanced Subsidiary
Unit Test C2 Question Leave
Number Blank
Specimen Paper
1

Time: 1 hour 2

4
Materials required for examination Items included with question papers
None None
5

Instructions to Candidates
In the boxes above, write your centre number and candidate number, your surname, initial(s)
and signature and the paper reference number.
The paper reference is shown at the top of this page.
Show all the steps in any calculations and state the units.
You may use a calculator.
Answer ALL the questions in the spaces provided in this question paper.

Information for Candidates

The total mark for this paper is 60. The marks for the various parts of questions are shown in
round brackets, e.g. (2).
A Periodic Table is printed on the back of this booklet.

Advice to Candidates
You are reminded of the importance of clear English and careful presentation in your answers
.
Total

Turn over

-----/-----
This publication may only be reproduced in accordance with Edexcel copyright policy.
Edexcel Foundation is a registered charity. © 2001 Edexcel

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1(a) (i) State one factor other than a change in temperature or use of a catalyst that
can influence the rate of a chemical reaction.
....................................................................................................................................

....................................................................................................................................
(1)
(ii) For the factor you have chosen explain the effect on the rate.

....................................................................................................................................

....................................................................................................................................
(2)
(b) The Maxwell- Boltzmann distribution of molecular energies at a given temperature T1
is shown below.

Number of TT1
molecules 1

with energy E

Energy E

(i) On the same axes draw a similar curve for a reaction mixture at a higher
temperature T2 .
(2)
(ii) Place a vertical line Ea at a plausible value on the energy axis to represent the
activation energy for a reaction.
(1)

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(iii) Use your answers to parts (i) and (ii) to explain why an increase in temperature
causes an increase in the reaction rate.

...................................................................................................................................

...................................................................................................................................
(3)
Total 9 marks

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2. The reaction in the Haber Process that is used to produce ammonia is a homogeneous
dynamic equilibrium:

N2 (g) + 3H2 (g) 2NH3 (g) ∆H = -92kJ mol-1

(a) State the meaning of the term dynamic equilibrium.

........................................................................................................................................

........................................................................................................................................
(2)
(b) Give, with a reason in each case , the effect of the following on the position of the
equilibrium above:

(i) an increase in pressure;

.................................................................................................................................

.................................................................................................................................
(2)
(ii) an increase in temperature.

.................................................................................................................................

.................................................................................................................................
(2)

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(c) (i) What temperature is used in the Haber Process?

.................................................................................................................................
(1)
(ii) Justify the temperature used in the Haber Process.

.................................................................................................................................

(3)

(d) (i) Name the catalyst used in the Haber Process.

........................................................................................................................................
(1)
(ii) How does a catalyst enable a reaction to occur more quickly?

........................................................................................................................................

........................................................................................................................................
(2)
Total 13 marks

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3. Consider the following reaction scheme: blank

step 1
C 3H6 C3H 7Br (major product)
propene S

aqueoues NaOH
step 2
C3H8 O
P

oxidation

CH 3COCH3

(a) (i) Give the reagent and condition needed for step 1.

........................................................................................................................................
(2)
(ii) Give the structural formula of S.

(1)
(b) (i) Give the structural formula of P.

(1)
(ii) State the type of reaction in:

step 1........................................................................................................................

the conversion of S to P...........................................................................................

(4)

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(c) Give the reagent and the condition needed for step 2.

........................................................................................................................................

........................................................................................................................................
(2)
(d) If S is reacted with a solution of hydroxide ions in ethanol, P is not the product. Draw
the structure of the compound that is produced in this reaction.

(1)
Total 11 marks

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4. In the preparation of the alcohol butan-2-ol, 13.7 g of 2-bromobutane was blank
hydrolysed with 9.0 g of potassium hydroxide in aqueous solution. The following
reaction occurred.

CH3 CHBrCH2 CH3 + KOH → CH3 CHOHCH2 CH3 + KBr

(a) Give the amount (number of moles) of each reactant in the above experiment,
and use your answers to state which reactant was present in excess.

(4)
(b) The reaction taking place can be classified as nucleophilic substitution. Explain
the term nucleophile and identify the nucleophile in the reaction.

...................................................................................................................................

...................................................................................................................................
(2)
(c) The above experiment was repeated under identical conditions, except that
2-iodobutane was used in place of 2-bromobutane. State and explain the effect
that this change would have on the rate of reaction.

...................................................................................................................................

...................................................................................................................................
(2)
Total 8 marks

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5. (a) Ethene and propene are in the same homologous series. Explain the term blank
homologous series.
........................................................................................................................................

........................................................................................................................................

........................................................................................................................................
(3)
(b) Draw a representative length of the polymer chain of poly(propene).

(1)
(c) Poly(propene) does not have a sharp melting temperature, but softens over a range
of temperatures. Suggest why this is so.
......................................................................................................................................
(1)
(d) (i) Tetrafluoroethene, C2 F4 , also forms a polymer. Suggest why this polymer is
very inert.
...............................................................................................................................
(1)
(ii) Give one use for poly(tetrafluoroethene).

.............................................................................................................................
(1)
(e) Ethane and ethene both react with bromine. Ethane does not react at room
temperature in the dark, whereas ethene does so extremely quickly. Explain in
terms of the bonding in each molecule why this is so.

........................................................................................................................................

........................................................................................................................................
(3)
Total 10 marks

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6. (a) Define the term standard enthalpy change of combustion. blank

........................................................................................................................................

........................................................................................................................................
(3)
(b) The equation for the combustion of ethanol in air is:

C2 H5OH (l) + 3O2 (g) → 2CO2 (g) + 3H2 O (l)

and the structural representation of this is:

H H

H C C O H + 3O O 2O C O + 3H O H

H H

(i) Calculate the enthalpy change for this reaction using the average bond enthalpy
values given below.

Average bond Average bond

Bond Bond
enthalpy / kJ mol-1 enthalpy / kJ mol-1

C-H +412 C-C +348

C-O +360 O-H +463

O=O +496 C=O +743

(3)

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(ii) Draw and label a reaction profile for this reaction.

Enthalpy

(3)

Total 9 marks
TOTAL FOR PAPER: 60 MARKS

END

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BLANK PAGE

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Centre Surname Initial(s)
Paper Reference (complete below)
No.
Candidate Signature
No. /
Paper Reference(s) Examiner’s use only

6243.02
Edexcel GCE Team Leader’s use only

Chemistry
Advanced Subsidiary
Unit Test C3B Question Leave
Number Blank
Specimen Paper
1

Time: 1 hour 2

4
Materials required for examination Items included with question papers
Nil Nil

Instructions to Candidates
In the boxes above, write your Centre Number and Candidate Number, the Paper Reference,
your surname, initial(s) and signature.
The paper reference is shown above.
Answer ALL the questions in the spaces provided in this question paper.
Show all the steps in any calculations and state the units.
You may use a calculator.

Information for Candidates

The total mark for this paper is 50. The marks for the various parts of questions are shown in
round brackets, e.g. (2).
A Periodic Table is printed on the back cover of this booklet.

Advice to Candidates
You are reminded of the importance of clear English and careful presentation in your answers.

Total

Turn over
Printer’s Log No.
-----/-----
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23
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1. (a) The observations made when tests were carried out on a white solid compound X are blank
shown in the table. X contains one metal ion and one anion.

Give the inferences, which follow the observations by completing the statements in the
spaces in the table.
(i) A flame test was carried out on X.

Observation Inference

A lilac flame. The metal ion is ……………………………

(1)
(ii) A sample of X was heated and the gas evolved tested.

Observation Inferences

The gas is ……………………………

A gas is given off which
relights a glowing spill.
X has the formula…………………….

(2)
(b) The observations made when tests were carried out on an aqueous solution, Y, are
shown in the tables below.

Give the inferences which follow the observations by completing the statements in
the tables.

(i) Powdered sodium hydrogen carbonate was added to Y in test tube. Any gas
evolved was tested.

Observations Inferences

Bubbles of gas evolved.

The gas is ……………………………
The gas turned
limewater cloudy.

Y contains …………………………. ions

(2)

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(ii) A few drops of aqueous barium chloride followed by dilute aqueous
hydrochloric acid was added to Y.

Observations Inferences

White precipitate which

The precipitate is ……………………………
does not dissolve in
dilute aqueous Y is aqueous………………………………….
hydrochloric acid.

(2)
(c) The organic compound Z has the structure:

CH2 CH CH CH3
OH

Complete the table below by writing the observations you would expect to make
when the tests described are carried out.

Tests Observations

Shake a few drops of Z

with bromine solution.

Add phosphorus
pentachloride to Z. Test
any gas evolved with
damp blue litmus.

Add aqueous potassium

dichromate acidified
with aqueous sulphuric
acid to Z and heat the
solution.

(6)
Total 13 marks

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2. A student was required to determine the enthalpy change for the reaction between iron
and copper sulphate solution.

The student produced the following account of their experiment.

A piece of iron, mass 3 g, was placed in a glass beaker. 50 cm3 of

0.5 mol dm-3 aqueous copper sulphate solution was measured using a
measuring cylinder and added to the beaker. The temperature of
the mixture was measured immediately before the addition and
every minute afterwards until no further change took place.

Fe + CuSO4 → FeSO4 + Cu

Timing Before 1 min 2 min 3 min 4 min 5 min

addition

Temperature / oC 22 27 29 26 24 22

(a) Suggest two improvements you would make to this experiment. Give a reason for
each of the improvements suggested.

Improvement 1.................................................................................................................

........................................................................................................................................

Reason 1...........................................................................................................................

........................................................................................................................................

Improvement 2.................................................................................................................

........................................................................................................................................

Reason 2...........................................................................................................................

........................................................................................................................................
(4)

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(b) In an improved version of the same experiment maximum temperature rise of 15.2o C
occurred when reacting excess iron with 50.0 cm3 of 0.500 mol dm-3 aqueous copper
sulphate solution.

(i) Using this data and taking the specific heat capacity of all aqueous solutions as
4.18 J g-1 deg-1 calculate the heat change.

(2)
(ii) Calculate the number of moles of copper sulphate used.

(1)
(iii) Calculate the enthalpy change of this reaction in kJ mol-1.

(2)
Total 9 marks

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3 1-bromobutane (boiling temperature 102 o C) may be prepared by the reaction shown in
the equation below.

C4 H9OH + NaBr + + H2 SO4 → C4 H9 Br + NaHSO4 + H2 O

The preparation is in three stages.
• Stage I: The reagents are heated for about 45 minutes in the apparatus shown in
Diagram 1.
• Stage II: Impure 1-bromobutane is extracted from the reaction mixture and transferred
to the round-bottomed flask in the apparatus shown in Diagram 2.
• Stage III: A sample of pure 1-bromobutane is obtained using the apparatus shown in
Diagram 2. The sample is weighed and the yield calculated.
(a) Give the names of the practical techniques carried out in the apparatus shown in
Diagrams 1 and 2.

Diagram 2

HEAT

Diagram 1

Diagram 1:......................................................................................................................

Diagram 2:......................................................................................................................
(2)
(b) (i) Explain why, in Stage I, the reactants are heated for such a long time.

........................................................................................................................................

........................................................................................................................................
(1)

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(ii) Explain the purpose and arrangement of the condenser in diagram 1.

.................................................................................................................................

.................................................................................................................................
(2)
(c) Briefly describe how you would use the apparatus shown in diagram 2 to give a
sample of pure 1-bromobutane.

........................................................................................................................................

........................................................................................................................................
(3)
(d) A student preparing 1-bromobutane by this method calculated that the maximum
yield in this preparation was 7.2 g. His actual yield was 3.1 g.

(i) Calculate the percentage yield.

(2)
(ii) Suggest two reasons why the actual yield was much lower than the maximum
yield.
Reason 1:.................................................................................................................

.................................................................................................................................

Reason 2: ................................................................................................................

.................................................................................................................................
(2)

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(e) A few drops of 1-bromobutane were added to 2 cm3 of ethanol in a test tube followed
by 5 cm3 of aqueous silver nitrate. The mixture was warmed in a water bath for a few
minutes. The 1-bromobutane was hydrolysed and a cream precipitate formed.

(i) Give the formula of the precipitate.

.................................................................................................................................
(1)
(ii) Suggest why ethanol was used in the experiment.

.................................................................................................................................
(1)
(iii) Suggest a reason for the use of a water bath.

.................................................................................................................................

.................................................................................................................................
(1)
Total 15 marks

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4.(a) In an experiment to standardise an aqueous solution of sodium hydroxide 0.25 g of blank
solid sulphamic acid, NH2 SO3 H, was dissolved in distilled water in a conical flask.
When the aqueous sodium hydroxide was run into the flask from a burette 23.45 cm3
was required to exactly react with the sulphuric acid solution. The equation for the
reaction is:

NH2 SO3 H(aq) + NaOH(aq) → NH2 SO3 Na(aq) + H2 O(l)

(i) Calculate the amount (number of moles) of sulphuric acid in 0.25 g.

Mr (NH2 SO3 H) = 97.0

(1)
(ii) State the amount (number of moles) of sodium hydroxide in 23.45 cm3 of
solution and hence calculate the concentration of the solution in mol dm-3.

(3)

(b) The balance used to weigh the sulphamic acid is accurate to ± 0.01 g. Calculate the
percentage error in the mass of the sulphamic acid weighed.

(1)

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(c) An alternative method to that described in (a) involves making an aqueous solution blank
of sulphamic acid of accurately known concentration.

Describe a procedure by which you would prepare 250 cm3 of aqueous sulphamic
acid of accurately known concentration. Assume that you are provided with a
weighing bottle containing between 2.40 g and 2.50 g of sulphamic acid and that this
is a suitable mass to use.

In your answer give full practical details inc luding the name of each piece of
apparatus used, how each would be prepared for the procedure and how you would
calculate the concentration (in mol dm-3) of the sulphamic acid solution. State, with a
reason, one appropriate safety precaution that should be taken.

........................................................................................................................................

........................................................................................................................................
(8)
Total 13 marks

TOTAL FOR PAPER: 50 MARKS

END

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Centre Surname Initial(s)
Paper Reference (complete below)
No.
Candidate Signature
No. /
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6244.01
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Chemistry
Advanced Level
Unit Test C4 Question Leave
Number Blank

Specimen Paper 1

Time: 1 hour 30 minutes 3

4
Materials required for examination Items included with question papers
None None
5

Instructions to Candidates
In the boxes above, write your Centre Number and Candidate Number, the Paper
Reference, your surname, initial(s) and signature.
The paper reference is shown above.
Answer ALL the questions in the spaces provided in this question paper.
Show all the steps in any calculations and state the units. You may use a calculator.

Information for Candidates

The total mark for this paper is 75. The marks for the various questions are shown in
round brackets: e.g. (2).
A Periodic Table is printed on the back of this booklet.

Advice to Candidates
You are reminded of the importance of clear English and careful presentation in your
Total
answers.

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Printer’s Log No.

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1. The formation of magnesium chloride from magnesium and chlorine may be represented
by the following Born- Haber cycle:

Mg2+ (g) + 2Cl - (g) + 2e-

Mg2+ (g) + 2Cl - (g)

Mg2+ (g) + Cl 2 (g) + 2e-

Mg (g) + Cl 2 (g)

Mg (s) + Cl 2 (g)

MgCl2 (s)

(a) Define the terms:

(i) Lattice energy.

.................................................................................................................................

.................................................................................................................................
(3)
(ii) Enthalpy of atomisation.

.................................................................................................................................

.................................................................................................................................
(2)

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(b) (i) Identify on the diagram the changes representing the enthalpy of atomisation of
magnesium.
(1)
(ii) Use the data below to calculate the first electron affinity of chlorine.

Value of the enthalpy change

Enthalpy change
/ kJ mol-1

Enthalpy of atomisation of magnesium +150

1st ionisation energy of magnesium +736

2nd ionisation energy of magnesium +1450

Enthalpy of formation of magnesium chloride -642

Enthalpy of atomisation of chlorine +121

Lattice energy of magnesium chloride -2493

(2)
(c) Hydrogen gas reacts with sodium metal to form an ionic solid, NaH, which contains
sodium cations. Draw a Born–Haber cycle which could be used to determine the
electron affinity of hydrogen.

(3)
Total 11 marks

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2. (a) (i) Give the structural formula of a nitrile, C4 H7 N, that has an unbranched chain. blank

(1)
(ii) Primary amines can be made by reducing nitriles. Suggest a reagent that could
be used for this purpose.

.................................................................................................................................
(1)
(iii) Draw the full structural formula of the amine produced by reducing the nitrile
given in (a)(i).

(1)
(b) Draw the structure of an isomer of C4 H11 N, which has a chiral centre in the
molecule, and identify the chiral centre.

(2)
(c) (i) What feature of an amine molecule make it both a base and a nucleophile?

.................................................................................................................................
(1)
(ii) Give, by writing an equation, an example of an amine acting as a base.

.................................................................................................................................
(1)
(d) Ethanoyl chloride, CH3 COCl, reacts with both amines and alcohols.

(i) Give the name of the type of compound produced when ethanoyl chloride reacts
with ethylamine, C2 H5 NH2 .

.................................................................................................................................
(1)

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(ii) State one of the advantages of reacting ethanoyl chloride with ethanol to make an
ester rather than reacting ethanoic acid with ethanol.

.................................................................................................................................

.................................................................................................................................
(1)
(e) Ethanoyl chloride can be made from ethanoic acid. Suggest a reagent suitable for this
conversion.

.................................................................................................................................
(1)
(f) Suggest how chloromethane can be converted into ethanoic acid via a Grignard
reagent. (Details of the experimental apparatus are not required.)

.................................................................................................................................

.................................................................................................................................
(4)
Total 14 marks

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3. (a) From the compounds of the elements in Group 4 of the Periodic Table, carbon to blank
lead, give the formula of:

(i) an acidic oxide; .........................................................................................................

(ii) an oxide which can behave as a base........................................................................

(2)
(b) Aluminium hydroxide is an amphoteric hydroxide.

(i) What is meant by the term amphoteric?

.................................................................................................................................

.................................................................................................................................
(1)
(ii) Write ionic equations which show the amphoteric behaviour of aluminium
hydroxide.

.................................................................................................................................

.................................................................................................................................
(3)
(c) Sodium chloride dissolves in water to give a neutral solution; phosphorus
pentachloride reacts with water to give an acidic solution. Interpret this information
in terms of the bonding in the compounds, giving equations where appropriate.
........................................................................................................................................

........................................................................................................................................

........................................................................................................................................
(4)

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(d) (i) State what happens when carbon tetrachloride is added to water. blank

.................................................................................................................................
(1)
(ii) State what happens when silicon tetrachloride is added to water.

.................................................................................................................................

.................................................................................................................................
(2)
(iii) Explain why carbon tetrachloride and silicon tetrachloride behave in different
ways when added to water.

.................................................................................................................................

.................................................................................................................................
(4)
Total 17 marks

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4. (a) Methane reacts with steam in a reversible reaction. In industry this reaction, carried blank
out at a pressure of 30 atm, is used to produce hydrogen for the manufacture of
ammonia.

CH4 (g) + H2 O(g) O(g) + 3H2 (g) ∆H = +210 kJ mol-1

(i) Define the term partial pressure as applied to a gas.

.................................................................................................................................

.................................................................................................................................
(1)
(ii) Write an expression for the equilibrium constant, Kp , for this reaction.

(1)
(iii) State and explain the effect of increasing the total pressure on the position of this
equilibrium.

.................................................................................................................................

(2)
(b) State the effect on the value of Kp for this equilibrium of the following.

(i) Increasing the total pressure.

.................................................................................................................................

(1)
(ii) Increasing the temperature.

.................................................................................................................................

(1)
(iii) Adding a catalyst.

.................................................................................................................................
(1)

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(c) There is a theory that methane, CH4 , constantly leaks from the earth’s crust. This is blank
not noticeable on land but at the bottom of a cold sea, such as off the Canadian coast,
the methane is trapped in a solid cage of water molecules.

CH4 (g) + 6H2 O (s) [CH4 (H2 O)6 ] (s)

methane hydrate

At –29 ºC the equilibrium pressure of the methane is 101.3 kPa.

(i) Write an expression for Kp for this equilibrium.

(1)
(ii) Calculate the value of Kp at –29 ºC stating its units.

(1)
(iii) At 0 ºC the equilibrium pressure of methane rises to 2600 kPa. What does this
tell you about the effect of temperature change on position of equilibrium and
about the enthalpy change for this reaction?

.................................................................................................................................

.................................................................................................................................
(2)
Total 11 marks

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5 Ethanoic acid, CH3 COOH, is a weak acid which can be used, with its salts, to make
buffer solutions.

(a) Explain what is meant by the terms weak and acid, in this context.

..................................................................................................................................

..................................................................................................................................
(2)
(b) Explain what is meant by the term buffer solution.

.................................................................................................................................

.................................................................................................................................
(2)
-3
(c) An aqueous solution of ethanoic acid of concentration 1.00 mol dm has a pH of
2.8. Sketch, with care, how the pH changes during the titration of 25.0 cm3 of
1.00 mol dm-3 aqueous ethanoic acid with aqueous sodium hydroxide of the same
concentration.

pH 10

0 20
10 30 40 50
3
Volume of sodium hydroxide added / cm
(4)

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(d) Indicate on your sketch the portion of the curve where the mixture is behaving as a
buffer.
(1)
(e) (i) Write an expression for the dissociation constant, Ka, for ethanoic acid.

(1)
(ii) Explain how the pKa of ethanoic could be found from the graph.

.................................................................................................................................

.................................................................................................................................
(2)
(f) Suggest, with reasoning, whether methyl orange or phenolphthalein would be the
better indicator for this titration.

........................................................................................................................................

........................................................................................................................................
(3)
(g) Explain why, as the titration proceeds, the flask becomes warm but not as warm as it
would in similar titration using 1.00 mol dm-3 solutions of hydrochloric acid and
sodium hydroxide.

........................................................................................................................................

........................................................................................................................................
(3)

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-5 -3
(h) A different monobasic weak acid has a dissociation constant of 1.8 x 10 mol dm . blank

(i) Define pH.

.................................................................................................................................
(1)
(ii) Calculate the pH of a 1.00 mol dm-3 aqueous solution of this acid.

(3)
Total 22 marks
TOTAL FOR PAPER: 75 MARKS

END

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Centre Surname Initial(s)
Paper Reference (complete below)
No.
Candidate Signature
No. /
Paper Reference(s) Examiner’s use only

6245.01
Edexcel GCE Team Leader’s use only

Chemistry
Advanced Level
Unit Test C5 Question Leave
Number Blank
Specimen Paper
1

Time: 1 hour 30 minutes 2

4
Materials required for examination Items included with question papers
None None
5

Instructions to Candidates
In the boxes above, write your Centre Number and Candidate Number, your surname,
initial(s), signature and the paper reference..
Answer ALL questions in the spaces provided in this question paper
Show all the steps in any calculations and state the units.
You may use a calculator.

Information for Candidates

The total mark for this paper is 75. The marks for the various parts of questions are shown in
round brackets, e.g. (2).
A Periodic Table is printed on the back cover of this booklet.
Advice to Candidates
You are reminded of the importance of clear English and careful presentation in your answers.

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45
Leave
blank
1. In an experiment to determine the rate of the reaction between persulphate ions and
iodide ions in aqueous solution.

S2 O2-8 + 2I → 2SO2-4 + I2

The following data were obtained:

Concentration / mol dm-3 Initial rate/

mol dm-3 s-1
S2 O82- I-

0.100 0.100 0.36

0.200 0.100 0.72

0.200 0.200 1.44

(a) (i) Deduce the order of reaction with respect to each of the reagents and hence
write the equation for the reaction.
......................................................................................................................................

......................................................................................................................................

......................................................................................................................................
(3)
(ii) With reference to this reaction state what is meant by the overall order of a
reaction.
....................................................................................................................................

....................................................................................................................................
(1)
(iii) Calculate the rate constant including units.

(2)
(iv) Explain why the rate equation cannot be written directly from the stoichiometric
equation for the reaction.
..................................................................................................................................

..................................................................................................................................
(1)

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(b) (i) Suggest a suitable experimental technique that would enable you to determine the
rate of the reaction given opposite.

...................................................................................................................................

...................................................................................................................................
(1)
(ii) Suggest a necessary condition that would help to ensure accurate results.

...................................................................................................................................
(1)
(iii) Suggest one advantage or disadvantage of your chosen experimental method.

...................................................................................................................................

...................................................................................................................................
(1)
Total 10 marks

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2. Alkenes undergo electrophilic addition whereas arenes, such as benzene, undergo blank
electrophilic substitution.

(a) What is an electrophile?

........................................................................................................................................
(1)
(b) Propene, CH3 CH=CH2 , reacts with HBr to give CH3 CHBrCH3 as the major product.

(i) What is the name of the compound CH3 CHBrCH3 ?

........................................................................................................................................
(1)
(ii) Give the mechanism for the reaction.

(3)
(iii) Explain why the major product is CH3 CHBrCH3 rather than CH3 CH2 CH2 Br.

......................................................................................................................................

......................................................................................................................................
(2)

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(c) Benzene C6 H6 reacts with CH3 Br to give C6 H5 CH3 .

(i) What catalyst may be used in this reaction?

........................................................................................................................................
(1)
(ii) Give the mechanism for the reaction. You should include the step that forms the
electrophile.

(4)
(d) Explain in terms of structure and bonding why benzene and propene react differently
with electrophiles.

........................................................................................................................................

........................................................................................................................................
(4)
Total 16 marks

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3. The following standard electrode potentials will be required in answering this question. blank

Eo /V
-0.76
Zn2+ + 2e- Zn
-0.26
V3+ + e- V2+
+0.17
SO42- + 2e- + 2H+ SO32- + H2O
+0.34
VO2+ + 2H+ + e- V3+ + H2 O
+1.00
VO2 + + 2H+ + e- VO2+ + H2 O

(a) Give the colours of the following ions:

VO2 + VO2+

V3+ V2+
(2)
+ 2+
(b) (i) Derive the overall equation for the reduction of VO 2 to VO by zinc in
acidic solution.

..............................................................................................................................

..............................................................................................................................
(2)
+
(ii) Give the formula of the vanadium species that would result if VO 2 ions were
to be reduced by sulphite ions, SO3 2-. Explain your answer using suitable Eº
values.
..............................................................................................................................

..............................................................................................................................

..............................................................................................................................
(3)

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(c) Disproportionation requires an element to have at least three oxidation states.

(i) Explain why this is so.

.............................................................................................................................

.............................................................................................................................
(1)
(ii) Derive an equation for the disproportionation of VO 2+ into VO 2 + and V3+.

..............................................................................................................................

..............................................................................................................................
(2)
Total 10 marks

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4. (a) Complete the electronic structure of a scandium atom, a copper atom and a Cu 2+ blank
ion.

3d 4s
Sc [Ar]

Cu [Ar]

Cu2+ [Ar]

(3)
(b) Both scandium and copper are d-block elements, but only copper is a transition
element. Explain the meaning of these two terms.

........................................................................................................................................

........................................................................................................................................
(2)
(c) Cu2+ exists in aqueous solution as the ion [Cu (H2 O6 )]2+.

(i) Give the name of the [Cu (H2 O6 )]2+ ion.

.................................................................................................................................
(1)
(ii) Draw the [Cu (H2 O)6 ]2+ ion so as to clearly show its shape.

(1)

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(iii) Explain the origin of the colour in [Cu (H2 O)6 ]2+ .

........................................................................................................................................

........................................................................................................................................
(3)
(d) (i) State what you would see if aqueous sodium hydroxide was added drop by drop
to a solution of [Cu (H2 O)6 ]2+ until the sodium hydroxide was in excess.

......................................................................................................................................

......................................................................................................................................
(2)
(ii) What type of reaction is occurring in (i)?

...................................................................................................................................

...................................................................................................................................
(1)

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(e) Pure copper is needed for electrical purposes. The purity of a sample of copper can
be found by reacting it with concentrated nitric acid, neutralising the resulting
solution and treating it with excess potassium iodide. Iodine is liberated and this can
be titrated with standard sodium thiosulphate solution. The reactions are:

Cu (s) + 4HNO3 (l) → Cu(NO3 )2 (aq) + 2NO2 (g) + 2H2 O(l)

2Cu2+(aq) + 4I-(aq) → 2CuI(s) + I2 (aq)

A copper foil electrode from an electric cell weighs 1.74 g. It was made into 250 cm3
of a solution of copper(II) ions. To 25.0 cm3 of this solution excess iodide ions were
added, and the mixture titrated with 0.100 mol dm-3 sodium thiosulphate solution. On
average 26.8 cm3 was required. Calculate the percentage purity of the copper foil.

(6)
Total 19 marks

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BLANK PAGE

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5. Consider the following reaction scheme: blank

step 1 step 2
C2H5Br C2H5MgBr C2H5COOH

PCl5
Room temperature

AlCl3 LiAlH4 , dry ether C9H12O

C3H5OCl C9H10O
A Benzene B C

(a) Give the reagents and conditions necessary for:

(i) step 1........................................................................................................................

(ii) step 2........................................................................................................................

(4)
(b) (i) State and explain one specific safety precaution necessary in performing step1.

.................................................................................................................................

.................................................................................................................................
(2)
(ii) Draw the apparatus that you would use for performing step 1.

(4)

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(c) Give the equation for the reaction between propanoic acid and phosphorus blank
pentachloride, making clear the structure of compound A.

(2)
(d) Compound B reacts with 2,4-dinitrophenylhydrazine but not with ammoniacal silver
nitrate solution. Give the structural formula for compound B and explain why B
reacts with 2,4- dinitrophenylhydrazine but not with ammoniacal silver nitrate.

........................................................................................................................................

........................................................................................................................................
(3)
(e) (i) Give the structural formula for C.

(1)
(ii) State why the ether solvent must be dry in the conversion of B to C.

..................................................................................................................................

..................................................................................................................................
(1)

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(f) The infra red spectra of B and of C are given below, together with a table of infrared
absorbencies.

Compound B:

Compound C:

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Infrared absorbencies.

Bond Assignment Wavenumbers / cm-1

Alkanes 2850-2950
C-H
Alkenes, arenes 3000-3100
C=C Alkenes 1610-1680

Benzene Ring Arenes 1450-1650

Aldehydes, ketones, amides 1680-1750
C=O
Esters, carboxylic acids
Free 3580-3670
O-H
Hydrogen bonded in 3230-3550
alcohols or phenols

Hydrogen bonded in 2500-3300

carboxylic acids

What is the evidence from these spectra for the conversion of the functional group in
B to that in C?

........................................................................................................................................

........................................................................................................................................
(3)
Total 20 marks

TOTAL FOR PAPER: 75 MARKS

END

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Centre Surname Initial(s)
Paper Reference (complete below)
No.
Candidate Signature
No. /
Paper Reference(s)

6246 B.02
Edexcel GCE
Chemistry
Advanced Level
Unit Test C6B (Synoptic)
Specimen Paper
Time: 1 hour 30 minutes

Materials required for examination Items included with question papers

Answer Book (AB8) None
Additional Answer Sheet (ASLi)
Graph Paper (ASG2)

Instructions to Candidates
Answer Section A plus any TWO questions from Section B in the answer book provided.
Complete the front cover of the answer book.
Show all the steps in any calculations and state the units. You may use a calculator

Information for Candidates

The total mark for this paper is 50. The marks for the various parts of questions are shown in
round brackets, e.g. (2).
A Periodic Table is printed on the back cover of this booklet.

Advice to Candidates
You must ensure that the answers to parts of questions are clearly numbered.
You are reminded of the importance of clear English and careful presentation in your answers.

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61
SECTION A

1. (a) One method of preparing ethyl ethanoate (boiling temperature 77 o C) includes the
following steps:

• ethanoic acid and ethanol are heated under reflux for about 40 minutes in the
presence of a little concentrated sulphuric acid;

• the reaction mixture is then distilled, everything boiling below 85ºC being
collected;

• the distillate is shaken with 30% aqueous sodium carbonate solution;

• the organic product is treated with anhydrous sodium sulphate or calcium

chloride;

• the organic product is redistilled, the liquid boiling between 76ºC and 80ºC being
collected.

Give the reasons for each of these procedures. Include in your answer a diagram of
the apparatus for heating under reflux.
(8)
(b) Ethyl ethanoate can also be prepared using the reaction of ethanol with ethanoyl
chloride. Suggest with reasons two advantages and one disadvantage of using this
method compared to the method in (a).
(3)
(c) Propylmethanoate, HCOOC3 H7 , is an isomer of ethyl ethanoate.
Suggest with reasoning, whether it is possible to distinguish between these two
compounds using low resolution n.m.r.
(3)

TOTAL FOR SECTION A: 14 MARKS

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Section B

Answer TWO questions from this section.

2. (a) The covalent compound urea, (NH2 )2 C=O, is commonly used as fertiliser in most of the
European Union whereas in the UK the most popular fertiliser is ionic ammonium
nitrate, NH4 NO3 . Apart from the nitrogen content, suggest two advantages of using urea
as a fertiliser compared with using ammonium nitrate.
(2)
(b) The ammonium ion in water has an acid dissociation constant, Ka = 5.62 x 10-10 mol
dm-3. The conjugate acid of urea has Ka = 0.66 mol dm-3. Use this data to explain which
of ammonia or urea is the stronger base.
(2)
(c) Ethanamide, CH3 CONH2 , can be converted into methylamine, CH3 NH2 .
(i) State the reagents and conditions for carrying out the conversion.
(3)
(ii) Suggest the formula of the likely product if urea were used instead of
ethanamide in this conversion.
(1)
(d) With gentle heating ammonium nitrate volatilises reversibly.

NH4 NO3 (s) NH3 (g) + NHO 3 (g) ∆H = +171kJ mol-1

(i) State why the expression for Kp for the reversible change does not include
ammonium nitrate.
(1)
(ii) 8.00 g of ammonium nitrate was gently heated in a sealed vessel until
equilibrium was reached. The equilibrium constant was found to be 15.7 atm2
under these conditions. Calculate the partial pressure of ammonia present at
equilibrium and, hence, the percentage of the ammonium nitrate which has
dissociated.
(One mole of gas under these conditions exerts a pressure of 50 atm).
(5)
(e) Ammonium nitrate can explode when heated strongly.

NH4 NO3 (l) → N2 O(g) + 2H2 O(g) ∆H = -23 kJ mol-1

Explain the concepts of thermodynamic and kinetic stability with reference to this
reaction.
(4)
Total 18 marks

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3.(a) (i) Use the idea of electronegativity to explain the nature of the bonding in sodium
chloride.
(3)
(ii) Aluminium ions have a radius of 0.053 nm compared with that for the sodium ion
of 0.102nm. Suggest why, as a result of this difference, aluminium chloride is
covalent rather than ionic.
(2)
(b) Argon does not have a chloride; explain in terms of the energy changes that would be
needed to form an ionic chloride why this is so.
(3)
(c) (i) Phosphorus pentachloride is made by the action of excess chlorine gas on white
phosphorus, P4 . Give an equation to represent this reaction.
(2)
(ii) Phosphorus pentachloride decomposes on heating just above its sublimation
temperature

PCl5 (g) → PCl3 (g) + Cl2 (g)

Explain whether or not this is a redox reaction.

(3)
(d) Some organic chlorine compounds are used in the manufacture of polyesters by
condensation polymerisation.
(i) Give an example of a polyester structure and the structures of suitable reagents
that could give rise to the polyester shown.
(3)
(ii) Use the examples given in (i) to explain the term condensation polymerisation.
(2)

Total 18 marks

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4. (a) One of the early rocket fuels was hydrazine, H2 NNH2.
(i) Draw a ‘dot-and-cross’ diagram to show the electronic structure of a hydrazine
molecule.
(1)
(ii) Deduce the value for the HNH bond angle in a hydrazine molecule. Explain your
reasoning.
(3)
(b) Hydrazine burns in oxygen as follows:
H2 N-NH2 + (g) + O2 → N2 (g) + 2H2 O (g)

When 1.00 kg of hydrazine is burnt in excess oxygen 1.83 x 104 kJ of heat energy is
released.

Use this and the average bond enthalpies below to calculate the N-N bond enthalpy.

Bond enthalpy/ Bond enthalpy/

Bond Bond
kJ mol-1 kJ mol-1
N-H +388 O=O +496

N=N +944 H-O +463

(4)
(c) Hydrazine is a powerful reducing agent in alkaline solution. It is oxidised to nitrogen
gas and water.
Vanadium exists in several oxidation states and some of its reduction potentials are
listed below.

VO2+ (aq) + H2 O(l) + e- V3+ (aq) + 2OH-(aq) Eo = -1.32 V

VO2+ (aq) + H2 O(l) + e- VO2+ (aq) + 2OH-(aq) Eo = -0.66 V

(i) Deduce the ionic half equation for the oxidation of hydrazine in alkaline solution.

(2)
(ii) Hydrazine will reduce vanadium (V) but not vanadium (IV). What does this tell
you about the value of the electrode potential for the reaction that you have
written in (c)(i)?
(1)
(iii)Write the overall ionic equation for the reduction of vanadium(V) ions by
hydrazine in alkaline solution.
(2)

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(d) Hydrazine reacts with carbonyl compounds in a similar way to
2, 4- dinitrophenylhydrazine.

(i) Write an equation for the reaction of hydrazine with propanol showing clearly the
structure of the organic product.
(2)
(ii) The organic product in (i) can exist as stereoisomers. Identify the type of
stereoisomerism shown and explain why it arises in this compound.
(3)
Total 18 marks

TOTAL FOR SECTION B: 36 MARKS

END

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Paper Reference (complete below)
No.
Candidate Signature
No. /
Paper Reference(s) Examiner’s use only

6243.01A
Team Leader’s use only
Edexcel GCE
Chemistry
Advanced Subsidiary Question Leave
Number Blank
Unit Test C3A
1
Specimen Paper
2
Time: 1 hour 45 minutes
3

4
Materials required for examination Items included with question papers
See the Confidential Instructions None
already issued to centres,
relating to this practical test.

Calculators and any notes or textbooks may be used during this test.

Instructions to Candidates
In the boxes above, write your centre number, candidate number, surname and
initials, the paper reference and your signature. The paper reference is shown above.
Answer ALL questions in the spaces provided in this book.

Information for Candidates

The total mark for this paper is 50. The marks for the various questions are shown in
round brackets: e.g. (2).

Advice to Candidates
You are reminded that you should take all the usual safety precautions when
working in a chemistry laboratory.

Total

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69
This test is divided into four questions. Leave
blank

In Question 1 you are required to carry out a series of qualitative reactions to identify a
Group 1 salt. (9 marks)
In Question 2 you are required to carry out a quantitative exercise to identify a Group 1
metal, M, in its hydrocarbonate, MHCO3 . (21 marks)
In Question 3 you are required to carry out a quantitative exercise to find the enthalpy
change when a Group 1 compound, Z, dissolves in water. (13 marks)
In Question 4 you are required to plan an experiment investigating a reaction involving a
Group 1 hydrocarbonate, MHCO3 . (7 marks)

Question 1

Identification of a Group 1 salt.

You are provided wit h about 1 g of a Group 1 salt, W, which contains one cation and one
anion.

Carry out the following tests on, W, recording your observations and inferences in the
spaces provided.

(a) Add a few drops of dilute, aqueous hydrochloric acid to about half of the sample of W,
on a watch glass. Carry out a flame test on the solution. In your inference identify the
cation.

Observation Inference

(2)
3
(b) Dissolve the remaining sample of W in about 6 cm of distilled water. Use half of this
solution for each of the following tests.

(i) Add 3 drops of aqueous silver nitrate followed by about 3 cm3 of dilute, aqueous
ammonia.

Observations Inferences

(3)

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(ii) Add 6 drops of dilute, aqueous hydrochloric acid followed by 6 drops of aqueous
chlorine. Include in your inferences a suggested formula for W. Leave
blank

Observations Inferences

(2)

(iii) Give the name and reagent that reacts with solid W and would confirm the
identity of the anion in W. Describe the observation you would expect to make.

Reagent .....................................................................................................................

Observation...............................................................................................................

.................................................................................................................................
(2)

(Total 9 marks)

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Question 2
Leave
Quantitative exercise to identify a Group 1 metal in its hydrocarbonate. blank

You are provided with:

• Solution X, aqueous MHCO3 of concentration 8.00 g dm-3; where M is a group 1

metal;
• Solution Y, aqueous sulphuric acid of concentration 0.050 mol dm-3.
• Methyl orange indicator.

You are required to titrate portions of the solution, X, with solution Y.

2MHCO3 (aq) + H2 SO4 (aq) → M2 SO4 (aq) + 2CO2 (g) + 2H2 O(l)

PROCEDURE
1. Rinse out, then fill, the burette with solution Y.
2. Rinse out the pipette with solution X. Transfer 25.0 cm3 of solution X to a conical flask.
Add 4 drops of methyl orange to the conical flask.
3. Titrate solution X with solution Y until the solution in the end-point is reached.
4. Record your burette readings in Table 1.
5. Repeat the procedure and attempt to obtain two titres that differ by no more than
0.20 cm3 . Record all your burette readings in Table 1.

Table 1
1 2 3 4 5
Burette reading
(final)
Burette reading
(initial)
Titre / cm3

List the numbers of the titrations that you will use to calculate the mean (or average) titre.

Calculate a mean titre.

Write the value of your mean titre in the space below.

……………..cm3 of solution Y reacts with 25.0 cm3 of solution X.

(14)

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Calculations and questions. Leave
blank
(a) Calculate the amount (number of moles) of sulphuric acid in the mean titre.

(1)
(b) Calculate the amount (number of moles) of MHCO3 in 25.0 cm3 of solution
X.

(1)

(c) Calculate the concentration of MHCO3 in solution X in mol dm-3. Use this value to
calculate the relative molecular mass of MHCO3 and then identify M.

(Relative atomic mass: H=1, Li=7, C=12, O=16, Na=23, K=39, Rb=85, Cs=133.)

(3)
(d) When properly used, the pipette used in the experiment will deliver a volume of
solution X within 0.5 % of 25.0 cm3 . Suggest two techniques which a student should
follow when using the pipette to ensure that the volume delivered is within 0.5 % of
25 cm3 .

Technique 1 ......................................................................................................................

........................................................................................................................................

Technique 2 ......................................................................................................................

........................................................................................................................................
(2)
(Total 21 marks)

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Question 3
Leave
Quantitative exercise to find the enthalpy change when a Group 1 compound dissolves blank
in water.

You are provided with:

• a sample of a Group 1 compound, Z, in a specimen tube.

You are required to find the molar enthalpy change when Z dissolves in water.

Z(s) + aq → Z(aq)

PROCEDURE
1. Rinse out a 50 cm3 measuring cylinder with distilled water, then use the measuring
cylinder to measure 50 cm3 of distilled water into a dry plastic cup held firmly in a beaker.
Place the thermometer in the distilled water in the cup.
2. Weigh the specimen tube containing Z. Record the mass of the tube and Z in Table 2.
3. Measure the temperature of the distilled water in the cup to the nearest 0.2 °C. Record the
temperature in Table 3.
4. Empty the sample of Z from the specimen tube into the plastic cup, stirring gently with the
thermometer. (The accuracy of your results will not be affected if a small amount of X is
left in the tube.) Continue stirring until all of the solid has been dissolved then record the
steady temperature of the solution to the nearest 0.2 °C. Record the temperature in Table
3.
5. Weigh the emptied tube and record the mass in Table 2.

Table 2

Mass of specimen tube + Z g

Mass of emptied specimen tube g

Mass of Z used g

(2)

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Table 3 Leave
blank
o
Temperature of distilled water before adding Z, T1 C
o
Steady temperature of solution, T2 C

Calculate the change in temperature, ∆T, by subtracting T1 from T2 .

∆T=T2 – T1 = …………………………….. =……………… o C

(6)

Calculations and questions

(a) Calculate the molar enthalpy change when Z dissolves in water using the formula.

21.1 x ∆T
∆H = − kJ mol-1
Mass of Z used

Include a sign and units with your value of ∆H which should be expressed to an
appropriate number of significant figures.

∆H=

(3)
(b) Suggest a change to the procedure, using the same apparatus that may lead to a more
accurate value of the molar enthalpy change. Explain the reason for your suggestion.

........................................................................................................................................

........................................................................................................................................
(2)
(Total 13 marks)

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Question 4
Leave
blank
Planning an experiment to find the relative molecular mass of a Group 1
hydrogencarbonate.

When a solid group 1 hydrogencarbonate reacts with dilute, aqueous sulphuric acid carbon
dioxide is evolved.

2MHCO3 (s) + H2 SO4 → M2 SO4 (aq) + 2CO2 (g) + 2H2 O(l)

You are required to plan an experiment using the apparatus shown below, the results of
which may be used to calculate the relative molecular mass of the hydrogencarbonate and
identify M. Assume that you are provided with a sample of the hydrogencarbonate and a
volume of acid (an excess); these will react to give a volume of carbon dioxide slighty less
than the capacity of the gas syringe.

You must include in your plan:

• The procedure and measurements you would take;

• Details of how the results would be used to calculate the relative molecular mass of the
hydrogencarbonate and identify M (but do not invent actual results);
• A discussion of the likely errors and the significance of these in identifying M;
• One safety measure and the reason for it.

You will need to make use of the fact that at the temperature of the experiment 1 mole of
carbon dioxide occupies a volume of 24.0 dm3 .
(Relative atomic mass: H=1, Li=7, C=12, O=16, Na=23, K=39, Rb=85, Cs=133.)

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........................................................................................................................................

........................................................................................................................................

(7)
(Total 7 marks)

TOTAL FOR PAPER: 50 MARKS

END

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Centre Surname Initial(s)
Paper Reference (complete below)
No.
Candidate Signature
No. /
Paper Reference(s) Examiner’s use only

6246.01A
Edexcel GCE Team Leader’s use only

Chemistry
Advanced Level
Unit Test C6A Question Leave
Number Blank
Specimen Paper
1

Time: 1 hour 45 minutes 2

4
Materials required for examination Items included with question papers
See Confidential Instructions already Nil
issued to centres relating to this practical
test.
Calculators and any notes or textbooks
may be used during this test

Instructions to Candidates
In the boxes above, write your centre number, candidate number, your surname, initial(s) and
signature and the paper reference number.
Answer ALL the questions in the spaces provided in this question paper.
Show all the steps in any calculations and state the units.

Information for Candidates

The total mark for this paper is 50. The marks for the various parts of questions are shown in round
brackets, e.g. (2).
You may use a calculator

Advice to Candidates
You are reminded that you should take all usual safety precautions when working in a chemistry
laboratory.

Total

Turn over
Printer’s Log No.
-----/-----
This publication may only be reproduced in accordance with Edexcel copyright policy.
Edexcel Foundation is a registered charity. © 2001 Edexcel

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79
This test is in four questions. You are required to:

In question 1 to carry out a series of tests on compound A in order to identify the

two cations and one anion in A. (16 marks)

In question 2 to carry out a series of tests on an organic compound B, C9 H8 O, in

order to suggest possible identities for B. (13 marks)

In question 3 to plan an exercise to confirm the identity of B. (8 marks)

In question 4 to measure the boiling temperature of the liquid product, C, of the

reduction of B. (13 marks)

Question 1
Tests on A

(a) (i) Add 3 cm3 of aqueous sodium hydroxide to a spatula measure of A in a test tube.
Gently warm the test tube. After removing the test tube from the Bunsen flame,
carefully smell any gas evolved. Carry out a simple test to confirm the identity of the
gas.

Observations Inferences

(3)

Dissolve the remaining sample of A in 10 cm3 of distilled water. Use this solution for
the tests which follow.

(ii) To 2 cm3 of aqueous A, add 6 drops of aqueous barium chloride followed by 10

drops of dilute hydrochloric acid.
Observations Inferences

(3)

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(iii) To 2 cm3 of aqueous A, add dilute aqueous ammonia drop by drop until the test tube
is about half full. The ammonia will then be in excess.
Observations Inferences

(3)

(iv) To 2 cm3 of aqueous A, add 10 drops of aqueous potassium iodide

followed by 6 drops of aqueous starch.
Observations Inferences

(3)

(v) Suggest the formulae of the two cations and one anion in A.

Cations ........................................ and .................................................

Anion .........................................................
(2)
(vi) Give the name of the type of reaction which occurs in (iv) when aqueous potassium
iodide is added to A. Write an ionic equation to represent the reaction.

Type of reaction ......................................………………………………………

Ionic equation ......................................................................................………...

(2)

(Total 16 marks)

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Question 2

Tests on B

(b) Carry out the tests listed below on the organic compound B, C9 H8 O. B has two
functional groups. Record the results of your tests in the ‘Observations’ spaces. Under
‘Inferences’ record the functional group, by name or formula, the presence of which may be
suggested by your observations. You are not expected to attempt to identify B in your
inferences.

(i) Using a dropping pipette, transfer 10 drops of B to a crucible. Carefully ignite B.

Observations Inferences

(2)

(ii) To 1 cm3 of B, add 8 drops of an aqueous solution of potassium manganate(VII)

acidified with dilute sulphuric acid. Stopper and gently shake the test tube.

Observations Inferences

(3)

(iii) To 2 cm3 of B, add 8 drops of aqueous bromine. Stopper and gently shake the test
tube.
Observations Inferences

(2)

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(iv) To 4 drops of B, add 2 cm3 of aqueous 2, 4−dinitrophenylhydrazine. Stopper and shake
the test tube gently.
Observations Inferences

(2)
(v) Mix 2 cm3 of each of Fehling’s solutions 1 and 2. Add 6 drops of B. Heat the
Test tube in a water bath at about 80 ºC.

Observations Inferences

(2)
(vi) On the evidence of the tests carried out write structures for two isomers of B.

Structure 1 Structure 2

(2)

(Total 13 marks)

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Question 3

If the product of the reaction that takes place in question 2 (b) (iv) is purified it may be
used to obtain information that would allow you to decide if B has either one of the
structures which you have drawn in (vi).

Devise an experimental procedure by which you could obtain this information. In your
answer, give the names of any practical techniques and materials that you plan to use.
Outline your planned procedure including any references to safety considerations involved
in the technique and the materials you will use. Explain how you would use the
information you obtain in an attempt to identify B.

You are not expected to carry out your planned procedure.

..........................................................................................................................….

..........................................................................................................................…..

.........................................................................................................................……
.
..........................................................................................................................…..

..........................................................................................................................…..

.........................................................................................................................….…

..........................................................................................................................……

...........................................................................................................................…..

............................................................................................................................….

...........................................................................................................................…..
(8)
(Total 8 marks)

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Question 4
In this part of the exercise you are to measure the boiling temperature of a liquid
C and use the data to identify C.

Procedure for measuring the boiling temperature of liquid C.

Thermometer

Sealed tube

Capillary tube

Ignition tube

Rubber ring

Oil

Liquid being tested

Stirrer

Gauze

Tripod

HEAT

Place liquid C in one of the clean dry ignition tubes to a depth of between 0.5 and
1.0 cm. Fix the tube to the side of the thermometer, with the liquid next to the
bulb, using one of the rubber rings. Clamp the thermometer with the bulb in the
oil as shown in the diagram above. Add a new capillary tube, sealed at one end, to
the liquid in the ignition tube with the open end below the surface.
As the oil is heated and the temperature of the liquid is raised, air in the capillary
tube expands and small bubbles slowly issue from the open end of the capillary
tube: when the liquid boils the stream of bubbles is rapid and continuous.
Heat the oil bath to about 70 ºC, then, whilst stirring, raise the temperature of the
oil by about 3 ºC per minute until the liquid in the ignition tube starts to boil. Stop
heating immediately and record the temperature of the oil in the results table
below. Continue to stir the oil as it cools and, as soon as bubbles cease to issue
from the capillary tube, record the temperature in the results table. The second
temperature is usually a more reliable figure for the boiling temperature than the
first one.

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Results table

Temperature Temperature
rising / o C falling / o C

Boiling temperature
of liquid C

Use the table of boiling temperatures below to decide the identity of compound C.

Name Structure Boiling Temp /

°C
Butan-1-ol CH3 CH2 CH2CH2 OH 117

Butan-2-ol CH3 CH2 CH(OH)CH3 99.5

2 methyl propan-1-ol CH3 CH(CH3 )CH2 OH 108

2 methyl propan-2-ol CH3 C(OH)(CH3 )CH3 82.5

(i) Identify C…………………………………………………………………….

(ii) Comment on the accuracy of the technique you used to find the boiling
temperature of C and suggest how a more accurate value could be found.
........................................................................................................................….

…………………………………………………………………………………

.......................................................................................................................….

…………………………………………………………………………………

(13)
(Total 13 marks)

TOTAL FOR PAPER: 50 MARKS

END

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Mark Scheme for Specimen Paper

Unit Test C1

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87
1 (a) (i) 2s22p63s23p4 (1) [1]
(ii) Protons = 16 (1) Neutrons = 18(1) [2]
(b) (i) • Energy change when 1 mole(1)
• Of gaseous atoms(1)
• Gains 1 electron per atom(1) [3]
(ii) • Electron and anion both negative(1)
• Repulsion occurs(1) [2]
Total 8 marks

2. (a) (i) electron configuration or 3d64s 2 or 4s2

or number of outer electrons (1) [1]

(ii) atoms of the same element (1) that have different

numbers of neutrons(1)
or
atoms with the same number of protons (1) but
different numbers of neutrons(1) [2]

(b) (i) A ionisation (not vaporisation)(1)

B acceleration(1)
C deflection(1)
D detection(1) [4]

(ii) (5.80 x 54) + (91.6 x 56) + (2.20 x 57) + (0.40 x 58) (1)
100
= 55.91(1) [2]
Total 9 marks
3 (a) (i) Mol of Ca used = 0.17/40 (1)
= 4.25 x 10-3
Volume of hydrogen produced =
4.25 x 10-3 x 24000 [2]
= 102 cm3 (1)

(ii) 4.25 x 10-3 x 6.0 x 1023 molecules [1]

= 2.55 x 1021 (1)
(b) Increases as group is descended(1) [1]
(c) (i) Ca(g) → Ca(g)+ + e -
1 mark for formulae and charges
1 mark for state symbols [2]
(ii) • Decreases as group is descended(1)
• Because although there is an increase in
nuclear charge(1)
• The electron being removed is further from
the nucleus(1)
• And more shielded from the nuclear charge(1) [4]
Total 10 marks

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4 (a) Cl
+
B +Cl
+ (1)
Cl

Must show all the outer electrons around

the chlorine
Do not have to be • and + [1]

(b) (i) Cl Cl
B
(1) [1]
Cl

(ii) The (three) bonding (electron) pairs (1)

repel as far apart as possible / position of [2]
minimum repulsion (1)

(c) (i) Power (of an atom) to attract (the pair of)

electrons (1)
in a covalent bond / bonding pair (1)
n.b. could answer question by comparing
the electronegativities of the B and Cl [2]

(ii) Bonds arranged symmetrically / molecule

symmetrical / bond polarities directional /
are vectors (1)
Bond polarities cancel (1)
[2]
Could be shown as a diagram
Total 8 marks

5 (a) (i) H2SO4: +6 / VI (1)

H2S: -2 (1)
SO2: +4 / IV (1) [3]

(ii) Iodide has greater reducing power (1)

reduces sulphur by more oxidation numbers
/ or correctly uses their numbers from part (i)
/ or an ‘electron gain’ type argument (1) [2]

(b) (i) 2Cl- → Cl2 + 2e- or Cl- → ½Cl2 + e -

or
2Cl- - 2e-→ Cl2 (1) [1]
(ii) OCl- + 2H+ + 2e- → Cl- + H 2O (2)
Or OCl- + 2H+ → Cl- + H 2O - 2e-
all species 1 mark, balancing 1 mark [2]

(iii) OCl- + 2H+ + Cl- → Cl2 + H 2O (1)

State symbols (1) [2]
Total 10 marks

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89
6 (a) (i) Sodium has one outer electron that is
delocalised into a sea of electrons others
have more (1).
Na+ smallest charge/ ion comparison of the
charges on the three ions (1)
Therefore weaker attraction between
sodium cation and delocalised electrons
hence lower melting temperature (1) [3]

(ii) Both held by van der Waals forces that

depends on the number of electrons (1)
P4 has less than S8 hence S 8 has a higher
melting temperature. (1) [2]

(b) (i) Structure - giant or macro + atomic /

molecular/ covalent (1)

Bonding - covalent (1) (ignore reference to

vdW)

Diagram - layers (1)

of flat hexagons (1)
(min of 2 hexagons correctly joined for the [4]
‘hexagon’ mark)

(ii) Structure – lattice / giant ionic / cubic (allow

face centred cubic) (1)

Bonding - Ionic (1)

Diagram – lattice of alternate clearly [3]

identified / Na+ and Cl- ions, must imply 3-D.
(1)

(c) (i) Delocalised or sea of electrons between

layers(1) [2]
Which can flow/move (1)

(ii) Ions (free to) move / mobile (in liquid state) [1]
(1)
Total 15 marks

Paper total 60 marks

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Mark Scheme for Specimen Paper

Unit Test C2

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91
1 (a) (i) any one from
concentration
pressure
surface area / particle size [1]

(ii) Pressure/ concentration:

Increase of pressure / concentration increases rate (1)
The particles are closer together therefore more
collisions / more collisions per unit volume per unit of
time (1)
Allow more ‘frequent’ collision

Or
Surface area:
Increase in surface area increase the rate (1)
More collisions on surface of solid /more surface available
for collisions (1) [2]

(b) (i) Similar curve with peak further to the right (1)
and lower maximum(1) [2]
Max 1 mark if second line crosses the first more than
once or crosses axis

(ii) vertical line placed to the right of both of the peaks (1) [1]

(iii) (At higher temperature average kinetic) energy of

molecules is greater (1)
More molecules / collisions have energy greater than /
equal to the activation energy (1)
∴more collisions are effective/ result in reactions (1) [3]

Total 9 marks

2 (a) Dynamic:
reaction occurring in both directions / rate of forward
reaction and reverse reactions equal (1)

Equilibrium:
constant concentrations / no change in macroscopic
properties (1) [2]

(b) (i) Higher yield of ammonia / (equilibrium position) moves

to. r.h.s (1)
Fewer product molecules (1) [2]

(ii) Lower yield of ammonia / (equilibrium position) moves to

l.h.s. (1)
since this absorbs heat/ shift in endothermic direction /
the reaction is exothermic (1) [2]

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(c) (i) 350 - 500°C / 623 – 773K [1]

(ii) High temp favours high rate (1) Or reverse argument

Low temp favours good yield (1)
Temperature used of 350-500°C compromise / balance
between yield and rate (1) [3]
consequential on first two points correct

(d) (i) Iron (not Fe) (1) [1]

ignore references to oxides

(ii) Provides alternative pathway / route

or
Explanation of what happens at the surface(1)
of lower activation energy (1) [2]
Second mark consequential on the first

Total 13 marks

3 (a) (i) HBr (name or formula) (1)

gas phase or inert / organic solvent (1) [2]

(ii) H H H
H C C C H
H Br H

Or CH3CHBrCH3 (1) [1]

H H H
(b) (i)
H C C C H
H OH H
Or CH3CH(OH)CH3 (1)
This mark is not consequential on (a)(ii) i.e. this is the [1]
only acceptable answer

(ii) electrophilic(1) addition (1)

nucleophilic (1) substitution/ hydrolysis (1) [4]
All marks stand alone in this part of the question

(c) Concentrated sulphuric acid / phosphoric acid /

aluminium oxide (1)
Heat/ 170oC for sulphuric acid / 70 oC for phosphoric acid
(1) [2]

(d) H H H
(1) [1]
H C C C H
H
Total 11 marks

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93
4 (a) Mr 2-bromobutane = 137 (1)
moles = 13.7/137 = 0.10 (1) allow 0.1
moles KOH = 9.0/56 = 0.16 (0.1607 or 0.161) (1)
KOH present in excess consequential (1) [4]

(b) lone pair donor / electron pair donor / lone or electron

pair can form co-ordinate / dative bond (1)
hydroxide ion / OH - (1) [2]

(c) rate increased (1)

C-I bond weaker (than C-Br bond) / lower bond energy
(1) [2]
Total 8 marks

5 (a) Group of compounds with the same general formula(1)

that
differ by –CH2 - (1)
Same or similar chemical properties / same functional [3]
group(1)

(b)
C H 3H CH3 H
C C C C
H H H H

At least one repeat unit and evidence of extension of [1]

chain(1)

(c) Different chain lengths / areas of crystalline and

amorphous structure (1) [1]

(d) (i) C-F bond strong/ high bond enthalpy/ bond not easily
broken/ steric hindrance by fluorines around carbon(1) [1]

(ii) Non-stick coatings e.g. in saucepans, in pipes, on skis,

stain-proofing of fabrics, waterproof clothing. (1) [1]

(e) Only single/ sigma bonds in ethane (1)

Allow saturated as an alternative to ‘only’, but types of
bonds must also be mentioned
Ethene also has π bond (1)
π bond weaker (and breaks) / electrons in π bond more [3]
accessible (1)
Total 10 marks

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6 (a) Enthalpy or heat change per mole (1)
For complete combustion (1)
At 1atm pressure and specified temperature (1) [3]

(b) (i) Bonds broken:

5C-H+C-O+O-H+3O=O = +4371 (1)
Bonds made:
4C=O + 6O-H = -5750 (1)
∆H = +4371-5750 = -1379 kJ mol-1 (1)
[3]
(ii) Exothermic (1)
Energy barrier (1) [3]
Fully labelled (1)

Total 9 marks

Paper total 60 marks

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Mark Scheme for Specimen Paper

Unit Test C3B

96
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1 (a) (i) Potassium / K + (1)
not K [1]

(ii) oxygen / O2 (1)

KNO3 / KClO3 / KO2 (1)
Do not allow K 2O [2]

(b) (i) carbon dioxide / CO2 (1)

hydrogen / H + / H 3O+ (1) [2]

(ii) barium sulphate / BaSO 4 (1)

sulphuric acid / H 2SO 4 (1) [2]

(c) Yellow / orange / brown (not red alone) (1)

to colourless / decolourised (1)

steamy fumes / steamy vapour / misty fumes (1)

litmus turns red (1) if candidates then go on to say the
litmus is bleached score zero for litmus test

orange (1) to green (1) [6]

Total 13 marks

2 (a) Note 1 mark for improvement 1 mark for related reason in each
case to max 4 marks. Reason must relate to improvement. Max 2
for improvement max. 2 for reason.

Improvement Insulate beaker/polystyrene cup/plastic cup/use lid (1)

Reason Prevents/ reduces heat loss or absorbs less heat (1)

Improvement Use pipette/ burette (1)

Reason More accurate (than measuring cylinder) (1)

Improvement Measure temperature for several minutes before the

addition (1)
Reason Allows more accurate value for the initial
temperature (1)

Improvement Measure temperature more often (1)

Reason Allows for better extrapolation/ more accurate
temperature change from graph (1)

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Improvement Read thermometer to 1dp /use more precise
thermometer/digital thermometer (1)
Reason Gives more accurate temperature change(1)

Improvement Stir mixture(1)

Reason Ensure even temperature/reaction faster less heat
loss with time(1)
Improvement Use finely divided iron/smaller pieces (1)
Reason Reaction faster less heat loss with time (1)
not speeds up alone
[4]

(b) (i) Heat change = 50.0 x 4.18 x 15.2J(1)

= 50.0 x 4.18 x 15.2 / 1000kJ
= 3.18kJ or 3180J (1)
Ignore sig. fig. Allow 1 mark for correct answer with no [2]
working
(ii) Number of mols of copper sulphate =
50.0 x 0.500 / 1000
= 0.025 (1) [1]

(iii) Enthalpy change per mol = 3.18/.025 = -127kJ(1)

negative sign (1)stand alone
consequential on (i) and (ii)
max. 4 sig. fig and answer must be in kJ mol-1 even if [2]
units omitted.
Total 9 marks

3 (a) diagram 1 (heating under) reflux (1)

diagram 2 distillation (1) allow fractional distillation [2]
(b) (i) reaction is slow / time needed for reaction to reach [1]
completion (1)

(ii) condenses vapours and returns liquid to flask / vapour

turns to liquid and returns to flask(1)
(it allows reaction at boiling point of reactants) without
loss / escape of material/reactants
prevents loss/escape of materials/reactants/products (1) [2]

(c) heat the mixture (slowly) (1)

collect only fraction/distillate (1)
produced at 102 °C / around 102 °C / between 100 -104°C
(1)
Need to make clear that only distillate at this [3]
temperature is collected e.g. rest discarded for second
mark

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(d) (i) 3.1 (1) x 100 = 43.1% (1) Allow 2-4 significant figures
7.2 [2]

(ii) two reasons from:

side reactions (1)
reaction incomplete (1) max [2]
product lost in purification / transfers (1)

(e) (i) AgBr (1) [1]

(ii) CH4H9Br + H 2O → C4H9 OH + H ++ Br-

CH3CH2CH2CH2Br + H 2O → CH3CH2CH2CH2OH + H++Br-

OH - + Br- (1) [1]

(iii) Reaction very slow at room temperature / heat speeds [1]

up the reaction /increases rate / flammable (1)
Do not allow constant temp.
Total 15 marks

4 (a) (i) 0.25 = 0.00258 / 2.58 x 10-3 / 0.0026 / 0.002577 (1) [1]
97

(ii) 0.00258 / same number of moles as calculated in (i) (1)

0.00258 x 1000 (1) = 0.110 (mol dm-3) (1) units not required
23.45
consequential on (i) [3]

(b) 2 x 0.01 x 100 = 8% (1)

0.25 [1]

(c) must be evidence of two weightings at some point

W Weighing
in the process (1)

P Preparation Rinsing out one piece of relevant apparatus

correctly (1)

D Dissolve Dissolve in water in beaker / volumetric flask (1)

R Rinse Rinse beaker and add washing to volumetric

flask / rinse funnel (if solid straight to volumetric
flask) (1)
Max
V Volumetric Volumetric / standard / graduated flask (1) 5
flask DO NOT AWARD IF CANDIDATE USES marks
VOLUMETRIC FLASK TO MEASURE OUT 250 cm3

M 250 cm3 Making up to mark / exactly 250 cm3 of solution

(1)

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99
S Shake Shake / invert / mix final solution (1) n.b. this is
at end

C concentration = mass of sulphamic acid x 1000 (1)

97 (or Mr) 250

H Safety
(solution of) acid is corrosive wear gloves (1) [8]
Total 13 marks

Paper total 50 marks

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Mark Scheme for Specimen Paper

Unit Test C4

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101
1 (a) (i) Lattice Energy –heat energy released (1)
when gaseous ions (1)
(come together to) form 1 mole solid / crystal / lattice (1)
[3]

(ii) Enthalpy of Atomisation - heat energy change for the

formation of one mole of gaseous atoms (1)
from an element in its standard state (1)
if state or imply exothermic max 1 [2]

(b) (i) correct step shown (1) must identify change [1]

(ii) +150 + 736 + 1450 + (2x121) + 642 = 3220

= 2493 + 2x (1)
2x = 727
x = -364 (1) sign vital [2]
(c)

Na+(g) + H(g) + e-

Na+(g) + H-(g)

Na(g) + H(g)

Na(g) + ½H2 (g)

Na(s) + ½H2 (g)

NaH(s)

Marking points on cycle

• all correct species and steps plus state symbols where
crucial (1 mark)
n.b. crucial steps Na (s) to Na (g) + gaseous ions to solid NaH
• complete cycle (1 mark)
• ½H 2 to H (1 mark)

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n.b. the whole cycle could be doubled to give 2 x electron
affinity [3]
n.b. an energy diagram as above is not essential any correct
cycle in any representation is equally acceptable
Total 11 marks

2 (a) (i) n.b. if H omitted penalise only once in this question

CH3CH2CH2CN [1]

(ii) LiAlH 4 / NaBH4 / Na + C 2H5 OH / H 2 + Ni or Pt catalyst / zinc

plus acid (1)
Name or correct formula [1]

(iii) H H H H H
H C
(1)
C C C N
H H H H
H
not CH3CH2CH2CH2NH2
consequential on (i) [1]
(b) H

H H H C H
H
H C C C * N
H H H H

Allow
CH 3 CH 3
CH3 CH 2 C NH2 or C 2H 5 C NH2
H H
(1+1) [2]

(c) (i) lone pair of electrons on the N atom (1) [1]

(ii) C4H9NH2 + H + → C4H9NH3+ (1)

not consequential on (b)/ allow molecular equation [1]
allow RNH2
[1]
(d) (i) amide (1)

(ii) faster / more control / better yield / not equilibrium / no

need to heat (1) [1]

(e) PCl5 / PCl3 / SOCl2 (1) or name [1]

(f) Make a Grignard reagent using magnesium (1)

in dry ether (1) not stand alone mark
react this with (solid) CO2 (1)
then hydrolyse with acid / + acid / + H + / + HCl (1) not stand

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103
alone

Alternative routes are possible

CH3Cl CH3MgCl CH3 COOH

Mg(1)/dry CO2 (1)
acid (1)
ether(1) [4]
HCHO
acid (1)

CH3 CH2 OH
(1) for all of
the steps and
K2 Cr2 O7 reagents
H2 SO4 apart from
acid which is
stand alone
CH3 CO2 H
Total 14 marks

3 (a) (i) CO2 / SiO2 (1)

(ii) PbO / PbO2 / SnO / SnO2 (1) allow GeO [2]

(b) (i) Reacts with both acids and bases / can act as both an acid
or a base / has both acidic and basic properties or
characteristics (1) [1]

(ii) Al2O3 (s) + 6H+ (aq) → 2Al3+ (aq) + 3H2O (l) (1)
Balanced and ionic
Al2O3 + 6OH - + 3H2O → 2Al(OH)63- /
Al2O3 + 2OH - → 2AlO 2- + H 2O /
Al2O3 (s) + 2OH - (aq) + 3H2O (l) → 2Al(OH)-4 (aq) (1)

Evidence of understanding of meaning of amphoteric (1)

i.e. two equations, one with H + and one with OH -- [3]

(c) NaCl + H 2O → Na+ + Cl- (1)

do not penalise omission of water
Ionic chlorides dissolve without hydrolysis / no hydrolysis
has occurred the bonding is ionic (1)
PCl5 + 4H2O → H3PO4 + 5HCl /
PCl5 + H 2O → POCl3 + 2HCl (1)
The bonding is covalent in the chloride and hydrolysis
occurs with water / covalent chlorides react with water to
give an acidic solution. (1) [4]

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(d) (i) Two layers formed / no reaction / nothing / immiscible (1) [1]

(ii) (Violent) reaction / hydrolysed (1)

Identification of one product / description of one product
(1)
e.g. steamy fumes / white fumes / white solid / gas / named [2]
product

(iii) The reaction takes place by the interaction of the lone pair
of electrons on the water (1)
Bonding to central (silicon/carbon) atom / attaching to
central atom (1)
In silicon the 3d orbital is available to accept the pair of
electrons (1)
In carbon no similar orbital is available / not enough energy
available to utilise vacant carbon orbitals / carbon
surrounded by chlorine atoms causing steric hindrance (1)
[4]

Total 17 marks

4 (a) (i) fraction of the total pressure generated by a gas (1) [1]

(ii) KP = p(CO) x p(H 2)3

p(CH4) x p(H 2O) (1) [1]

(iii) Increase in total pressure will result in less product

molecules in the equilibrium mixture / equilibrium moves
to left (1)
because more molecules on product side of the
equilibrium than on left hand /reactant side (1) [2]

(b) (i) No change (1) [1]

(ii) Kp increase (1) [1]

(iii) No change (1) [1]

(ii) 9.87 x 10-3 kPa-1 (1) [1]

(iii) equilibrium has moved left (1)

exothermic as written /in the forward direction (1) [2]
Total 11 marks

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105
5 (a) only partially dissociated / ionised (1)
into H + ions / H 3+O / proton donor (1) [2]

(b) (a solution that) resists change in pH / retains an almost

constant pH (1)
on addition of small quantities of acid or alkali (1) [2]

(c)

Marking points
General shape (1)
Vertical section at 25 cm 3(1)
End point around pH 9 and vertical between about 7 to
11(1)
Starting point at 2.8 (1)
[4]
(d) Horizontal portion of graph below pH 7 indicated on
graph (1) [1]

(e) (i) Ka = [CH3COO-][H +]

[CH3COOH] (1) [1]

(ii) pH = pKa at halfway to neutralisation point = 12.5 cm 3 (1)

Because pH = pKa when [CH3COO-] = [CH3COOH](1) [2]

(f) Phenolphthalein (1)

indictor changes colour between pH 7 and 10 this is
vertical part of graph (1)
methyl orange would change in acid between pH4 and
pH6 (1)
n.b. +ve statement about methyl orange [3]

(g) exothermic reaction / heat (energy) released during

reaction (1)
HCl is strong acid fully ionised (1)
this is weak acid so some energy used for dissociation (1) [3]

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(h) (i) pH = -log(10) [H +] or in words [1]

(ii) 1.8 x 10-5 = [H +]2 (1)

1
[H +] = 1.8 x 10-5 = 4.24 x 10-3 (1)
pH = -log(4.24 x 10-3)
= 2.37/2.4 (1) 2 to 4 sig. figs. [3]

Total 22 marks

Paper total 75 marks

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Mark Scheme for Specimen Paper

Unit Test C5

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1 (a) (i) Working to show first order with respect to [S 2O 82 ] (1)
Working to show first order with respect to [I- ] (1)
overall equation(1) [3]
Consequential

(ii) Sum of power of the concentration terms (for thio and

iodide) in rate equation / number of each species involved up
to and including or, in, the rate-determining step in the
reaction mechanism / Sum of the partial / individual orders /
general equation of the form [thio]m [iodide]n
overall order = m + n (1) [1]

(iii) 36 (1) dm3mol-1s-1 (1) [2]

Consequential on part (i)

(iv) Rate equation depends on mechanism / rate equation only

involves those species in the rate determining step / slowest
step(1) [1]

(b) (i) Colorimetry / conductivity / remove samples and titrate with

(standard) sodium thiosulphate solution (1) [1]

(ii) Constant temperature (1) [1]

(iii) Colorimeter / conductivity adv that monitoring is continuous

/ does not need removal of samples
or
disadv of titration is problems with timing (1) [1]
Total 10 marks

2 (a) Species seeking negative charge / electron deficient /

electron pair (lone pair) acceptor (1) [1]
If say must be a positive ion then zero marks

(b) (i) 2-bromopropane (1) [1]

(1) for structure
(ii)
CH3CH CH2 CH3CH CH3 CH3CHBrCH3

H Br (1) Br
(1) for both

The arrow for the attack of the bromide ion must not go [3]
from the negative charge
Do not need lone pair of electrons on the bromide
If mechanism gives 1-bromopropane can get first and third
mark

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109
(iii) (major product) involves 2 o carbocation as intermediate (1)
which is more stable / has a lower E a of formation /more
electron releasing groups around the carbon atom than the [2]
1o carbocation (1)

This could be shown as diagrams.

n.b. Markovnikov’s Rule is not an explanation of why the
major product is formed simply a means of remembering
which is the major product.

(c) (i) Aluminium chloride / iron(III) chloride / iron / or bromides / [1]

correct formulae (1)

(ii) CH3Br + AlCl 3 CH3 + BrAlCl 3 (1)

(1) CH3
CH3 CH3

H +H

(1) for arrow

alternative way (1) for structure
of showing part played by catalyst

(1) (1)
CH3 BrAlCl3

[4]

Kekulé intermediate
CH3
H

(d) delocalised π electron / from p-orbitals system in benzene

(1)

substitution enables delocalisation to be preserved (1)

π bond in propene weaker than π bond in benzene (1)

(π bond broken in) formation of two single bonds (on

addition to propene ) which is energetically more [4]
favourable than substitution (1)

Total 16 marks

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3 (a) VO2+ yellow VO2+ blue

V3+ green V2+ Lavender/mauve/lilac/purple/

[2]
violet

All four correct 2 marks - any 2 correct 1 mark

(b) (i) 2VO2+ + Zn + 4H+ à 2VO2+ + 2H2O + Zn2+

species (1) balance (1) [2]

(ii) V3+
or
V3+ and VO2+(1) allow [V(H 2 O) 6]3+
E value for both reduction reactions positive so feasible (1)
(further) reduction (to V 2+ ) not feasible since E value [3]
negative(1)

(c) (i) Disproportionation requires the original oxidation states to

be able to both rise and fall (1)
or
In disproportionation a species must be able to be reduced
and to be oxidised thus needs 3 oxidation states (1) [1]

(ii) 2VO2+ à VO2+ + V 3+

species (1) balance (1) [2]

Total 10 marks

4 (a) Sc [Ar] ↑ ↑↓
Cu [Ar] ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑
Cu2+ [Ar]↑↓ ↑↓ ↑↓ ↑↓ ↑ [3]
Cu consequential on structure for Cu
2+

(b) Electronic configuration differs from previous element by an

electron in a d (sub) shell / electrons are filling the d-shell (1)
transition elements have at least one ion with partially-filled
d-shell (1) [2]
Not ‘highest energy shell is the ‘d’-shell
outer electron in ‘d’ shell

(c) (i) Hexaaquacopper(II) 2+ [1]

(ii) H 2O [1]

H2O H 2O
Cu
H2O H 2O
H 2O

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111
(iii) d-orbitals split (in energy by ligands ) / or diagram to
illustrate (1)
electron transitions/ jumps from lower to higher energy
level (1)
absorbs light in visible region (1) [3]

(d) (i) Blue precipitate (1)

Insoluble/ remains in excess sodium hydroxide (1) [2]

(ii) Deprotonation / acid base (1) [1]

(e) 2S2O3 2- + I2 → S4 O6 2- + 2I- / or clearly stated (1)

amount of thio = 26.8 x 0.1 / 1000 = 2.68 x 10-3 mol(1)

ratio of copper to thio is 1:1 (1)
total amount of copper = 2.68 x 10-3 mol x 10 =2.68 x 10-2 mol
(1)
mass of copper = 2.68 x 10-2 mol x 63.5 g mol-1 = 1.70g (1)
purity = 1.70x100 / 1.74 = 97.8 / 97.7 % (1)
allow 2 to 4 sig figs in final answer mark consequentially [6]
Total 19 marks

5 (a) (i) Magnesium (1)

Dry Ether(1) [2]

(ii) (Solid) carbon dioxide (1) then / followed by

dilute HCl (1) [2]
Carbon dioxide and dil HCl scores 1 mark
Any named mineral acid can score
Ignore state of carbon dioxide

(b) (i) (ether) flammable (1)

No naked flames / use water bath / heating mantle(1) [2]

This is a diagrammatic
representation of a set
(ii) up that could be used.
The marks are for the
Some means of adding particular elements not
bromoethane safely. their orientation
Or
Calcium chloride
drying tube Reflux condenser

Water bath /
Magnesium heating mantle
+ This mark lost if
ether Bunsen present
or heat ↑

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Marking
Flask + Reflux condenser (1)
Water bath / heating mantle (1) Consequential on first mark
Some means of excluding water vapour e.g. calcium chloride
guard tube or some means of adding reactants without
danger (1)

Overall diagram (1) this must work and this must be safe i.e. [4]
not closed

structure of acid chloride showing at least expansion of COCl

(1) products (1) [2]

(d) O
C C 2H 5

(1)
2,4-dinitrophenylhydrazine reacts with carbonyl group (1)
this carbonyl compound is a ketone and cannot be oxidised
by/ cannot reduce ammoniacal silver nitrate (1)
This is consequential on B being shown as a ketone [3]

(e) (i) OH
C C2H5
H

[1]
(1)
This is consequential on a ketone being shown in (d)

(ii) The lithium aluminium hydride would react with any water (1) [1]

(f) B has absorption peak in region 1680 - 1750 showing

carbonyl (1)
but peak in region of 3250 - 3550 is present ( not present in
B) showing alcohol group / allow broad peak if range
omitted (1)
comparison between two spectra (1) [3]

Total 20 marks

Paper total 75 marks

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113
Mark Scheme for Specimen Paper

Unit Test C6B

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1 (a) Conc. H 2SO4 catalyst (1)
40 minutes since reaction slow (1)
ester boils below 85oC (1)
sodium carbonate removes acid (1)
Na2SO4 removes water (1)
76oC – 80oC fraction contains most of the ester (1)

diagram (2) max (1) if closed or other silly error

H2
O

H2 O

[8]

(b) Advantages:
Reaction much faster/ no need to heat / fast at room
temperature (1)
Reaction goes to completion / reaction not equilibrium /
better yield of ester (1)
Disadvantage:
Hydrogen chloride gas given off –toxic/ need to use fume
cupboard (1) [3]
(c) H O H H O H H H
H C C O C C H H C O C C C H
H H H H H H

Ethyl ethanoate Propyl methanoate

Ethyl ethanoate has three peaks: at 1.2ppm due to the

methyl in the ethyl group, 2ppm due to the methylene
group, and 4.1ppm due to the methyl adjacent to the
carbonyl group. These are in ratio 3:2:3 (1)
Propyl methanoate has four peaks: 1ppm due to the methyl
part of the propyl group; 1.7ppm due to the methylene
group next to this; 4.1ppm due to the methylene group next
to the oxygen atom; 8.1ppm due to the hydrogen next to
the C=O group. These are in ratio 3:2:2:1. (1)

Therefore it will be possible to distinguish between the two

(1) [3]
Total 14 marks

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115
2 (a) Low(er) solubility or not easily leached
non-explosive
neutral
less osmotic pressure / less scorching
slow release Any two for 1 mark each [2]

(b) Ammonia is the stronger base because

ammonium ion is the weaker acid (2)
or
The weaker the acid, the stronger is its
conjugate base (1)
Therefore (NH4+ weaker acid / smaller K a)
ammonia is stronger base (1)
or
Ka for NH4+ is less than Ka for conjugate acid of
urea(1)
therefore the ammonia is the stronger base(1) [2]

(c) (i) Bromine (1)

NaOH(1)
Order of adding/addition and heat (1) [3]

(ii) NH2NH2(1) [1]

(d) (i) Ammonium nitrate is a solid / not a gas (1) [1]

(ii) KP = P NH3 PHNO3(1)

PNH3 = √15.7 = 3.96 atm (1)

3.96 atm = 3.96 x 1/50 moles of ammonia
= 0.079 moles (1)
Moles of NH4NO3 = 8.00/80 = 0.100 (1)

% dissoc = 0.079/0.1 x100 = 79% (1) [5]

(e) Energy level of ammonium nitrate is higher

than energy level of products (1)
therefore ammonium nitrate is
thermodynamically unstable with respect to
products ( or the reverse argument) (1)
Ammonium nitrate is kinetically stable (1)
Strong heating needed to overcome high
activation energy (1) [4]

Total 18 marks

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3 (a) (i) Electronegativity: tendency of an atom to draw electrons in a
bond towards itself (1)
large electronegativity difference between sodium and
chlorine (1)
Chlorine attracts electrons to form Cl- ion hence ionic bond [3]
(1)

(ii) Al3+ much more charge dense than Na+ (1)

so much more polarising tending to covalent bonding (1) [2]

(b) Ar ionisation energy so high (1)

that is not compensated by (1)
the lattice energy (1) [3]

(c) (i) P4 + 10Cl2 → 4PCl5

Allow
P4 → PCl3 → PCl5
for species (1) for balancing (1) [2]

(ii) Oxidation number of phosphorus changes from 5 to 3

therefore reduction (1)
Oxidation number of chlorine changes from -1 to 0 therefore
oxidation (1)
It is a redox reaction (1) [3]

(d) (i) O O O O
C C O (CH2)2 O C C

Reagents

O O
HO (CH2)2 OH and Cl O C C O Cl

1 mark each [3]

The polyester needs to show at least one ester link and some
evidence for extension of the chain for the mark. The exact
groups between the ester links are not important
The reagents are consequential on the ester drawn

(ii) A polymer is made by the elimination of a small molecule –

in this case hydrogen chloride (1)

between two molecules each of which has a reactive group [2]

at each end of the molecule (1)
Total 18 marks

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117
H H

. .. . H

..+ .+
.. .+
4 (a) (i) (1)
H N N

+
[1]
(ii) Basic shape around each nitrogen – triangular pyramidal
since 3 bonding and one lone pair of electron (1)
Pairs of electrons repel each other as far as possible / to
position of minimum repulsion around each nitrogen (1)
Because lone pairs repel more than bond pairs giving
angle of about 107o(1) [3]

(b) Amount hydrazine = 1000g/32g mol-1 = 31.25 mol (1)

∆HcO = - 1.83 x 10 4 / 31.25 = - 585.6 kJ mol-1 (1)
Break N-N Make N≡N - 944
4 x N-H + 388 x 4 4 x O-H - 463 x 4
O=O + 496
(Bond energy N-N + 2048) - 2796 (1)
(Bond energy N-N + 2048) – 2796 = 586
∴ Bond energy N-N = + 162 kJ mol-1 (1) [4]

(ii) E O values for (i) > +0.66V but < +1.32 / between +0.66 and
+1.32 / reduction potential for N 2 /N 2H4
less negative than – 1.32V but more negative than – 0.66V
(1) [1]

(iii) 4VO2+ + N 2H4 → 4VO2+ + N 2 + 4OH -

or
4VO2+ + 4H2O + N 2H4 + 4OH - → 4VO2+ + 8OH - + N 2 + 4H2 O
species (1) balance (1) [2]

H H H H H
(d) (i) H N N H + O C C2H5 H N N C C2H5 + H2O

Equation(1) structure of product (1) [2]

(ii) The carbon nitrogen double bond restricts rotation(1) and

this leads to geometric isomerism(1)
With the NH2 and C2H5 on the same or different sides of
the molecule / or structures drawn(1)

H2N H .. H
N
.. C N C
C2H5 H2N C2H5
Trans Cis
[3]
Total 18 marks
Paper Total 50 marks

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BLANK PAGE

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119
Mark Scheme for Specimen paper

Unit Test C3A

120

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Question 1

(a) Lilac / mauve / pinkish / purple (1) Potassium / K /K + (1) [2]

(b) (i)
any yellow ppt (1) AgI / I- / iodide / KI / iodine
anion (1) or AgBr / Br Br-
Insoluble(1) Not iodine [3]

(ii) Brown or red solution / I 2 / black KI (1) only, [2]

ppt or solid (1) not bromide or chloride accept
NaI if flame colour yellow
(iii) Concentrated sulphuric acid (1)

Purple gas / black solid / bad-egg smell / yellow solid (1) [2]

Total 9 marks

Question 2

Table 1 Check subtractions and averaging arithmetic, correcting if necessary.

Any Two recorded titres within 0.2 (3) 0.3 (2) 0.5 (1)
All volumes, including mean titre, recorded to 2 dp–allow one slip
but withhold this mark if any readings are in the wrong boxes. (1)
Allow initial reading of 0 or 0.0
All subtractions correct (1)
Record these marks on the script below table
Mean For correct averaging of chosen values or for choosing identical
titre values and for recording the average correct to 2 or 3 dp or to
nearest 0.05 cm3(1)
Accuracy Award marks for accuracy as follows using the titre supplied by the
centre supervisor. If you suspect that this value is inaccurate and that
using it will be unfair to the candidates you may have to use a
different titre. A number of possibilities exist.
• Ignore the supervisor's titre and average all or most of the
candidate's titres.
• assume that the centre made up solutions exactly as specified and
use a theoretical value of 23.8 cm3
• Use an average of the titres gained by the candidates who
perform well in the other part s of the paper. Ignore the
candidates who are clearly weak.

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Marks awarded for accuracy if average titre
difference is less than or equal to difference
given
Difference + + + + + + + +
d= 0.20 0.30 0.40 0.50 0.60 0.70 0.80 1.00
Mark 8 7 6 5 4 3 2 1
e.g. a difference of 0.45 would score 5 marks

Penalty If the candidate has averaged titres which differ by more than
0.2cm3 then, using the outermost titres, the examiner must subtract
marks from the accuracy mark. The examiner must also subtract
marks if the mean has been corrected because of incorrect
subtraction and new titres outside 0.2 cm3 have been used.

Range 0.00 0.21 0.31 0.41 0.51 0.61 0.71 0.81 0.91
between titres to to to to to to to to to
averaged / cm 3 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

Subtract from 0 1 2 3 4 5 6 7 8
accuracy mark

(a) Titre x 0.05 (1)

1000 [1]
(b) 2 x answer to (a) (1) [1]

(c) Answer to (b) x 1000 (1)

25
Mr = 8.0 (1)
conc in mol dm-3
M = Na (1) [3]

(d) Two techniques from:

• avoiding air bubbles
• reading pipette at eye-level / correct reference to meniscus
• touching side of flask with tip of pipette / touching solution with [2]
• tip of pipette
• leaving drop in tip of pipette
• rinsing out with solution X before use
Total 21 marks

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Question 3

Table 2 All weighings recorded in correct spaces to at least 2 dp (1)

Correct subtraction (1)
[2]
Table 3 Both temperatures recorded in correct spaces to at least 1dp. (1)
Correct subtraction including sign (1)
Accuracy Multiply the candidate's - corrected if necessary - mass by 1.55 and
record this figure to 1 dp close to the candidates T value (corrected
if necessary) on page 7.
Record the difference between the two values on the script.
Award accuracy marks as follows

Difference + 0.5 + 0.8 + 1.0 + 1.5

Mark 4 3 2 1 [6]

If assumed mass of 3.1g subtract 1 mark from accuracy mark ( no

negatives.

(a) Correct arithmetic (1)

Positive sign (1)
Value to 3sf and units (1) [3]

(b) The principle is general change (1) reason for change (1)

Note ; If a candidate changes the apparatus give 1 mark for

reasoning [2]
Examples might include:
• Take a series of temperature readings / repeat experiment (and
average results ) (1)

• To allow for odd / erratic temperatures / heat gain from

surroundings (1)

• Use more solid (1) larger T value(1)

• Put a lid on apparatus(0) to prevent heat losses (1)

• Use the same thermometer / different thermometer (0) reading

to an accuracy of 0.1 °C (1)
Total 13 marks

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Question 4

Planning • General Procedure

Procedure used (1) and measurements taken (1) 4p 4p
Procedure:
Add MHCO3 + acid and stopper flask / use suspended test tube
in large flask (1)
Measurements:
Mass of MHCO3 and ( final ) volume of carbon dioxide / when
effervescence stops record volume of gas in syringe (1)

• Calculation 4c 4c
Explain how to convert volume of CO2 to moles by correct use of
24.0 (1)
Use of moles MHCO3 = mass MHCO3 ÷ Mr MHCO3 to find Mr (1)
Hence find identity of M (1)

• Errors 4e 4e
One likely error eg escape of gas before bung replaced / solid
did not all react / carbon dioxide soluble in acid (1)
Should not affect identification since even if M r is slightly wrong
it will still correspond to nearest Group 1 metal atomic mass (1)

• Safety 4s
Sensible safety precaution and reason eg eye protection–acid
hazard (1) [7]

Total 7 marks
Paper Total 50 marks

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Mark Scheme for Specimen Paper

Unit Test C6A

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The mark scheme is written into the questions.

Question 1
Tests on A
(a) (i) Add 3 cm3 of aqueous sodium hydroxide to a spatula measure of A
in a test tube. Gently warm the test tube. After removing the test
tube from the Bunsen flame, carefully smell any gas evolved. Carry
out a simple test to confirm the identity of the gas.

Observations Inferences

description of ammonia smell (1)

red litmus turns blue (1) ammonia (1)

[3]
Dissolve the remaining sample of A in 10 cm3 of distilled water. Use this
solution for the tests which follow.
(ii) To 2 cm3 of aqueous A add 6 drops of aqueous barium chloride
followed by 10 drops of dilute hydrochloric acid.

Observations Inferences
white precipitate (1)

insoluble in acid (1) BaSO4//SO4 2-/sulphate (1)

[3]

(iii) To 2 cm3 of aqueous A add dilute aqueous ammonia drop by drop until
the test tube is about half full. The ammonia will then be in excess.
Observations Inferences

brown precipitate (1) insoluble in excess (1) Fe(OH)3 (1)

[3]

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(iv) To 2 cm3 of aqueous A add 10 drops of aqueous potassium iodide
followed by 6 drops of aqueous starch.
Observations Inferences
brown solution (1)
blue-black colour (1) iodine (1)
[3]
(v) Suggest the formulae of the two cations and one anion in A.
Cations Fe3+ and NH4 +
Anion SO42- (3 correct score 2 marks, 2 correct scores 1 mark)
[2]
(vi) Give the name of the type of reaction which occurs in (iv) when aqueous
potassium iodide is added to A. Write an ionic equation to represent the
reaction.
Type of reaction oxidation / redox (1)

Equation 2Fe3+ + 2I- →2Fe2+ + I 2 (1)

[2]
Total 16 marks

Question 2
Tests on B
(b) Carry out the tests listed below on the organic compound B, C9H8O. B
has two functional groups.

Record the results of your tests in the Observations spaces. Under Inferences
record the functional group, by name or formula, the presence of which may be
suggested by your observations. You are not expected to attempt to identify B
in your Inferences.
(i) Using a dropping pipette transfer 10 drops of B to a crucible. Carefully ignite
the B.

Observations Inferences
smoky flame(1) benzene / aromatic (1)

[2]

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(ii) To 1 cm3 of B, add 8 drops of an aqueous solution of potassium
manganate(VII) acidified with dilute sulphuric acid. Stopper and gently
shake the test tube.
Observations Inferences

Mauve / purple colour of potassium reducing agent present(1)

manganate(VII) discharged /
alcohol or aldehyde (1)
decolourised (1)
unsaturated carbon double bond (1)
Any two
[Max 3]
3
(iii) To 2 cm of B add 8 drops of aqueous bromine. Stopper and gently
shake the test tube.

Observations Inferences
Orange / yellow to colourless (1) unsaturated / alkene (1)

[2]
(iv) To 4 drops of B add 2 cm 3 of aqueous 2, 4−dinitrophenylhydrazine.
Stopper and shake the test tube gently.

Observations Inferences
yellow / orange precipitate (1) carbonyl group(1)

[2]
3
(v) Mix 2 cm of each of Fehling’s solutions 1 and 2. Add 6 drops of B. Heat
the test tube in a water bath at about 80 oC.

Observations Inferences
red precipitate (1) aldehyde (1)

[2]

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(vi) On the evidence of the tests carried out write structures for two isomers of
B.

Structure 1 Structure 2

CH CHCHO CH CH2

CHO

[2]
Total 13 marks

Question 3
(1 mark is to be awarded for a proposed method that (i) works and
is (ii) logical. Candidates cannot score full marks on this section of
the question without this mark)
Method to include:
filter off 2, 4−DNP derivative (1)
dissolve in hot (1)
minimum / filter hot (1)
cool / crystallise (1)
filter off crystals (1)
dry crystals (1)
measure melting point (1)
check mp with listed mp’s of derivatives (1)
safety (1)

[Max 8]
Total 8 marks

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Question 4
For a pair of results in which the rising and falling temperatures do not
differ by more than 5 oC (1 )

For an actual falling temperature differing from the ideal by:

not more than 2 oC (5)

not more than 3 oC (4)
not more than 4 oC (3)
not more than 5 oC (2)
not more than 6 oC (1)
[6]
(i) Product must be C 9H10O (1)

Structure of product based on the structure drawn in part (b)(vi)

showing saturation of the double bond only.(1)
[2]
(ii) Very difficult to judge the exact temperature

Poor conduction between the liquid and the oil

Difficult to control temperature rise and fall
Repeat experiment with (fresh) sample till reproducible results
obtained
Use a distillation procedure
[5]
Total 13 marks

Paper total 50 marks

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General Guidance on Marking

Examiners should look for qualities to reward rather than faults to penalise. This does not
mean giving credit for incorrect or inadequate answers, but it does mean allowing
candidates to be rewarded for answers showing correct application of principles and
knowledge, and for critical and imaginative thinking. Examiners should therefore read
carefully and consider every response; even if it is not what is expected it may be worthy of
credit.

Using the Mark Scheme

1. The mark scheme gives you:

• an idea of the types of response expected
• how individual marks are to be awarded
• the total mark for each question
• examples of responses that should not receive credit.
2. ; separates points for the award of each mark.
3. / means that the responses are alternatives and either answer should receive full
credit.
4. ( ) means that a phrase/word is not essential for the award of the mark but helps the
examiner to get the sense of the expected answer.
5. Phrases/words in bold indicate that the meaning of the phrase/word is essential to the
answer.
6. ecf (error carried forward) means that a wrong answer given in an earlier part of a
question is used correctly in answer to a later part of the same question.

Marking

1. You must give a tick (in red) for every mark awarded. The tick must be placed on the
script close to the answer. The mark awarded for part of a question should be written
in the margin close to the sub-total.
2. The sub-total marks for a question should be added together and the total written and
ringed at the end of the question then transferred to the front of the script.
3. Suggestion/explanation questions should be marked correct even when the suggestion
is contained within the explanation.
4. Do not award marks for repetition of the stem of the question.
5. Make sure that the answer makes sense. Do not give credit for correct words/phrases
which are put together in a meaningless manner. (Quality of written Communication).
Answers must be in the correct context.

131

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THE PERIODIC TABLE
1 2 Group 3 4 5 6 7 8

Period key
1 Atomic Nu mber 2

Sym bol
1 H He
Hy drog en Na me Helium
1 4
Molar mass in
-1
g mol
3 4 5 6 7 8 9 10

2 Li Be B C N O F Ne
Lithium Be rylium Bo ron Carb on Nitrog en Oxygen Flu orine Neon
7 9 11 12 14 16 19 20
11 12 13 14 15 16 17 18

3 Na Mg Al Si P S Cl Ar
So dium Magnesium Aluminiu m Silicon Pho sph oru s Sulph ur Ch lorine Argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36

4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Potassium Calcium Sc an dium Titan iu m Van adium Ch romiu m Mangan ese Iro n C obalt Nic kel Cop per Zinc Gallium Germa nium Arsen ic Se len iu m B romin e Kry pton
39 40 45 48 51 52 55 56 59 59 6 3.5 65.4 70 73 75 79 80 84

132
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Rub idium Str ontium Yttrium Zirco nium Nio bium Molybd enum Technetium Ru thenium R hod ium Palladium Silver Cadm iu m Ind iu m Tin Antimo ny Tellurium Io dine Xen on
85 88 89 91 93 96 (99 ) 10 1 1 03 10 6 10 8 11 2 11 5 119 1 22 12 8 1 27 1 31
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

6 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Caesiu m B arium Lanth anum Hafn iu m Tan talu m Tung sten R heniu m Osmium Irid ium Platinum Gold Mercur y Thallium Lead Bismuth Po lo niu m Astatine Rad on
133 137 1 39 17 8 18 1 184 18 6 19 0 1 92 195 1 97 20 1 2 04 207 209 (21 0) (2 10) (22 2)
87 88 89 104 105 10 6

7 Fr Ra Ac Unq Unp Unh

Fr an cium Radium Actin iu m Un nilquad iu m Unn ilp entium Unn ilh exium
(223 ) ( 226 ) ( 227 ) (2 61) (262 ) ( 263)

www.XtremePapers.net
58 59 60 61 62 63 64 65 66 67 68 69 70 71

Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Praseo-
C erium d ymium Neody mium Pro meth ium Samar iu m Eu ropiu m Gad olinium Terbium Holmium Er bium Thuliu m Ytterb ium Lutetium
14 0 1 41 144 (1 47) 150 15 2 157 159 1 63 1 65 16 7 1 69 17 3 175

90 91 92 93 94 95 96 97 98 99 10 0 101 102 10 3

Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
Thor iu m Pro tactin ium Uranium Neptunium Cu rium B erkelium C alifo rniu m Einstein iu m Fermium Mendeleviu m Nobelium Lawrenc iu m

232 (23 1) 23 8 (2 37) (24 2) (243 ) (24 7) (245 ) (25 1) ( 254 ) (25 3) ( 256 ) (2 54) ( 257 )
© 2002 EDEXCEL Foundation
This publication may only be reproduced in accordance with Edexcel copyright policy.
Edexcel Foundation is a Registered charity.

For more information on Edexcel qualifications please contact our

Customer Response Centre on 0207 7393 4500
or email: [email protected]
or visit our website: www.edexcel.org.uk

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