AJPM3/02 Test- 02

DURATION : 180 Minutes DATE : 17/11/2024 M.MARKS : 300

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (2) 26. (2) 51. (1)
2. (1) 27. (4) 52. (4)
3. (4) 28. (4) 53. (3)
4. (3) 29. (1) 54. (1)
5. (1) 30. (1) 55. (2)
6. (4) 31. (2) 56. (1)
7. (2) 32. (2) 57. (4)
8. (3) 33. (2) 58. (2)
9. (3) 34. (4) 59. (1)
10. (1) 35. (2) 60. (4)
11. (2) 36. (4) 61. (2)
12. (2) 37. (3) 62. (1)
13. (2) 38. (3) 63. (3)
14. (4) 39. (4) 64. (1)
15. (2) 40. (4) 65. (4)
16. (4) 41. (4) 66. (1)
17. (2) 42. (1) 67. (1)
18. (3) 43. (1) 68. (2)
19. (3) 44. (3) 69. (3)
20. (3) 45. (2) 70. (4)
21. (11) 46. (3) 71. (0)
22. (2) 47. (7) 72. (3)
23. (151) 48. (3) 73. (25)
24. (8) 49. (7) 74. (0)
25. (20) 50. (3) 75. (5)

[1]
 SECTION-I (PHYSICS)
1. (2) PA = 243P
2GM For gas B :
Escape velocity Ve = Adiabatic process  PVγ constant
R
7
For diatomic gas  =
5
 
1 1 = P2V2
PV
 7
PB  V1   V  5
=  =  PB = 37 P
P  V2   V / 243 
From the conservation of energy. PB 37 P
 = =9
−GMm 1 −GMm PA 243P
+ mVe2 = +0
R 8 h [10 Apr, 2023 (Shift-I)]
−GMm 1 2GMm −GMm
 + =
R 8 R h 5. (1)
1 1 −1 For isothermal process,
 − =
4R R h  Vf 
W = nRT ln   and PV = constant
4R  Vi 
 h=
3  I→Q
[27 July, 2022 (Shift-II)] For isobaric process
P = constant
2. (1) V
Velocity should be given so as to reach a point  = constant
T
where field is zero and Q = nCpT
M 9M  II → R
= .
x 2
(12a − x)2 For adiabatic process
x = 3a PVγ = constant
By CoE
and W =
(
nR Ti − T f )
−
GMm 9GMm 1 2
− + mv = −
9GMm GMm
− +0  −1
9a 3a 2 9a 3a  III → P
1 2 16GMm
mv = For isochoric process,
2 9a V = constant
4 2GM P
v=  = constant
3 a T
[6 Sep, 2020 (Shift-II)] and W = 0
 Q =  U
3. (4) IV → S
Change in length due to rise in temperature [4 Sep, 2020 (Shift-II)]
Δl = lαΔT
Δl1 = Δl2 6. (4)
lα1ΔT1 = lα2 ΔT2 Maxwell’s distribution law applies to all ideal
1 T2 gases including monoatomic, diatomic and
= triatomic gases
2 T1
Statement I is false
2 T − 27
= At the same temperature, the most probable speed
5 177 − 27 of molecules in a gas depends on their molar
T = 87°C masses. Therefore monoatomic, diatomic,
[11 Jan, 2019 (Shift-II)] triatomic gases will have different most probable
4. (3) speed.
For gas A : Isothermal process,  PV = constant Statement II is false
P1V1 = P2V2 [25 Feb, 2021 (Shift-II)]
PV = PA (V/243)
[2]
7. (2) −(1+ )
2
I  P
T = 2 −(1+ )
Mgd 2
f  32 P 
T1 I =
T2
= 1
I2 i  P 
= 16
MR2 9MR2 17MR2
I1 = + = [7 Jan, 2020 (Shift-II)]
2 16 16
2
MR 9MR 13MR2
2 11. (2)
I2 = + = In case-1
4 16 16
T1 17 Electric field between spherical surface
 =
T2 13
[5 Sep, 2020 (Shift-II)]

8. (3)
r 2 L 9r 2 L
1 = =  and 2 = = 9 In case-2
L L Electric field between surfaces remain unchanged.
Tension in both are the same = T
Let the speed of the wave in the wires be V1 and
V2
T T V
V1 = = V ,V2 = =
 9 3
So fundamental frequencies in both wires are  Potential difference between them remain
V V V V unchanged too.
f1 = 1 = and f 2 = 2 =
2L 2L 2L 6L [8 April, 2019 (Shift-I)]
Frequency at which both resonate is L.C.M. of
V 12. (2)
both frequencies i.e., .
2L
Hence no. of loops in wires are 1 and 3
−ms
dT
dt
(
= eA T 4 − T04 )
respectively.
−
dT eA 4
dt
=
ms
(
T − T04 −
dt
=
ms
)
dT 4eAT03
(T )

T = T0 + (Ti – T0)e–kt
4eAT03
Where k = =
ms
Ratio of number of peaks on thicker string to the
4eAT03 dT dT 1
number of peaks on thinner string is 3 : 1. k=   k 
[8 April, 2019 (Shift-I)] vs dt dt s
ρA s A > ρB s B k A < k B
9. (3) dT dT

v2 v2 dt A dt B
S= =
2a  qE 
2 
 m
mv2
 E=
2qS
50 10−6 104 25 [8 April, 2019 (Shift-I)]
E= −6
= 103 = 0.83104 N/C
2  20 10 1.5 3
[29 June, 2022 (Shift-I)] 13. (2)
Given, number of mole, n = 1
10. (1) Vf V /8
W1 = nRT ln = 1 RT ln i = −RT ln8
T Vi Vi
Relaxation time () 
P W2 = 0

[3]
 Vi 3R RT  1 
32Pi  − Pi  Vi C= +
W3 =
i i − Pf V f
PV
= 8 2 V  2bv 
 −1  −1 3R R
3RT 9 C= +
 W3 = = RT 2 2
( − 1) 2 C = 2R
 Wtotal = W1 + W2 + W3 Q = nCT = (1)(2R) (T2 − T1 )
= (4.5 – 2.1) RT = 2.4 RT Q = 6 RT1
[24 Feb, 2021 (Shift-II)] Process 2 → 3 is isobaric
5
14. (4) Q1 = nC p (T3 − T2 ) = (1) R (T3 − T2 )
2
We have speed v = gx
T2 V2 V2
dv 1 g = =
= g. . gx = T3 V3 V1
dt 2 x 2
V2 T
g = 2 =2
 A( 2 f ) =
2
V1 T1
2
i.e.,8 f A = g
2 2
T3 =
T2
2
5 T
15. (2) Q1 = − R 2 = −5RT1
Tube closed at one end and open at other end 2 2
v 3v 5v 3 3RT1
f1 = , f3 = , f2 = Q2 = nCv (T1 − T3 ) = R (T1 − 2T1 ) = −
4L 4L 4L 2 2
f5 = 5 f1 , f3 = 2 f1 13RT1
f1 = 50Hz Q1 + Q2 = −
2
13RT1
16. (4) Heat dissipated = = Q'
2
Sloe of A is greater therefore SA < SB.
19. (3)
17. (2)
2 2 4
Velocity of the body executing SHM is  =1+ = 1+ =
( )
f 6 3
v2 = 2 A2 − y 2
 RT
vsound =
Acceleration of the body is m
a = y 2
3RT
vms =
 a = y
2 4 2 m
2 2
Given that,  = = = 2 rads–1 and v = a at 20. (3)
T 
0 A
10 cm from mean position, so we have C= , where x is separation between plates.
v2 = a2 x
 (
2 A2 − y 2 = 4 y 2 ) 1 dC 1 dA 1 dx
=
C dT A dT x dT
−

 A2 − y2 = 2 y2 dC 1 dx 1 dA
For = 0, =
 ( ) (
A2 = 2 + 1 y 2 = 22 + 1 102 = 500 ) dT
 3s = 2
x dT A dT

 A = 10 5
21. (11)
18. (3)
T2
=4
T1
dT
T = bv2  = 2bv
dv
p dv
C = Cv +
n dT
[4]
  2m2 m ( M − 3m) 2m ( M − 3m )  9
U = −G  + +   L2 + e = = 153 cm
4
 d d d 
 e = 2 cm & L2 = 151 cm
For U to be minimum,
[29 June, 2022 (Shift-II)]
dU
=0
dm
24. (8)
 2 × 2 m + (M – 6m) + 2M – 12m = 0
M 14
 =
m 3
[27 Aug, 2021 (Shift-I)]

22. (2)
Mean free path
1
 2
d
1 d22
 =
 2 d12
2
 dO 
  He =  2  O2 = 2 10−7 m
 d He 
3C
[25 July, 2021 (Shift-II)] C
Ceq = 2 = 3C
3C 5
C+
23. (151) 2
v [17 March, 2021 (Shift-I)]
500 = …(i)
4 ( L1 + e )
9v 25. (20)
500 = …(ii)
4 ( L2 + e ) Speed v =  A2 − x2 and | a |= 2 | x |

 L1 + e = = 17cm
4
SECTION-II (CHEMISTRY)
26. (2)
hc
KE = −

 hc
 mv2 = ….(1)
2 
 hc
 m ( v') =  9
2
….(2)
2 
2
v 1
   =  v' = 3v
 v'  9
[8 April, 2019 (Shift-II)]

27. (4)

[5]
28. (4) 34. (4)

In
due to conjugation, stability of the carbocation
increases.
[20 July, 2021 (Shift-I)]

29. (1) [12 Jan, 2019 (Shift-I)]

, 
H2C = O  H2C  O (carbon does not form 35. (2)
Refer IUPAC nomenclature rules.
five bonds)
36. (4)
Sn belongs to 14th group.
g = 14, p = 5, v = 4
[12 April, 2019 (Shift-I)]

37. (3)
XeO4 → sp3
30. (1)
SF6 → sp3d2
BF3 → sp2
ClF3 → sp3d
[27 June, 2022 (Shift-I)]

Two bulky groups on ortho position shows more 38. (3)

ortho effect (SIR effect).

31. (2)

Hydrogen attached to secondary carbon are

have different called secondary hydrogens.

39. (4)
arrangement of carbons along each side of
polyvalent functional groups. Bond order of N2 , N2+ , NO+ , NO, CN− and CN
3° Amine and 2° amine are treated as different are 3, 2.5, 3, 2.5, 3, 2.5 respectively. Higher is
functional groups. bond order smaller is bond length. Bond order of
CO and CO+ are 3 and 3.5.
32. (2)
Left to right in a period, the atomic radius 40. (4)
generally decreases and in a group, top to
bottom, atomic radius increases. Hence, the order
would be:
Cl > C > N > F
[8 Jan, 2020 (Shift-II)]

33. (2) CH3–CH2–CHO can't be prepared by using above

method.
[24 Feb, 2021 (Shift-II)]

41. (4)
Stability of alkene  Extent of Hyperconjugation

[6]
42. (1) C
|
Compounds which are acidic in nature liberate C – C – C – NH – C
hydrogen gas on reacting with Na.
48. (3)
43. (1) Structure (iii), (vi) and (vii) have
1 V1 D.O.U = 1
t1 2r1 V1 n2 n1 r 4R 2
= ; = ; = 1 = =
1 V2 V2 n1 n2 r2 9R 3 49. (7)
t2 2r2
t2 V1 r2 n2 r2 3 9R 27 t 8
=  =  =  =  1=
t1 V2 r1 n1 r1 2 4R 8 t2 27

44. (3)

NH3 ,SO2 ,SF4 contain one lone pair on C.A.

45. (2)
Ga(31) – [Ar]3d10 4s2 4p1

46. (3)
N2O, NO and CO are neutral oxides
remaining are acidic oxides.

47. (7)
Lone pairs present on doubly bonded atom are
with C5H13N, Possible 2 ° Amines are
localised hence don't participate in resonance.
C – C – C – NH – C – C
C – C – C – C – NH – C
50. (3)
C – C – NH – C – C
| 1 1 
C E = 2.18 10−18  2 − 2 
1 4 
C − C – C* – C
| 2.18 10−18 15
NH−C = −34
= 3.08 1015 sec−1
16  6.625 10
C
|
C − C− NH − C
|
C

SECTION-III (MATHEMATICS)
51. (1) Integrating both sides, we get
After rearrangement
 y
x e y / x = ln( x) − sin −1   + c
e y/ x
[ xdy − ydx] = xdx + ( ydx − xdy)  x
x2 − y 2
It passing through (1, 1)
e = – sin–1 1 + c
 xdy − ydx  dx x ( xdy − ydx) 
 e y/ x  = x − 2  c=e+
 x 2
 x −y 2 x2 2
 y 
Hence, e y / x = ln( x) − sin −1   + e +
dx
 e y / x d ( y / x) = −
d ( y / x)  x 2
x 1 − ( y / x) 2 [28 June, 2022 (Shift-I)]

[7]
52. (4) d  loge sin x 
After rationalization we get
= − loge 2  
dx  loge cos x 
I =
ln 2
− ln 2  (  )
e x  ln e x + 1 + e2 x  dx  cos x sin x 
 sin x loge cos x + cos x loge sin x 
= − loge 2  
Put ex = u  ex dx = du  ( loge cos x )2 

( )
2  
I =  ln u + 1 + u 2 du
1/2
− loge 2 ( cot x ln cos x + tan x lnsin x )
( )
2
= u ln u + 1 + u 2  1 At x = 30 =
 
2
( ln cos x )2
2  u2u 
− 1 +  du  3 1 1
1/2 2   − ln 2  3 ln + ln 
u + 1 + u  2 1 + u2 
=  2 3 2
1 1+ 5  2 u  3
2
= 2ln(2 + 5) − ln   − 1/2 du
 ln 
2  2  1 + u2  2 
1 1+ 5  5  
= 2ln(2 + 5) − ln   − ln 2  3ln
3
− ln 2 
2  2  2
=−  2 
   3
2
  3  ln 
 2   2(2 + 5)2  5  2 
(2 + 5)  5
= ln  − = e  −
(( ) )
log
 1  2  (1 + 5)1/2  2 − ln 2 3 ln 3 − ln 2 − ln 2
  5 +12  =
   

2
 2   3
3  ln 
[11 April, 2023 (Shift-I)]  2 

53. (3) =−
(
ln 2 3ln 3 − 4ln 2 )
( ) ( )
2
 3
1
1 t2 + 3 − t 2 +1 3  ln 
2 0 t 2 + 1 t 2 + 3
I=  2 
( )( )
dt
 16 
ln 2  ln 
1 −1 1 t
1
=  3 3
= tan t − tan −1 
2
2 2 3 30 3
3  ln 
   2 
= − [26 July, 2022 (Shift-II)]
8 12 3
[27 Aug, 2021 (Shift-II)]
56. (1)
54. (1) y( x2 + 1)dx − x2dy = 0
Let f (x) = |x|9 + 3|x|7 + 5|x|5 + 8|x| – 7
x2 + 1 dy
f (–x) = f (x), so graph is symmetrical about y-  2
dx =
x y
axis
f (0) = –7  1  dy
1 + 2  dx = y
for x > 0  x 
f ' (x) > 0  1 root Integrating both sides, we get
[28 June, 2022 (Shift-I)] 1
x − = ln y + c
x
55. (2) x = 1, y = e  c = –1
d
D = − loge 2 ( logcosx sin x ) 1
x − +1
dx  y=e x
[29 Jan, 2023 (Shift-I)]

[8]
57. (4) 61. (2)
Let tanθ = t Let point P (h, k ),M(1,2) and N (−2,1)

=
(1 − t 2 ) dt  (h −1)2 + (k − 2)2 − (h + 2)2 + (k −1)2  = 6
 
( t + 1)2  |(2h + 1) (– 3) + (2k – 3) (–1)| = 6

=
(1 − t ) dt  6h + 2k = 6
(1 + t )  3x + y = 3
 2   3x + y = 3 (for IIIrd quadrant)
=   −1 +
1 + t 
dt
  Area =
3
= −t + 2ln (1 + t ) + c 2
= − tan  + 2ln (1 + tan ) + c
[26 July, 2022 (Shift-I)]

[9 Jan, 2020 (Shift-II)] 62. (1)

dx
58. (2)  ( x − 1)3/4 ( x + 2)5/4
x4 x3
y= − + x2 + 3 ( 0  x  2) dx
12 2 = 3/4
x3 3 x 2  x −1 
dy
 =m= − + 2x  x+2 ( x + 2)3/4 ( x + 2)5/4
dx 3 2  
dx

dm
= x2 − 3x + 2 = ( x − 1)( x − 2) = 3/4
dx  x −1 
 x + 2  ( x + 2)
2
[26 Feb. 2021 (Shift-I)]  
x −1 3
59. (1) Put =t  dx = dt
Given, f(x) + f(π–x) = a x+2 ( x + 2)2
 1/4
I =  f ( x)sin 2 xdx …(i) 1 dt 1 t1/4 4  x −1 
0  
3 t 3/4
= 
3 1
+C = 
3  x + 2 
+C
On applying King's Rule, we get

4
I =  f ( − x)  sin 2 ( − x)dx  f (1) = 0
0
 [31 Aug, 2021 (Shift-I)]
I =  f ( − x)sin 2 xdx …(ii)
0
Equ (i) + Equ (ii) 63. (3)

2I =   f ( x ) + f (  − x ) sin 2 xdx
0
 /2
 2I =  a  sin xdx = 2a
2
 sin
2
x dx
0 0
a
 I=
4
[6 April, 2023 (Shift-II)]

60. (4) 1
 
f (x) = 3x3 + 2x – 7 A  x3/2   1 9 x
3
f ' (x) = 9x2 + 2 > 0 = 8  +  x 9 − x2 + sin −1 
Increasing function  invertible g(x) is inverse
2  3  2 2 3 1
 2 0
of f(x)
 g ( f ( x)) = x 2 1
( 1
= 8  + 3  0 + 9sin −1 (1) − 1 8 − 9sin −1 
3 2 3
)
Diff. w.r.t x
g '( f ( x)) f '( x) = 1 8 2  9 1
 A= +  − 2 2 − 9sin −1 
f (2) = 21, f ' (2) = 38 3  2 3
g' (21)  f ' (2) = 1 [29 Jan, 2023 (Shift-I)]
1
 g ' ( 2) =
38 64. (1)
[25 June, 2022 (Shift-I)] Let h(x) = f1(x) – f2(x) = 2x – 3sinx + x cos x
h(0) = 0
[9]
 h'(x) = 2 – 2cos x – x sin x 1
h''(x) = sin x – x cos x 4 f   + 3 f ( x) = 2 + x ....( ii )
 x
h'''(x) = x sin x Solving the equations we get
h'''(x) > 0  h''(x)>0 h'(x) > 0  h(x) > 0 4
7 f ( x ) = − 3x + 2
x
65. (4)
4
2x − 7 7 f '( x) = − 2 − 3
f '( x) = 0
( x − 2)( x − 5)
x
[13 April, 2023 (Shift-I)]
 7
 x   2,   ( 5,  )
 2 68. (2)
10 12
But domain x  (–, 2)  (5, )
 x dx = 5 &   x dx = 10 + 11 = 21
0 10
66. (1)
L :9x + 5 y = 45 …(i)
69. (3)
2  5 + 1 0 10
Px = = The given line is tangent to the curve at point (1,
1+ 2 3 6) and cuts the curve at (–2, –3)
0  2 + 9 1
Py = =3
 (x )
1
27
1+ 2 Area = 3
+ 5 − ( 3x + 3) dx =
−2
4
[12 April, 2023 (Shift-I)]

70. (4)
r0 = 3, t = 0
r = 7, t = 5
r = ?, t = 10
4
V = r 3
3
P(10/3, 3)
dV dr
1 5 + 2  0 5 = 4r 2
Similarly, Qx = = dt dt
1+ 2 3
dr
1 0 + 2  9  C = 4r 2 (C is constant)
Qy = =6 dt
1+ 2
dr C
Q : (5 / 3,6)  =
dt 4r 2
3
MR = PQ Integrating we get
2
 4r dr =  cdt + 
2
106
PQ =
9 4r 3
= Ct + 
3
3
Area = ( PQ )2 t = 0, r = 3
4   = 36
3 106
=  4
Ct = r 3 − 36
4 9 3
53 3 t = 5, r = 7
= 4
18 5C =  73 − 36 .....( i )
[6 April, 2023 (Shift-I)] 3
t = 10
4
67. (1) 10C = r 3 − 36 .....(ii )
1 3
Replace x → Using equations
x
1 1 r3 = 659
4 f ( x) + 3 f   = 2 + ....( i )
 
x x [24 June, 2022 (Shift-I)]

[10]
71. (0) 
−1
 =
( x+1)2 dx 4
I1 =  e
 answer
0
  1 6  1 6 
Let x + 1 = t
= 4  +  + (10 − 8)(10 − 9 ) = 3
dx = dt   2   2  
 
0
2
I1 =  et dt [29 July, 2022 (Shift-II)]
1
2 73. (25)
2/3 9 x − 2  2/3
 
dx = 3  e(3x−2) dx
2 2
 dy 
I2 
= 3 e  3 dy dy
y  + x − y − x = 0
1/3 1/3  dx  dx dx
Let 2 – 3x = t dy  dy   dy 
y  − 1 + x  − 1 = 0
–3dx = dt dx  dx   dx 
0
I 2 = − et dt
2  dy  dy 
 y dx + x  dx − 1 = 0
1   
I 1 + I2 = 0  either ydy + xdx = 0 or dy – dx = 0
Since the curves pass through the point (3, 4)
72. (3)  x2 + y2 = 25 or x – y + 1 = 0
Perpendicular length of vertex from given
diagonal 74. (0)
( cos  − sin ) 10 ( cos  − sin ) + 10 (sin  + cos ) 2
− 10 2x − 1
Let = z  y = f ( z)
= x2 + 1
( cos  − sin )2 + ( cos  + sin )2
dy dz
10  = f '( z ) 
= dx dx

( )
2 dz
 a = 10 = sin z 2  f ' ( z ) = sin z 2
dx
 (
103 + 12 10 + 5 m12 + m22 = 1130 ) 2
 2x − 1  d  2x −1 
= sin  2   
1  x + 1  dx  x2 + 1 
 m12 + = 2 (m1m2 = –1)
m12
= sin  2 
2
(
 2x − 1  2 1 + x − x
2
.
)
( m12 − 1) ( )
2
=0  x +1 x2 + 1
2

m1 = 1, –1 1 dy
At x = , =0
2 dx

75. (5)
2
y = x2 x
( )
ln y = 2 x2 ln x

m −1 1 dy 2 x2
tan 45 = = + 4 x  ln x
m +1 y dx x
dy
 m=0 = y  2 x + 4 x  ln x
− ( cos  − sin )
dx
Slope of given diagonal = dy
cos  + sin   = 1( 2 + 0 ) = 2
dx x=1
 
= tan   − 
 4
d2y   1  dy
  = y 2 + 4  x  + ln x  +  2 x + 4 x  ln x 
Slope of other diagonal = − cot   −  dx 2
  x  dx
 4

[11]
 −3
d2y d 2x 2
 dy  d y
= 1( 2 + 4 (1 + 0 ) ) + ( 2 + 0 )  2 = 10  = −  dx  
dx2 x =1
dy 2   dx2
Clearly  d 2x  1 5
−1   2  = −  10 = −
dx  dy   dy  8 4
=   x=1
dy  dx 
−2 [27 June. 2022 (Shift-II)]
d  dx   dy  d y
2
   = −  dx  
dx  dy    dx2
−2
d  dx  dy  dy  d y
2
    = −  dx  
dy  dy  dx   dx2

[12]