12th JEE Main

Additional Test

DURATION : 180 Minutes DATE : 16/01/2025 M.MARKS : 300

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (1) 26. (2) 51. (3)
2. (3) 27. (2) 52. (2)
3. (4) 28. (3) 53. (4)
4. (2) 29. (3) 54. (2)
5. (2) 30. (2) 55. (2)
6. (3) 31. (2) 56. (2)
7. (2) 32. (4) 57. (2)
8. (2) 33. (1) 58. (2)
9. (3) 34. (3) 59. (2)
10. (3) 35. (4) 60. (1)
11. (3) 36. (1) 61. (3)
12. (2) 62. (3)
37. (2)
13. (2) 63. (1)
14. (3) 38. (1)
64. (3)
15. (3) 39. (2)
65. (4)
16. (4) 40. (2)
66. (2)
17. (3) 41. (2)
67. (3)
18. (3) 42. (4)
68. (1)
19. (4) 43. (4)
69. (4)
20. (2) 44. (3)
70. (1)
21. (4) 45. (1)
71. (15)
22. (15) 46. (2)
72. (7)
23. (40) 47. (63)
73. (5)
24. (0) 48. (1)
74. (10)
49. (3)
25. (64) 75. (0)
50. (8)

[1]
 SECTION-I (PHYSICS)
1. (1) MR 2 5 11
M = + MR 2 = MR 2
2 At the mean position of plate A spring 4 2 4
K
Q2 9. (3)
will be elongated by
2 A0 K Ig × Rg = (I – Ig)R, putting values we get
R = 0.1 Ω
2. (3)
X 10. (3)
=
R0 100 − y 10  x 
=  2000 cos  2000t  
Since null point remains unchanged t   17 
X 40
=  R = 6Ω = 200 m/s
R 60
And 6 = 78Rt  Rt = 6.5Ω 11. (3)
Rt + 78 dQ = dU + dW  CdT = CV dT + PdV
Rt − R0
= = 8.3  10−4 K −1  C = Cv +
PdV
= Cv +
PdV
= Cv +
RT dV
R0t dT PV V dT
dT
RT
3. (4) 3R RT 1 3 R
N = mg − Tsin = +  = R + = 2R
2 V2 2 K 2 2
Tcos − N = ma
12. (2)
4. (2) 3m 3 R R
For COM, x=   x=
Let initial pressure of the three samples be PA, PB 4 4 2 6
and PC. mR 2
I1 (complete disc) = + mx 2
PA(V)3/2 = (2V)3/2P 2
PB = P mR 2 mR 2  19 
= + = mR 2  
PCV = P(2V) 2 36  36 
PA : PB : PC = (2)3/2 : 1 : 2 2
m R 1 m R I 
2
I 2 (colour disc) =       
4  2  2 4  6 2
5. (2) 2 2
The effective focal length of the given m R 1 M  R R
=    +  + 
42 2 4 6 2
combination is 1 = 2 + 1  f eff = 15 cm
f eff fL fM 2 mR 2 41 41
=  = mR
The effective combination behaves as a mirror 4 72 288
therefore we can calculate the location of final 111
image using mirror formula. I = I1 − I 2 = mR 2
288
1 1 1
= +
f u v
13. (2)
6. (3)
Electric field lines inside the sphere A and B is
not going to change

7. (2)
2ML2 3J V = arcosθ
JL =  =
3 2ML  V  
E( R ) = −   = (ar cos ) = − a cos 
 r 0 r
8. (2) V 1
E(0) = = +  ar sin  = a sin 
MR 2  MR 2  r ()r r
I Xx = + 2 + MR 2 
4  4  E = −a

[2]
14. (3) v 
x = Dtan = D  w  sec − tan
 vsw 
dx v 
 = D  w sectan − sec2  = 0
d  vsw 
vw
  tan − sec = 0
vsw
vsw 2
 sin = =
vw 3
So the angle with stream direction is equal to 90°
dFT = dmg.cos 
+ sin−12/3
.R cos d g
90
17. (3)
FT =  dFT = Rg  cos d  3v
45 vrell| = v + vcos60 =
2
FT Rg  1  4 g  2 − 1
aT = = 1− =   v 3
m   2R / 8  2   2  vrel ⊥ = vsin60 =
2
v
rel ⊥2 v 2  3 3v 2
15. (3) aN = = =
r 4  / 2 2l
 4k − k  3k
k( x ) =k +  .x = k + x
 d  d 18. (3)
 0 Ak( x ) Let the plank shifts to left by distance x
 dC =
L
M ( L − x ) = 2Mx  x = lim
dx
1 1 dx 1
d
dx 3 x→

C
=
dC 
=  = 
 0 Ak( x )  0 A x =0 k + 3k x So distance from O = + =
L L 5L
d 3 2 6
d
 3k 
log e  k +
d 0
x 19. (4)
1 
= . 2
0 A 3k  1 
Z = R2 + 
d   C 
1 d 2d log e 2  As we introduce dielectric, capacitance
 = .log e 4 =
C 3 0 kA 3 0 kA increases reducing the impedance of the
circuit.
3 0 kA  I rms increases
 C=
2d log e 2 20. (2)

16. (4)

36 m/s
= = 1.2 m
30
 0.3 m
vsw  cos = vs cos
21. (4)
vw − vsw  sin = vs sin As voltage across C is 30 V, voltage across 3 µF
vw − vswsin must be 60 V which implies both the capacitors
tan =
vswcos have same charge i.e., the bridge consisted of
vw capacitors is balanced
= sec − tan 3 2
vsw  = i.e., X = 4F
6 X
[3]
22. (15)  TA – TB = 0
1 1  U = 0
e yz = exyz − exy = B (2 R ) 2 − B ( R 2) 2
2 2

( )
1 25. (64)
= B 4 R 2 − 2 R 2 = B R 2
2 Mdl1
| E |= = M
2 dt
 10  −2
 e = 3  5  = 15  10 volt E − t
R
M  − t
R
 100  Then I 2 = 1 − e L  = 1 − e L 
R  R  
   
23. (40) M  M   1  M   e − 1
= 1 − e−1  = 1− =
1 C R   R  e  R  e 
I max = Q   = C  V  = v0
LC L 0.64M 
=
R
24. (0)
2 P0V0 2P V
TA = ; TB = 0 0
R R
SECTION-II (CHEMISTRY)
26. (2) 31. (2)
KMnO4 + FeSO4 + H+ → Fe3+ + Mn2+
 NH3  = 0.3 M  NH+4  = 0.2 M
 
Yellow colour due to Fe3+.
pOH = pK b + log
  = 4.74 + log 2
Salt
27. (2) base 3
= 4.74 + 0.30 – 0.48 = 4.56
pH = 14 – 4.56 = 9.44

32. (4)
−COOH + HCO3− →− COO− + CO2 + H2O
−SO3H + HCO3− →SO32− + CO2 + H2O
−CH2OH + HCO3− → No reaction
1
−COOH + Na → − COO − Na + + H 2
2
1
28. (3) −SO3H + Na → − SO3− Na + + H 2
2
The rate of the third bromination is greater than
1
the rate of the second bromination and the rate of −CH 2 OH + Na → − CH 2 O − Na + + H 2
the second bromination is greater than the rate of 2
the first bromination.
33. (1)
29. (3) Both are functional isomers not metamers
Since CN– and NO+ are iso eletronic, they have
bond order equal to 3 as per MOT. 34. (3)
Effect of temperature on equilibrium constant
30. (2) Based on Le Chatelier’s principle
For Balmer series, the electron de-excites from
nth orbit to 2nd orbit. The wave number of 35. (4)
emission spectrum of H-atom in Balmer series is Both NF3 and NH3 have identical shape and a
given by lone pair of electron on N-atom
 1 1  R ( n + 2 ) (n − 2)
v = R 2 − =
 (2) ( n) 2  4n 2

[4]
 41. (2)
If X, Y and Z do not form ppt with dil HCl and
form ppt with dil H2S in mineral acid it means
cation X, Y and Z belong to 2nd group. X and Y
are insoluble in ammonium poly sulphide it
means X and Y belongs to 2(1) and Z belongs to
BF3 has zero D.M. being symmetrical molecule 2(2).
Hence correct order is NH3 > NF3 > BF3
42. (4)

36. (1)
O
C OH
O
H OH 43. (4)
C H
Br2 + H2O HO H Oxymercuration - demarcation gives
H OH H OH Markovnikov's addition product but without
HO H H OH
H OH
rearrangement.
CH2OH
H OH Red. P + HI
CH3 (CH2)4 CH3
CH2OH
44. (3)
37. (2) None of fac or Mer isomer is optically active, so
enantiomers are not possible.
O O OH
LiAID4 H2O

D D 45. (1)
105 - Unp - Unnilpentium
38. (1)
H = U + P2 V2 − P1V1 46. (2)
Moles at eq. P2(g) + Q 2(g) 2PQ(g)
U = q + w
2− x 4− x 2x
q = 2740kJ 4x 2
4
Kc = x=
(2 − x)(4 − x) 3
1 
w = −Area ofplot = −   2  9 + 1  2   105 Pa m3 2 4 8
2  [PQ] = = Moles
3 4 3 4
= –1100 kJ
3 8
= = 2.0M
U = 2740 − 1100 = 1640kJ 3 4
H = 1640 + [1 4 − 10  2]  100 = 40kJ
47. (63)
39. (2) Meq. Of reductant in 25 mL = Meq. Of KMnO4
PCl+4 – sp hybridization → Tetrahedral
3
= 20 × 0.01 × 5
PCl−4 – sp d dhybridization with 1 → lp see saw
3
 Meq. Of reductant in 1 litre
AsCl3 – sp3 hybridization with 1 lp → Pyramidal = 20 × 0.01 × 5 × 40 = 40

40. (2) A+2 a → 2A+ b + 2e−

–CHO, and > C = 0 are  n-factor of A+2 a = 2
reduced by NaBH4 but not
 Meq. of reductant = 40
w
  1000 = 40
M/2

[5]
 2.52  2  1000 49. (3)
 = 40
M 8
Moles of Na2CO3.xH2O =
M 106 + 18x
 M = 126; = 63 If solution is diluted then number of moles of
2
Na2CO3⋅XH2O remain same.
8
48. (1) Moles of Na2CO3⋅xH2O in 1 L =
106 + 18x
rate = 10–5 [R – X][OH–] + 10–6 [R – X]
Moles of Na2CO3.xH2O in
% of S N 2 reaction
100 mL = 1  8 

−5 − 10  106 + 18x 
10 [R − X][OH ]
=  100
−
10 [R − X][OH − ] + 10−6 [R − X] 2 mol of HCl react with 1 mol of Na2CO3.xH2O
Moles of HCl = 10–2 × 1 = 0.01
10−5  [OH − ]
=  100 Moles of Na2CO3.xH2O
10−5 [OH − ] + 10−6 ⇒ 5 × 10–3 mol
At [OH–] = 0.0001 8 5
−5
= x=3
10  0.001 1060 + 180 x 1000
= −5
 100
10  0.001 + 10−6
50. (8)
10−8  100
=
10−8 + 100  10−8
100
= = 0.99%
101
x = two boron + four hydrogen atom having
2c – 2e bond
y = both boron

SECTION-III (MATHEMATICS)
51. (3)  x −1  5
f (2x) = f (2x + 1) f(x) = 5
 1 53. (4)
f ( x) = f  x + 
 2 100
For selecting any two numbers out 100 = C2
1
So period of f (x) is 100
2 P(S) = C2
So f (4) = f  2 + 1  4  Now number of ways for getting product of two
 2 
numbers is divisible by ‘3’ =
33
C2 +33 C1 67 C1
 1 
f (6) = f  2 +  8  33
C2 + 33  67
 2  So P( E ) = = 0.55
100
C2
 1 
f (8) = f  2 +  12  (where 33 is total number from 1 to 100 which is
 2 
multiple of 3)
So f (2) = f (4) = f (6) = f (8)
54. (2)
So value of f (2) + f (4) – (6) = f (8) = 0
n(S) = 3 × 3 × 3 × 3 = 81
n(E) = all four elements are 0
52. (2) + exactly three elements are 0
f ( x) = x − 1 + x + 24 − 10 x − 1 + exactly two elements are 0
+ no element is 0
1  x  26
n(E) = 1 + (4C3 × 2C1) + (4 × 2 × 2) + (1 + 1 + 4)
(5 − )
2
f ( x) = x − 1 + x −1 = 1 + 8 + 16 + 6 = 31

[6]
55. (2)  sin nx
= dx
x – 8  0, 8 – x  0 0 sin x
x=8 
 I n+ 2 − I n = 2 cos(n + 1) xdx = 0,if n  N ,
when x = 8. L.H.S = 0, R.H.S = 0 0
 x = 8 is only solution
61. (3)
56. (2) z1 + z2 + .zn =∣ ( z1 − 1) + ( z2 − 2 ) + 

f ( x ) = e x , g ( x ) = x, x  0 + ( zn − n) + (1 + 2 + 3 + .n ) |
 z1 − 1 + z2 − 2 + . + zn − n + (1 + 2 + + n )
f ( t ) =  f ( t − x )  g ( x ) dx
t
0  (1 + 2 + 3 + . + n ) + (1 + 2 + 3 + . + n )
 n ( n + 1) 
t t−x
= e  xdx
0 = 2.  = n ( n + 1)
t  2 
= et  e− x  xdx
0  z1 + z2 + .zn  n ( n + 1)
 
( )
t t
= et  − xe− x −  −e− x dx  Hence maximum value of z1 + z2 + .zn is
 0 0  n(n +1).

( ) ( )0
t
= et −te−t + et −e− x
62. (3)
= −t + et −e−t + 1( ) Let 2, 4, 5, 6, 8, 17 is xi.
Then 5, 11, 14, 17, 23, 50 can be represented by
= −t − 1 + et ( 3xi − 1) .
 Required variance = 9 × 23.33 = 209.97
= et − ( t + 1)
63. (1)
57. (2) For PR − PQ to be maximum, P should lie on
Applying componendo and dividendo we get the line segment joining R and Q.
dy e− x x y
= x = e−2 x Equation of QR is + = 1 −x + y = a
dx e −a a
 2 y = −e −2 x + C
 2 ye2 x = C e2 x − 1

58. (2)
b2 a 2e2
1− 2
= 1 − 2
 e2  e − 1 = 0
a b
5 −1
e=  (a + x)2 = 4ax
2
 x = a, y = 2a
59. (2) So, line QR, on extending intersects the parabola
f(g(x)) = x at M, so M is (a, 2a).
f  ( g ( x ) ) .g  ( x ) = 1 64. (3)
1 3− 2
g ( 2) = Slope of IB, m1 = =1
f ( a) 2 −1
Slope of BC, m2 = 2 + 3
a2 + 1
=
a10

60. (1)
 sin nx + 2 x cos x
In =  dx
− (1 + 4 x )sin x
 −x
 sin nx + 2 cos x − sin nx + 2 cos x 
x
=  +  dx
(1 + 4− x ) ( − sin x)  m2 − m1
 (1 + 4 )sin x
x
 IBC =  = tan −1
0
1 + m2 m1

[7]
 67. (3)
−1 2 + 3 −1
= tan
(
1+ 2 + 3 ) y = f(x)

1+ 3
= tan −1
3+ 3

1+ 3
= tan −1
(
3 1+ 3 )
1
= tan −1
3
= 30° 68. (1)
 ABC = 2 = 60o (1, 2)  R and (2, 1)  R
Second method :  R is reflexive but not symmetric
IE
sin  = 69. (4)
BI
3 +1 | a + b + c |= 9 + 15 + 25
IE =
2 3 + 2  | a + b + c |= 5 2
BI = 2
70. (1)
3 +1 1 3 +1
sin  = = = I = I1 − 2 I 2 = 
dx
− 2
dx
2 2 3+2 2 4+2 3 2 8 4 4
ex + x
+ 3x
e3 x + 8e x +
e e ex
(e3 x − 2e x ) dx
=
e4 x + 8e2 x + 4
e x (e2 x − 2)dx
= , put ex = t
(e ) + 8(e ) + 4
x 4 x 2

(
y = 2+ 3 x− 3 )  ex dx = dt
θ = 30º, 2θ = 60º (t 2 − 2) dt
= 4
t + 8t 2 + 4
 2  2
65. (4) 1 − 2  dt 1 − 2  dt
= t  =  t 
15 15  1 1  4  2
2
x15 + = x +  + + .....15times  t2 + 8 + 2 +
2
x  x x  t  t  − 2t  + 8
 t  t
Applying A.M – G.M inequality  2
 1 − 2  dt
=   t 2
2
put t + = z
1 1   2 t
x15 +  + + ...... + 15 times  1
t +  + 4
 x x    x15   ..... 
1 1 1 16  t
 
16  x x x  2
 1 − 2  dt = dz
x15 +
15  t 
 x 1 dz 1 z
16 = = tan −1   + c
z +4
2 2 2
15
Minimum value of x 15
+ is 16.  2
x  t+ 
1
= tan −1  t +c

2  2 
66. (2)  
(1 + 20)100 = 1 + 100C1 ( 20 ) + 100C2 (20)2 + .....
1
1  t2 + 2  1  e2 x + 2 
= tan −1   + c = tan −1  +c
 01 2  2t  2  2e x 
   

[8]
71. (15) 73. (5)
Six number in A.P. are a – 5d, a – 3d, a – d, a + Y = x3 − 2 x 2 + x + 5
d, a + 3d, a + 5d  f (0) = 5
according to question 6a = 3
1
a= 74. (10)
2
OP  iˆ = 2  x=2
Also, (a – 5d) = 4(a – d)
a – 5d = 4a – 4d P  (2, 125) & Q  (– 2, – 115)
3a = –d
3 75. (0)
d =−
2 dy y 1 1 1
− 2 tan   = − sec    2 (linear)
Terms of A.P. are 8, 5, 2, –1, –4, –7 dx x  x  x x
1 
 − x 2 tan x dx
1
72. (7)  e = sec  
 x
x3 y3 z3
+ + 1 1
( x − z )( x − y ) ( y − x)( y − z ) ( z − x)( z − y )  solution y sec = tan + k
x x
( x + y + z )( x − y )( y − z )( z − x) y → −1 as x → 
= = x+ y+ z
( x − y )( y − z )( z − x)
 k = –1
 Total number of possible values = 7 1 1
 y = sin − cos
x x

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[9]