JEE Main - 2024 (30 Jan.

Shift-2)
MATHEMATICS
1. For α, β  (0, π/2), let 3sin(α + β) = 2sin(α – β) 6. Let f:R→R be a function defined by
and a real number k be such that tan α = k tan β. x
f (x) = , and g(x) = f (f (f (f (x)))).
Then, the value of k is equal to (1 + x 4 )1/4
[Trigonometric Ratio] 2 5 2
(1) –5 (2) 5 Then, 18 x g(x)dx is equal to
0
(3) 2/3 (4) –2/3 [Definite Integration]
(1) 33 (2) 36
2. Suppose 2– p, p, 2 – α, α are the coefficients of (3) 42 (4) 39
four consecutive terms in the expansion of (1 + x)n.
Then the value of p2 – α2 + 6α + 2p equals 7. If the domain of the function
[Binomial Theorem]  2x + 3  −1  2x − 1 
f (x) = loge   + cos   is
2
 4x + x − 3   x +2 
(1) 8 (2) 6
(3) 10 (4) 4 (, ] , then the value of 5 – 4 is equal to
[Function]
3. Let f : R – {0} → R be a function satisfying (1) 12 (2) 9
(3) 10 (4) 11
 x  f (x)
f = for all x, y, f(y)  0. If f(1) = 8. Consider the system of linear equations x + y + z = 5,
 y  f (y)
x + 2y + 2z = 9, x + 3y + z = , where , 
2024, then
 R. Then, which of the following statement is
[Function] NOT correct?
(1) xf(x) + f(x) = 2024 [Determinant]
(2) xf(x) – 2023 f(x) = 0 (1) System has infinite number of solutions if
(3) xf(x) – 2024 f(x) = 0 λ = 1 and μ =13
(2) System has unique solution if   1 and μ  13
(4) xf(x) + 2024 f(x) = 0
(3) System is inconsistent if  = 1 and μ  13
(4) System is consistent if   1 and  =13
4. Let A(, 0) and B(0, ) be the points on the line
5x + 7y = 50. Let the point P divide the line 9. Let y = f(x) be a thrice differentiable function in
segment AB internally in the ratio 7:3. Let 3x– (–5, 5). Let the tangents to the curve y = f(x) at
25 = 0 be a directrix of the ellipse (1, f(1)) and (3, f(3)) make angels /6 and /4,
respectively with positive x-axis. If
x2 y2 3
( )
E: + = 1 and the corresponding focus be  2 
a 2 b2 27  f  (t) + 1f (t)dt =  +  3 where  
S. If from S, the perpendicular on the x-axis 1 
passes through P, then the length of the latus are integers, then the value of  +  equals
rectum of E is equal to, [Application of Derivative]
[Ellipse] (1) – 14 (2) – 16
32 25 (3) 36 (4) 26
(1) (2)
5 9
10. Let a and b be be two distinct positive real
32 25
(3) (4) numbers. Let 11th term of a GP, whose first term
9 3
is a and third term is b, is equal to pth term of
5. Let f(x) = (x + 3)2 (x – 2)3, x  [–4, 4]. If M and another GP, whose first term is a and fifth term
m are the maximum and minimum values of f, is b. Then p is equal to
respectively in [–4, 4], then the value of M – m is [Sequence & Series]
[Application of Derivative] (1) 25 (2) 20
(1) 108 (2) 600 (3) 21 (4) 24
(3) 608 (4) 392
[1]
11. Let a and b be two vectors such that | b | = 1and
17. Let f: R →R be defined as f(x) = ae2x + bex +cx.
| b  a |= 2. Then | (b  a) − b |2 is equal to
If f(0) = –1, f  ( loge 2) = 21 and
[Vector]
loge 4 39
(1) 1 (2) 3 0 (f (x) − cx)dx =
2
, then the value of |a + b
(3) 4 (4) 5
+ c| equals
12. Bag A contains 3 white, 7 red balls and Bag B [Definite Integration]
contains 3 white, 2 red balls. One bag is selected (1) 10 (2) 16
at random and a ball is drawn from it. The (3) 12 (4) 8
probability of drawing the ball from the bag A,
if the ball drawn is white, is 18. Let P be a point on the hyperbola
[Probability] x 2 y2
(1) 1/9 (2) 1/4
H: − = 1 , in the first quadrant such that
9 4
(3) 3/10 (4) 1/3 the area of triangle formed by P and the two foci

13. Let L1 : r = (iˆ − ˆj + 2k)

ˆ + (iˆ − ˆj + 2k),
ˆ  R of H is 2 13 . Then, the square of the distance
of P from the origin is
L2 : r = (jˆ − k)
ˆ +(3iˆ + ˆj + pk),
ˆ  R, and
[Hyperbola]
L : r = ( ˆi + mjˆ + nk),
3
ˆ  R (1) 20 (2) 18
be three lines such that L1 is perpendicular to L2 (3) 26 (4) 22
and L3 is perpendicular to both L1 and L2. Then,
the point which lies on L3 is 19. Let a = ˆi + ˆj +k,
ˆ , . Let a vector b be
[3-D]

(1) (1, 7, –4) (2) (–1, 7, 4) such that the angle between a and b is and
4
(3) (1, –7, 4) (4) (–1, –7, 4) 2
b =6. If a  b = 3 2 , then the value of
14. Let a and b be real constants such that the
(a )
2
function f defined by
2
+ 2 a  b is equal to
x 2 + 3x + a ,x  1 [Vector]
f (x) =  be differentiable on
bx + 2 ,x  1 (1) 75 (2) 95
2 (3) 85 (4) 90
R. Then, the value of  f (x)dx equals.  x 0 0
−2
20. Let R =  0 y 0  be a non-zero 3 × 3 matrix,
[Differentiability] 0 0 z
 
(1) 15/6 (2) 19/6
(3) 17 (4) 21  2 
where xsin  = ysin   + 
 3 
15. If z is a complex number, then the number of
common roots of the equations  4 
=z sin   +   0,  (0,2) . For a square
z1985 + z100 + 1 = 0 and z3 + 2z2 + 2z + 1 = 0, is  3 
equal to matrix M, let trace (M) denote the sum of all the
[Complex Number-I] diagonal entries of M. Then, among the
(1) 0 (2) 3 statements:
(3) 2 (4) 1 (I) Trace (R) = 0
(II) If trace (adj(adj(R)) = 0 , then R has exactly
16. If x2 – y2 + 2hxy + 2gx + 2fy + c = 0 is the locus
of a point, which moves such that it is always one non-zero entry.
equidistant from the lines x + 2y + 7 = 0 and [Matrix]
2x – y + 8 = 0, then the value of g + c + h – f (1) Both (I) and (II) are true
equals (2) Only (I) is true
[Straight Line] (3) Neither (I) nor (II) is true
(1) 14 (2) 29
(3) 6 (4) 8 (4) Only (II) is true

[4]
 27. In an examination of Mathematies paper, there
21. The number of real solution of the equation are 20 questions of equal marks and the question
( )
x x 2 + 3 x + 5 x − 1 x − 2 = 0 is paper is divided into three sections: A, B and C.
A student is required to attempt total 15
[Function] questions taking at least 4 questions from each
section. If section A has 8 questions, section B
22. Let Y=Y(X) be a curve lying in the first has 6 questions and section C has 6 questions,
quadrant such that the area enclosed by the line then the total number of ways a student can
Y–y = Y'(x)(X–x) and the co-ordinate axes, select 15 questions is
where (x, y) is any point on the curve, is always [P & C]
− y2
+ 1 , Y (x)  0 . If Y(1)=1, then 12Y(2)
2Y (x) 28. Let Sn be the sum to n-terms of an arithmetic
progression 3, 7, 11, ........ If
equals_______
[Straight Line]  6 n 
40    Sk   42 , then n equals____
 ( + 1) k =1 
n n
23. The variance  2 of the data [Sequence & Series]

xi 0 1 5 6 10 12 17 29. Consider two circles C1: x2 + y2 = 25 and C2:(x–a)2

fi 3 2 3 2 6 3 3 +y2 =16, where   (5,9) . Let the angle
is between the two radii (one to each circle) drawn
[Statistics] from one of the intersection points of C1 and C2
 63 

Let  =  
n (
 nC 2 
)
 and  =  Ck Ck +1 
n −1 n n be sin −1   . If the length of common chord
 8 

k
24.  
 
k =0  k + 1  k =0  k+2 
  of C1 and C2 is  then the value of ()2 equals
If 5 = 6, then n equals [Circle]
[Binomial Theorem]
30. Let a line passing through the point (–1, 2, 3)
25. The number of symmetric relations defined on x −1 y − 2 z +1
intersect the lines L1 : = = at
the set {1, 2, 3, 4} which are not reflexive is __ 3 2 −2
[Relation] x + 2 y − 2 z −1
M(, , ) and L2: = = at
−3 −2 4
26. The area of the region enclosed by the parabola
( +  + )2
(y – 2)2 = x – 1, the line x –2y + 4 = 0 and the N(a, b, c). Then, the value of
positive coordinate axes is _______ (a + b + c)2
[Area Under the Curve] equals___________
[3-D]

[5]
 Physics
31. A particle of charge '–q' and mass 'm' moves in a
circle of radius 'r' around an infinitely long line
charge of linear charge density '+  '. Then time (2)
period will be given as:
(Consider k as Coulomb's constant)
[Electric Charge & Field]
1 2kq
(1) T =
2 m
(3)
m
(2) T = 2r
2kq
1 m
(3) T =
2r 2kq
42 m 3
(4) T 2 = r
2kq (4)

32. For the photoelectric effect, the maximum

kinetic energy (Ek) of the photoelectrons is
plotted against the frequency (v) of the incident
photons as shown in figure. The slope of the  5
34. If three moles of monoatomic gas   =  is
graph gives  3
mixed with two moles of a diatomic gas
 7
  = 5  , the value of adiabatic exponent  for
 
the mixture is
[Dual Nature of Radiation & Matter] [Thermodynamics & KTG]
(1) Planck's constant (1) 1.40 (2) 1.52
(2) Ratio of Planck's constant to electric charge
(3) 1.75 (4) 1.35
(3) Charge of electron
(4) Work function of the metal
35. In a nuclear fission reaction of an isotope of
33. A block of ice at –10ºC is slowly heated and mass M, Three similar daughter nuclei of same
converted to steam at 100ºC. Which of the mass are formed. The speed of a daughter nuclei
following curves represent the phenomenon in terms of mass defect M will be:
qualitatively:
[Nuclear Physics]
[Thermal Properties of Matter]
2cM Mc2
(1) (2)
M 3

(1) 3M 2M

(3) c (4) c
M M

[6]
36. Match List -I with List-II 10 m along inclined surface, the work done
List-I List-II against frictional force is:
[g = 10 m/s2]
A Gauss's law of I 1
magnetostatics  [Link] =   pdV [Work, Power & Energy]
0

B Faraday's law of II
 [Link] = 0
electro magnetic
induction
C Ampere's law III −d
 [Link] = dt  [Link]
D Gauss' law of IV
 [Link] = 0I
electrostatics (1) 5 3 J (2) 5 J
Choose the correct answer from the options (3) 10 J (4) 5 ×103 J
given below:
[Electromagnetic Waves] 41. In the given circuit the voltage across load
(1) A–I, B–III, C–IV, D–II resistance (RL) is:
[Semiconductors]
(2) A–IV, B–II, C–III, D–I 1.5 k
(3) A–III, B–IV, C–I, D–II
(4) A–II, B–III, C–IV, D–I D1 D2
15 v (Ge) (Si) RL 2.5 k
37. Three blocks A, B and C are pulled on a
horizontal smooth surface by a force of 80 N as
shown in figure (1) 14.00 V (2) 8.50 V
A B C (3) 9.00 V (4) 8.75 V
T1 T2 F = 80 N
5 kg 3 kg 2 kg
42. Choose the correct statement for processes A & B
The tension T1 and T2 in the string are shown in figure.
respectively: [Thermodynamics & KTG]
[NLM]
(1) 88N, 96 N (2) 40 N, 64 N
(3) 60 N, 80 N (4) 80 N, 100 N

38. If the total energy transferred to a surface in

time t is 6.48 ×105 J, then the magnitude of the
total momentum delivered to this surface for
complete absorption will be: P−1
(1) = k for process B and T = k for process A
[Dual Nature of Radiation & Matter] T
(1) 2.46 ×10–3 kg m/s (2) 2.16 ×10–3 kg m/s (2) PV = k for process B and A.
(3) 1.58 ×10–3 kg m/s (4) 4.32 ×10–3 kg m/s (3) PV = k for process B and PV = k for
process A.
39. Escape velocity of a body from earth is 11.2 km/s. T
(4) = k for process A and PV = k for
If the radius of a planet be one third the radius of P−1
earth and mass be one -sixth that of earth, the process B.
escape velocity from the planet is:
[Gravitation] 43. Projectiles A and B are thrown at angles of 45º
and 60º with vertical respective from top of a
(1) 11.2 km/s (2) 4.2 km/s 400 m high tower. If their ranges and times of
(3) 8.4 km/s (4) 7.9 km/s flight are same, the ratio of their speed of
projection VA ;VB is : [Take g = 10 ms–2]
40. A block of mass 1 kg is pushed up a surface [Motion in a Plane]
inclined to horizontal at an angle of 60º by a (1) 1 : 2 (2) 2:1
force of 10 N parallel to the incline surface as
shown in figure. When the block is pushed up by (3) 1: 2 (4) 1: 3
[
6]
44. A block of mass m is placed on a surface having
vertical cross section given by y = x2 / 4 . If 51. A power transmission line feeds input power at
2.3 kV to a step down transformer with its
coefficient of friction is 0.5 the maximum height primary winding having 3000 turns. The output
above the ground at which block can be placed power is delivered at 230 V by the transformer.
without slipping is: The current in the primary of the transformer is
[Friction] 5 A and its efficiency is 90 %. The winding of
(1) 1/2 m (2) 1/6 m transformer is made of copper. The output
(3) 1/3 m (4) 1/4 m current of transformer is______ A.
[Alternating Current]
45. If 50 Vernier divisions are equal to 49 main
scale division of a traveling microscope and one 52. Two dises of moment of inertia I1=4 kg m2 and
smallest reading of main scale is 0.5 mm, the I2 = 2 kg m2, about their central axes & normal
Vernier constant of traveling microscope is to their planes, rotating with angular speeds 10
[Unit & Measurement] rad/s & 4rad/s respectively are brought into
(1) 0.01 mm (2) 0.01 cm contact face to face with their axes of rotation
(3) 0.1 mm (4) 0.1 cm coincident. The loss in kinetic energy of the
system in the process is J.
46. An electron revolving in nth Bohr orbits has [Rotational Motion]
magnetic moment  n .If n n x , the value of x is 53. In an experiment to measure the focal length (f)
[Atomic Physics] of a convex lens, the magnitude of object
(1) 2 (2) 0 distance (x) and the image distance (y) are
(3) 3 (4) 1 measured with reference to the focal point of the
lens. The y–x plot is shown in figure. The focal
47. If mass is written as m = kcPG−1/2h1/2 then the length of the lens is cm
value of P will be: (Constant have their usual [Ray Optics]
meaning with k  dimensionless constant) 40
[Unit & Measurement] A
(1) 1/2 (2) 2 30 y B
(3) –1/3 (4) 1/3 (cm)
C
20
48. When a potential difference V is applied across D E
a wire of resistance R, it dissipates energy at a 10
rate W. If the wire is cut two halves and these
halves are connected mutually parallel across the
x (cm)
same supply, the energy dissipation rate will
10 20 30 40
become:
[Current Electricity]
(1) 1/4 W (2) 4W 54. Two resistance of 100  and 200  are
(3) 1/2 W (4) 2W connected in series with a battery of 4V and
negligible internal resistance. A voltmeter is
49. A beam of unpolarised light of intensity I0 is used to measure voltage across 100 resistance,
passed through a polaroid A and then through which gives reading as 1V. The resistance of
another polaroid B which is oriented so that its
principal plane makes an angle of 45º relative to voltmeter must be________.
that of A. The intensity of emergent light is: [Current Electricity]
[Wave Optics]
(1) I0 / 2 (2) I0 55. Two identical charged spheres are suspended by
(3) I0 / 8 (4) I0 / 4 strings of equal lengths. The strings make an
angle of 37º with each other. When suspended in
50. An alternating voltage V(t) = 220sin100 t volt
a liquid of density 0.7 g/cm3, the angle remains
is applied to a purely resistive load of 50 . The
same. If density of material of the sphere is
time taken for the current to rise from half of the
peak value to the peak value is: 1.4 g/cm3, the dielectric constant of the liquid is
[Alternating Current]   3
(1) 3.3 ms (2) 5 ms  tan37 = 4 
 
(3) 2.2 ms (4) 7.2 ms
[Electric Charge & Field]
[
7]
 [Mechanical properties of Fluid]
56. A point source is emitting sound waves of 59. The current of 5A flows in a square loop of side
intensity 16×10–8 Wm–2 at the origin. The 1m is placed in air. The magnetic field at the
difference in intensity (magnitude only) at two centre of the loop is x 2 10−7 T. The value of
points located at a distances of 2m and 4m from X is _________
the origin respectively will be_______×10–8 [Moving Charge & Magnetism]
Wm–2
[Waves] 60. A vector has magnitude same as that of
A = 3i + 4j and is parallel to B = 4i + 3j . The x
57. A simple pendulum is placed at a place where its
and y components of this vector in first quadrant
distance from the earth's surface is equal to the
are x and 3 respectively where x = _________
radius of the earth. If the length of the string is
[Vectors]
4m, then the time period of small oscillations
will be s.______ [take g = 2 ms–2]
[Gravitation]

58. A big drop is formed by coalescing 1000 small

identical drops of water. If E1 be the total
surface energy of 1000 small drops of water and
E2 be the surface energy of single big drop of
water, then E1: E2 is x: 1 where x= ______

[
8]
 CHEMISTRY
61. The coordination geometry around the 65. Reduction potential of ions are given below:
manganese in decacarbonyldimanganese (0) is ClO−4 lO−4 BrO−4
[Co-ordination Compound] E0 = 1.19 V E0 = 1.65 V E0 = 1.74 V
(1) Square pyramidal The correct order of their oxidising power is:
(2) Octahedral [p-Block]
(3) Trigonal bipyramidal − −
(1) BrO4  IO4  ClO4 −

(4) Square planar

(2) BrO−4  ClO−4  IO−4

62. Given below are two statements: (3) IO−4  BrO−4  ClO−4
Statement-I: Along the period, the chemical (4) ClO−4  IO−4  BrO−4
reactivity of the elements gradually increases
from group 1 to group 18. 66. The solution from the following with highest
Statement-II: The nature of oxides formed by depression in freezing point/lowest freezing
group 1 elements is basic while that of group 17 point is
elements is acidic. [Solution]
(1) 180 g of benzoic acid dissolved in benzene
In the light of the above statements, choose the
(2) 180 g of acetic acid dissolved in benzene
most appropriate from the options given below: (3) 180 g of acetic acid dissolved in water
[Periodic Classification] (4) 180 g of glucose dissolved in water
(1) Both Statement I and Statement II are False
(2) Both Statement I and Statement II are True 67. Alkaline oxidative fusion of MnO2 gives "A"
(3) Statement I is True But Statement II is which on electrolytic oxidation in alkaline
False solution produces B. A and B respectively are
[d & f Block]
(4) Statement I is False but statement I is true
(1) Mn 2 O7 and MnO−4
63. If a substance 'A' dissolves in solution of a (2) MnO24− and MnO7
mixture of 'B' and 'C' with their respective (3) MnO24− and MnO−4
number of moles as nA,nB and nC, Mole fraction
(4) Mn 2 O3 and MnO24−
of C in the solution is
[Solution]
68. Given below are two statements:
nC nC Statement-I: Since Fluorine is more
(1) (2)
n A − n B − nC n A + n B + nC electronegative than nitrogen, the net dipole
nB nC moment of NF3 is greater than NH3.
(3) (4) Statement-II: In NH3, the orbital dipole due to
nA + nB n A  n B  nC lone pair and the dipole moment of NH bonds
are in opposite direction, but in NF3 the orbital
64. A and B formed in the following reactions are: dipole due to lone pair and dipole moments of
CrO2Cl2 + 4NaOH → A + 2NaCl + 2H2 O N-F bonds are in same direction.
In the light of the above statements, choose the
A + 2HCl + 2H2O2 → B + 3H2O most appropriate from the options given below:
[Salt Analysis] [Chemical Bonding]
(1) A = Na 2Cr2O4 , B = CrO4 (1) Statement I is true but Statement II is false.
(2) A = Na 2Cr2O7 , B = CrO3 (2) Both Statement I and Statement II are true.
(3) Statement I is false but Statement II is true.
(3) A = Na 2Cr2O7 , B = CrO5
(4) Both Statement I and Statement II are false.
(4) A = Na 2CrO4 , B = CrO5

[
9]
69. Given below are two statements: One is labelled O O

as Assertion A and the other is labelled as C–H C–H

(1) +
Reason R:
Assertion A: H2 Te is more acidic than H2S. OH OH
Reason R: Bond dissociation enthalpy of H2Te
is lower than H2S. (2)
In the light of the above statements, choose the
most appropriate from the options given below:
[p-Block] (3)
(1) Both A and R are true and R is the correct
explanation of A.
(2) A is true but R is false. (4)
(3) Both A and R are true but R is NOT the
correct explanation of A.
74. Given below are two statements:
(4) A is false but R is true. Statement-I: High concentration of strong
nucleophilic reagent with secondary alkyl
halides which do not have bulky substituents
70. The molecule / ion with square pyramidal shape is
will follow SN2 mechanism.
[Chemical Bonding] Statement-II: A secondary alkyl halide when
treated with a large excess of ethanol follows
(1)  Ni(CN)4 2− (2) PCl5
SN1 mechanism.
(3) PF5 (4) BrF5 In the light of the above statements, choose the
most appropriate from the options given below:
[Haloalkane & Haloarenes]
71. Salicylaldehyde is synthesized from phenol, (1) Both Statement I and Statement II are false.
when reacted with (2) Statement I is true but Statement II is false.
(3) Statement I is false but Statement II is true.
[Aldehyde, Ketone] (4) Both Statement I and Statement II are true.
(1) CCl4, NaOH
75. Choose the correct statements about the
(2) HCCl3, NaOH
hydrides of group 15 elements.
(3) CO2, NaOH [p-Block]
O (A) The stability of the hydrides decreases in
the order NH3  PH3  AsH3  SbH3 >BiH3
(4) H Cl , NaOH (B) The reducing ability of the hydride
increases in the order NH3<
PH3<AsH3<SbH3<BiH3
72. Which among the following purification (C) Among the hydrides, NH3 is strong
methods is based on the principle of "Solubility" reducing agent while BiH3 is mild reducing
in two different solvents? agent.
(D) The basicity of the hydrides increases in the
[POC] order NH3  PH3  AsH3  SbH3  BiH3
(1) Distillation Choose the most appropriate from the options
(2) Sublimation given below:
(1) A and B only (2) A and D only
(3) Differential Extraction
(3) B and C only (4) C and D only
(4) Column Chromatography
76. The correct stability order of carbocations is
73. M-chlorobenzaldehyde on treatment with 50% [GOC]
KOH solution yields + + +

[Aldehyde, Ketone] (1) (CH3 )3 C+  CH3 − CH2  (CH3 )2 CH  CH3

+ + + +
(2) CH3  ( CH3 )2 CH  CH3 − CH2  ( CH3 )3 C

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 + + +
CH3  CH3 − CH2  CH3 – CH  ( CH3 ) C+
(3) |
CH3 (2)
+ + + +
(4) (CH3 )3 C  (CH3 )2 CH  CH3 − CH2  CH3
77. The orange colour of K2Cr2O7 and purple colour (3)
of KMnO4 is due to
[d & f Block]
(1) d→d transitions in K2Cr2O7 and charge
(4)
transfer transitions in KMnO4.
(2) d→d transitions in KMnO4 and charge
transfer transitions in K2Cr2O7.
(3) Charge transfer transition in both. 81. Number of metal ions characterized by flame
(4) d → d transitions in both test among the following is_________________
Sr 2+ ,Ba 2+ ,Ca 2+ ,Cu 2+ , Zn 2+ ,Co 2+ ,Fe 2+
78. The products A and B formed in the following
reaction scheme are respectively [Salt Abalysis]

82. Total number of species from the following

which can undergo disproportionation reaction
is___ H2O2 ,ClO3− ,P4 ,Cl2 ,Ag,Cu +1, F2 ,NO2 , K+
[Amine]
[d-Block]
(1) 83. Two reactions are given below:
3 
2Fe(s) + O2( g) → Fe2O3( s) , H = −822 kJ / mol
2
(2) 1
C(s) + O2( g) → CO(g) , H = −110 kJ / mol
2
Then enthalpy change for following reaction
3C(s) + Fe2O3(s) → 2Fe(s) + 3CO(g) is kJ mol.
(3) 84. NO2 required for a reaction is produced by
decomposition of N2O5 in CCl4 as by equation
2 N2O5( g) → 4NO2( g) + O2( g)
(4)
The initial concetration. of N2O5 is 3mol L–1 and
it is 2.75 mol L–1 after 30 minutes. The rate of
79. IUPAC name of following compound is: formation of NO2 is x×10–3 mol L–1 min–1, value
CH3 − CH − CH 2 − CN of x is (nearest integer)
| [Chemical Kinetics]
[Nomenclature]
NH 2 85. Number of complexes which show optical
isomerism among the following is
(1) 2-Aminobutanenitrile 3− 3+
cis − Cr ( ox )2 Cl2  , Co (en )3  ,cis − Pt (en )2 Cl2 
2+
,
 
(2) 3-Aminopropanenitrile + 2+
(3) 3-Aminobutanenitrile cis − Co (en )2 Cl2  trans- − Pt ( en )2 Cl2  ,
(4) 2-Aminopentanenitrile 3−
trans − Cr ( ox )2 Cl2 
[Co-ordination Compound]
80. Products A and B formed in the following set of
reactions are
86. The pH of an aqueous solution containing 1M
benzoic acid (pKa = 4.20) and 1 M sodium
benzoate is 4.5. The volume of benzoic acid
solution in 300 mL of this buffer solution
[Hydrocarbon] is__________ mL. (given: log 2 = 0.3)
[Ionic Equilibrium]
(1)

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87. The total number of correct statements,
regarding the nucleic acids is 89. Number of geometrical isomers possible for the
[Biomolecules] given structure is/ are________
(1) RNA is regarded as the reserve of genetic [Isomerism]
information
(2) DNA molecule self-duplicates during cell
division
(3) DNA synthesizes proteins in the cell
(4) The message for the synthesis of particular
proteins is present in DNA
(5) Identical DNA strands are transferred to
daughter cells.
90. Number of spectral lines obtained in He+
spectra, when an electron makes transition from
88. 2-chlorobutane + Cl2 → C4H8Cl2 (isomers) Total
fifth excited state to first excited state will be
number of optically active isomers shown
[Atomic Structure]
by C4H8Cl2, obtained in the above reaction
is_____
[Hydrocarbon]

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 Answer key
Mathematics
1. (1) 11. (4) 21. (1)
2. (1) 12. (4) 22. (20)
3. (3) 13. (2) 23. (29)
4. (1) 14. (3) 24. (10)
5. (3) 15. (3) 25. (960)
6. (4) 16. (1) 26. (5)
7. (1) 17. (4) 27. (11376)
8. (2) 18. (4) 28. (9)
9. (4) 19. (4) 29. (1575)
10. (3) 20. (4) 30. (196)

Physics

31. (2) 41. (4) 51. (45)

32. (1) 42. (3) 52. (24)
33. (3) 43. (3) 53. (20)
34. (2) 44. (4) 54. (200)
35. (4) 45. (1) 55. (2)
36. (4) 46. (4) 56. (3)
37. (2) 47. (1) 57. (8)
38. (2) 48. (2) 58. (10)
39. (4) 49. (4) 59. (40)
40. (2) 50. (1) 60. (4)

Chemistry

61. (2) 71. (2) 81. (4)

62. (4) 72. (3) 82. (6)
63. (2) 73. (4) 83. (492)
64. (4) 74. (4) 84. (17)
65. (1) 75. (1) 85. (4)
66. (3) 76. (4) 86. (100)
67. (3) 77. (3) 87. (3)
68. (4) 78. (4) 88. (3)
69. (1) 79. (3) 89. (4)
70. (4) 80. (2) 90. (10)

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