According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
SAFETY DATA SHEET
AQUA-PETROSOL
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name
AQUA-PETROSOL
Product no.
6006
▼Unique formula identifier (UFI)
4MMH-605R-F001-YFUJ
1.2. Relevant identified uses of the substance or mixture and uses advised against
▼Relevant identified uses of the substance or mixture
oil . Dirt remover
Restricted to professional users.
Uses advised against
None known.
1.3. Details of the supplier of the safety data sheet
Company and address
Knud E. Dan A/S
Lunikvej 40
2670 Greve
Denmark
+45 43692422
+45 43690578
Contact person
Lars Bøgeholm
E-mail
lbj@[Link]
Revision
03/10/2024
SDS Version
3.0
Date of previous version
20/03/2023 (2.0)
1.4. Emergency telephone number
Contact the poison hotline: +45 82 12 12 12 (24 hour service)
See section 4 “First aid measures”.
SECTION 2: Hazards identification
Classified according to Regulation (EC) No. 1272/2008 (CLP).
2.1. Classification of the substance or mixture
Eye Irrit. 2; H319, Causes serious eye irritation.
2.2. Label elements
Hazard pictogram(s)
Signal word
Warning
Hazard statement(s)
Causes serious eye irritation. (H319)
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According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
Precautionary statement(s)
General
-
Prevention
Wear eye protection. (P280)
▼Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. (P305+P351+P338)
If eye irritation persists: Get medical advice/attention. (P337+P313)
Storage
-
Disposal
-
Hazardous substances
None known.
▼Additional labelling
UFI: 4MMH-605R-F001-YFUJ
▼Labelling of contents according to Detergents Regulation (EC) No 648/2004
< 5%
· Amphoteric surfactants
· Non-ionic surfactants
· Phosphates
2.3. Other hazards
▼Additional warnings
This mixture/product does not contain any substances known to fulfil the criteria for PBT and vPvB classification.
This product does not contain any substances considered to be endocrine disruptors in accordance with the
criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2023/707.
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable. This product is a mixture.
3.2. ▼Mixtures
Product/substance Identifiers % w/w Classification Note
2-(2-butoxyethoxy)ethanol CAS No.: 112-34-5 1-3% Eye Irrit. 2, H319 [1], [3]
EC No.: 203-961-6
REACH: 01-2119475104-xxxx
Index No.: 603-096-00-8
beta-alanin, N-(2-aminoethyl)- CAS No.: 93820-52-1 1-3% Eye Irrit. 2, H319
N-(2-hydroxyethyl)-, N-kokos- EC No.: 298-632-7
acylderivater, mono sodium REACH: 17-2120078025-60
salt Index No.:
Alkylalkohol, ethoxyleret CAS No.: 68439-46-3 1-3% Eye Irrit. 2, H319 [19]
EC No.:
REACH:
Index No.:
Alcohols, C9-11 ethoxylated, CAS No.: 68439-46-3 1-3% Acute Tox. 4, H302 [19]
primær liniar EC No.: Eye Dam. 1, H318
REACH:
Index No.:
See full text of H-phrases in section 16. Occupational exposure limits are listed in section 8, if these are available.
Other information
[1] European occupational exposure limit.
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According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
[3] According to REACH, Annex XVII, the substance is subject to restrictions.
[19] UVCB = Unknown or variable composition, complex reaction products or of biological materials
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
In the case of accident: Contact a doctor or casualty department – take the label or this safety data sheet.
Contact a doctor if in doubt about the injured person’s condition or if the symptoms persist. Never give an
unconscious person water or other drink.
Inhalation
Upon breathing difficulties or irritation of the respiratory tract: Bring the person into fresh air and stay with
him/her.
Skin contact
Upon irritation: rinse with water. In the event of continued irritation, seek medical assistance.
▼Eye contact
If in eyes: Flush eyes immediately with plenty of water or isotonic water (20-30 °C) for at least 5 minutes and
continue until irritation stops. Remove contact lenses. Make sure to flush under upper and lower eyelids. If
irritation continues, contact a doctor. Continue flushing during transport.
Ingestion
If the person is conscious, rinse the mouth with water and stay with the person. Never give the person anything to
drink.
In case of malaise, seek medical advice immediately and bring the safety data sheet or label from the product. Do
not induce vomiting, unless recommended by the doctor. Have the person lean forward with head down to avoid
inhalation of or choking on vomited material.
Burns
Not applicable.
4.2. Most important symptoms and effects, both acute and delayed
Irritation effects: This product contains substances, which may cause irritation upon exposure to skin, eyes or lungs.
Exposure may result in an increased absorption potential of other hazardous substances at the area of exposure.
4.3. Indication of any immediate medical attention and special treatment needed
If eye irritation persists: Get medical advice/attention.
Information to medics
Bring this safety data sheet or the label from this product.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Not applicable.
5.2. Special hazards arising from the substance or mixture
Fire will result in dense smoke. Exposure to combustion products may harm your health. Closed containers, which are
exposed to fire, should be cooled with water. Do not allow fire-extinguishing water to enter the sewage system and
nearby surface waters.
If the product is exposed to high temperatures, e.g. in the event of fire, dangerous decomposition compounds are
produced. These are:
Carbon oxides (CO / CO2)
5.3. Advice for firefighters
Wear self-contained breathing apparatus and protective clothing to prevent contact. Upon direct exposure contact
the chemical emergency services on 72 85 20 00 (24 h service) in order to obtain further advice.
SECTION 6: Accidental release measures
6.1. ▼Personal precautions, protective equipment and emergency procedures
Contaminated areas may be slippery.
6.2. Environmental precautions
Avoid discharge to lakes, streams, sewers, etc.
Keep unauthorized persons away from the spill
6.3. Methods and material for containment and cleaning up
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous
earth and place in container for disposal according to local regulations.
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According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
Wherever possible cleaning should be performed with normal cleaning agents. Avoid use of solvents.
6.4. Reference to other sections
See section 13 “Disposal considerations” on handling of waste.
See section 8 "Exposure controls/personal protection" for protective measures.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Smoking, drinking and consumption of food is not allowed in the work area.
See section 8 "Exposure controls/personal protection" for information on personal protection.
7.2. Conditions for safe storage, including any incompatibilities
Containers that have been opened must be carefully resealed and kept upright to prevent leakage.
Recommended storage material
Always store in containers of the same material as the original container.
Storage conditions
5 - 25 °C
Incompatible materials
Strong acids, strong bases, strong oxidizing agents, and strong reducing agents.
7.3. Specific end use(s)
This product should only be used for applications quoted in section 1.2.
SECTION 8: Exposure controls/personal protection
8.1. ▼Control parameters
2-(2-butoxyethoxy)ethanol
Long term exposure limit (8 hours) (mg/m³): 68
Long term exposure limit (8 hours) (ppm): 10
Short term exposure limit (15 minutes) (mg/m³): 101
Short term exposure limit (15 minutes) (ppm): 15
Annotations:
E = Substance has an EC limit.
Statutory order 291 on exposure limits for substances and mixtures (19/03/2024)
DNEL
2-(2-butoxyethoxy)ethanol
Duration: Route of exposure: DNEL:
Long term – Systemic effects - General population Dermal 10 mg/kg uge/dag
Long term – Systemic effects - Workers Dermal 20 mg/kg/ uge/dag
Long term – Local effects Inhalation 5 mg/m3
Long term – Local effects - Workers Inhalation 10 ppm
Long term – Local effects - Workers Inhalation 67.5 mg/m³
Long term – Systemic effects - General population Inhalation 5 mg/kg uge/dag
Long term – Systemic effects - Workers Inhalation 10 ppm
Short term – Local effects - General population Inhalation 7,5 ppm
Short term – Local effects - Workers Inhalation 14 ppm
Short term – Local effects - Workers Inhalation 101.2 mg/m³
Long term – Systemic effects - General population Oral 6.25 mg/kg bw/day
Short term Oral 1,3 mg/kg uge/dag
Alkylalkohol, ethoxyleret
Duration: Route of exposure: DNEL:
Long term – Systemic effects - General population Dermal 1250 mg/kg
Long term – Systemic effects - Workers Dermal 2080 mg/kg
Long term – Systemic effects - General population Inhalation 87 mg/m3
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According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
Long term – Systemic effects - Workers Inhalation 294 mg/m3
Long term – Systemic effects - General population Oral 25 mg/kg
PNEC
2-(2-butoxyethoxy)ethanol
Route of exposure: Duration of Exposure: PNEC:
Freshwater 1 mg/l
Freshwater 1.1 mg/L
Freshwater sediment 4 mg/l
Freshwater sediment 4.4 mg/kg
Intermittent release (freshwater) 11 mg/L
Marine water 0,1 mg/l
Marine water 110 µg/L
Marine water sediment 0,4 mg/l
Marine water sediment 440 µg/kg
Sewage treatment plant 200 mg/l
Soil 0,4 mg/l
Alkylalkohol, ethoxyleret
Route of exposure: Duration of Exposure: PNEC:
Freshwater 0,104 mg/l
Freshwater sediment 13,7 mg/kg
Marine water 0,104 mg/kg
Marine water sediment 13,7 mg/kg
Sewage treatment plant 1,4 mg/l
Soil 1 mg/kg
8.2. ▼Exposure controls
Apply general control to prevent unnecessary exposure
General recommendations
Smoking, drinking and consumption of food is not allowed in the work area.
Exposure scenarios
There are no exposure scenarios implemented for this product.
▼Exposure limits
Occupational exposure limits have not been defined for the substances in this product.
▼Appropriate technical measures
Apply standard precautions during use of the product. Avoid inhalation of vapours.
▼Hygiene measures
In between use of the product and at the end of the working day all exposed areas of the body must be washed
thoroughly. Pay special attention to hands, forearms and face.
Measures to avoid environmental exposure
No specific requirements.
Individual protection measures, such as personal protective equipment
▼Generally
In the event the work process is within scope of the Danish statutory order on work with code numbered products
(Work Inspectorate Order no. 302/1993), then personal protection equipment shall be selected as set out herein. If
applicable, please refer to the code number of this product in section 15.
Use only CE marked protective equipment.
Respiratory Equipment
No specific requirements
Skin protection
No specific requirements.
Hand protection
No specific requirements.
Eye protection
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According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
Type Standards
Wear safety glasses EN166
with side shields.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid
Colour
Blue
Odour / Odour threshold
Characteristic
pH
9
Density (g/cm³)
1.09
▼Kinematic viscosity
No relevant or available data due to the nature of the product.
Particle characteristics
Does not apply to liquids.
Phase changes
▼Melting point/Freezing point (°C)
No relevant or available data due to the nature of the product.
Softening point/range (°C)
Does not apply to liquids.
Boiling point (°C)
>100
▼Vapour pressure
No relevant or available data due to the nature of the product.
▼Relative vapour density
No relevant or available data due to the nature of the product.
▼Decomposition temperature (°C)
No relevant or available data due to the nature of the product.
Data on fire and explosion hazards
Flash point (°C)
>100
▼Flammability (°C)
No relevant or available data due to the nature of the product.
▼Auto-ignition temperature (°C)
No relevant or available data due to the nature of the product.
▼Lower and upper explosion limit (% v/v)
No relevant or available data due to the nature of the product.
Solubility
Solubility in water
Completely soluble
▼n-octanol/water coefficient (LogKow)
No relevant or available data due to the nature of the product.
▼Solubility in fat (g/L)
No relevant or available data due to the nature of the product.
9.2. Other information
Other physical and chemical parameters
No data available.
▼Oxidizing properties
No relevant or available data due to the nature of the product.
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According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
SECTION 10: Stability and reactivity
10.1. Reactivity
No data available.
10.2. Chemical stability
The product is stable under the conditions, noted in section 7 “Handling and storage”.
10.3. Possibility of hazardous reactions
None known.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
Strong acids, strong bases, strong oxidizing agents, and strong reducing agents.
10.6. ▼Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced
SECTION 11: Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity
Product/substance 2-(2-butoxyethoxy)ethanol
Species: Rabbit
Route of exposure: Dermal
Test: LD50
Result: 2700 mg/kg ·
Product/substance 2-(2-butoxyethoxy)ethanol
Species: Rat
Route of exposure: Oral
Test: LD50
Result: 5660 mg/kg ·
Product/substance Alkylalkohol, ethoxyleret
Species: Rat
Route of exposure: Oral
Test: LD50
Result: >2000 mg/kg ·
Product/substance Alkylalkohol, ethoxyleret
Species: Rat
Route of exposure: Dermal
Test: LD50
Result: > 2000 mg/kg ·
Skin corrosion/irritation
Based on available data, the classification criteria are not met.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory sensitisation
Based on available data, the classification criteria are not met.
▼Skin sensitisation
Product/substance Alkylalkohol, ethoxyleret
Test method: OECD 406
Species: Guinea pig
Description: Negativ
Result: No adverse effect observed (not sensitising)
Germ cell mutagenicity
Based on available data, the classification criteria are not met.
Carcinogenicity
Based on available data, the classification criteria are not met.
Reproductive toxicity
Based on available data, the classification criteria are not met.
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According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
STOT-single exposure
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
11.2. Information on other hazards
Long term effects
Irritation effects: This product contains substances, which may cause irritation upon exposure to skin, eyes or lungs.
Exposure may result in an increased absorption potential of other hazardous substances at the area of exposure.
▼Endocrine disrupting properties
This mixture/product does not contain any substances known to have hormone-disrupting properties in relation to
health.
Other information
None known.
SECTION 12: Ecological information
12.1. Toxicity
Product/substance 2-(2-butoxyethoxy)ethanol
Species: Fish
Duration: 96 hours
Test: LC50
Result: 1300 mg/l ·
Product/substance 2-(2-butoxyethoxy)ethanol
Species: Daphnia
Duration: 24 hours
Test: LD50
Result: 3200 mg/l ·
Product/substance 2-(2-butoxyethoxy)ethanol
Species: Algae
Duration: 96 hours
Test: LD50
Result: >100 mg/l ·
Product/substance Alkylalkohol, ethoxyleret
Species: Daphnia
Duration: 48 hours
Test: LD50
Result: 13,4 mg/l ·
Product/substance Alkylalkohol, ethoxyleret
Species: Fish
Duration: 96 hours
Test: LC50
Result: 1 -10 mg/L
Product/substance Alkylalkohol, ethoxyleret
Species: Algae
Duration: 72 hours
Test: EC50
Result: 1-10 mg/L
Product/substance Alcohols, C9-11 ethoxylated, primær liniar
Species: Fish
Duration: 96 hours
Test: LC50
Result: 23,7 mg/l ·
Product/substance Alcohols, C9-11 ethoxylated, primær liniar
Species: Algae
Duration: 48 hours
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According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
Test: EC50
Result: 13,4 mg/l ·
12.2. ▼Persistence and degradability
Product/substance 2-(2-butoxyethoxy)ethanol
Result: 90-100
Conclusion: Readily biodegradable
Test: TG 301 E- Test Modified OECD Screening Test -70%
Product/substance Alkylalkohol, ethoxyleret
Result: >60
Conclusion: Readily biodegradable
Test: OECD 301 D
Product/substance Alcohols, C9-11 ethoxylated, primær liniar
Result: >60 %
Conclusion: Readily biodegradable
Test: TG 301 F - Manometric Respirometry Test - 60%
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in
Regulation (EC) No 648/2004 on detergents. Data to support this assertion are held at the disposal of the competent
authorities of the Member States and will be made available to them, at their direct request or at the request of a
detergent manufacturer.
12.3. ▼Bioaccumulative potential
Product/substance 2-(2-butoxyethoxy)ethanol
LogKow: 0,5600
Conclusion: No potential for bioaccumulation
12.4. Mobility in soil
No data available.
12.5. ▼Results of PBT and vPvB assessment
This mixture/product does not contain any substances known to fulfil the criteria for PBT and vPvB classification.
12.6. ▼Endocrine disrupting properties
This mixture/product does not contain any substances considered to have endocrine-disrupting properties in relation
to the environment.
12.7. Other adverse effects
None known.
SECTION 13: Disposal considerations
13.1. ▼Waste treatment methods
Product is not covered by regulations on dangerous waste.
Commission Regulation (EU) No 1357/2014 of 18 December 2014 on waste.
▼EWC code
07 06 99 Wastes not otherwise specified
Specific labelling
Not applicable.
Contaminated packing
Packaging containing residues of the product must be disposed of similarly to the product.
SECTION 14: Transport information
14.1 14.2 14.3 14.4 14.5 Other
UN / ID UN proper shipping name Hazard class(es) PG* Env** informatio
n:
ADR - - Transport hazard class: - - No See below
for
additional
information.
IMDG - - Transport hazard class: - - No See below
for
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According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
14.1 14.2 14.3 14.4 14.5 Other
UN / ID UN proper shipping name Hazard class(es) PG* Env** informatio
n:
additional
information.
IATA - - - - - -
* Packing group
** Environmental hazards
▼Additional information
ADR / See Table A, section 3.2.1 for any information on special provisions, requirements, or warnings in connection
with transport. See section 5.4.3, for instructions in writing regarding mitigation of damages in relation to incidents or
accidents during transport.
IMDG / See section 3.2.1, for any information on special provisions, requirements, or warnings in connection with
transport.
14.6. Special precautions for user
Not applicable.
14.7. Maritime transport in bulk according to IMO instruments
No data available.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Restrictions for application
Restricted to professional users.
Demands for specific education
No specific requirements.
SEVESO - Categories / dangerous substances
Not applicable.
▼REACH, Annex XVII
2-(2-butoxyethoxy)ethanol is subject to REACH restrictions (entry 55).
▼Labelling of contents according to Detergents Regulation (EC) No 648/2004
< 5%
· Amphoteric surfactants
· Non-ionic surfactants
· Phosphates
Product registration number
144419
▼Regulation on work involving coded products
Code number (1993): 00-3.
▼Additional information
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in
Regulation (EC) No 648/2004 on detergents. Data to support this assertion are held at the disposal of the
competent authorities of the Member States and will be made available to them, at their direct request or at the
request of a detergent manufacturer.
Sources
Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March 2004 on detergents.
Commission Regulation (EU) No 1357/2014 of 18 December 2014 on waste.
Arbejdstilsynets bekendtgørelse nr. 301 af 13. maj 1993 om fastsættelse af kodenumre med senere ændringer.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on
classification, labelling and packaging of substances and mixtures (CLP).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).
15.2. Chemical safety assessment
No
SECTION 16: Other information
Full text of H-phrases as mentioned in section 3
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According to EC-Regulation 1907/2006 (REACH), annex II, including changes implemented by EC-Regulation 2020/878
H302, Harmful if swallowed.
H318, Causes serious eye damage.
H319, Causes serious eye irritation.
▼Abbreviations and acronyms
ADN = European Provisions concerning the International Carriage of Dangerous Goods by Inland Waterway
ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
CAS = Chemical Abstracts Service
CE = Conformité Européenne (European conformity)
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
CSA = Chemical Safety Assessment
CSR = Chemical Safety Report
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EINECS = European Inventory of Existing Commercial chemical Substances
ES = Exposure Scenario
EUH statement = CLP-specific Hazard statement
EuPCS = European Product Categorisation System
EWC = European Waste Catalogue
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
GWP = Global warming potential
IARC = International Agency for Research on Cancer (IARC)
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of
1978. ("Marpol" = marine pollution)
OECD = Organisation for Economic Co-operation and Development
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail
RRN = REACH Registration Number
SCL = A specific concentration limit
SVHC = Substances of Very High Concern
STOT-RE = Specific Target Organ Toxicity - Repeated Exposure
STOT-SE = Specific Target Organ Toxicity - Single Exposure
TWA = Time weighted average
UN = United Nations
UVBC = Unknown or variable composition, complex reaction products or of biological materials
VOC = Volatile Organic Compound
vPvB = Very Persistent and Very Bioaccumulative
Additional information
The classification of the mixture in regard of health hazards is in accordance with the calculation methods given by
Regulation (EC) No. 1272/2008 (CLP).
The safety data sheet is validated by
lbj
▼Other
A change (in proportion to the last essential change (first cipher in SDS version, see section 1)) is marked with a
triangle.
The information in this safety data sheet applies only to this specific product (mentioned in section 1) and is not
necessarily correct for use with other chemicals/products.
It is recommended to hand over this safety data sheet to the actual user of the product. Information in this safety
data sheet cannot be used as a product specification.
Country-language: DK-en
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