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Chap1 Chem1200

The document outlines the key concepts from Chapter 1, including measurement, significant figures, scientific notation, unit analysis, and the metric system. It emphasizes the importance of understanding accuracy and precision in measurements, as well as the proper use of significant figures in mathematical operations. Supplementary resources are available on Blackboard, and certain sections require independent reading as they are not covered in lectures.

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0% found this document useful (0 votes)
49 views23 pages

Chap1 Chem1200

The document outlines the key concepts from Chapter 1, including measurement, significant figures, scientific notation, unit analysis, and the metric system. It emphasizes the importance of understanding accuracy and precision in measurements, as well as the proper use of significant figures in mathematical operations. Supplementary resources are available on Blackboard, and certain sections require independent reading as they are not covered in lectures.

Uploaded by

gaethavee
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

1/22/2025

SOME MEMORIZATION IS REQUIRED FOR CHAPTER 1

SOME SUPPLEMENTARY RESOURCES ARE AVAILABLE IN BLACKBOARD


Check Course Documents Folder

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1/22/2025

SECTIONS 1.1-1.3 ARE NOT


PRESENTED IN LECTURE
You will need to read Sections 1.1-1.3 on your own. There are problems assigned for
these sections in the homework, and they will be covered on quizzes and midterms.

There is a video in the Chapter 1 folder on Blackboard that goes over much of this.

Chapter 1
• Measurement
• Significant Figures
• Scientific Notation
• Unit Analysis (aka factor label method)
• Metric System

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1/22/2025

Measurement: An experimental process by which some


property of a system is quantified.

Measurements come in two types:


Exact Measurement:

Inexact Measurement:

(cm)

Measurement: An experimental process by which some


property of a system is quantified.

Measurements come in two types:


Exact Measurement:

Need to be able
to characterize
the error here.
{ Inexact Measurement:

(cm)

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1/22/2025

Characterizing a Measurement:
Accuracy: How close to the true value a
measurement is.
Precision: How reproducible a measurement is.
Example: Two thermometers

Example: Two thermometers


Average human body temperature: 98.6oF
Does the child have a fever?
Thermometer #1: Thermometer #2:
95.6oF 96.6oF
98.6oF 96.5oF
101.6oF 96.7oF

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Example: Two thermometers


Average human body temperature: 98.6oF
Does the child have a fever?
Thermometer #1: Thermometer #2:
95.6oF 96.6oF
98.6oF 96.5oF
101.6oF 96.7oF
Go to doctor, get checked
“True” value is 98.6oF

Should we throw away the thermometers?

Example: Two thermometers


Go to doctor, get checked
“True” value is 98.6oF
Should we throw away the thermometers?
Thermometer #1: Thermometer #2:
95.6oF 96.6oF
98.6oF 96.5oF
101.6oF Accuracy: How close to the true value a 96.7oF
measurement is.
Precision: How reproducible a measurement is.

Thermometer #1 is Thermometer #2 is
accurate but not precise but not
precise. accurate.
Understanding the problems lets us correct them.

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1/22/2025

Example: Two thermometers


Average human body temperature: 98.6oF
Does the child have a fever?
Thermometer #1: Thermometer #2:
95.6oF Thermometer #1 is 96.6oF Thermometer #2 is
98.6oF accurate but not 96.5oF precise but not
o
101.6 F precise. 96.7oF accurate.
Average: 98.6oF 96.6oF

To use the thermometer, make multiple To use the thermometer,


measurements and take the average. make one measurement and
add 20F (calibration).

More generally: Counter poor precision with multiple measurements.


Counter poor accuracy with calibration.

Quick and dirty way to handle error: Significant figures

Convention: When measuring an object, report the


value such that the last digit is an estimate

(cm)

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1/22/2025

Chapter 1
• Measurement
• Significant Figures
• Scientific Notation
• Unit Analysis (aka factor label method)
• Metric System

Quick and dirty way to handle error: Significant figures

Convention: When measuring an object, report the


value such that the last digit is an estimate
Correct
values:
6.2 cm
(cm)
6.3 cm

6.24 cm
6.25 cm
6.26 cm

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1/22/2025

Mathematics with Significant Figures: Addition & Subtraction


Challenge: Once you have an estimate of error included in significant
figures, you need to preserve that information when you do math.

If one pencil is 6.24 cm long and another is 3.2 cm long, how long
would they be if you placed them end to end?

6.24 cm 3.2 cm
Error in measurement +/-0.01 cm Error in measurement +/- .1cm

Mathematics with Significant Figures: Addition & Subtraction


Challenge: Once you have an estimate of error included in significant
figures, you need to preserve that information when you do math.

If one pencil is 6.24 cm long and another is 3.2 cm long, how long
would they be if you placed them end to end?

6.24 cm 3.2 cm
Error in measurement +/-0.01 cm Error in measurement +/- .1cm

Can’t suddenly know the length more accurately after adding them
– have to preserve error.

Most important error is the larger error.

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1/22/2025

Mathematics with Significant Figures

6.24 cm 3.2 cm
Error in measurement +/-0.01 cm Error in measurement +/- .1cm

Can’t suddenly know the length more accurately after adding them
– have to preserve error.

Most important error is the larger error.


Add numbers and stop at last digit they have in common:
6.24 cm
+3.2 cm
9.44 cm mathematical answer
9.4 cm correct answer including error

Mathematics with Significant Figures: Addition & Subtraction

6.24 cm 3.2 cm
Error in measurement +/-0.01 cm Error in measurement +/- .1cm

Can’t suddenly know the length more accurately after adding them
– have to preserve error.

Most important error is the larger error.


Add numbers and stop at last digit they have in common:
6.24 cm
+3.2 cm
9.44 cm mathematical answer
9.4 cm correct answer including error

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1/22/2025

A Note on Rounding Off (from Flowers):


If the digit to be dropped (the one immediately to the right of the digit to be retained) is
less than 5, “round down” and leave the retained digit unchanged; if it is more than 5,
“round up” and increase the retained digit by 1; if the dropped digit is 5, round up or
down, whichever yields an even value for the retained digit. (The last part of this rule
may strike you as a bit odd, but it’s based on reliable statistics and is aimed at avoiding
any bias when dropping the digit “5,” since it is equally close to both possible values of
the retained digit.)

A Note on Rounding Off (from Flowers):


If the digit to be dropped (the one immediately to the right of the digit to be retained) is
less than 5, “round down” and leave the retained digit unchanged; if it is more than 5,
“round up” and increase the retained digit by 1; if the dropped digit is 5, round up or
down, whichever yields an even value for the retained digit. (The last part of this rule
may strike you as a bit odd, but it’s based on reliable statistics and is aimed at avoiding
any bias when dropping the digit “5,” since it is equally close to both possible values of
the retained digit.)

Indicating sig figs in numbers ending in 0


100 100 100. 100.0
+/-10 +/-1 +/-1 +/-0.1

Won’t have to worry about this when we get to scientific notation!

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1/22/2025

Mathematics with Significant Figures: Multiplication & Division

Need to be able to count the number of significant figures.

Product of two numbers has the same number of sig figs as the multiple that has
the least sig figs.

126 x 0.33 = 41.58 = 42


3 s.f. 2 s.f. math ans 2 s.f. (correct)

Same rule for division

126/12 = 10.5 = 10.


3 s.f. 2 s.f. math ans 2 s.f. (correct)

Mathematics with Significant Figures: Multiplication & Division

Need to be able to count the number of significant figures.

Product of two numbers has the same number of sig figs as the multiple that has
the least sig figs.

126 x 0.33 = 41.58 = 42


3 s.f. 2 s.f. math ans 2 s.f. (correct)

Same rule for division Need to be able to count s.f.

126/12 = 10.5 = 10.


3 s.f. 2 s.f. math ans 2 s.f. (correct)

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Counting Significant Figures:


1) All nonzero numbers are significant
2) Zeroes between significant digits are significant
3) Leading zeroes are not significant
4) Zeroes that fall at the end of a number after a decimal are significant
5) If a number ends in a decimal, all numbers (including zeroes) to the left
of the decimal are significant. But this is true only when the decimal
point is actually written.
6) When a number ends in zero but has no decimal, zeroes may or may not
be significant. Do not write numbers this way!

167 3 s.f.
167.0 4 s.f.
1.05 3 s.f
1050 AMBIGUOUS! DO NOT WRITE NUMBERS THIS WAY
1050. 4 s.f.
1050.0 5 s.f.

Counting Significant Figures:


1) All nonzero numbers are significant
2) Zeroes between significant digits are significant
3) Leading zeroes are not significant
4) Zeroes that fall at the end of a number after a decimal are significant
5) If a number ends in a decimal, all numbers (including zeroes) to the left
of the decimal are significant. But this is true only when the decimal
point is actually written.
6) When a number ends in zero but has no decimal, zeroes may or may not
be significant. Do not write numbers this way!

Product of two numbers has the same number of sig figs as the multiple that has the
least sig figs.
2.000 x 4.0 = 8.0 1.0 x 4.0000 = 4.0 2.00 / 4.0000 = 0.500
4 s.f. 2 s.f. 2 s.f. 2 s.f. 5 s.f. 2 s.f. 3 s.f. 5 s.f. 3 s.f.

2.0 x 4.0 = 8.0 0.0 x 4.0000 = 0.0 20.0 / 4.0000 = 5.00


2 s.f. 2 s.f. 2 s.f. 2 s.f. 5 s.f. 2 s.f. 3 s.f. 5 s.f. 3 s.f.

2 x 4.0 = 28s.f.
1 s.f. 2 s.f.
2 x 0.0
1 s.f.
=0
2 s.f. 1 s.f. 1.000 / 2.00 = 0.500
4 s.f. 3 s.f. 3 s.f.

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FINAL NOTE: EXACT NUMBERS HAVE INFINITELY MANY SIG FIGS

There are exactly 10 bowling pins at the end of an alley.

If each pin weighs 1.53 kg, then the total mass of pins is:

1.53 kg x 10 = 15.3 kg (treat 10 as 10.0000 because it is exact)

There are exactly 12 mints in a container. If each mint weighs 1.5g, what is
the mass of exactly 30 containers of mints?

30 containers x 12 mints = 360 mints (exact)


360 x 1.5g = 540g

SCIENTIFIC NOTATION
Current population:
8.20 billion

Awkward way to write numbers

8,200,000,000

Still awkward, and we need that silly overline

8.20x109
Inexact number Rule: Prefactor is always written so there
Information on sig figs here Exact number
is 1 digit to the left of the decimal.
Handles magnitude

This is a convenient way to do things: 16.0 x103


• Every digit in the prefactor is significant Becomes
• Exponential handles the magnitude 1.60x104

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1/22/2025

Chapter 1
• Measurement
• Significant Figures
• Scientific Notation
• Unit Analysis (aka factor label method)
• Metric System

SCIENTIFIC NOTATION
Current population:
8.20 billion

Awkward way to write numbers

8,200,000,000

Still awkward, and we need that silly overline

8.20x109
Inexact number 109 = 10x10x10x10x10x10x10x10x10
Information on sig figs here Exact number = 1,000,000,000
Handles magnitude

This is a convenient way to do things:


• Every digit in the prefactor is significant
• Exponential handles the magnitude

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1/22/2025

From Flowers, 2e

General rules for exponents:

(an)(am) = an+m 103 x 105 = 103+5 = 108

a-n=1/(an) 10-3 = 1/103 = 1/1000 = 0.001

ao=1 10o=1

an/(am)=an a-m = an-m 103/104 = 103-4 = 10-1 = 1/10 =0.10

(3.2x1012) (4.1x103) = (3.2 x 4.1)x1012+3 = 13x1015 = 1.3x1016

(3.2x1012)/(4.1x103) = (3.2/4.1)x1012-3= 0.78x109 = 7.8x108

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General rules for exponents:

Adjusting prefactors:
(3.2x1012) (4.1x103) = (3.2 x 4.1)x1012+3 = 13x1015 = 1.3x1016

You cannot change the value of the number, but you can change the way it is written.

Getting from 13x1015 to 1.3x1016 means making the prefactor smaller and the exponent larger

Try thinking of it this way:

(13x1015)x1 = 13x1015 No real information here

Just rewriting 1=10/10

Distributing 10 in a way that is convenient

Adjusting prefactors:
0.0300x10-7 Not good scientific notation – need prefactor to be larger and exponent term to be smaller

(0.0300x10-7) x 1 Again, just multiplying by 1. This time, we need to write 1 as 102/102

Just rewriting 1=102/102

Distributing 102 in a way that is convenient

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1/22/2025

Chapter 1
• Measurement
• Significant Figures
• Scientific Notation
• Unit Analysis (aka factor label method)
• Metric System

Chapter 1
• Measurement
• Significant Figures
• Scientific Notation
• Unit Analysis (aka factor label method)
• Metric System

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1/22/2025

What Should a Good System of Units Look Like?

Units are designed, they serve a purpose

What should the goal be for the designers?

System of units should do 3 things:


1) Be indestructible
2) Be reproducible anywhere in the world
3) Be flexible: Same system should allow you to measure the weight
of a ship, a cannonball, and a feather

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1/22/2025

The French Revolution!

Liberte!
Egalite!
Fraternite!

Prefix Value Symbol


Giga 109 G
Mega 106 M
Kilo 103 K
deci 10-1 D
centi 10-2 c Know the ones in red!

milli 10-3 m
micro 10-6 μ
nano 10-9 n
pico 10-12 p
femto 10-15 f

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1/22/2025

How the French National Academy Defined the Meter

North Pole
Goal: Distance from North Pole to
Equator = 10,000,000 m by definition

Equator

Method: Measure one arc very


precisely, get latitude, estimate from
that.
This is not how the modern metric system is defined!

The Plan:
1) Send 2 members of the academy to find the distance from
Dunkirk to Barcelona – one goes north, one goes south
2) Measure latitude at ends very precisely
3) Estimate the distance from North Pole to Equator, define meter
4) Wait for a grateful World Republic to acknowledge their
contribution to the Liberation of Man

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1/22/2025

From: K. Alder, “The Measure


Of All Things,” The Free Press,
New York, 2002.

Went north from Paris Went south from Paris


From: K. Alder, “The Measure
Of All Things,” The Free Press,
New York, 2002.

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The Outcome:
1) Survey took seven years to complete
2) Funny thing: Earth not as round as they thought – Defeats the
whole purpose!
3) World Republic fails to materialize

The Outcome:
1) Survey took seven years to complete
2) Funny thing: Earth not as round as they thought – Defeats the
whole purpose!
3) World Republic fails to materialize
4) Over 7 billion people cannot buy water without paying homage
to two hapless ideologues.

Only the US, Myanmar, and Liberia don’t use the metric system!

Modern definition of the meter:


Length traveled by light in vacuum
during 1/299,792,458 of a second.

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1/22/2025

Prefix Value Symbol


Giga 109 G
Mega 106 M
Kilo 103 K
deci 10-1 D
centi 10-2 c Know the ones in red!

milli 10-3 m
micro 10-6 μ
nano 10-9 n
pico 10-12 p
femto 10-15 f

23

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