INTERMEDIATE

second year Intermediate

OXYGEN
PASS GUARANTEE QUESTIONS
UNIT –I SOLID STATE

UNIT -II. SOLUTIONS

UNIT-III ELETRO CHEMISTRY AND CHEMICAL KINETICS

UNIT-IV SURFACE CHEMISTRY

UNIT-V METALLURGY

UNIT-VI P-BLOCK ELEMENTS

UNIT-VII d, f and CO-ORDINATION COMPLEX COMPOUNDS

UNIT-VIII POLYMERS

UNIT-IX BIOMOLECULES

UNIT-X CHEMISTRY IN EVERY DAY LIFE

UNIT-XI ORGANIC CHEMISTRY

 1. SOLID STATE
2 Marks
1. What are F-centers ?
2. Explain Ferro magnetism with suitable example ?
3.What is Para magnetism with example ?
4.How do you distinguish between crystal lattice and unit cell?
5. What is meant by the term Co-ordination number ?
6.Explain anti Ferro -magnetism with suitable example?
4 Marks
1. Derive Bragg’s equation?
2. Explain the Schottky defect and frenkel defect with suitable examples?
3. What is Doping? Describe the two main p -type and n-type
Semiconductors and contrast their conduction mechanism?
2. SOLUTIONS
2 Marks
1. What are Isotonic solutions? Give examples ?
2.What are Ideal solutions? Give examples?
3.What is Ebullioscopic constant ?
4.What is Cryoscopic constant
5. Calculate the Molarity of 4g NaOH dissolved in 500ml of the Solution?
6. Define Osmosis ?
7. Define Molarity ?
8.What is relative lowering of vapour pressure ?
9. What is Osmatic pressure?

4 Marks
1. State Henry’s law and Write its application?
2. What is mole fraction ? Calculate the mole fraction of H2SO4 on the solution
of 98% (w/w) H2SO4 ?
3. State Roult’s law ? Vapour pressure of water of 293k is 17.535mm of Hg
calculate the vapour pressure of solution at 293k when 25gm of glucose is
dissolve in 450gm of water?
4. What are Colligative properties ? Give examples?
5. A solution of Glucose in water is labelled as 10% w/w. What would
be the molarity of the solution?
6. Vapour pressure of benzene at certain temperature is 0.850bar. A non-volatile,
Non-electrolyte solution weight is 0.5g when added 39g of benzene vapour
pressure of the solution is 0.845 bar. What is Molar mass of the substance?
3.ELETROCHEMISTRY
2 Marks
1. The standard emf of Daniel cell is 1.1V ,calculate the standard Gibb’s
energy for the cell reaction. Zn + Cu+2 Zn+2+Cu
2. What is Corrosion ? Give example?
3. What is fuel cell? Give example ?
4. Define a) Cell constant b) Molar conductivity
5. How is Gibb’s Energy related to cell emf ?

4 Marks
1. What are Primary and Secondary batteries ? Give examples ?
2. State and Explain the Faraday first and second law?
3. What is Electrolysis ? Explain the working of Galvanic cell?
4. State & Explain Kohlrash law of independent Migration of ions and its
applications?
5. What is SHE? Explain with diagram?
6 A solution of CuSO4 is electrolysed for 10 min with a current of 1.5 amp.
What is the mass of copper deposited at the cathode?

3. CHEMICAL KINETICS
2 Marks

1. What is rate determining step in a complex reaction?

2. What are the Pseudo first order reaction ?
3. What is rate of reaction?
4. Define zero order reaction ?
5. Write the units of zero, first, second, third order reactions?
6. A reaction has a half-life of 10 minutes. Calculate the rate constant for the
first order reaction?

4 Marks
1. What is Order and Molecularity of a reaction ? Write differences
between them ?
2. Write examples for zero, first, second, third of reactions.
3. Derive the integrated reactions of first order ?
4. Derive equation which describes the effect of temperature on rate constant ?
5. What is half life of the reaction? Calculate the half life of the first order
reaction whose rate constant is 200S-1.
8 Marks
6.Write the Silent futures of the Collision theory of reaction ?

4. SURFACE CHEMISTRY
ADSORPTION
4 Marks
1. What is adsorption ? What are the different types of adsorption? Write
differences between them ?
CATALYSIS
4 Marks
1. What is catalysis explain types with examples ?
2. Name any two enzyme catalysed reactions. Give the reactions ?
COLLOIDS
 2 Marks
1. How is artificial Rain produced ?
2. What is Coagulation?
3 .What is Hardy - Schulze law ?
4. What is dialysis ? How is it can be made fast?
5. Sky appear blue in colour, explain ?
6.What is Emulsifying agent ?

4 Marks
1. What is lyophilic and lyophobic sol? Explain with example?
2. Define a) Tyndall Effect b) Brownian movement?
3. What is Emulsion? Explain types with examples?
4.What are Micelles ?How do micelles differ from a normal colloidal solutions?
5. Define a) Gold number b) Protective colloids?
6. Name dispersed phase and Dispersed medium in following
a) Fog b) Smoke c) Mist d) blood

5. METALLURGY
2 Marks
1. Explain Poling ?
2. What is the role of depressant in froth floatation process ?
3. Give the Composition of the following alloys
a) Brass b) Bronze c) German silver
4. What is role of Cryolite in the metallurgy of aluminium ?
5. What is blister copper? Whys is it so Called ?
6 What is matte.?Give its composition?
7. What is the difference between mineral and Ore ?
8.Explain Gangue, Slag and flux ?
9. State the role of silica in the metallurgy of Copper ?
4 Marks
1. What is the difference between Roasting & Calcination with examples?
2. Explain froth floatation method?
3. Explain Zone refining ?
4. Write any two Ores with formula of the following metals?
a) Zinc b) Copper c) Aluminium d) Iron
5. Describe the Method for the refining of Nickel ?
6. Explain the Extraction of Alumina from Bauxite ?
6. VA GROUP ELEMENTS
2 Marks
1. Explain why is NH3 basic while BiH3 is only feebly basic?
2. PH3 is a weaker base than NH3 Explain?
3. NH3 forms hydrogen bonds but PH3 does not form why ?
4. PH3 lower boiling point than NH3 why ?
5. Why does NH3 act as a Lewis base ?
6. What happens when white phosphorous is heated with Conc NaOH
 solution an inert atmosphere of CO2 ?
7. Ammonia is Good complex agent? Explain ?
8. Write two Neutral oxides of Nitrogen?
9. A mixture of Ca3P2 and CaC2 is used in making Holmes signal explain?
10. Nitrogen Molecule highly stable why ?
4 Marks
1. How is ammonia manufactured by Haber process ?
2. How is ammonia reacts with following a) ZnSO4 b) CuSO4 c) AgCl
3. Write the difference between the properties of white phosphorous and red
phosphorous ?
4. Write the Chemical reactions that occur in the manufacture of Nitric acid ?

6. VIA GROUP ELEMENTS

2 Marks

1. SO2 can be used as an antichlor ? Explain ?

2. Why group -16 elements called as Chalcogens?
3. H2S is Gas while H2O is liquid why?
4. H2S is less acidic than H2Te explain ?
5.H2O neutral while H2S is acidic why explain ?
6.What is Tailing of mercury? How is it removed ?
7.What is Allotropy?

4 Marks
1. Describe the manufacturing of H2SO4 by contact process?
2.How is ozone prepared from oxygen? Explain its reaction with
a) PbS b)KI c) Hg d) Ag e) NO f) C2H2
3. Write a short note on the allotropy of sulphur
a) Monoclinic b) Rhombic

7. VIIA GROUP ELEMENTS

2 Marks

1. Write the reactions of F2 and Cl2 with water

2. How is Cl2 manufactured by Deacon’s?
3.Electron Gain enthalpy of fluorine is less than of chlorine explain ?
4. HF is liquid while HCl is gas explain ?
5. What is inter halogen compounds? Give example.
8 Marks
6. How is chlorine obtained in the laboratory ? How does it react with the
following.
a) Cold dil, NaOH b) excess NH3 c) KI d) Na2S2O3 e) Slaked lime
7. How does chlorine react with the following ?
a) Iron b) hot NaOH c) FeSO4 d) I2 e) H2S
 8. VIII GROUP EMEME
2 Marks

1. Write the name and formula of the first Nobel Gas compound prepared
by Berthelot ?
2. In modern diving apparatus a mixture of He and O2 is used ? Why ?
3. Write the structure and hybridisation of
a) XeO3 b) XeOF4
4 Marks
1. Write the reactions of XeF2, XeF4, XeF6 with water ?
2. Give the preparation method of following ?
a) XeO2F2 b) XeOF4
3. How is prepared following ?
a) XeF2 b)XeF4 c)XeF6 d) XeO3
4. Write the structure and Hybridization of following ?
a)XeF2 b)XeF4 c)XeF6 d) XeO3
5. Write the Uses of noble Gases?
9. d, f BLOCK ELEMENTS
2 Marks
1. Why Zn+2 is diamagnetic where as Mn+2paramagentic explain?
2 .What is an alloy ? Give example?
3. What is Lanthanide contraction?
4. Explain CuSO4 .5H2O blue in colour where as anhydrous CuSO4 is colour less
why?
5. What is interstitial compounds ? Give example?
6. Calculate the spin only magnetic moment of Fe2+ ion ?
7. Calculate the magnetic moment of divalent ion in agueous solution if
its atomic number is 25?
4 Marks
1. Write the characteristics of transition elements.
2. What is Misch - metal ? Write its uses?
CO-ORIDINATION COMPOUNDS
2 Marks
1. [Fe(CN)4]2- and [Fe(H2O)6]2+ are of different colours in dilute solutions why ?
2. [NiCl4]-2 is paramagnetic while Ni(CO)4 is diamagnetic why ?
3. [CO(NH3)6]+3 is an inner orbital complex where as [Ni(NH3)6]2+ is an
outer orbital complex? Explain?
4 .[Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3- is
weakly paramagnetic Explain?
5. What is Chelate ligand? Give example?
6. What is ligand ? Give an example
7.What is an ambidentate ligand ? Give example
8. [Cr(NH3)6]3+ is paramagnetic while [Ni(CN)4]+2 is diamagnetic Why?
9. A solution of [Ni(H2O)6]2+ is Green but a solution of [Ni(CN)4]2- is
colour less why?
4 Marks
1.Using IUPAC norms write the formulas for the following ?
1) Tetra hydroxo zincate ( ii)ion
2) Hexa amine cobalt (iii) Sulphate
3) Potassium tetra chloro palladate (ii)
4) potassium tri(oxalato)Chromate (iii)
2. Write the formula for the following coordination compounds
a) Tetra amine aqua chloro cobalt (iii) chloride
b) Potassium tetra hydroxo zincate (ii)
c) Potassium tri oxalate aluminate (iii)
d) Dichloro -bis (ethane-1,2-diamine) cobalt (iii)
e) Tetra carbonyl nickel(o)
3. Write the IUPAC names of the following coordination compounds .
i) [CO(NH3)6]Cl3 ii) [Pt(NH3)2Cl2 iii) [Ti(H2O)6]3+ iv) [NiCl4]2-
4. Explain Werner’s theory of coordination compounds with suitable examples
8. POLYMERS
2 Marks
1. What are monomer and Polymers? Give example ?
2. What is Polymerization ? Give an example of Polymerization ?
3. What is addition polymer ? Give example ?
4. What is condensation polymer ? Give example ?
5. What are copolymers ? Give example?
6. What are Elastomers ? Give example ?
7. What are fibres ? Give examples ?
8. What are Thermoplastic polymers ? Give example ?
9 .What are Thermosetting polymers? Give example ?
10. What is Ziegler –Natta catalyst ?
11. What PDI (Poly Dispersity Index)?
12. What is Vulcanization of rubber ?
13. What is biodegradable polymer? Give one example.
14. What is PHBV ? How is it useful to man ?
15. Explain Co-polymerization with an example ?
4 Marks
1. Write the names and structure of the monomers for the following
i) PVC ii) Teflon iii) Bakelite iv) Polystyrene v) Nylon-6 vi) Nylon-6,6
2. Write the names and structures of the monomers of the following po
i) Buna-S ii) Buna-N iii) Dacron or Terylene iv) Neoprene
 9.BIO-MOLECULES
2 Marks
1. Define carbohydrates ?
2. Why are sugars classified as reducing and non reducing sugars ?
3. Write two methods of preparation of Glucose ?
4. What are amino acids? Give two examples?
5. What do you mean by essential and Non- essential amino acids ? Give two
examples?
6.What is Zwitter ion ? Give an example?
7. What are proteins? Give an example?
8.What are Enzymes ? Give examples ?
9.What is the Peptide bond?
4 Marks
1. Give the sources of the following vitamins and name the diseases
caused by their deficiency a) A b)D c) E d) K
2. What are hormones ? Give one example for each ?
i) Steroid hormones ii) Polypeptide hormones iii) Amino acid derivatives
4. What are Fibrous and Globular proteins? Write the differentiate
between them ?
10. CHEMISTRY IN EVERY DAY LIFE
2 Marks
1. What are antacids ? Give examples.
2. What are antihistamines ? Give examples.
3. What are Tranquilizers ? Give example ?
4. What are barbiturates ?
5. What are analgesics ? How are they classified ?
6. What are narcotic analgesics ? Give examples.
7. What are non-narcotic analgesics ? Give examples.
8. What are antimicrobials ?
9. What are antiseptics? Give example.
10. What are antibiotics ? Give example .
11. What are disinfectants ? Give example.
12. What are the main constitutions of Dettol ?
13.What is tincture of iodine ? What is its use ?
14. What are anti fertility drugs ? Give example.
15. What are artificial sweetening agents ? Give example.
16. What are food preservatives ? Give example.
17. What is saponification ?
18.What is the difference between a soap and a synthetic detergent ?

11. ORGANIC CHEMISTRY

(NAMED REACTIONS)
2 Marks
1. Kolbe reaction explain?
2. Explain Reimer-Tiemer reaction ?
3. Explain Rosen-mund reaction?
4. Explain Etard reaction ?
5. Explain Gatter-mann reaction ?
6. Explain Gattermann - Koch reaction ?
7.Explain Diazotization reaction?
8. Explain Carbylamines reaction ?
9. Explain Sandmeyer reaction ?
10. Explain Williamsons’ synthesis reaction ?
11. Explain Etherification reaction ?
12. Explain HVZ reaction ?
13. Dehydration reaction explain ?
14.Explain Decarboxylation reaction ?
15. Explain Aldol reaction ?
16. Explain Cross- Aldol reaction ?
17. Explain Cannizaro reaction ?
4 Marks
1.Explain SN1 reaction with example ?
2. Explain SN2 reaction with example ?
3. Which compound in each of the following pairs will react faster in SN2
reaction with OH-
a) CH3Br or CH3I b) (CH3)3CCl or CH3Cl
4. Explain acidity of Phenol ?
8 Marks
5. preparation and properties of cyanides and isocyanides.
6. What are the General methods of preparation and chemical properties of
aniline ?
Prepared by
M. DHARMARAO
JL IN CHEMISTRY
GJC BOYS -SRIKAKULAM