Sec: SR_CO-SC (APEX) CTM-1 Date: 05-02-2025

Time: 3 Hrs Max. Marks: 300

PHYSICS SECTION – I [Link]: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. One mole of an ideal gas is taken from state A to state B by three different processes, (a) ACB
(b) ADB (c) AEB as shown in the P – V diagram. The heat absorbed by the gas is:

A) Greater in process (b) then in (a)

B) The least in process (b)
C) The same in (a) and (c)
D) Less in (c) then in (b)

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2. A thermodynamic process of one mole ideal monoatomic gas is shown in figure. The
efficiency of cyclic process ABCA will be:

P
100
A) 25% B) 12.5% C) 50% D) %
13
3. A gas undergoes an adiabatic process and an isothermal process. The two processes are plotted
on a
P – V diagram. The resulting curves intersect at a point P. Tangents are drawn to the two
curves at P. These make angles of 135 & 121 with the positive V-axis. If tan 59  5 / 3 , the gas
likely to be:

A) Monoatomic
B) Diatomic
C) Triatomic
D) A mixture of monoatomic & diatomic gases
4. In a cyclic process ABCA for an ideal gas. In AB, BC and CA process 50 J, 20 J and 5 J heat is
supplied to an ideal gas. In process AB internal energy of gas increases by 60 J and in process
BC work done by gas is 30 J. The increase in internal energy of gas in process CA is:
A) 50 J B) -50 J C) 75 J D) 55 J
5. Two identical rectangular rods of metal are welded end to end in series between
temperature 0 C and 100 C and 10 J of heat is conducted (in steady state process)
through the rod in 2.00 min. If 5 such rods are taken and joined as shown in figure
maintaining the same temperature difference between A and B, then the time in
which 20 J heat will flow through the rods is:

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A) 30 sec B) 2 min C) 1 min D) 20 sec

6. Two conducting movable smooth pistons are kept inside a non conducting, adiabatic container
with initial positions as shown. Gas is present in the three parts A, B & C having initial
pressure as shown. Now the pistons are released. Then the final equilibrium position length of
part A will be

L L L L
A) B) C) D)
8 4 6 5
7. An ice block at 0 C is dropped from height ‘h’ above the ground. What should be the value of
‘h’ so that it melts completely by the time it reaches the bottom assuming the loss of whole
gravitational potential enegy is used as heat by the ice? [Given: Lf= 80 cal/gm]
A) 33.6 m B) 33.6 km C) 8 m D) 8 km
8. One mole of an ideal gas at a temperature T1K expands slowly according to the law
P
= constant. Its final temperature is T2K. The work done by the gas is
V
R 2R
A) R  T2 -T2  B) 2R  T2 -T2  C)  T2 -T2  D)  T2 -T2 
2 3
9. n moles of a gas filled in a container at temperature T is in equilibrium initially. If
the gas is compressed slowly and isothermally to half its initial volume the work done
by the atmosphere on the piston is:

nRT nRT  1
A) B)  C) nRT  n 2   D) -nRT/n2
2 2  2 

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10. In the experiment of finding specific heat capacity of a liquid using calorimeter, the mass,
specific heat capacity and initial temperature of the sphere was 1000.0 gm, 0.50 cal/gmoC and
80.0 oC respectively. The mass of liquid and the calorimeter are 900.0 gm and 200.0 gm
respectively and initially both were at room temperature 20.0o C then the specific heat capacity
of unknown liquid in correct significant figure is-
cal cal cal cal
A) 2 B) 1.0 C) 3.00 D) 1.50
gmo C gmo C gmo C gmo C
11. On an X temperature scale, water freezes at-125.0 oX and boils at 375.0 oX. On a Y temperature
scale, water freezes at -70.0 oY and boils at -30.0oY. The value of temperature on X-scale equal
to the temperature of 50.0oY on Y-scale is:
A) 455.0oX B) -125.0oX C) 1375.0 oX D) 1500.0 oX
12. 1gm water at 100oC is given heat to convert it into steam at 100oC at 1 atmospheric pressure.
The change in internal energy of water is:- [Latent heat of vaporisation of water is= 540
cal/gm, Density of water vapour at 100oC = (1/1681) gm/cm3, Density of water at 100oC = 1
gm/cm3, 1 atmospheric pressure= 1.0 105 Nm-2 , Mechanical equivalent of heat=4.2 J/cal]
A) 540 cal B) 500 cal C) 40 cal D) 0
13. A hot black body emits the energy at the rate of 16 J m -2s -1 and its most intense radiation

corresponds to 20,000 A . When the temperature of this body is further increased and its most

intense radiation corresponds to 10,000 A , then the energy radiated in J m -2s -1 will be:
A) 4 B) 1 C) 64 D) 256
14. Equal volumes of water and alcohol when put in similar calorimeters take 100 sec and 74 sec.
respectively to cool from 50o C to 40o C . The thermal capacity (in cal/gm) of each calorimeter is
numerically equal to the volume (in cm3) of either liquid. The specific gravity of alcohol is 0.8.
If the specific heat capacity of water is 1 cal/g, the specific heat capacity of alcohol will be:
(Assume Newton’s law of cooling to be valid).
A) 0.6 cal/goC B) 0.8 cal/goC C) 1.6 cal/goC D) 1.8
cal/goC
15. Maxwell’s velocity distribution curve is given for the same quantity for two different
temperatures. For the given curves.

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A) T1 >T2 B) T1 <T2 C) T1  T2 D) T1 =T2

16. A gaseous mixture consists of equal number of moles of two ideal gases having adiabatic
exponents  1 and  2 and molar specific heats at constant volume Cv1 and Cv 2 respectively.
Which of the following statements is/are correct?
1   2
A) Adiabatic exponent for gaseous mixture is equal to
2
Cv1  Cv 2
B) Molar specific heat at constant volume for gaseous mixture is equal to
2
Cv1  Cv 2  R
C) Molar specific heat at constant pressure for gaseous mixture is equal to
2
2R
D) Adiabatic exponent for gaseous mixture is
Cv1  Cv 2

17. One mole of an ideal gas is kept enclosed under a light piston (area=10 -2m 2) connected by a
compressed spring (spring constant 100 N/m). The volume of gas is 0.83 m3 and its
temperature is 100k. The gas is heated so that it compresses the spring further by 0.1 m. The
work done by the gas in the process is : (Take R=8.3 J/K-mole and suppose there is no
atmosphere).
A) 3 J B) 6 J C) 9 J D) 1.5 J
18. 32 g of O2 is contained in a cubical container of side 1m and maintained at a temperature of
127 0C. The isothermal bulk modulus of elasticity of the gas in terms of universal gas constant
R is
A) 127 R B) 400 R C) 200 R D) 560 R
19. An insulated container is divided into two equal portions. One portion contains one mole of an
ideal monoatomic gas at pressure P and temperature T, while the other portion is a perfect
vacuum. If the intermediate partition is removed and the gas is allowed to expand, the change
in the internal energy of gas is.
3 RT
A) RT B) PV C) D) Zero
2 2

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20. Two solid bodies of equal mass m initially at T = 0oC are heated at a uniform and same rate
under identical conditions. The temperature of the first object with latent heal L1 and specific
heat capacity in solid state C1 changes according to graph 1 on the diagram. The temperature of
the second object with latent heat L2 and specific heat capacity in solid state C2 changes
according to graph 2 on the diagram. Based on what is shown on the graph, the latent heats L1
and L2 , and the specific heat capacities C1 and C2 in solid state obey which of the following
relationships:

A) L1  L 2 ; C1 < C 2 B) L1 <L2 ;C1 < C 2 C) L1 >L2 ;C1  C 2 D) L1 <L2 ;C1  C 2

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the
decimals, Mark nearest Integer only. Have to Answer All questions and question will be evaluated according
to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21. Three moles of an ideal gas being initially at a temperature To  273K were isothermally
expanded n = 5.0 times its initial volume and then isochorically heated so that the pressure in
the final state become equal to that in the initial state. The total amount of heat transferred to
the gas during the process equals Q=80kJ . Find the ratio  =C p / Cv for this gas

22. 20gm of He enclosed in a cylinder under a piston is transferred quasistically (i.e. slowly) from
state A at pressure 18 atm and volume 4 lit. to state B at pressure 15.8 atm and volume 8.4 lit.
as shown in the fig. Find the maximum temperature of the gas during the process. (in kelvin)

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23. 5gm of Helium having r.m.s speed of molecules 1000 m/s and 24 gm of oxygen having r.m.s
speed of 1000 m/s are introduced into a thermally isolated vessel. Find the r.m.s speed (in m/s)
oxygen individually when thermal equilibrium is attained. Neglect the heat capacity of the
vessel.
24. What amount of heat is to be transferred to nitrogen in the isobaric heating process for that gas
to perform the work A=2.0J?
25. Two bodies A and B have thermal emissivities of 0.01 and 0.81 respectively. The outer surface
areas of the two bodies are same. The two bodies emit total radiant power at the same rate. The
wavelength B corresponding to maximum spectral radiancy in the radiation from B is shifted
from the wavelength corresponding to maximum spectral radiancy in the radiation A by 1 m .
If the temperature of A is 5802 K, calculate temperature of B (in kelvin).

CHEMISTRY SECTION – I [Link]: 100

(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
26. Following two equilibrium is simultaneously established in a container
PCl5  g   PCl3  g   Cl2  g 
CO  g   Cl2  g   COCl2  g 

If some Ni(s) is introduced in the container forming Ni  CO  4  g  then at new equilibrium

A) PCl3 concentration will increase

B) PCl3 concentration will decrease
C) Cl2 concentration will remain same
D) CO concentration will remain same
27. The yield of product in the reaction 2 A  g   B  g   2C  g   Q kJ would be lower at:

A) low temperature and low pressure

B) high temperature & high pressure
C) low temperature and to high pressure
D) high temperature & low pressure

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28. 5.1 g NH 4 SH is introduced in 3.0 L evacuated flask at 3270 C.30% of the solid NH 4 SH

decomposed to NH 3 and H 2 S as gases. The K p of the reaction at 327 0 C is ( R  0.082 L atm

mol 1K 1 , Molar mass of S  32 mol 01 , molar mass of N  14 g mol 1 )

A) 1 104 atm 2 B) 4.9 103 atm 2 C) 0.242 atm2 D) 0.242 10 4 atm2
29. For the reaction, 2SO2  g   O2  g   2SO3  g  , H  57.2kJ mol 1 and K c  1.7  1016 , Which of

the following statement is INCORRECT?

A) The equilibrium constant large suggestive of reaction going completion and so no catalyst is
required.
B) The equilibrium will shift in forward direction as the pressure increase.
C) The equilibrium constant decreases as the temperature increases.
D) The addition of inert gas at constant volume will not affect the equilibrium constant.
30. Which of the following lines correctly show the temperature dependence of equilibrium
constant, K, for an exothermic reaction?

A) B and C B) C and D C) A and D D) A and B

31. At a certain temperature in a 5 L vessel, 2 moles of carbon monoxide and 3 moles of chlorine
were allowed to reach equilibrium according to the reaction, CO  Cl2  CO Cl2 .At equilibrium

, if one mole of CO is present then equilibrium constant  K c  for the reaction is:-

A) 1 B) 3 C) 2 D) 2.5
32. At 320 K, a gas A2 is 20% dissociates to A  g  . The standard free energy change at 320 K and 1

atm in J mol 1 is approximately:  R  8.314 JK 1; n 2  0.693; n 3  1.098 

A) 4281 B) 4763 C) 2068 D) 1844

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33. The vapour pressure of a pure liquid ‘A’ is 70 torr at 270C. If forms an ideal solution with
another liquid B. The mole fraction of B is 0.2 and total vapour pressure of the solution is 84
torr at 270C. The vapour pressure of pure liquid B at 270C is
A) 14 B) 56 C) 140 D) 70
34. 1.0 molar aqueous solution of an electrolyte A2 B3 is 60% ionised. The boiling point of the

solution at 1 atm is   0.52 K kg mol 1 

A) 274.76 K B) 377 K C) 376.4 K D) 374.76 K

35. The lowering of vapour pressure of 0.1 M aqueous solutions of NaCl , CuSO4 and K 2 SO4 are:
A) All equal B) In the ration of [Link] 1.5
C) In the ratio of [Link] D) In the ratio of 1.5: 1: 2.5
36. The Henry’s law constant for the solubility of N 2 gas in water at 298 K is 0.1105 atm. The
mole fraction of N 2 in air is 0.8. The number of moles N 2 from air dissolved in 10 moles of
water at 298 K and 5 atm pressure is:-
A) 4.0 104 B) 4.0 105 C) 5.0 104 D) 4.0 105
37. For which of the following vant Hoff’s factor is not correctly matched-
Salt Degree of dissociation   i

A) Na2 SO4 50 % 2

B) K 3  Fe  CN 6  75 % 3.25

C)  Ag  NH 3  2  Cl 80 % 1.8

D) Cr  NH 3 5 Cl  SO4 90 % 2.8

38. Assuming each salt to be 90 % dissociated, which of the following will have highest boiling
point?
A) Decimolar Al2  SO4 3 B) Decimolar BeCl2

C) Decimolar Na2 SO4 D) A solution obtained by equal volumes of (B) and (C)
39. Molar volume of liquid A (d=0.8 gm/ml) increase by factor of 2000 when it vapourises at
200K. Vapour pressure of liquid A at 200 K is [R=0.08 L-atm/mol-K] Molar mass of
A=80g/mol)
A) 0.4 atm B) 8 atm C) 0.8 atm D) 0.08 atm

40. Which of the following contain largest number of carbon atoms?

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A) 15 gm ethane, C2 H 6 B) 40.2 gm sodium oxalate, Na2C2O4
C) 72 gm glucose, C6 H12O6 D) 35 gm pentene, C5 H10
41. A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of CO2 . The
empirical formula of the hydrocarbon is
A) C2 H 4 B) C3 H 4 C) C6 H 5 D) C7 H8
42. The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1: 4. The ratio of
number of their molecule is:
A) 1: 8 B) 3: 16 C) 1: 4 D) 7: 32
43. The most abundant elements by mass in eh body of a healthy human adult are:
Oxygen (61.4%); Carbon (22.9%), Hydrogen (10.0%) ; and Nitrogen (2. 6%). The weight
which a 75 kg person would gain if all 1 H atoms are replaced by 2 H atoms is
A) 15 kg B) 37.5 Kg C) 7.5 Kg D) 10 Kg
44. 1 gram of a carbonate  M 2CO3  on treatment with excess HCl produces 0.01186 mole of CO2

.the molar mass of M 2CO3 in g mol 1 is:-

A) 1186 B) 84. 3 C) 118.6 D) 11.86
45. The ratio of mass percent of C and H of an organic compound  CX HY OZ  is 6:[Link] one molecule

of the above compound  CX HY OZ  contains half as much oxygen as required to burn one

molecule of compound C X HY completely to CO2 and H 2O . The empirical formula of compound

C X HY OZ is

A) C2 H 4O B) C3 H 4O2 C) C2 H 4O3 D) C3 H 6O3

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals, Mark nearest Integer only. Have to Answer All questions and question will be evaluated according
to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
46. A 20 ml mixture of C2 H 4 and C2 H 2 undergoes sparking in gas eudiometer with just sufficient
amount of O2 and shows contraction of 37.5 ml. The volume (in ml) of C2 H 2 in the mixture is.
47. 1.6 g of an organic compound containing sulphur, when treated with series of reagents,
produces H 2 SO4 which on reaction with BaCl2 produces 0.233 g of BaSO4 . Calculate % by mass
of S in the organic compound (Given: Atomic weight of Ba =137)

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48. In reaction A  2B  2C  D, initial concentration of B was 1.5 times of A , but at equilibrium

the concentration of A and B became equal. The equilibrium constant for the reaction is:
49. A molecule M associates in a given solvent according to the equation M   M n .For a certain

concentration of M, the van’t Hoff factor was found be 0.9 and the fraction of associated
molecules was 0.2. The value of n is:
50. In Carius method of estimation of halogens, 250 mg of an organic compound gave 141 mg of
AgBr. The percentage of bromine in the compound is: (Atomic mass Ag=108; Br=80)
MATHS SECTION – I [Link]: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
51. Set of all real values of p such that both the roots of the equation  p  5 x 2  2 px   p  4   0 are

positive, one is less than 2 and other is lying between 2 and 3 is

 49   49   49 
A)  , 24  B)  5,   C)   , 4    , D)  4, 
 4   4   4 

52. Let f(x) and g(x) be two quadratic polynomials

f  x   ax 2  bx  c, g  x   dx 2  ex  f where a, b, c, d,e, f  R .

If H(x)= f(x).g(x) where ad=1 and H(1)=1. H(2)=2, H(3)=3, then

 H  1  H  5  
    where   represents fractional function  is
 H  0   H  4  

5 2 3 4
A) B) C) D)
7 7 7 7
2 2
2  1   1 
53. If  ,  are the roots of 3 x  5 x  7  0 then the value of     is
 3  5   3  5 
67 67 109 109
A) B) C) D)
63 441 441 63
54. The quadratic equations x 2  6 x  a  0 and x 2  cx  6  0 have one root common. The other
roots of the first and second equations are integers in the ratio 4:3. Then ‘a’ possible common
root is
A) 3 B) 2 C) 1 D) 5

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
55. If  and  are the roots of the quadratic equation, x 2  x sin   2sin   0,   0,  , then
 2

 12   12
is equal to :
 12   12     24
212 212 212 26
A) 12
B) 12
C) 6
D) 12
 sin   4   sin   8   sin   8  sin   8 
2 x 2  3x  2
56. Let a and b be greatest and least value of the expression , x  R respectively then
2 x 2  3x  2
The quadratic with a, b as root is
A) 7 x 2  15 x  7  0 B) 7 x 2  50 x  7  0 C) 15 x 2  7 x  15  0 D) 50 x 2  7 x  50  0
57. Coefficient of variation of two distributions are 60 and 70, and their standard deviations are 21
and 16, respectively. Then sum of the arithmetic mean is
A) 57.85 B) 22.85 C) 35.85 D) 52.85
58. The mean of two samples of sizes 200 and 300 were found to be 25, 10 respectively and their
standard deviations are 3 and 4 respectively. The variance of combined sample of size 500 is
A) 64 B) 65.2 C) 67.2 D) 64.2
59. Two variables X and U are related by the relationship X = 5 + 2U. The mean and the coefficient
of variation of X are 10 and 2.6 respectively. Then which of the following options is/are
INCORRECT?
A) Coefficient of variation of U is 1.3
B) Coefficient of variation of U is 5.2
C) Mean of U is 2.5
D) Mean of U is 20
60. Consider the given data with frequency distribution
xi 3 8 11 10 5 4
then the mean deviation about the mean of above data and The mean
fi 5 2 3 2 4 4

deviation about the median of the above data is

A) 5.4 B) 5.1 C) 5.7 D) 5.3
n n
102 S  S
61. Define a sequence S  n  3721   
1681 n  1 then the value of
61S
50
?
49
51

A) 2 B) 41 C) 61 D) 30
n  n  1 n  2  n  3   n
1
62. If S 
n
then lim    ?
12  tn
r 1
r 

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Where [.] denotes the cell (x).
(Least integer greater than or equal to x)
A) 2 B) 1 C) 3 D) 0
n
1
63. Let   lim  2
then length of the tangent draw on from (-1,4) to the circle
n 
k 1 4k  1
2 2
x  y  8 x  6 y  2  1  0 is
A) 6 B) 7 C) 4 D) 3
 
k
64. Let L   and  be a set having LL elements.
nk
K 1 n 1 2
m= no. of reflexive relations defined on 
n= no. of symmetric relations defined on 
m
Then ?
n
A) 2 B) 4 C) 3 D) 6
21
87
65. If  16n
n 1
2
 8n  3
N

And let G , G ,....G be N- geometric means inserted between 4 and 9.

1 2 N

Define  : N  N such that  ( n) =no .of positive divisors of (n)

N

Then    G   i
 i 1 
A) 62 B) 64 C) 49 D) 63
 x, y, z    :  x, y, z  is a  3

66. Let S  
 solution of (*), x, y, z  0 
Where (*) represents the system of equations 4x+18/y=14, 2y+9/z=15, and 9z+16/x=17
Then n(s) =?
A) 4 B) 1 C) 0 D) 2
2
67. The sum of all values of '  ' for which the equation 4  x     12 has a solution and    in 

1,   ,[.] denotes greatest integer less than or equal to x.

A) 13 B) 7 C) 6 D) 11
68. Let '  ' be the greatest integer for which 5x2-16, 2x ,  are distinct consecutive terms of an 2

arithmetic progression, where x   if the common difference of the AP is m/n, such that ‘m’
and ‘n’ are relatively prime than m+n=?
A) 133 B) 147 C) 143 D) 158

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69. Let a,b,c,d  R be an AP
xa xb xac
And ( x)  x  b xc x 1
xc xd x b  d
2

And   x dx  4 then positive common difference of this AP is

0

A) 3 B) 2 C) 1 D) 4
1 1 1
70. The sum of the series 1     .....
4.2! 16.4! 64.6!

e 1 e 1 e 1 e 1
A) B) C) D)
2 e 2 e e 2e

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the
decimals, Mark nearest Integer only. Have to Answer All questions and question will be evaluated according
to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
71. Let  and  be the roots of x 2  x  1  0 , with    . For all positive integers n, define

n  n  89  b n 
an  , n  1 b1  1 and bn  an 1  an1 , n  2 then   n  is equal to
   3 n 1 10 

72. If  ,  are the roots of   x 2  x   x  5  0 and 1 , 2 are the two values of  for which  ,  are

   
connected by the relation   4 , then the value of 1  2  ?
  2 1

73. For positive integer m and n such that m  10  n  1 , both the mean and the median of the set
m, m  4, m  10, n  1, n  2, 2n are equal to n. What is m + n ?
74. If 1 ,  2 ,  3 ,......,  2019 are distinct zeroes of the polynomial P  x   x 2019  19 x 2018  1 and f(x) be

 1 
another polynomial whose degree is 2019 and satisfying f  i    0 for i=1, 2, 3, …….,
 i 
361 f  1
2019. Then the value of is
f 1

75. Consider the quadratic equation  c  5 x 2  2cx   c  4   0, c  5 . Let S be the set of all integral

values of c for which one root of the equation lies in the interval (0, 2) and its other root lies in
the interval (2, 3). Then the least integral value of c in S is

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