Experiment 14
in
thegiyensalt by qualitative analysis.
negative ions present
To detect the
positive and Laboratory Manual)
of
Aim : Experiment No. 7.l
|Reference:
stand
Apparatus Reguired :
holdo lest tabe
Test tbe IRat tuhe
of inorganic salt : Inference
[A] Dry tests Observation
SI. No.
Test may be
1. Colour Blue
Smell
2.
Smell
coS,NOS,Br
ayo absert
3. Heat 0.5g of salt envolved
in a dry test tube may be
Flame test
Grenish Blul
4.
Borax bead test
5.
6.
Charcoal cavity test
Cobalt Nitrate test
7
anion :
[B] Tests for detection of
Inference
Observation
SI. No. Test
1. 0.1g salt + dilute H,SO,
on heating envolved absent
46
2. 0.1g salt + 1 mL
concentrated No ervolved
H,SO, on heating No3
3. Water extract or 'clified sodiumAuote pptisiotasneg So
carbonate extract by dilute HCItol3chi (nsoluble i
Psesent
+ BaCl, ConcBAneution of HNO3
4 Water extract of salt or sodium 3
carbonate extract + acetic acid No yelouo ppt
(till solution becomes acidic) +
lead acetate Obtained cbsent
5 Water extract or sodium.
carbonate extract + concentrated No Hed colous 04
HNO, + ammonium molybdate albsert
Golion
[C] Confirmatory tests of anion :
SI. No. Test Observation Inference
0.S. +ead
Sulphte acectte. ppts So
Sotuion
D], Chemical equations of anion :
NagsOg + Ct C00)2Pb Pbso, + 20hig (00 Na
eact sulpate.
(cote ppt
47
|E) Group tests for detection of cation:
Preparation of original solution : Original solution (0.S.) = Salt +
SL. No. Test Observation
Infere neSvesi
1. Salt + dilute NaOH
Group (0) is hse
solution, on heating Wo ppt obtai ned
2 0.S. + dilute HCI No. ppt o btun ed Group (1) is sen
3. 0.S. + dilute HCI + on Group (1) is
passing H,S gas Black ppt obain ed
4 0.S. + 2-3 drops of Group (l) isohseat
concentrated HNO,+ heat
+ 0.2 g NH,CI + add
NH,OH solution in excess NO. ppt obtained
(tillit smells of ammonia)
5 0.S. + 0.2g NH,CI+ Group (TV) is bsont
NH,OH (add till it smells
of ammonia) + on passing
H,S gas No. ppt obtincd
6. 0.S. + 0.2g NH,CI + Group (V) is esen4
NH,OH (add till it smells
of ammonia) + 0.5g
(NH),CO, No. pot Obtained
7. 0.S.+. 0.2g NH,CI + Group (VI) is Ahsent
NH,OH(add till it smells
of ammonia) + Na,HPO,
solution Wo. ppt obtoined
F] Analysis of group cations:
SI. No. Test Observation Inference
+2
0.s. + Kue (n (hocol ate PPt obained (onfirmed
48
(GI Confirmatory tests of cation :
SL. No. Test Observation Inference
0.S + kufeCnG Qhocolate Ppt
obtained Congirmed
HJ Chenmical equations of cation-:
u (Ntg)4] 60, +4 CHs(004 usOy t4CHg (00NH4.
[I] Result table :
Cation of inorganic Anion of inorganic Molecular formula and
salt and its náme salt and its name name of inorganic salt
+2 So4
Gpgn salplate.
Sign of subject teacher/Lab teacher
49
