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Inorganic Chemistry: Periodic Table Quiz

The document contains a set of questions and answers related to the periodic table and inorganic chemistry, focusing on concepts such as atomic and ionic radii, isoelectronic series, and properties of elements. It includes multiple-choice questions, subjective questions, and an answer key. The content is designed for educational purposes, likely for students studying chemistry.

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0% found this document useful (0 votes)
58 views2 pages

Inorganic Chemistry: Periodic Table Quiz

The document contains a set of questions and answers related to the periodic table and inorganic chemistry, focusing on concepts such as atomic and ionic radii, isoelectronic series, and properties of elements. It includes multiple-choice questions, subjective questions, and an answer key. The content is designed for educational purposes, likely for students studying chemistry.

Uploaded by

vipulakarte21
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

PERIODIC TABLE (Inorganic Chemistry)

DPP-02
Only one correct:
1. For the element X, student Surbhi measured its radius as 102 nm, [Link] as 113 nm and Mr.
agarwal as 100 nm using same apparatus. Their teacher explained that measurements were
correct by saying that recorded values by three students were
(A) Crystal, vander Waal and covalent radii
(B) Covalent, crystal and vander Waal radii
(C) Vander Waal, ionic and covalent
(D) None is correct
2. Which of the following combination contains only isoelectronic series :
(A) N3− , O2− , Cl− , Ne (B) F − , Ar, S 2− , Cl−
(C) P 3− , S 2− , Cl− , Ar (D) N3− , F − , O2− , Ar
3. Which among the following species has the same number of electrons in its outermost as well as
penultimate shell ?
(A) Mg 2+ (B) O2− (C) F − (D) Ca2+
4. The specie having smallest ionic radius is :-
(A) Al3+ (B) Ba2+ (C) K + (D) Mg 2+
More than one correct:
5. The correct order of radii is:
(A) N < Be < B (B) F − < O2− < N3− (C) Na > Li < K (D) Fe2+ > Fe3+ > Fe4+
6. Choose the correct statement.
(A) Be and Al are not in same group.
(B) All the transition metal correspond to d-block.
(C) Be and Al are having lot of similarities in their properties.
(D) The atomic radius gradually decreases from Sc to Zn.
Subjective :
7. A monoatomic anion of unit charge contain 45 neutrons and 36 electrons. What is atomic mass
number of element and in which group of periodic table does it lie.
8. Arrange in decreasing order of atomic size : Na, Cs, Mg, Si, Cl.
9. In the ionic compound KF, the K + and F − ions are found to have practically radii, about 1.34Å each.
What do you predict about the relative covalent radii of K and F ?
10. Which one of the following pair would have a large size :
(i) K or K + (ii) Br or Br (iii) O2− or F − (iv) Li+ or Na+
(v) P or As (vi) Na+ or Mg +2
1
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PERIODIC TABLE (Inorganic Chemistry)

ANSWER KEY
DPP-02
1. A 2. C 3. D 4. A 5. BCD 6. ABC
7. Atomic mass No. 80, Group No. 17
8. (Cs > Na > Mg > Si > CI ) 9. (rk > 1.34Å > rF )
10. (i) K (ii) Br − (iii) O2− (iv) Na+ (v) As (vi) Na+ ]

2
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Common questions

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Be and Al show similarities, particularly in their resistance to oxidation, forming stable oxoanions, and forming oxides with amphoteric properties. This grouping is significant as it demonstrates elements' behavior based on periodic trends rather than just group alignment, highlighting the concept of diagonal relationships in the periodic table .

Given that the ionic radii of K+ and F− are similar at approximately 1.34 Å, the covalent radius of K is expected to be larger than F. This suggests that in covalent bonding, potassium's larger covalent radius causes more electron cloud deformation, revealing differences in atomic size and bonding characteristics .

The ionic radius is determined by the nuclear charge and the electron configuration, including the number of electrons and their distribution among available energy levels. Among the given options, Al3+ has the smallest ionic radius due to its high positive charge, which pulls the remaining electrons closer to the nucleus .

The term 'ionic radius' is preferred over 'atomic radius' for ions since it specifically reflects an ion's size after electron loss or gain, impacting electron cloud size directly during compound formation, unlike the neutral atom radius. Using KF as an example, the equal ionic radii of K+ and F− illustrates ionic interactions' specific effects forming stable structures, which atomic radii alone can't quantify .

To determine an element's group, analyze its electron configuration and count after adjusting for ionic charges. For a monoatomic anion with 36 electrons, deducing the original electron count indicates loss or gain, with elements structured to fulfill octet completion typical to certain groups. Such an analytic process shows the element aligning with Group 17 requirements based on electron count influence by ionic charge .

Atomic size is influenced by the increasing number of electron shells as you move down a group in the periodic table, and the increased effective nuclear charge across a period. Therefore, the correct order of atomic size is Cs > Na > Mg > Si > Cl, with Cs being the largest because it has the most electron shells, and Cl being the smallest due to the higher effective nuclear charge without additional shells .

Within transition metals, the atomic radius generally decreases from Sc to Zn due to an increase in nuclear charge, despite additional electrons being added to the d-orbital. These electrons do not efficiently shield the increased positive charge which results in a stronger attraction between the nucleus and the electron cloud, leading to a diminished atomic radius .

An isoelectronic series consists of ions and atoms that have the same number of electrons. The combination P3−, S2−, Cl−, Ar fits these criteria as each of these has 18 electrons, making them part of the same isoelectronic series .

An anion with 36 electrons suggests it's derived from an element in Group 17, the halogens, as gaining one electron from an atomic number of 35 results in a stable electron configuration. The presence of 45 neutrons alongside implies it is an isotope of bromine, confirming its placement in Group 17 due to neutron variation among natural isotopes .

The measurements of radius for element X recorded by Surbhi, Mr. Gupta, and Mr. Agarwal were 102 nm, 113 nm, and 100 nm, respectively. These differences signify different types of radii measurements: Surbhi's measurement corresponds to the crystal radius, Mr. Gupta's to the van der Waals radius, and Mr. Agarwal's to the covalent radius .

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