MUMBAI / AKOLA / DELHI / KOLKATA / GHAZIABAD / NASHIK / GOA / BOKARO / PUNE
IIT – JEE/NEET: 2025/2026 DATE: 08/12/2024
TIME: 1:30 Hr. TOPIC: HEAT & THERMODYNAMICS MARKS: 100
SINGLE CORRECT ANSWER TYPE
This section contains 25 multiple choice questions. Each question has 4 options (A), (B), (C) and
(D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The temperature of n-moles of an ideal gas is increased from T0 to 2T0 through a process p = . Find work done in this process.
T
2. When an ideal diatomic gas is heated at constant pressure, the fraction of the heat energy supplied, which increases the internal
energy of the gas, is:
2 3
(a) (b)
5 5
3 5
(c) (d)
7 7
3. At 27°C two moles of an ideal monatomic gas occupy a volume V. The gas expands adiabatically to a volume 2V. Calculate.
(a) Final temperature of the gas
(b) Change in its internal energy and
(c) The work done by the gas during the process
[R=8.31 J/mol-K]
5
4. A gaseous mixture enclosed in a vessel consists of one gram mole of a gas A with = and some amount of gas B with =
3
7
at a temperature T. The gases A and B do not react with each other and are assumed to be ideal. Find the number of gram
5
19
moles of the gas B if for the gaseous mixture is .
13
5. Heat energy absorbed by a system in going through a cyclic process as shown in the figure [V in litres and p in kPa] is:
30
10
10 30 p
(a) 107J (b) 104J
(c) 10 J
2
(d) 103J
6. Two Carnot engines A and B are operated in succession. The first one, A receives heat from a source at T 1 = 800K and rejects
to sinks at T2 K. The second engine B receives heat rejected by the first engine and rejects to another sink at T 3 = 300K. If the
work outputs of two engines are equal, then the value of T 2 is:
(a) 100K (b) 300K
(c) 550K (d) 700K
7. When a gas expands along AB, it does 500J of work and absorbs 250J of heat. When the gas expands along AC, it does 700J
of work and absorbs 300J of heat.
(a) How much heat does the gas exchange along BC?
(b) When the gas makes the transition from C to A along CDA, 800J of work are done on it from C to D. How much heat
does it exchange along CDA?
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p
D C
A B
V
8. One mole of an ideal gas is taken through a cyclic process. The minimum temperature during the cycle is 300K. Then, net
exchange of heat for complete cycle is:
U
2U0 A B
U0 C
D
V0 V
2V0
(a) 600R In 2 (b) 300 R In 2
(c) –300 R In 2 (d) 900 R In 2
9. p-T diagram of one mole of an ideal monatomic gas is shown. Processes AB and CD are adiabatic. Work done in the complete
cycle is:
p
B C
A D
O T 3T 4T 5T T
(a) 2.5RT (b) –2RT
(c) 1.5RT (d) –3.5RT
10. An ideal monoatomic gas undergoes a process in which its internal energy U and density vary as U=constant. The ratio of
change in internal energy and the work done by the gas is:
3 2
(a) (b)
2 3
1 3
(c) (d)
3 5
11. An ideal monoatomic gas is taken through a process dQ = 2dU. The molar heat capacity for the process is (where dQ is heat
supplied and dU is a change in internal energy)
(a) 2.4R (b) 3R
(c) R (d) 2R
12. One mole of a monoatomic ideal gas undergoes the process A→B in the given p-V diagram. The molar heat capacity for this
process is:
p
6p0 B
3p0
A
V
V0 5V0
3R 13R
(a) (b)
2 6
5R
(c) (d) 2R
2
p
13. For an adiabatic expansion of a perfect gas, the value of is equal to:
p
1
V V
(a) − 2 (b) −
V V
V V
(c) − (d) − 2
V V
14. In the figure shown, the processes leveled 1, 2, 3 and 4 are
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p
1
2 3
O T
(a) Isothermal, adiabatic, isobaric, isochoric (b) Isothermal, adiabatic, isochoric, isobaric
(c) Isothermal, isobaric, isochoric, adiabatic (d) Adiabatic, isochoric, Isothermal, isobaric
15. Temperature of 2 moles of a monatomic gas is increased from T to 2T. Match the following two columns.
Column I Column II
(a)Work done by gas in isobaric process (i)3RT
(b)Change in internal energy in isobaric process (ii)4RT
(c)Work done by gas in adiabatic process (iii)2RT
(d)Change in internal energy in an adiabatic process (iv)None of these
16. Match the following two column:
Column I Column II
(a)Isobaric expansion (i)W > U
(b)Isochoric cooling (ii)W < U
(c)Adiabatic expansion (iii)Q = U
(d)Isothermal expansion (iv)Q < U
17. The radius of a ring is R and its coefficient of linear expansion is . If the temperature of ring increases by , then its
circumference will increase by:
(a) R (b) 2 R
(x) R (d) R
2 4
18. Figure shown the isotherms of a fixed mass of an ideal gas at three temperature T A, TB and TC, then:
1
V
A
p
O
(a) TA > TB > TC (b) TA < TB < TC
(c) TB < TA < TC (d) TA = TB = TC
19. A polyatomic gas with n degree of freedom has a mean energy per molecule given by:
n 1
(a) RT (b) RT
2 2
n 1
(c) KT (d) RT
2 2
20. In a process, the pressure of a gas remains constant. If the temperature is doubled, then the change in the volume will be:
(a) 100% (b) 200%
(c) 50% (d) 25%
21. The graph which represents the variation of mean kinetic energy E of gas molecules with temperature t°C is:
E
E
(a) (b)
toC toC
E E
(d)
toC toC
2
22. A gas is found to obey law p V = constant. The initial temperature and volume are T 0 and V0. If the gas expands to a volume
3V0, its final temperature becomes:
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T0 T
(a) (b) 0
3 3
(c) 3T0 (d) None of these
23. A cyclic process ABCD is shown in the p-V diagram. Which of the following curves represents the same process?
p
A B
V
p
A B
A B
(b)
(a)
C
C
D D
T T
p p
A A B
(d)
D C C D
T T
24. Variation of internal energy with density of one mole of monoatomic gas is depicted in the figure shown. Corresponding
variation of pressure with volume can be depicted as (Assuming the curve is rectangular hyperbola).
U
P P
(a) (b)
V V
P
P
(d)
V V
25. The number of molecules per unit volume of a gas is given by:
p kT
(a) (b)
kT p
p RT
(c) (d)
RT p
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